BIPOLAR PLATE OF AN ELECTROCHEMICAL CELL WITH LOW THICKNESS
20170279132 · 2017-09-28
Assignee
Inventors
Cpc classification
H01M8/0265
ELECTRICITY
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0267
ELECTRICITY
International classification
Abstract
The invention pertains to a bipolar plate in which each of the distribution channels is located facing a dividing rib of the opposite conductive sheet; and in which said distribution channels include portions of various depths that are arranged so as to form a longitudinal alternation between: an enhanced distribution zone, in which: the distribution channels have a combined cross section of a high distribution value, and the cooling channels have a combined cross section of a low cooling value; and an enhanced cooling zone, in which: the distribution channels have a combined cross section of a value that is lower than the high distribution value, and the cooling channels have a combined cross section of a value that is higher than the low cooling value.
Claims
1. Bipolar plate, intended to be positioned between two electrodes of adjacent electrochemical cells, including a first conductive sheet and a second conductive sheet each having an inner face and an outer face, the conductive sheets being joined to one another by the inner faces, and each including reliefs at least partially delimiting, on the outer faces, distribution channels that are intended to distribute reactive gases, the distribution channels of one and the same conductive sheet being separated pairwise by a dividing rib intended to make contact with one of said electrodes, and on the inner faces, cooling channels that are intended to allow the flow of a heat-transfer fluid; wherein each of said distribution channels is located facing a dividing rib of the opposite conductive sheet; and wherein said distribution channels include portions of various depths that are arranged so as to form a longitudinal alternation between: a first zone, referred to as an enhanced distribution zone, in which: the distribution channels have a combined cross section of a first value, referred to as a high distribution value, and the cooling channels have a combined cross section of a first value, referred to as a low cooling value; and a second zone, referred to as an enhanced cooling zone, in which: the distribution channels have a combined cross section of a value that is lower than the high distribution value, and the cooling channels have a combined cross section of a value that is higher than the low cooling value.
2. Bipolar plate according to claim 1, in which the distribution channels have, in the enhanced distribution zones, a portion the depth of which is referred to as the nominal depth; and, in the enhanced cooling zones, a portion the depth of which, referred to as the decreased depth, is less than the nominal depth.
3. Bipolar plate according to claim 2, in which each distribution channel includes a back wall connected to the adjacent dividing ribs, the portions of nominal depth making mechanical contact with the opposite dividing ribs via their back wall.
4. Bipolar plate according to claim 1, in which, in the enhanced distribution zones, some distribution channels have a portion the depth of which is referred to as the nominal depth, and other distribution channels have a portion the depth of which, referred to as the decreased depth, is less than the nominal depth.
5. Bipolar plate according to claim 4, in which at least one cooling channel extends, in the enhanced distribution zones, between the back wall of a portion of decreased depth of a distribution channel and an opposite dividing rib.
6. Bipolar plate according to claim 5, in which, in the enhanced distribution zones, said cooling channel is transversally delimited by two portions of nominal depth of distribution channels of the same conductive sheet.
7. Bipolar plate according to claim 1, in which a distribution channel has a portion of decreased depth in a first enhanced distribution zone, and a portion of nominal depth in a second enhanced distribution zone that is successive to the first zone.
8. Bipolar plate according to claim 1, in which the cooling channels have, in the enhanced distribution zones, a transverse dimension, in the plane of the bipolar plate, of a first value and, in the enhanced cooling zones, a transverse dimension of a value that is higher than said first value.
9. Bipolar plate according to claim 8, in which, in at least one enhanced cooling zone, there is a communication of fluid between all of the cooling channels.
10. Bipolar plate according to claim 1, in which the distribution channels of a conductive sheet that is intended to make contact with a cathode of an electrochemical cell have portions of nominal depth in the enhanced distribution zones.
11.Electrochemical cell, including: a bipolar plate according to claim 1; a membrane/electrode assembly, one of said electrodes of which is in contact with the first or the second conductive sheet of the bipolar plate.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0031] Other aspects, aims, advantages and features of the invention will become more clearly apparent upon reading the following detailed description of preferred embodiments thereof, which description is provided by way of non-limiting example and with reference to the appended drawings, including
[0032]
[0033]
[0034]
[0035]
[0036]
DETAILED DESCRIPTION OF PARTICULAR EMBODIMENTS
[0037] In the figures and in the subsequent description, the same references represent identical or similar elements. Moreover, the various elements are not represented to scale so as to enhance the clarity of the figures. Moreover, the various embodiments and variants are not mutually exclusive and can be combined with one another.
[0038] Various embodiments and variants will be described with reference to a fuel cell and in particular to a PEM (proton exchange membrane) fuel cell, the cathode of which is supplied with oxygen and the anode of which with hydrogen. However, the invention is applicable to any type of fuel cell, and in particular to those operating at low temperatures, i.e. temperatures below 200° C., and to electrochemical electrolyzers.
[0039]
[0040] The electrochemical cells here belong to a stack of cells of a fuel cell. Each electrochemical cell includes a membrane/electrode assembly 2 formed from an anode 3 and a cathode 4 that are separated from each other by an electrolyte 5, here comprising a polymer membrane. The membrane/electrode assemblies 2 of the electrochemical cells are placed between bipolar plates 1 that are capable of bringing reactive species to the electrodes and of removing the heat produced during the electrochemical reaction.
[0041] A direct orthonormal coordinate system (X, Y, Z) is defined here and will be referred to in the rest of the description, where the Z axis is oriented along the axis of stacking of the electrochemical cells and along the thickness of the bipolar plate, and where the X and Y axes define a plane parallel to the plane of the bipolar plate.
[0042] In a manner known per se, each electrode 3, 4 includes a gas diffusion layer (GDL), placed in contact with a bipolar plate 1, and an active layer located between the membrane 5 and the diffusion layer. The active layers are the site of electrochemical reactions. They include materials allowing the oxidation and reduction reactions at the respective interfaces of the anode and cathode with the membrane to take place. The diffusion layers are made from a porous material that permits the diffusion of the reactive species from the distributing circuit of the bipolar plates 1 to the active layers, and the diffusion of the products generated by the electrochemical reaction to the same distributing circuit.
[0043] Each bipolar plate 1 is formed from two conductive sheets 10, 20 that are bonded and joined to one another, these conductive plates being stamped so as to form circuits for distributing reactive gases over the electrodes 3, 4 of each of the electrochemical cells, and a cooling circuit located between the conductive sheets 10, 20. Thus, a first conductive sheet 10, referred to as an anodic conductive sheet, is intended to make contact with the anode 3 of a membrane/electrode assembly 2 of an electrochemical cell, while the second conductive sheet 20, referred to as a cathodic conductive sheet, is intended to make contact with the cathode 4 of a membrane/electrode assembly 2 of an adjacent electrochemical cell.
[0044] As also illustrated in
[0045] The conductive sheets 10, 20 take the form of laminae, or elementary plates of low thickness, made of an electrically conductive material, for example a metal or even a composite, for example a graphite-filled composite. The thickness may be of the order of a few tens of microns up to a few hundred microns in the case of metal sheets, for example from around 50 μm to 200 μm.
[0046] Each conductive sheet includes reliefs, or embossments, obtained for example by stamping or forming in a press, the form of which on one face is complementary to the form on the opposite face. These reliefs form, on the outer faces 11, 21, the circuits for distributing reactive gases and, on the inner faces 12, 22, a cooling circuit including channels through which a heat-transfer fluid is intended to flow.
[0047] As also illustrated in
[0048] It is possible to define a local depth of a distribution channel as the dimension along the Z axis between the back wall of the channel and a plane passing through the adjacent dividing ribs. It is also possible to define a local width of a dividing rib as the dimension of the rib in cross section. Furthermore, the term “adjacent”, or “transversally adjacent”, is understood to mean juxtaposed along an axis that is transverse to the longitudinal axis of a given channel.
[0049] According to the invention, each distribution channel is located facing a dividing rib of the opposite conductive sheet. The term “located facing” is understood to mean that the channel is located in line with, i.e. perpendicular to, a dividing rib along the Z axis corresponding to the thickness of the bipolar plate. More specifically, the back wall of a distribution channel of a conductive sheet is located in line with an opposite dividing rib along the Z axis, and not in line with a back wall of a distribution channel of the opposite conductive sheet. Furthermore, the term “distribution channel” is understood to mean some or all of the distribution channels of one and the same distribution network. Lastly, each distribution channel is located facing a dividing rib, over some or all of its length.
[0050] Thus, by virtue of this arrangement of the distribution channels of the two conductive sheets, the depth of one distribution channel is not limited by that of a distribution channel of the opposite conductive sheet, unlike in the example of the prior art described above. The depth of the distribution channels may therefore vary along the longitudinal axis between a nominal value for which the back wall advantageously makes contact with the opposite dividing rib, and a value, referred to as the decreased value, that is lower than the nominal value. Stated otherwise, each distribution channel may include portions of nominal depth and portions of decreased depth. The term “nominal depth” is understood to mean a depth ensuring a flow cross section that allows an optimal flow of fluid.
[0051] In this configuration, the thickness of the bipolar plate is then substantially decreased with respect to that of the bipolar plate according to the example of the prior art described above. Specifically, the thickness of the bipolar plate here corresponds substantially to the nominal depth of a distribution channel, by virtue of the thicknesses of the conductive sheets, while the thickness of the bipolar plate in the example of
[0052] Moreover, in order to ensure, in addition, that the reactive gases and the heat-transfer fluid flow properly, the distribution channels include portions of various depths, these portions being arranged so as to form a longitudinal alternation between: [0053] a first zone, referred to as an enhanced distribution zone, in which: [0054] the distribution channels Ca, Cc have a combined cross section of a first value, referred to as a high distribution value, and [0055] the cooling channels Cr have a combined cross section of a first value, referred to as a low cooling value; and [0056] a second zone, referred to as an enhanced cooling zone, in which: [0057] the distribution channels have a combined cross section of a value, referred to as the low distribution value, that is lower than the high distribution value, and [0058] the cooling channels have a combined cross section of a value, referred to as the high cooling value, that is higher than the low cooling value.
[0059] The term “combined cross section”, or “combined flow cross section”, is understood to mean the sum of the cross sections of the passage of fluid through the channels in question, in a plane that is transverse to the longitudinal axis of the channels. This may be a combined flow cross section relating to the reactive gases or to the heat-transfer fluid. The high distribution value is preferably higher than the low cooling value, and a low distribution value is preferably lower than a high cooling value.
[0060] Furthermore, the term “alternate” is understood to mean that the various zones come one after the other in turns repeatedly, either periodically or not periodically, along the longitudinal axis of the channels.
[0061] Thus, the zones in which the distribution of the reactive gases is enhanced and the zones in which cooling by means of the flow of the heat-transfer fluid is enhanced alternate along a longitudinal axis of the channels. In particular, the value of the combined flow cross section of the distribution channels in the enhanced distribution zones is higher than the value that it has in the enhanced cooling zone, which results in a decrease in local head losses in the distribution channels at the enhanced distribution zones, thereby improving the local flow of the reactive gases. Furthermore, the value of the flow cross section of the cooling channels in the enhanced cooling zone is higher than the value that it has in the enhanced distribution zone, which results in a decrease in local head losses in the cooling channels at the enhanced cooling zones, thereby improving the local flow of the heat-transfer fluid.
[0062]
[0063] Some of the anodic distribution channels have a portion of nominal depth, here the anodic channel Ca1, Ca3, while others have a portion the depth of which, referred to as the decreased depth, is less than the nominal depth, here the channels Ca2, Ca4. In this example, the portions Da1, Da3 of nominal depth of the anodic channels are such that the back wall of the channels Ca1, Ca3 is in mechanical contact with the corresponding cathodic rib Nc1, Nc3. The portion Sa2, Sa4 of decreased depth of the channels Ca2, Ca4 is such that the corresponding back wall does not make contact with the facing cathodic rib Nc2, Nc4, but it nonetheless allows reactive gases to flow.
[0064] The cooling channels are located between two distribution channels of one and the same conductive sheet the depth of which is nominal, and are superposed onto distribution channels of the opposite conductive sheet the depth of which is decreased. Thus, the cooling channel Cr1 is superposed onto the portion Sa2 of the anodic channel Ca2 and is transversally bordered by the portions Dc1, Dc2 of the cathodic channels Cc1 and Cc2. It is therefore delimited along the Z axis by the back wall of the anodic channel Ca2 and by the opposite cathodic rib Nc2, and along the Y axis by the lateral walls of the cathodic channels Cc1 and Cc2.
[0065] This configuration is referred to as an enhanced distribution configuration to the extent that the value of the combined flow cross section of the cathodic and anodic distribution channels is a first high distribution value. Specifically, multiple distribution channels are of nominal depth, here namely the cathodic channels Cc1, Cc2, Cc3 and the anodic channels Ca1, Ca3. Thus, the distribution channels the depth of which is nominal exhibit low local head losses, thereby helping to ensure that the reactive gases flow properly.
[0066] This configuration also results in a local mechanical reinforcement of the bipolar plate to the extent that the lateral walls of the channels of nominal depth making contact with the opposite rib here allow the mechanical clamping forces to be transmitted directly into a membrane/electrode assembly of a membrane/electrode assembly cell of the neighbouring cell. With a constant clamping force, there is thus a decrease in the mechanical stresses to which the conductive sheets are subjected with respect to the configuration of
[0067]
[0068] The value of the combined flow cross section of the cooling channels is here higher than the value that it has in the enhanced distribution zone illustrated in
[0069] In this example, the anodic and cathodic distribution channels all have portions of decreased depth, such that the distribution channels are not in local mechanical contact with an opposite dividing rib, and a communication of fluid between the cooling channels Cr1 and Cr2 is ensured. This is due to the fact that the depths of the cathodic channels Cc2, Cc3 and of the anodic channel Ca3 are here decreased. Thus, the sum of the decreased depth of a cathodic channel and of the decreased depth of an anodic channel is lower than the thickness of the bipolar plate, the latter being defined as the distance along the Z axis between two parallel planes, one passing through the anodic ribs and the other passing through the cathodic ribs. The cooling channels Cr1, Cr2 therefore communicate with one another, which allows a transverse mixing of the flow of heat-transfer fluid, and hence improves the spatial uniformity of the removal of the heat produced.
[0070] The first and second zones alternate longitudinally, such that the distribution and cooling channels have successive zones in which the flow of the reactive gases and that of the heat-transfer fluid are enhanced in turn. This longitudinal alternation between the first and second zones is possible even though the thickness of the bipolar plate is low.
[0071]
[0072] The cathodic distribution channels Cc1, Cc2, Cc3 again have a portion Dc1, Dc2, Dc3 of nominal depth, and are here in mechanical contact, at their back wall, with the opposite anodic dividing ribs Na2, Na3, Na4.
[0073] Some of the anodic distribution channels have a portion of nominal depth while others have a portion of decreased depth that is less than the nominal depth. More specifically, the anodic channels which had portions of nominal and decreased depths, respectively, in the preceding enhanced distribution zone (
[0074] The cooling channels are always located between two cathodic portions of nominal depth, and are superposed onto the anodic portions of decreased depth. Thus, the cooling channel Cr2 is now superposed onto the portion Sa3 of the anodic channel Ca3 and is transversally bordered by the portions Dc2, Dc3 of the cathodic channels Cc2 and Cc3. It is therefore delimited along the Z axis by the back wall of the anodic channel Ca3 and by the opposite cathodic rib Nc3, and along the Y axis by the lateral walls of the cathodic channels Cc2 and Cc3.
[0075] This enhanced distribution configuration helps to ensure that the reactive gases flow properly, as well as to increase mechanical reinforcement. Moreover, the fact that the cooling channels do not face the same distribution channels from one enhanced distribution zone to the other makes it possible to improve the uniformity of the distribution of the reactive gases and the removal of the heat produced by the electrochemical cells in operation.
[0076] In general, each distribution channel, whether it is on the anodic sheet or on the cathodic sheet, may have a portion of decreased depth the value of which may be different or identical to that of the other portions of decreased depth. By way of example, the depth value of the anodic portions of decreased depth may be lower than that of the cathodic portions of decreased depth.
[0077]
[0078] The cathodic conductive sheet 20 includes distribution channels Cc1, Cc2, Cc3 that extend in parallel to one another and here in a substantially rectilinear manner. Each cathodic channel, for example the channel Cc1, alternates longitudinally between a portion Dc1 of nominal depth and a portion Sc1 of decreased depth. The portions of nominal depth and of decreased depth, respectively, of the various cathodic distribution channels Cc are here positioned adjacently to one another, along the Y axis. Thus, in the planes A1-A1 and A2-A2, the cathodic channels Cc have portions Dc of nominal depth while in the planes B-B, they have portions Sc of decreased depth.
[0079] The anodic conductive sheet 10 includes distribution channels Ca1, Ca2, Ca3 that extend in parallel to one another and here in a substantially rectilinear manner. Each anodic channel, for example the channel Ca1, alternates longitudinally between a portion Da1 of nominal depth and a portion Sa1 of decreased depth. Unlike the cathodic channels, at least one portion Da1 of nominal depth of an anodic channel Ca1 is positioned adjacently along the Y axis to a portion Sa2 of decreased depth of a neighbouring anodic channel Ca2. In this example, each portion Da of nominal depth is adjacent, along the Y axis, to two portions Sa of decreased depth.
[0080] This longitudinal alternation between portions Da of nominal depth and portions Sa of decreased depth for the anodic channels Ca results in a transverse undulation, i.e. a local transverse offset, of the cooling channels Cr. Thus, the cooling channels Cr1, Cr2 undulate transversely along their longitudinal axis, and thus alternately come to face the anodic channels Ca1 then Ca2 for the channel Cr1, and to face the anodic channels Ca3 then Ca4 for the channel Cr2.
[0081] Moreover, in the enhanced cooling zones such as located in the transverse planes B-B and illustrated in
[0082] Each distribution channel of a conductive sheet is facing a dividing rib of the opposite conductive sheet, thereby allowing the thickness of the bipolar plate to be substantially decreased.
[0083] In this example, the back wall of the portions of nominal depth make contact with the opposite dividing rib, thereby ensuring a mechanical reinforcement of the bipolar plate.
[0084] Furthermore, the longitudinal alternation between the enhanced distribution zones and the enhanced cooling zones makes it possible to maintain a good flow of both the reactive gases and the heat-transfer fluid.
[0085] Moreover, the fact that each cathodic distribution channel has a portion of nominal depth in the enhanced distribution zones is particularly advantageous when the reactive gas distributed is oxygen contained in the air.
[0086]
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[0088]
[0089]
[0090]
[0091]
[0092]
[0093] Various variants of and modifications to the embodiment described above will be apparent to those skilled in the art.
[0094] Thus, the distribution channels may extend longitudinally in a rectilinear manner or have undulations, or transverse offsets, in the plane (X, Y) of the bipolar plate.
[0095] Moreover, the distribution channels may have multiple zones in which the nominal depth and/or the decreased depth mutually differ, in particular between the input and the output of the distribution channels.
[0096] Furthermore, the distribution channels may extend longitudinally and have at least one zone in which they are mutually arranged as illustrated in
[0097] The distribution channel portions of nominal depth are advantageously in mechanical contact with the opposite dividing ribs. Alternatively, the value of the nominal depth may be such that mechanical contact is not ensured either for the anodic channels or for the cathodic channels. A cooling channel may then be present between the back wall of the channel of nominal depth and the opposite dividing rib.
[0098] Cooling channels that are superposed onto anodic distribution channels in the enhanced distribution zones have been described. As a variant, they may be superposed onto the cathodic distribution channels.
[0099] Cooling channels that are superposed onto distribution channels of the same distribution circuit in the enhanced distribution zones, here namely certain anodic channels, have been described. As a variant, one or more cooling channels may additionally be superposed onto distribution channels of the opposite conductive sheet.
[0100] Thus, by way of illustration,
[0101] Furthermore, as illustrated in
[0102] The various embodiments and variants may be fully or partly combined with one another and may be applied to the anodic distribution circuit and/or to the cathodic distribution circuit.