MODULE, REACTOR, SYSTEM AND METHOD FOR TREATING WATER
20170247276 · 2017-08-31
Assignee
Inventors
- Ronen-Itzhak SHECHTER (Kiryat Tivon, IL)
- Eytan Baruch LEVY (Rosh Ha-ain, IL)
- Lior ESHED (Haifa, IL)
- Yaron BAR-TAL (Ganey Tikvah, IL)
- Tomer SPECTOR (Petach Tikva, IL)
- Noam Mordechai SIEGEL (Tel-Aviv, IL)
Cpc classification
C02F3/1278
CHEMISTRY; METALLURGY
C02F2209/003
CHEMISTRY; METALLURGY
C02F2203/00
CHEMISTRY; METALLURGY
Y02W10/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
Abstract
The present disclosure provides a water treatment module, a bioreactor comprising one or more of such modules and a receptive water treatment system. Also provided herein is a method making use of the above module, bioreactor and system. The water treatment module comprises (i) at least one elongated gas enclosure comprising a gas inlet and two vertical walls, at least one vertical wall comprising a water-impermeable and gas-permeable membrane having a water-facing side and a gas-facing side, the two vertical walls separating between water external to said enclosure and gas within said enclosure, the gas enclosure being in a rolled or folded configuration to thereby define a convoluted horizontal path and one or more water-treatment spaces formed between opposite water facing sides of the enclosure; and (ii) a diffuser arrangement comprising gas diffusers configured for introducing a stream of gas into the one or more water treatment spaces.
Claims
1-74. (canceled)
75. A water treatment module comprising: at least one elongated gas enclosure comprising a gas inlet and two vertical walls, at least one vertical wall comprising a water-impermeable and gas-permeable membrane having a water-facing side and a gas-facing side, the two vertical walls separating between water external to said enclosure and gas within said enclosure, the gas enclosure being in a rolled or folded configuration to thereby define a convoluted horizontal path and one or more water-treatment spaces formed between opposite water facing sides of the enclosure; and a diffuser arrangement comprising gas diffusers configured for introducing a stream of gas into the one or more water treatment spaces.
76. The module of claim 75, wherein the convoluted enclosure defines one or more elongated water-treatment spaces configured to be in communication with said water.
77. The module of claim 75, wherein the gas diffusers comprise gas release openings positioned below the one or more water-treatment spaces.
78. The module of claim 75, comprising one or more first spacer elements disposed within said elongated gas enclosure and configured to maintain a first minimal distance between opposite gas facing sides of the two vertical walls.
79. The module of claim 75, comprising one or more second spacer elements disposed within the one or more water treatment spaces to maintain a second minimal distance between said opposite water-facing sides.
80. The module of claim 78, wherein the one or more spacer element is in the form of grid.
81. The module of claim 78, wherein the one or more spacer elements are integrally formed with at least one of the vertical walls.
82. The module of claim 78, wherein the spacer elements are configured as abutments on the at least one vertical wall.
83. The module of claim 75, wherein the diffusers comprise gas openings for discharging gas bubbles into the water-treatment space.
84. The module of claim 75, wherein the diffuser arrangement is formed as a second elongated aeration enclosure below said gas enclosure.
85. The module of claim 84, wherein the aeration enclosure is integrally formed with said gas enclosure.
86. The module of claim 75, comprising a diffuser arrangement comprising at least one gas diffuser having: a first generally vertical conduit, a second generally vertical conduit and a gas/liquid chamber; the first conduit being in gas communication at its top with one or more gas openings and being in fluid communication at its bottom with the second conduit; the second conduit being in fluid communication at its top with the gas/liquid chamber; and the gas/liquid chamber having a sealed top, being in gas communication with a source of gas at a pressure sufficient for displacing liquid out of said chamber and at least one opening at its bottom to a source of liquid.
87. The module of claim 86, wherein said diffuser is integrally formed at a bottom portion of the elongated gas enclosure.
88. The module of claim 75, comprising a support structure connected to at least a top portion or bottom portion of said enclosure and configured to maintain the enclosure in its intended convoluted horizontal path configuration when submerged in water.
89. The module of claim 75, wherein said rolled configuration is a spiral and the module comprises a central vertical tube configured to receive said water and channel it into the one or more water-treatment spaces.
90. A water treatment module comprising at least one elongated enclosure comprising two vertical walls, each wall having a water-facing side and a gas-facing side, and further each wall comprising opposite facing and spaced apart abutments.
91. The water treatment module of claim 90, wherein the spaced apart abutments define the thickness of one or more spacer elements, and the spacer elements have a different thickness.
92. A water treatment module comprising: at least one elongated gas enclosure comprising a gas inlet and two vertical walls, at least one vertical wall comprising a gas facing water-impermeable and gas-permeable membrane being coated or laminated, on its water facing side, with a second polymer the two vertical walls separating between water external to said enclosure and gas within said enclosure, the gas enclosure defining one or more water-treatment spaces formed between opposite water facing sides of the enclosure; and a diffuser arrangement comprising gas diffusers configured for introducing a stream of gas into the one or more water treatment spaces.
93. The water treatment module of claim 92, wherein said membrane comprises a first polymeric fabric comprising a first polymeric sheet and a water facing layer comprising a second polymer layer.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0058] In order to better understand the subject matter that is disclosed herein and to exemplify how it may be carried out in practice, embodiments will now be described, by way of non-limiting example only, with reference to the accompanying drawings, in which:
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DETAILED DESCRIPTION
[0078] Reference is made to
[0079] The two vertical walls are longitudinally sealed at any of a top end 118 and bottom end 120 thereof. Sealing may be by welding, bonding, sewing or any other means of fixedly attaching the two walls so as to form a liquid-sealed enclosure. In an alternative embodiment, the enclosure is formed as a single unit where the two walls are integrally formed as part of an elongated sleeve.
[0080] Gas enclosure 110 is rolled or winded (folded) to form a convoluted horizontal path configuration. In this particular embodiment, gas enclosure 110 is rolled in a concentric spiral configuration. Yet, other configurations are equally applicable. In some alternative configurations, the convoluted horizontal path is provided by rolling the enclosure in an elliptical spiral configuration. Yet in some other alternative configurations, the convoluted horizontal path is provided by winding in an accordion (“back and forth snaking” or “zigzag”) configuration, as illustrated in
[0081] Walls 114 and 116 define between their respective water-facing sides a continuous and equally spiraling water-treatment space 122 which is formed between opposite water-facing sides of enclosure 110. In some embodiments, the convoluted enclosure defines more than one elongated water treatment spaces. This is achieved, for example, by introducing partition walls extending vertically from one side of one wall to the facing side of its opposite wall (not illustrated).
[0082] Both walls 114 and 116 are water impermeable. At least one, and at times, both of walls 114 and 116 comprise gas permeable membrane portions. In some embodiments, the membrane comprises a polymer fabric. For example, the polymer fabric can be a non-woven polymeric fabric, such as a fabric formed from a first polymeric sheet extrusion coated or laminated with a second, water facing polymer film or layer. By some embodiments, the first polymeric sheet comprises a polyolefin (including a spun bonded polyolefin), such as polyethylene (particularly high density PE) or polypropylene, or comprises a polyester.
[0083] The water facing polymer film or layer is one that can provide the membrane with its water impermeability while permitting the gas permeability. In one embodiment, the water facing polymeric sheet comprises poly (n-alkyl acrylate) homo-and copolymers, known for their gas permeability. In yet an alternative embodiment, the water facing polymeric sheet comprises poly(methylpentene) such as poly(4-methyl-1-pentene) (PMP), typically used in gas permeable packaging.
[0084] It is noted that poly (n-alkyl acrylate) are compatible with polyolefins while poly(methylpentene) are compatible with polyesters. Accordingly, in one embodiment, the water impermeable, gas permeable membrane comprises a first polymeric sheet comprising a polyolefin and a water facing polymeric sheet comprising a poly (n-alkyl acrylate); and in another embodiments, the water impermeable, gas permeable membrane comprises polyester and a water facing polymeric sheet comprising a PMP.
[0085] The polymers forming the water impermeable, gas permeable membrane can be combined by any suitable technique known in the art such as extrusion coating, hot lamination and/or cold lamination.
[0086] The present disclosure also provides an elongated enclosure comprising a wall separating from an internal elongated path within said enclosure and a space external to said elongated enclosure, the wall comprising a first polymeric material extrusion coated with a second water impermeable, gas permeable membrane.
[0087] It is to be noted that the exemplary polymeric fabrics and materials described above are applicable also for use in other embodiments described above.
[0088] Gas enters the gas enclosure through inlet 112 and while it flows along the gas enclosure 110 portions thereof diffuse into the surrounding water in the water space via the gas impermeable membrane. At times, and in accordance with some embodiments, gas enclosure 110 comprises a gas outlet 124 from which the gas is either vented to the atmosphere, blown into the water within the water treatment space, collected and/or re-circulated into the gas enclosure. The gas flow is generally in the direction from gas inlet 112 to gas outlet 124 and in the
[0089] In use, when water space 122 accommodates contaminated or polluted water, a biofilm will grow on the water facing side of the wall comprising the water impermeable, gas permeable membrane. Module 100 further comprises a diffuser arrangement 126 comprising a gas inlet 128, being in gas-flow communication via dedicated tubes, such as a manifold 130 to diffusers 132, each having at least one opening configured to release a stream of gas bubbles into the water treatment space 122. In some embodiments, the diffuser arrangement 126 is constructed and operative to introduce a stream of gas bubbles such that it flows upwards alongside the water-facing walls of the gas enclosure 110. In some embodiments, the gas discharged from the diffuser's openings facilitates water turbulence and mixing, to support biofilm growth on the one hand and minimize clogging of the water space by the growing biofilm, on the other hand.
[0090] In the embodiment illustrated in
[0091] In some embodiments, diffusers 132 are configured to provide fine bubbles. In some embodiments, the diffusers are configured as a porous or perforated tube, a punched or perforated membrane, a membrane with fine pores or a nozzle.
[0092] In accordance with some other exemplary embodiments, the diffusers can have downward facing openings, such as seen in
[0093] An exemplary module, by an embodiment of this disclosure, is shown in
[0094] Illustrated in
[0095] In some embodiments, module 100 contains at least one of the reinforcing/support elements. In some alternative embodiments a combination of the said reinforcing elements are included in the module.
[0096] The support element (top, bottom and/or core) is configured for retaining enclosure 110 in its convoluted configuration, preferably when the gas enclosure is submerged (even partially) in water. The fixation is achieved, for example, by connecting or otherwise firmly attaching enclosure 110 to said reinforcing structures. At times, top support element 140 and bottom support element 142 are fixed to central core element 144.
[0097] Bottom support element 142 is also configured and operative to hold enclosure 110 above diffuser arrangement 120. Where multiple modules 100 are stacked one on top of the other, there can be a single bottom support element 142 below the bottom module and one top support element 140 above the upper module or there may be provided also intermediate support elements that are positioned between two stacked modules. A single central core structure 144 can be used to concentrically align two or more stacked water treatment modules.
[0098] In some embodiments, central core structure 144 serves also as a feed buffer (or feed well) for the water between intermittent gas sparging from the diffusers and thereby water mixing events, through which it is mixed into the water treatment spaces during the intermittent mixing event and as a result of which raw wastewater (i.e. water before treatment) does not come in direct contact with the vertical walls (and the membrane) and does not cause biofilm overgrowth and consequent clogging of the membrane.
[0099] The present disclosure also provides a bioreactor comprising a water impermeable, gas permeable membrane within a water treatment chamber, and a second chamber integrally formed within said bioreactor, the second chamber configured to receive water to be treated and communicate said water to the water treatment chamber. In some embodiments, the second chamber is physically located within the water treatment chamber.
[0100] The reinforcing structures can be configured in a variety of shapes and formed of a variety of materials, such as, and without being limited thereto, fiberglass, a fiber reinforced polymer and/or stainless steel.
[0101] In some embodiments, central core element 144 can act as a skeleton to which elements of module 100 are connected and thus fixed in place. In some embodiments, central core structure 144 has a cross section dimension of at least 200 mm. As appreciated, the dimensions of central core structure 144 can vary depending on the overall dimensions of the module. Generally, the cross section dimensions of the central core structure should be small with respect to efficient volume usage, but yet, not too small, to allow the rolling of the gas enclosure around it and to the sufficient water flow therethrough during operation.
[0102] Turning now to
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[0104] First spacer element 150 is designed to ensure an open pathway for the gas flowing in gas enclosure 110, and in other words, a minimal distance between opposite gas facing walls of the gas enclosure 110.
[0105] As can be seen in
[0106] In some embodiments, second spacer element 160 is a sheet that has an array of dimpled abutments 162 (namely each defining dimples on one side and protrusions on the other) projecting in opposite sides of sheet, the distance between the plane defined by the apex of the protrusions at one side and that defined by the protrusions at the other side defining the thickness of spacer element 160. These protrusions that are formed by forming portions of the sheet (thus leaving a depression at the opposite side) can also be seen in
[0107] Second spacer element is disposed alongside enclosure 110, at the water treatment space. In some embodiments, second spacer element 160 can extend throughout the entire water treatment space alongside the enclosure 110 and in some other embodiments, several separated spacer elements are disposed within said space, each occupying a segment thereof.
[0108] Second spacer element 160 is designed to ensure an open space for the water within the water treatment space 122; and in other words, a minimal distance between opposite facing water facing sides of the walls of the enclosure 110. While the space 122 can, at times, expand, the second spacer ensures that the clearance between the two vertical walls would not be less than the minimal distance dictated by the width of second spacer element.
[0109] It is noted that the structure and configuration of the first spacer element 150 and second spacer element 160 is but an example and is not limited to those illustrated. Additionally, first and second spacer element can have the same or different configuration, each independently can be in the form of an open flow or hydraulic element, such as a net, or a sheet with protrusions, such as the illustrated dimpled sheet. In some embodiments, the protrusion extend in only one direction from the sheet (one sided protrusions) and in some other embodiments, the protrusion extend from the sheet in two opposite directions (double sided protrusions), as shown in
[0110] As alternative to a dimpled sheet, the spacer can comprise distributed individual and discrete three dimensional elements attached to at least one side of at least one of the vertical walls and thus maintaining the distance dictated by the discrete elements' thickness. In some embodiments, the individual elements are formed of a polymer material such as hot glue applied onto any of the water facing side and/or air facing sides of the vertical walls. In other embodiments the individual elements are formed of pieces, such as plastic discs, placed onto the side of any of the water facing side and/or air facing side of the one or both vertical walls.
[0111] The present disclosure also provides a bioreactor with at least one spacer element comprising a surface holding, discrete, spaced apart, abutments (three dimensional elements). In some embodiments, the spaced apart abutments are located on a water impermeable, gas permeable membrane as disclosed herein.
[0112] Also disclosed herein is an elongated enclosure comprising a wall separating from an internal elongated path within said enclosure and a space external to said elongated enclosure, the wall integrally comprising discrete, spaced apart abutments of a kind described herein.
[0113] In some embodiments, the membrane with the spaced apart abutments forms part of a bioreactor of a kind described herein.
[0114] In some embodiments, the first and/or second spacer element is a combination of any of the above spacer configurations. For example, the spacer element can comprise a net like structure that is laminated to a dimpled sheet, etc.
[0115] The minimal distance dictated by first spacer element, as illustrated spacer element 150 and the minimal distance dictated by second spacer element, as illustrated spacer element 160 are independent from one another and can be the same or different.
[0116] The selection of the type and/or width of the second spacer can depend on the type of water to be treated. The selection of the type and/or width of the first spacer can depend on the type of gas to be introduced into the enclosure and some operational conditions, such as pressure of gas within the enclosure and others.
[0117] When using spacers of same configuration, they are arranged such that they do not interdigitate, e.g. when both spacers have protrusions, such as the exemplified dimples, the spacers can be arranged such a protrusion/dimple from one spacer essentially faces an opposite protrusion/dimple from the other spacer so as to avoid interdigitation of the protrusions. Similarly, when using one spacer in a form of a grid or a net, and the other in a form of a sheet of protrusions, the spacers can be arranged such that the protrusions do not fit into the openings of the other spacer.
[0118] The spacer elements may be of the same or different material. In some embodiments, spacer element 150 and spacer element 160 are each, independently made, from a water durable polymeric material. Non-limiting examples of polymeric materials include high density polyethylene, low density polyethylene, polyethylene terephthalate (PET), polypropylene, polyamide.
[0119] In some examples, the spacers are characterized by having a compressive strength of above 2 ton/m.sup.2, at times, above 20 ton/m.sup.2 as determined by the manufacturer and tested by internationally known standards to comply with at least two requisites: (i) withstand forces applied during processing and (ii) withstand water pressure (mainly applicable to requirements from first spacer 150).
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[0121] While in certain embodiments, the first and second spacer elements are separately formed elements, in some other embodiments, the first or the second spacer element is integrally formed with at least one of the vertical walls of enclosure 110. At times, thus, the integral-vertical wall is configured to provide several functionalities: (i) water impermeability; (ii) water side spacing; (iii) gas side spacing and (iv) optionally gas permeability and biofilm growth support. This can be achieved, for example, and without being limited thereto, by a water impermeable, gas permeable membrane having, integrally formed protrusions formed on the inner face and on the outer face.
[0122] Similarly, in some other embodiments, the second spacer element is integrally formed with at least one of the vertical walls of enclosure 110. This means that at least one of the enclosure's vertical walls is configured to provide also the minimal required distance from its opposite facing water facing vertical wall. In other word, the membrane has protrusions on one water-facing side that maintain spacing from the opposite facing wall. In some embodiments, the integral spacer-vertical wall is configured to provide several functionalities: (i) water impermeability; (ii) water side spacing ; (iii) optionally gas permeability and biofilm growth support. This can be achieved, for example, and without being limited thereto, using a water impermeable, gas permeable (optional) membrane having, integrally formed therewith, outwardly extending protrusions.
[0123] In some embodiments, only one of the two vertical walls of an enclosure is gas permeable. In some embodiments, only portions of one or both the two vertical walls are gas permeable. In yet some other embodiments, one or both of the vertical walls of an enclosure are essentially entirely gas permeable.
[0124] The present disclosure also provides an elongated enclosure comprising a wall separating from an internal elongated path within said enclosure and a space external to said elongated enclosure, at least a portion of the wall comprising a gas permeable membrane, said wall further comprising spaced apart abutments extending outwardly from said enclosure and/or inwardly into said internal path.
[0125] Reference is now made to
[0126] The embodiment illustrated in
[0127] Diffuser arrangement 226 is provided with a gas inlet aperture 264 and spaced apart gas diffuser openings 232 in the form of openings formed at the bottom side of enclosure 226 such that gas bubbles are discharged out of openings 232 into water treatment space 222 and ascend along the external face of the wall of enclosure 210 as represented by arrow 233. As can be seen diffuser arrangement 226 also includes a spacer element 250′ that is shown to have the same configuration as that of element 250 (albeit, can have a different configuration).
[0128] The present disclosure also provides an elongated enclosure comprising a wall separating from an internal elongated path within said enclosure and a space external to said elongated enclosure, said enclosure comprising a first elongated zone for treating water and an integrally formed, second elongated zone, parallel to said first elongated zone that is configured to discharge gas to faces of the elongated enclosure at said first elongated zone.
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[0130] The unique features of module 300 of this disclosure are the diffusers in the diffuser arrangement that are seen in
[0131] Diffuser arrangement 326 of this embodiment includes an elongated inverted trough-shaped element 368 that has a sealed top end 370 (see
[0132] The manner of operation of the diffuser arrangement of this embodiment is illustrated in
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[0134] From an operational point of view, initially the gas/liquid chamber 478, the cylindrical space 404 defined by the first generally vertical conduit 380D and the second generally vertical conduit 480U are filled with water. Then gas pressure exerts a water-displacing force that causes lowering if the water level in gas/liquid chamber 478 and, at the same time, pushing the water downwardly in the first generally vertical conduit 480D and in the second generally vertical conduit 380D that exits through the diffusers 438. Once the first generally vertical conduit 480D and the second generally vertical conduit 480U are drained of water, gas communication downwardly into the first generally vertical conduit 480D and upwardly in the second generally vertical conduit 480U so established causes a burst of gas discharge out of diffuser head 434. This burst drains the gas causing water to re-enter and a restart of this operational cycle.
[0135] Turning now to alternative configurations of the module disclosed herein, reference is made to
[0136]
[0137] In some embodiments enclosure 510 is winding over or around vertical elements 543 of a supporting structure 540.
[0138] In some embodiments enclosure 510 has several gas inlets, similar to gas inlet 512 along its length and several gas outlets, like gas outlet 524 in order to reduce pressure drop or head losses. In some point along the length of elongated enclosure 510 there is an outlet (not illustrated) for discharge of condensated water and leaks. Otherwise, this module operates functionally in a similar manner to water treatment modules of other embodiments described above.
[0139] In some embodiments, the module forms a part of a bioreactor, where one or more of the disclosed modules are placed within a water environment, e.g. tank, basin, water pond etc as further detailed with respect to
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[0141] Specifically, as can be seen in
[0142] Each module 600 is enclosed within a respective tank 602 including a tank cover 602′ that is configured to hold water to be treated and module 600 submerged in the water. Top support element is attached to tank 602 and tank cover 602′ via attachment elements 645. Tank 602 comprises water inlet 605 and treated water outlet 606.
[0143] In some embodiments, as also illustrated in
[0144] The present disclosure also provides a bioreactor for water treatment comprising a water treatment space and an integrally formed weir (chamber) at a top portion of said water treatment space, said weir configured to receive clarified treated water and to discharge said clarified treated water from the bioreactor. In some embodiments, the integrally formed weir is operable to discharge the clarified treated water when water in the water treatment space is at rest (i.e. essentially no mixing or turbulence in the water).
[0145] A bioreactor as disclosed herein can also or as an alternative to weir 608 be equipped with a solid-liquid separation tank (e.g. clarifier) for receiving discharged treated water that includes suspended solids and for removing solids from said treated water. Specifically, and as also illustrated in
[0146] Furthermore, a bioreactor as disclosed herein can comprise one or more sensors for sensing one or more treatment parameters indicative of the quality of water within said tank. The sensors can be of any type known or needed to be used in water quality monitoring and assurance. These include any one and any combination of pH sensors, oxidation-reduction potential (ORP) sensors, dissolved oxygen sensors, optical-density sensors (turbidity sensors), chemical sensors (e.g. to determine level of N-containing compounds including nitrate or ammonium) and potentiometric sensors etc. Typically but not exclusively or mandatory the sensors would be located at a point of exit of the treated water so as to monitor quality of the treated water. In one embodiment the monitored parameter is used in controlling operation of one or more elements of the bioreactor. In some embodiments, based on data received from one or more sensors the operation of the diffuser arrangement can be manipulated. For example, mixing frequency and/or mixing duration caused by the diffuser arrangement can be increased as a response to any indication for decline in effluent quality.
[0147] Further, the bioreactor can comprise a plurality of modules. In one embodiment, two modules are staked one on top of the other in a manner similar to that illustrated in
[0148] In some embodiments, multiple treatment tanks, each containing one or more modules, e.g. of a type illustrated in any of
[0149] The bioreactor disclosed herein can also be part of a water treatment system 601 (water treatment plant) such as that schematically illustrated in
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[0151] In an alternative embodiment, a system in accordance with the present disclosure can comprise a plurality of modules submerged together within a single tank as shown in the exemplary illustration of
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[0155] As can be appreciated by those versed in the art, the module, bioreactor and/or system disclosed herein can be constructed and operated to treat water in combination with other types of modules, bioreactors and/or systems. In some embodiments, a system comprising a plurality of modules or bioreactors as disclosed herein can be used to provide a first stage or as a subsequent treatment stage of water in combination with one or more other types of water treatment modules. In other words the systems of the present invention can be installed upstream and/or downstream of other water treatment systems as part of a complete water treatment plant. Without being limited thereto, module, bioreactor and/or system as disclosed herein can be operated in combination with a system as disclosed in PCT Publication No. WO/11073977 the content of which is incorporated herein by reference. Generally, WO/11073977 describes a system with a spirally rolled enclosure, similar to the gas enclosure disclosed herein, that is intended to hold and channel the water and support biofilm growth within it.
[0156] The module, bioreactor and/or system disclosed herein can be configured to treat various types of water using respectively different types of gases. In the following, when referring to a system it is to be understood as similarly referring to module or a bioreactor mutatis mutandis. Some exemplary methods of water treatment making use of a system disclosed herein are described with reference to the flow charts illustrated in
[0157] Generally, the system is configured to perform water treatment by performing the following general method steps: [0158] introducing gas into the gas enclosure; [0159] introducing water to be treated into a bioreactor; [0160] operating the diffuser arrangement (continuously or periodically or upon need) to introduce gas streams into the water held within the bioreactor; [0161] collecting treated water.
[0162] In some embodiments, the gas introduced into gas enclosure is air. In some other embodiments, the gas introduced into the gas enclosure is air enriched with oxygen, another oxygen-containing gas mixture or methane or a methane-containing gas mixture.
[0163] In some embodiments, the system is operated in a batch mode, namely, a batch of water is introduced into the bioreactor(s) and treated water is collected once the water has reached the desired quality (the desired quality being dependent on the particular need of the water and is typically a priori determined on a case by case basis). When operating in a batch mode once the treated water reaches a pre-defined quality criteria, the treated water is collected, typically via a treated water outlet. A pre-defined quality criteria can vary, depending on the type of water, the defined use of the treated water (e.g. for drinking, for irrigation, for industry, etc), the stage of treatment, e.g. when the system is part of a water treatment plant including a combination of water treatment systems, etc.
[0164] In some other embodiments, the system is operated in a continuous mode where water is continuously introduced into a bioreactor from one location and is discharged from another location of the bioreactor(s).
[0165] In yet some other embodiments, the system is operated such that water to be treated is fed in an essentially continuous mode while treated water is periodically discharged. The discharge of treated water is halted during operation of the diffuser arrangement and thereby mixing of the water within the tank is halted as well.
[0166] In some embodiments, the gas arrangement is operated periodically. As an example, the diffuser arrangement can be operated regularly 10-20 seconds every 5-20 minutes. In addition or alternatively, the diffuser arrangement can be operated upon need, e.g. to allows scouring excess accumulation of biofilm on the membrane or to improve treated water quality when such accumulation or water quality deterioration is detected (e.g. using dedicated sensors such as ORP or DO) and/or when there is a need to cause turbulence in the water undergoing treatment and thereby mixing of suspended solids. In some other embodiments, the diffuser arrangement is operated continuously.
[0167] Turning now to non-limiting examples of using a bioreactor according to some embodiments of the present disclosure,
[0168] Nitrified water can be coupled to anoxic oxidation of methane to thereby produce carbon dioxide, Nitrogen gas and water according to the following series of chemical reactions:
CH.sub.4+4NO.sub.3.sup.−.fwdarw.>CO.sub.2+4NO.sub.2.sup.−+2H.sub.2O
3CH.sub.4+8NO.sub.2.sup.−+8H.sup.+.fwdarw.3CO.sub.2+4N.sub.2+10H.sub.2O
[0169] To this end, methane gas is fed into the gas enclosure
[0170] The methane containing gas can be obtained from various sources. In some examples, the methane containing gas is a biogas derived from anaerobic reactors e.g. from an anaerobic digestor employed in biological wastewater (sewage) treatment facilities.
[0171] In accordance with one embodiment illustrated in
[0172] Mixing is performed periodically by pressurized air being introduced through diffuser arrangement and is ejected into the water treatment spaces between the walls of the spirally rolled gas enclosure, also providing scouring of biofilm from the water facing sides of the gas enclosure. A biofilm that develops on the outer surface of the vertical walls of the gas enclosure and is operative to oxidize methane gas that diffuses through the membrane using the nitrogen oxides in the water, thus, reducing nitrogen oxides in the water (denitrifying the water).
[0173] In accordance with yet another embodiment being illustrated in
[0174] Tank where (i) organic material is oxidized by the aid of the aerated air within the Aeration Tank (ii) ammonia is oxidized to nitrate to thereby provide nitrified water that enters, along with its sludge, into bioreactor 610, where nitrified water undergoes denitrification. Also illustrated in
[0175] Solid settling devices (clarifiers) are known in the art and at times include a conically shaped basin with a sludge discharge at the bottom thereof, while water is discharged (overflows) from an outlet located (at a top location) above the sludge discharge.
[0176] Treated water exiting bioreactor 610 is received by a Clarifier for subsequent solid-liquid separation in the clarifier. At times, part of the sludge from Clarifier is communicated (circulated or recirculated) into a Aeration Tank where it is mixed with water to be treated as described above. Notably, the return sludge from Clarifier is active biomass that treats the water in Aeration Tank. Then it is separated from the water in the clarifier in order to discharge clear water and in order to retain the active solids in the system.
[0177] Considering the above, the present disclosure also provides a water treatment method comprising (i) submerging within nitrified water an elongated enclosure comprising a wall separating from an internal elongated path within said enclosure and nitrified water treatment space external to said elongated enclosure, the wall comprising a water impermeable, methane permeable membrane; and (ii) flowing within said internal elongated path methane gas.
[0178] In some embodiments, the methane gas diffuses to the nitrified water treatment space to participate in redox reaction of nitrogen oxide species in the nitrified water.
[0179] In some embodiments, the methane gas is a biogas derived from anaerobic reactors.
[0180]
[0181] At times, and while not illustrated, commercially available methanol, acetate or other sources of biodegradable organic matter can be used to facilitate the anoxic denitrification process. Further, at times, gas containing methane can be received as biogas from an anaerobic reactor, e.g. from a sludge digester, treating excess sludge from a biological wastewater treatment process.
[0182] The above operational configurations overcome problems of insufficient resources (electron donors) for denitrification to the levels required by regulations. A common solution for such lack of resources is purchasing methanol or a acetate or a different soluble biodegradable organic material, to be fed to an anoxic denitrification part of the biological treatment process. The process illustrated in
[0183] It follows from the above that the present disclosure also provides methods for producing organic compound containing solution. The method comprises (i) submerging within water an elongated enclosure comprising a wall separating from an internal elongated path within said enclosure and water treatment space external to said elongated enclosure, the wall comprising a water impermeable, methane permeable membrane; and (ii) flowing within said internal elongated path methane gas; (iii) communicating treated water to an activated sludge tank whereby organic compound containing solution is produced.
[0184] In some embodiments, the method comprises discharging air (or any other gas including at least oxygen containing species) into said water treatment space. The biofilm oxidizes the methane in the presence of the oxygen containing species introduced into the water and produces inter alia, organic compounds in solution. The organic compounds can be, for example, methanol, acetate, butyrate, etc. This solution can then be used as electron donor solution in denitrifiation processes, such as those described herein. In some embodiments, the methane gas is a biogas derived from anaerobic reactors.
[0185] Turning now to
[0186]
[0187] Further illustrated in
[0188] Finally, it follows the above that the present disclosure also provides a method for determining aeration schedule of water during water treatment, the method comprises receiving data relating to quality of the water and modifying gas diffusing/discharging schedule according to said data. In some embodiments, said data is received from a quality indicator of a kind described herein. In some embodiments, the aeration schedule comprises duration of aerations from gas diffusing arrangement of a kind described herein,