Melting furnace for producing metal
09744588 · 2017-08-29
Assignee
Inventors
- Takashi Oda (Chigasaki, JP)
- Hisamune Tanaka (Chigasaki, JP)
- Takeshi Shiraki (Chigasaki, JP)
- Norio Yamamoto (Chigasaki, JP)
Cpc classification
F27B19/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D11/12
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B14/0806
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B14/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B22D21/005
PERFORMING OPERATIONS; TRANSPORTING
F27B2014/0818
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B2014/0812
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D3/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B22D11/1245
PERFORMING OPERATIONS; TRANSPORTING
B22D41/015
PERFORMING OPERATIONS; TRANSPORTING
F27B7/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B14/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B22D11/1243
PERFORMING OPERATIONS; TRANSPORTING
F27B2014/008
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B22D7/06
PERFORMING OPERATIONS; TRANSPORTING
International classification
B22D7/06
PERFORMING OPERATIONS; TRANSPORTING
F27B19/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B22D11/00
PERFORMING OPERATIONS; TRANSPORTING
B22D41/015
PERFORMING OPERATIONS; TRANSPORTING
F27B7/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
In production of a reactive metal using a melting furnace for producing metal having a hearth, ingots can be efficiently produced by efficiently cooling the ingots extracted from the mold provided in the melting furnace. In addition, an apparatus structure in which multiple ingots can be produced with high efficiency and high quality from one hearth, is provided. A melting furnace for producing metal is provided, the furnace has a hearth for having molten metal formed by melting raw material, a mold in which the molten metal is poured, an extracting jig which is provided below the mold for extracting ingot cooled and solidified downwardly, a cooling member for cooling the ingot extracted downwardly of the mold, and an outer case for keeping the hearth, the mold, the extracting jig, and the cooling member separated from the air, wherein at least one mold and extracting jig are provided in the outer case, and the cooling member is provided between the outer case and the ingot, or between the multiple ingots.
Claims
1. A melting furnace for producing metal, comprising: a hearth for holding molten metal formed by melting raw material, a mold in which the molten metal is poured, the mold comprising: a primary cooling portion in an upper part of the mold, the primary cooling portion having a top and a bottom, and the primary cooling portion configured to provide a first monotonically decreasing temperature from top to bottom, a secondary cooling portion in a lower part of the mold, the secondary cooling portion having a top and bottom, and the secondary cooling portion configured to provide a second monotonically decreasing temperature from top to bottom, different than the first monotonically decreasing temperature, an inflection point of temperature distribution between the primary cooling portion and the secondary cooling portion, and an open bottom beneath the secondary cooling portion, an extracting jig for extracting an ingot cooled and solidified downwardly, which is provided below the mold, a cooling member for cooling the ingot extracted downwardly of the mold, and an outer case for keeping the hearth, the mold, the extracting jig, and the cooling member separated from the air, wherein the ingot has a surface, wherein the cooling member is provided between the outer case and the ingot, while the cooling member extends along the extracting direction of the ingot with a certain gap from the ingot surface, wherein the melting furnace for melting metal is an electron beam furnace, and wherein the primary cooling portion comprises an upper wall of the mold having a thickness increasing portion in which thickness of the upper mold wall increases in an upper direction of the wall, and wherein the secondary cooling portion comprises a lower wall of the mold having a parallel portion in which thickness of the lower mold wall is constant.
2. The melting furnace for producing metal, according to claim 1, wherein a cooling medium flowing in the mold is supplied to the primary cooling portion and the secondary cooling portion, and the temperature of the cooling medium supplied to the primary cooling portion is higher than that of the cooling medium supplied to the secondary cooling portion.
3. The melting furnace for producing metal, according to claim 2, wherein the cooling medium flowing in the mold is serially supplied to the primary cooling portion and the secondary cooling portion, the cooling medium is flowing continuously through a cooling coil wound around the primary cooling portion and the secondary cooling portion, and the cooling coil is wound relatively sparsely around the primary cooling portion and is wound relatively densely around the secondary cooling portion.
4. The melting furnace for producing metal, according to claim 2, wherein the cooling medium flowing outside of the mold consists of a primary cooling medium for cooling the primary cooling portion and a secondary cooling medium for cooling the secondary cooling portion, being provided separately and in parallel, the primary cooling medium flowing in a coil wound around the primary cooling portion, and the secondary cooling medium flowing in a coil would around the secondary cooling portion.
5. The melting furnace for producing metal, according to claim 2, wherein a tapering portion is formed at a lower part of the secondary cooling portion, in which a diameter of an inner surface of the mold decreases along the extracting direction of the ingot.
6. The melting furnace for producing metal, according to claim 1, further comprising metal held within the mold, the metal comprising: a meniscus portion having a liquid phase; the ingot located below the meniscus portion; and a liquid-solid interface between the meniscus portion and the ingot, and wherein the liquid phase directly contacts the primary cooling portion of the mold.
Description
BRIEF EXPLANATION OF DRAWINGS
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BEST MODE FOR CARRYING OUT THE INVENTION
(33) The best mode of the present invention is explained in detail as follows by way of example of a case in which the melting furnace for melting metal is an electron beam melting furnace, with reference to the drawings. In the following explanation, a case in which the raw material is titanium sponge, the ingot to be produced is of titanium metal, and a cross section of the ingot produced is square, is exemplified; however, the electron beam melting furnace of the present invention is not limited to the production of titanium ingots, and the present invention can also be employed for a high-melting point metal such as zirconium, hafnium, tungsten or tantalum, other metals which can be produced in ingots by an electron beam melting furnace, or alloys of these metals. In addition, regarding the cross section, the present invention is not limited to a rectangle, and the present invention can be employed for any other cross sectional shape such as a circle, ellipse, barrel, polygon, or other irregular shapes.
First Embodiment (Single Ingot+Tabular Cooling Member)
(34)
(35) In the melting area 40 which is divided by melting area wall 41, a raw material supplying device 10 such as Archimedes can or the like for supplying titanium raw material 12 consisting of titanium sponge or titanium scrap, a raw material conveying device 11 such as a vibrating feeder or the like for conveying the raw material 12, a hearth 13 for melting the raw material supplied, an electron beam radiating device 14 for melting the raw material 12 supplied in the hearth 13 to form molten metal 20, a mold 16 consisting of water cooled copper or the like for forming an ingot by cooling and solidifying the molten metal 20, and an electron beam radiating device 15 for forming molten metal pool 21 by radiating electron beam inside the mold 16, are provided.
(36) At a lower area of the mold 16 of the melting area 40, the extracting area 50 that is divided by an extracting area outer case 51 is provided. Inside of the extracting area 50, an extracting jig 30 for extracting ingot 22 produced in the mold 16 downwardly is arranged. It should be noted that the melting area 40 and the extracting area 50 are constructed so that reduced pressured is maintained.
(37) First, the raw material 12 supplied from the raw material supplying device 10 is melted in the hearth 13 by the electron beam radiating device 14 to form the molten metal 20. The molten metal 20 is supplied from downstream of the hearth 13 to inside of the mold 16. A stub (not shown) is provided in the mold 16 before melting of the raw material 12, this stub functions as the bottom part of the mold 16. The stub is made of as same metal as the raw material 12, and it is unified with the molten metal 20 supplied in the mold 16 to form the ingot 22.
(38) The surface of the molten metal 20 continuously supplied on the stub in the mold 16 is heated by the electron beam radiating device 15 to keep molten metal pool 21, and the bottom of the molten metal pool 21 is cooled and solidified by the mold 16 and is unified with the stub so as to form the ingot 22.
(39) The ingot 22 formed in the mold 16 is extracted at the extracting area 50 with control of the extracting rate of the extracting jig 30 engaged to the stub so that the level of the molten metal pool 21 is maintained at a constant level.
(40) The above explanation is for the common construction and action of the electron beam melting furnace for producing a single ingot of the conventional technique and in the present invention, in addition, in the first embodiment of the present invention, as shown in
(41)
(42) As shown in
Second Embodiment (Single Ingot+Square Bracket Shaped Cooling Member)
(43) In the second embodiment of the present invention, as shown in
(44) As shown in
(45) By the second embodiment of the present invention, since the cooling member 61 having a cross section of a square bracket shape is provided in the extracting area 50, heat radiation of the ingot 22 can be promoted more than in the case of the first embodiment, thus cooling can be performed faster.
Third Embodiment (Single Ingot+Square Shaped Cooling Member)
(46) In the third embodiment of the present invention, as shown in
(47) As shown in
(48) By the third embodiment of the present invention, since the cooling member 62 having a cross section of a square shape is provided in the extracting area 50, the ingot can be cooled from all the directions, heat radiation of the ingot 22 can be promoted more than in the case of the first and second embodiments, and thus cooling can be performed faster.
Fourth Embodiment (Single Ingot+Coil Shape Cooling Member)
(49) In the fourth embodiment of the present invention, as shown in
(50) As shown in
(51) By the fourth embodiment of the present invention, since the cooling member 63 having a coil shape is provided in the extracting area 50, the ingot can be cooled from all the directions, heat radiation of the ingot 22 can be promoted in the same manner as in the third embodiment, and thus cooling can be performed faster.
Fifth Embodiment (Multiple Ingots+Tabular Cooling Member)
(52)
(53) In the electron beam melting furnace shown in
(54) The above explanation is for the common construction and action of the electron beam melting furnace for producing multiple ingots of conventional technique and the present invention, and in addition, in the fifth embodiment of the present invention, as shown in
(55)
(56) As shown in
(57) However, in the fifth embodiment of the present invention, since the tabular cooling member 60 is provided between the ingots 22, heat radiation is also promoted on the surfaces where the ingots mutually face, thereby enabling rapid cooling. As a result, uniform cooling can be performed on all of the surfaces of the ingots.
(58) In the above explanation of the fifth embodiment, the example in which ingots are produced in two lines is explained; however, the present embodiment is not limited to the production of ingots in two lines, and for example, production of ingots in three or more lines is possible. In that case, the ingot 22 and the cooling member 60 are provided alternately.
Sixth Embodiment (Multiple Ingots+Square Bracket Shaped Cooling Member)
(59) In the sixth embodiment of the present invention, as shown in
(60) As shown in
(61) By the sixth embodiment of the present invention, since the cooling member 61 having cross section of a square bracket is provided in the extracting area 50, heat radiation of the ingot 22 can be promoted more than in the case of the fifth embodiment, and thus cooling can be performed faster.
(62) In the above explanation of the sixth embodiment, the example in which ingots are produced in two lines is explained; however, the present embodiment is not limited to the production of ingots in two lines, and for example, production in which combination of the ingot and the cooling member is provided multiply, in three or more lines, is possible.
(63) In addition, the two cooling member having a cross section of a square bracket shape shown in
Seventh Embodiment (Multiple Ingots+Square Shaped Cooling Member)
(64) In the seventh embodiment of the present invention, as shown in
(65) As shown in
(66) By the seventh embodiment of the present invention, since the cooling member 62 having a cross section of the shape of a square is provided in the extracting area 50, the ingot can be cooled from all directions, heat radiation of the ingot 22 can be promoted more than in the case of the fifth and sixth embodiments, and thus cooling can be performed more rapidly.
(67) In the above explanation of the seventh embodiment, the example in which ingots are produced in two lines is explained; however, the present embodiment is not limited to the production of ingots in two lines, such as an example of production in which combination of the ingot and the cooling member is provided multiply, in three or more lines, is possible.
Eighth Embodiment [Multiple Ingots+Coil Shaped Cooling Member]
(68) In the eighth embodiment of the present invention, as shown in
(69) As shown in
(70) By the eighth embodiment of the present invention, since the cooling member 63 having a coil shape is provided in the extracting area 50, the ingot can be cooled from all directions, heat radiation of the ingot 22 can be promoted the same as in the seventh embodiment, and thus cooling can be performed more rapidly.
(71) In the above explanation of the eighth embodiment, the example in which ingots are produced in two lines is explained; however, the present embodiment is not limited to the production of ingots in two lines, and for example, production in which combination of the ingot and the cooling member is provided multiply, in three or more lines, is possible.
Ninth Embodiment (Multiple Ingots+Triangular Pillar Shaped Cooling Member)
(72) Next, another embodiment of the present invention is explained.
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(74) By the ninth embodiment of the present invention, even in a case in which surfaces of the ingots in two lines are not parallel to each other, since the cooling member provided between the ingots is a triangular pillar and two surfaces thereof face each surface of the ingots in parallel, heat radiation can be also promoted even between the ingots, and thus cooling can be performed faster. As a result, uniform cooling from all of the surfaces of the ingots is possible.
Tenth Embodiment (Multiple Ingots+Triangular Pillar Shaped Cooling Member)
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(77) By the tenth embodiment of the present invention, even in a case in which ingots are provided in a radial fashion and surfaces of the ingots are not parallel to each other, since the cooling member provided between the ingots is a triangular pillar and two surfaces thereof face each surface of the ingots in parallel, heat radiation can also be promoted even between the ingots, and thus cooling can be performed more rapidly. As a result, uniform cooling from all of the surfaces of the ingots is possible. In addition, by the present embodiment, multiple ingots can be efficiently produced in a limited space.
(78) Other Variation (Nonrectangular Ingot+Cooling Member)
(79)
(80) Furthermore, as shown in
(81) Furthermore, in a manner similar to the explanation of embodiments of a rectangular ingot, multiple combinations of an ingot 23 and a cooling member shown in
(82) Furthermore, as shown in plane view in
(83) Furthermore, as shown in
(84) A feature of the present invention is that the cooling member is provided between the multiple ingots, and/or between the outer case and the ingot. Among these, in the embodiment in which the cooling member is provided between the multiple ingots, as already explained in
(85) In addition, although description is omitted in the figure, the cooling member can be provided between the ingot 22 and the outer case 51. Furthermore, by combining both embodiments as shown in
(86) If the mutual heating between the ingots 22 is reduced, there will be no gradient of temperature distribution along a cross sectional direction in each ingot 22 extracted from the mold. As a result, thermal deformation of ingot that is produced can also be effectively reduced. Finally, an ingot having superior linear properties can be produced.
(87) In the present invention, it is preferable that the temperature gradient in which temperature decreases from a top part of a cooling member to a bottom part of the cooling member, is given to a cooling member provided along a vertical direction. As a result, compared to a case in which such temperature gradient is not given to the cooling member, the casting surface of the ingot produced is improved.
(88) Furthermore, in the present invention, it is preferable that the temperature gradient in which temperature decreases from a bottom part of a cooling member to a top part of the cooling member, is given to a cooling member provided along a vertical direction. As a result, compared to a case in which such a temperature gradient is not given to the cooling member, linearity of the ingot produced is improved.
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(92) In the structure of this embodiment, hot water (H) is supplied to the first portion 69a, and the hot water (H) is expelled from the portion. It is preferable that the temperature of the hot water supplied to the first portion 69a be in a range from 50 to 70° C.
(93) In addition, it is preferable that cold water (L) be supplied to bottom of the third portion 69c, that the cold water (L) be expelled from top of the portion, and that the cold water (L) that is expelled be supplied to a bottom of the second portion 69b. It is preferable that temperature of the cold water supplied be in a range from 5 to 20° C.
(94) By producing a negative temperature gradient in which temperature decreases from the top to the bottom in the cooling member 69, as mentioned above, since the ingot 22 just after it is extracted from the mold 16 is cooled step by step, and is not cooled suddenly, therefore, the casting surface of the ingot 22 produced can be improved.
(95) Furthermore, in the present invention, although not shown in the figure, it is possible for the cold water (L) to be supplied to the first portion 69a and the second portion 69b, and for the hot water (H) to be supplied to the third portion 69c, unlike in the
(96) By giving a positive temperature gradient, in which temperature increases from the top to the bottom in the cooling member 69 as mentioned above, since mutual heating between the ingots 22 just after extracted from the mold 16 is reduced, it is therefore possible for the temperature distribution in the ingot to be prevented from being nonuniform, and linearity of the ingot can be improved.
(97) Although description in figure is omitted, the present invention is not limited to an ingot having a cross section of a rectangle and a circle, and the present invention can be employed for any other ingots having cross sectional shapes such as an ellipse, barrel, polygon, or other irregular shapes formed by curve, as long as it can be practically produced, and can be employed to a case of ingots in single line and in a case of ingots in multiple lines. In each case, the cooling member of the present invention has a shape surrounding all or part of circumference of the ingot surface, and extends along the ingot surface while having a certain gap from the ingot surface.
(98) The cooling member for cooling a metallic ingot is made of a metal having good heat conductivity, and it is preferable that a cooling medium be used in the member itself. As the cooling method, a method in which all surfaces of a copper member are cooled by being a jacket structure of the member, a method in which a cooling medium is flowing through a pathway in advance formed in the cooling member so as to cool the member, and a method in which a metallic pipe is provided at the surface of the cooling member in a coil shape so as to cool the cooling member, can be mentioned. By employing one of these methods, heat in the ingot can be efficiently removed.
(99) As a material for the cooling member, any materials which exhibit heat conduction effects can be selected, and for example metals, ceramics, heat-resistant engineering plastics or the like can be mentioned, and in particular, in the present invention, among these materials, material having superior heat conductivity such as copper, aluminum, iron or the like is desirably used.
(100) As a cooling medium, water, organic solvent, oil or gas can be used.
(101) In another cooling method for the cooling member, a method using the so-called Peltier effect, which is exhibited by bonding two or more kinds of different metals and applying direct current to the member, may be mentioned. In this method, one surface of the member of the Peltier element facing to the ingot is cooled, while the opposite surface of the member radiates heat. This method can be used alone or by combining with another cooling method explained so far. In this case, as the member, cladding material of copper and constantan (a copper-nickel alloy) or cladding material of copper and a nickel chromium alloy, can be desirably used.
Eleventh Embodiment (Mold Having One Kind of Cooling Material+Thickness Increasing Portion+Parallel Portion)
(102) A desirable embodiment of the mold 16 of the electron beam melting furnace in
(103) A mold 80 of the present embodiment consists of a first cooling portion (thickness increasing portion) 80a which is an upper part of the mold, and a second cooling portion (parallel portion) 80b which is a lower part of the mold. The first cooling portion (thickness increasing portion) 80a is provided from a region corresponding to a meniscus portion 21a in which a liquid phase of mold pool 21 of the molten metal held in the mold 16 directly contacts with an upper region than the meniscus portion. In the first cooling portion, thickness of the mold wall increases in the upper direction.
(104) The second cooling portion (parallel portion) 80b is provided from a region corresponding to a part where a solid phase of the mold pool 21 contacts, to a lower region than the part. In the second cooling portion, thickness of the mold wall is constant.
(105) At the outside of the mold 80, cooling medium 80d is supplied to the thickness increasing portion 80a and the parallel portion 80b in common.
(106) First, the raw material 12 supplied from the raw material supplying device 10 is melted by the electron beam gun 14 in the hearth 13 so as to form the molten metal 20. The molten metal 20 is supplied from downstream of the hearth 13 to inside of the mold 16. A stub not shown in the figure is provided in the mold 16 before melting of the raw material 12, this stub functions as a bottom part of the mold 16. The stub consists of as similar metal as the raw material 12, and forms ingot 22 by being unified with the molten metal 20 supplied in the mold 16.
(107) Surface of the molten metal 20 continuously supplied on the stub in the mold 16 is heated by the electron beam gun 15 so as to form molten metal pool 21. Bottom part of the molten metal pool 21 is cooled and solidified by the mold 16, and forms ingot 22 by unifying with the stub. The ingot 22 generated in the mold 16 is extracted to the extracting area 50 while controlling extracting rate of the extracting jig 30 engaged to the stub so that level of the molten metal pool 21 becomes constant.
(108) The feature of the present embodiment is that temperature distribution in which temperature monotonically decreases from the top part to the bottom part of the mold wall is given to the mold wall, and that there is at least one inflection point in the temperature distribution, as shown in
(109) That is, as arranging the temperature distribution as mentioned above, since cooling is relatively mild at the primary cooling portion 80a so that the mold pool is maintained at high temperature, the meniscus portion 21a can be formed so as to be long. On the other hand, since cooling is relatively rapid at the secondary cooling portion 80b, solidification is promoted, the solid-liquid interface 21b at the bottom part of the mold pool has a broader shape than a parabola shape, that is, a shallow mold pool can be formed. In this way, mixing of molten metal is promoted even around the vicinity of the bottom part of the mold pool 21, and the ingot extracted is prevented from being affected by the bottom portion of the mold pool, which is a melted part. As a result, an ingot having a superior casting surface can be produced.
(110)
(111) In addition, the situation of temperature depending on position (coordinate L) in the mold is described as a conceptual graph in
(112) It should be noted that a curve convex in the lower direction is shown in
Twelfth Embodiment (Mold Having Two Kinds of Cooling Medium)
(113) Hereinafter twelfth to fourteenth embodiments of the melting furnace for producing metal are explained. In the following embodiments, explanation of construction elements that are the same as in the twelfth embodiment is omitted, and only a mold part that is different is explained.
(114)
(115) At the outside of the mold 81, mutually separate divided pathways are formed, and a primary cooling medium 81d and a secondary cooling medium 81e are supplied to cool the primary cooling portion 81a and the secondary cooling portion 81b of the mold, respectively. Temperature of the primary cooling medium 81d is higher than that of the secondary cooling medium 81e. Therefore, heat absorption amount of the primary cooling portion 81a is small and that of the secondary cooling portion 81b is large.
(116) By this structure, since cooling is relatively mild in the primary cooling portion 81a, and thus the mold pool is maintained at a high temperature, the meniscus portion 21a can be formed longer; on the other hand, since cooling is relatively rapid in the secondary cooling portion 81b and thus solidification is promoted, the solid-liquid interface 21b at the bottom part of the mold pool can be formed in a broader shape than a parabolic shape, that is, the mold pool can be formed to be shallow. By this structure, mixing of the molten metal components is promoted even around the bottom part of the mold pool 21, and thus the ingot extracted is prevented from being affected by the bottom portion of the mold pool that is a melted portion. As a result, an ingot having a superior casting surface can be produced.
Thirteenth Embodiment (Mold Having One Kind Cooling Medium+Single Coil)
(117)
(118) Outside of the mold 82, a single coil is wound. The coil is wound relatively sparsely around a part corresponding to the primary cooling portion 82a, and is wound relatively densely around a part corresponding to the secondary cooling portion 82b. A cooling medium 82d is supplied to the single coil.
(119) In this embodiment, since the coil is sparsely wound (the number of coils is small) around the primary cooling portion 82a and is densely wound (the number of coils is large) around the secondary cooling portion 82b, the heat absorption amount is proportion to the number of the coil windings, and thus the heat absorption amount at the primary cooling portion 82a is small and the heat absorption amount at the secondary cooling portion 82b is large.
(120) By this structure, since cooling is relatively mild in the primary cooling portion 82a, and thus the mold pool is maintained at a high temperature, the meniscus portion 21a can be formed longer; on the other hand, since cooling is relatively rapid in the secondary cooling portion 82b, and thus solidification is promoted, the solid-liquid interface 21b at the bottom part of the mold pool can be formed in a broader shape than a parabolic shape, that is, the mold pool can be formed so as to be shallow. By this structure, mixing of the molten metal components is promoted even around the bottom part of the mold pool 21, and thus the ingot extracted, is prevented from being affected by the bottom portion of the mold pool, which is the melted portion. As a result, an ingot having a superior casting surface can be produced.
Fourteenth Embodiment (Mold Having Two Kinds of Cooling Medium+Two Coils)
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(122) Outside of the mold 83, two coils are wound so that two kinds of cooling medium can be separately supplied. Unlike in the thirteenth embodiment, a coil corresponding to the primary cooling portion 83a and a coil corresponding to the secondary cooling portion 83b are mutually separated. A cooling medium 83d having relatively higher temperature is supplied to the coil around the primary cooling portion 83a, and a cooling medium 83e having relatively lower temperature is supplied to the coil around the secondary cooling portion 83b.
(123) In this embodiment, since the cooling medium of relatively higher temperature is supplied to the primary cooling portion 83a and the cooling medium of relatively lower temperature is supplied to the secondary cooling portion 83b, heat absorption amount at the primary cooling portion 83a is small and the heat absorption amount at the secondary cooling portion 83b is large.
(124) By this structure, since cooling is relatively mild in the primary cooling portion 83a, and thus the mold pool is maintained at a high temperature, the meniscus portion 21 can be formed longer; on the other hand, since cooling is relatively rapid in the secondary cooling portion 83b, and thus solidification is promoted, the solid-liquid interface 21b at the bottom part of the mold pool can be formed in a broader shape than a parabolic shape, that is, the mold pool can be formed so as to be shallow. By this structure, mixing of the molten metal components is promoted even around the bottom part of the mold pool 21, and thus the ingot that is extracted is prevented from being affected by the bottom portion of the mold pool, which is a melted portion. As a result, an ingot having a superior casting surface can be produced.
(125) Variation (Mold Having Tapered Part)
(126) In addition to the molds 80 to 83 explained above, tapered portions 80c to 83c, can be provided at a lower end part of the secondary cooling portions 80b to 83b, respectively, as shown in
(127) By arranging the tapered portions 80c to 83c, compression by stress can be added to the surface of the ingot extracted in the molds 80 to 83, and as a result, the casting surface can be improved.
(128) It is preferable that the tapering angle θ of the tapered portion in the present invention be in a range from 1 to 5 degrees. In a case in which the tapering angle θ is less than 1 degree, notable improvement in the casting surface is not obtained, and in a case in which the tapering angle θ is greater than 5 degrees, the ingot cannot be extracted from the mold.
(129) In the embodiments of the present invention, it is preferable that the relationship of length of the primary cooling portion and the secondary cooling portion be in a range such that the primary cooling portion to the secondary cooling portion=45 to 55:45 to 55 in a case in which the tapered portion is not provided, and it is preferable that the primary cooling portion to the secondary cooling portion (portion except for the tapered portion) to the tapered portion=45 to 55:20 to 25:20 to 25 in a case in which the tapered portion is provided.
(130) The preferable embodiment of the process for production of ingot using electron beam melting furnace mentioned above can be employed also in a plasma arc melting furnace, and as a result, an ingot having a superior casting surface and linearity can be produced.
(131) By producing a metallic ingot by the present invention as described above, cooling can be performed rapidly, deterioration of the ingot by oxidation by the air can be reduced, and production efficiency of the ingot can be improved. Furthermore, since heat radiation from the ingot can be performed to all directions uniformly, deformation of the ingot due to nonuniform temperature distribution can be prevented.
(132) In this way, in the melting furnace for producing metal of the present invention, by arranging at least one cooling member between ingots extracted from the mold, and/or between the ingot and the outer case, not only can warping of the ingot produced be effectively reduced, but also the casting surface of the ingot produced can be improved by arranging temperature distribution to the cooling member.
EXAMPLES
(133) Hereinafter the present invention is explained in detail with reference to Examples and Comparative Examples.
Example 1
(134) Using the electron beam melting furnace having a following apparatus construction, titanium ingots were produced.
(135) 1. Raw material for melting
(136) Titanium sponge (diameter range: 1 to 20 mm)
(137) 2. Apparatus construction
(138) 1) Hearth (material and structure: water cooled copper hearth, molten metal exhaust ports: two)
(139) 2) Mold (water cooled copper mold: one, cross sectional shape: rectangle)
(140) 3) Cooling member (provided around ingot)
(141) Temperature of cooling water: 20° C.
(142) Temperature gradient: none
(143) 3. Ingot produced
(144) Shape: diameter 100
(145) 4. Ingot extracting mechanism
(146) An ingot extracting jig was provided below each mold, and the ingots were extracted at the same time.
(147) 5. Pressure controlling
(148) While monitoring a pressure meter provided in the furnace, pressure inside of the furnace was controlled within a certain range.
(149) Time required for cooling ingot in a case in which the cooling member was provided surrounding circumference of the ingot (diameter 100) held at 1000° C. to 300° C. in the mold 16 as shown in
(150) TABLE-US-00001 TABLE 1 Cooling member Provided Not Provided Cooling time (min) 60 180
Example 2
(151) Time required for cooling the ingot was measured under conditions similar to those in Example 1, except that the cooling member shown in
(152) TABLE-US-00002 TABLE 2 Cooling member Provided Not Provided Cooling time (min) 100 180
Example 3
(153) Time required for cooling the ingot was measured under conditions similar to those in Example 1, except that two ingots were produced by two molds, and except that the cooling member shown in
(154) TABLE-US-00003 TABLE 3 Cooling member Provided Not Provided Cooling time (min) 120 300
Example 4
(155) Time required for cooling the ingot was measured under conditions similar to those in Example 1, except that two ingots were produced by two molds, and except that the cooling member shown in
(156) TABLE-US-00004 TABLE 4 Cooling member Provided Not Provided Cooling time (min) 60 300
Example 5
(157) Time required for cooling the ingot was measured under conditions similar to those in Example 1, except that two ingots were produced by two molds, and except that the cooling member shown in
(158) TABLE-US-00005 TABLE 5 Cooling member Provided Not provided Cooling time (min) 100 300
Example 6
(159) As a result of two ingots being produced and extracted at the same time under conditions similar to those in Example 1 except that two ingots were produced by two molds and except that apparatus construction shown in
Example 7
(160) Two ingots were produced under conditions similar to those in Example 6 except that the apparatus shown in
Example 8
(161) Two ingots were produced under conditions similar to those in Example 7 except that apparatus shown in
Example 9
(162) Two ingots were produced under conditions similar to those in Example 6 except that the two cooling members 60 were provided as shown in
Example 10
(163) Using the apparatus shown in
Comparative Example 1
(164) Two ingots were produced in a manner similar to that in Example 6 except that the cooling member 60 was not provided. As a result, action of the ingot extracting device slowed down when 30% of total melting time passed, and therefore, the current value of the motor was confirmed. Then, compared to an ordinary case, the value was increased up to the control upper limit. Therefore, halting the extracting device and electron beam, the inside of the apparatus was cooled to room temperature. Observing the situation of the ingots produced, it was confirmed that warping was generated on each surface of the ingots facing each other.
(165) The test conditions and the test results of Examples 6 to 10 and Comparative Example 1 are shown in Table 6. It was confirmed that not only can linearity of the ingot produced be maintained, but also the casting surface of the ingot produced can be improved by arranging cooling member of the present invention between ingots extracted from the molds.
(166) TABLE-US-00006 TABLE 6 Number Cooling member Extracting Casting Linearity of molds Number Temperature distribution rate ratio surface of ingot Example 6 2 1 None 2.0 B B Example 7 2 1 Distributed (negative 2.0 A B temperature gradient) Example 8 2 1 Distributed (positive 2.0 B A temperature gradient) Example 9 2 2 None 2.0 B A Example 10 2 2 None 2.1 B B C. Example 1 2 — — 1.0 — D
Example 11
(167) Titanium ingots were produced in the following apparatus construction and conditions.
(168) 1. Raw material for melting
(169) Titanium sponge (diameter range: 1 to 20 mm)
(170) 2. Apparatus construction
(171) 1) Hearth (water cooled copper hearth)
(172) 2) Mold:
(173) Type 1: mold having a thickness increasing portion shown in
(174) Upper tapering angle=10 degrees
(175) Type 2: mold having a thickness increasing portion, a parallel portion, and a tapering portion shown in
(176) Upper tapering angle=10 degrees
(177) Lower tapering angle=1 degree
(178) Thickness increasing portion length:Parallel portion length:Tapering portion length=50:25:25
(179) Type 3: mold having ceramic lining on inner surface shown in
(180) Using the mold having a thickness increasing portion of the abovementioned type 1, electron beam melting of titanium sponge was performed and an ingot of 500 kg was produced. The casting surface of the ingot produced was observed visually, and evaluation was performed and the results are shown in Table 7.
Example 12
(181) An ingot of 500 kg was produced in a manner similar to that in Example 11, except that the mold having thickness increasing portion, parallel portion, and lower tapering portion of type 2 was used. The casting surface of the ingot produced was observed visually, and evaluation was performed and the results are shown in Table 7.
Comparative Example 2
(182) An ingot of 500 kg was produced in a manner similar to that in Example 11, except that the mold having a ceramic lining of type 3 was used. After production, as a result of observing the conditions inside the mold, the ceramic lining on the inner surface was removed.
(183) TABLE-US-00007 TABLE 7 Casting surface Mold Top Middle Bottom Example 11 Type 1 B B B Example 12 Type 2 A A A C. Example 2 Type 3 C D D A: Casting surface is extremely superior B: Casting surface is superior C: Casting surface is rough in parts D: Casting surface is rough over the entire surface
Example 13
(184) The condition of the casting surface of the ingot extracted from the mold and conditions of extracting of ingot were researched in a manner similar to that in Example 12, except that tapering angle of the mold shown in
(185) It was confirmed that a superior casting surface can be obtained in a case of the tapering angle of 1 to 5 degrees compared to a case in which the tapering angle was 0 degrees; that is, a case of the mold having only the thickness increasing portion and not having the tapering portion shown in
(186) TABLE-US-00008 TABLE 8 Taper angle Items 0 1 3 5 7 Casting surface C A A A — Extracting condition B B B B D
Example 14
(187) Ingots were produced in a manner similar to that in Example 11, except that wall thickness of the thickness increasing portion of the top portion of the mold was varied to double, three times, and four times. The casting surface of each ingot was examined. The results are shown in Table 9. In a case in which wall thickness of the thickness increasing portion is more than double, the casting surface of the ingot was improved; however, notable improvement in the casting surface was not observed in a case in which wall thickness was less than double. Therefore, it was confirmed that the casting surface was improved by making the wall thickness of the thickness increasing portion more than double wall thickness of the parallel portion of the mold wall.
(188) TABLE-US-00009 TABLE 9 Thickness of thickness increasing portion (—) 1.0 1.5 2.0 3.0 4.0 Casting surface B B A A A
(189) It was confirmed that not only can the linearity of the ingot produced be maintained, but also the casting surface of the ingot produced can be improved by arranging a cooling member of the present invention between ingots extracted from the molds, according to the test conditions and test results of Examples and Comparative Examples described mentioned.
(190) Furthermore, by using a mold having a cooling structure of the present invention, an ingot having a superior casting surface can be produced.
(191) By the present invention, while preferably maintaining properties such as linearity or casting surface of the ingot, in addition, multiple ingots can be efficiently produced at the same time.
EXPLANATION OF REFERENCE NUMERALS
(192) 10 . . . Raw material supplying device, 11 . . . raw material conveying device, 12 . . . raw material, 13 . . . hearth, 14,15 . . . electron beam radiating device, 16 . . . mold, 17-19 . . . sluice, 20 . . . molten metal, 21 . . . molten metal pool, 21a . . . meniscus portion, 21b . . . solid-liquid interface, 22 . . . ingot (square cross section), 23 . . . ingot (circular cross section), 30 . . . ingot extracting jig, 40 . . . melting area, 41 . . . melting area outer case, 50 . . . extracting area, 51 . . . extracting area outer case, 60 . . . cooling member (tabular jacket), 61 . . . cooling member having a square bracket shaped jacket, 62 . . . cooling member having a square shaped jacket, 63,67 . . . cooling member (coil), 64,65 . . . cooling member (triangular pillar (prism) shaped jacket), 66 . . . cooling member (circular), 68 . . . cooling member, 69 . . . cooling member (divided), 69a-69c . . . first to third portions of divided cooling member, 70 . . . tabular member, 71 . . . tabular member (circular shape), 72 . . . fixing jig, 80-84 . . . mold, 80a-84a . . . primary cooling portion, 80b-84b . . . secondary cooling portion, 80c-84c . . . tapering portion, 80d-84d . . . (primary) cooling medium, 81e,83e . . . secondary cooling medium, 85 . . . ceramic, H . . . hot water, L . . . cold water.