MWIR photodetector with compound barrier with P-N junction
09748427 · 2017-08-29
Assignee
Inventors
- Rajesh D Rajavel (Oak Park, CA, US)
- Hasan Sharifi (Agoura Hills, CA)
- Terence J De Lyon (Newbury Park, CA, US)
- Pierre-Yves Delaunay (Santa Monica, CA, US)
- Brett Z Nosho (Santa Monica, CA, US)
Cpc classification
H01L31/03046
ELECTRICITY
H01L31/109
ELECTRICITY
Y02E10/544
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
H01L31/103
ELECTRICITY
H01L31/101
ELECTRICITY
Abstract
The invention describes a device which enables MWIR photodetectors to operate at zero bias and deliver low dark current performance. The performance is achieved by incorporating a p-n junction in the barrier. The device consists of a p-type contact layer, a p-n junction in the compound barrier (CB) with graded composition and/or doping profiles, and an n-type absorber (p-CB-n) device.
Claims
1. A photodetector structure comprising: a compound barrier layer disposed on an absorber layer; a first contact layer disposed on the absorber layer opposite the compound barrier layer, the compound barrier comprising: a first barrier layer comprising a first material having a first doping type disposed on the absorber layer, a second barrier layer comprising the first material having a second doping type disposed on the first barrier layer; wherein the absorber layer has the first doping type; the first doping type is opposite the second doping type; and wherein the first barrier layer and second barrier layer have a same doping level such that the first and second barrier layers of opposite conductivity types introduce a p-n junction in the compound barrier to minimize band bending in the absorber layer.
2. The photodetector of claim 1, wherein the absorber layer comprises a III-V semiconductor material.
3. The photodetector of claim 1, further comprising a second contact layer disposed on the second barrier layer.
4. The photodetector of claim 1, further comprising a second contact layer doped the second doping type disposed on the second barrier layer.
5. The photodetector of claim 3, wherein the second contact layer has a band gap equal to or greater than that of the absorber layer.
6. The photodetector of claim′, wherein a substrate is disposed on the first contact layer opposite the absorber layer.
7. The photodetector of claim 6, wherein the substrate is GaAs.
8. A photodetector structure comprising: a buffer layer disposed on a substrate; a first contact layer with a first contact layer doping type disposed on the buffer layer; an absorber layer with an absorber layer doping type disposed on the first contact layer, wherein the first contact layer doping type is same as the absorber layer doping type and a first contact layer band gap is equal to or larger than an absorber layer band gap; a compound barrier layer disposed on the absorber layer; wherein the compound barrier layer has a band gap greater than the band gap of the absorber layer and comprising: a first barrier layer comprising a first material with a first barrier layer doping type disposed on the absorber layer, the first barrier layer doping type is the same as the absorber layer doping type; a second barrier layer comprising the first material with a second barrier layer doping type disposed on the first barrier layer wherein the second barrier layer doping type is opposite the first barrier layer doping type; wherein the first barrier layer and the second barrier layer have a same doping level such that the first barrier layer and second barrier layer of opposite conductivity types introduces a p-n junction in the compound barrier to minimize band bending in the absorber layer; a cladding layer disposed on the second barrier layer.
9. The photodetector of claim 8, further comprising a second contact layer with a second contact layer doping type opposite the absorber layer doping type disposed on the cladding layer.
10. The photodetector of claim 1, wherein the first material comprises AlGaSb, AlAs.sub.xSb.sub.1-x, AlGa.sub.xSb.sub.1-x, AlInAsSb, or AlGaAsSb.
11. The photodetector of claim 8, wherein the first material comprises a superlattice of InAs/GaInSb/AlGaSb.
12. The photodetector of claim 8, wherein the first material comprises AlAs.sub.xSb.sub.1-x, AlGa.sub.xSb.sub.1-x, AlInAsSb, or AlGaAsSb.
13. The photodetector of claim 8, wherein: the first barrier layer is graded in composition; and the second barrier layer is graded in composition.
14. The photodetector of claim 8, wherein: the first contact layer and the compound barrier layer comprise antimony and one or more of the following: Al, Ga, In, As or N.
15. The photodetector of claim 8, wherein: at least one of the absorber layer, the first contact layer; or the compound barrier layer comprises a binary alloy, a ternary alloy, or a quaternary alloy.
16. The photodetector of claim 1, wherein the first material is a superlattice of In As/GaInSb/AlGaInSb.
17. The photodetector of claim 1, wherein the first material comprises a plurality of alternating monolayers of InAs and GaSb.
18. The photodetector of claim 8, wherein: the first barrier layer is graded in doping level; and the second barrier layer is graded in doping level.
19. The photodetector of claim 1, wherein: the first barrier layer is graded in composition; and the second barrier layer is graded in composition.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The accompanying drawings, together with the specification, illustrate exemplary embodiments of the present invention, and, together with the description, serve to explain the principles of the present invention.
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DETAILED DESCRIPTION
(25) In the following detailed description, only certain exemplary embodiments of the present invention are shown and described, by way of illustration. As those skilled in the art would recognize, the described exemplary embodiments may be modified in various ways, all without departing from the spirit or scope of the principles of the present invention. Accordingly, the drawings and description are to be regarded as illustrative in nature, and not restrictive.
(26) The problems described in the Background section are at least partially solved by the principles of the present invention, including, by using a barrier layer structure comprising a p-n junction and including a contact layer whose doping type is opposite to that of the absorber layer.
(27) The principles of the present invention disclose a p-CB-n (or alternatively n-CB-p based device) based device which exhibits broad photodetector response at a bias of zero volts (i.e. zero volt turn-on), has minimal barriers that can impede the flow of minority carriers, and hence represents appropriate band alignment necessary for the collection of photo-generated minority carriers. In contrast to the principles of the present invention, prior art barrier based mid wave infrared (MWIR) photodetectors reported in the literature have turn-on voltages of ˜100 to 700 mV due to the presence of one or more barriers. The presence of multiple barriers can compromise the quantum efficiency performance of the device. From Molecular Beam Epitaxy (MBE) growth and Focal Plane Array (FPA) performance reproducibility standpoints, it is desirable to utilize a design that offers zero turn-on voltage. Zero turn-on voltage enables one to quickly track performance drifts from the expected baseline performance. One embodiment according to the principles of the present invention achieves this by doping the contact p-type which facilitates unimpeded flow of holes from the n-type absorber to the contact.
(28) The principles of the present invention results in two fundamental device design attributes: doping the contact p-type for an n-type absorber and introducing a p-n junction in the barrier.
(29) While the embodiments according to the principles of the present invention are described in the context of MWIR devices, the principles of the present invention are applicable to Short Wave Infrared (SWIR) and Long Wave Infrared (LWIR) photodetectors as well.
(30) Prior-art designs of “nBn” photodetectors are based on a structure shown in
(31) The primary characteristic to the design in
(32) By way of example and not limitation, the following embodiments are particularly suited for detecting light in the 0.5 micron to 20 micron wavelengths. Different material combinations will allow other wavelengths of light to be detected.
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(34) Continuing with
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(36) Typical materials for the barrier layers 711/713 are AlAs.sub.XSb.sub.1-X, AlGa.sub.XSb.sub.1-X or an alloy consisting substantially of AlInAsSb or AlGaAsSb with barrier layer 711 doped p-type and barrier layer 713 doped n-type. Preferred doping levels range between 1E14 and 1E17. Doping materials, by way of example and not limitation, may be beryllium, carbon, silicon or tellurium.
(37) In an alternative embodiment, the contact layer 712 may be doped p-type to a concentration substantially between 1.0E16 and 1.0E19 per cm.sup.3. Doping materials, by way of example and not limitation, may be beryllium or carbon.
(38) The thicknesses of the barrier layers 711/713 may be between 50 nm to 400 nm with 150 nm preferred for the barrier layer 711 and 100 nm for the barrier layer 713 in one embodiment.
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(41) As shown in
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(43) The structure diagram of the p-CB-n device according to the principles of the present invention that provides zero-turn on voltage operation is shown in
(44) The corresponding current density vs. voltage characteristics of the detectors with p-type contact 1101 and the prior art n-type contact 1102 are shown in
(45) To achieve improved performance, additional layers can be utilized in the device 1200 structure as illustrated in
(46) Focal plane arrays that have multiple pixels can be fabricated by shallow etching of the top contact layer and terminating the etch on or within Barrier3 1223 to delineate the pixels. Barrier3 1223 may comprise an aluminum alloy with less than about 75% aluminum, such as AlGaAsSb or AlInAsSb, such that it is less prone to degradation as compared to the Barrrier2 1211 and Barrier 1 1213 compositions which can have higher aluminum contents.
(47) A heavily doped p-type region 1221 that is adjacent the p-type contact layer 1212 can be utilized to achieve good ohmic contacts and lateral conductivity as needed. The contact layers 1212 and 1221 may comprise a wide band gap material as compared to the absorber layer 1214 such that it does not absorb the radiation that is being sensed, and can promote double pass absorption in the absorber layer 1214 (through the use of a metallized surface). Likewise, a heavily doped, n-type contact layer 1225 can be used adjacent the absorber 1214 as well to also reduce the contact resistance and increase lateral conductivity across the focal plane array. This n-type contact layer 1225 can consist of a wide bandgap alloy (as compared to the absorber) such that it transmits the radiation that is being sensed and also serves to reflect the holes (minority carrier) away from the absorber/contact interface. Utilizing wide bandgap contact layers at the top (1221 and 1212, or alternatively 1221 or 1212) and the bottom layer (1225) enable the detector 1200 to accommodate light incidence from the top or the bottom side depending on the detector or read-out integrated circuit integration architecture and the fabrication process.
(48) Continuing with the embodiment illustrated in
(49) Materials for the device 1200 in
(50) In particular the layers 1215, 1224 and 1222 with reference to
(51) Alternatively the layers 1215, 1222 and 1224 with reference to
(52) In an array of devices 1200, the array common contact can be made through the contact layer 1212/1221 while the absorber 1214, graded layer 1224 and barrier layers 1213/1211/1223 are reticulated. See
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(54) Without implying a limitation,
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(56) The ability to controllably dope the barrier layer is critical for control of the electric field in the absorber layer of the device. With proper selection of the barrier doping, the electric field in the absorber layer can be minimized, which eliminates substantially all generation-recombination current contribution to the dark current. Specifically, the absorber layer in the vicinity of the barrier layer preferably has a low electric field strength to minimize depletion of the absorber layer. Preferably the electric field strength is less than about 10 V/cm. Depletion of the absorber layer can result in increased dark current (generation-recombination current)
(57) Without implying a limitation, a typical techniques to fabricate the infrared photodetector devices 700 and 1200 includes Molecular Beam Epitaxy and metallorganic chemical vapor deposition. The fabrication of a detector array can be accomplished by delineating individual pixels. This can be accomplished in many ways. Pixel delineation can be achieved by a shallow etch that etches the contact layer (
(58) The foregoing Detailed Description of exemplary and preferred embodiments is presented for purposes of illustration and disclosure in accordance with the requirements of the law. It is not intended to be exhaustive nor to limit the invention to the precise form(s) described, but only to enable others skilled in the art to understand how the invention may be suited for a particular use or implementation. The possibility of modifications and variations will be apparent to practitioners skilled in the art. Other embodiments are within the scope of the claims. No limitation is intended by the description of exemplary embodiments which may have included tolerances, feature dimensions, specific operating conditions, engineering specifications, or the like, and which may vary between implementations or with changes to the state of the art, and no limitation should be implied therefrom. Applicant has made this disclosure with respect to the current state of the art, but also contemplates advancements and that adaptations in the future may take into consideration of those advancements, namely in accordance with the then current state of the art. It is intended that the scope of the invention be defined by the claims as written and equivalents as applicable. Reference to a claim element in the singular is not intended to mean “one and only one” unless explicitly so stated. Moreover, no element, component, nor method or process step in this disclosure is intended to be dedicated to the public regardless of whether the element, component, or step is explicitly recited in the claims. No claim element herein is to be construed under the provisions of 35 U.S.C. Sec. 112, sixth paragraph, unless the element is expressly recited using the phrase “means for . . . ” and no method or process step herein is to be construed under those provisions unless the step, or steps, are expressly recited using the phrase “comprising the step(s) of . . . .”