DUAL GRID CATALYST BASKET AND METHOD OF INDEPENDENTLY SUPPORTING PRIMARY AND SECONDAY CATALYSTS
20170239635 · 2017-08-24
Assignee
Inventors
Cpc classification
C01B21/26
CHEMISTRY; METALLURGY
B01J2208/00814
PERFORMING OPERATIONS; TRANSPORTING
Y02C20/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
Abstract
An ammonia oxidation catalyst basket design has two support grids. A first grid supports the primary catalyst and a separate, second grid supports the secondary catalyst. This dual grid design separates the two catalysts, and enables the catalysts to be independent of each other. Any interruption in the primary or the secondary catalyst does not impede or adversely impact on the structure or function of the other catalyst.
Claims
1. A catalyst basket comprising: a housing; first support grid mounted to the housing for supporting an associated primary catalyst; and a separate, second support grid mounted to the housing independently supporting an associated secondary catalyst.
2. The catalyst basket of claim 1 wherein the second support grid is spaced from the first support grid.
3. The catalyst basket of claim 1 wherein the first support grid includes openings that allow gas flow therethrough.
4. The catalyst basket of claim 3 wherein the second support grid includes openings that allow gas flow therethrough.
5. The catalyst basket of claim 1 wherein a primary catalyst is sealed along a periphery thereof.
6. A method of supporting first and second catalysts in a catalyst basket comprising: supplying a housing mounting a first support grid to the housing for supporting a primary catalyst; and mounting a separate, second support grid to the housing for supporting a secondary catalyst and does not support the primary catalyst.
7. The method of claim 6 wherein the first and second support grids are mounted in spaced relation to independently support the primary and secondary catalysts, respectively.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0017]
[0018]
[0019]
DETAILED DESCRIPTION
[0020] Turning to
[0021] Between the first and second ends 112, 120 of the housing 110, a support flange 122 extends inwardly from an inner perimeter 124 of the housing 110. The support flange 122 has a generally stepped configuration in cross-section that forms first and second perimeter support surfaces 126, 128.
[0022] A first support grid 140 is supported along an outer perimeter portion thereof by the first surface 126 of the support flange 122. The first grid 140 is a rigid, foraminous structure (i.e., has a series of openings therethrough) and is shown here as a honeycomb grid although such a description should not be deemed as a limitation on the present disclosure. The first grid 140 supports a primary catalyst 142. One example of a primary catalyst is a platinum gauze that reacts with the gas flow, namely ammonia of a gas flow mixture that may comprise about 13% ammonia and 87% air, although other mixtures and percentages can be used without departing from the cope and intent of the present disclosure. The platinum gauze extends over the entire cross-sectional area or opening through the basket in preferred arrangements. The platinum reacts with the ammonia in the oxidation process.
[0023] A mesh screen 144 may also be interposed between the first grid 140 and the primary catalyst 142 to provide further support to the primary catalyst. In addition, a weighted ring 150 is received into the first end 112 of the housing 110, and the weighted ring provides a downward holding force on the primary catalyst 142 and mesh screen 144, that retains the primary catalyst in place on the first support grid 140. More specifically, the weighted ring 150 is dimensioned to engage outer perimeter portions of the primary catalyst 142 and the mesh screen 144, and hold these components against the second surface 128 of the support flange 122. In this manner, the potential for “gapping” to form between the outer perimeter of the primary catalyst and the housing is reduced.
[0024] A second support grid 160 is axially spaced (in a direction oriented along the gas flow path through the basket) from the first grid 140 in the housing 110. The second grid 160 and preferably a mesh screen 162 are also foraminous structures that support a secondary catalyst 170, namely a N.sub.2O abatement catalyst. In the illustrated embodiment of the present disclosure, the secondary catalyst 170 is shown as pellets that fill the axial space between the first and second grids. Preferably, the second grid 160 supports the secondary catalyst 170 independently of the primary catalyst 120. By independently supporting the secondary catalyst 170, the improved ammonia oxidation catalyst basket of the present disclosure overcomes many of the issues noted in the Background. The first and second grids separate the catalysts from each other and allow for these catalysts to perform independently of each other. Any movement of the secondary catalyst (i.e., the pellets) does not impact the primary catalyst so that there is less risk of gapping. Another advantage of the design of the present disclosure is that the primary catalyst 142 remains flat during a campaign cycle and this is likewise important to maintain the seal at the perimeter of the primary catalyst.
[0025] In summary, the platinum primary catalyst 142 is supported along its outer perimeter and sealed against the housing 110. It is desirable that all of the incoming gas (ammonia and air mixture) flow through the platinum gauze 142. The foraminous structure or first grid 140 is typically placed beneath the platinum gauze 142 to allow the gas to flow therethrough and provide a support surface beneath a central portion of the platinum gauze. A perimeter portion of the platinum gauze 142 is supported on an inner diameter shoulder 128 of the housing 110.
[0026] The secondary catalyst 170 or secondary abatement is received on an upper surface of the second grid 160 in axially spaced relation and beneath the platinum gauze 142. The present disclosure teaches supporting a primary catalyst independently of the secondary catalyst.
[0027] The present disclosure finds particular application in high pressure plants, where high pressure may range from approximately 135 to approximately 160 psi (e.g. about 150 psi), and may likewise find application in medium pressure plants where the operating pressure ranges from approximately 50 psi to approximately 100 psi. Again, however, these details are provided for sake of completeness and should not be deemed as a limitation to the present disclosure.
[0028] This written description uses examples to describe the disclosure, including the best mode, and also to enable any person skilled in the art to make and use the disclosure. The patentable scope of the disclosure is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal language of the claims. Moreover, this disclosure is intended to seek protection for a combination of components and/or steps and a combination of claims as originally presented for examination, as well as seek potential protection for other combinations of components and/or steps and combinations of claims during prosecution.