SOLVENT EXTRACTION AND STRIPPING SYSTEM

Abstract

An apparatus for separating a mixture of two liquids of different densities which liquids are substantially insoluble in one another includes a hollow permeable body having a recess for receiving a first fluid which can flow from the recess through the permeable body to an exterior of the permeable body. A housing surrounds and is spaced from the exterior of the permeable body. The housing has an inlet for a second fluid and an outlet for a mixture of the first and second fluid. A baffle or baffles are provided in the space between the exterior of the permeable body and the housing, and to define a mixing channel in space between the exterior of the permeable body and the housing so that the second fluid can enter the housing inlet and flow through the mixing channel to the outlet, while picking up fluid on the exterior of the permeable body.

Claims

1. An apparatus for mixing of two liquids of different densities which liquids are substantially insoluble in one another, said apparatus comprising: a first mixing vessel in the form of an elongate cylindrical housing having a first fluid inlet for introduction of a first fluid adjacent a first end, and a fluid outlet adjacent a second end, said first mixing vessel including a permeable body in the form of a cylindrical tube coaxially disposed within and spaced from an interior wall of said cylindrical housing, said permeable body having a second fluid inlet for a second fluid adjacent said first end and being closed adjacent said second end, said permeable body being at least partially filled with loosely packed finely divided media or frits, and having a baffle or baffles in the space between the exterior of the permeable body and an interior wall of the housing, the baffle or baffles being spaced to define a mixing channel through the space between the exterior of the permeable body and the interior wall of the housing so that the first fluid can enter the housing inlet and flow through the mixing channel to the outlet, while picking up the second fluid permeating through the permeable body to the exterior of the permeable body; and a second mixing vessel, similar to the first mixing vessel, said second mixing vessel also being in the form of an elongate cylindrical housing also having a first fluid inlet for introduction of a first fluid adjacent a first end and a fluid outlet adjacent a second end, said first mixing vessel including a permeable body in the form of a cylindrical tube coaxially disposed within and spaced from an interior wall of said cylindrical housing, said permeable body having a fluid inlet for a second fluid adjacent said first end and being closed adjacent said second end, said permeable body being at least partially filled with loosely packed finely divided media or frits, and having a baffle or baffles in the space between the exterior of the permeable body and an interior wall of the housing, the baffle or baffles being spaced to define a mixing channel through the space between the exterior of the permeable body and the interior wall of the housing so that the first fluid can enter the housing inlet and flow through the mixing channel to the outlet, while picking up the second fluid permeating through the permeable body to the exterior of the permeable body; wherein: said first and second fluid inlet conduits are connected respectively, via valving, to said first fluid inlets of said first and second mixing vessels, and said first and second outlet conduits are connected respectively, via valving, to said first and second mixing vessels outlets, so that one mixing vessel may remain in service, while the other mixing vessel may be taken off line for maintenance or cleaning.

2. The apparatus of claim 1, wherein the mixing channel is substantially in the shape of a helix.

3. The apparatus according to claim 1, in which the baffle is formed of a series of elongated segments formed end-to-end.

4. The apparatus according to claim 1, wherein the permeable body has pores in the range selected from the group consisting of 0.2 to 400 microns, 20 to 200 microns, and 60 to 100 microns.

5. (canceled)

6. An apparatus for separating and recovery of metal from a metal-containing source by a solvent extraction/electrowinning process, comprising a mixing device for mixing a metal-containing aqueous solution and an immiscible organic extractant, wherein the mixing device comprises the apparatus as claimed in claim 1, said apparatus further comprising a centrifugal separator selectively connected to the first or second mixing device via the first and second outlet conduits.

7. (canceled)

8. The apparatus according to claim 6, wherein the centrifugal separator separates the mixture into two streams, a heavy phase and a light phase, the heavy phase comprising primarily an aqueous phase containing metal; said apparatus further comprising a conduit carrying the heavy phase to an electrowinning stage.

9. The apparatus according to claim 8, further comprising a conduit selectively carrying the light phase to the first or second mixing device.

10. The apparatus according to claim 6, wherein the metal comprises copper.

11. A method for separating a mixture of a first and a second fluid of different densities, which fluids are substantially insoluble in one another, said method comprising providing an apparatus as claimed in claim 1, flowing the first fluid from an interior of the permeable body to an exterior of the permeable body, and contacting the fluid on the exterior of the permeable body with the second fluid.

12. The method according to claim 11, wherein the permeable body has pores in the range of 0.2 to 400 microns, preferably 20 to 200 microns, more preferably 60 to 100 microns.

13. The method according to claim 11, including the step of flowing the first fluid through the media or fit.

14. A method for separating and recovery of metal from a metal-containing source by a solvent extraction/electrowinning process, comprising providing a metal-containing aqueous solution and an immiscible organic extractant to a mixing device, wherein the mixing device comprises an apparatus as claimed in claim 1, whereupon the organic extractant is dispersed in the copper-containing aqueous solution and extracts metal from the aqueous solution, passing the resulting dispersion through a mixing conduit to a centrifugal separator, and separating the organic extractant containing copper from the aqueous solution.

15. The method according to claim 14, including the steps of controlling a travel time between the mixing device and the centrifuge to between 5-120 seconds, preferably 20-60 seconds, more preferably 35-45 seconds.

16. The method according to claim 14, wherein the centrifugal separator separates the mixture into two streams, a heavy phase and a light phase, the heavy phase comprising primarily an aqueous phase containing metal, and including the step of passing the heavy phase to an electrowinning stage.

17. The method as claimed in claim 14, including the step of returning the light phase at least in part, to the mixing device.

18. The method as claimed in claim 14, wherein the metal comprises copper.

19. A centrifugal separator, comprising a rotatable tank in the shape of a vertical right cylinder in a housing, at least one inlet adjacent a lower end of the housing and at least two outlets adjacent an upper end of the housing, and wherein an upper end of the rotatable tank is provided with a plurality of vertical baffles which create a plurality of chambers in the upper end of the rotatable tank.

20. The centrifugal separator as claimed in claim 19, further including one or more additional inlets between the inlet adjacent the lower end of the housing and the outlets.

21. The apparatus of claim 1, wherein the first fluid inlet of the first mixing vessel or the second mixing vessel, as the case may be, is laterally disposed adjacent the second fluid inlet of said permeable body.

22. The apparatus of claim 1, wherein the baffle has the form of a continuous elongated helical strip.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0039] Further features and advantages of the present invention will be seen from the following detailed description, taken in conjunction with the accompanying drawings, wherein like numerals depict like parts, and wherein:

[0040] FIG. 1 is flow diagram of a system for the hydrometallurgical production of a metal such as copper in accordance with one aspect the present invention;

[0041] FIG. 1A is a side elevational view, in cross section, showing details of an apparatus for dispersing an organic fluid such as kerosene into an aqueous-based solution in accordance with another aspect of the present invention;

[0042] FIG. 2 is a side elevational view, in cross section, of a centrifugal contactor-separator employed in accordance with the present invention;

[0043] FIG. 2A is a cross-sectional view of the rotating cylinder portion of the centrifugal contractor-separator of FIG. 2; and

[0044] FIG. 3 is a flow diagram, similar to FIG. 1 of an alternative system for the hydrometallurgical production of a metal such as copper in accordance with the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0045] The invention will now be described in connection with the production of copper from a copper-containing ore. Referring first to FIGS. 1 and 1A, a copper containing pregnant leach solution (PLS) 10 from a copper oxide ore heap 12, is fed to a first mixing vessel 14A where the pregnant leach solution is mixed with an organic liquid extractant such as a hydroxyl oxime ion exchanger in kerosene supplied from tank 16. Referring in particular to FIG. 1A, mixing vessel 14A comprises an elongate cylindrical housing 18 having an inlet 20 at one end, and an outlet 22 at the other end. A permeable body 24 in the shape of a cylindrical tube is coaxially disposed within the cylindrical housing 18. However, housing 18 and permeable body 24 need not be cylindrical—they may be square, or rectangular or have other geometric shapes in cross-section. The permeable body 24 is connected to the housing inlet 20 at one end 26, and a disc 28 closes the end of permeable body 24 adjacent the housing outlet 22.

[0046] The outer wall of permeable body 24 is spaced from the interior wall of housing 18. A helical baffle 30 is located within the annular space between the outer wall of permeable body 24 and the inner wall of housing 18. Baffle 30 may be a continuous elongated helical strip or formed as a series of segments. Mixing vessel 14A also has a lateral inlet 32 adjacent the inlet 20 end.

[0047] Permeable body 24 can be made of permeable or porous metal, and is filled with loosely packed finely divided media or frits such as powdered metal particles or ceramic particles. Various permeable and porous metals are available commercially from a variety of vendors including Mott Metallurgical Corporation of Farmington, Conn. The permeable or porous metal used in this invention preferably has substantially uniform pore sizes, or at least most of the pores are within an acceptable range for the intended purpose, and typically are in the range of 0.2 to 400 microns, preferably 20 to 200 microns, more particularly 60 to 100 microns. The porous media or fits should be inert to the liquids being handled. For example, the media or frits can be made of particles of ceramic, or stainless steel, Nickel 200, Monel® 400, Inconel® 600, Hastelloy® C276, Alloy 20, gold, platinum, silver, and titanium. As will be described below, the media or frits, by their nature, cause the droplets of the organic solvent to finally divide, dispersing fine droplets on the outer surface of the permeable body 24, where they are picked up by the PLS.

[0048] In use, the organic liquid extractant in kerosene is introduced through inlet 20 into the interior of permeable body 24. PLS is introduced into the interior of mixing vessel 14A through lateral inlet 32, into the space between the outer wall of permeable body 24 and the inner wall of mixing vessel 14A. The organic liquid extractant is forced through the permeable body 24 and emerges from the permeable body in the form of a fine organic liquid extractant droplets where the droplets are picked up by the flowing PLS, forming a dispersion of kerosene droplets in the PLS. The PLS preferably is flowed under turbulent conditions so that the droplets of the organic liquid extractant are quickly dispersed before having an opportunity to coalesce. The organic liquid extractant, which is substantially immiscible with the aqueous based PLS solution, extracts copper from the pregnant leach solution, and emerges from the mixing vessel 14A via outlet 22.

[0049] Alternatively, the PLS may be introduced into the interior of permeable body 24, and the organic liquid extractant introduced into the interior of the mixing vessel 14A through lateral inlet 32, into the space between the outer wall of permeable body 24 and the inner wall of mixing vessel 14A. In such case, the PLS is forced through the permeable body 24, and emerges from the permeable body in the form of fine droplets which are picked up by the flowing organic liquid extractant, forming a dispersion of aqueous droplets in the kerosene.

[0050] The solution emerging from outlet 22 is passed via conduit 34A to an extract stage centrifugal separator 100A as will be described in detail below. Conduit 34A includes inline baffles shown in phantom as 98A for maintaining the fluid in a mixed condition. Conduit 34A is sized and shaped relative to the flow of fluid from mixing vessel 14A to provide a travel or residence time sufficient to permit substantial mass transfer of copper in the aqueous solution to the organic liquid extractant. Ordinarily, a residence time of 5-120 seconds, preferably 20-60 seconds, more preferably 35-45 seconds, is sufficient before the fluid is introduced into a centrifugal separator 100A. Alternatively, one or more loops may be included in the conduit 34A, or the cross sectional size of the conduit 34A increased so that the flow from mixing vessel 14A is controlled to within the target residence time of 5-120 seconds.

[0051] As will be described below, centrifuge separator 100A creates two exit streams-a light phase (organic) and a heavy phase (aqueous raffinate). The aqueous raffinate is recycled to the leach heap to dissolve more copper. The organic phase exiting the centrifuge 100A is transferred to another mixing vessel 14B, similar to mixing vessel 14A, where it is mixed with lean electrolyte from the electrowinning stage 60 as will be discussed below. As before, the organic liquid extractant is forced through the permeable body 24 contained in mixing vessel 14B, and emerges from the permeable body in the form of a fine organic liquid extractant droplets where the droplets are picked up by the flowing electrolyte, forming a dispersion of kerosene droplets in the electrolyte. As before, the electrolyte preferably is flowed under turbulent conditions so that the droplets of the organic liquid extractant are quickly dispersed before having an opportunity to coalesce. The electrolyte or stripping solution, which is substantially immiscible with the organic liquid extractant removes (strips) copper from the organic liquid extractant and emerges from the mixing vessel 14B, where it is passed via conduit 34B which also contains inline baffles shown in phantom as 98B, similar to conduit 34A, for maintaining the fluid in a mixed condition. As before, conduit 34B is sized and shaped relative to the flow of the fluid from mixing vessel 14A to provide a travel or residence time sufficient to permit substantial mass transfer of copper in the aqueous solution to the organic liquid extractant. The fluid then passed to a second strip stage centrifuge 100B which is similar in construction to centrifuge 100A as will be described in detail below, and in which a light organic phase is partially stripped of copper and returned to tank 16, and a rich copper electrolyte phase is passed to an electrowinning cell 60.

[0052] Referring in particular to FIG. 2, there is shown centrifugal separator 100A. However, centrifugal separator 100B is essentially the same. Centrifugal separator 100A, which is similar to the centrifugal separator described in our prior U.S. Pat. No. 6,440,054, comprises a rotatable cylinder 102 in the shape of a vertical right cylinder contained in a housing 104 having vertical side wall 106 bottom wall 108 and top wall 109. A vertical drive shaft 112 is suspended at the upper end of housing 104 by an upper thrust bearing. Centrifugal separator 100A has an inlet 116 for input of an organic/aqueous mixed phase, i.e., from conduit 34A. The solution enters the central opening (orifice) 140 of the rotating cylinder 102. The dispersion entering central orifice 140, gets deflected towards the outside wall of the cylinder by a horizontal deflecting baffle 142 provided close to the entrance. Referring also to FIG. 2A, unlike the centrifugal separator described in our aforesaid U.S. Pat. No. 6,440,054, the mixing box at the bottom of the centrifugal separator is eliminated, and the upper end of rotating cylinder 102 provided with a plurality of vertical baffles 146 which create several chambers ranging from 4 to 8. In a preferred embodiment, we create four (4) chambers. The rotating cylinder 102 imparts to the liquid a practically rigid body rotation. The inner surface of the rotating liquid has almost a vertical shape because of high ‘g’ except a small parabolic portion adjacent the bottom. The dispersion entering at the bottom region 148 gets separated as it moves upwards. The rate of separation depends upon the droplet size distribution, their settling velocities under the centrifugal action (rΩ2), where r is the radius of the bowl/chamber and Ω is the rotation speed), densities, viscosities and coalescing behavior of the two phases. For complete separation, adequate height needs to be provided for a given level of (rΩ2). Inside the bowl/chamber the solution is separated into two phases—a light phase which is discharged through the ports 144 and exits the unit through the top port 110, and a heavy phase which is discharged through outlet ports 156 and leaves the unit through outlet 158. The heavy phase outlet ports 156 have variable positions which are selected and changed according to the relative flow rates of the heavy and light phases and the relative volumes of each phase within the centrifugal separator 100A.

[0053] FIG. 3 shows an alternative embodiment of the invention. The FIG. 3 embodiment includes two mixing vessels 14A1 and 14A2, and 14B1 and 14B2 for both the extract stage as well as the strip stage connected through valving and conduits 10A, 10B, 34A, 34B, so that one mixing vessel may remain in service, while the other mixing vessel is taken off line for maintenance or cleaning.

[0054] The present invention provides various advantages over prior art processes. For one, the system is closed. Thus, loss of organic solvent, i.e. due to evaporation is avoided. Also, by passing the organic phase through finely divided media or frits, and a permeable body before the organic phase is mixed with the PLS, a micro dispersion of the organic phase is formed in the PLS. Thus, less organic solvent is needed in the overall process. Also, higher throughput may be achieved with smaller equipment overall, thus adding to equipment savings, as well as operational savings.

[0055] Also, from studies and tests we found that entrainment of the organic phase in the aqueous is generated in the mixing step and not influenced by the separator. The quantity of entrainment is substantially effected by air ingestion. Using the hollow permeable body mixing apparatus as above described greatly reduces the possibility of air entrainment in the liquid and thus improves separation in the downstream separator (any separator for that matter).

[0056] Also, if air is excluded from the dispersion in the mixer, then organic-in-aqueous entrainment is minimized and aqueous-in-organic entrainment essentially reduced essentially to undetectable levels. Thus, our mixing apparatus as above described allows for a reduction, if not essentially elimination of air entrainment in the liquid thus reducing entrainment of one phase in the other phase. Conventional prior art mixing devices cannot achieve this since by design conventional mixing systems are exposed to the atmosphere and draw air into the liquid.

[0057] Various changes may be made in the above invention without the departing from the spirit and scope thereof. While the recovery of copper by electrowinning (post solvent extraction) has been described in the above working example, recovery of other metals, or other post-solvent extraction steps are possible. By way of example, Uranium may be recovered as ‘yellow cake’ (approximately 80% U3O8) by precipitation and calcining of ammonium uranyl sulfate. Also, some recovery systems employ crystallization to create a nickel sulfate or copper sulfate crystal. And, while electrowinning creates 99.99+ pure copper at the cathode, other metals, for example, zinc, are also electrowon. And some operations also use spray drying technology to create a metal salt dust. Still other changes including recovery of other metals including, but not limited to zinc, nickel, cobalt and uranium, using appropriate extractants, e.g. as above described, are possible.