Organic electroluminescent materials and devices

Abstract

A compound that has the structure according to Formula 1: ##STR00001##
as well as, devices and formulations containing the compound of Formula 1 are disclosed. In the compound of Formula 1: X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, and X.sup.6 are independently selected from the group consisting of C—R and N; each R is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and at least one R comprises a donor group with at least two electron donating nitrogens.

Claims

1. A compound having a structure according to Formula 2: ##STR00200## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 represent no substitutions up to the maximum available substitutions; wherein each R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 substitution is independently selected from the group consisting of; deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfonyl, sulfonyl, phosphino, and combinations thereof; and wherein Ar.sup.1 and Ar.sup.2 are substituted or unsubstituted aromatic or heteroaromatic groups which may join with ring C to form fused rings.

2. The compound of claim 1, wherein the nitrogen bonded to Ar.sup.1 and Ar.sup.2 is a tertiary amine.

3. The compound of claim 1, wherein the nitrogen of the carbazole is connected meta to the nitrogen of Ring A.

4. The compound of claim 1, wherein the nitrogen of the carbazole is connected ortho to the nitrogen of Ring A.

5. The compound of claim 1, wherein at least one R.sup.4 or R.sup.5 substituent comprises a donor group with at least two electron donating nitrogens, and the donor group comprises a tertiary amine.

6. The compound of claim 1, selected from the group consisting of: ##STR00201## ##STR00202## ##STR00203## ##STR00204## ##STR00205## ##STR00206##

7. A first device comprising a first organic light emitting device, the first organic light emitting device comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a host and an emissive dopant having a structure according to Formula 1: ##STR00207## wherein X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, and X.sup.6 are independently selected from the group consisting of C—R and N; wherein each R is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein at least one R comprises a donor group with at least two electron donating nitrogens.

8. The first device of claim 7, wherein the first device emits a luminescent radiation at room temperature when a voltage is applied across the organic light emitting device, and wherein the luminescent radiation comprises a delayed fluorescence process.

9. The first device of claim 7, wherein the emissive layer further comprises a first phosphorescent emitting material.

10. The first device of claim 9, wherein the emissive layer further comprises a second phosphorescent emitting material.

11. The first device of claim 9, wherein the first device emits a white light at room temperature when a voltage is applied across the organic light emitting device.

12. The first device of claim 11, wherein the compound of Formula 1 emits a blue light with a peak wavelength of about 400 nm to about 500 nm.

13. The first device of claim 11, wherein the compound of Formula 1 emits a yellow light with a peak wavelength of about 530 nm to about 580 nm.

14. A first device comprising a first organic light emitting device, the first organic light emitting device comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having a structure according to Formula 2: ##STR00208## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 represent no substitutions up to the maximum available substitutions; wherein each R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 substitution is independently selected from the group consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein Ar.sup.1 and Ar.sup.2 are substituted or unsubstituted aromatic or heteroaromatic groups which may join with ring C to form fused rings.

15. The first device of claim 14, wherein the nitrogen of the carbazole is connected meta to the nitrogen of Ring A.

16. The first device of claim 14, wherein the nitrogen of the carbazole is connected ortho to the nitrogen of Ring A.

17. The first device of claim 7, wherein the device is one or more of a consumer product, an organic light-emitting device, and a lighting panel.

18. The first device of claim 14, wherein the device is one or more of a consumer product, an organic light-emitting device, and a lighting panel.

19. The first device of claim 14, wherein the emissive layer further comprises a first phosphorescent emitting material.

20. The first device of claim 14, wherein the compound of Formula 2 is a host material.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows an organic light emitting device.

(2) FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.

(3) FIG. 3 shows Formula 1 as disclosed herein.

DETAILED DESCRIPTION

(4) Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.

(5) The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.

(6) More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), which are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.

(7) FIG. 1 shows an organic light emitting device 100. The figures are not necessarily drawn to scale. Device 100 may include a substrate 110, an anode 115, a hole injection layer 120, a hole transport layer 125, an electron blocking layer 130, an emissive layer 135, a hole blocking layer 140, an electron transport layer 145, an electron injection layer 150, a protective layer 155, a cathode 160, and a barrier layer 170. Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164. Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.

(8) More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F.sub.4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.

(9) FIG. 2 shows an inverted OLED 200. The device includes a substrate 210, a cathode 215, an emissive layer 220, a hole transport layer 225, and an anode 230. Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230, device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200. FIG. 2 provides one example of how some layers may be omitted from the structure of device 100.

(10) The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device 200, hole transport layer 225 transports holes and injects holes into emissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2.

(11) Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2. For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.

(12) Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.

(13) Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.

(14) Devices fabricated in accordance with embodiments of the invention may be incorporated into a wide variety of consumer products, including flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads up displays, fully transparent displays, flexible displays, laser printers, telephones, cell phones, personal digital assistants (PDAs), laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, vehicles, a large area wall, theater or stadium screen, or a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.), but could be used outside this temperature range, for example, from −40 degree C. to +80 degree C.

(15) The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.

(16) The term “halo” or “halogen” as used herein includes fluorine, chlorine, bromine, and iodine.

(17) The term “alkyl” as used herein contemplates both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, and the like. Additionally, the alkyl group may be optionally substituted.

(18) The term “cycloalkyl” as used herein contemplates cyclic alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 7 carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, and the like. Additionally, the cycloalkyl group may be optionally substituted.

(19) The term “alkenyl” as used herein contemplates both straight and branched chain alkene radicals. Preferred alkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl group may be optionally substituted.

(20) The term “alkynyl” as used herein contemplates both straight and branched chain alkyne radicals. Preferred alkyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted.

(21) The terms “aralkyl” or “arylalkyl” as used herein are used interchangeably and contemplate an alkyl group that has as a substituent an aromatic group. Additionally, the aralkyl group may be optionally substituted.

(22) The term “heterocyclic group” as used herein contemplates aromatic and non-aromatic cyclic radicals. Hetero-aromatic cyclic radicals also means heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 or 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperdino, pyrrolidino, and the like, and cyclic ethers, such as tetrahydrofuran, tetrahydropyran, and the like. Additionally, the heterocyclic group may be optionally substituted.

(23) The term “aryl” or “aromatic group” as used herein contemplates single-ring groups and polycyclic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is aromatic, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Additionally, the aryl group may be optionally substituted.

(24) The term “heteroaryl” as used herein contemplates single-ring hetero-aromatic groups that may include from one to three heteroatoms, for example, pyrrole, furan, thiophene, imidazole, oxazole, thiazole, triazole, pyrazole, pyridine, pyrazine and pyrimidine, and the like. The term heteroaryl also includes polycyclic hetero-aromatic systems having two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Additionally, the heteroaryl group may be optionally substituted.

(25) The alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl may be optionally substituted with one or more substituents selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, cyclic amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

(26) As used herein, “substituted” indicates that a substituent other than H is bonded to the relevant position, such as carbon. Thus, for example, where R.sup.1 is mono-substituted, then one R.sup.1 must be other than H. Similarly, where R.sup.1 is di-substituted, then two of R.sup.1 must be other than H. Similarly, where R.sup.1 is unsubstituted, R.sup.1 is hydrogen for all available positions.

(27) The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzonethiophene, etc. means that one or more of the C—H groups in the respective fragment can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.

(28) It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.

(29) It is believed that the internal quantum efficiency (IQE) of fluorescent OLEDs can exceed the 25% spin statistics limit through delayed fluorescence. As used herein, there are two types of delayed fluorescence, i.e. P-type delayed fluorescence and E-type delayed fluorescence. P-type delayed fluorescence is generated from triplet-triplet annihilation (TTA).

(30) On the other hand, E-type delayed fluorescence does not rely on the collision of two triplets, but rather on the thermal population between the triplet states and the singlet excited states. Compounds that are capable of generating E-type delayed fluorescence are required to have very small singlet-triplet gaps. Thermal energy can activate the transition from the triplet state back to the singlet state. This type of delayed fluorescence is also known as thermally activated delayed fluorescence (TADF). A distinctive feature of TADF is that the delayed component increases as temperature rises due to the increased thermal energy. If the reverse intersystem crossing rate is fast enough to minimize the non-radiative decay from the triplet state, the fraction of back populated singlet excited states can potentially reach 75%. The total singlet fraction can be 100%, far exceeding the spin statistics limit for electrically generated excitons.

(31) E-type delayed fluorescence characteristics can be found in an exciplex system or in a single compound. Without being bound by theory, it is believed that E-type delayed fluorescence requires the luminescent material to have a small singlet-triplet energy gap (ΔE.sub.S-T). Organic, non-metal containing, donor-acceptor luminescent materials may be able to achieve this. The emission in these materials is often characterized as a donor-acceptor charge-transfer (CT) type emission. The spatial separation of the HOMO and LUMO in these donor-acceptor type compounds often results in small ΔE.sub.S-T. These states may involve CT states. Often, donor-acceptor luminescent materials are constructed by connecting an electron donor moiety such as amino- or carbazole-derivatives and an electron acceptor moiety such as N-containing six-membered aromatic rings.

(32) This disclosure is based on the development that donor-acceptor compounds with naphthyridine as the acceptor may be efficient emitters with emissions originated from the charge transfer (CT) state. These compounds may be used as emitters, e.g., delayed fluorescence emitters, in OLEDs. Commonly used electron acceptors used are triazene or cyano groups. While these groups are strongly electron deficient, OLEDs incorporating them may not be very stable. The naphthyridine compounds described herein are believed to produce more stable OLED devices because the donor-acceptor compounds include acceptors that allow electron delocalization.

(33) According to one embodiment, a compound having a structure according to Formula 1:

(34) ##STR00004##
is disclosed.
In the compound of Formula 1:

(35) X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, and X.sup.6 are independently selected from the group consisting of C—R and N;

(36) each R is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and

(37) at least one R comprises a donor group with at least two electron donating nitrogens.

(38) In some embodiments, the compound of Formula 1 is non-metallic. In some embodiments, the only heteroatoms present in the compound of Formula 1 are N, S, B, O, Se, Si, P and Ge.

(39) In some embodiments, the “combinations thereof” option for R indicates that R can be further substituted by a moiety selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. In other embodiments, R is not further substituted.

(40) In some embodiments adjacent R groups can be joined to form a fused ring. In other embodiment, adjacent R groups are not fused.

(41) In some embodiments, at least one of X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, and X.sup.6 is N.

(42) In some embodiments, at least two nitrogens of the donor group are separated by at least three carbon atoms.

(43) In some embodiments, one of the at least two electron donating nitrogens of the donor group is directly connected to Ring A or Ring B. In some embodiments, the donor group comprises a carbazole and the nitrogen of the carbazole is directly connected to Ring A or Ring B. In some such embodiments, another nitrogen of the donor group is a tertiary amine, which may be separated by at least three carbon atoms in some embodiments.

(44) In some embodiments, one of the at least two electron donating nitrogens of the donor group is connected ortho or meta to a nitrogen of Ring A or Ring B. In some embodiments, X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5 and X.sup.6 are C—R, and one of the at least two electron donating nitrogens of a donor group is connected ortho or meta to the nitrogen of Ring A or the nitrogen of Ring B.

(45) In some embodiments, the donor group comprises a tertiary amine. In some embodiments, an aryl or heteroaryl group can be bonded directly to the tertiary amine.

(46) In some embodiments, the compound can have a structure according to Formula 2:

(47) ##STR00005##
In the compounds of Formula 2:

(48) Ar.sup.1 and Ar.sup.2 can be substituted or unsubstituted aromatic or heteroaromatic groups which may join with ring C to form fused rings, and

(49) R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 can represent no substitution; mono, di, tri or tetra substitution of deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

(50) In some more specific embodiments, the compound can be selected from the group consisting of:

(51) ##STR00006## ##STR00007## ##STR00008## ##STR00009## ##STR00010## ##STR00011##

(52) According to another embodiment, a compound having a structure according to Formula 3:

(53) ##STR00012##
is disclosed.
In the compound of Formula 3:

(54) X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, and X.sup.8 are independently selected from the group consisting of C—R and N;

(55) at least two of X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, and X.sup.8 are N;

(56) each R is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and

(57) at least one R comprises a donor group with at least two electron donating nitrogens.

(58) In some embodiments, at least two of X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, and X.sup.8 are N. In some embodiments, at least three of X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, and X.sup.8 are N. In some embodiments, at least one of X.sup.1, X.sup.2, X.sup.3, and X.sup.4 is N, and at least one of X.sup.5, X.sup.6, X.sup.7, and X.sup.8 is N. Any of the of the options for R described with respect to Formula 1 are equally applicable to the broader scope of Formula 2.

(59) According to another aspect of the present disclosure, a first device is also provided. The first device includes a first organic light emitting device, that includes an anode, a cathode, and an organic layer disposed between the anode and the cathode. The organic layer can include a host and a phosphorescent dopant. The organic layer can include a compound comprising a compound according to Formula 1 or 3 and any variations of the compound as described herein.

(60) In some embodiments, the first device can be one or more of a consumer product, an organic light-emitting device, and a lighting panel.

(61) The first device can emit a luminescent radiation at room temperature when a voltage is applied across the organic light emitting device. The luminescent radiation can include a delayed fluorescence process.

(62) In some embodiments, the first device emits a white light at room temperature when a voltage is applied across the organic light emitting device. In some embodiments, the compound of Formula 1 emits a blue light with a peak wavelength of about 400 nm to about 500 nm, while the compound of Formula 1 emits a yellow light with a peak wavelength of about 530 nm to about 580 nm in other embodiments.

(63) In some embodiments, the emissive layer further comprises a host material. In some embodiments, the emissive layer further comprises a first phosphorescent emitting material. In some embodiments, the emissive layer further comprises a second phosphorescent emitting material.

(64) In some embodiments, the first device comprises a second organic light emitting device, wherein the second organic light emitting device is stacked on the first organic light emitting device. The second organic light emitting device can be disposed between the anode and the cathode.

(65) In yet another aspect of the present disclosure, a formulation that comprises a compound having a structure according to Formula 1 or Formula 3 and any variations of the compound as described herein. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, and an electron transport layer material, disclosed herein.

(66) Combination with Other Materials

(67) The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.

(68) HIL/HTL:

(69) A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but not limit to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoO.sub.x; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.

(70) Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:

(71) ##STR00013##

(72) Each of Ar.sup.1 to Ar.sup.9 is selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each Ar is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

(73) In one aspect, Ar.sup.1 to Ar.sup.9 is independently selected from the group consisting of:

(74) ##STR00014##
wherein k is an integer from 1 to 20; X.sup.101 to X.sup.108 is C (including CH) or N; Z.sup.101 is NAr.sup.1, O, or S; Ar.sup.1 has the same group defined above.

(75) Examples of metal complexes used in HIL or HTL include, but not limit to the following general formula:

(76) ##STR00015##
wherein Met is a metal, which can have an atomic weight greater than 40; (Y.sup.101—Y.sup.102) is a bidentate ligand, Y.sup.101 and Y.sup.102 are independently selected from C, N, O, P, and S; L.sup.101 is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

(77) In one aspect, (Y.sup.101—Y.sup.102) is a 2-phenylpyridine derivative. In another aspect, (Y.sup.101—Y.sup.102) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc.sup.+/Fc couple less than about 0.6 V.

(78) Host:

(79) The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. While the Table below categorizes host materials as preferred for devices that emit various colors, any host material may be used with any dopant so long as the triplet criteria is satisfied.

(80) Examples of metal complexes used as host are preferred to have the following general formula:

(81) ##STR00016##
wherein Met is a metal; (Y.sup.103—Y.sup.104) is a bidentate ligand, Y.sup.103 and Y.sup.104 are independently selected from C, N, O, P, and S; L.sup.101 is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

(82) In one aspect, the metal complexes are:

(83) ##STR00017##
wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.

(84) In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y.sup.103—Y.sup.104) is a carbene ligand.

(85) Examples of organic compounds used as host are selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each group is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

(86) In one aspect, host compound contains at least one of the following groups in the molecule:

(87) ##STR00018## ##STR00019##
wherein R.sup.101 to R.sup.107 is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20; k′″ is an integer from 0 to 20. X.sup.101 to X.sup.108 is selected from C (including CH) or N. Z.sup.101 and Z.sup.102 is selected from NR.sup.101, O, or S.
HBL:

(88) A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED.

(89) In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.

(90) In another aspect, compound used in HBL contains at least one of the following groups in the molecule:

(91) ##STR00020##
wherein k is an integer from 1 to 20; L.sup.101 is an another ligand, k′ is an integer from 1 to 3.
ETL:

(92) Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.

(93) In one aspect, compound used in ETL contains at least one of the following groups in the molecule:

(94) ##STR00021##
wherein R.sup.101 is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar.sup.1 to Ar.sup.3 has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X.sup.101 to X.sup.108 is selected from C (including CH) or N.

(95) In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:

(96) ##STR00022##
wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L.sup.101 is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.

(97) In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. encompasses undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also encompass undeuterated, partially deuterated, and fully deuterated versions thereof.

(98) In addition to and/or in combination with the materials disclosed herein, many hole injection materials, hole transporting materials, host materials, dopant materials, exiton/hole blocking layer materials, electron transporting and electron injecting materials may be used in an OLED. Non-limiting examples of the materials that may be used in an OLED in combination with materials disclosed herein are listed in Table 1 below. Table 1 lists non-limiting classes of materials, non-limiting examples of compounds for each class, and references that disclose the materials.

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No. 5,061,569 EP650955 J. Mater. Chem. 3, 319 (1993) 0 Appl. Phys. Lett. 90, 183503 (2007) Appl. Phys. Lett. 90, 183503 (2007) Triaylamine on spirofluorene core Synth. Met. 91, 209 (1997) Arylamine carbazole compounds Adv. Mater. 6, 677 (1994), US20080124572 Triarylamine with (di)benzothiophene/ (di)benzofuran US20070278938, US20080106190 US20110163302 Indolocarbazoles Synth. Met. 111, 421 (2000) Isoindole compounds Chem. Mater. 15, 3148 (2003) Metal carbene complexes US20080018221 Phosphorescent OLED host materials Red hosts Arylcarbazoles Appl. Phys. Lett. 78, 1622 (2001) Metal 8-hydroxy- quinolates (e.g., Alq.sub.3, BAlq) Nature 395, 151 (1998) 0 US20060202194 WO2005014551 WO2006072002 Metal phenoxy- benzothiazole compounds Appl. Phys. Lett. 90, 123509 (2007) Conjugated oligomers and polymers (e.g., polyfluorene) Org. Electron. 1, 15 (2000) Aromatic fused rings WO2009066779, WO2009066778, WO2009063833, US20090045731, US20090045730, WO2009008311, US20090008605, US20090009065 Zinc complexes WO2010056066 Chrysene based compounds WO2011086863 Green hosts Arylcarbazoles Appl. Phys. Lett. 78, 1622 (2001) US20030175553 0 WO2001039234 Aryltriphenylene compounds US20060280965 US20060280965 WO2009021126 Poly-fused heteroaryl compounds US20090309488 US20090302743 US20100012931 Donor acceptor type molecules WO2008056746 WO2010107244 Aza-carbazole/ DBT/DBF JP2008074939 US20100187984 Polymers (e.g., PVK) Appl. Phys. Lett. 77, 2280 (2000) Spirofluorene compounds 0 WO2004093207 Metal phenoxy- benzooxazole compounds WO2005089025 WO2006132173 JP200511610 Spirofluorene- carbazole compounds JP2007254297 JP2007254297 Indolocarbazoles WO2007063796 WO2007063754 5-member ring electron deficient heterocycles (e.g., triazole, oxadiazole) J. Appl. Phys. 90, 5048 (2001) WO2004107822 Tetraphenylene complexes 0 US20050112407 Metal phenoxy- pyridine compounds WO2005030900 Metal coordination complexes (e.g., Zn, Al with N{circumflex over ( )}N ligands) US20040137268, US20040137267 Blue hosts Arylcarbazoles Appl. Phys. Lett, 82, 2422 (2003) US20070190359 Dibenzothiophene/ Dibenzofuran- carbazole compounds WO2006114966, US20090167162 US20090167162 WO2009086028 US20090030202, US20090017330 US20100084966 Silicon aryl compounds 0 US20050238919 WO2009003898 Silicon/Germanium aryl compounds EP2034538A Aryl benzoyl ester WO2006100298 Carbazole linked by non-conjugated groups US20040115476 Aza-carbazoles US20060121308 High triplet metal organometallic complex U.S. Pat. No. 7,154,114 Phosphorescent dopants Red dopants Heavy metal porphyrins (e.g., PtOEP) Nature 395, 151 (1998) Iridium(III) organometallic complexes Appl. Phys. Lett. 78, 1622 (2001) US20030072964 00 US20030072964 01 US20060202194 02 US20060202194 03 US20070087321 04 US20080261076 US20100090591 05 US20070087321 06 Adv. Mater. 19, 739 (2007) 07 WO2009100991 08 WO2008101842 09 U.S. Pat. No. 7,232,618 Platinum(II) organometallic complexes 0 WO2003040257 US20070103060 Osminum(III) complexes Chem. Mater. 17, 3532 (2005) Ruthenium(II) complexes Adv. Mater. 17, 1059 (2005) Rhenium (I), (II), and (III) complexes US20050244673 Green dopants Iridium(III) organometallic complexes Inorg. Chem. 40, 1704 (2001) US20020034656 U.S. Pat. No. 7,332,232 US20090108737 WO2010028151 0 EP1841834B US20060127696 US20090039776 U.S. Pat. No. 6,921,915 US20100244004 U.S. Pat. No. 6,687,266 Chem. Mater. 16, 2480 (2004) US20070190359 US 20060008670 JP2007123392 WO2010086089, WO2011044988 0 Adv. Mater. 16, 2003 (2004) Angew. Chem. Int. Ed. 2006, 45, 7800 WO2009050290 US20090165846 US20080015355 US20010015432 US20100295032 Monomer for polymeric metal organometallic compounds U.S. Pat. No. 7,250,226, U.S. Pat. No. 7,396,598 Pt(II) organometallic complexes, including polydentated ligands Appl. Phys. Lett. 86, 153505 (2005) Appl. Phys. Lett. 86, 153505 (2005) 0 Chem. Lett. 34, 592 (2005) WO2002015645 US20060263635 US20060182992 US20070103060 Cu complexes WO2009000673 US20070111026 Gold complexes Chem. Commun. 2906 (2005) Rhenium(III) complexes Inorg. Chem. 42, 1248 (2003) Osmium(II) complexes U.S. Pat. No. 7,279,704 Deuterated organometallic complexes US20030138657 Organometallic complexes with two or more metal centers 0 US20030152802 U.S. Pat. No. 7,090,928 Blue dopants Iridium(III) organometallic complexes WO2002002714 WO2006009024 US20060251923 US20110057559 US20110204333 U.S. Pat. No. 7,393,599, WO2006056418, US20050260441, WO2005019373 U.S. Pat. No. 7,534,505 WO2011051404 U.S. Pat. No. 7,445,855 US20070190359, US20080297033 US20100148663 0 U.S. Pat. No. 7,338,722 US20020134984 Angew. Chem. Int. Ed. 47, 4542 (2008) Chem. Mater. 18, 5119 (2006) Inorg. Chem. 46, 4308 (2007) WO2005123873 WO2005123873 WO2007004380 WO2006082742 Osmium(II) complexes U.S. Pat. No. 7,279,704 0 Organometallics 23, 3745 (2004) Gold complexes Appl. Phys. Lett. 74, 1361 (1999) Platinum(II) complexes WO2006098120, WO2006103874 Pt tetradentate complexes with at least one metal- carbene bond U.S. Pat. No. 7,655,323 Exciton/hole blocking layer materials Bathocuprine compounds (e.g., BCP, BPhen) Appl. Phys. Lett. 75, 4 (1999) Appl. Phys. Lett. 79, 449 (2001) Metal 8-hydroxy- quinolates (e.g., BAlq) Appl. Phys. Lett. 81, 162 (2002) 5-member ring electron deficient heterocycles such as triazole, oxadiazole, imidazole, benzoimidazol Appl. Phys. Lett. 81, 162 (2002) Triphenylene compounds US20050025993 Fluorinated aromatic compounds Appl. Phys. Lett. 79, 156 (2001) Phenothiazine- S-oxide 0 WO2008132085 Silylated five- membered nitrogen, oxygen, sulfur or phosphorus dibenzoheterocycles WO2010079051 Aza-carbazoles US20060121308 Electron transporting materials Anthracene- benzoimidazole compounds WO2003060956 US20090179554 Aza triphenylene derivatives US20090115316 Anthracene- benzothiazole compounds Appl. Phys. Lett. 89, 063504 (2006) Metal 8-hydroxy- quinolates (e.g., Alq.sub.3, Zrq.sub.4) Appl. Phys. Lett. 51, 913 (1987) U.S. Pat. No. 7,230,107 Metal hydroxy- benoquinolates Chem. Lett. 5, 905 (1993) Bathocuprine compounds such as BCP, BPhen, etc Appl. Phys. Lett. 91, 263503 (2007) 0 Appl. Phys. Lett. 79, 449 (2001) 5-member ring electron deficient heterocycles (e.g., triazole, oxadiazole, imidazole, benzoimidazole) Appl. Phys. Lett. 74, 865 (1999) Appl. Phys. Lett. 55, 1489 (1989) Jpn. J. Apply. Phys. 32, L917 (1993) Silole compounds Org. Electron. 4, 113 (2003) Arylborane compounds J. Am. Chem. Soc. 120, 9714 (1998) Fluorinated aromatic compounds J. Am. Chem. Soc. 122, 1832 (2000) Fullerene (e.g., C60) US20090101870 Triazine complexes US20040036077 Zn (N{circumflex over ( )}N) complexes U.S. Pat. No. 6,528,187

Synthetic Examples

Synthesis of Compound 1

(100) An oven-dried resealable Schlenk tube was charged with 3-bromo-1,8-naphthyridine (357 mg, 1.7 mmol), 9-phenyl-9H,9′H-3,3′-bicarbazole (764 mg, 1.87 mmol), copper(I) iodide (65 mg, 0.34 mmol), K.sub.3PO.sub.4 (902 mg, 4.25 mmol), evacuated and backfilled with argon. Trans-1,2-cyclohexanediamine (97 mg, 0.68 mmol) and dried toluene (3.4 mL) were then added under argon. The Schlenk tube was sealed with a Teflon valve and the reaction mixture was stirred at 120° C. for 24 h. The resulting dark-orange solution was cooled to room temperature and diluted with dichloromethane (DCM) (50 mL) and ammonium hydroxide solution (50 mL), then stirred at room temperature for 1 h. The organic phase was separated and the aqueous phase was extracted by DCM (50 mL×3). The combined organic phase was dried over magnesium sulfate, then filtered. The filtrate was concentrated and the residue was purified by flash chromatography on silica gel (EA/DCM/triethylamine 1:5:0.01) to afford the pure product of Compound 1 (748 mg 82%).

Synthesis of Compound 2

(101) An oven-dried resealable Schlenk tube was charged with 3-bromo-1,8-naphthyridine (357 mg, 1.7 mmol), N-(4-(9H-carbazol-3-yl)phenyl)-N-phenyldibenzo[b,d]furan-2-amine (936 mg, 1.87 mmol), copper(I) iodide (65 mg, 0.34 mmol), K.sub.3PO.sub.4 (902 mg, 4.25 mmol), evacuated and backfilled with argon. Trans-1,2-cyclohexanediamine (97 mg, 0.68 mmol), and dried toluene (3.4 mL) were then added under argon. The Schlenk tube was sealed with a Teflon valve and the reaction mixture was stirred at 120° C. for 24 h. The resulting dark-orange solution was cooled to room temperature and diluted with DCM (50 mL) and ammonium hydroxide solution (50 mL), then stirred at room temperature for 1 h. The organic phase was separated and the aqueous phase was extracted by DCM (50 mL×3). The combined organic phase was dried over magnesium sulfate, then filtered. The filtrate was concentrated and the residue was purified by flash chromatography on silica gel (EA/DCM/triethylamine 1:5:0.01) to afford the pure product of Compound 2 (780 mg 73%).

(102) Photoluminescence and photoluminescence quantum yield (PLQY) experiments were carried out and summarized in Table 2. mCP doped films (95:5 by weight of mCP:emitter) were fabricated vacuum thermal evaporation.

(103) TABLE-US-00002 TABLE 2 PLQY in Em.sub.max in mCP mCP film film Compound (%) (nm) 1 48 465 2 58 481

(104) Solvatochromism experiments were carried out and summarized in Table 3. Photoluminescence spectra of Compound 1 and Compound 1 in solvents with different polarity were obtained at room temperature, and bathochromic shift was observed as the polarity of the solvent increased, suggesting the emissive origin of these classes of compound arised from donor-acceptor based CT state.

(105) TABLE-US-00003 TABLE 3 Em.sub.max in 3- Em.sub.max in 2- methylpentane Em.sub.max in methyltetrahydrofuran Compound (nm) toluene (nm) (nm) 1 414 475 512 2 428 500 566

DEVICE EXAMPLES

(106) All OLED device examples were fabricated by high vacuum (<10′ Torr) thermal evaporation. The anode electrode was ˜800 Å of indium tin oxide (ITO). The cathode was 10 Å of LiF followed by 1,000 Å of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H.sub.2O and O.sub.2) and a moisture getter was incorporated inside the package.

Device Example 1

(107) The organic stack of the Device Examples consists of sequentially, from the ITO surface, 100 Å of LG101 (purchased from LG Chem, Korea) as the hole injection layer (HIL), 300 Å of TAPC the hole transporting layer (HTL), 300 Å of mCP doped with 10% of the emitter Compound 1 as the emissive layer (EML), 400 Å of TmPyPB as the ETL.

(108) Device Example 2 was fabricated in the same way as Device Example 1 except Compound 2 was used as the emitter instead of Compound 1.

(109) Device Example 1 had an external quantum efficiency of 7.8% at 1 cd/m.sup.2. The CIE was 0.161, 0.237. Device Example 2 has an external quantum efficiency of 11% at 1 cd/m.sup.2. The CIE was 0.197, 0.356. This demonstrates that naphthyridine acceptor compounds with multiple N-atom donors can result in high efficiency OLEDs when used a emitters.

(110) It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.