Fuel cell and manufacturing method thereof having integrated membrane electrode assembly and gas diffusion layer

Abstract

A fuel cell having a membrane electrode assembly (MEA) comprising an electrolyte membrane, an anode and a cathode; and a gas diffusion layer (GDL) combined with both surfaces of the MEA is provided. In particular, the GDL includes a first layer having a first surface that comes in contact with a reaction region of the MEA, a second layer formed on a second surface of the first layer, and a third layer formed along a peripheral portion between a first region in which both the first layer and the second layer are formed and a second region in which only the second layer is formed. The first layer may be a first microporous layer, the third layer may be a second microporous layer having a viscosity lower than that of the first microporous layer, and the second layer is not the first microporous layer and the second microporous layer.

Claims

1. A fuel cell comprising: a membrane electrode assembly (MEA) having an electrolyte membrane, an anode and a cathode; and a gas diffusion layer (GDL) integrated into both surfaces of the membrane electrode assembly, wherein the gas diffusion layer includes a first layer having one surface that comes in contact with a reaction region of the membrane electrode assembly, a second layer formed on the other surface of the first layer, and a third layer formed along a peripheral portion between a first region in which both the first layer and the second layer are formed and a second region in which only the second layer is formed, wherein the first layer and third layer comprise a microporous layer and the microporous layer of the third layer is extended from the one surface in the direction of a separator longer than the microporous layer of the first layer.

2. The fuel cell according to claim 1, wherein the first layer is a first microporous layer, the third layer is a second microporous layer made of a material having a viscosity lower than that of the first microporous layer, and the second layer does not comprise the first microporous layer and the second microporous layer.

3. The fuel cell according to claim 1, wherein the third layer comprises an adhesive component.

4. The fuel cell according to claim 1, further comprising a frame configured to integrate the MEA with the GDL.

5. The fuel cell according to claim 4, wherein the frame is formed of a polymer material, a metal material or a ceramic material.

6. The fuel cell according to claim 4, wherein the frame is isolated from the first layer and comes in contact with the third layer.

7. The fuel cell according to claim 4, wherein the frame is isolated from the first region by the third layer.

8. The fuel cell according to claim 4, wherein a material forming the frame penetrates into a portion of the second layer, which is formed in the second region.

9. The fuel cell according to claim 4, wherein the fuel cell further comprises at least one manifold, one side of the frame comes in contact with the MEA and the GDL, and the other side of the frame comes in contact with the manifold.

10. A method for manufacturing a fuel cell, the method comprising: combining a gas diffusion layer (GDL) with both surfaces of a membrane electrode assembly (MEA) having an electrolyte membrane, an anode and a cathode, the gas diffusion layer comprising a first layer whose one surface comes in contact with a reaction region of the membrane electrode assembly, a second layer formed on the other surface of the first layer, and a third layer formed along a peripheral portion between a first region in which both the first layer and the second layer are formed and a second region in which only the second layer is formed, wherein the first layer and the third layer comprise a microporous layer and the microporous layer of the third layer is extended from the one surface in the direction of a separator longer than the microporous layer of the first layer.

11. The method according to claim 10, wherein the first layer is a first microporous layer, the third layer is a second microporous layer made of a material having a viscosity lower than that of the first microporous layer, and the second layer is not made of the first microporous layer and the second microporous layer.

12. The fuel cell according to claim 10, wherein the third layer comprises an adhesive component.

13. The method according to claim 10, further comprising injection-molding a frame configured to integrate the MEA with the GDL.

14. The method according to claim 13, wherein the frame is formed of a polymer material, a metal material or a ceramic material.

15. The method according to claim 13, wherein the frame is combined with the side of each of the membrane electrode assembly and the gas diffusion layer so as to integrate the membrane electrode assembly with the gas diffusion layer.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The above and other objects, features and advantages of the present invention will be more clearly understood from the following detailed description taken in conjunction with the accompanying drawing, in which:

(2) FIG. 1 shows an MEA structure fabricated using a conventional lamination technology;

(3) FIG. 2A is a top view of a GDL 40 according to an exemplary embodiment of the present invention;

(4) FIG. 2B is a side view of a GDL 40 according to an exemplary embodiment of the present invention;

(5) FIG. 3 shows a fuel cell comprising a combination of a GDL 40, an electrolyte membrane 10, a catalyst layer 30a, 30b and a frame 50a according to an exemplary embodiment of the present invention;

(6) FIG. 4 shows an upper mold 50b and a lower mold 50c, which are used to form a frame 50a by an injection molding process according to an exemplary embodiment of the present invention, and an injection-molded frame 50a; and

(7) FIGS. 5A and 5B show the shape and location of a frame 50a according to an exemplary embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

(8) It is understood that the term “vehicle” or “vehicular” or other similar term as used herein is inclusive of motor vehicles in general such as passenger automobiles including sports utility vehicles (SUV), buses, trucks, various commercial vehicles, watercraft including a variety of boats and ships, aircraft, and the like.

(9) The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. As used herein, the term “and/of” includes any and all combinations of one or more of the associated listed items.

(10) FIGS. 2A and 2B show a top view and a side view of a GDL 40 according to an exemplary embodiment of the present invention individually; FIG. 3 shows a fuel cell comprising a combination of a GDL 40, an electrolyte membrane 10, a catalyst layer 30a, 30b and a frame 50a according to an exemplary embodiment of the present invention; and FIG. 4 shows an upper mold 50b and a lower mold 50c, which are used to form a frame 50a by an injection molding process according to an exemplary embodiment of the present invention, and an injection-molded frame 50a.

(11) Referring to FIGS. 2A and 2B, the GDL 40 according to an exemplary embodiment of the present invention comprises a first layer 42 adjacent to the reaction region of the MEA 100, a second layer 46, and a third layer 44 disposed outside the first layer 42. The first layer 42 comprises a first microporous layer, and the third layer 44 comprises a second microporous layer made of a material having a viscosity lower than the material of the first microporous layer. The second layer 46 may not comprise the first microporous layer and the second microporous layer.

(12) Also, the third layer 44 may include an adhesive component, and the second layer 46 may not comprise a microporous layer and an adhesive component.

(13) Referring to FIGS. 3 and 4, the GDL 40 according to an embodiment of the present invention is combined (embedded in) with both surfaces of the MEA 100, and the GDL 40 and the MEA 100 may be integrated with each other by an injection-molded frame 50a. Specifically, the frame 50a can be injection-molded on the sides of the MEA 100 and the GDL 40 inserted between an upper mold 50b and a lower mold 50c so as to integrate the MEA 100 with the GDL 40. This frame 50a may be made of a polymer material, particularly a liquid crystal polymer (LCP), a metal material or a ceramic material. Further, it may be made of an electrically insulating material.

(14) The GDL 40 may comprise a first layer 42 whose one surface is adjacent to the reaction region of the MEA 100, a second layer 46 formed on the other surface of the first layer 42, and a third layer 44 formed along a peripheral portion between a first region 52 (reaction region) in which both the first layer 42 and the second layer 46 are formed and a second region 54 in which only the second layer 46 is formed. The first layer 42 comprises a first microporous layer, and the third layer 44 comprises a second microporous layer made of a material having a viscosity lower than the material of the first microporous layer. The second layer 46 should not comprise the first microporous layer and the second microporous layer.

(15) The third layer 44 may also be an adhesive component. In this case, the first layer 42 comprises a microporous layer, the third layer 44 comprises an adhesive component, and the second layer 46 does not comprise a microporous layer and an adhesive component.

(16) The frame 50a in the exemplary embodiment of the present invention is preferably not adjacent to the first layer 42 and is adjacent to the third layer 44. The frame 50a may be isolated from the first region 52 by the third layer 44. In other words, the third layer 44 functions to isolate the frame 50a from the first region 52 consisting of the first layer 42 and second layer 46. On the other hand, during injection molding, the frame 50a may be formed on the second layer 46 portion formed in the second region 54. The second layer 46 may be made of material having relatively high porosity.

(17) In other words, the material forming the frame 50a may penetrate into the second layer 46 portion corresponding to the second region 54. For example, when the material of the frame 50a is a liquid polymer material, this material does not come in contact with the first layer 42 and second layer 46 of the first region 52 due to the third layer 44 formed between the frame 50a and the first region 52, but may penetrate into the second layer 46 portion formed in the second region 54. In connection with this, FIG. 3 shows a structure in which the material of the frame 50a penetrated into a portion of the second layer 46 formed in the second region 54, and FIG. 4 shows the upper mold 50b, the lower mold 50c and the frame 50a formed in the mold.

(18) FIGS. 5A and 5B show the shape and location of a frame 50a according to an embodiment of the present invention. As shown in FIGS. 5A and 5B, a fuel cell according to an exemplary embodiment of the present invention may comprise manifolds 60. One side of the frame 50a may come in contact with each side of the MEA 100 and the GDL 40, and the other side of the frame 50a may be adjacent to the manifold 60. As shown in FIG. 5B, the thickness of a portion of the frame 50a, which is adjacent to the manifold 60, may be less than the thickness of a portion of the frame 50a, which comes in contact with the side of each of the MEA 100 and the GDL 40.

(19) As described above, according to the present invention, the MEA and the GDL are integrated with each other by an injection molding process, and thus can be easily assembled and handled. The loss of the MEA can be eliminated, thus reducing the costs of production. Further, the number of processes for producing the fuel cells can be reduced, and thus the production line can be simplified and the productivity can be increased.

(20) Moreover, the injection molding process can be performed in an automated and accurate manner, and thus the product's failure rate can be reduced and mass production becomes possible. Also, because there is no electrolyte membrane on the manifold side, it is possible to reduce corrosion of the wall portion of a fuel cell stack, which can be caused by a phenomenon in which water produced by electrochemical reactions flows out of the fuel cell through the electrolyte membrane. Also, it is possible to ensure stable electrical insulation.

(21) Finally, since the frame is formed outside the reaction region of the MEA, the GDL can be prevented from being broken and over-compressed when it is compressed by the separator during cell assembling.

(22) Although the preferred embodiments of the present invention have been described for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims.