Flow rate control mechanism and gas chromatograph including flow rate control mechanism

Abstract

One end of carrier gas channel, purge gas channel and split gas channel is connected to sample gasification chamber. The other end of carrier gas channel, purge gas channel, and split gas channel is connected to a flow rate control mechanism in the form of carrier gas flow rate control block, purge gas flow rate control block and split gas flow rate control block respectively. Carrier gas flow rate control block, purge gas flow rate control block and split gas flow rate control block constitute a flow rate control unit. This reduces the possibility of leakage of gas to the outside and admixture of impurities from the outside in the flow rate control mechanism.

Claims

1. A gas chromatograph apparatus comprising: a flow rate control mechanism comprising a single block in which are integrally joined: a first connection unit for connecting a gas supply source which supplies gas; a second connection unit for connecting a gas channel for guiding gas from said gas supply source to a predetermined part; an internal channel which connects said first connection unit to said second connection unit; and a flow rate control valve which controls the flow rate of gas flowing between said first connection unit and said second connection unit by adjusting the channel width of said internal channel; analytical column for separating a sample; detector for detecting the sample which has been separated in said analytical column; sample introduction channel for guiding the sample into said analytical column; sample injection unit for injecting the sample into said sample introduction channel; and carrier gas supply unit which supplies a carrier gas to the sample injection unit for conveying the sample injected from the sample injection unit toward the analytical column, wherein the flow rate control mechanism is interposed between the carrier gas supply source and the channel of said carrier gas supply unit which communicates with the sample injection unit.

2. The gas chromatograph apparatus as described in claim 1, further comprising, within said block, a sensor connection channel for connecting a pressure sensor to said internal channel, one end of which second channel communicates with said internal channel.

3. The gas chromatograph apparatus as described in claim 2, wherein said block integrally retains said pressure sensor.

4. A gas chromatograph apparatus comprising: a flow rate control mechanism comprising a single block in which are integrally joined: a first connection unit for connecting a gas supply source which supplies gas; a second connection unit for connecting a gas channel for guiding gas from said gas supply source to a predetermined part; an internal channel which connects said first connection unit to said second connection unit; and a flow rate control valve which controls the flow rate of gas flowing between said first connection unit and said second connection unit by adjusting the channel width of said internal channel; an analytical column for separating a sample, a detector for detecting the sample which has been separated in said analytical column, a sample introduction channel for guiding the sample into said analytical column, a sample injection unit for injecting the sample into said sample introduction channel, a carrier gas supply unit which supplies a carrier gas to said sample injection unit for conveying the sample injected from said sample injection unit toward said analytical column, a detector gas supply unit for supplying detector gas to said detector, and the flow rate control mechanism interposed between the detector gas supply source and the channel of said detector gas supply unit which communicates with said detector.

5. The gas chromatograph of claim 4, further comprising, within said block, a sensor connection channel for connecting a pressure sensor to said internal channel, one end of which second channel communicates with said internal channel.

6. The gas chromatograph of claim 5, wherein said block integrally retains said pressure sensor.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a channel diagram showing an example of embodiment of a gas chromatograph.

(2) FIG. 2 is a diagram showing an example of the structure of various flow rate control blocks of a flow rate control unit, where (A) is a front cross-sectional view, (B) is a cross-sectional view at the location W-W of (A), and (C) is a cross-sectional view at the location X-X, location Y-Y and location Z-Z of (A).

(3) FIG. 3 is a cross-sectional view showing an example of the structure of a sample introduction unit and sample gasification chamber.

(4) FIG. 4 is a channel diagram showing an example of embodiment of a detector gas flow rate control unit.

(5) FIG. 5 is a channel diagram showing an example of a conventional gas chromatograph.

(6) FIG. 6 is a plan view showing an example of a conventional flow rate control mechanism of a gas chromatograph using a channel substrate.

DETAILED DESCRIPTION OF THE EXEMPLARY EMBODIMENTS

(7) In a preferable example of embodiment of the present invention, within the block, there is further provided a sensor connection channel whereof one end communicates with the internal channel and which serves for connecting a pressure sensor to the internal channel. Conventionally, when connecting a pressure sensor to a channel through which gas flows, it was necessary to connect the pressure sensor via a connection block to the channel through which gas flows, so the number of channel connection parts using a sealing member such as an O-ring would further increase. By contrast, by making it possible to directly connect the pressure sensor to the block of the flow rate control mechanism of the present invention by providing a channel for connecting the pressure sensor, the increase in the number of channel connection parts using a sealing member such as an O-ring can be kept to a minimum.

(8) An example of embodiment of a gas chromatograph will be described below using FIG. 1.

(9) This gas chromatograph comprises a flow rate control unit 1, sample gasification chamber 4, sample introduction channel 5, analytical column 6, detection channel 7 and detector 8.

(10) One end of carrier gas channel 10, purge gas channel 12 and split gas channel 14 is connected to sample gasification chamber 4. The other end of carrier gas channel 10, purge gas channel 12 and split gas channel 14 is connected respectively to a flow rate control mechanism in the form of carrier gas flow rate control block 24, purge gas flow rate control block 40 and split gas flow rate control block 52. Carrier gas flow rate control block 24, purge gas flow rate control block 40 and split gas flow rate control block 52 constitute a flow rate control unit 1.

(11) A sample injection unit 2 is provided in the top of sample gasification chamber 4. In sample gasification chamber 4, as shown in FIG. 3, a portion of the carrier gas supplied through carrier gas channel 10 conveys the sample injected from sample injection unit 2 towards insert unit 90, and the rest of the carrier gas passes as purge gas through purge gas channel 12 and is discharged to the outside. A portion of the gas containing gasified sample (hereinafter, sample gas), conveyed toward the insert 90, passes through sample introduction channel 5 and is guided to analytical column 6, while the rest of the sample gas passes as split gas through split gas channel 14 and is discharged to the outside. Gas containing components separated in analytical column 6 passes through detection channel 7 and is guided to detector 8 to undergo detection.

(12) Carrier gas flow rate control block 24 comprises a flow rate control valve 28 which controls the flow rate of carrier gas flowing between internal channels 30-32 by adjusting the width of the channel connecting one end of internal channel 30 and one end of internal channel 32. The other end of channel 30 communicates with a first channel connection part in the form of pipe connection unit 26 for connecting a carrier gas bottle, and the other end of channel 32 communicates with a second channel connection unit in the form of pipe connection unit 27 to which is connected a carrier gas channel 10 leading to sample introduction unit 2. Pressure sensor 34 is connected to internal channel 30 and differential pressure sensor 36 is connected to internal channel 32. Differential pressure sensor 36 is also connected to internal channel 46 of purge gas flow rate control block 38 and measures the differential pressure between the two channels 32 and 46.

(13) Purge gas flow rate control block 38 comprises a flow rate control valve 42 which controls the flow rate of purge gas flowing between internal channels 46-44 by adjusting the width of the channel connecting one end of internal channel 44 to one end of internal channel 46. The other end of channel 44 communicates with pipe connection unit 40 for connecting a purge gas discharge channel, and the other end of channel 46 communicates with pipe connection unit 41 for connecting purge gas channel 12, which leads to sample introduction unit 2. Pressure sensor 48 is connected to internal channel 44, and differential pressure sensor 36 and pressure sensor 50 are connected to internal channel 46.

(14) Split gas flow rate control block 52 comprises a flow rate control valve 56 which controls the flow rate of split gas flowing between internal channels 60-58 by adjusting the width of the channel connecting one end of internal channel 58 and one end of internal channel 60. The other end of internal channel 58 communicates with pipe connection unit 54, and the other end of internal channel 60 communicates with pipe connection unit 55 for connecting split gas channel 14 which leads to sample introduction unit 2.

(15) The cross-sectional structure of carrier gas flow rate control block 24, purge gas flow rate control block 38 and split gas flow rate control block 52 is shown in FIG. 2. FIG. 2 (B) shows the cross-section of position W-W of (A), and (C) shows the cross-section at position X-X of carrier gas flow rate control block 24, position Y-Y of purge gas flow rate control block 38 and position Z-Z of split gas flow rate control block 52.

(16) First, the carrier gas flow rate control block 24 will be described.

(17) Hollow parts 61, 62 and 64 are provided inside the carrier gas flow rate control block 24. Hollow part 61 communicates via a channel with pipe connection unit 26. Hollow part 61 communicates via a channel with hollow part 62. The tip of pipe 34a of pressure sensor 34 is inserted into hollow part 62 and is connected to the channel which communicates with hollow part 61. The connection part between pipe 34a and the channel communicating with hollow part 61 is sealed with an O-ring 76. Pressure sensor 34 is thereby connected to hollow part 61. Pressure sensor 34 is supported by a member provided on carrier gas flow rate control block 24, and is integrally joined with carrier gas flow rate control block 24.

(18) Hollow part 64 communicates via a channel with pipe connection unit 27. Furthermore, the tip of pipe 36a of differential pressure sensor 36 is inserted into hollow part 64, and the gap between the outer circumference of pipe 36a and the inner circumference of hollow part 64 is sealed with an O-ring 78. Differential pressure sensor 36 is thus connected to hollow part 64.

(19) Hollow part 61 and hollow part 64 both communicate with flow rate adjustment unit 28b. Flow rate adjustment unit 28b adjusts the flow rate of carrier gas flowing from hollow part 61 to hollow part 64 by adjusting the width of the channel connecting hollow part 61 to hollow part 64 by means of a diaphragm of valve driving unit 28a. The supply rate of carrier gas from a carrier gas bottle connected to pipe connection unit 26 is adjusted in this way.

(20) Next, the purge gas flow rate control block 38 will be described.

(21) Hollow parts 66, 68, 70 and 72 are provided inside the purge gas flow rate control block 38. Hollow part 66 and hollow part 68 communicate via a channel, and hollow part 66 and hollow part 70 also communicate via a channel. The tip of pipe 48a of pressure sensor 48 is inserted into hollow part 68, and pipe 48a is connected to one end of the channel at the rear wall of hollow part 68 which communicates with hollow part 66. The connection area between pipe 48a and the channel which communicates with hollow part 66 is sealed by means of an O-ring 82. Pressure sensor 48 is thus connected to hollow part 66. Pressure sensor 48 is retained by a member provided on the purge gas flow rate control block 38 and is integrally joined with the purge gas flow rate control block 38.

(22) Pipe connection unit 41 is connected via a channel to hollow part 70. Furthermore, the tip of pipe 36b of differential pressure sensor 36 is inserted into hollow part 70, and the gap between the outer circumference of pipe 36b and the inner circumference of hollow part 70 is sealed with an O-ring 80. In this way, the differential pressure sensor 36 is connected inside the hollow part 70.

(23) Hollow part 72 communicates with pipe connection part 40 via a channel. Furthermore, the tip of pipe 50a of pressure sensor 50 is inserted into hollow part 72, and the gap between the outer circumference of pipe 50a and the inner circumference of hollow part 72 is sealed by O-ring 84. In this way, the pressure sensor 50 is connected inside hollow part 72. Pressure sensor 50 is secured to split gas flow rate control block 54.

(24) Hollow part 66 and hollow part 72 communicate with flow rate adjustment part 42b. Flow rate adjustment unit 42b adjusts the flow rate of purge gas flowing from hollow part 66 to hollow part 72 by adjusting the width of the channel connecting hollow part 66 and hollow part 72 by means of the diaphragm of valve driving unit 42a. The purge gas flow rate from pipe connection unit 40 is adjusted in this manner.

(25) Next, the split gas flow rate control block 52 will be described.

(26) A hollow part 74 is provided inside the split gas flow rate control block 52. Pipe connection unit 55 is connected via channel 55a to hollow part 74. Hollow part 74 communicates with flow rate adjustment unit 56b, and pipe connection unit 54 is also connected via a channel to flow rate adjustment unit 56b. Flow rate adjustment unit 56b adjusts the flow rate of split gas flowing from hollow part 74 to pipe connection unit 54 by adjusting the width of the channel connecting hollow part 74 and pipe connection unit 54 by means of a diaphragm of valve driving part 56a. The split gas flow rate from pipe connection unit 54 is adjusted in this manner.

(27) Based on the above configuration of blocks 24, 38 and 52, all the channels from inlet to outlet for carrier gas, purge gas or split gas are fashioned within a single block, and the valve mechanism which adjusts the flow rate of the gas passing through those channels is also provided within the same block, so the places which need to be sealed using an O-ring are limited to the connection locations of the pressure sensor and differential pressure sensor, allowing the structure of the flow rate control unit 1 comprising these blocks 24, 38 and 52 to be made into a structure with a low possibility of outflow of gas to the outside and admixture of gas or impurities from the outside.

(28) Employing this sort of structure eliminates the need for a channel substrate on which components such as valves and connecting members are mounted and connected via internal channels. As a result, the problem of air-tightness at the connection areas of these components to the channel substrate is eliminated. Furthermore, since the channel substrate and parts such as connection blocks for connecting the components to the channel substrate become unnecessary, the number of component parts is reduced and costs can be decreased.

(29) Furthermore, gas, which is required in principle, is supplied to the detector 8. If the detector 8 is, for example, a hydrogen flame ionization detector (FID), it is necessary to supply at least hydrogen and air as the detector gas to the detector 8. FIG. 4 is an example of the channel configuration for supplying detector gas to detector 8, and in this example, as the flow rate control mechanism which controls the supply rate of detector gas to the detector 8, flow rate control blocks 200, 204 and 208 having an equivalent structure to carrier gas flow rate control block 24 are interposed in channels 202, 206 and 210 which communicate with the detector gas supply sources and detector 8. Examples of detector gas include, for instance, hydrogen as detector gas 1, air as detector gas 2 and nitrogen or helium as detector gas 3.

(30) In this way, it is possible to use a flow rate control mechanism (flow rate control block) consisting of a single block not just as a carrier gas flow rate control unit but also in other places where gas flow rate needs to be controlled. It is thereby possible to prevent outflow of gas to the outside and admixture of foreign substances from the outside and to simplify the device configuration.

DESCRIPTION OF REFERENCES

(31) 1 Flow rate control mechanism 2 Sample injection unit 4 Sample gasification chamber 5 Sample introduction channel 6 Analytical column 7 Detection channel 8 Detector 10 Carrier gas channel 12 Purge gas channel 14 Split gas channel 24 Carrier gas flow rate control block 26, 27, 40, 41, 54, 55 Pipe connection unit 28, 42, 56 Flow rate control valve 30, 32, 44, 46, 58, 60 Channel (within block) 34, 48, 50 Pressure sensor 36 Differential pressure sensor