COCOA POWDER FOR BEVERAGES AND METHODS OF PREPARING THE SAME
20220304328 · 2022-09-29
Assignee
Inventors
Cpc classification
A23G1/56
HUMAN NECESSITIES
A23G1/00
HUMAN NECESSITIES
International classification
A23G1/56
HUMAN NECESSITIES
Abstract
The present invention relates to methods for the preparation of cocoa- or chocolate-based beverages with excellent, rich taste, favorable organoleptic properties and high contents of nutritionally beneficial components, wherein the method comprises the steps of: a) adding water to cocoa beans or nibs to form a suspension; b) wet grinding said suspension; c) subjecting said suspension to a heat treatment at a temperature of 70° C. or less; d) separating the suspension into a water phase (heavy phase), a fat phase (light phase) and a solid phase, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising cocoa powder and water; e) separating at least cocoa powder from the solid phase, and a step of mixing the thus produced cocoa powder or chocolate products obtained therefrom with a water source to provide the cocoa- or chocolate-based beverage. In addition, related uses and products are disclosed, which include cocoa drinks, chocolate drinks and instant cocoa powder.
Claims
1. A method for producing a cocoa beverage comprising the steps of: a) adding water to cocoa beans or nibs to form a suspension; b) wet grinding said suspension; c) subjecting said suspension to a heat treatment at a temperature of 70° C. or less; d) separating the suspension into a water phase (heavy phase), a fat phase (light phase) and a solid phase, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising cocoa powder and water; e) separating at least cocoa powder from the solid phase, and f) mixing the separated cocoa powder with a water source to provide the cocoa beverage.
2. The method according to claim 1, wherein step e) comprises a step of drying the solid phase in a dryer after separation in three phases to obtain cocoa aroma and dried cocoa powder.
3. The method according to claim 1 wherein the separated cocoa powder is mixed with at least water and/or milk directly after step e).
4. A method for producing a chocolate beverage comprising the steps of: a) adding water to cocoa beans or nibs to form a suspension; b) wet grinding said suspension; c) subjecting said suspension to a heat treatment at a temperature of 70° C. or less; d) separating the suspension into a water phase (heavy phase), a fat phase (light phase) and a solid phase, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising cocoa powder and water; e1) separately processing the three phases, which comprises: 1) neutralizing and/or removing acidic components formed in the cocoa beans via the water phase, 2) separating cocoa butter from the fat phase, 3) separating cocoa powder from the solid phase, and 4) separating cocoa aroma and a polyphenolic powder from at least the water phase; e2) recombining the cocoa aroma extract with the cocoa butter extract; e3) mixing the recombined extracts with at least said cocoa powder extract, and optionally with said polyphenolic powder extract and/or milk powder; e4) conching said mixture to prepare a chocolate; e5) optionally comminuting the chocolate; and e6) mixing the chocolate with a water source to provide the chocolate beverage.
5. The method according to claim 4, wherein step 3) comprises a step of drying the solid phase in a dryer after separation in three phases to obtain cocoa aroma and dried cocoa powder.
6. The method according to claim 1 wherein step b) comprises: b1) wet grinding said cocoa bean water suspension in a first coarse grinding step in a first mill; and b2) wet grinding said cocoa bean water suspension in a second fine grinding step in a second mill such that cocoa bean particles with an average particle size of 40 micrometers or less are obtained.
7. The method according to claim 1, wherein the water source is water or milk and/or wherein steps a) to e) are performed without use of non-water solvents.
8. The method according to claim 1 wherein the cocoa powder is non-alkalized.
9. The method according to claim 1, comprising a step of separating polyphenolic powder from at least the water phase, and recombining the polyphenolic powder with the cocoa powder prior to the mixing with the water source.
10. The method according to claim 1, wherein the steps prior to the mixing with the water source are performed at temperatures of no more than 70° C. and/or wherein mixing with the water source is performed at temperatures of between 40° C. and 85° C.
11. The method according to claim 1, wherein steps a) to e) are performed without addition of a non-cocoa fruit constituent apart from the water source.
12. A cocoa or chocolate beverage manufactured by the method according to claim 1.
13. Use of a cocoa powder for the preparation of a cocoa or chocolate beverage, wherein the cocoa powder is obtained by a method comprising the separation of a water phase (heavy phase) and a solid phase from an aqueous suspension of wet ground cocoa beans, and recovering the cocoa powder from the solid phase.
14. Use of a cocoa powder for the preparation of a cocoa or chocolate beverage according to claim 13, wherein the method comprises a) adding water to cocoa beans or nibs to form a suspension; b) wet grinding said suspension; c) subjecting said suspension to a heat treatment at a temperature of 70° C. or less; d) separating the suspension into a water phase (heavy phase), a fat phase (light phase) and a solid phase, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising cocoa powder and water; and e) separating at least cocoa powder from the solid phase.
15. An instant cocoa powder obtained by a method comprising the steps of: a) adding water to cocoa beans or nibs to form a suspension; b) wet grinding said suspension; c) subjecting said suspension to a heat treatment at a temperature of 70° C. or less; d) separating the suspension into a water phase (heavy phase), a fat phase (light phase) and a solid phase, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising cocoa powder and water; e) separating at least cocoa powder from the solid phase, or e1) separately processing the three phases, which comprises: 1) neutralizing and/or removing acidic components formed in the cocoa beans via the water phase, 2) separating cocoa butter from the fat phase, 3) separating cocoa powder from the solid phase, and 4) separating cocoa aroma and a polyphenolic powder from at least the water phase; e2) recombining the cocoa aroma extract with the cocoa butter extract; e3) mixing the recombined extracts with at least said cocoa powder extract, and optionally with said polyphenolic powder extract and/or milk powder; e4) conching said mixture to prepare a chocolate; and e5) comminuting the chocolate; and instantizing the cocoa powder obtained in step e) or the comminuted chocolate obtained in step e5) to obtain the instant cocoa powder.
16. The method of claim 6 comprising wet grinding said cocoa bean water suspension in the second fine grinding step in the second mill such that cocoa bean particles with an average particle size of 20 micrometers are obtained.
17. The method according to claim 4 wherein step b) comprises: b1) wet grinding said cocoa bean water suspension in a first coarse grinding step in a first mill; and b2) wet grinding said cocoa bean water suspension in a second fine grinding step in a second mill such that cocoa bean particles with an average particle size of 40 micrometers or less are obtained.
18. The method according to claim 4 wherein the water source is water or milk and/or wherein steps a) to e) are performed without use of non-water solvents.
19. The method according to claim 4 wherein the cocoa powder is non-alkalized.
20. The method according to claim 2 further comprising roasting the solid phase.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0015]
[0016]
DETAILED DESCRIPTION OF THE INVENTION
[0017] For a more complete understanding of the present invention, reference is now made to the following description of the illustrative embodiments thereof:
[0018] In the present description, a distinction is made between the terms “cocoa beverage” and “chocolate beverage”, wherein the former intends to denote cocoa-based drinks based on (partially) defatted cocoa powder and the latter describes cocoa-based drinks based on chocolate.
[0019] The method for producing a cocoa beverage according to a first embodiment of the present invention is generally characterized by the steps of: a) adding water to cocoa beans or nibs to form a suspension; b) wet grinding said suspension; c) subjecting said suspension to a heat treatment at a temperature of 70° C. or less; d) separating the suspension into a water phase (heavy phase), a fat phase (light phase) and a solid phase, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising cocoa powder and water; e) separating at least cocoa powder from the solid phase, and f) mixing the separated cocoa powder with a water source to provide the cocoa beverage. Accordingly, the cocoa powder obtained during this method substantially differs from conventional cocoa powder as it is not produced from cocoa liquor.
[0020] Surprisingly, it has been found that despite of the pre-extraction of the cocoa beans/nibs with water during the three-phase separation in step d), the produced cocoa beverage exhibits a rich aromatic profile without unpleasant bitter, astringent or acidic flavors, in combination with high antioxidant contents and satisfactory smooth texture without necessitating alkalization. In addition, the method is simple when compared to traditional methods and enables faster processing from the bean to the prepared drink.
[0021] An exemplary overview of the method according to the first embodiment is shown in
[0022] The subject cocoa beverage production technique generally begins with forming a suspension of cocoa beans or nibs by adding water, either prior or during the grinding of the cocoa beans/nibs. The cocoa beans or nibs may be fermented, unfermented, incubated, pre-roasted, or non-roasted cocoa beans or nibs. In one embodiment, green cocoa beans may be processed together with pulp and mucilage (i.e. with only the pod shell being removed) as starting material. While not being particularly limited, the weight ratio of water to cocoa beans/nibs in the formed suspension is preferably between 1:1 to 6:1, more preferably 2:1 to 4:1, especially preferably about 3:1, which may advantageously affect the processability in the further steps (e.g. facilitated pumping, grinding and easier phase separation).
[0023] It will be understood that alternative water-containing liquids may also be used in step a), preferably liquids selected from one or more of coffee, tea and liquids having water contents of from 60 to about 95% by weight, such as fruit juices, fruit juice concentrates, or milk, for example, in order to provide for additional flavors. In such a case, it is preferable that the water content in the formed suspension falls into the above-defined ratios. Since the thermal load in the further method steps is relatively low, temperature-sensitive flavors originating from said liquids are retained and may favorably interact with the primary and secondary flavors of the cocoa bean.
[0024] In order to obtain coffee-flavored cocoa products, coffee beans (whole or broken, unroasted or roasted) may be mixed to the fermented cocoa beans/nibs when forming the suspension in water, provided that the cocoa beans/nibs form the major part in the bean mixture so that the content of coffee beans does not interfere or negatively affect the wet milling and phase separation steps. Preferably, the coffee bean content is less than 20% by weight of the bean mixture, more preferably less than 10% by weight.
[0025] In step b), the cocoa beans/nibs are subjected to a single or multiple wet grinding step(s), which result in bean particle sizes of preferably 50 μm or smaller, more preferably 40 μm or smaller, even more preferably 20 μm or smaller. In a preferred embodiment, step b) comprises a step b1) wet grinding said cocoa bean water suspension in a first coarse grinding step in a first mill; and b2) wet grinding said cocoa bean water suspension in a second fine grinding step in a second mill such that cocoa bean particles with an average particle size of 40 μm or less, or preferably 20 μm or less are obtained. The bean particle size reduction may be accomplished by using disc mills (e.g. perforated disc mill), colloid mills (e.g. toothed colloid mills), or corundum stone mills, for example. It is preferable that in at least one grinding step, cocoa bean cells are macerated to enable the solvent (water) to wet the cocoa bean material better due to increased available surface area of the macerated cocoa beans. The methods and devices used for wet milling are not particularly limited as long as undesirable emulsification by significant frictional heat production or high mechanical forces is avoided. When using multiple grinding steps, it may be preferred that a coarse wet grinding step (e.g., optionally with further water) is carried out using a perforated disc mill, and the coarsely milled suspension is then pumped to a toothed colloid mill for a fine grinding step.
[0026] After the wet grinding step, the suspension is subjected to a thermal treatment at a temperature of no more than 70° C. in step c) in order to reduce the overall thermal load and prevent emulsification. From the viewpoint of a favorable balance of cocoa butter yield and preservation of desirable flavors, such as aromatics, anti-oxidants and/or vitamins, heating temperatures of from 43 to 65° C. are preferable. In terms of cocoa butter liquefaction and/or improved mechanical phase separation, a heating temperature range of from 45 to 50° C. is particularly preferable. Without being limited thereto, heating of the wet-milled suspension may be carried out by a scrap or tube heat exchanger.
[0027] Thereafter, phase separation is carried out in step d) so that three phases, i.e. a water phase (heavy phase), a fat phase (light phase) and a solid phase are obtained, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising cocoa powder and water. In addition, the solid phase may comprise residual cocoa butter in a content of up to 30% by weight, preferably less than 27% by weight, more preferably less than 20% by weight relative to the total dry weight. Preferably, devices employing centrifugal forces may be utilized to achieve mechanical particle separations, such as decanters or nozzle separators. For instance, the suspension may be decanted to separate coarse or large or high mass solids from liquid(s) and then smaller and/or fine solid particles may be further separated from liquids and/or oil products may be separated from non-oil products.
[0028] By separating the water phase from the solid phase comprising the cocoa powder, the concentration of acidic components and unpleasant water-soluble aroma components in the cocoa beverage is remarkably reduced without requiring alkalization (or Dutching). Also, if deemed appropriate, water-soluble acids may be added prior to phase separation in any desired amount deemed favorable with regard to the adjustment of the pH conditions and/or for the purpose of improving the flavor development within the cocoa beans or nibs, since their addition does not necessarily result in a sour or bitter taste in the final product.
[0029] Multiple phase separation and recombination steps may be employed to achieve an improved separation between the water phase (heavy phase), the fat phase (light phase) and the solid phase. For example, the fat phase obtained by an initial decanting step may be further filtered or centrifuged to separate remaining fine particles or water from the fat phase and the thus obtained fine particles and water may be recombined with the water and solid phases from the initial decanting step or at a later processing stage of said phases. Also, the water phase may be subjected to further purification steps, e.g. by filtration using vacuum rotation filters in order to remove fine particles, which may then be recombined with the solid phase.
[0030] Upon separation of the three phases (i.e. the water phase (heavy phase), the fat phase (light phase) and the solid phase), these may be independently processed to separate cocoa butter (from the fat phase), cocoa powder (from the solid phase), cocoa aroma (from the water phase and/or the solid phase) and a polyphenolic concentrate (from the water phase), as is illustrated by
[0031] The fat phase (light phase) may be filtered (e.g. by employing a vibrating screen) and/or conveyed to a 3-phase separator (e.g. centrifuge) to remove fine particles (which may be optionally added to the solid phase prior or during the drying/roasting step) and residue water (which may be optionally added to the water phase prior to aroma recovery). Cocoa butter may be obtained by filtering the purified fat phase.
[0032] In step e), cocoa powder is separated from the solid phase, e.g. by drying. The (wet) solid phase obtained after separation in the three phases may be optionally treated with a heatable roll grinder to reduce particle size and begin pre-drying. Also, sugar, sugar solution and/or fruit juices may optionally be added to separated cocoa solids before drying to improve flavor development during the drying/roasting process. Preferably, step e) comprises a step of drying and optionally roasting of the solid phase in a dryer after separation in three phases to obtain cocoa aroma and dried cocoa powder. Further preferably, the solid phase is gently dried and simultaneously roasted at a temperature of between 55 and 100° C., from the viewpoint of reducing the thermal load and preserving the health-inducing components preferably at a temperature selected from between 55 and 70° C. under reduced pressure, in order to allow roasted flavors and other aromas to be collected. Preferably, the drying/roasting step is carried out in a mixing device as is disclosed in EP 3 114 941 A1, wherein said mixing device comprises a cylindrical, tubular body arranged with its axis horizontal and closed at its opposite ends by end plates, and having a coaxial heating or cooling jacket through which, for example, diathermic oil or another fluid is intended to flow to keep the internal wall of the body at a predetermined temperature. The tubular body has an inlet and outlet openings for the solid phase. The outlet opening communicates, by means of a duct, with a device for separating the aroma phase from the dried product. The device further comprises a bladed rotor is supported for rotation in the tubular body, its blades being arranged as a helix and oriented for centrifuging the solid phase being processed and simultaneously transporting it towards the outlet opening. Using this mixing device advantageously allows the drying/roasting step and the separation of the roasted flavors and other aromatics to be carried out continuously and also remarkably accelerates the processing of cocoa beans up to the preparation of the cocoa powder (dry cocoa matter), resulting in processing durations of less than 20 minutes, typically less than 15 minutes.
[0033] In a preferred embodiment, the cocoa powder produced in step e) has a total polyphenol content of at least 20 mg ECE((−)-epicatechin equivalents)/g of defatted dry matter, more preferably at least 30 mg ECE/g of defatted dry matter, especially preferably at least 40 mg ECE/g of defatted dry matter. Preferably, the cocoa powder has a flavonoid concentration of at least 10 mg ECE/g of defatted dry matter, more preferably at least 20 mg ECE/g of defatted dry matter, especially preferably at least 30 mg ECE/g of defatted dry matter. In another preferred embodiment, the cocoa powder has a proanthocyanidine concentration of at least 2 mg PCE (procyanidin B2 equivalents)/g of defatted dry matter, more preferably at least 3 mg PCE/g of defatted dry matter, especially preferably at least 4 mg PCE/g of defatted dry matter.
[0034] The total polyphenol content, and the flavonoid and proanthocyanidine concentrations may be determined by common spectrophotometric methods known to the skilled artisan. For example, the total polyphenol content may be determined by using a Folin-Ciocalteu assay with (−)-epicatechin as standard, in accordance with the method disclosed in Folin-Ciocalteu index, Off. J. Eur. Communities 1990, 41, 178-179, and Cooper et al., J. Agric. Food Chem 2008, 56, 260-265. The total flavonoid content may be determined by means of an aluminum chloride colorimetric assay, for example, in accordance with Emelda et al. Int. J. Chem Tech Res. 2014, 6(4), 2363-2367, using (−)-epicatechin as standard. An acid-butanol method (such as e.g. Bates-Smith assay or a Porter method) using procyanidin B2 as standard may be employed to spectrophotometrically determine the content of proanthocyanidine.
[0035] Steps a) to e) are preferably performed without use of non-water based solvents in order to avoid additional steps of solvent removal and to preserve high contents of nutritionally beneficial components in the cocoa powder extract.
[0036] In the final step f) of the method according to the first embodiment, the separated cocoa powder is mixed with a water source to provide the cocoa beverage. While the water source is not particularly limited as long as it enables sufficient dispersion of cocoa powder particles, it is preferably selected from water or water-containing liquids as mentioned above with respect to step a). Especially preferably, the water source is water or milk (which includes, but is not limited to cow milk, goat milk, soy milk, rice milk, coconut milk, almond milk, flax milk, hemp milk, oat milk, or the like).
[0037] The (dried) cocoa powder may be subjected to a solubilisation treatment or dispersion enhancement prior to step f). For this purpose, however, it is preferred that such a treatment is performed without addition of alkaline agents, such as in the enzymatic process disclosed n WO 2008/059064 A1, for example. Further examples of such methods will be known to the skilled artisan.
[0038] In general, it is preferred that the cocoa powder is non-alkalized in order to preserve high contents of nutritionally beneficial components.
[0039] Further additives (e.g. vitamins, minerals, salts, lecithin), flavors (e.g. vanilla, caramel, cinnamon, nut flavors), thickening agents (e.g. corn starch) and sweeteners (such as sugar (e.g. sucrose, lactose, dextrose, maltose, fructose, saccharose) or cocoa pulp) may be added during or before the mixing step. However, in a further preferred embodiment, steps a) to e) are performed without addition of a non-cocoa fruit constituents apart from the water source. For instance, as indicated in
[0040] Also, it is generally preferred that the steps prior to the mixing with the water source are performed at temperatures of no more than 70° C., whereas mixing with the water source is preferably performed at temperatures of between 40° C. and 85° C.
[0041] The mixing step f) may be carried out by suitable techniques and devices known to the skilled artisan.
[0042] In a preferred embodiment, the water source is mixed with the cocoa powder directly after step e). In general, in case of microorganism spoilage of cocoa extracted materials (i.e. cocoa butter, cocoa powder, cocoa aroma and polyphenolic concentrate), deodorization may be accomplished by use of a vacuum de-aerator. Moreover, if microorganism contamination occurs, a high pressure treatment such as pascalisation is possible (e.g., which is desirable because it can preserve aromatic compounds). If both microorganism spoilage and contamination occurs, heat treatment and deodorization may be employed. However, the method according to the present invention advantageously allows a fast processing of the cocoa beans/nibs, so that growth of microorganisms may be kept at a minimum.
[0043] In view of the above, the present invention according to the first embodiment enables rapid, simple and cost-effective production of high-quality cocoa beverages while preserving the contents of nutritionally valuable components.
[0044] In a second embodiment, the present invention relates to a method for producing a chocolate beverage comprising the steps of: a) adding water to cocoa beans or nibs to form a suspension; b) wet grinding said suspension; c) subjecting said suspension to a heat treatment at a temperature of 70° C. or less; d) separating the suspension into a water phase (heavy phase), a fat phase (light phase) and a solid phase, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising cocoa powder and water; e1) separately processing the three phases, which comprises: 1) neutralizing and/or removing acidic components (e.g. acetic or citric acid formed in the cocoa beans during fermentation) via the water phase, 2) separating cocoa butter from the fat phase, 3) separating cocoa powder from the solid phase, and 4) separating cocoa aroma and a polyphenolic powder from at least the water phase; e2) recombining the cocoa aroma extract with the cocoa butter extract; e3) mixing the recombined extracts with at least said cocoa powder extract, and optionally with said polyphenolic powder extract and/or milk powder; e4) conching said mixture to prepare a chocolate; e5) optionally comminuting the chocolate; and e6) mixing the chocolate with a water source to provide the chocolate beverage.
[0045] In contrast to the first embodiment, the method of the second embodiment differs in that in step e) the three phases are separately processed and suitably recombined and conched to provide a chocolate, which is then mixed with a water source in step e5) in analogy to step f) of the first embodiment to provide a chocolate drink. It will be understood that the first and second embodiments may be combined as desired, and that the preferred features of steps a) to f) according to the first embodiment may likewise apply for the second embodiment.
[0046] An exemplary scheme of a method starting with step e2) according to the second embodiment is shown in
[0047] In a third embodiment, the present invention relates to cocoa or chocolate beverages manufactured by the method according to the first and second embodiments described above, respectively. The cocoa and chocolate beverages are characterized by excellent organoleptic properties and high contents of nutritionally valuable components when compared to conventionally produced cocoa-based beverages.
[0048] A fourth embodiment of the present invention is defined by the use of a cocoa powder for the preparation of a cocoa or chocolate beverage, wherein the cocoa powder is obtained by a method comprising the separation of a water phase (heavy phase) and a solid phase from an aqueous suspension of wet ground cocoa beans, and recovering the cocoa powder from the solid phase. The use according to the invention enables production of cocoa or chocolate beverages with surprisingly rich flavor and high preserved contents of natural cocoa ingredients despite the pre-extraction with water.
[0049] Preferably, the cocoa powder used according to the fourth embodiment of the invention is prepared by a method comprising the separation of an aqueous suspension of wet ground cocoa beans or nibs into three phases, i.e. a water phase (heavy phase), a fat phase (light phase) and a solid phase, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising the cocoa powder and water. In embodiments, said method may further comprise the steps of: a) adding water to cocoa beans or nibs to form a suspension; b) wet grinding said suspension; c) subjecting said suspension to a heat treatment at a temperature of 70° C. or less; d) separating the suspension into a water phase (heavy phase), a fat phase (light phase) and a solid phase, said fat phase comprising cocoa butter as a major component and solids and/or water as minor components and said solid phase comprising cocoa powder and water; and e) separating at least cocoa powder from the solid phase. Especially preferred methods of cocoa powder preparation are described with respect to the first and second embodiments above.
[0050] In a fifth embodiment, the present invention relates to an instant cocoa powder obtained by instantizing the cocoa powder separated in step e) of the method according to the first embodiment or the comminuted chocolate in step e5) of the method according to the second embodiment to obtain the instant cocoa powder.
[0051] The wording “instantizing”, as used herein, denotes any processing step which enhances solubility and/or dispersibility of the cocoa/chocolate powder. Suitable methods include, but are not limited to agglomeration techniques such as e.g. steam agglomeration, fluidized bed agglomeration, freeze drying agglomeration, thermal agglomeration or spray drying. In preferred embodiments, instantization is performed starting with mixtures comprising the cocoa/chocolate powder, a hydrophilic agent (e.g. sugars selected from water-soluble monosaccharides, disaccharides, polysaccharides and mixtures thereof; polyols selected from sorbitol, glycerol, erythritol, maltitol, isomalt, mannitol, lactitol, threitol, arabitol, ribitol and xylitol) and an emulsifying agent (e.g. lecithin), optionally in a blend with other additives, which may be selected from bulking agents, aromas, milk solids, coloring agents, vitamins, polyphenols (including polyphenolic powder extracted from at least the water phase), nutraceuticals, and stabilizing agents (e.g., maltodextrin or cellulose-based stabilizers as those disclosed in U.S. Pat. No. 4,980,193 A or U.S. Pat. No. 4,311,717 A), for example. When using such mixtures, it may be preferable that the components are not added during the preparation of the cocoa/chocolate powder. Preferably, the cocoa/chocolate powder used for instantization has an average particle size of 2 to 100 μm, more preferably of 5 to 50 μm.
[0052] Once given the above disclosure, many other features, modifications, and improvements will become apparent to the skilled artisan.