APPARATUSES FOR PRODUCING OPTICAL EFFECT LAYERS
20170232727 · 2017-08-17
Inventors
- Evgeny Loginov (Renens, CH)
- Mathieu Schmid (Lausanne, CH)
- Claude-Alain Despland (Prilly, CH)
- Pierre Degott (Crissier, CH)
- Edgar Muller (Lausanne, CH)
Cpc classification
B05D5/065
PERFORMING OPERATIONS; TRANSPORTING
B05D3/207
PERFORMING OPERATIONS; TRANSPORTING
B41F19/005
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
The apparatus and methods of the present disclosure relate to devices comprising spinning magnets driven by electric motors for use with printing or coating equipment. These devices and methods are for orienting magnetic or magnetisable pigment particles in an unhardened coating composition on a substrate. Specifically, these devices and methods are for producing optical effect layers. The apparatus comprises a holder, onto which is mounted a motor and a permanent magnet assembly. The motor is configured to spin the permanent magnet assembly. The holder is configured to be removably fixed to a base of a rotating magnetic cylinder (RMC) or a flatbed printing unit.
Claims
1. An apparatus for producing an optical effect layer comprising: a holder, the holder having mounted thereto: a motor; and a permanent magnet assembly, wherein the motor is configured to spin the permanent magnet assembly, wherein the holder is configured to be removeably fixed to a circumferential mounting groove of a rotating magnetic cylinder or a mounting recess of a flatbed printing unit, and wherein the permanent magnet assembly is removably fixed to the holder.
2. The apparatus of claim 1 further comprising a support configured to be removeably fixed to the holder, wherein the support comprises a cavity.
3. The apparatus of claim 1, wherein the motor comprises a rotor part and a stator part, wherein the rotor part further comprises a recess, and the permanent magnet assembly is removeably coupleable to the recess via a rotation transmission shaft.
4. The apparatus of claim 1, wherein the motor comprises a rotor part and a stator part, and wherein the rotor part disposed within the cavity of the support and the stator part is located external of the support and electromagnetically coupled to the rotor part.
5. The apparatus of claim 4, wherein a ring shaped element that interacts with the magnetic field of the rotor part is disposed between the permanent magnet assembly and the rotor part.
6. The apparatus of claim 2, wherein the permanent magnet assembly is fixed to the support by a bearing to allow for relative rotation therebetween.
7. The apparatus of claim 6, wherein the bearing is a Conrad-type bearing.
8. A rotating magnetic cylinder comprising at least one of the apparatuses of claim 1 mounted to the rotating magnetic cylinder through the holder.
9. A flatbed printing unit comprising at least one of the apparatuses of claim 1 mounted to the flatbed printing unit through the holder.
10. A method of making an optical effect layer on a substrate, the method comprising: providing a substrate carrying a wet coating composition comprising magnetic or magnetizable pigment particles; providing an apparatus according to claim 1; orienting the magnetic or magnetizable pigment particles aggregately by way of a rotating magnetic field produced by spinning the permanent magnet assembly with the motor to produce the optical effect layer; and hardening the coating composition.
11. A method of modifying an existing rotating magnetic cylinder or a flatbed printing unit having non-spinneable permanent magnet assemblies, the method comprising removing one or more non-spinneable permanent magnet assemblies from the rotating magnetic cylinder or the flatbed printing unit and replacing them with one or more spinneable permanent magnet assemblies, characterized wherein the one or more spinneable petinanent magnet assemblies are removeably fixed to a circumferential mounting groove of the rotating magnetic cylinder or a mounting recess of the flatbed printing unit.
12. A method for protecting a security item, such as a banknote, comprising the steps of: i) applying a coating composition comprising magnetic or magnetizable pigment particles to a substrate; ii) exposing the coating composition to a rotating magnetic field produced by the spinning permanent magnet assembly of the apparatus of claim 1 to substantially orient at least part of the magnetic or magnetic pigment particles aggregately to produce an optical effect layer; iii) hardening the coating composition so as to fix the magnetic or magnetizable pigment particles in a substantially oriented state or oriented state.
13. A method of making an optical effect layer on a substrate, the method comprising: providing a substrate carrying a wet coating composition comprising magnetic or magnetizable pigment particles; providing an apparatus according to claim 8; orienting the magnetic or magnetizable pigment particles aggregately by way of a rotating magnetic field produced by spinning the permanent magnet assembly with the motor to produce the optical effect layer; and hardening the coating composition.
14. A method of making an optical effect layer on a substrate, the method comprising: providing a substrate carrying a wet coating composition comprising magnetic or magnetizable pigment particles; providing an apparatus according to claim 9; orienting the magnetic or magnetizable pigment particles aggregately by way of a rotating magnetic field produced by spinning the permanent magnet assembly with the motor to produce the optical effect layer; and hardening the coating composition.
15. A method for protecting a security item, such as a banknote, comprising the steps of: i. applying a coating composition comprising magnetic or magnetizable pigment particles to a substrate; ii. exposing the coating composition to a rotating magnetic field produced by the spinning permanent magnet assembly of an apparatus of claim 8 to substantially orient at least part of the magnetic or magnetic pigment particles aggregately to produce an optical effect layer; iii. hardening the coating composition so as to fix the magnetic or magnetizable pigment particles in a substantially oriented state or oriented state.
16. A method for protecting a security item, such as a banknote, comprising the steps of: i. applying a coating composition comprising magnetic or magnetizable pigment particles to a substrate; ii. exposing the coating composition to a rotating magnetic field produced by the spinning permanent magnet assembly of an apparatus of claim 9 to substantially orient at least part of the magnetic or magnetic pigment particles aggregately to produce an optical effect layer; iii. hardening the coating composition so as to fix the magnetic or magnetizable pigment particles in a substantially oriented state or oriented state.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DETAILED DESCRIPTION
Definitions
[0093] The following definitions clarify the meaning of the terms used in the description and in the claims.
[0094] As used herein, the indefinite article “a” indicates one as well as more than one and does not necessarily limit its referent noun to the singular.
[0095] As used herein, the term “about” means that the amount, value or limit in question may be the specific value designated or some other value in its neighborhood. Generally, the term “about” denoting a certain value is intended to denote a range within ±5% of the value. For example, the phrase “about 100” denotes a range of 100±5, i.e. the range from 95 to 105. Generally, when the term “about” is used, it can be expected that similar results or effects according to the invention can be obtained within a range of ±5% of the indicated value. However, a specific amount, value or limit supplemented with the term “about” is intended herein to disclose as well the very amount, value or limit as such, i.e. without the “about” supplement.
[0096] As used herein, the term “and/or” means that either all or only one of the elements of said group may be present. For example, “A and/or B” shall mean “only A, or only B, or both A and B”. In the case of “only A”, the term also covers the possibility that B is absent, i.e. “only A, but not B”.
[0097] The term “comprising” as used herein is intended to be non-exclusive and open-ended. Thus, for instance a coating composition comprising a compound A may include other compounds besides A. However, the term “comprising” also covers, as a particular embodiment thereof, the more restrictive meanings of “consisting essentially of” and “consisting of”, so that for instance “a coating composition comprising a compound A” may also (essentially) consist of the compound A.
[0098] The term “aggregately” is used to indicate that, upon the influence of an external magnetic field, a sufficient number of magnetic or magnetizable pigment particles of the wet and not yet hardened composition are oriented along a field line at the same time in order to establish a visual effect. Preferably, this sufficient number is around 1000 or more pigment particles being oriented along said field line at the same time. More preferably, this sufficient number is around 10000 or more pigment particles being oriented along said field line at the same time.
[0099] As used herein, the term “wet coating” means an applied coating, which is not yet hardened, for example a coating in which the contained magnetic or magnetizable pigment particles are still able to change their positions and orientations under the influence of external forces acting upon them.
[0100] The term “coating composition” refers to any composition which is capable of forming a coating, such as an optical effect layer on a solid substrate and which can be applied e.g. by a printing method.
[0101] The term “optical effect layer (OEL)” as used herein denotes a layer that comprises oriented magnetic or magnetizable pigment particles and a binder, wherein the orientation and position of the magnetic or magnetizable pigment particles are oriented by a magnetic field, then subsequently, simultaneously or partially simultaneously fixed in their orientation and position through hardening. The term “optical effect layer” (OEL) refers either to the layer comprising the oriented magnetic or magnetizable pigment particles (i.e. after the orientation step) or to the layer comprising the oriented magnetic or magnetizable pigment particles frozen in their orientation and position (i.e. after the hardening step).
[0102] The term “magnetic axis” or “South-North axis” denotes a theoretical line connecting the South and the North pole of a magnet and extending through them. These terms do not include any specific direction. Conversely, the term “South-North direction” and S4N on the figures denote the direction along the magnetic axis from the South pole to the North pole.
[0103] The term “spin”, “spinning” or “spinneable” refers to the rotation of the spinning permanent magnet assembly (PMA) described herein, regardless of its rotation frequency.
[0104] The term “substantially parallel” refers to deviating not more than 20° from parallel alignment and the term “substantially perpendicular” refers to deviating not more than 20° from perpendicular alignment.
[0105] The term “security element” or “security feature” is used to denote an image or graphic element that can be used for authentication purposes. The security element or security feature can be overt and/or covert.
DETAILED DESCRIPTION OF THE INVENTION
[0106] The present invention concerns particular apparatuses for making OELs with the help of spinning permanent magnet assemblies (PMA) (6). The apparatuses described herein are suitable to be used in, or in conjunction with, or to be part of a printing or coating equipment. In particular the apparatuses described herein may be comprised in a rotating magnetic cylinder (RMC) of a sheetfed or webfed printing or coating equipment used for orienting magnetic or magnetizable pigment particles in a coating composition applied to a substrate, or in a flatbed printing unit with the same aim.
[0107] A used herein, the term “rotating magnetic cylinder” (RMC) refers to the part of a high-speed continuous printing press that serves to magnetically orient the magnetic or magnetizable pigment particles, thus producing an optical effect layer (OEL).
[0108] According to one embodiment depicted in
[0109] As used herein, “stator part” and “stator” may be used indiscriminately to describe the same technical element. This also applies to “rotor part” and “rotor”.
[0110] According to another embodiment depicted in
[0111] According to the embodiments described in
[0112] If the apparatus of the invention is part of a rotating magnetic cylinder (RMC), the bottom part of the holder (1a, 1b) is curved according to the curvature radius of the circumferential mounting groove of the rotating magnetic cylinder (RMC).
[0113] Preferably, the holder (1a, 1b) is made from one or more non-magnetic materials selected from the group consisting of low conducting materials, non-conducting materials and mixtures thereof, such as for example engineering plastics and polymers, titanium, titanium alloys and austenitic steels (i.e. non-magnetic steels). Engineering plastics and polymers include without limitation polyaryletherketones (PAEK) and its derivatives polyetheretherketones (PEEK), poletherketoneketones (PEKK), polyetheretherketoneketones (PEEKK) and polyetherketoneetherketoneketone (PEKEKK); polyacetals, polyamides, polyesters, polyethers, copolyetheresters, polyimides, polyetherimides, high-density polyethylene (HDPE), ultra-high molecular weight polyethylene (UHMWPE), polybutylene terephthalate (PBT), polypropylene, acrylonitrile butadiene styrene (ABS) copolymer, fluorinated and perfluorinated polyethylenes, polystyrenes, polycarbonates, polyphenylenesulfide (PPS) and liquid crystal polymers. Preferred materials are PEEK (polyetheretherketone), POM (polyoxym ethylene), PTFE (polytetrafluoroethylene), Nylon® (polyamide) and PPS. Titanium-based materials have the advantage of excellent mechanical stability and low electric conductivity. The holder may however also be of aluminum or aluminum alloys which have the advantage of being easily worked
[0114] According to the embodiments described in
[0115] The fixation system of the support (3a, 3b) to the holder (1a, 1b) may comprise any form of releasable threadable fixation or any other form of mechanical fixation. In an embodiment, the support (3a, 3b) is fixed to the holder (1a, 1b) through a rotating cam placed vertically into the sidewalls of the holder (1a, 1b), the rotating cam being rotatable such that the cam surface, when rotated, may fit into a longitudinal notch carved into the side of the support (3a, 3b). This fixation system ensures a fast exchange of the support (3a, 3b) comprising the permanent magnet assembly (PMA) (6) as well as a high reliability under working conditions.
[0116] Preferably, the motor (2a, 2b+2c) is an electric motor.
[0117] Suitable electric motors are either DC (direct current) or AC (alternating current) motors. DC motors can be categorized into brush-type DC motors and brushless DC motors (hereafter referred to as BLDC motors). As used herein, the terms “brushless DC motor” and “BLDC motor” refer to electric motors powered by direct current and possessing a stator bearing magnet-wire coils and a rotor bearing permanent magnets. The current is addressed to the magnet-wire coils in the required sequence through a current control unit (CCU), hence the adjective “brushless”. In brush-type DC motors, the rotor carries electric coils which are addressed with current through a mechanical commuter and gliding carbon brush contacts. In brushless DC motors, which are preferred due to the absence of gliding electric contacts, the coils are part of the stator, and the commutation of the electric current in the coils is performed with the help of an electronic circuit.
[0118] According to one embodiment, the electric motor described herein is a BLDC motor, said BLDC motors can be subdivided into a) cup- or shell-type BLDC motors, where the rotor is internal and the stator is external, and b) disc-shaped (or “pancake”) BLDC motors, where the stator is internal and the rotor is external. There are also switched reluctance motors (hereafter referred to as SR motors). In SR motors, the permanent magnets of the rotor are replaced by poles made of magnetizable material, like pure iron or silicon iron (e.g. electrical steel).
[0119] According to one embodiment, the electric motor described herein is a disc-shaped BLDC motor. Disc-shaped BLDC motors are particularly preferred due to their high torque-to-weight and size ratio.
[0120] The rotor also comprises a central axle (16), designed to fit into the rotational bearing (13) of the stator, such that the stator can be located inside the bell-shaped rotor, having a gap distance of the order of 1 mm or less, preferably 0.3 to 1 mm, between the poles (11) of the stator and the multipole magnet (15) of the rotor.
[0121] Other embodiments for the BLDC motors are possible, the limitations being the restricted physical space available in the apparatus of the invention described herein and the ability to provide a high torque at low rotation frequency while being smooth and silent in operation.
[0122] In the embodiments described in
[0123] The current control unit (CCU) may be of a “static” (i.e. fixed frequency) or preferably of a “dynamic” (i.e. adaptive) type. Static CCUs drive the winding assembly with a “rotating” polyphase (in particular triphase) current of fixed frequency. In conjunction with the rotor of the electric motor (2a, 2b+2c), this results in a synchronous motor, which has the tendency of losing synchronization (i.e. “falling off”) under load. More elasticity is provided by “dynamic” current control units, which sense the position of the rotor of the electric motor (2a, 2b+2c) and address the winding assembly with electric current accordingly. Such motor resists breaking attempts and starts without problems from stand.
[0124] The current control unit (CCU) may comprise a sensor assembly, said sensor assembly being able to sense an attribute of the magnetic field of the rotor of the electric motor (2a, 2b+2c), e.g. its intensity or another indicator of its rotational position. The current control unit (CCU) comprises a controller (e.g. a processor or control circuitry) configured to use the sensed attribute to correspondingly address the winding assembly of the stator of the electric motor (2a, 2b+2c) with electrical current. In a particular embodiment, the controller implements a control loop based on the sensed attribute to control the spinning frequency of the rotor of the electric motor (2a, 2b+2c) at a fixed value. The sensor assembly may comprise one or more sensors. Preferably, the number of sensors matches the number of phases of the winding assembly. The one or more sensors may be Hall effect sensors.
[0125] In another embodiment, the coils of the winding assembly of the stator of the motor (2a, 2b+2c) may themselves be used as the sensors of the position of the rotor, through an evaluation of the induced voltage produced at them (sensorless motor control via back-EMF). As used herein, the term “back-EMF” refers to the back-electromotive force, or counter-electromotive force which is the voltage induced in the magnet-wire coils of the stator by the spinning rotor. The induced voltage is opposite to the voltage applied by the current control unit (CCU); it progressively counteracts the current flow through the motor at higher spinning frequency. For sensorless motor control a motor in “Star-configuration” is needed. Such motor has 4 connections (U, V, W and Common). Two of the three phases (U,V and W) are addressed with current in the required sense (+ − or − +), and the back-EMF generated between the third phase (W) and the common connector (Com) is measured; it may have a positive, zero, or negative value, depending on the position of the rotor. A controller evaluates the back-EMF and determines thereof the next pair of phases to be addressed and the sense of the electric current. The scheme of such a sensorless motor controller is given in
[0126] The current control unit (CCU) may be configured to apply a phase-shifted alternating current (e.g. sinusoidal) to the magnet-wire coils of the winding assembly or the current control unit (CCU) may be configured to apply a phase-shifted current to the magnet-wire coils of the winding assembly in a square wave form, in a trapezoidal form or in another form. In particular, the current control unit (CCU) may be configured to selectively and sequentially turn on and off the magnet-wire coils and repeat this in sequence to generate a rotating magnetic field.
[0127] As shown in
[0128] The permanent magnet assembly (PMA) (6) of the apparatus described herein comprises one or more permanent magnets (M1, M2, M3, . . . Mn). When the permanent magnet assembly (PMA) comprises more than one permanent magnets, the South-North direction of each of the permanent magnets (M1, M2, M3, . . . Mn) may be arranged in any relative orientation to each other, and the permanent magnets may be made of the same magnetic material or of different magnetic materials.
[0129] When the permanent magnet assembly (PMA) (6) comprises two or more permanent magnets (M1 and M2, M3, . . . Mn), the two or more permanent magnets are preferably disposed in a mechanically symmetric arrangement with respect to the spinning axis such that the permanent magnet assembly is mechanically balanced when spinning. Otherwise, balancing weights made of a non-magnetic material may also be used to allow for a balanced running while spinning the permanent magnet assembly (PMA) (6). On the other hand, the two or more permanent magnets may be magnetically symmetric or magnetically non-symmetric with respect to the spinning axis of the permanent magnet assembly.
[0130] According to a first preferred embodiment of the permanent magnet assembly (PMA) (6), and as shown in
[0131] According to a second preferred embodiment, the permanent magnet assembly (PMA) (6) is a single bar dipole permanent magnet having its South-North direction substantially parallel to the substrate/support surface. The visual effect is the same as shown in
[0132] According to a third preferred embodiment, the permanent magnet assembly (PMA) (6) comprises an even or an odd number of n bar dipole permanent magnets (n=1 . . . N, N≦2) aligned such as to correctly balance rotational inertia, their respective South-North direction being substantially parallel to the substrate/support surface. If n is an even number, the South-North direction of the first permanent magnet (n=1) is collinear to the South-North direction of the last permanent magnet (n=N), the South-North direction of the second permanent magnet (n=2) is collinear to the South-North direction of the penultimate permanent magnet (n=N−1), and so on, such that the South-North direction of the n.sup.th permanent magnet is collinear to the South-North direction of the (N-n+1).sup.th permanent magnet. If n is an odd number, the South-North direction of the permanent magnet disposed at the rotation axis (or, in other words, at the (N+1)/2.sup.th position) may be disposed such that its South-North direction is collinear to the South-North direction of the permanent magnets disposed just before and after it (or in other words, at the (N−1)/2.sup.th and at the (N+3)/2.sup.th positions, respectively), or opposite to their South-North direction.
[0133] According to a fourth preferred embodiment, the permanent magnet assembly (PMA) comprises an even number of n bar dipole permanent magnets (n=1 . . . N, N≦2, N/2∈Z, Z being the mathematical space containing all integer numbers) aligned such as to correctly balance rotational inertia, their South-North directions being substantially perpendicular to the substrate/support surface and antiparallel to each other. In other words, the South-North direction of the first permanent magnet (n=1) is antiparallel to the South-North direction of the last permanent magnet (n=N), the South-North direction of the second permanent magnet (n=2) is antiparallel to the South-North direction of the penultimate permanent magnet (n=N−1), and so on, such that the South-North direction of the n.sup.th permanent magnet is antiparallel to the South-North direction of the (N-n+1).sup.th permanent magnet.
[0134] The spinning permanent magnet assemblies (PMA) (6) of the first to fourth embodiments described hereabove give access, when integrated into the apparatus of the invention, to optical effects that are not accessible to non-spinneable permanent magnet assemblies (PMA) aimed at generating static magnetic fields.
[0135] Other embodiments of suitable spinning permanent magnet assemblies (PMA) (6) may be found in the co-pending European applications 13150693.3 and 13150694.1.
[0136] The one or more permanent magnets (M1, M2, M3, . . . Mn) comprised in the spinning permanent magnet assembly (PMA) (6) described herein are made of one or more strong magnetic materials. The one or more permanent magnets generate a sufficiently strong magnetic field to orient the magnetic or magnetizable pigment particles of the wet and not yet hardened coating composition described herein. Suitable strong magnetic materials are materials having a maximum value of energy product (BH).sub.max of at least 20 kJ/m.sup.3, preferably at least 50 kJ/m.sup.3, more preferably at least 100 kJ/m.sup.3, even more preferably at least 200 kJ/m.sup.3.
[0137] The one or more permanent magnets (M1, M2, M3, . . . Mn) comprised in the permanent magnet assembly (PMA) are preferably made of one or more sintered or polymer bonded magnetic materials selected from the group consisting of Alnicos such as for example Alnico 5 (R1-1-1), Alnico 5 DG (R1-1-2), Alnico 5-7 (R1-1-3), Alnico 6 (R1-1-4), Alnico 8 (R1-1-5), Alnico 8 HC (R1-1-7) and Alnico 9 (R1-1-6); hexaferrites of formula MFe.sub.12O.sub.19, (e.g. strontium hexaferrite (SrO*6Fe.sub.2O.sub.3) or barium hexaferrites (BaO*.sub.6Fe.sub.2O.sub.3)), hard ferrites of the formula MFe.sub.2O.sub.4 (e.g. as cobalt ferrite (CoFe.sub.2O.sub.4) or magnetite (Fe.sub.3O.sub.4)), wherein M is a bivalent metal ion), ceramic 8 (SI-1-5); rare earth magnet materials selected from the group comprising RECo.sub.5 (with RE=Sm or Pr), RE.sub.2TM.sub.17 (with RE=Sm, TM=Fe, Cu, Co, Zr, Hf), RE.sub.2TM.sub.14B (with RE=Nd, Pr, Dy, TM=Fe, Co); anisotropic alloys of Fe Cr Co; materials selected from the group of PtCo, MnAlC, RE Cobalt 5/16, RE Cobalt 14.
[0138] Alternatively, the spinning permanent magnet assembly (PMA) (6) may further comprise, in addition to the one or more permanent magnets (M1, M2, M3, . . . Mn), one or more parts made of one or more magnetizable materials (Y1, Y2, Y3, . . . Yn) (also referred in the art as yokes or cores, pole pieces or magnetizable parts), and/or one or more parts made of one or more non-magnetic materials. Said one or more magnetizable parts serve to direct and concentrate the magnetic field generated by the one or more permanent magnets of the spinning permanent magnet assembly (PMA) (6). The one or more magnetizable parts are made of one or more soft magnetic materials, i.e. materials having high magnetic permeability (expressed as Newton per square Ampere, N.Math.A.sup.−2) and low coercivity (expressed in Ampere per meter, A.Math.n.sup.−1) to allow for fast magnetization and demagnetization. The permeability is preferably between about 2 and about 1,000,000, more preferably between about 5 and about 50,000 N.Math.A.sup.−2 and still more preferably between about 10 and about 10,000 N.Math.A.sup.−2. The coercivity is typically lower than 1000 A.Math.m'. The one or more soft magnetic materials described herein include without limitation pure iron (from annealed iron and carbonyl iron), nickel, cobalt, soft ferrites like manganese-zinc ferrite or nickel-zinc ferrite, nickel-iron alloys (like permalloy-type materials), cobalt-iron alloys, silicon iron and amorphous metal alloys like Metglas® (iron-boron alloy), preferably pure iron and silicon iron (electrical steel), as well as cobalt-iron and nickel-iron alloys (permalloy-type materials), which all exhibit a high permeability and a low coercivity. In addition to the one or more permanent magnets (M1, M2, M3, . . . Mn) described herein, alone or combined with one or more parts made of one or more of magnetizable materials (Y1, Y2, Y3, . . . Yn), and/or one or more parts made of one or more non-magnetic materials, the spinning permanent magnet assembly (PMA) (6) described herein may comprise an engraved magnetic plate such as those disclosed for example in WO 2005/002866 A1 and WO 2008/046702 A1, so as to locally modify the magnetic field of the one or more permanent magnets. Engraving influences the magnetic field generated by the one or more permanent magnets (M1, M2, M3, . . . Mn) to produce the desired OEL. In an embodiment, the engraving represents at least part of the desired OEL and is reproduced in the magnetic or magnetizable pigment particles under the influence of the rotating magnetic field generated by the spinning permanent magnet assembly (PMA) (6).
[0139] The embodiments of the at least one or more permanent magnets (M1, M2, M3, . . . Mn), the optional one or more parts made of magnetizable material (Y1, Y2, Y3 . . . Yn), the optional one or more parts made of non-magnetic material are in no way limited to the particular embodiments described above. Depending on the desired OEL, other embodiments are possible, the only limitation being the physical space available for the spinning permanent magnet assembly (PMA) (6) within the apparatus of the invention describes herein.
[0140] The spinning permanent magnet assembly (PMA) (6) described herein may be built from a casing bearing one or more recesses or holes in which the one or more permanent magnets (M1, M2, M3, . . . Mn), the one or more parts made of one or more magnetizable materials (Y1, Y2, Y3, . . . Yn) when present, and the one or more parts made of one or more non-magnetic materials when present, are inserted in a disposition suitable to generate the desired OEL. The optional casing is made of one or more materials selected from the group consisting of non-magnetic materials, soft magnetic materials, permanent magnetic materials and mixtures thereof. Preferably, the optional casing is made of non-magnetic, low or non-conducting materials. They may be the same as used to build the holder (1a, 1b), the support (3a, 3b) and the magnet holder (5a, 5b), or a different material selected from the same group. Preferably, the optional casing has the external shape of a disc or of a regular polygon, in order to correctly balance the mechanical forces while spinning. Alternatively, the optional casing may take the shape of an irregular polygon or of any irregular body and the mechanical balance may be established by balancing weights.
[0141] As shown in
[0142] In one embodiment depicted in
[0143] In another embodiment depicted in
[0144] Preferably, the magnet holder (5a, 5b) has the external shape of a disc or of a regular polygon, in order to correctly balance the mechanical forces while spinning.
[0145] Suitable materials for the magnet holder (5a, 5b) may be the same as used for the optional casing of the spinning permanent magnet assembly (PMA) (6), the holder (1a, 1b) and the optional support (3a, 3b), or a different material selected from the same group.
[0146] According to
[0147] Suitable ball bearings are selected from the group consisting of fill-slot bearings, in which the geometry of the cage constrains the balls in the radial direction but leave them freely move in the axial direction, and Conrad-type bearings, in which the balls are constrained in the axial and the radial directions, thus allowing them to withstand both radial and axial loads. Conrad-type bearing are preferred since the apparatus described herein is suitable to be installed in the circumferential mounting grooves of a rotating magnetic cylinder (RMC), the rotation of said rotating magnetic cylinder (RMC) generating strong gyroscopic forces inside the apparatus of the invention described herein.
[0148] Preferably, the ball bearings described herein are selected from the group consisting of metal bearings, hybrid metal-ceramic bearings and plastic bearings. In a metal construction, the cage, the races and the balls of the bearing are made from a metal or a metal alloy. Metallic materials or metal alloys include without limitation austenitic steels like stainless steel, aluminum, titanium, tungsten, brass and copper. In a hybrid metal-ceramic bearing, the cage and the races of the bearing are made from metal, usually stainless steel or titanium, and the balls are made from a ceramic material. Commonly used ceramic materials include without limitation aluminum oxide (corundum), silicon nitride, silicon carbide, tungsten carbide, and silicon oxide (glass), from which silicon nitride is particularly preferred. In a plastic bearing, the cage and the races are made from the same plastic material, and the balls are made from the same or from a different material. Suitable plastics for making the cage and the races of the bearing include without limitation polyamides (like Nylon®), phenolic resins (like phenol-formaldehyde or Bakelite®), polyacetals (also known as POM, i.e. polyoxymethylenes), polypropylene, polyethylene, perfluorinated polyethylene (like PTFE or Teflon®), and suitable materials for making the balls may be the same as used for the cage and the ring, or may include other materials, like glass.
[0149] With the aim of reducing friction inside the bearing, lubricating agents may be used. Such lubricating agents include without limitation mineral oils, vegetable oils, synthetic oils, greases, silicone greases and fluoropolymer greases.
[0150] According to one embodiment depicted in
[0151] In a preferred embodiment, the disc-shaped BLDC motor (2a) has a stator part facing down the holder (1a) and a rotor part facing away from it and surrounding the stator part, as depicted on
[0152] In another embodiment, the disc-shaped BLDC motor (2a) has a rotor part facing down the holder (1a) and a stator part facing away from it, the lower rotor part being equipped with a shaft that goes through the upper stator part and is removeably connected to the shaft's coupling end of the magnet holder as previously described. The disc-shaped BLDC motor (2a) may possess one central rotor part and two stator parts, one facing down the holder (1a) and the other facing away from it. In such a case, the rotor part is equipped with a shaft that goes through the upper stator part and is removeably connected to the shaft's coupling end of the magnet holder (5a) as previously described.
[0153] In another embodiment, the disc-shaped BLDC (2a) motor is a motor of the type used in CD or DVD drives, which are designed to supply high torque in small mechanical dimensions. The construction of this motor is analogous to the motor depicted in
[0154] In a particular embodiment of the bearing of the disc-shaped BLDC motor (2a), the bearing is of a hybrid, thin-section, large-diameter Conrad type and is fitted at the outer periphery of the rotor. This type of bearings usually comprises a cage and races made of stainless steel or titanium, and balls made of silicon nitride or another ceramic material. This embodiment may be particularly advantageous when the holder (1a) comprises a central fixation system (standard screw, Allen screw or bolt) which must remain accessible to removeably fix the holder (1a) in the circumferential mounting groove of a rotating magnetic cylinder (RMC) or in the mounting recess of a flatbed printing unit. In such a case, the stator part of the disc-shaped BLDC motor (2a) comprises a central hole to give access to the fixation system. The diameter of the hole is between 5 mm and 20 mm, preferably between 7 mm and 15 mm, even more preferably between 8 mm and 12 mm.
[0155] The current control unit (CCU) has a configuration that depends on the motor's construction. It is positioned on the same circuit board as the motor (2a) or on a separate board.
[0156] In the embodiment depicted in
[0157] In such a case, the recess of the rotor preferably has a square, triangular, polygonal or regular polygonal shape and the shaft has a corresponding shape. The section of the recess of the rotor is chosen such as to allow easy access to the fixation system of the holder (1a) through the central hole of the stator.
[0158] In an embodiment, the bearing (4) spinneably holding the magnet holder (5a) and the spinning permanent magnet assembly (PMA) (6) may be placed at the outer periphery of the magnet holder (5a), thus allowing a more compact design but also slightly reducing the diameter of the spinning permanent magnet assembly (PMA) (6) and the area of the OEL.
[0159] According to one embodiment depicted in
[0160] The rotor (2c) comprises one or more parts made of a strong magnetic material such as those described hereabove for the one or more parts (M1, M2, M3 . . . Mn) of the permanent magnet assembly (PMA). Preferably the rotor (2c) comprises one or more NdFeB or CoSm magnets. The rotor (2c) magnetically interacts with the magnet-wire coils of the stator (2b) to set the permanent magnet assembly (PMA) (6) into spinning.
[0161] As used herein, the term “winding assembly” refers to a plurality of magnet-wire coils that are connected to provide the stator part of an electric motor. Preferably, the winding assembly comprises two or more magnet-wire coils.
[0162] The construction of the rotor (2c) depends on the configuration of the winding assembly of the stator (2b) and on the way it is addressed with electric current by the current control unit (CCU). To obtain a net torque from an electric motor, the interaction product of the magnetic fields generated by the winding assembly of the stator (2b) and the permanent magnets of the rotor (2c), integrated between zero and 27, must be different from zero.
[0163] The stator part (2b) is made of a pole piece comprising at least two or more iron cores, a winding assembly and an optional current control unit (CCU). Such an arrangement is depicted in
[0164] The winding assembly of the stator (2b) comprises two or more magnet-wire coils that are wound around the two or more cores of the pole piece of the stator (2b) using standard magnet wire having a copper or aluminum core and one or more insulating layers. Preferably, the magnet wire is of the “self-bonding” type, which means that the insulating layers are covered with a thermoplastic adhesive layer which can be activated by heat (hot air or oven) or by appropriate solvents. This allows the production of self-standing magnet-wire coils through a simple baking or solvent exposure after their winding onto an appropriate form.
[0165] The wires of the winding assembly of the stator (2b) are connected to an external current control unit (CCU). Preferably, the wires of the winding assembly of the stator are interconnected to form a 3-phase motor (U, V, W+Common) circuit of the “star” (or “Y”) or “delta” type, as depicted in
[0166] The current control unit (CCU) is preferably disposed close to the stator part (2b) of the electric motor, e.g. on the same circuit board, or on a separate board.
[0167] The gap distance between the rotor (2c) and the magnet-wire coils of the stator (2b) should be as small as possible to maximize the magnetic flux between the stator (2b) and the rotor (2c). Typically, said gap distance has a value between 0.1 mm and 3 mm, preferably between 0.3 mm and 1 mm.
[0168] Since the spinning permanent magnet assembly (PMA) (6) and the rotor (2c) are very close to each other, a ring-shaped element (7 in
[0169] According to the embodiment of
[0170] In a preferred embodiment, the bearing (4) may be advantageously placed at the outer periphery of the magnetizable ring-shaped element (7), thus allowing for a more compact design without reducing the diameter of the spinning permanent magnet assembly (PMA). In this embodiment, a particularly preferred bearing is a hybrid Conrad-type ball bearing comprising a cage and races made of a non-magnetic, low-conducting metal like stainless steel or titanium, and ceramic balls like silicon nitride or silicon carbide.
[0171] The magnet holder (5b) carrying the spinning permanent magnet assembly (PMA) (6), the magnetizable ring-shaped element (7), the rotor (2c) and the bearing (4) is spinneably fixed to a hub of the cylindrical cavity of the support (3b). The hub may raise from the close bottom part of the support (3b) or coming down from the close upper part of the support (3b), which allows minimizing the gap between the rotor (2c) and the stator (2b). Alternatively, the hub may be fixed to both a close bottom part and a close upper part of the support (3b) to increase the robustness of the apparatus described herein.
[0172] As shown in
[0173] As shown in
[0174] The spinning frequency of the spinning permanent magnet assembly (PMA) (6) is preferably chosen such that it undergoes at least one complete revolution over the course of exposure of the magnetic or magnetizable pigment particles to the rotating magnetic field. The spinning permanent magnet assembly (PMA) (6) will spin at least once through a full revolution to ensure that a rotationally symmetric aggregate orientation of the magnetic or magnetizable pigment particles is produced to result in the desired OEL.
[0175] When the apparatus of the invention described herein is part of a rotating magnetic cylinder (RMC) for orienting magnetic or magnetizable pigment particles of the printed coating composition, the required spinning frequency depends on the printing speed of the printing or coating equipment comprising said rotating magnetic cylinder (RMC), on the position of the hardening device and on the construction of the spinning permanent magnet assembly (PMA) (6). The speed of rotation of the outer periphery of the rotating magnetic cylinder (RMC), and thus the speed of movement of the substrate in the machine direction, and the spinning frequency of the spinning permanent magnet assembly (PMA) (6) are set such that the spinning permanent magnet assembly (PMA) (6) performs at least one complete revolution) (360° while the part of the substrate carrying the coating composition is on the rotating magnetic cylinder (RMC) and hence exposed to the generated rotating magnetic field. The part of the coating composition exposed to the rotating magnetic field remains stationary relative to the rotating magnetic cylinder (RMC) to ensure the quality of the OEL. In an embodiment, the spinning permanent magnet assembly (PMA) (6) performs at least one complete revolution)(360° during the application of the rotating magnetic field to the magnetic or magnetizable pigment particles as the spinning permanent magnet assembly (PMA) (6) and the substrate moves in the machine direction at the same speed. For typical industrial printing speeds of at least 8000 sheets per hour, typically 8,000 to 10,000 sheets per hour, the required spinning frequency is preferably at least around 50 Hz, more preferably at least around 30 Hz, and even more preferably at least around 50 Hz.
[0176] When the apparatus of the invention described herein is part of a flatbed printing unit, the required spinning frequency of the spinning permanent magnet assembly (PMA) (6) depends on the printing speed (in sheets per hour) of said flatbed printing unit, on the position of the hardening device and on the construction of the permanent magnet assembly (PMA) (6). The spinning frequency of the spinning permanent magnet assembly (PMA) (6) is set such that the spinning permanent magnet assembly (PMA) (6) makes at least one complete revolution while the part of the substrate carrying the coating composition is on of the flatbed printing unit comprising the one or more apparatuses of the invention, and hence exposed to the generated rotating magnetic field. For typical industrial printing speeds of 100-300 sheets per hour, the spinning frequency required is preferably at least around 0.5 Hz, more preferably at least around 5 Hz, and even more preferably at least around 20.
[0177] The apparatus described herein has a surface to be brought in contact with, or close to, a substrate surface carrying a wet and not yet hardened coating composition comprising magnetic or magnetizable pigment particles. The substrate feeder feeds the substrate (under the form of a web or sheets) such as to expose the magnetic or magnetizable pigment particles dispersed in the wet and not yet hardened coating composition to the rotating magnetic field produced by the spinning permanent magnet assembly (PMA) (6). To this aim, the magnetic or magnetizable pigment particles must be brought into sufficiently close proximity to the rotating magnetic field such that the local field strength of the magnetic field is high enough to aggregately orient the magnetic or magnetizable pigment particles so as to produce the desired OEL. Preferably, the distance between the spinning permanent magnet assembly (PMA) (6) and the coating composition comprising the magnetic or magnetizable pigment particles is between 0.1 and 10 mm, preferably between 0.2 and 5 mm, more preferably between 0.5 and 3 mm.
[0178] The device is preferably built in such a way that the spinning axis z of the spinning permanent magnet assembly (PMA) (6) is substantially perpendicular to the substrate surface. A rotating magnetic field of a desired pattern is generated by the spinning permanent magnet assembly (PMA) (6). The rotating magnetic field acts on the magnetic or magnetizable pigment particles dispersed in the wet and not yet hardened coating composition to aggregately orient the particles so as to produce the desired OEL. Upon the exposure of the magnetic or magnetizable pigment particles to the rotating magnetic field, rotationally symmetric optical effects depending on the configuration of the spinning permanent magnet assembly (PMA) (6) are obtained. Examples of effects are disclosed in the co-pending European patent applications 13150694.1 and 13150693.3.
[0179] The rotating magnetic cylinder (RMC) comprising one or more apparatuses of the invention described herein is preferably part of a rotary, continuous printing press. The coating composition is applied by a printing process selected from the group consisting of screen printing, intaglio printing, rotogravure printing and flexography printing. Preferably, the coating composition is applied by a screen printing process.
[0180] WO 2008/102303 A1
[0181] Subsequently or partially simultaneously (as described in WO 2012/038531 A1) with the orientation of the magnetic or magnetizable pigment particles by the rotating magnetic field generated by the spinning permanent magnet assembly (PMA) (6) of the apparatus described herein, the coating composition comprising said pigment particles is hardened to thereby fix or freeze the magnetic or magnetizable pigment particles in the substantially oriented state or oriented state. By “partially simultaneously”, it is meant that both steps are partly performed simultaneously, i.e. the times of performing each of the steps partially overlap. In the context described herein, when hardening is performed partially simultaneously with the orientation step b), it must be understood that hardening becomes effective after the orientation so that the pigment particles orient before the complete hardening of the OEL.
[0182] Therefore, to ensure that the coating composition is hardened partially simultaneously with the orientation of the magnetic or magnetizable pigment particles provided by the one or more apparatuses of the invention described herein, the hardening device may be arranged along the path of the substrate above the rotating magnetic cylinder (RMC).
[0183] The flatbed printing unit comprising one or more apparatuses of the invention described herein is preferably part of a longitudinal, discontinuous printing press. The coating composition is applied by a printing process preferably selected from the group consisting of screen printing and intaglio printing. Preferably, the coating composition is applied by a screen printing process.
[0184] The press comprises a flat printing screen and a printing platen for receiving the substrate under the form of sheets, and a magnetic orienting unit comprising one or more apparatuses described herein (as described in
[0191] Further details regarding the process of printing and orienting magnetizable or magnetic pigment particles using a flatbed printing unit may be found in WO 2010/066838 A1.
[0192] Preferably, the coating composition is an ink or coating composition selected from the group consisting of radiation curable compositions, thermally drying compositions, oxidatively drying compositions, and combinations thereof. Particularly preferably, the coating composition is an ink or coating composition selected from the group consisting of radiation curable compositions. Radiation curing, in particular UV-Vis curing, advantageously leads to a rapid increase in viscosity of the coating composition after exposure to the curing radiation, thus preventing any further movement of the pigment particles and in consequence any loss of orientation after the magnetic orientation step.
[0193] According to one embodiment of the invention describes herein, a plurality of the apparatuses described herein, each one comprising a holder (1a, 1b), a motor (2a, 2b+2c), a permanent magnet assembly (PMA) (6) and, according to embodiments of the first aspect of the invention, a support (3a, 3b), may be removeably fixed adjacent to one another longitudinally and/or laterally in the mounting recesses of a flatbed screen printing machine, as described in WO 2010/066838 A1, or in circumferential mounting grooves of a rotating magnetic cylinder (RMC), as described in WO 2008/102303 A2. Each one of the plurality of apparatuses described herein is able to aggregately orient the magnetic or magnetizable pigment particles of the wet and not yet hardened coating composition according to the pattern defined by the spinning permanent magnet assembly (PMA) (6) and the optional engraved plate comprised in the lid, thereby creating a plurality of individual OEL's. The individual OEL's will be spaced, but adjacent to one another, along the width and the length of the substrate, according to the spacing and arrangement of the apparatuses described herein.
[0194] Optionally, a cover plate according to W02008/102303A2, made of a non-magnetic material such as austenitic steel, aluminum, titanium or an engineering plastic or polymer, may be used to cover the apparatuses of the invention described herein. This ensures that the surface of the rotating magnetic cylinder (RMC) is substantially uniform and that the sheets or web fed from the substrate feeder seamlessly transfer to the surface of the rotating magnetic cylinder (RMC). Advantageously, the cover plate may be provided with openings at the locations corresponding to the position of the apparatuses of the invention described herein.
[0195] The substrate feeder is configured to feed the sheets or web and the rotating magnetic cylinder (RMC) is configured to rotate in such a way that, as long as the portion of the substrate carrying the wet and not yet hardened composition is in contact with the rotating magnetic cylinder (RMC), it is stationary relative to the spinning permanent magnet assembly (PMA) (6). By the subsequent, partially simultaneous or partially simultaneous hardening of the coating composition comprising the oriented magnetic or magnetizable pigment particles, an array of individual OEL's is produced on the sheet or web.
[0196] Should the operator of the printing equipment want to produce other optical effects generated by static magnetic fields, due to the holder (1a, 1b) being removeably coupled to the base of the rotating magnetic cylinder (RMC) or the flatbed printing unit, it is possible to easily replace one or more spinning permanent magnet assemblies (PMA) (6) as described herein with one or more non-spinneable permanent magnet assemblies (PMA) as known in the art. It may also be possible to install one or more apparatuses described herein and one or more apparatuses comprising non-spinneable permanent magnet assemblies (PMA) on the same rotating magnetic cylinder (RMC) or on the same flatbed printing unit.
[0197] The methods and apparatuses described herein are particularly suitable for making optical effect layers in the field of security, cosmetic and/or decorative applications. According to one embodiment, the substrate described herein is a security document such as those described hereabove.
[0198] Also described herein are uses of the apparatus described herein for making an optical effect layer on the substrate, said substrate being preferably a security document.
[0199] Also described herein are methods for protecting a security document, said method comprising the steps of i) applying, preferably by a printing process described herein, the coating composition comprising magnetic or magnetizable pigment particles described herein on the substrate described herein, ii) exposing the coating composition to the rotating magnetic field of apparatuses described herein so as to aggregately orient at least a part of the magnetic or magnetizable pigment particles to produce rotationally symmetric optical effects, and iii) hardening the coating composition so as to fix the magnetic or magnetizable pigment particles in their adopted orientations and positions.
[0200] An aspect of the present invention relates to security documents comprising the OEL obtained by the apparatus of the invention described herein. Each security document may comprise more than one OELs, i.e., during the printing and orienting process, more than one OEL may be produced on the same sheet or security document.
[0201] Security documents include without limitation value documents and value commercial goods. Typical example of value documents include without limitation banknotes, deeds, tickets, checks, vouchers, fiscal stamps and tax labels, agreements and the like, identity documents such as passports, identity cards, visas, driving licenses, bank cards, credit cards, transaction cards, access documents or cards, entrance tickets, public transportation tickets or titles and the like, preferably banknotes, identity documents, right-conferring documents, driving licenses and credit cards. The term “value commercial good” refers to packaging materials, in particular for cosmetic articles, nutraceutical articles, pharmaceutical articles, alcohols, tobacco articles, beverages or foodstuffs, electrical/electronics articles, fabrics or jewellery, i.e. articles that shall be protected against counterfeiting and/or illegal reproduction in order to warrant the content of the packaging like for instance genuine drugs. Examples of these packaging materials include without limitation labels, such as authentication brand labels, tamper evidence labels and seals.
[0202] Alternatively, the OEL may be produced on an auxiliary substrate such as for example a security thread, security stripe, a foil, a decal, a window or a label and consequently transferred to a security document in a separate step.
EXAMPLES
[0203] All examples have been carried out by using the UV-curable screen printing ink of the formula given in Table 1 below.
TABLE-US-00001 TABLE 1 Epoxyacrylate oligomer 28% Trimethylolpropane triacrylate monomer 19.5% Tripropyleneglycol diacrylate monomer 20% Genorad 16 (Rahn) 1% Aerosil 200 ® (Evonik) 1% Speedcure TPO-L (Lambson) 2% Irgacure ® 500 (BASF) 6% Genocure EPD (Rahn) 2% BYK ®-371 (BYK) 2% Tego Foamex N (Evonik) 2% platelet-shaped 7-layer optically variable magnetic pigment 16.5% particles (*) (*) gold-to-green optically variable magnetic pigment particles of diameter d50 about 9.5 μm and thickness about 1 μm, obtained from JDS-Uniphase, Santa Rosa, CA.
Example 1
[0204] An apparatus according to the invention described herein was used to orient the optically variable magnetic pigments of the ink detailed in Table 1. Said apparatus comprised: [0205] i) a holder (depicted in
[0211] The disc-shaped BLDC motor iii) was fixed onto the base plate ii) and both were inserted into the holder i). The permanent magnet vi) was glued with an epoxy glue (UHU 30 min) onto the magnet holder v), which was removeably fixed onto the motor iii) via its “claws and spring” coupling mechanism. The U, V, W and Common connector pads of the base plate were connected to the motor driver iv) according to
[0212] A 25 mm×25 mm square sample was printed onto a fiduciary paper (Louisenthal) with the UV-curable screen printing ink of Table 1 with a laboratory screen printing device. The thickness of the printed layer was about 20 μm. While the ink was still in a wet and not yet hardened state, the apparatus described hereabove was placed on the rear face of the substrate, 3 mm below the printed area, and allowed to spin for a few seconds at an estimated spinning frequency of about 30 Hz. The ink was hardened while being in the magnetic rotating field of the apparatus by a 0.5 s exposure to an UV LED (Phoseon FireFly 395 nm) positioned at a distance of about 50 mm from the substrate above the coating composition.
[0213] The photographic picture of the resulting OEL, representing a portion of a sphere, is shown in
Example 2
[0214] An apparatus according to the invention described herein was used to orient the optically variable magnetic pigments of the ink detailed in Table 1. Said apparatus comprised: [0215] i) a holder (depicted in
[0224] The stator ii) was glued into the cylindrical cavity of the holder i) with an epoxy glue (UHU 30min). The support iv) comprising the permanent magnet assembly (PMA) ix) was inserted into the holder i) and maintained into place by the addition of friction force and magnetic interaction between the iron core of the stator ii) and the permanent magnets of the rotor vii). The stator ii) was externally powered with a laboratory power supply GW Instek GPS-4303 set at a voltage of 9V and driven via the motor controller iii).
[0225] A 25 mm×25 mm square sample was printed onto a fiduciary paper (Louisenthal) with the UV-curable screen printing ink of Table 1 with a laboratory screen printing device. The thickness of the printed layer was about 20 μm. While the ink was still in a wet and not yet hardened state, the apparatus hereabove was placed on the rear face of the substrate, 3 mm below the printed area, and allowed to spin for a few seconds at an estimated spinning frequency of about 15 Hz. The spinning axis of the permanent magnet assembly (PMA) was perpendicular to the substrate surface. The ink was hardened while being in the rotating magnetic field of the device by being exposed during 0.5 s to an UV LED (Phoseon FireFly 395 nm) positioned at a distance of about 50 mm from the substrate carrying the coating composition.
[0226] The photographic picture of the resulting OEL, representing a ring with a central bump, is shown in