PYROLYSIS SYSTEM AND METHOD OF USE
20220034505 · 2022-02-03
Inventors
Cpc classification
F23G5/442
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23G2205/121
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23G2205/18
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C10B53/07
CHEMISTRY; METALLURGY
A62D3/40
HUMAN NECESSITIES
F23G2201/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B09B3/00
PERFORMING OPERATIONS; TRANSPORTING
F23G2900/50201
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23G5/0273
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23G2209/281
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23G2204/204
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F23G5/10
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C10B47/26
CHEMISTRY; METALLURGY
F23G2201/80
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F23G5/027
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C10B53/07
CHEMISTRY; METALLURGY
F23G5/10
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A pyrolysis system and method of use is capable of continuously processing feedstock. The pyrolysis system has enclosed pyrolysis tubes heated by a heating means to pyrolyze feedstock. Conveying mechanisms such as augers transport the feedstock into and through the pyrolysis tubes. The pyrolysis tubes can be heated to a desired temperature range using a heat exchanger, such as a molten metal bath, or inductively heated using induction coils wrapped around the pyrolysis tubes. The feedstock is physically separated from the outside environment by the enclosed pyrolysis tubes. A dynamic feedstock plug is formed upstream of the pyrolysis tubes to prevent air and moisture from entering via the inlet of the pyrolysis tubes. An outlet section connected to the outlets of the pyrolysis tubes separates the gaseous and solid products of pyrolysis and permits removal of the products while preventing air and moisture from entering into the system.
Claims
1. A pyrolysis system for the continuous pyrolysis of feedstock and removal of products of the pyrolysis of feedstock to downstream equipment, comprising: one or more pyrolysis tubes configured to receive feedstock from one or more conveyors; heating means for heating the one or more pyrolysis tubes and pyrolyzing the feedstock therein; and an outlet section for receiving and directing the products of pyrolysis to the downstream equipment; wherein the pyrolysis tubes are substantially enclosed to prevent the feedstock and products of pyrolysis from leaving the pyrolysis tubes except via the outlet section.
2. The pyrolysis system of claim 1, wherein the one or more conveyors each have a first stage auger extending therethrough and operatively connected to a first drive mechanism configured to rotate the first stage auger for conveying the feedstock towards the one or more pyrolysis tubes.
3. The pyrolysis system of claim 1, further comprising one or more second stage augers extending through a respective one of the one or more pyrolysis tubes and operatively connected to a respective second drive mechanism configured to rotate the second stage auger for conveying the feedstock through the one or more pyrolysis tubes towards the outlet section.
4. The pyrolysis system of claim 1, wherein the one or more conveyors each comprise a radial constriction located towards an outlet end of the one or more conveyors for consolidating the feedstock and forcing air and water out therefrom.
5. The pyrolysis system of claim 1, wherein: the heating means comprises a heat exchanger having a heat exchange medium stored in a heat exchange chamber; one or more heat sources are configured to heat the heat exchange medium; and the one or more pyrolysis tubes are at least partially immersed in the heat exchange medium for receiving heat therefrom.
6. The pyrolysis system of claim 1, wherein: the one or more pyrolysis tubes are made at least partially of a ferromagnetic material; and the heating means comprises one or more induction coils wrapped around each of the one or more pyrolysis tubes and operatively connected to at least one AC power source configured to deliver a driving alternating current thereto for heating the one or more induction coils.
7. The pyrolysis system of claim 1, wherein the outlet section comprises a gas conduit for receiving gases of the products of pyrolysis and a solids collection portion for receiving solid residue of the products of pyrolysis.
8. The pyrolysis system of claim 7, wherein: the gas conduit comprises a one-way valve for permitting gases of the products of pyrolysis to exit the pyrolysis system while maintaining the substantially inert environment of the pyrolysis section; and the solids collection portion comprises a solids removal valve for permitting the solid residue to be removed while maintaining the substantially inert environment of the pyrolysis section.
9. A pyrolysis apparatus for the continuous pyrolysis of feedstock and removal of products of the pyrolysis of feedstock to an outlet section, comprising: one or more pyrolysis tubes configured to receive feedstock at an inlet end and direct the products of pyrolysis to the outlet section via an outlet end; and heating means for heating the one or more pyrolysis tubes and pyrolyzing the feedstock therein; wherein the pyrolysis tubes are substantially enclosed except at the inlet end and outlet end.
10. The pyrolysis system of claim 9, wherein: the heating means comprises a heat exchanger having a heat exchange medium stored in a heat exchange chamber; one or more heat sources are configured to heat the heat exchange medium; and the one or more pyrolysis tubes are at least partially immersed in the heat exchange medium for receiving heat therefrom.
11. The pyrolysis system of claim 10, wherein the heat exchange medium is a molten metal.
12. The pyrolysis system of claim 11, further comprising an inert gas stored in the heat exchange chamber for mitigating oxidation of the molten metal.
13. The pyrolysis system of claim 9, wherein: the one or more pyrolysis tubes are made at least partially of a ferromagnetic material; the heating means comprises one or more induction coils wrapped around each of the one or more pyrolysis tubes and operatively connected to at least one AC power source configured to deliver a driving alternating current thereto for inductive heating of the one or more induction coils.
14. The pyrolysis system of claim 13, wherein each of the one or more pyrolysis tubes have at least two induction coils of the one or more induction coils wrapped therearound, and each of the at least two induction coils are connected to a respective AC power source.
15. The pyrolysis system of claim 14, wherein each of the at least two pyrolysis tubes are axially separated by a thermal and magnetic insulator.
16. A method of continuously pyrolyzing feedstock and directing products of the pyrolysis of feedstock to an outlet section, comprising: receiving feedstock in one or more pyrolysis tubes; preventing the feedstock and products of pyrolysis from leaving the pyrolysis tubes except via the outlet section; and heating the one or more pyrolysis tubes to within a desired temperature range, for the feedstock, for pyrolyzing the feedstock therein.
17. The method of claim 16, further comprising permitting gases of the product of pyrolysis to exit via a gas conduit of the outlet section while preventing air and moisture from entering into the one or more pyrolysis tubes.
18. The method of claim 16, further comprising removing solid residue of the products of pyrolysis from the outlet section while preventing air and moisture from entering into the one or more pyrolysis tubes.
19. The method of claim 16, further comprising compressing the feedstock to form a plug upstream of the one or more pyrolysis tubes for preventing air and moisture from entering into the one or more pyrolysis tubes.
20. The method of claim 16, further comprising heating axial segments of each of the one or more pyrolysis tubes to a different temperature.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DESCRIPTION
[0055] With reference to
[0056] In embodiments, the pyrolysis system 2 is generally horizontally oriented, such that, while there may be inclined portions of the system 2, the feedstock 10 proceeds generally horizontally from the feed section 12 through the pyrolysis section 14 and into the outlet section 16.
[0057] With reference to
[0058] In embodiments, the feedstock 10 can be prepared before being loaded into the feed hopper 18, such as by shredding, grinding, and otherwise being broken down to smaller pieces for ease of conveyance and more efficient heat transfer thereto during pyrolysis. In order to more effectively pyrolyze tires, the tires can be shredded into “crumbs” so that they will fit inside the various components of the pyrolysis system 2. For example, with reference to
[0059] In the embodiment depicted in
[0060] The outlet end 30 of the conveyor 26 can have a feedstock consolidation means 40, such as a radial constriction/nozzle, configured to compress feedstock 10 passing therethrough. Such compression forces out residual water and/or air within the feedstock 10 and consolidates the feedstock 10 before it enters the pyrolysis section 14. In one aspect, it is desirable to remove water and air from the feedstock 10 to maintain a substantially inert environment within the downstream pyrolysis section 14 for more effective pyrolysis. Water and air removed from the feedstock 10 flows back towards the first end 28 of the conveyor 26 and can be evacuated via one or more removal ports 42 located upstream of the radial constriction/nozzle 40. Further, the compressed feedstock 10 forms a feedstock plug/door 41 that prevents air and moisture from entering into the one or more pyrolysis tubes 44 downstream, thus helping to maintain an inert environment therein.
[0061] Referring still to
[0062] The pyrolysis section 14 comprises one or more pyrolysis tubes 44 configured to receive feedstock 10 from the feed section 12. The pyrolysis tubes 44 are heated to within a desired temperature range using a heating means 46 to pyrolyze the feedstock 10 therein. It may be desirable to pyrolyze feedstock 10 within multiple pyrolysis tubes 44 as opposed to a single large pyrolysis tube 44 or kiln, as the multiple pyrolysis tubes 44 present a greater surface-area-to-unit-volume compared to a single pyrolysis tube 44 of the same volume, thus providing for more efficient heat transfer to the feedstock 10 therein. The pyrolysis tubes 44 are substantially enclosed, such that the only points of ingress and egress are at the inlets and outlets of the pyrolysis tubes 44, respectively. Confining the feedstock 10 within the pyrolysis tubes 44 along the entire length of the pyrolysis section 14 is advantageous, as the products of pyrolysis such as gases G and solid residue S are all displaced out the outlet end of the pyrolysis tubes 44 on a continuous basis as new feedstock 10 is introduced.
[0063] In an embodiment illustrated in
[0064] The heat exchanger 47 further comprises at least one heat source 52, such as an electric heater or burners, configured to heat the molten metal heat exchange medium 50 within the heat exchange/bath chamber 48 to the desired temperature range. Preferably, the heat source 52 is located toward the bottom of the heat exchange/bath chamber 48 so as to take advantage of convection currents to circulate and more evenly heat the molten metal heat exchange medium 50. In embodiments, a circulation mechanism 88, such as a circulation propeller 90 or similar device, can be located within the heat exchange/bath chamber 48 to more deliberately circulate the molten metal heat exchange medium 50 for more even heat distribution. One or more thermocouples 54 can be located in the heat exchange/bath chamber 48 to measure the temperature of the molten metal 50 heat exchange medium. In some embodiments, the pyrolysis tubes 44 can be made of steel or similar material with a ceramic coating to resist corrosion caused by the molten metal 50 heat exchange medium.
[0065] As shown in
[0066] As stated above, in embodiments, a second stage auger 38 can be located in each of the pyrolysis tubes 44 to convey feedstock 10 therethrough. The second stage auger 38 can be connected to, and in-line with, the first stage auger 36 so as to be driven by the same drive mechanism 34. In other embodiments, the second stage auger 38 can be radially spaced from the first stage auger 36 and driven by its own respective drive mechanism 34, or a common second stage drive mechanism 34, such as when multiple pyrolysis tubes 44 are configured to receive feedstock 10 from the feed section 12. For example, second stage augers 38 can extend from the outlet section 16 into each of the pyrolysis tubes 44, and the drive mechanisms 34 can be located toward the outlet ends of the pyrolysis tubes 44. High temperature and low pressure shaft seals can be incorporated at the point at which the second stage augers 38 pass into the outlet ends of the pyrolysis tubes 44. Gases G and particulate matter S produced from the pyrolysis of feedstock 10 are directed by the second stage augers 38 towards the outlet end of the pyrolysis tubes 44, which is in communication with the outlet section 16.
[0067] The outlet section 16 can comprise a gas conduit 60 and a solids collection portion 62. The gas conduit 60 is located towards an upper portion of the outlet section 16 and directs the evolved hot condensable and non-condensable gases G produced during the pyrolysis process to downstream equipment, such as cyclone separators, condensers, and the like (not shown), which process the evolved gases and separate any particulate matter that may have been carried therewith. These gases can be cooled to separate the non-condensable portion of the gases from the condensable gases. Non-condensable gases can be used to supplement fuel used by heat source 52 to heat the heat exchange/bath chamber 48, or can be incinerated or otherwise disposed of. The condensable gases can be processed further to produce commercial products such as low-sulphur gasoline, diesel gas, and synthetic gas. In some embodiments, a one-way valve, such as a check valve, can be located along the gas conduit 60 and configured to permit gases to exit the outlet section 16 towards downstream equipment, but prevent air from entering the outlet section 16 therethrough to maintain a substantially inert environment in the pyrolysis tubes 44. The solids collection portion 62 is located towards a lower portion of the outlet section 16 and is configured to receive particulates and other solid residue S produced by the pyrolysis process, such as in a collection chamber 66. The solids collection portion 62 can have a solids removal valve 64 configured to allow solid residue to be removed therefrom, such as into solids receptacle 67, for processing or disposal, while preventing air from entering the outlet section 16 therethrough to maintain a substantially inert environment in the pyrolysis tubes 44. For example, the solids removal valve 64 could be a rotary valve that functions as an airlock.
Inductive Heating
[0068] In an alternative embodiment, with reference to
[0069] The pyrolysis tubes 44 and/or the second stage augers 38 therein are made at least partially of a ferromagnetic material, for example steel, such that the magnetic field created by the driving electrical alternating current I flowing through the induction coils 70 generates an induced electrical alternating current in the pyrolysis tubes 44 and/or the second stage augers 38, thereby heating the pyrolysis tubes 44 and second stage augers 38 via induction heating. The induction coils 70 need not be in contact with the tubes 44 to generate and transmit heat thereto.
[0070] The number of induction coils 70 that are positioned around each pyrolysis tube 44 can depend upon the nature of the feedstock 10 to be pyrolyzed and the feed rate required for compete pyrolysis of the feedstock 10 to occur. For example, the number of induction coils 70, the coil configuration and/or the required heat input for pyrolysis are a function of the type of feedstock 10, the mass flow rate (i.e. feed rate) of the incoming feedstock 10, the specific heat capacity of the feedstock 10, the temperature differential between the feedstock 10 and the optimum pyrolysis temperature and/or optimum heating rate, as well as, the thermal/electrical conductivity of the pyrolysis tubes 44. The amount of induction heating available is a function of the number of induction coils 70, the current carrying capacity of the coils, the frequency of the alternating current power source and the amount of current and voltage being applied to the induction coils 70. The actual length of the pyrolysis tubes and the number of induction coils 70 and coil configuration will then be determined accordingly. Typically, the higher the feed rate, the more induction heating (i.e. induction coils) will be required.
[0071] In embodiments, the temperature along a pyrolysis tube 44 can be varied by utilizing multiple induction coils 70 axially spaced along the pyrolysis tube 44, each induction coil 70 connected to a corresponding AC power source 72. The induction coils 70 of a pyrolysis tube 44 can be thermally and magnetically isolated from adjacent induction coils 70 by a thermal/magnetic insulator 74, such as a ceramic insulator. Each AC power source 72 can provide a driving alternating current I of differing frequency, current, or voltage to its respective induction coil 70 to heat portions of the pyrolysis tube 44 corresponding to the induction coils 70 to different temperatures. Managing the heating of the pyrolysis tubes 44 in this manner provides greater control over, and improves the efficiency of, the pyrolysis process by allowing for variable and selectable pyrolysis temperatures along the length of each pyrolysis tube 44 for optimal pyrolysis of the feedstock 10. For example, the induction coils 70 closer to the inlet of a pyrolysis tube 44 can be configured to heat the pyrolysis tube 44 to a higher temperature to rapidly heat the feedstock 10 as it enters the pyrolysis tube 44, while induction coils 70 closer to the outlet can be configured to heat the pyrolysis tube 44 to relatively lower temperatures to maintain the temperature of the feedstock 10 therein, thereby optimizing the pyrolysis of the feedstock 10. The same effect could be achieved by adjusting the number of windings of the induction coils 70 connected in series to vary the density of the heating.
[0072] A reverse heating configuration can also be implemented to provide for a more gradual heating of the feedstock 10. In some embodiments, the second stage augers 38 can have ceramic insulator segments 77 juxtaposed to the thermal/magnetic insulators 74 (see
[0073] The inductive heating described above generates heat for the pyrolysis process directly in the pyrolysis tubes 44 and, in embodiments, also in the second stage auger 38, as opposed to the more indirect form of requiring heat to be transferred from the heat sources 52 to the heat exchange medium 50, by conduction from the heat exchange medium 50 to the pyrolysis tubes 44, and finally from the pyrolysis tube 44 to the feedstock 10, with losses occurring at each step. Direct heating of the pyrolysis tubes 44 via induction eliminates the need for an intermediate heat exchange medium 50 such as molten metal or hot gases, and heats the feedstock 10 from the outside via the pyrolysis tubes 44 as well as the inside via the auger 38. The above-described inductive heating allows for more efficient transfer of heat to the feedstock 10 than that afforded by prior art heating technologies, due to fewer losses occurring in the conversion of electrical energy supplied to the induction coils 70 to heat in the pyrolysis tubes 44 and augers 38, relative to the conduction of heat from a heat source 52 to the pyrolysis tubes 44 via a heat exchange medium 50.
[0074] In embodiments, as shown in
[0075] In order to increase the thermal efficiency of the heating process, an insulation layer 76, such as a layer of calcium silicate or insulating ceramic, may be installed between the pyrolysis tubes 44 and the induction coils 70. Such an insulation layer 76 will not only provide insulation to minimize heat loss back out from the pyrolysis tubes 44 toward the feed section 12, but it will also keep the induction coils 70 from being heated themselves by the radiant heat emanating from the pyrolysis tubes 44, thereby reducing the amount of cooling water that will be required to keep the induction coils 70 sufficiently cool. In embodiments, the insulation layer 76 can be applied to, or wrapped around, the surface of the pyrolysis tubes 44. In other embodiments, the insulation layer 76 can be applied to, or wrapped around, the induction coils 70.
[0076] Thermocouples 54 can be located at various locations on the pyrolysis tubes 44 to measure the temperature thereof, such that an operator can ensure that each section of the pyrolysis tubes 44 is maintained within a desired temperature range for pyrolysis.
Multiple Pyrolysis Streams
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Series Connection
[0079] In another embodiment, with reference to
Auger Configurations
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[0081] With reference to
[0082] In some embodiments, the second stage augers 38 or vanes 35 can have ceramic insulator segments 77 juxtaposed to the thermal/magnetic insulators 74 that may be placed along the pyrolysis tube 44, such that segments of the second stage augers 38 or vanes 35 are thermally and magnetically isolated and can be heated up to different temperatures by corresponding induction coils 70.
Operation
[0083] With reference to the exemplary embodiment shown in
[0084] In this embodiment, heat transfer is taking place between the molten metal heat exchange medium 50, pyrolysis tube 44 walls, and the feedstock 10 therein. Confining the feedstock 10 within pyrolysis tubes 44 for the entirety of the pyrolysis process provides an efficient method of transporting the feedstock 10 through the pyrolysis system 2, prevents contamination of the molten metal heat exchange medium 50 with feedstock/pyrolysis products and vice versa, and allows for the produced gases G and any residual solid material S to be transported through the pyrolysis section 14 on a continuous basis.
[0085] This technology is an improvement on conventional technology in that it allows for the continuous introduction of feedstock 10 into the pyrolysis system 2 and the removal of any particulate residue S that could remain after pyrolysis. The large surface-area-to-cross-sectional-area ratio provided by using multiple small-diameter pyrolysis tubes 44 permits more efficient heat transfer to the feedstock 10 relative to existing pyrolysis technologies, which expedites the pyrolysis process and thus increases throughput capacity.
[0086] Immaterial modifications may be made to the embodiments described herein without departing from the scope of the invention. The word “comprising” is used in its inclusive sense and does not exclude other elements being present. The indefinite article “a” before a component does not exclude more than one of the features being present. Each one of the individual features described herein may be used in one or more embodiments and is not, by virtue only of being described here, to be construed as essential to all embodiments as defined by the claims.