SEMICONDUCTOR LASER DEVICE STRUCTURES AND METHODS OF FABRICATION THEREOF
20220311206 · 2022-09-29
Inventors
Cpc classification
H01S5/2045
ELECTRICITY
H01S5/12
ELECTRICITY
H01S5/1082
ELECTRICITY
H01S5/34306
ELECTRICITY
H01S5/1237
ELECTRICITY
International classification
H01S5/028
ELECTRICITY
H01S5/026
ELECTRICITY
H01S5/10
ELECTRICITY
Abstract
Semiconductor device structures comprising laser diode cavities with at least one of a mode-selective filter and a phase-alignment element, and methods for their fabrication, are disclosed. An example device structure comprises a surface-etched grating distributed-feedback (SEG DFB) laser with a mode-selective reflector structure. The reflector structure is designed to provide higher pot feedback of the fundamental TE0 mode and suppression of higher order mode effects. The reflector structure may be a single interface (single facet) mirror type reflector comprising a spatially patterned reflector, or a multi-interface distributed Bragg reflector (DBR). A phase alignment element may be included to provide precise optical phase control. A photodetector for back-facet power monitoring may be included. A method of fabrication is disclosed, based on a self-aligned process in which DBR features are included on the same mask that is used for the DFB laser grating.
Claims
1-19. (canceled)
20. A device structure comprising a distributed feedback (DFB) laser diode comprising a surface-etched grating (SEG) supporting a fundamental optical mode, the DFB laser diode having etched front and back facets, wherein the back facet comprises a mode-selective structured reflector providing higher feedback of a fundamental mode TE0 compared to higher order modes.
21. The device structure of claim 20, wherein the mode-selective structured reflector is a phase-aligned mode-selective reflector structure spaced from teeth of the SEG by a phase-alignment region.
22. The device structure of claim 20, wherein the mode-selective structured reflector comprises a single interface reflector on the back-facet comprising a spatially patterned reflective coating on said back-facet that provides said higher feedback of the fundamental mode TE0 relative to higher order modes.
23. The device structure of claim 22, wherein the mode-selective reflector structure is a phase-aligned reflector structure wherein the single interface reflector comprises an etched trench defining the back-facet, and the back-facet is spaced from teeth of the SEG by a phase-alignment region.
24. The device structure of claim 23, wherein a sidewall of the trench defines the back-facet and the spatially patterned reflective coating comprises a high reflectivity coating in a region aligned to the TE0 mode and a lower reflectivity coating on other parts of the sidewall.
25. The device structure of claim 24, wherein the trench is one of: a rectangular trench, a trapezoidal trench, hexagonal trench, and trenches of other suitable geometric forms including curved forms.
26. The device structure of claim 20, wherein the mode-selective structured reflector comprises a multi-interface distributed Bragg reflector (DBR) structure defined by a plurality of etched and un-etched regions defining a series of trenches aligned to the back-facet, sidewalls of said trenches of the DBR structure comprising a dielectric coating that provides said higher feedback of the fundamental mode TE0 relative to higher order modes.
27. The device structure of claim 26, wherein the DBR structure is a phase-aligned DBR structure spaced from teeth of the SEG by a phase-alignment region.
28. The device structure of claim 27, wherein the trenches have a geometric form which is one of a rectangular trench, a trapezoidal trench, a hexagonal trench, and trenches of other suitable geometric forms including curved forms.
29. The device structure of claim 26, wherein the etched and unetched regions comprise a plurality of (2m+1)*λ/4 etched and not-etched sections, comprising 1 to 3 periods, where m=1 in air or other low index material, and 2 in semiconductor or other high index material.
30. The device structure of claim 20, further comprising a detector for back-facet power monitoring.
31. The device structure of claim 26, wherein the SEG DFB laser is a VC SEG DFB laser fabricated from an epitaxial layer structure comprising a plurality of semiconductor layers grown on a semiconductor substrate; the plurality of semiconductor layers comprising a first contact layer, a first cladding layer, a first separate confinement heterostructure, a multi-quantum well active gain region, a second separate confinement heterostructure, and a second cladding layer and a second contact layer; a surface-etched grating (SEG) comprising a set of periodic trenches defined along a top surface of a mesa etched through the plurality of semiconductor layers, the SEG forming a vertically coupled waveguide Bragg grating supporting a fundamental optical mode, wherein the first and second separate confinement heterostructures provide vertical optical confinement of the fundamental optical mode; and at least one layer of the plurality of semiconductor layers forms an aperture layer that provides lateral optical confinement of the fundamental optical mode and lateral confinement of current injection; and wherein etched regions of the DBR structure are etched through at least upper layers of said plurality of semiconductor layers.
32. The device structure of claim 31, wherein etched regions of the DBR structure are etched through layers of said plurality of semiconductor layers to the first cladding layer.
33. A method of fabricating a device structure comprising a SEG DFB laser and a phase-aligned mode-selective reflector structure, comprising: providing a substrate comprising an epitaxial layer structure for the SEG DFB laser; depositing a primary etch mask layer comprising one of more layers of etch mask materials; and patterning the primary etch mask layer in a single process step to define patterns of etch and not-etch regions for each of a plurality of phase-aligned structures, which comprise at least the SEG for the DFB laser, a phase-alignment region, and a mode-selective reflector structure; and processing the plurality of phase-aligned etched structures by a sequence of area selective masking and etching steps.
34. The method of claim 33, comprising performing an initial etch to an initial etch depth to define initial parts of each of the plurality of phase-aligned etched structures.
35. The method of one of claim 33, comprising: patterning a first area selective etch (SE) mask which exposes a first area of the primary etch mask comprising patterns for at least the SEG, phase alignment region and mode-selective reflector structure, and protects other areas of the primary etch mask; performing a first etch to a first etch depth defining the SEG and defining first depth etched/not-etched regions for the phase-alignment region and the mode-selective reflector structure; and if required, removing the first area selective etch mask; depositing and patterning a second area selective etch (SE) mask layer which protects the SEG and exposes areas of the primary etch mask comprising the phase-alignment region and the mode-selective reflector structure; performing a second etch to a second etch depth defining second depth etched/not-etched features of the phase-alignment region and the mode-selective reflector structure; and if required, removing the second area selective etch mask.
36. The method of claim 35, further comprising, for n≥3: depositing and patterning an n.sup.th selective etch (SE) mask layer; and performing an n.sup.th etch to a n.sup.th etch depth further defining features of the phase-alignment region and the mode-selective reflector structure; and if required, for n>3, repeating area selective masking and etching, until each of the plurality of phase-aligned etched structures for the SEG, the phase-alignment region and the mode-selective reflector structure, and any other phase-aligned etched structures are completed.
37. The method of claim 33, wherein the primary mask layer defines etch and not-etch regions for the mode-selective reflector comprising a trench for a single interface back facet reflector; and after steps comprising the first etch step and at least a second etch defining the mode-selective reflector comprising the trench, depositing a spatially patterned reflective coating on a sidewall of the trench defining the back-facet of the SEG DFB laser, the spatially patterned reflective coating comprising a first region of a high reflectivity coating that provides higher feedback to a fundamental TE0 mode relative to higher order modes of the SEG DFB laser, and other regions of the spatially patterned reflective coating having a lower reflectivity coating.
38. The method of claim 33, wherein the primary mask layer defines etch and not-etch regions for the mode-selective reflector comprising a series of trenches of a mode-selective DBR structure; and after steps comprising the primary etch step and at least a first selective etch defining the mode-selective reflector comprising the series of trenches, depositing a dielectric coating on sidewalls of the series of trenches to form a DBR structure that provides higher feedback to a fundamental TE0 mode relative to higher order modes of the SEG DFB laser.
39. The method of claim 33, wherein the primary mask layer further defines etch/not etch regions of a detector for back-facet power monitoring.
40. The method of claim 35, wherein the first area selective masking step and first etch defining the SEG is performed after the second etch forming the phase-alignment region and mode-selective reflector structure.
41-45. (canceled)
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
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[0062] VC SEG DFB lasers may be coupled with transition waveguides, mode converters, and/or spot size converters to reduce higher order mode effects, e.g. to suppress TE1 and TE2 modes, for reliable operation at ≥2.5 Gb/s. For example, VC SEG DFB laser structures with etched rear reflectors may be structured to be compatible with monolithically integrated multi-guide vertical integration.
[0063] However, operation under some conditions, e.g. without transition waveguides and spot size converters, may result in unacceptable multi-transverse mode operation. For some applications, it is desirable to operate this type of VC SEG DFB laser without transition waveguides and spot size converters. Thus, there is a need for alternative solutions to suppress or reduce higher order mode effects, particularly for operation at ≥10 Gb/s.
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[0066] In other embodiments, the etched trench providing the back-facet reflector may have other geometric forms. The etched trenches for the mirror structures of
[0067] Suitable geometric forms and dimensions of the back-facet reflector are determined by optical modelling, based on parameters such as, the refractive indexes of the III-V materials of the laser mesa and the metal and/or dielectric facet coating materials (e.g. gold, silicon nitride, silicon oxynitride, et al.), lateral x-y dimensions of the laser aperture, layer thicknesses of facet coatings. It may be preferable that the spatially patterned reflector is formed by a coating of a dielectric material, rather than a metal reflector. If a metal reflector is used, plasmonic interactions may need to be considered.
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[0070] For each of the structures shown in
[0071] The mode selective filter may comprise laterally defined features. For example,
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[0073] After coating, in cross-section, the etched trenches may taper in width, e.g. as shown schematically in
[0074] For some applications, it may be desirable to select a mode other than the TE0 mode. In alternative embodiments, not illustrated, the selected mode is e.g. a first order TE1 mode and the spatially patterned reflector provides higher feedback of the TE1 mode relative to other modes, e.g. for lateral coupling to a waveguide.
[0075] In fabrication of the device structures described above, phase alignment of the SEG DFB grating teeth and the back facet reflector structure is an important consideration, whether this is a single interface reflector, e.g. as shown in
[0076] To define the reflector structure with the required phase-adjust region, a suitable fabrication process is needed. The fabrication process must provide precise alignment for any sort of etched feature which need precise positioning relative to other etched features, such as aligning single interface reflectors or a multi-interface DBR type structure to the DFB grating with precise optical phase control. To provide phase-aligned laser reflectors, additional features defining the phase-aligned laser reflectors are included on the same mask that is used to define the DFB laser grating. This process also provided the ability to differentially mask regions to adjust etch depths of various features independently, e.g. for some different types of structures as shown schematically in the various views in
[0077] An example of an epitaxial layer structure (epi-layer stack) 300 for a fabrication of a device comprising a VC SEG DFB laser and structured reflector of an exemplary embodiment is shown schematically in
[0078] In a process for fabrication of the VC SEG DFB laser comprising a DBR reflector according to the embodiments shown in
[0079] Exemplary Fabrication Process
[0080] In the process illustrated schematically in
[0081] Mask Design
[0082] Design of the phase-aligned (PA) mask for the DFB laser with a mode-selective single interface mirror or mode-selective DBR structure requires that the propagation constants for the desired mode are determined for each region, i.e. the unetched regions and the etched regions. For the unetched regions, any processes for shifting absorption or emission bands are considered. For etched regions, any dielectric coatings and filling materials are considered. The design of the DFB grating pattern includes any chirp defined by the grating period and/or lateral extent of the grating teeth. These parameters are used to define the desired un-etched/etched/un-etched pattern, including the distance from the last grating tooth to the first etched reflecting surface, dimensions of the etched regions and un-etched regions, e.g. dimensions for defining the mirror, DBR, waveguides, et al., while taking into account mask alignment accuracy for differentially etched areas, and residues left after subsequent processing. All elements are laid out on a single PA mask layer. At least one secondary etch (SE) mask is laid out to allow differential etching in some areas, while protecting other areas.
[0083] Process Variants
[0084] The process flow of the embodiment illustrated schematically in
[0085] The following are two examples of variants of the process.
[0086] Example Process Flow—Variant A [0087] 1. Deposit a primary (Phase Alignment (PA)) hard mask [0088] 2. Expose the PA mask layer pattern into the primary hard mask [0089] 3. Etch the shallowest etch first (i.e. first etch to first etch depth, e.g. for grating etch) [0090] 4. Deposit a secondary SE (selectively etched vs primary) hard mask [0091] 5. Photolithographically pattern the SE mask and selectively etch the secondary hard mask to allow etch access through the primary hard mask to the appropriate regions for additional etching [0092] 6. Etch the exposed regions [0093] 7. Strip the secondary SE hard mask [0094] 8. Optionally, fill the etched regions with a suitable dielectric material [0095] 9. Repeat steps 4-8 if required, e.g. to define features with different etch depths [0096] 10. Remove remaining secondary SE hard mask [0097] 11. Remove primary hard mask, if desired [0098] 12. Optionally, at this point or later in the overall laser fabrication sequence, process the trenches for desired fill material
[0099] Ideally the etched regions, e.g. the trenches of the reflector, are filled with air or other very low refractive index material. Low index minimizes the number of trenches for a given reflectivity. In practice, the trenches may be filled with a material such as BCB, which has a refractive index of ˜1.55-1.6. A hybrid fill may be used, e.g. a first layer of fill on the sidewalls and a bulk fill. The options chosen depend on process flow and available materials in the process.
[0100] Example Process Flow—Variant B
[0101] Similar to Variant A, except each etch is explicitly opened for the specific etch [0102] 1. Expose the PA mask layer pattern into the primary hard mask [0103] 2. Deposit secondary SE (selectively etched vs primary) hard mask [0104] 3. Photolithographically pattern the SE mask and selectively etch the secondary hard mask to allow etch access through the primary hard mask to the appropriate regions for additional etching [0105] 4. Etch the exposed regions [0106] 5. Strip the secondary SE hard mask [0107] 6. Repeat steps 3-5 as required [0108] 7. Remove remaining secondary hard mask [0109] 8. Remove primary hard mask, if desired.
[0110] In summary, a self-aligned process is used to form the device structure comprising a SEG DFB laser with a phase-aligned DBR structure which is configured to suppress higher order mode effects. The device structure is relatively simple to fabricate. A stepper mask is used to define both the surface etched grating and the DBR structure with phase-alignment. The first hard mask defines the fundamental pattern of interest, and at least one second mask, which is patterned differentially from the first hard mask, enables a sequence of etches of different etch depths to be performed independently to define the various elements of the required device structure. For example, a front facet could be added, and additional masks can be used to define other features. Typically, the shallowest etch is performed first. However, in variants of the method, the DBR structure may be defined first while the SEG grating mask is protected, and then the SEG grating is etched subsequently.
[0111] The resulting laser device structures of example embodiments provide at least one of good quality, low cost and high performance (high efficiency).
[0112] The process uses dielectric coatings for the DBR structure, which avoids use of metal reflectors such as gold, that have a complex refractive index, which would mean that plasmon effects would need to be taken into consideration.
[0113] The ability to use stepper mask photolithography to define features of the DFB grating and the phase-aligned mode-selective DBR structure provides increased flexibility relative to e-beam writing. The latter is a relatively expensive, and less accessible process.
[0114] The disclosed self-aligned fabrication process also allows for the grating to be made with chirp, either periodic chirp or chirp of the coupling coefficient. For chirp of the coupling coefficient, the width of the grating determines the coupling coefficient, and the process is scalable. The process also provides increased flexibility to include non-DFB laser features with SEG to make DFB lasers.
[0115] In the VC SEG DFB laser of the examples described above, the SEG is e.g. a third order grating. Although the grating period is limited by current lithographic technology, as technology improves in the future to facilitate definition of features of smaller dimension, the order of the SEG may be as low as first order. Smaller size grating teeth allows for many more teeth per unit length, with potential ability to provide more control of the refractive index created by the etched/not etched regions.
[0116] The process described in detail with reference to device structures of exemplary embodiments may also modified to be more generally applicable to structures comprising other forms of reflectors, such as echelle steps, sampled grating structures, photonic bandgap structures, aperiodic grating structures, apodized gratings, et al.
[0117] For example, lateral couplers or interference devices may be included, e.g. to position echelle grating teeth relative to the SEG grating of the DFB laser.
[0118] As another example, the mode-selective filter may comprise a first DBR reflector and a second DBR reflector, e.g. a first DBR reflector that acts as a broadband filter for the overall mode and a second DBR on the output to further select or tune a selected mode. Or, for example, a second DBR layer with multiple pitches in parallel (not sequence) with a waveguide selector (spatial demux) may be structured to choose which specific wavelength to couple, without requiring a taper layer.
[0119] Thus, more generally, the method may be extended for patterning a plurality of phase-aligned etched structures into a semiconductor substrate. For example, a method for patterning a plurality of phase-aligned etched structures into a semiconductor substrate comprises, alone or in combination with other process steps: providing the substrate with the desired structure; depositing a primary etch mask, comprising one or more layers of primary etching-mask materials; patterning the primary etch mask in a single high relative dimensional fidelity step.
[0120] Patterning the primary etch mask defines patterns for each of the plurality of phase-aligned etched structures, for subsequent etching of all desired phase-aligned patterns. That is, a single primary etch mask defines patterns for all etched structures which are to be phase-aligned. The method then proceeds, e.g. by at least the following steps: [0121] providing additional patterned etch-protecting materials, e.g. area selective etch mask, over some regions of the primary mask; [0122] etching the semiconductor areas exposed through the primary etch-mask to achieve a target result; [0123] optionally, removing the etch protecting materials; and repeating these steps until all desired phase-aligned etched structures are completed.
[0124] If required, in one or more additional steps, some or all of the etched regions may be filled, e.g. with dielectric or other material.
[0125] After etching and completion of all desired phase-aligned etched structures, the primary etch-mask materials are removed, if required.
[0126] The primary etch masking layer defines the patterns for all desired phase-aligned structures in a single process step. The single high dimensional fidelity step could be single mask photolithography (e.g. the mask is typically made from an e-beam exposure), single write on-wafer via e-beam or focused ion beam, or other similar process capable of high fidelity relative positioning within the single application.
[0127] Then, a series of etch steps are performed, each using an area selective etch mask that exposes a part of the phase alignment primary etch mask, to allow one or more of the phase-aligned etch structures to be defined. For example, a first area selective etch mask is defined to expose a first area of the primary etch mask, and leave other areas protect, and then a first etch is performed to a required etch depth, e.g. a first etch depth through the exposed first area of the primary etch mask. If required, the first area selective etch mask is removed. Then, these process steps are repeated with a second area selective etch mask and a second etch to a second depth, and if required an nth area selective etch mask and nth etch to an nth etch depth for n≥3, until etched and not-etched regions are defined for all the phase-aligned device structures. As mentioned above, optionally, and if required, after each etch, or after completion of all etches, some or all of the etched regions may be filled, e.g., with a suitable dielectric material.
[0128] A schematic cross-sectional view of the mesa structure 1250 of a VC SEG DFB laser of another embodiment is shown in
[0129] A schematic diagram of a VC SEG DFB laser 2000 of yet another embodiment is shown in
[0130] In the example embodiments described in detail above, a VC SEG DFB laser comprises a phase-aligned mode-selective filter, which provides higher feedback of a fundamental mode, i.e. TE0 compared to other mode orders. In other embodiments, the phase-alignment region may be omitted and/or the detector for back-facet monitoring may be omitted from the VC SEG DFB laser. The method of fabrication is modified accordingly to omit these features.
[0131] In another embodiment, a SEG DFB laser comprises a mode-selective DBR back facet reflector, which in fabrication is defined by a first phase-aligned etch, and a non-mode selective, single interface front facet, which in fabrication is defined by a second a phase-aligned etch.
[0132] While laser device structures including a mode-selective filter comprising structured reflectors providing higher feedback to a selected mode, and a phase-alignment structure have been described with particular applicability to VC SEG DFB lasers, these features may also be applicable, independently or in combination, to other types of laser diodes.
[0133] For example, in semiconductor devices comprising laser diodes other embodiments a mode selective filter may be advantageous for multi-mode laser cavities, including Fabry-Perot (FP), DFB and DBR laser cavities, and may include spatially patterned reflectors fabricated from dielectric and/or metal layers.
[0134] In other embodiments, a phase alignment element may be advantageous for single longitudinal mode laser diodes (not FP laser diodes) with mode management structures such as DFB and DBR laser cavities, with either single mode or multi-mode cavities. The latter may include mode selective filters comprising spatially patterned reflectors comprising dielectric and/or metal layers. Inclusion of a detector for back-facet power monitoring is advantageous for embodiments comprising laser cavities supporting a single transverse mode, and multi-transverse mode laser cavities (i.e. any of FP, DFB and DBR laser cavities), and power monitoring benefits from dielectric reflectors.
[0135] While specific embodiments of semiconductor structures comprising laser diodes have been described with features comprising one or more of mode-selective filters, comprising single facet or multi-facet reflectors; phase-alignment elements; and detectors for back-facet monitoring, these embodiments are described by way of example only. Other embodiments of FP, DFB and DBR laser diodes comprising feasible combinations of these features, may provide one or more advantages over prior art device structures.
[0136] Although embodiments of the invention have been described and illustrated in detail, it is to be clearly understood that the same is by way of illustration and example only and not to be taken by way of limitation, the scope of the present invention being limited only by the appended claims.