Gas sensor
09733208 · 2017-08-15
Assignee
Inventors
Cpc classification
International classification
Abstract
A gas sensor according to the present invention includes a sensor element made of a solid electrolyte and having at least a cylindrical portion arranged coaxially with an axis of the sensor element and a front end portion closing a front end of the cylindrical portion and a heater formed into either a cylindrical shape or a cylindrical column shape and located inside the sensor element to heat the sensor element by heat generation thereof, wherein a front end portion of the heater is in contact with an inner surface of the front end portion of the sensor element; and wherein a lateral portion of the heater is in contact with an inner circumferential surface of the cylindrical portion of the sensor element.
Claims
1. A gas sensor, comprising: a sensor element made of a solid electrolyte and having a cylindrical portion arranged coaxially with an axis of the sensor element, a front end portion closing a front end of the cylindrical portion, and a connection region connecting the cylindrical portion and the front end portion; and a heater formed into either a cylindrical shape or a columnar shape and located inside the sensor element so as to heat the sensor element by heat generation thereof; wherein the heater has a front end portion and a lateral portion which meets the front end portion at an interface between the front end portion and the lateral portion; wherein the front end portion of the heater is in contact with an inner surface of the front end portion of the sensor element; wherein the lateral portion of the heater that is to the rear of the interface is in contact with an inner circumferential surface of the cylindrical portion of the sensor element; and wherein a chamfered portion is formed on a front end edge of the heater and kept from contact with the inner surface of the front end portion and the connection region of the sensor element.
2. The gas sensor according to claim 1, wherein the inner surface of the front end portion of the sensor element is made flat.
3. The gas sensor according to claim 1, wherein the connection region is defined as an arc curved surface along a boundary between the inner surface of the front end portion and the inner circumferential surface of the cylindrical portion such that the inner surface of the front end portion and the inner circumferential surface of the cylindrical portion are connected smoothly by the connection region.
4. The gas sensor according to claim 1, wherein the sensor element satisfies a relationship of 0.3≦r/R where R is a diameter of the inner circumferential surface of the cylindrical portion; and r is a diameter of the inner surface of the front end portion.
5. The gas sensor according to claim 4, wherein the sensor element satisfies a relationship of r/R=0.47 where R is the diameter of the inner circumferential surface of the cylindrical portion; and r is the diameter of the inner surface of the front end portion.
6. The gas sensor according to claim 1, wherein the front end portion of the sensor element has an outer surface defining a front end of the sensor element; and wherein both of the inner and outer surfaces of the front end portion of the sensor element are made flat.
7. The gas sensor according to claim 6, wherein a thickness of the front end portion of the sensor element in a direction of the axis is larger than or equal to a radial thickness of a region of the cylindrical portion of the sensor element with which the heater is brought into contact.
8. The gas sensor according to claim 1, wherein a thickness of the front end portion of the sensor element in a direction of the axis is equal to a radial thickness of a region of the cylindrical portion of the sensor element with which the heater is brought into contact.
9. The gas sensor according to claim 1, wherein the heater includes a ceramic rod, a ceramic layer covering an outer circumference of the ceramic rod, with a front end portion of the ceramic rod protruding from a front end of the ceramic layer, and a heating element disposed in a front end part of the ceramic layer; wherein the front end portion of the ceramic rod is in contact with the inner surface of the front end portion of the sensor element; and wherein the heating element or ceramic layer is in contact with the inner circumferential surface of the cylindrical portion of the sensor element.
10. The gas sensor according to claim 1, wherein a chamfered portion is formed on a front end edge of the front end portion of the heater, the chamfered portion extending between the lateral portion and the front end portion of the heater, which chamfered portion is not in contact with the inner surface of the front end portion of the sensor element and is not in contact with the connecting region of the sensor element.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DESCRIPTION OF REFERENCE NUMERALS
(9) 1: Gas sensor
(10) 11: Sensor body (Sensor element)
(11) 12: Cylindrical portion
(12) 13: Front end portion
(13) 15: Connection region
(14) 16: Outer electrode
(15) 19: Inner electrode
(16) 20: Heater
(17) 25: Chamfered portion
DESCRIPTION OF THE EMBODIMENTS
(18) A gas sensor according to one embodiment of the present invention will be described below with reference to
(19) In the present embodiment, the gas sensor is embodied as an oxygen gas sensor fixed to a cylinder head of an internal combustion engine of a vehicle such as a passenger car, with a front end part of the gas sensor inserted in an exhaust gas passage inside the cylinder head, so as to measure the concentration of oxygen in an exhaust gas. It is herein noted that, in the following description, the term “front” refers to a side at which a protector 80 is attached to a metal shell 60 with respect to the direction of an axis O; and the term “rear” refers to a side opposite the front side.
(20) The gas sensor 1 according to the present embodiment is of the type having a heater 20 for heating a gas sensing element 10 (discussed later) such that the gas sensing element 10 can be activated by heat of the heater 20 to measure the concentration of oxygen in the exhaust gas.
(21) More specifically, the gas sensor 1 has a gas sensing element 10, a heater 20, a separator 30, a seal member 40, metal terminals 50 and lead wires 55 surrounded by a metal shell 60, a protector 80 and an outer tube 90 as shown in
(22)
(23) The element body 11 (sensor element 11) generally includes a circular cylindrical portion 12 extending in the direction of the axis O and a front end portion 13 closing a front end (lower end in
(24) In the present embodiment, the cylindrical portion 12 has an inner circumferential surface formed with a diameter of 3.0 mm. As to the thickness of the element body 11, i.e., the thickness between inner and outer surfaces of the element body 11, a part of the element body 11 directly below the flange portion 14 is 1.0 to 1.5 mm in thickness; and a part of the element body 11 located rear of the flange portion 14 is 2.0 mm in thickness. Further, a front end part of the cylindrical portion 12 is 0.5 mm in thickness. The inner circumferential surface of the cylindrical portion 12 is formed such that at least the vicinity of a front end of the inner circumferential surface, i.e., the vicinity of a region of the inner circumferential surface with which the heater 20 is brought into contact is made constant in diameter.
(25) As shown in
(26) By the formation of the connection region 15 as such a smooth arc curved surface, it is possible to avoid the occurrence of cracking in the boundary between the inner surface of the front end portion 13 and the inner circumferential surface of the cylindrical portion 12 and thereby effectively prevent breakage of the element body 11.
(27) Further, there is satisfied a relationship of 0.3≦r/R where R is the inner diameter (or inner radius) of the cylindrical portion 12; and r is the diameter (or radius) of the flat region of the inner surface of the front end portion 13 as shown in
(28) As the solid electrolyte material of the element body 11, a solid solution of Y.sub.2O.sub.3 or CaO in ZrO.sub.2 is typically usable. It is alternatively feasible to use a solid solution of an oxide of any other alkali earth metal or rare earth metal in ZrO.sub.2. Further, HfO.sub.2 may be added to the solid solution of alkali earth metal oxide or rare earth metal oxide in ZrO.sub.2.
(29) The outer electrode 16, the vertical lead 17 and the annular lead 18 are formed on the outer surface of the element body 11. The outer electrode 16 is made of Pt or Pt alloy (hereinafter referred to as “Pt-based material”) in porous form and located on a front end part of the gas sensing element 10. The vertical lead 17 is a conductor made of Pt-based material so as to extend from the outer electrode 16 in the direction of the axis. The annular lead 18 is an annular conductor made of Pt-based material on a lower surface (lower side in
(30) As shown in
(31) In general, the heater 20 includes a circular ceramic rod 21 made of alumina and a ceramic layer 22 made of alumina and covering an outer circumference of the ceramic rod 21. A heating element 23 is disposed in a front end part of the ceramic layer 22 and adapted to generate heat upon energization thereof. As the heating element 23, a heating resistor 24 is made of any material capable of generating heat upon energization thereof, such as tungsten material, is embedded in the ceramic layer 22 (see
(32) The heater 20 is arranged diagonally relative to the axis of the gas sensing element 10. A front end portion of the ceramic rod 21 of the heater 20 protrudes from the ceramic layer 22 and is brought into direct contact with the flat region of the inner surface of the front end portion 13 of the element body 11. The heating element 23 of the heater 20 is brought into direct contact with the inner lateral circumferential surface of the cylindrical portion 12 of the element body 11. A chamfered portion 25 is formed on a front end edge of the heater 20 and kept from contact with the inner surface (e.g. connection region 15) of the front end portion 13 of the element body 11 (sensor element 11). A pair of electrodes 26 is arranged on a rear end part of the heater 20 and electrically connected to the heating element 23 so as to supply therethrough power to the heating element 23. In
(33) The separator 30 is made of electrically insulating material such as alumina in a cylindrical shape and disposed between the gas sensing element 10 and the seal member 4 as shown in
(34) A radially outwardly protruding flange portion 32 is formed on an outer circumferential surface of the separator 30. A substantially cylindrical metallic holder member 33 is arranged around the outer circumferential surface of the separator 30 at a position front of the flange portion 32 such that the separator 30 is inserted in the metallic holder member 33.
(35) The seal member 40 is made of elastic material such as fluoro rubber in a cylindrical shape and disposed on a rear end of the gas sensor 1. The seal member 40 is formed as a substantially cylindrical plug having its height direction in agreement with the direction of the axis O to close a rear end of the outer tube 90. The seal member 40 is fitted in the rear open end of the outer tube 90 so as to come into contact with a rear end face of the separator 30 and is fixed in the outer tube 90 by forming an outer tube crimp portion 91 on the outer tube 90 at a position corresponding to a lateral surface of the seal member 40. The outer tube crimp portion 91 is formed into a concave recess shape circumferentially around the outer tube 90 by radially inwardly deforming the outer tube 90. An air communication hole 41 is formed through the radial center of the seal member 40 in the direction of the axis O. Four lead insertion holes 42 are formed through the seal members 40 at circumferentially evenly spaced positions radially outside the air communication hole 41.
(36) The air communication hole 41 is adapted to introduce air to the inside of the outer tube 90, which is closed by the seal member 40. A filter member 43 and a metallic fixing member 44 are inserted in the air communication hole 41. The filter member 43 is a thin-film filter made of e.g. fluoro resin such as PTFE (polytetrafluoroethylene) with a micrometer-scale network structure so as to allow communication of air but not allow permeation of water drops etc. The fixing member 44 is a cylindrical fixture for fixing the filter member 43 in the seal member 40. The filter member 43 is fixed in the seal member 40 by holding the filter member 43 between an outer circumference of the fixing member 44 and an inner circumference of the air communication hole 41.
(37) The four metal terminals 50 are made of nickel alloy (such as Inconel 750; registered trademark of INCO Limited in U.K.) and electrically connected to the outer and inner electrodes 16 and 19 of the element body 11 and the electrodes 26 of the heater 20, respectively. Metal cores of the lead wires 55 are crimped and electrically connected to the respective metal terminals 50. In
(38) The metal shell 60 is made of stainless steel (such as SUS 310S according to JIS) and is substantially cylindrical in shape as shown in
(39) The metal shell 60 has a thread portion 62 for mounting the gas sensor 1 to cylinder head of the internal combustion engine (not shown) and a hexagonal portion 63 engageable with a mounting tool for screwing the thread portion 62 into the cylinder head. The thread portion 62 and the hexagonal portion 63 are also formed along the entire circumference of the metal shell 60. An annular gasket 64 is arranged between the thread portion 62 and the hexagonal portion 63 so as to prevent gas leakage from the gas sensor 1 and the cylinder head.
(40) A front end fitting portion 65 on which the protector 80 is fitted is formed on the metal shell 60 at a position front of the thread portion 62. An outer circumferential surface of the front end fitting portion 65 is made smaller in diameter than that of the thread portion 62. A rear end fitting portion 66 on which the outer tube 90 is fitted and a crimp fixing portion 67 by which the gas sensing element 10 is fixed by crimping are formed on the metal shell 60 at positions rear of the hexagonal portion 63.
(41) In the metal shell 60, a metallic front packing 71, a cylindrical alumina supporting member 72, a metallic rear packing 53, a filling member 74 of talc powder, an alumina sleeve 75 and an annular ring 76 are placed in order of mention from the step portion 61 toward the rear. A step portion is formed on an inner circumferential surface of the supporting member 72 such that the flange portion 14 of the element body 11 is supported by the step portion. The rear packing 73 is held between the supporting member 72 and the flange portion 14.
(42) The ring 76 is arranged between the sleeve 75 and the crimp fixing portion 67 so as to, when a frontward force is applied by deforming the crimp fixing portion 67 radially inwardly and frontwardly, transmit the applied frontward force to the filling member 74, the rear packing 73, the supporting member 72 and the front packing 71. By this pressing force, the filling member 74 is compressed in the direction of the axis O to hermetically seal the clearance between the inner circumferential surface of the metal shell 60 and the outer circumferential surface of the element body 11.
(43) The protector 80 is adapted to protect the gas sensing element 10, which protrudes inside the gas passage in the state that the gas sensor 1 is fixed to the cylinder head, from collision with water drops and foreign matter etc. flowing through the gas passage. The protector 80 is made of stainless steel (such as SUS 310S according to JIS) and formed as a protection member to cover the front end part of the gas sensing element 10. The protector 80 has a cylindrical shape formed in the direction of the axis with a closed front end. A rear edge portion of the protector member 80 is fixed by welding to the front end fitting portion 65 of the metal shell 60.
(44) In the present embodiment, the protector 80 consists of a bottomed cylindrical outer protector member 81 having an open circumferential edge portion fitted on the front end fitting portion 65 and a bottomed cylindrical inner outer protector member 82 fixed in the outer protector member 81. Namely, the protector 80 has a double structure of the outer and inner protector members 81 and 82.
(45) Introduction holes 83 are formed in circumferential surfaces of the outer and inner protector members 81 and 82 so as to introduce the gas to the sensor inside. In
(46) The outer tube 90 is made of stainless steel (such as SUS 304L according to JIS) different in kind from that of the metal shell 60 and is fixed to the metal shell 60 by inserting the rear end fitting portion 66 of the metal shell 60 into the outer tube 90. The rear end part of the gas sensing element 10 protruding from the rear end of the metal shell 30 is placed together with the separator 30 and the seal member 40 within the outer tube 90.
(47) In the above configuration, the inner surface of the front end portion 13 of the element body 11 is made flat so that the front end and lateral surface of the heater 20 can be easily respectively brought into direct contact with the inner surface of the front end portion 13 and the inner circumferential surface of the cylindrical portion 12 of the element body 11. It is therefore possible to raise the temperature of the element body 11 in a short time and reduce the time required for activation of the gas sensing element 10 as compared to the cases where only the front end of the heater 20 is brought into the inner surface of the front end portion 13 of the element body 11 and where only the lateral surface of the heater 20 is brought into contact with the inner circumferential surface of the cylindrical portion 12 of the element body 11. It is also possible to uniformize the temperature distribution of the front end of the element body 11 and limit variations in the output of the gas sensing element 10.
(48) For example, it is assumed that the inner surface of the front end portion 13 is spherical in shape. In this case, it is likely that the front end of the heater 20 will be slid on the spherical inner surface of the front end portion 13 and led to the center of the inner surface of the front end portion 13 at the time of bringing the front end of the heater 20 into contact with the inner surface of the front end portion 13 while keeping the lateral surface of the heater 20 in contact with the inner circumferential surface of the cylindrical portion 12. As the lateral surface of the heater 20 and the inner circumferential surface of the cylindrical portion 12 tend to be apart from each other, it becomes difficult to bring the front end and lateral surface of the heater 20 into direct contact with the inner surface of the front end portion 13 and the inner circumferential surface of the cylindrical portion 12, respectively.
(49) In the case where the inner surface of the front end portion 13 is made flat, on the other hand, it is easier to receive the front end of the heater 20 on the inner surface of the front end portion 13 upon contact thereof and thereby less likely to cause a force that moves the lateral surface of the heater 20 and the inner circumferential surface of the cylindrical portion 12 apart from each other at the time of bringing the front end of the heater 20 into contact with the inner surface of the front end portion 13 while keeping the lateral surface of the heater 20 in contact with the inner circumferential surface of the cylindrical portion 12. It is thus possible to facilitate bringing the front end and lateral surface of the heater 20 into direct contact with the inner surface of the front end portion 13 and the inner circumferential surface of the cylindrical portion 12, respectively. The inner surface of the front end portion 13 may be flat in a direction perpendicular to the axis of the element body 11.
(50) In the case where the front end of the element body 11, that is, the outer surface of the front end portion 13 is made flat, the volume of the front end portion 13 can be made smaller than in the case where the outer surface of the front end portion 13 is made spherical in shape. It is thus possible to, even when the element body 11 is heated at the same rate, increase the rate of temperature increase of the element body 11 and reduce the time required for activation of the gas sensing element 10 in the case where the outer surface of the front end portion 13 is made flat.
(51) Furthermore, the thickness of the front end portion 13 is the same as the thickness of the cylindrical portion 12. It is thus possible to decrease the volume of the front end portion 13 while securing the strength of the front end portion 13 as compared to the case where the thickness of the front end portion 12 is made larger than the thickness of the cylindrical portion 12.
(52) In the gas sensor 1, there is a clearance left between the chamfered portion 25 on the front end edge of the heater 20 and the inner surface of the front end portion 13 of the element body 11 (sensor element 11) so that the chamfered portion 25 on the front end edge of the heater 2 is kept from contact with the inner surface of the front end portion 13 of the element body 11 (sensor element 11).
(53) As the front end edge of the heater 2 can be prevented from interfering with the inner surface of the front end portion 13 of the element body 11 (sensor element 11), it is possible to facilitate bringing the lateral surface of the heater 20 into contact with the inner circumferential surface of the cylindrical portion 12 while bringing the front end of the heater 20 in contact with the inner surface of the front end portion 13.
(54) Herein, the correspondence of terminologies between the scope of claims and the above embodiment are as follows. By way of example, the element body 11 (sensor element 11) corresponds to the claimed sensor element; the cylindrical portion 12 corresponds to the claimed cylindrical portion; the front end portion 13 corresponds to the claimed front end portion; the connection region 15 corresponds to the claimed connection region; and the heater 20 corresponds to the claimed heater.
(55) Although the present invention has been described with reference to the above specific embodiments, the present invention is not limited to these specific embodiments. Modification and variation can be made without departing from the scope of the present invention.
(56) For example, the outer surface of the front end portion 13 of the element body 11 may be made flat as shown in
(57) In the case where the outer surface of the front end portion 13 is formed into such a curved shape, the thickness of the front end portion 13 of the element body 11 is made larger than the thickness of the cylindrical portion 12 of the element body 11 so that it is possible to effectively prevent breakage of the front end portion 13 as compared to the case where the thickness of the front end portion 13 of the element body 11 is made smaller than the thickness of the cylindrical portion 12 of the element body 11. As the front end of the heater 20 collides with the front end portion 13 of the element body 11 at the time of insertion of the heater 20, it is likely that, if the front end portion 13 is insufficient in thickness and poor in strength, a defect such as crack will occur in the front end portion 13 of the element body 11. This defect may develop to a crack under the effect of temperature changes of the element body 11 and become a cause of breakage.
(58) As shown in
(59) Next, an explanation will be given of results of comparative measurement test of the gas sensor to which the present invention is applied and two comparative (conventional) gas sensors. The comparative measurement test was conducted for three items: “temperature difference between different sensor element regions”, “sensor activation time” and “sensor output variations”.
(60) One of the comparative (conventional) gas sensors was of the type where a heater is brought into contact with a lateral inner surface of a sensor element (i.e. so called “lateral-contact-structure”) as shown in
(61)
(62)
(63) As is seen from the measurement test results of
(64) The “sensor activation time” of the front-contact-structure gas sensor was the longest. The “sensor activation time” of the lateral-contact-structure gas sensor was shorter than that of the front-contact-structure gas sensor. The “sensor activation time” of the gas sensor according to the present invention was further shorter than that of the lateral-contact-structure gas sensor. It apparent from these measurement test results that the gas sensor according to the present invention was able to effectively reduce the sensor activation time as compared to the front-contact-structure gas sensor and the lateral-contact-structure gas sensor.
(65) The “sensor output variations” of the lateral-contact-structure gas sensor was the largest. The “sensor output variations” of the gas sensor according to the present invention and the “sensor output variations” of the front-contact-structure gas sensor were smaller than those of the lateral-contact-structure gas sensor. It is apparent from these measurement test results that, as compared to the lateral-contact-structure gas sensor, the gas sensor according to the present invention was unlikely to cause output variations.
(66) To sum up, it has been shown by the above measurement test results that it is possible for the gas sensor according to the present invention to effectively reduce the time required for activation of the element body of the gas sensing element (sensor element) and limit variations in the output from the element body of the gas sensing element (sensor element) as compared to the front-contact-structure gas sensor and the lateral-contact-structure gas sensor.