Three-piece oil ring for internal combustion engines, expanding element, and annular element

Abstract

A three-piece oil ring for an internal combustion engine may include an expanding element defining at least a first side and a second side opposite the first side. A first upper annular segment may be associated with the first side of the expanding element. A second lower annular segment may be associated with the second side of the expanding element. The first annular segment and the second annular segment may each include a first internal side surface and a second external side surface. A metallic tungsten matrix coating may be disposed on at least one of the expanding element, the first annular segment and the second annular segment via chemical vapor deposition. The coating may contain a tungsten nanocarbide that may include at least one of WC, W2C, W3C and W12C. The coating may include a thickness between 5 μm and 150 μm and a hardness between 1000HV and 3500HV.

Claims

1. A three-piece oil ring for an internal combustion engine, comprising: an expanding element defining at least a first side and a second side opposite the first side, a first upper annular segment associated with the first side of the expanding element and a second lower annular segment associated with the second side of the expanding element, wherein each of the first annular segment and the second annular segment include a first internal side surface and a second external side surface, and a chemical vapor deposition coating of a metallic tungsten matrix material homogeneously dispersed on at least one of the expanding element, the first annular segment and the second annular segment, the metallic tungsten matrix material containing a distribution of tungsten nanocarbides including at least one of WC, W2C, W3C and W12C, wherein the coating includes a thickness between 5 μm and 150 μm and a hardness between 1000 HV and 3500 HV; and wherein the coating defines an external surface facing away from the at least one of the expanding element, the first annular segment and the second annular segment, and wherein the distribution of tungsten nanocarbides provides a hardness variation in the coating such that the hardness at the external surface is reduced according to a depth of the coating away from the external surface.

2. The ring according to claim 1, wherein the hardness variation defines a reduction in hardness of up to 50% as compared to the hardness of the coating at the external surface.

3. The ring according to claim 1, wherein the coating is disposed only on at least one of the internal side surface and the external side surface of the at least one of the first annular segment and the second annular segment.

4. The ring according to claim 1, wherein the coating is disposed on all surfaces of at least one of the first annular segment and the second annular segment.

5. The ring according to claim 3, wherein the thickness of the coating disposed on the internal side surface of the at least one of the first annular segment and the second annular segment is less than or equal to 70% of the thickness of the coating disposed on the external side surface of the at least one of the first annular segment and the second annular segment.

6. The ring according to claim 1, wherein the expanding element includes at least one first region on the first side interfacing with the first annular segment and at least one second region on the second side interfacing with the second annular segment, wherein the coating is disposed on the at least one first region and the at least one second region of the expanding element.

7. The ring according to claim 1, further comprising a pure nickel layer underlying the coating to facilitate adhesion of the metallic tungsten matrix material.

8. The ring according to claim 1, wherein the coating is deposited at a temperature between 450° C. and 650° C.

9. An expanding element for a three-piece oil ring, comprising: a plurality of first regions configured to interface with a first annular segment; a plurality of second regions configured to interface with a second annular segment; and a chemical vapor deposition coating homogeneously dispersed on at least one of the plurality of first regions and the plurality of second regions, the coating composed of a metallic tungsten matrix material containing a distribution of tungsten nanocarbides including at least one of WC, W2C, W3C and W12C, wherein the coating includes a thickness between 5 μm and 150 μm and a hardness between 1000 HV and 3500 HV; and wherein the coating defines an external surface facing away from the at least one of the plurality of first regions and the plurality of second regions, and wherein the distribution of tungsten nanocarbides provides a hardness variation in the coating such that the hardness at the external surface is reduced according to a coating depth from the external surface, the coating depth being defined by a direction running orthogonal to the at least one of the plurality of first regions and the plurality of second regions.

10. An annular segment for a three-piece oil ring, comprising: a first internal side surface and a second external side surface, and a chemical vapor deposition coating of a metallic tungsten matrix material homogeneously dispersed on at least one of the first internal side surface and the second external side surface, the metallic tungsten matrix material of the coating having a distribution of tungsten nanocarbides including at least one of WC, W2C, W3C and W12C, wherein the coating includes a thickness between 5 μm and 150 μm and a hardness between 1000 HV and 3500 HV; wherein the coating defines an external surface facing away from the at least of the first internal side surface and the second external side surface, and wherein the distribution of tungsten nanocarbides provides a hardness variation in the coating such that the hardness of the coating is reduced from the external surface according to a depth of the coating, the coating depth being defined by a distance from the external surface in a direction running orthogonal to the at least one of the first internal side surface and the second external side surface; and wherein the coating has a greater hardness at the external surface than away from the external surface along the coating depth.

11. The annular segment according to claim 10, wherein the coating is disposed only on at least one of the internal side surface and the external side surface.

12. The annular segment according to claim 10, wherein the first internal side surface and the second external side surface merge with two transverse surfaces, wherein the coating covers the first internal side surface, the second external side surface and the two transverse surfaces.

13. The annular element according to claim 10, wherein the hardness variation defines a reduction in hardness of up to 50% as compared to the hardness of the coating at the external surface.

14. The annular segment according to claim 10, wherein the thickness of the coating on the internal side surface is less than or equal to 70% of the thickness of the coating on the external side surface.

15. The annular segment according to claim 10, further comprising a pure nickel layer underlying the coating to facilitate adhesion of the metallic tungsten matrix material.

16. The expanding element according to claim 9, wherein the hardness variation defines a reduction in hardness of up to 50% as compared to the hardness of the coating at the external surface.

17. The expanding element according to claim 16, further comprising a pure nickel layer disposed between at least one of (i) the coating and the plurality of first regions and (ii) the coating and the plurality of second regions.

18. The expanding element according to claim 9, further comprising a pure nickel layer underlying the coating to facilitate adhesion of the metallic tungsten matrix material.

19. The ring according to claim 1, wherein the coating has a Young's modulus of about 410 GPa.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The present invention will be described in greater detail below based on an example of embodiment displayed in the figures. The figures show the following:

(2) FIG. 1—is a perspective schematic view of a portion of a certain oil scraping ring, wherein the expander and the upper and lower annular segments which form said ring can be visualized.

(3) FIG. 2—is a schematic figure of a plurality of annular segments onto which the tungsten carbide coating was applied by means of the chemical deposition process (CVD) on the respective inner and outer side surfaces.

(4) FIG. 3—corresponds to a sectional photograph of the expander of the ring which is the object of the present invention and three enlarged views.

(5) FIG. 4—corresponds to a detailed view of the tungsten carbide coating on the piston ring which is the object of the present invention.

(6) FIG. 5—is a photograph of an expander of a currently known oil ring, wherein a significant wear after a certain time of use can be noticed.

(7) FIG. 6—is a photograph of the expander of an oil ring of the ring which is the object of the present invention, whose wear was significantly lighter than that of the expander shown in FIG. 5.

DETAILED DESCRIPTION

(8) FIG. 1 shows a three-piece oil control ring for use in the groove of a piston of any internal combustion engine, e.g., the ring 1 object of the present invention. In the figure, which displays a partial perspective view, one can clearly notice the existence of an expander 2 having a substantially annular shape comprising a plurality of regions 9 (called pads) for the association of a first upper annular element 3 and a second lower annular element 4, each having, respectively, a first inner side surface 5 and a second outer side surface 6.

(9) The expander 2 presses the first and the second annular elements 3, 4 against the cylinder wall when the ring is duly mounted on the engine and controls the thickness of the oil film on the cylinder wall.

(10) The main novelty of the ring object of the present invention lies in the fact that the expander 2 and/or the first and second annular segments 3, 4 are coated with a tungsten carbide WC) coating 7 applied by means of the chemical deposition process (CVD), which is something that has never been disclosed by any prior-art document and that imparts to the present ring extremely advantageous durability and manufacture cost characteristics.

(11) In a three-piece oil ring, the wear occurs primarily in the region of contact between the inner side surfaces 5 of the annular segment 3, 4 and the pads 9 of the expander.

(12) In most of the conventional products, a coating of chromium nitride is applied to the region of pads 9 through the physical vapor deposition (PVD) or galvanic process. Another common technique currently consists in executing a nitriding procedure in the expander element by gaseous diffusion (with nitrogen diffusion). Said chemical element, diffused in the surface, increases its resistance to the wear of the part.

(13) The application of a coating 7 of tungsten carbide to the expander element 2 and to the first and second annular segments 3, 4 in the ring object of the present invention, it is especially adequate to the expander element due to 2 its complex geometry, for it guarantees easily and economically the deposition of a film in the desired thickness in locations such as the pads 9.

(14) Describing in other words, by being filed homogenously to all the expander element, the coating 7 is applied to the regions 9 of the expander element to which the first and the second annular elements 3, 4 are associated.

(15) The chemical vapor deposition process (CVD) is used for the application of coating in a specific substrate. As a general rule, a substrate is exposed in an environment in which volatile elements react and are deposited homogeneously in the whole exposed surface, being therefore specially indicated for the expander 2.

(16) Besides of homogeneously applying the tungsten carbide coating 7 to the expander element 2, adequately coating the pads 9, the same process of CVD is used for applying to the first and second annular segments 3, 4 which preferably, but not necessarily exhibit identical format and constitution.

(17) In a preferred manner, a series of annular segments 3, 4 is set as illustrated in FIG. 2, and this stack is placed in the environment where the coating will be applied. Due to the reduced thickness of the segments, it is possible to set dozens of segments, which creates a total inner lateral surface and a big total outer lateral surface, behold, the sum of the surfaces of each one of the stacked segments.

(18) Thus, in a sole step, it is possible to apply the coating to the inner and outer surfaces 5, 6 of various annular segments 3, 4, which makes the manufacture of said components very economical.

(19) Alternatively, it is possible to apply the coating of a tungsten carbide by CVD only to an inner surface 5 of the annular segment 3, 4, only to the outer surface 6, or still to the whole surface of the annular segment, unless the resulting invention is no longer included in the scope of protection of the appended claims. As another possible, but not mandatory, alternative the coating 7 applied to the inner side surface 5 presents thickness of no more than 70% of the thickness of the coating applied to the outer side surface 6.

(20) In a preferred embodiment, the process of CVD is performed in a temperature substantially between 450° C. and 650° C., considerably lower in comparison to the temperatures normally used in such type of process (1000° C.), ensuring that there is no damage to the substrate (expander 2 and/or annular segments 3, 4) by the exposure to high temperatures. The coating 7 is obtained by the chemical reaction of gases, namely, the tungsten hexafluoride as the gas which provides the metal, the hydrogen gas, as the reactive gas and a gas as propane or, which serves as carbon source.

(21) The combination of said in specified proportions, in contact to the heated substrate (expander 2 and/or annular segments 3, 4) the coating is formed, which equally covers it.

(22) In a preferable way, the aforesaid gases are inserted in specific proportions so that the metallic tungsten matrix coating 7 containing tungsten nanocarbide WC, W2C, W3C, W12C or a mixture thereof, with thickness between 5 μm and 150 μm (more preferably between 5 μm and 40 μm) and hardness between 1000 HV and 3500 HV.

(23) Also preferably, it is previously applied a pure nickel layer 8 with adhesive function to the coating 7 (bonding layer, see FIG. 4), having a preferred thickness between 1 μm and 5 μm. The pure nickel layer favors adhesion of the tungsten carbide layer formed and deposited by the CVD process.

(24) Also according to a preferred, non-limiting embodiment, due to the reduced percentage of tungsten carbide the Young's modulus (E) is about 410 GPa, therefore similar to the percentage of pure tungsten metal. This is an ad-vantage over the coatings obtained by physical vapor deposition (PVD), which has typical values around 250 GPa.

(25) As a characteristic of the formed tungsten carbide coating 7, it presents a hardness variation so that the hardness of the surface is reduced according to the depth of the coating, the reduction being of up to 50% compared to the hardness of the surface.

(26) The piston ring which is object of the present invention has a number of advantages and benefits over the rings currently known, namely: (a) increase of the tenacity and excellent adhesion of the coating 7 compared to the existing solutions; (b) increase of the piston's life by deposition of the tungsten carbide coating in the regions of the expander 2, wherein the deposition is currently difficult, as in the pads 9; (c) increased resistance to fatigue of the ring due to the elimination of the nitride layer; (d) increased resistance to wear in the inner 5 and outer 6 surfaces of the annular segments 3, 4.

(27) It should be noted that they are also new inventions and have inventive activity, and that the expander element 2 and the annular element 3, 4 are constructed according to the provisions of the present invention. These elements separately are important not only because they conform the present piston ring, but also because they are sold separately in the aftermarket.

(28) In essence, the expander element 2 for use in the present three-piece oil control ring for internal combustion engines comprise a plurality of regions (pads 9) to which the first and second annular elements 3, 4 are linked. To those regions it is applied by the chemical vapor deposition process (CVD) a metallic tungsten matrix coating 7 containing WC, W2C, W3C, W12C tungsten nanocarbides or a mixture thereof, with a thickness between 5 μm and 150 μm and a hardness between 1000 HV and 3500 HV.

(29) The annular element 3, 4 for use in the present three-piece oil control ring for internal combustion engines, in turn, contains the referred first inner side surface 5 and second outer side surface 6, and thereto it is applied by the chemical vapor deposition process (CVD) a metallic tungsten matrix coating 7 containing WC, W2C, W3C, W12C tungsten nanocarbides or a mixture thereof, with a thickness between 5 μm and 150 μm and a hardness between 1000 HV and 3500 HV.

(30) Since it was described an example of preferred embodiment, it must be understood that the scope of the present invention encompasses other possible variations, such as the use of surface treatments and ceramic and metal coatings, with the purpose of improving the wear and corrosion resistance characteristics and reducing the frictional forces, thus being limited only by the content of the appended claims, including possible equivalents.