Household water filter element for removing radioactive substances

Abstract

The present invention relates to a filter element for disinfecting, cleaning and purifying household water, by removing pollutants such as heavy metals, bacteria, VOCs, and even radioactive substance. The present filter element comprises activated carbon, ion exchange resins (cationic and anionic), biopolymer and transitional metal oxide. Said biopolymer and transitional metal oxide are both in particle form and said transitional metal oxide particle can be either incorporated into the biopolymer particle or directly incorporated into the present filter element as individual particle. Maximum capacity of the present filter element can reach up to 150 L of household water. Some of the pollutants can be removed by up to 99% by the present filter element. A method of preparing the present filter element is also disclosed herein.

Claims

1. A filter element for disinfecting, cleaning and purifying household water comprising activated carbon, ion exchange resins, biopolymer, and metal oxide; said ion exchange resins including cationic and anionic ion exchange resins; said biopolymer being in particle form ranging from 1 μm to 100 μm; said metal oxide also being in particle form ranging from 10nm to 10 μm and incorporated into said biopolymer particle through in-situ process to form a biopolymer-metal oxide particle; said activated carbon, cationic ion exchange resins, anionic ion exchange resins, and the biopolymer-metal oxide particle having a weight ratio of 25:41:17:17 in said filter element and at said weight ratio the filter element having a maximum capacity of about 150 L household water to be filtered, wherein said metal oxide is hydroxy iron oxide (α-FeOOH) and said biopolymer-metal oxide particle is chitosan/hydroxy iron oxides/alginate (CHA) particle.

2. The filter element of claim 1, wherein pollutants to be removed from the water by said filter element comprise heavy metals, volatile organic compounds (VOCs), halogen, bacteria and radioactive substances.

3. The filter element of claim 2, wherein said heavy metals comprise cadmium, lead, silver, zinc, and copper.

4. The filter element of claim 2, wherein said VOCs comprise benzene, toluene, and ethylbenzene.

5. The filter element of claim 2, wherein said halogen comprises chlorine.

6. The filter element of claim 2, wherein said bacteria comprises E. coli.

7. The filter element of claim 2, wherein said radioactive substances comprise radioactive barium, strontium, and iodine.

8. A household water filtering system comprising the filter element of claim 1.

9. A method of preparing the filter element of claim 1, said method comprising: (a) preparing hydroxy iron oxide (α-FeOOH) nanoparticles; (b) incorporating said α-FeOOH nanoparticles obtained from (a) into a first mixture of chitosan and alginate and then stirring thereof until a plurality of chitosan/hydroxy iron oxide/alginate (CHA) particles is formed; (c) mixing said CHA particles obtained from (b) with activated carbon, ion exchange resins to form a second mixture; (d) adding said second mixture obtained from (c) into a filter housing to form the filter element; (e) washing said filter element with deionized water until filtrate becomes clear.

10. The method of claim 9, wherein said preparing in (a) comprises dissolving iron (II) sulphate (FeSO.sub.4.H.sub.2O) into a mixture of H.sub.2O and glycerol in a volume ratio of 7:1 and stirring the mixture for at least 10 minutes, followed by transferring the mixture into an autoclave to heat up at about 120° C. for 24 hours, collecting precipitate formed after heating overnight, washing said precipitate with another mixture of H.sub.2O and glycerol, and drying the washed precipitate at 60° C. for about an hour; hydroxy iron oxide nanoparticles are formed after said drying.

11. The method of claim 9, wherein said incorporating in (b) comprises mixing said hydroxy iron oxide nanopartieles in the first mixture of chitosan at 2 wt. % and sodium alginate at 0.5 wt. %, followed by adding said mixture drop by drop into 0.5 wt. % of calcium chloride under stirring until the CHA particles are formed.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows SEM images of hydroxy iron oxide (α-FeOOH) particles flower-like or clamps of flower-like 3-D structure.

(2) FIG. 2 is a flow chart depicting fabrication process of hydroxy iron oxide (α-FeOOH) particles.

(3) FIG. 3 is a flow chart depicting fabrication process of the present filter element according to an embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

(4) The phrase “hydroxyl iron oxide/oxides” used herein may refer to “Goethite” which is commonly used in the art with the chemical formula of α-FeOOH.

(5) Reference will now be made in detail to the presently preferred embodiment of the present invention, serve to explain the principles of the invention. These embodiments or examples are described in sufficient detail to enable those skilled in the art to practice the invention, and it is to be understood that other embodiments may be utilized, and that changes may be made without departing from the spirit of the present invention.

EXAMPLES

Example 1

Comparison in Removal Percentage of Various Pollutants Between Conventional Filter and Present Filter

(6) In this example, the presently claimed filter in the weight of 90 g is configured to include the following components and weight ratio: activated carbon (AC):cationic ion exchange resin (IES):anionic ion exchange resin (IES):chitosan/hydroxy iron oxides/alginate (CHA) particles=25:41:17:17. For comparison, a commercial water filter also in the weight of 90 g is used, which includes activated carbon (AC):ion exchange resin (IES) in a weight ratio of 25:75. 150 L water containing different pollutants is filtered through both filters. The initial concentration of different pollutants in the filtrate is listed in Table 1.

(7) TABLE-US-00001 TABLE 1 Pollutants Concentration Chlorine 0.34 mg/L   Iodine 0.213 mg/L   Benzene 47 μg/L Toluene 49 μg/L Ethylbenzene 44 μg/L Copper 46 μg/L Cadmium 23 μg/L Mercury 5.2 μg/L  Zinc 40 μg/L Lead 41 μg/L E. coli 1 × 10.sup.5/L

(8) Removal percentage of different elements or agents by the present filter and the convention filter in this example is shown in Table 2.

(9) TABLE-US-00002 TABLE 2 Present Filter Conventional Filter Heavy Metal Cd 99% 96% Pb 95% 88% Hg 94% 95% Zn 86% 91% Cu 98% 95% Halogen Cl >85% >83% VOC Benzene >89% 89% Toluene >89% >90% Ethylbenzene 86% 87% Bacteria E. Coli 96% 78% Radioactive Ba isotope 42% 37% substances Sr isotope 38% 36% I isotope >53% 3%

(10) The present filter element has very high removal rate on heavy metals, VOCs, radioactive substances, and bacterium. Also, the pH of the effluent is not affected by the filter element. In this example, the maximum capacity of the present filter is 40 gallons (˜150 L) and no clogging or significantly slow flow rate is observed during filtering such volume of water.

Example 2

Comparison in Removal Percentage of Pollutants by Present Filter with Different Weight Ratio of Filtering Components

(11) TABLE-US-00003 Cd 2.4 Cu 3.4 Pb 3.1 Zn 17.3 Hg 1.6 Ba isotope 2.8 Sr isotope 1.6

(12) Removal percentage of different heavy metals or radioactive substances by the filter with different weight ratio of filtering components is shown in Table 4.

(13) TABLE-US-00004 TABLE 4 AC:Cationic IES:Anionic AC:Cationic IES:Chitosan/ IES:Anionic hydroxy iron IES:Chitosan/ AC:Cationic oxides/alginate (CHA) alginate (CA) IES:Anionic particles = particles = IES = 25:41:17:17 25:41:17:17 25:41:34 Zn 84% 83% 63% Cd 78% 74% 42% Cu 93% 84% 60% Pb 99% 94% 72% Hg 50% 48% 25% Sr isotope 65% 60% 40% Ba isotope 67% 60% 45%

(14) From Table 4, the filter incorporated with the chitosan/hydroxy iron oxides/alginate (CHA) particles has the highest removal percentage of the tested heavy metals or radioactive substances among the three samples in this example. The filter incorporated with the activated carbon and ion exchange resins only has the lowest removal percentage, about two-third to half of the removal percentage of the filter with the CHA particles. In this example, the filter with the CHA particles can effectively remove 1.5 L of tap water within 3 minutes.

(15) FIG. 2 illustrates how the hydroxy iron oxide (α-FeOOH) particles are fabricated for being incorporated into the filter element of the present invention. A mixture of H.sub.2O/glycerol is first prepared (201). The volume ratio of H.sub.2O/glycerol is 7:1. In an embodiment, a mixture containing 35 mL H.sub.2O and 5mL glycerol is prepared. Once the mixture of H.sub.2O/glycerol is formed, iron (II) sulphate (FeSO.sub.4.H.sub.2O) is dissolved into the mixture (202). In one embodiment, 0.111 g of FeSO.sub.4.H.sub.2O is dissolved into the mixture obtained from 201. After addition of FeSO.sub.4.H.sub.2O, the mixture is stirred for about 10 minutes. The mixture after stirring is then transferred into a 50 mL autoclave (203). The mixture is heated at 120° C. for 24 hours (204). The precipitate formed from 204 is collected which is α-FeOOH precipitate. The collected α-FeOOH precipitate is then washed with H.sub.2O/glycerol (205). After being washed with H.sub.2O/glycerol, the α-FeOOH precipitate is dried at 60° C. for about an hour (206). After drying, the hydroxy iron oxide in particle form is formed and ready for use/further processing (207).

(16) FIG. 3 illustrates how the hydroxy iron oxide (α-FeOOH) nanoparticles of the present invention are incorporated into the chitosan-alginate particle and mixed with other components to form the filter element of the present invention. 100 mg of the prepared hydroxy iron oxide (α-FeOOH) nanoparticles according to the embodiment illustrated in FIG. 3 are mixed in 2 wt. % of chitosan solution with 0.5 wt. % sodium alginate solution together, followed by adding the mixture drop by drop under stirring into 0.5 wt. % calcium chloride (301). Activated carbon, ion exchange resins, and hydroxy iron oxide nanoparticles incorporated into chitosan-alginate particles (CHA particles) are mixed together at a desired weight ratio (302). The desired weight ratio according to Example 2 is 25:41:17:17 for activated carbon:cationic ion exchange resins:anionic ion exchange resins:CHA particles. After the mixture of activated carbon, cationic and anionic ion exchange resins, and CHA particles is thoroughly mixed to form the filter elements, the filter elements are added into a filter housing (303). The filter housing can be a filtering column, cylindrical container, or container in other shape. The filter elements are then washed with deionized water until the filtrate becomes clear (304). The filter elements after that are ready for use.

INDUSTRIAL APPLICABILITY

(17) The present filter element is useful in making drinking water filter for removing various pollutants including certain radioactive substances. The present filter element can be used at household level or even be scaled up to industrial level if necessary.

(18) It is understood that the method described herein may be performed in different order, concurrently and/or together with other steps not mentioned herein but readily appreciated by one skilled in the art to obtain the filter medium of the present invention. Without further elaboration, it is believed that one skilled in the art can, based on the description herein, modify the present invention without departing the spirit of the present invention and utilize the present invention to its fullest extend. All publication recited herein are hereby incorporated by reference in their entirety.