Method for producing metal foils
11430605 · 2022-08-30
Assignee
Inventors
Cpc classification
H01F1/15333
ELECTRICITY
H01F41/0213
ELECTRICITY
International classification
Abstract
There is provided a method for producing metal foils, capable of easily crystalizing amorphous soft magnetic material of a plurality of metal foils into nano-crystal magnetic by uniformly heating the metal foils. Separating members (magnets) are disposed on the opposite sides of a laminate, which has been obtained by laminating a plurality of metal foils made of amorphous soft magnetic material, in the laminated direction of the laminate, and the metal foils forming the laminate are magnetized with the magnets. Thus, the adjacent metal foils are separated from each other in the laminated direction and a gap is formed between the metal foils. The metal foils are heated with the gap formed therebetween so that the amorphous soft magnetic material of each metal foil is crystalized into nano-crystal magnetic material.
Claims
1. A method for producing metal foils made of nano-crystal magnetic material, the method comprising: disposing separating members each including at least a magnet on opposite sides of a laminate obtained by laminating a plurality of metal foils made of amorphous soft magnetic material, in a laminated direction of the laminate, and magnetizing the metal foils forming the laminate using the magnet, so as to separate the metal foils that are adjacent to each other in the laminated direction and form a gap between the metal foils; and heating the plurality of metal foils with the gap formed between the metal foils, thereby crystalizing the amorphous soft magnetic material of each of the metal foils into nano-crystal magnetic material.
2. The method for producing metal foils according to claim 1, wherein a portion of each separating member facing the laminate includes a first portion and a second portion alternately disposed in the laminated direction of the laminate, the first portion being adapted to magnetize one of the metal foils using magnetism of the magnet, the second portion being adapted to block the magnetism of the magnet.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(19) Hereinafter, a method for producing metal foils according to the present disclosure will be described with reference to the drawings. With reference to
(20) 1. Metal Foil
(21) Metal foils produced in the present embodiment are metal foils made of nano-crystal soft magnetic material. The production method described below includes applying heat treatment to metal foils made of amorphous soft magnetic material to crystalize the amorphous soft magnetic material into nano-crystal magnetic material, thereby producing metal foils.
(22) Now, amorphous soft magnetic material or nano-crystal soft magnetic material forming metal foils will be described. Examples of the amorphous soft magnetic material and nano-crystal soft magnetic material include, but are not limited to, material containing at least one magnetic metal selected from the group consisting of Fe, Co, and Ni and at least one non-magnetic metal selected from the group consisting of B, C, P, Al, Si, Ti, V, Cr, Mn, Cu, Y, Zr, Nb, Mo, Hf, Ta, and W.
(23) Typical examples of the amorphous soft magnetic material or nano-crystal soft magnetic material include, but are not limited to, a FeCo-based alloy (e.g., FeCo and FeCoV), a FeNi-based alloy (e.g., FeNi, FeNiMo, FeNiCr, and FeNiSi), a FeAl-based alloy or a FeSi-based alloy (e.g., FeAl, FeAlSi, FeAlSiCr, FeAlSiTiRu, and FeAlO), a FeTa-based alloy (e.g., FeTa, FeTaC, and FeTaN) or a FeZr-based alloy (e.g., FeZrN). A Fe-based alloy may contain at least 80 at % of Fe.
(24) As another example of the amorphous soft magnetic material or nano-crystal soft magnetic material, a Co-based alloy containing Co and at least one of Zr, Hf, Nb, Ta, Ti, or Y may be used. The Co-based alloy may contain at least 80 at % of Co. Such a Co-based alloy is likely to become an amorphous state when it is deposited as a film, and exhibits excellent soft magnetism because it has small magnetocrystalline anisotropy and few crystal defects and grain boundaries. Examples of the amorphous soft magnetic material include CoZr, CoZrNb, and CoZrTa-based alloys.
(25) The amorphous soft magnetic material as used herein is soft magnetic material having an amorphous structure as a main structure. In the amorphous structure, no clear peak appears in an X-ray diffraction pattern, and only a broad halo pattern can be observed. Meanwhile, a nano-crystal structure can be formed by applying heat treatment to the amorphous structure, and in a nano-crystal soft magnetic material having a nano-crystal structure, a diffraction peak can be observed in a position corresponding to a gap between lattice points on the crystal plane. Based on the width of the diffraction peak, the crystallite size can be calculated with the Scherrer equation.
(26) In the nano-crystal soft magnetic material as used herein, each nano-crystal has a crystallite size of less than 1 μm as calculated with the Scherrer equation based on the full width at half maximum (FWHM) of a diffraction peak of an X-ray diffraction pattern. In the present embodiment, the crystallite size of each nano-crystal (the crystallite size as calculated with the Scherrer equation based on the full width at half maximum (FWHM) of a diffraction peak of an X-ray diffraction) may be equal to or less than 100 nm, or equal to or less than 50 nm. In addition, the crystallite size of each nano-crystal may be equal to or greater than 5 nm. If nano-crystals have a crystallite size within such a range, magnetic properties can be improved. Meanwhile, the crystallite size of a conventional electromagnetic steel sheet is of the order of μm, and typically equal to or greater than 50 μm.
(27) The amorphous soft magnetic material can be obtained by, for example, melting metal material, which has been prepared to have the above-mentioned composition, at a high temperature in a high-frequency melting furnace or the like to obtain a uniform molten metal and quenching the result. The quenching rate is, for example, about 10.sup.6° C./sec, though it depends on the material used. However, the quenching rate is not particularly limited as long as an amorphous structure can be obtained before the material crystallizes. In the present embodiment, the metal foil as will be described later can be obtained by blowing the molten metal of the metal material onto a rotating cooling roll to produce a metal foil strip made of amorphous soft magnetic material and forming the strip into a desired shape by punching, for example. In this manner, quenching a molten metal can obtain soft magnetic material having an amorphous structure before the material crystalizes. The metal foil may have a thickness not greater than 0.05 mm, for example, and not less than 0.01 mm, for example. It should be noted that in the drawings as will be described later, the metal foil formed is a rectangular metal foil or a fan-shaped metal foil according to the shape of a rotor core of a motor, but the shape of the metal foil is not limited to them.
(28) In the present embodiment, metal foils made of nano-crystal magnetic material are produced from the thus-prepared metal foils made of amorphous soft magnetic material. Now, some embodiments according to the present disclosure will be described.
First Embodiment
(29) As illustrated in
(30) Next, a laminate 10 is produced by overlaying the plurality of metal foils 11 as prepared. The laminate 10 results from laminating the metal foils 11 such that each metal foil 11 is movable. The metal foils 11 are not tied to each other and can be separated from each other. The number of metal foils 11 to be laminated is not particularly limited as long as the plurality of metal foils 11, 11 is arranged such that a gap C is formed therebetween in the laminated direction in the state illustrated in
(31) As illustrated in
(32) As illustrated in
(33) In this manner, the plurality of metal foils 11, 11 can be easily arranged in a state where the metal foils 11, 11, which are magnetized by the magnets 21, repel each other and the plurality of metal foils 11, 11 has a gap formed therebetween, between the magnets 21. In the present embodiment, each metal foil 11 is in contact with each separating member 20, but each metal foil 11 need not be in contact with each separating member 20 as long as the gap C can be formed between the metal foils 11, 11. The same applies to the other embodiments described later.
(34) In
(35) Next, the plurality of metal foils 11, 11 is heated (subjected to heat treatment) in the state illustrated in
(36) In this manner, if the plurality of metal foils 11, 11 is heated so that the amorphous soft magnetic material is crystalized in a state where the gap C is formed between the metal foils 11, 11, heat is inputted to each metal foil 11. During this crystallization, each metal foil 11 generates heat by itself, but since the generated heat is discharged through the gap C between the metal foils 11, 11, it is possible to avoid an excessive temperature rise of the metal foil 11. As a result, each metal foil 11 can be uniformly heated, and the metal foil 11 made of nano-crystal magnetic material having uniform crystals can be obtained.
(37) The conditions of heat treatment for each metal foil 11 are not particularly limited as long as the material can be crystalized, and may be appropriately selected in consideration of the composition of metal material and the desired magnetic properties to be obtained, for example. Therefore, the temperature of the heat treatment is higher than the crystallization temperature of the soft magnetic material of the metal foil, for example, though not particularly limited thereto. Accordingly, performing heat treatment on the amorphous soft magnetic material allows the amorphous soft magnetic material to change (be crystalized) into nano-crystal soft magnetic material. The heat treatment may be performed in an inert gas atmosphere.
(38) The crystallization temperature is a temperature at which crystallization occurs. Since exothermic reaction occurs during crystallization, the crystallization temperature may be determined by measuring the temperature at which heat is generated along with the crystallization. For example, the crystallization temperature can be measured under the condition of a predetermined heating rate (e.g., 0.67 Ks.sup.−1) using differential scanning calorimetry (DSC). The crystallization temperature of amorphous soft magnetic material is, for example, from 300 to 500° C., though it differs depending on the material used. Similarly, the crystallization temperature of nano-crystal soft magnetic material can also be measured using differential scanning calorimetry (DSC). Although nano-crystal soft magnetic material already has crystals generated therein, crystallization further progresses if the nano-crystal soft magnetic material is heated to the crystallization temperature or higher. The crystallization temperature of nano-crystal soft magnetic material is, for example, from 300 to 500° C., though it differs depending on the material used.
(39) The heating temperature in this step is not particularly limited as long as it is equal to or higher than the temperature at which amorphous soft magnetic material crystalizes into nano-crystal soft magnetic material. For example, the heating temperature may be equal to or higher than 350° C., or equal to or higher than 400° C. Setting the heating temperature to 400° C. or higher allows crystallization to progress efficiently. Further, the heating temperature may be equal to or lower than 600° C., or equal to or lower than 520° C., for example. Setting the heating temperature to 520° C. or lower can more easily avoid excessive crystallization and suppress generation of by-products (for example, Fe.sub.2B).
(40) The heating time for the crystallization step is not particularly limited, but may be not shorter than 1 second and not longer than 10 minutes, or not shorter than 1 second and not longer than 5 minutes.
(41) The method for heating each metal foil is not particularly limited as long as the metal foil can be uniformly heated, and any method can be used, such as heating in an atmosphere in a high-temperature heating furnace, heating with an infrared heater, heating with an electromagnetic coil, and heating with heated hot air.
(42) For example, among the above-described heating methods, the metal foil 11 may be heated with heated gas (hot air). More specifically, in the present embodiment, as illustrated in
(43) As a result, due to the gas flowing through the gap C, the gas having a stable temperature flows on the surface of each metal foil 11, and thus each metal foil 11 is uniformly heated. In addition, even when the metal foil 11 generates heat by itself during crystallization, and the surface temperature of the metal foil 11 locally rises to the heating temperature or higher, since the temperature of the gas flowing on the surface is lower than the surface temperature of the metal foil 11 while it generates heat, it is possible to discharge the heat generated by the metal foil 11 to the gas passing over the surface of the metal foil 11. Accordingly, the surface temperature of the metal foil 11 can be maintained more evenly.
(44) In the first embodiment, as illustrated in
(45) Now, as illustrated in the top right view of
(46) Next, as illustrated in the bottom left view in
(47) Finally, as illustrated in the bottom right view in
(48) As described above, as illustrated in
Second Embodiment
(49) As illustrated in
(50) A rod 33, which reciprocates in a direction in which the other opposing coupling member 32 is disposed, is inserted through each coupling member 32. In the present embodiment, the rod 33 is coupled to a driving source that causes the rod 33 to reciprocate. For example, the rod 33 is coupled to a driving source, such as a hydraulic or pneumatic actuator having a piston and a cylinder, an electrical actuator having a motor and the like. The driving source of the rod 33 is not particularly limited as long as it can cause the rod 33 to linearly reciprocate.
(51) The end of each rod 33 has a holding plate 31 attached thereto. The holding plate 31 serves to hold a plurality of metal foils 11, 11 in the state of a laminate 10. The holding plate 31 is disposed in a space between the pair of separating members 20, 20 and moves along with the rod 33 within the space.
(52) In a state where the pair of holding plates 31, 31 is positioned closest to each other along with the movement of the rods 33, the distance between the opposing surfaces of the holding plates 31, 31 is equal to or slightly greater than the thickness of the laminate 10 in the laminated direction F. This allows the laminate 10 to be easily inserted between the holding plates 31, 31 and further allows the laminate 10 to be easily removed from the separating device 30 after crystallization.
(53) The metal foils 11 made of nano-crystal magnetic material are produced using such a separating device 30. The second embodiment differs from the first embodiment in that it uses the separating device 30 in the step of forming a gap C between the metal foils 11, 11. Therefore, only this feature will be described, and the description of the same steps will be omitted.
(54) First, as illustrated in
(55) Next, the rods 33 are moved to move the holding plates 31, 31 in the direction away from the laminate 10. Also in the present embodiment, the separating members 20 (magnets 21) are disposed on the opposite sides of the laminate 10 in the laminated direction F of the laminate 10, and the plurality of metal foils 11, 11 forming the laminate 10 is magnetized by the magnets 21 through a series of such process. Therefore, as illustrated in
(56) After that, in the state illustrated in
Third Embodiment
(57) As illustrated in
(58) More specifically, in the present embodiment, as illustrated in
(59) As illustrated in
(60) In the present embodiment, each first portion 22A only need to be capable of magnetizing each metal foil 11 of the laminate 10 with the magnetism of the magnet 21, and such portion of the first portion 22A may be formed as part of the magnet 21. Furthermore, the first portion 22A may be formed as a magnet so that the magnet 21 may be omitted.
(61) When such separating members 20 are used, the plurality of metal foils 11, 11 is magnetized by the first portions 22A. Therefore, the plurality of metal foils 11, 11 is arranged at some intervals therebetween. Furthermore, since the second portions 22B are portions for blocking the magnetism of the magnet 21, the metal foils 11 are not disposed on the second portions 22B.
(62) In this arrangement, for example, if impact is applied to each metal foil 11 during delivery or hot air is blown on each metal foil in the crystallization step, the attitude of each metal foil 11 may change as illustrated in
(63) However, even in this case, since the second portion 22B for blocking the magnetism of the magnet is disposed between the metal foils 11, 11, even if part of each metal foil 11 becomes likely to fall off the first portion 22A, the attitude of the metal foil 11 is corrected in the arrow direction of
(64) In
(65) Hereinafter, a method for producing a motor will be briefly described with reference to
(66) First, a punching step S1 is performed. In this step, as illustrated in
(67) Next, a laminating step S2 is performed. In this step, the plurality of metal foils 11 is laminated to produce the laminate 10. The laminate 10 is obtained by overlaying the metal foils 11, 11 so that they are not tied to each other.
(68) Next, a gap forming step S3 is performed. In this step, a pair of separating members 20, 20 is disposed on the opposite sides of the laminate 10. More specifically, the device illustrated in
(69) Next, a crystallization step S4 is performed. In this step, as illustrated in
(70) Next, a fixing step S5 is performed. In this step, the separated metal foils 11, 11 are removed from the heating device 50 and brought into close contact with each other with a predetermined pressure to form a laminate 10A. At this time, the metal foils 11 may be tied to each other with a resin such as an adhesive. Furthermore, as illustrated in
(71) Finally, an assembling step S6 is performed. In this step, a coil (not illustrated) is disposed on teeth (not illustrated) of the stator core to form a stator 60, and the stator 60 and a rotor 70 are disposed in a case (not illustrated), whereby a motor 100 is produced.
(72) While the embodiments of the present disclosure have been described in detail above, the present disclosure is not limited thereto, and can be subjected to various kinds of changes of design without departing from the spirit and scope of the present disclosure described in the claims.
(73) In the present embodiment, a stator core of a motor is produced by laminating metal foils made of nano-crystal soft magnetic material, but a rotor core of a motor may be produced by laminating metal foils.