PTFE material having an anti-corona effect

Abstract

The present invention provides a material based on high density polytetrafluoroethylene (PTFE) and its applications, such as in the production of electric cable. The PTFE material of the invention includes PTFE, a metal oxide, a lubricant and a wetting agent.

Claims

1. A material based on polytetrafluoroethylene (PTFE), the material having a density of more than 1.45 and being prepared from a mixture comprising: PTFE; 5% to 15% by weight of metal oxide particles; 15% to 30% by weight of a lubricant; and 0.1% to 1% by weight of a wetting agent; the percentages by weight being based on the weight of PTFE, wherein the wetting agent is a fatty alcohol and the metal oxide particles have a grain size in the range of 10 nm to 1 μm.

2. The material according to claim 1, wherein the lubricant is a liquid based on hydrocarbons.

3. The material according to claim 2, wherein the lubricant is a liquid based on an isoparaffinic hydrocarbon.

4. The material according to claim 1, wherein the wetting agent is dodecan-1-ol.

5. The material according to claim 1, wherein the grain size is in the range of 150 nm to 500 nm.

6. The material according to claim 1, wherein the metal oxide is selected from the group consisting of titanium dioxide, alumina, zinc oxide, copper oxide, magnesium oxide and silver oxide.

7. The material according to claim 1, further comprising 0 to 3% by weight of a pigment.

8. The material according to claim 1, in the form of a tape.

9. A process for producing the material according to claim 1, the process comprising: mixing the PTFE, the metal oxide particles, the lubricant, the wetting agent and an optional pigment; and extruding the resulting product.

10. An electric cable comprising the material according to claim 8 wound around a conductive core.

11. A process for producing the electric cable according to claim 10, the process comprising: winding the tape around the conductive core; and curing at a maximum temperature of 450° C.

12. An electrical insulator comprising the material according to claim 1.

Description

OBJECT AND SUMMARY OF THE INVENTION

(1) The inventors' studies have led them to the development of a novel material based on polytetrafluoroethylene and metal oxide, having an anti-corona effect that overcomes the above-mentioned difficulties.

(2) Thus, the present invention provides a material based on polytetrafluoroethylene (PTFE) of normal density prepared from a mixture comprising: PTFE; 5% to 15% by weight of a metal oxide, preferably 5% to 12% by weight, still more preferably 5% to 10% by weight; 15% to 30% by weight of a lubricant, preferably 20% to 27% by weight; and 0.1% to 1% by weight of a wetting agent, preferably 0.3% to 0.7% by weight;

(3) the percentages by weight being given relative to the total weight of PTFE.

(4) The term “PTFE” means an unmodified or modified PTFE. The term “modified” refers to a branched PTFE wherein the branch is bonded to the carbon chain of the PTFE via an oxygen atom.

(5) The term “normal density” means a material based on PTFE with a density of more than 1.45.

(6) The term “metal oxide” principally means oxides of alkaline-earth metals, transition metals, and poor metals. Advantageously, the metal oxide is selected from the group constituted by titanium dioxide, alumina, zinc oxide, copper oxide, magnesium oxide, and silver oxide.

(7) Once extruded, the PTFE material as prepared above has the following composition: PTFE; 5% to 15% by weight of a metal oxide, preferably 5% to 12% by weight, still more preferably 5% to 10% by weight; and traces of a lubricant and/or a wetting agent;

(8) the percentages by weight being given relative to the total weight of PTFE.

(9) Preferably, the lubricant is a hydrocarbon-based liquid such as an isoparaffinic hydrocarbon, in particular Isopar™, and the wetting agent is a fatty alcohol, advantageously dodecan-1-ol. The wetting agent can provide the PTFE with better miscibility with the fillers and thus promotes the production of a homogeneous mixture.

(10) Isopar™ (Exxon Mobil Chemical) is a high-purity mixture of synthetic isoparaffinic hydrocarbons.

(11) The material of the invention can thus be used to dissipate the electrons created during partial discharge (anti-corona effect). The percentages chosen for the metal oxide and for the lubricant, together with the presence of a wetting agent, can result in a final high-density PTFE material. In addition, this material may be prepared by extrusion.

(12) Advantageously, the grain size and the specific surface area of the metal oxide particles should be controlled. The grain size should preferably be in the range 10 nm [nanometer] to 1 μm [micrometer], preferably in the range 150 nm to 500 nm. Similarly, metal oxide particles with a specific surface area in the range 3 m.sup.2/g [square meter per gram] to 200 m.sup.2/g, preferably in the range 5 m.sup.2/g to 50 m.sup.2/g, are preferred.

(13) In one embodiment of the invention, the material also comprises 0 to 3% by weight of a pigment.

(14) For an application in the field of electric cables, the material of the invention is in the form of a tape, generally several kilometers long and 3 mm [millimeter] to 400 mm in width after extrusion and trimming. When offered for sale, the width of the tape is advantageously 5 mm to 30 mm.

(15) The invention also provides a process for producing a PTFE material as described above, comprising the steps consisting in: mixing the PTFE, the metal oxide, the lubricant, the wetting agent and the optional pigment; and extruding the product resulting from the mixing step.

(16) Preferably, the above-described mixing step is carried out in two stages. The process thus comprises the following steps, consisting in: preparing a first mixture comprising the metal oxide and the powdered PTFE; preparing a second mixture comprising the lubricant, the wetting agent and the optional pigment; spraying the second mixture onto the first mixture; homogenizing and then screening the resulting product; and extruding the resulting product.

(17) This process can be used to obtain a more homogeneous product since it limits aggregates considerably. During the subsequent calendering step, the presence of aggregates in the material is a critical element because the final tape obtained must be very thin, of the order of 50 μm to 200 μm in thickness.

(18) As mentioned above, the process in general comprises two additional steps after extrusion: calendering; and drying.

(19) Calendering is carried out at a pressure of more than 150 bar and drying at a temperature of 130° C. to 230° C.

(20) The tape may be delivered uncured when it is intended to be used as a starting material, or cured when it has already been formed into the finished product. The curing step is carried out in an oven at a temperature of less than 450° C., preferably less than 400° C.

(21) Finally, the invention provides the various uses of the material of the invention.

(22) In accordance with a first use, the material of the invention is an electrical insulator, particularly suitable for the production of electric cables. In particular, the characteristics of this material make it a material of choice for applications in the aviation field.

(23) Thus, the invention provides an electric cable comprising a tape formed from a material of the invention wound around a conductive core.

(24) The term “conductive core” means a strand that allows conduction, such as a strand of copper or alumina several millimeters in diameter, optionally treated with silver to improve the conductivity.

(25) The same cable may include one or more conductive cores. They may be surrounded by a polyimide film, for example Kapton® (Dupont), before winding with one or more tapes of the invention.

(26) Advantageously, the cable may be prepared by means of a process comprising the steps consisting in: winding a tape around a conductive core; and curing the cable at a temperature of less than 450° C., preferably less than 400° C.

(27) In accordance with a second use, the material of the invention is used as an electrical insulator, in particular in the aviation field. In fact, in addition to its anti-corona effect, the material of the invention advantageously has heat resistant properties.

(28) The invention can be better understood from the following example, given purely by way of illustration.

EXAMPLE 1

Comparison of Two Formulations of PTFE Material

(29) Formulations:

(30) TABLE-US-00001 Formulation 1 Formulation 2 PTFE powder (kg) 10 10 Filler ZnO Al.sub.2O.sub.3 Quantity of filler (kg) 1 1 Grain size (nm) 500 100 Specific surface area (m.sup.2/g) 15 10 Isopar.sup. ™ (kg) 2.5 2.9 Density (in finished product) 1.5 1.38

(31) Production Process:

(32) The process comprises three steps: mixing; extrusion/calendering; trimming/packaging.

(33) Mixing: the metal oxide and the PTFE powder are mixed in order to constitute the first mixture. Advantageously, this first mixture is screened to avoid the presence of aggregates. The lubricant (Isopar), the wetting agent and the optional pigments are then mixed to form a second mixture. The second mixture is then sprayed over the first mixture and the resulting product is then mixed again and screened to make it homogeneous.

(34) Extrusion/calendering: the product is then compacted to produce a preform, in general a cylinder 30 cm [centimeter] high and 10 cm in diameter. These preforms are then extruded and calendered to obtain a tape of the desired thickness (for example 76 μm). This tape is then fed into an oven to evaporate off the lubricant, and is wound onto a reel.

(35) Trimming/packaging: this final step can be used to package the tape (for example coiled or on a universal reel).

(36) The tape may be delivered to clients uncured. When used on the cable, it undergoes a heat treatment at a maximum temperature of 450° C., preferably 380° C.

CONCLUSION

(37) Example 1 can be used to obtain a tape that can be used, in contrast to Example 2. The tape of Example 2 had a tacky texture (delamination) and its density was non-homogeneous.