SEMICONDUCTOR STRUCTURE AND FORMING METHOD THEREOF
20220037489 · 2022-02-03
Inventors
Cpc classification
H01L29/66575
ELECTRICITY
H01L29/7833
ELECTRICITY
H01L29/7835
ELECTRICITY
H01L29/0607
ELECTRICITY
H01L29/517
ELECTRICITY
H01L21/28176
ELECTRICITY
H01L29/513
ELECTRICITY
H01L29/6656
ELECTRICITY
H01L29/66659
ELECTRICITY
H01L29/4941
ELECTRICITY
International classification
H01L29/423
ELECTRICITY
Abstract
A semiconductor structure and a forming method thereof are provided. The forming method includes: providing a semiconductor substrate including a source region and a drain region spaced apart; and forming a gate oxide layer, an interface layer and a gate layer on one side of the semiconductor substrate. The gate oxide layer, the interface layer and the gate layer are all disposed between the source region and the drain region. The interface layer is disposed on one side of the gate oxide layer facing away from the semiconductor substrate. The gate layer is disposed on one side of the interface layer facing away from the gate oxide layer. The area of orthographic projection of the interface layer on the semiconductor substrate is smaller than the area of orthographic projection of the gate oxide layer on the semiconductor substrate.
Claims
1. A forming method of a semiconductor structure, comprising: providing a semiconductor substrate comprising a source region and a drain region spaced apart; and forming a gate oxide layer, an interface layer and a gate layer on one side of the semiconductor substrate, wherein the gate oxide layer, the interface layer and the gate layer are all disposed between the source region and the drain region, the interface layer is disposed on one side of the gate oxide layer facing away from the semiconductor substrate, the gate layer is disposed on one side of the interface layer facing away from the gate oxide layer, and an area of orthographic projection of the interface layer on the semiconductor substrate is smaller than an area of orthographic projection of the gate oxide layer on the semiconductor substrate.
2. The forming method of claim 1, wherein a dielectric constant of the interface layer is greater than that of the gate oxide layer.
3. The forming method of claim 1, further comprising: forming a barrier layer on a surface and a side wall of a structure constituted by the interface layer and the gate layer together.
4. The forming method of claim 1, wherein the forming the gate oxide layer, the interface layer and the gate layer on one side of the semiconductor substrate comprises: sequentially forming a gate oxide layer, an interface layer and a gate layer on a surface of the semiconductor substrate by adopting an atomic layer deposition process; etching the gate oxide layer, the interface layer and the gate layer by utilizing photolithographic patterning and etching; and etching a side wall of the interface layer by adopting an isotropic etching process, to enable a width of the interface layer to be smaller than that of the gate oxide layer.
5. The forming method of claim 4, wherein the etching the gate oxide layer, the interface layer and the gate layer by utilizing photolithographic patterning and etching comprises: forming a photoresist layer on one side of the gate layer facing away from the interface layer; exposing and developing the photoresist layer, to form a developing region within which the surface of the gate layer is exposed; etching the gate oxide layer, the interface layer and the gate layer in the developing region to form a gate structure; and removing the photoresist layer.
6. The forming method of claim 3, further comprising: forming an isolation layer on one side of the barrier layer facing away from the side wall, wherein one end of the isolation layer is flush with one side of the gate layer facing away from the interface layer, and the other end of the isolation layer is in contact with a surface of the semiconductor substrate.
7. The forming method of claim 1, wherein the gate layer comprises a first dielectric layer, a second dielectric layer and a gate electrode layer, the second dielectric layer is disposed between the first dielectric layer and the gate electrode layer, the first dielectric layer is disposed on a surface of the interface layer facing away from the gate oxide layer, and a material of the second dielectric layer is titanium nitride.
8. The forming method of claim 2, wherein the gate layer comprises a first dielectric layer, a second dielectric layer and a gate electrode layer, the second dielectric layer is disposed between the first dielectric layer and the gate electrode layer, the first dielectric layer is disposed on a surface of the interface layer facing away from the gate oxide layer, and a material of the second dielectric layer is titanium nitride.
9. The forming method of claim 3, wherein the gate layer comprises a first dielectric layer, a second dielectric layer and a gate electrode layer, the second dielectric layer is disposed between the first dielectric layer and the gate electrode layer, the first dielectric layer is disposed on a surface of the interface layer facing away from the gate oxide layer, and a material of the second dielectric layer is titanium nitride.
10. The forming method of claim 4, wherein the gate layer comprises a first dielectric layer, a second dielectric layer and a gate electrode layer, the second dielectric layer is disposed between the first dielectric layer and the gate electrode layer, the first dielectric layer is disposed on a surface of the interface layer facing away from the gate oxide layer, and a material of the second dielectric layer is titanium nitride.
11. The forming method of claim 5, wherein the gate layer comprises a first dielectric layer, a second dielectric layer and a gate electrode layer, the second dielectric layer is disposed between the first dielectric layer and the gate electrode layer, the first dielectric layer is disposed on a surface of the interface layer facing away from the gate oxide layer, and a material of the second dielectric layer is titanium nitride.
12. The forming method of claim 6, wherein the gate layer comprises a first dielectric layer, a second dielectric layer and a gate electrode layer, the second dielectric layer is disposed between the first dielectric layer and the gate electrode layer, the first dielectric layer is disposed on a surface of the interface layer facing away from the gate oxide layer, and a material of the second dielectric layer is titanium nitride.
13. The forming method of claim 7, wherein the semiconductor substrate further comprises: a drain epitaxial region adjacent to the drain region, wherein other end of the drain epitaxial region is adjacent to an end portion of the gate oxide layer close to the drain region, and a doping concentration of the drain epitaxial region is smaller than that of the drain region.
14. The forming method of claim 13, wherein the semiconductor substrate further comprises: a source epitaxial region, wherein one end of the source epitaxial region is adjacent to the source region, the other end of the source epitaxial region is adjacent to an end portion of the gate oxide layer close to the source region, and a doping concentration of the source epitaxial region is smaller than that of the source region.
15. A semiconductor structure, manufactured by the forming method of the semiconductor structure of any one of claim 1.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0011] The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the present disclosure and, together with the specification, serve to explain the principles of the present disclosure. It is apparent to those of ordinary skill in the art that the drawings in the following description only illustrate some embodiments of the present disclosure, and other drawings may be obtained by those of ordinary skill in the art from these drawings without any creative effort.
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[0025] In the drawings: 100 semiconductor substrate; 101 drain region; 110 gate oxide layer; 120 gate layer; 1 semiconductor substrate; 11 source region; 12 drain region; 13 source epitaxial region; 14 drain epitaxial region; 2 gate oxide layer; 3 interface layer; 4 gate layer; 41 first dielectric layer; 42 gate electrode layer; 43 second dielectric layer; 5 barrier layer; 6 isolation layer; 61 first isolation layer; 62 second isolation layer; 63 third isolation layer.
DETAILED DESCRIPTION
[0026] Exemplary embodiments will now be described more fully with reference to the accompanying drawings. However, the exemplary embodiments can be implemented in a variety of forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided to make the present disclosure thorough and complete, and the concepts of the example embodiments are fully communicated to those skilled in the art. The same reference numerals in the drawings indicate the same or similar structures, and thus the detailed descriptions thereof are omitted.
[0027] Although relative terms, such as “on” and “under”, are used in this specification to describe a relative relationship between one component and another component represented in the drawings, these terms are used in this specification only for convenience, for example, according to the directions of the examples described in the drawings. It will be appreciated that if a device illustrated in the drawings is flipped upside down, a component described as being “on” another component becomes a component described as being “under” the another component. When a structure is described as being “on” another structure, it may mean that the structure is integrally formed on the another structure, or the structure is “directly” disposed on the another structure, or the structure is “indirectly” disposed on the another structure through a structure.
[0028] The terms “one”, “a/an”, “the”, and “said” are used to indicate one or more elements/components/etc. The terms “including” and “having” are open-type inclusive and mean that there may be additional elements/components/etc. in addition to the listed elements/components/etc. The terms “first” and “second” are used merely as labels and are not intended to limit the number of objects.
[0029] In the related art, as shown in
[0030] The embodiments of the present disclosure provide a forming method of a semiconductor structure. As shown in
[0031] In S110, a semiconductor substrate is provided. The semiconductor substrate includes a source region and a drain region spaced apart.
[0032] In S120, a gate oxide layer, an interface layer and a gate layer are formed on one side of the semiconductor substrate. The gate oxide layer, the interface layer and the gate layer are all disposed between the source region and the drain region. The interface layer is disposed on one side of the gate oxide layer facing away from the semiconductor substrate. The gate layer is disposed on one side of the interface layer facing away from the gate oxide layer. The area of orthographic projection of the interface layer on the semiconductor substrate is smaller than the area of orthographic projection of the gate oxide layer on the semiconductor substrate.
[0033] According to the forming method of the semiconductor structure, since the interface layer is disposed between the gate oxide layer and the gate layer, a physical size between the gate layer and the drain region is increased, and an electric field between a drain and a gate is reduced, so that a drain leakage current is reduced. Therefore, the standby power consumption can be effectively reduced, and the device reliability can be improved. Also, breakdown of the gate oxide layer is effectively avoided due to the increase of the size.
[0034] The operations of the forming method according to the embodiment of the present disclosure are described in detail below.
[0035] As shown in
[0036] The material of the semiconductor substrate may be but not limited to silicon, and may also be other materials, which is not limited thereto. As shown in
[0037] In an embodiment, the source region 11 and the drain region 12 may be implanted with phosphorus ions by ion implantation. In practice, other processes may be adopted to dope the source region 11 and/or the drain region 12, which is not limited herein.
[0038] It should be noted that there may be a channel region between the source region 11 and the drain region 12. A current may flow in the channel region, and the current in the channel region may be controlled by a potential of the gate layer 4 to achieve a gate control function.
[0039] As shown in
[0040] As shown in
[0041] The gate oxide layer 2 is formed right above the channel region of the semiconductor substrate 1, and may be a thin film formed on the surface of the semiconductor substrate 1 or a coating layer formed on the surface of the semiconductor substrate 1, which is not limited herein.
[0042] The interface layer 3 is arranged on one side of the gate oxide layer 2 facing away from the semiconductor substrate 1, so that the physical size between the gate layer 4 and the drain region 12 can be increased, the electric field between the drain region 12 and the gate layer 4 is reduced, thereby reducing the drain leakage current. Therefore, the standby power consumption can be effectively reduced, and the device reliability can be improved. Also, the GIDL effect is reduced due to the arrangement of the interface layer 3, and the breakdown of the gate oxide layer 2 can be effectively avoided.
[0043] The gate layer 4 is arranged on one side of the interface layer 3 facing away from the gate oxide layer 2 and is used for controlling electric field intensity on a surface of a source or a drain, thereby controlling a current between the source and the drain. The gate layer 4 may be a thin film formed on the surface of the interface layer 3 facing away from the gate oxide layer 2, or may be a coating layer formed on the surface of the interface layer 3 facing away from the gate oxide layer 2, which is not limited herein.
[0044] In an embodiment, the gate layer 4 may include a first dielectric layer 41 and a gate electrode layer 42. The first dielectric layer 41 may be arranged between the gate electrode layer 42 and the interface layer 3, the material of the first dielectric layer 41 may be polysilicon or doped polysilicon, or the like, and the material of the gate electrode layer 42 may be metal tungsten.
[0045] In an embodiment, as shown in
[0046] In an embodiment, as shown in
[0047] In S1210, a gate oxide layer, an interface layer and a gate layer are sequentially formed on the surface of the semiconductor substrate by adopting an atomic layer deposition process.
[0048] As shown in
[0049] The material of the gate oxide layer 2 may include silicon dioxide, a high-k dielectric material or other dielectric materials. The thickness of the gate oxide layer may range from 20 Å to 30 Å, for example, 20 Å, 22 Å, 24 Å, 26 Å, 28 Å, or 30 Å.
[0050] The interface layer 3 is formed on the surface of the gate oxide layer 2 facing away from the semiconductor substrate 1. The material of the interface layer may be silicon nitride or other high-k dielectrics. The thickness of the interface layer may range 50 Å to 100 Å, for example, 50 Å, 60 Å, 70 Å, 80 Å, 90 Å, or 100 Å.
[0051] In some embodiments, the interface layer 3 may be formed on the gate oxide layer 2 by a process such as chemical vapor deposition, physical vapor deposition, atomic layer deposition, spin coating, ink jet, screen printing, coating, or vacuum evaporation, which is not limited herein.
[0052] The gate layer 4 is formed on one side of the interface layer 3 facing away from the gate oxide layer 2. In some embodiments, the gate layer 4 may be formed by a process such as chemical vapor deposition, vacuum evaporation, or atomic layer deposition. When the gate layer 4 has a multilayer structure, layer-by-layer deposition may be performed, and a molding process corresponding to a material type of each layer may be selected according to the material type.
[0053] In an embodiment, the gate layer 4 may include a first dielectric layer 41, a second dielectric layer 43 and a gate electrode layer 42. The material of the first dielectric layer 41 may be polysilicon. The material of the second dielectric layer 43 may be titanium nitride. The material of the gate electrode layer 42 may be metal tungsten. The first dielectric layer 41 may be formed on the interface layer 3 by adopting an atomic layer deposition process. The second dielectric layer 43 may be formed on the first dielectric layer 41 by adopting a chemical vapor deposition process. The gate electrode layer 42 may be formed above the second dielectric layer 43 by vacuum evaporation. In some embodiments, the gate layer 4 may further include other layers, and the layers may be formed by adopting other processes, which is not limited herein.
[0054] In S1220, the gate oxide layer, the interface layer and the gate layer are etched by photolithographic patterning and etching.
[0055] The gate oxide layer 2, the interface layer 3 and the gate layer 4 are etched by photolithographic patterning and etching to form a gate structure. That is, the gate structure includes a gate oxide layer 2, an interface layer 3 and a gate layer 4 right above the channel region between the source region 11 and the drain region 12.
[0056] In an embodiment, as shown in
[0057] In S1221, a photoresist layer is formed on one side of the gate layer facing away from the interface layer.
[0058] A photoresist layer may be formed on one side of the gate layer 4 facing away from the interface layer 3 by spin coating or other manners. The material of the photoresist layer may be a positive photoresist or a negative photoresist, which is not limited herein.
[0059] In S1222, the photoresist layer is exposed and developed, to form a developing region within which the surface of the gate layer is exposed.
[0060] The photoresist layer is exposed by a mask. A pattern of the mask is matched with patterns required by the gate oxide layer 2, the interface layer 3 and the gate layer 4. Subsequently, the exposed photoresist layer is developed to form a developing region, a pattern of which is the same as the patterns required by the gate oxide layer 2, the interface layer 3 and the gate layer 4.
[0061] In S1223, the gate oxide layer, the interface layer and the gate layer are etched in the developing region to form a gate structure.
[0062] The etching method may include processes such as dry etching, wet etching or plasma etching. It should be noted that the etching of the gate oxide layer 2, the interface layer 3 and the gate layer 4 may be implemented by performing photoetching process one time, and the gate oxide layer 2, the interface layer 3 and the gate layer 4 may be sequentially etched respectively. That is, only one layer is etched at a time. The gate oxide layer 2 is etched, the interface layer 3 is then etched, and the gate oxide layer 2 is finally etched.
[0063] In S1224, the photoresist layer is removed.
[0064] After the etching process is completed, the photoresist layer on the surface of the gate layer 4 may be removed by cleaning with a cleaning solution or by a process such as ashing.
[0065] In S1230, a side wall of the interface layer is etched by adopting an isotropic etching process so that the width of the interface layer is smaller than that of the gate oxide layer.
[0066] As shown in
[0067] In an embodiment, the forming method of the semiconductor structure of the present disclosure may further include the following operation S130.
[0068] In S130, a barrier layer is formed on a surface and a side wall of a structure constituted by the interface layer and the gate layer together.
[0069] As shown in
[0070] In an embodiment, the material of the barrier layer 5 is silicon dioxide. The thickness of the barrier layer may range 30 Å to 50 Å, for example, 30 Å, 35 Å, 40 Å, 45 Å, or 50 Å.
[0071] In an embodiment, the forming method of the semiconductor structure of the present disclosure may further include the following operations S140.
[0072] In S140, an isolation layer is formed on one side of the barrier layer facing away from the side wall. One end of the isolation layer is flush with one side of the gate layer facing away from the interface layer, and the other end of the isolation layer is in contact with the surface of the semiconductor substrate.
[0073] As shown in
[0074] In an embodiment, the isolation layer 6 may have a multilayer structure, and may include a first isolation layer 61, a second isolation layer 62 and a third isolation layer 63. The first isolation layer 61 may be adjacent to the barrier layer 5. The second isolation layer 62 may be located between the first isolation layer 61 and the third isolation layer 63. A material of the first isolation layer 61 may be silicon nitride, a material of the second isolation layer 62 may be silicon oxide, and a material of the third isolation layer 63 may be silicon nitride.
[0075] In an embodiment, the semiconductor substrate 1 further includes a drain epitaxial region 14. As shown in
[0076] In addition, a doping concentration of the drain epitaxial region 14 is smaller than that of the drain region 12. In an embodiment, the drain epitaxial region 14 and the drain region 12 have the same doping type. In an embodiment, a n-type doping material may be doped within the drain epitaxial region 14, to form the drain epitaxial region 14 into an n-type semiconductor. The n-type doping material may be an element located in Group IV in the Periodic Table of the Elements, for example, phosphorus.
[0077] The drain epitaxial region 14 may be implanted with phosphorus ions by ion implantation. In practical, other processes may be adopted to dope the drain epitaxial region 14, which is not limited herein. It should be noted that in a first embodiment of the present disclosure, as shown in
[0078] In an embodiment, the semiconductor substrate 1 may further include a source epitaxial region 13. The source epitaxial region 13 is disposed between the source region 11 and the drain region 12 and may be adjacent to the source region 11. An end portion of the source epitaxial region deviating from the source region 11 may be adjacent to an end portion of the gate oxide layer 2 close to the source region 11, which can reduce the channel electric field, and reduce the hot carrier effect.
[0079] In addition, a doping concentration of the source epitaxial region 13 is smaller than that of the source region 11. In an embodiment, the source epitaxial region 13 and the source region 11 have the same doping type. In some embodiment, a n-type doping material may be doped within the source epitaxial region 13, to form the source epitaxial region 13 into an n-type semiconductor. The n-type doping material may be an element located in Group IV in the Periodic Table of the Elements, for example, phosphorus.
[0080] The source epitaxial region 13 may be implanted with phosphorus ions by ion implantation. In practical, other processes may be adopted to dope the source epitaxial region 13, which is not limited herein. It should be noted that the source epitaxial region 13 may be doped by ion implantation after the gate oxide layer 2, the interface layer 3 and the gate layer 4 are formed. The source epitaxial region 13 may also be doped before the gate oxide layer 2, the interface layer 3 and the gate layer 4 are formed, which is not limited herein.
[0081] It should be noted that during formation, both the source region 11 and the drain region 12 may be bilaterally doped, or any one of the source region 11 or the drain region 12 may be unilaterally doped, which is not limited herein.
[0082] The embodiments of the present disclosure further provide a semiconductor structure which is manufactured by the forming method of the semiconductor structure in any one of the embodiments described above. Referring to
[0083] After considering the specification and implementing the disclosure disclosed here, other implementation solutions of the present disclosure would readily be conceivable to those skilled in the art. The present disclosure is intended to cover any variations, usage, or adaptations of the present disclosure. These variations, usage, or adaptations conform to the general principles of the disclosure and include such departures from the present disclosure as come within known or customary practice in the art. The specification and embodiments are only regarded as exemplary, and the true scope and spirit of the present disclosure are indicated by the appended claims.