EXTERNAL MICRO-INTERFACE PAPERMAKING WASTEWATER TREATMENT SYSTEM AND WASTEWATER TREATMENT METHOD THEREOF
20220267182 · 2022-08-25
Assignee
Inventors
- Zhibing ZHANG (Nanjing, CN)
- Zheng ZHOU (Nanjing, CN)
- Feng ZHANG (Nanjing, CN)
- Lei LI (Nanjing, CN)
- Weimin MENG (Nanjing, CN)
- Baorong WANG (Nanjing, CN)
- Gaodong YANG (Nanjing, CN)
- Huaxun LUO (Nanjing, CN)
- Guoqiang YANG (Nanjing, CN)
- Hongzhou TIAN (Nanjing, CN)
- Yu CAO (Nanjing, CN)
Cpc classification
C02F1/52
CHEMISTRY; METALLURGY
C02F2301/08
CHEMISTRY; METALLURGY
Y02W10/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C02F2303/24
CHEMISTRY; METALLURGY
C02F2209/08
CHEMISTRY; METALLURGY
C02F9/00
CHEMISTRY; METALLURGY
C02F1/001
CHEMISTRY; METALLURGY
C02F2303/26
CHEMISTRY; METALLURGY
International classification
C02F9/00
CHEMISTRY; METALLURGY
Abstract
An external micro-interface papermaking wastewater treatment system and a wastewater treatment method are proposed. The wastewater treatment system includes a grating water collection tank, a first coagulation sedimentation tank, an inclined screen and a second coagulation sedimentation tank which are connected in sequence, a heat exchanger, a preheater and a wet oxidation reactor, wherein the heat exchanger is provided with a first inlet, a first outlet, a second inlet and a second outlet. A feed inlet is disposed on a side wall of the wet oxidation reactor, an oxidation water outlet is disposed on a top of the wet oxidation reactor, the feed inlet is connected with a micro-interface generator for dispersing and breaking gas into gas bubbles, a liquid phase inlet and a gas phase inlet are disposed on the micro-interface generator, and the gas phase inlet is connected with an air compressor.
Claims
1. An external micro-interface papermaking wastewater treatment system, comprising a grating water collection tank, a first coagulation sedimentation tank, an inclined screen and a second coagulation sedimentation tank which are connected in sequence, a heat exchanger, a preheater and a wet oxidation reactor, wherein the heat exchanger is provided with a first inlet, a first outlet, a second inlet and a second outlet; a feed inlet is disposed on a side wall of the wet oxidation reactor, an oxidation water outlet is disposed on a top of the wet oxidation reactor, the feed inlet is connected with a micro-interface generator for dispersing and breaking gas into gas bubbles, a liquid phase inlet and a gas phase inlet are disposed on the micro-interface generator, and the gas phase inlet is connected with an air compressor; wherein the micro-interface generator is a pneumatic micro-interface generator, a number of the micro-interface generator is more than one, and the micro-interface generators arranged in parallel from top to bottom; wherein the first inlet is in communication with the second coagulation sedimentation tank, the first outlet is in communication with the liquid phase inlet of the micro-interface generator through the preheater, the second inlet is in communication with the oxidation water outlet, and the second outlet is connected with an aeration biological filtration tank.
2. (canceled)
3. The external micro-interface papermaking wastewater treatment system according to claim 1, further comprising: a sludge tank connected to both the first coagulation sedimentation tank and the second coagulation sedimentation tank.
4. The external micro-interface papermaking wastewater treatment system according to claim 1, wherein the first coagulation sedimentation tank is composed of two or more coagulation sedimentation tanks connected in series; and the second coagulation sedimentation tank is composed of two or more coagulation sedimentation tanks connected in series.
5. The external micro-interface papermaking wastewater treatment system according to claim 1, wherein the second coagulation sedimentation tank comprises three filter layers arranged from top to bottom, and each filter layer is filled with a flocculating sub stance.
6. The external micro-interface papermaking wastewater treatment system according to claim 1, further comprising: an ion exchanger, and the ion exchanger is connected to the aeration biological filtration tank for neutralizing alkalis in wastewater.
7. The external micro-interface papermaking wastewater treatment system according to claim 6, further comprising: a COD concentration monitoring device and a disinfection tank, wherein the COD concentration monitoring device is connected to the ion exchanger for monitoring a water quality and discharging a qualified water into the disinfection tank, and the COD concentration monitoring device is connected with the aeration biological filtration pond for returning an unqualified water into the aeration biological filtration tank for further treatment.
8. The external micro-interface papermaking wastewater treatment system according to claim 7, wherein a first solenoid valve is disposed on a first connection pipeline between the COD concentration monitoring device and the disinfection tank, and a second solenoid valve is disposed on a second connection pipeline between the COD concentration monitoring device and the aeration biological filter tank.
9. A wastewater treatment method by using the external micro-interface papermaking wastewater treatment system according to claim 1, comprising the following steps: a wastewater first enters the grating water collection tank to remove large-scale floating and suspended matters, and then enters the first coagulation sedimentation tank to flocculate and settle SS pollutants in the wastewater; the wastewater settled by the first coagulation settling enters the inclined screen to recover fibers in the wastewater; the wastewater passing through the inclined screen then enters the second coagulation sedimentation tank for treatment; and the wastewater treated in the described steps is heated and then enters the micro-interface generator, and compressed air or oxygen is introduced into the micro-interface generator at the same time, and after dispersed and broken micro-bubbles and the wastewater are fully emulsified in the micro-interface generator, and then enters the wet oxidation reactor for wet oxidation treatment; and a product after wet oxidation treatment enters the aeration biological filtration tank for biological oxidation treatment after heat exchange and cooling.
10. The wastewater treatment method according to claim 9, wherein a reaction temperature of the wet oxidation treatment is 170-180° C., and a reaction pressure is 3-3.5 MPa.
11. The wastewater treatment method according to claim 10, wherein the reaction temperature of the wet oxidation treatment is 175° C., and the reaction pressure is 3.2 MPa.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0030] By reading the detailed description of the preferred embodiments below, various other advantages and benefits will become clear to those of ordinary skill in the art. The drawings are only used for the purpose of illustrating the preferred embodiments, and are not considered as a limitation to the invention. Also, throughout the drawings, the same reference numerals are used to denote the same components. In the drawings:
[0031]
DETAIL DESCRIPTION
[0032] In order to make the purpose and advantages of the invention clearer, the invention will be further described below in conjunction with the embodiments. It should be understood that the specific embodiments described here are only used to explain the invention, and are not used to limit the invention.
[0033] Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the scope of the present invention. If specific conditions are not indicated in the embodiments, it shall be carried out in accordance with the conventional conditions or the conditions recommended by the manufacturer. The reagents or instruments used without the manufacturer's indication are all conventional products that can be purchased on the market.
[0034] It should be understood that in the description of the invention, orientations or position relationships indicated by terms upper, lower, front, back, left, right, inside, outside and the like are orientations or position relationships are based on the direction or position relationship shown in the drawings, which is only for ease of description, rather than indicating or implying that the device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation of the invention. In addition, the terms “first”, “second”, and “third” are only used for descriptive purposes, and cannot be understood as indicating or implying relative importance.
[0035] Further, it should also be noted that in the description of the invention, terms “mounting”, “connected” and “connection” should be understood broadly, for example, may be fixed connection and also may be detachable connection or integral connection; may be mechanical connection and also may be electrical connection; and may be direct connection, also may be indirection connection through an intermediary, and also may be communication of interiors of two components. Those skilled in the art may understand the specific meaning of terms in the invention according to specific circumstance.
[0036] In order to explain the technical solutions of the present invention more clearly, specific embodiments are used for description below.
EMBODIMENTS
[0037] Referring to
[0038] Specifically, after being heat exchanged in the heat exchanger 50 and then being heated by the preheater 60, the wastewater enters the micro-interface generator 80 from the liquid phase inlet 81, and air or oxygen enters the micro-interface generator 80 through the gas-phase inlet 82 after being compressed by the air compressor 90 and is dispersed and broken into bubbles. The air compressor 90 is preferably a centrifugal air compressor, because the centrifugal air compressor has a large amount of air, does not need lubrication inside, saves oil and does not pollute the compressed gas.
[0039] The compressed air or oxygen is dispersed into air bubbles, sufficiently emulsified with the wastewater in the micro-interface generator 80, and then enters the wet oxidation reactor 70 for an oxidation reaction, by means of the effect of the micro-interface generator, increasing the contact area of the gas-liquid two phases, and improving the mass transfer effect. It should be understood that the described micro-interface generators 80 is not limited to the number. In order to improve the dispersion and mass transfer effects, additional micro-interface generators can be additionally provided. Multiple micro-interface generators can be provided in series or in parallel before the wet oxidation reactor 70. Preferably, the micro-interface generators are provided in parallel from top to bottom. In this embodiment, the type of the micro-interface generator is a pneumatic micro-interface generator, and compressed air or oxygen is used as a power drive.
[0040] The heat exchanger 50 of the embodiment is provided with a first inlet 51, a first outlet 52, a second inlet 53, and a second outlet 54; the second coagulation sedimentation tank 40 is preferably connected to the first inlet 51 through a booster pump. The first outlet 52 is connected to the liquid phase inlet 81 of the micro-interface generator 80 through the pre-heater 60. Before the wastewater passes through the heat exchanger 50 and enters the liquid phase inlet 81, pre-heating is performed. An oxidation water outlet 71 is further disposed at the top of the wet oxidation reactor 70. The oxidation water outlet is connected to the second inlet 53. The oxidation water from the oxidation water outlet 71 enters the heat exchanger 50 through the second inlet 53 for heat exchange. The oxidation water to be treated is heated while being cooled, thereby achieving the purpose of fully utilizing energy. Then, the oxidation water after heat exchange enters the aeration biological filtration tank 100 passing through the second outlet 54. Preferably, a condenser can be added between the second outlet 54 and the aeration biological filtration tank 100, and the oxidation water is cooled before entering the aeration biological filtration tank 100 after heat exchange.
[0041] In the present embodiment, the wastewater treatment system further includes an ion exchanger 110, a COD concentration detection device 120 and a disinfection tank 130. The ion exchanger 110 is connected with the aeration biological filtration tank 100 and is used for neutralizing alkali in wastewater. The COD concentration monitoring device 120 is connected with the ion exchanger 110 and is used for monitoring water quality and discharging qualified water into the disinfection tank 130. The COD concentration monitoring device 120 is connected with the aeration biological filtration tank 100. In addition, a first solenoid valve 150 is disposed on a connection pipeline between the COD concentration monitoring device 120 and the disinfection tank 130; and a second solenoid valve 160 is disposed on a connection pipeline between the COD concentration monitoring device 120 and the aeration biological filtration tank 100.
[0042] Specifically, the ion exchanged clean water first enters the COD concentration monitoring device 120 for monitoring the concentration of the COD in the water. If the concentration of the COD in the clean water is lower than a pre-set value, the requirements are satisfied, and recycling can be performed. A first solenoid valve 150 is turned on and the water enters a disinfection tank 130 for ultraviolet or ozone disinfection. If the COD concentration of the clean water is higher than the pre-set value, the second solenoid valve is opened, and the water is returned to the aeration biological filtration tank 100 passing through the pipeline for biological purification again.
[0043] The working process and principle of the external micro-interface papermaking wastewater treatment system of the present invention are briefly described below: a papermaking wastewater first enters a grating water collection tank 10 to remove large-scale floating and suspended matter, and then enters the first coagulation sedimentation tank 20 to flocculate and settle SS pollutants in the wastewater; the wastewater settled by the first coagulation settling enters the inclined screen 30 to recover fibers in water; the wastewater passing through the inclined screen then enters the second coagulation sedimentation tank 40 for treatment; the wastewater treated in the described steps enters the micro-interface generator 80 after being heated, and compressed air or oxygen is introduced into the micro-interface generator 80, and after dispersed and broken micro-bubbles and wastewater are fully emulsified in the micro-interface generator 80, and then enters the wet oxidation reactor 70 for wet oxidation treatment; and the reaction temperature of the wet oxidation treatment is 170-180° C., and the reaction pressure is 3-3.5 MPa. Preferably the reaction temperature is 175° C., and the reaction pressure is 3.2 MPa. The oxidation product enters the heat exchanger 50 through the oxidation water outlet 71, exchanges heat with the wastewater to be treated, and then enters the aeration biological filtration tank 100 through the cooler for biodegradation treatment. The biodegraded water is neutralized alkali in the wastewater by the ion exchanger 110, and enters the COD concentration detection device 120 for monitoring water quality and discharging qualified water into the disinfection tank 130 for disinfection and recycling.
[0044] So far, the technical solution of the invention has been described in conjunction with the preferred embodiments shown in the drawings. However, it is easily understood by those skilled in the art that the protection scope of the invention is obviously not limited to these specific embodiments. Without departing from the principle of the invention, those skilled in the art can make equivalent changes or substitutions to the relevant technical features, which will fall into the protection scope of the invention. The above are only preferred embodiments of the invention rather than limits to the invention. Those skilled in the art may make various modifications and changes to the invention. Any modification, equivalent replacement, improvement and the like made within the spirit and principle of the invention all should be included in the protection scope of the invention.