Photoluminescence-Enhanced Sandwich Structure of Luminescent Films and Method

Abstract

A sandwich structure for enhancement of photoluminescence (PL) from luminescent films and the corresponding preparation method are disclosed. The sandwich structure comprises a support, a luminescent film grown on the support, and a single-layer close-packed microsphere array deposited onto the luminescent film. The microspheres have high transmittance excitation light and emitted light, respectively. The low price of dielectric microspheres is beneficial to industrial applications. The stable chemical properties of dielectric microspheres make PL enhanced in a long term. Both metal and non-metal materials can be used as the support in the sandwich structure. These features significantly improve the technique of PL enhancement for luminescent films.

Claims

1. A process for fabricating a sandwich structure of support-film-microspheres for enhancement of photoluminescence from luminescent films, wherein the sandwich structure comprises a support, a luminescent film and a single-layer close-packed microsphere array; the support is attached on one side of the luminescent film and dielectric microspheres are applied on the other side of the luminescent film as the single-layer close-packed microsphere array in which the dielectric microspheres contact each other; characterized in that the process comprising the following steps: i) diluting the dielectric microspheres with a solvent to form suspension liquid; ii) drawing the suspension liquid by a dropper; iii) spreading the suspension liquid on the luminescent film fixed on the support; iv) drying the suspension liquid resulting in the single-layer close-packed microsphere array on the surface of the luminescent film.

2. The process according to claim 1, wherein the solvent is volatile selected from the group consisting of water, ethanol and isopropanol.

3. The process according to claim 1, wherein the concentration of dielectric microspheres in the suspension liquid is between 10.sup.4 and 10.sup.6 μL.sup.−1.

4. The process according to claim 1, wherein the diameters of the dielectric microspheres are between 1.5 and 7.5 μm.

5. The process according to claim 1, wherein the suspension liquid is applied on the luminescent film by drop coating, spraying or immersing.

6. The process according to claim 1, wherein drying the suspension liquid by spontaneous evaporation, heating evaporation or blowing evaporation.

7. The process according to claim 1, wherein the single-layer close-packed microsphere array is self-assembled during drying the suspension liquid.

8. The process according to claim 1, wherein the dielectric microsphere consists of a compound selected from the group consisting of fused silica, polystyrene and polymethylmethacrylate.

9. The process according to claim 1, wherein the luminescent film consists of a compound selected from the group consisting of zinc oxide, gallium nitride and silicon carbide luminescent films.

10. The process according to claim 1, wherein the support consists of a compound selected from the group consisting of titanium, silicon carbide, graphene and alumina.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0017] For a complete understanding of the present invention, and the advantages thereof, the descriptions of the drawings are giving below:

[0018] FIG. 1 shows a schematic diagram illustrating a method to fabricate sandwich structures of SFMs for PL enhancement of luminescent films, on which a single-layer close-packed dielectric microsphere array is capped.

[0019] FIG. 2 shows a reference PL spectrum of zinc oxide (ZnO) film grown on a silicon carbide (SiC) substrate and the enhanced PL spectrum by capping with 5-μm-diameter fused silica (SiO.sub.2) microspheres.

[0020] FIG. 3 shows a reference PL spectrum of zinc oxide (ZnO) film grown on a titanium (Ti) substrate and the enhanced PL spectrum by capping with 5-μm-diameter fused silica (SiO.sub.2) microspheres.

[0021] FIG. 4 shows a reference PL spectrum of zinc oxide (ZnO) film grown on a graphene substrate and the enhanced PL spectrum by capping with 5-μm-diameter fused silica (SiO.sub.2) microspheres.

[0022] FIG. 5 shows a reference PL spectrum of zinc oxide (ZnO) film grown on an alumina (Al.sub.2O.sub.3) substrate and the enhanced PL spectrum by capping with 5-μm-diameter fused silica (SiO.sub.2) microspheres.

[0023] FIG. 6 shows a reference PL spectrum of zinc oxide (ZnO) film grown on a silicon carbide (SiC) substrate and the enhanced PL spectrum by capping with 7.5-μm-diameter fused silica (SiO.sub.2) microspheres.

[0024] FIG. 7 shows a reference PL spectrum of zinc oxide (ZnO) film grown on a silicon carbide (SiC) substrate and the enhanced PL spectrum by capping with 2.5-μm-diameter fused silica (SiO.sub.2) microspheres.

[0025] FIG. 8 shows a reference PL spectrum of zinc oxide (ZnO) film grown on a silicon carbide (SiC) substrate and the enhanced PL spectrum by capping with 1.5-μm-diameter fused silica (SiO.sub.2) microspheres.

[0026] FIG. 9 shows a reference PL spectrum of zinc oxide (ZnO) film grown on a silicon carbide (SiC) substrate and the enhanced PL spectrum by capping with 5-μm-diameter polystyrene (PS) microspheres.

[0027] FIG. 10 shows a reference PL spectrum of zinc oxide (ZnO) film grown on a silicon carbide (SiC) substrate and the enhanced PL spectrum by capping with 5.5-μm-diameter polymethylmethacrylate (PMMA) micro spheres.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

[0028] The following detailed description is recommended to carry out the invention. The description is not to be taken in a limiting sense, but is intended to cover alternatives, modifications and equivalents that may be included within the spirit and scope of the various embodiments as defined by the appended claims.

[0029] In the following description of embodiments, numerous specific details are set forth in order to provide a thorough understanding of the present preparation method. However, the preparation method may be practiced without these specific details.

[0030] As shown in FIG. 1, dielectric microspheres are first diluted to be suspension 101. Then the suspension is drawn by a dropper 102 and deposited onto the luminescent film 104 grown on a support 105 by drop coating 103. The film surface is sufficiently wetted by the suspension drop 106. When the suspension is dried, the microspheres are self-assembled to be a single-layer close-packed array 107 on the luminescent film. The sandwich structure of SFMs is therefore formed.

[0031] As disclosed herein, the solvent used in suspension 101 for dilution of dielectric microspheres is volatile. The concentration of microsphere in suspension is 10.sup.4˜10.sup.6 μL.sup.−1. The volatile solvent may be water, ethanol, isopropanol, etc. The diameter of dielectric microsphere deposited onto the film surface 104 is ranging from 1.5 to 7.5 μm. The film surface can be wetted by the microsphere suspension 101 via drop coating, spraying, or immersing. Furthermore, the luminescent film 104 may be grown on any supports 105. The solvent can be dried by spontaneous evaporation, heating evaporation or blowing evaporation. The single-layer close-packed microsphere array is self-assembled by liquid surface tension during solvent evaporation.

[0032] Presented here is experimental verification that PL enhancement is feasible with various sandwich structures of SFMs. The experiments were performed using commercial microspheres with diameters ranging from 1.5 to 7.5 μm (Bang Laboratories, US). A 325-nm He-Cd fibre-coupled laser (Kimmon KoHa Co., Ltd) was used as the PL excitation source. The backward scattering PL spectra were captured by a spectrograph (Princeton Instruments).

Example 1

[0033] Fused silica (SiO.sub.2) microspheres with average diameters of 5 μm were diluted by isopropanol to form a SiO.sub.2 microsphere suspension 101. The microsphere concentration was about 1×10.sup.5 μL.sup.−1. The suspension was drawn by a dropper 102 and then deposited onto the surface of zinc oxide (ZnO) film 104 grown on a silicon carbide (SiC) substrate 105 by drop coating 102. The film surface was therefore wetted 106. After the isopropanol in suspension was dried by spontaneous evaporation at room temperature, the single-layer close-packed microsphere array 201 was self-assembled and the sandwich structure of SFMs was obtained. As shown in FIG. 2, the PL peak intensity excited from the sandwich structure 203 is 11 times higher than that excited from the film without capping with SiO.sub.2 microspheres 202.

Example 2

[0034] Fused silica (SiO.sub.2) microspheres with average diameters of 5 μm were diluted by water to form a SiO.sub.2microsphere suspension 101. The microsphere concentration was about 4×10.sup.4 μL.sup.−1. The suspension was drawn by a dropper 102 and then deposited onto the surface of zinc oxide (ZnO) film 104 grown on a titanium (Ti) substrate 105 by drop coating 102. The film surface was therefore wetted 106. After the water in suspension was dried by spontaneous evaporation at room temperature, the single-layer close-packed microsphere array 301 was self-assembled and the sandwich structure of SFMs was obtained. As shown in FIG. 3, the PL peak intensity excited from the sandwich structure 303 is 3 times higher than that excited from the film without capping with SiO.sub.2 microspheres 302. The zinc oxide (ZnO) film 104 can be replaced by gallium nitride and silicon carbide luminescent films.

Example 3

[0035] Fused silica (SiO.sub.2) microspheres with average diameters of 5 μm were diluted by ethanol to form a SiO.sub.2 microsphere suspension 101. The microsphere concentration was about 8×10.sup.4 μL.sup.−1. The suspension was drawn by a dropper 102 and then deposited onto the surface of zinc oxide (ZnO) film 104 grown on a graphene substrate 105 by drop coating 102. The film surface was therefore wetted 106. After the ethanol in suspension was dried by spontaneous evaporation at room temperature, the single-layer close-packed microsphere array 401 was self-assembled and the sandwich structure of SFMs was obtained. As shown in FIG. 4, the PL peak intensity excited from the sandwich structure 403 is 3 times higher than that excited from the film without capping with SiO.sub.2 microspheres 402.

Example 4

[0036] Fused silica (SiO.sub.2) microspheres with average diameters of 5 μm were diluted by water to form a SiO.sub.2 microsphere suspension 101. The microsphere concentration was about 1×10.sup.4 μL.sup.−1 . The suspension was drawn by a dropper 102 and then deposited onto the surface of zinc oxide (ZnO) film 104 grown on an alumina (Al.sub.2O.sub.3) substrate 105 by drop coating 102. The film surface was therefore wetted 106. After the water in suspension was dried by heating evaporation at 50° C., the single-layer close-packed microsphere array 501 was self-assembled and the sandwich structure of SFMs was obtained. As shown in FIG. 5, the PL peak intensity excited from the sandwich structure 503 is 4 times higher than that excited from the film without capping with SiO.sub.2 microspheres 502.

Example 5

[0037] Fused silica (SiO.sub.2) microspheres with average diameters of 7.5 μm were diluted by water to form a SiO.sub.2 microsphere suspension 101. The microsphere concentration was about 2×10.sup.4 μL.sup.−1. The suspension was drawn by a dropper 102 and then deposited onto the surface of zinc oxide (ZnO) film 104 grown on a silicon carbide (SiC) substrate 105 by drop coating 102. The film surface was therefore wetted 106. After the water in suspension was dried by blowing evaporation at room temperature, the single-layer close-packed microsphere array 601 was self-assembled and the sandwich structure of SFMs was obtained. As shown in FIG. 6, the PL peak intensity excited from the sandwich structure 603 is 4 times higher than that excited from the film without capping with SiO.sub.2 microspheres 602.

Example 6

[0038] Fused silica (SiO.sub.2) microspheres with average diameters of 2.5 μm were diluted by water to form a SiO.sub.2 microsphere suspension 101. The microsphere concentration was about 2×10.sup.5 μL.sup.−1. The suspension was drawn by a dropper 102 and then deposited onto the surface of zinc oxide (ZnO) film 104 grown on a silicon carbide (SiC) substrate 105 by drop coating 102. The film surface was therefore wetted 106. After the water in suspension was dried by blowing and heating evaporation at 50° C., the single-layer close-packed microsphere array 701 was self-assembled and the sandwich structure of SFMs was obtained. As shown in FIG. 7, the PL peak intensity excited from the sandwich structure 703 is 4 times higher than that excited from the film without capping with SiO.sub.2 microspheres 702.

Example 7

[0039] Fused silica (SiO.sub.2) microspheres with average diameters of 1.5 μm were diluted by isopropanol to form a SiO.sub.2 microsphere suspension 101. The microsphere concentration was about 1×10.sup.6 μL.sup.−1. The suspension was sprayed onto the surface of zinc oxide (ZnO) film 104 grown on a silicon carbide (SiC) substrate 105 by a sprayer. The film surface was therefore wetted 106. After the isopropanol in suspension was dried by spontaneous evaporation at room temperature, the single-layer close-packed microsphere array 801 was self-assembled and the sandwich structure of SFMs was obtained. As shown in FIG. 8, the PL peak intensity excited from the sandwich structure 803 is 3 times higher than that excited from the film without capping with SiO.sub.2 microspheres 802.

Example 8

[0040] Polystyrene (PS) microspheres with average diameters of 5 μm were diluted by water to form a PS microsphere suspension 101. The microsphere concentration was about 4×10.sup.4 μL.sup.−1. The zinc oxide (ZnO) film 104 grown on a silicon carbide (SiC) substrate 105 was immersed in the suspension and then vertically lifted out. The film surface was therefore wetted 106. After the water in suspension was dried by spontaneous evaporation at room temperature, the single-layer close-packed microsphere array 901 was self-assembled and the sandwich structure of SFMs was obtained. As shown in FIG. 9, the PL peak intensity excited from the sandwich structure 903 is 11 times higher than that excited from the film without capping with PS microspheres 902.

Example 9

[0041] Polymethylmethacrylate (PMMA) microspheres with average diameters of 5.5 μm were diluted by water to form a PMMA microsphere suspension 101. The microsphere concentration was about 3.5×10.sup.4 μL.sup.−1. The zinc oxide (ZnO) film 104 grown on a silicon carbide (SiC) substrate 105 was immersed in the suspension and then vertically lifted out. The film surface was therefore wetted 106. After the water in suspension was dried by heating evaporation at 50° C., the single-layer close-packed microsphere array 1001 was self-assembled and the sandwich structure of SFMs was obtained. As shown in FIG. 10, the PL peak intensity excited from the sandwich structure 1003 is twice higher than that excited from the film without capping with PMMA microspheres 1002.

[0042] Although illustrative embodiments of the present invention have been described herein, it should be understood that the invention is not limited to the preferred embodiments and that various other changes and modifications may be made without departing from the spirit and scope of the invention as set forth in the following claims.

OTHER PUBLICATIONS

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