Algae modified pp spunbond non-woven fabric

Abstract

The present invention discloses an algae modified pp spunbond non-woven fabric, which contains 0.1-2% of alginate. The algae modified pp spunbond non-woven fabric has a moisture regain of 0.2-3.5%, and an antibacterial rate ≥98%. The algae modified pp spunbond non-woven fabric prepared in the invention contains modified alginic acid, and also has hydrophilic functional groups, such as hydroxyl and amido groups, and hydrophobic functional groups such as branched alkyl groups. After spinning with pp into non-woven fabrics, protons can be both generated and received, so that when liquid is encountered on the surface of non-woven fabrics, the surface tension of liquid can be significantly reduced; additionally, there are a large number of gaps in the dense interpenetrating network structure formed by the modified alginic acid, which forms a structure like sponge having good hygroscopicity; moreover, the algae modified pp spunbond non-woven fabric absorbs water rapidly, the surface remains dry after absorbing water, and it can absorb many times its mass of water, so it has an excellent hydrophilicity.

Claims

1. A method for producing an alginate modified polypropylene spunbond non-woven fabric, which contains 0.1-2% by mass of alginate in the polypropylene spunbond non-woven fabric, the method comprising: adding polypropylene and alginate accounting for 0.1-2% of the total weight into a horizontal double helical ribbon mixer at a certain mass ratio to form a first mixture, heating the first mixture to 40-80° C., mixing the first mixture at a medium speed for 20-40 minutes, and then adding polyethylene glycol, polyvinyl pyrrolidone and an antioxidant to the mixer to form a second mixture, heating the second mixture to 180-190° C., and mixing the second mixture at a high speed for 20-40 minutes, to form a mixture liquid, injecting the mixture liquid into a spinning box, spinning fibers from the mixture liquid, cooling the spun fibers with a quenching air case, and drawing the spun fibers to form a fiber mesh, and hot rolling the fiber mesh into cloth to form the alginate modified polypropylene spunbond non-woven fabric.

2. The method according to claim 1, wherein hot rolling is performed at a temperature of 140-150° C.

3. The method according to claim 1, wherein the mixture liquid is injected into the spinning box at a pressure of 2-5 MPa.

4. The method according to claim 1, further comprising generating the alginate by modifying alginic acid by performing the following steps: extracting alginic acid from natural algae, dissolving the alginic acid in a solvent to form a first solution, adding 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and N-hydroxy succinimide to the first solution at 10-35° C. and reacting with stirring for 5-10 hours to form a reaction solution, adding a polyamine to the reaction solution and reacting with stirring at 40-80° C. for 10-24 hours to form a mixed solution containing reaction molecules, adding deionized water to the mixed solution and dialyzing the mixed solution with a dialysis bag to separate reaction molecules with a molecular weight of less than 3500 to form a dialysate containing reaction molecules with a molecular weight above 3500, and lypophilizing the dialysate to form the alginate; wherein the solvent is N,N-dimethylformamide or dimethyl sulfoxide, wherein the polyamine is hexamethylenediamine or tri(2-aminoethyl)amine, and wherein a mass ratio of alginic acid, the solvent, 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride, N-hydroxy succinimide, polyamine and deionized water is 100:300-600:5-15:7-14:1-10:300-600.

5. The method according to claim 1, wherein the the polyethylene glycol is Polyethylene glycol 4000 or Polyethylene glycol 6000.

6. The method according to claim 5, wherein the polyvinyl pyrrolidone is Polyvinyl pyrrolidone K30.

Description

DESCRIPTION OF THE EMBODIMENTS

(1) The present invention will be further described with reference to the following specific embodiments.

Embodiment 1

(2) An algae modified pp spunbond non-woven fabric, including the following raw materials: polypropylene 90 kg, modified alginic acid 0.2 kg, polyethylene glycol 1 kg, polyvinyl pyrrolidone 0.3 kg and an antioxidant 0.3 kg;

(3) The antioxidant is Antioxidant 3125;

(4) Wherein the modified alginic acid is prepared following the steps below:

(5) 100 kg alginic acid is dissolved in 300 kg N,N-dimethylformamide, into which are added 5 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 7 kg N-hydroxy succinimide at 10° C. and reacted with stirring for 10 hours to get a reaction solution; 1 kg hexamethylenediamine is added into the reaction solution and reacted with stirring at 40° C. for 10 hours to get a mixed solution; 300 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid.

Embodiment 2

(6) An algae modified pp spunbond non-woven fabric, including the following raw materials: polypropylene 100 kg, modified alginic acid 1 kg, polyethylene glycol 5 kg, polyvinyl pyrrolidone 0.1 kg and an antioxidant 0.6 kg;

(7) The antioxidant is Antioxidant 2013;

(8) Wherein the modified alginic acid is prepared following the steps below:

(9) 100 kg alginic acid is dissolved in 600 kg dimethyl sulfoxide, into which are added 15 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 14 kg N-hydroxy succinimide at 35° C. and reacted with stirring for 5 hours to get a reaction solution; 10 kg tri(2-aminoethyl)amine is added into the reaction solution and reacted with stirring at 80° C. for 24 hours to get a mixed solution; 600 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid.

Embodiment 3

(10) An algae modified pp spunbond non-woven fabric, including the following raw materials: polypropylene 94 kg, modified alginic acid 1.2 kg, polyethylene glycol 4 kg, polyvinyl pyrrolidone 0.15 kg and an antioxidant 0.4 kg;

(11) The antioxidant is Antioxidant 3125;

(12) Wherein the modified alginic acid is prepared following the steps below:

(13) 100 kg alginic acid is dissolved in 400 kg N,N-dimethylformamide, into which are added 10 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 10 kg N-hydroxy succinimide at 25° C. and reacted with stirring for 4 hours to get a reaction solution; 5 kg hexamethylenediamine is added into the reaction solution and reacted with stirring at 50° C. for 14 hours to get a mixed solution; 400 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid.

Embodiment 4

(14) An algae modified pp spunbond non-woven fabric, including the following raw materials: polypropylene 95 kg, modified alginic acid 1.5 kg, Polyethylene glycol 4000 3 kg, Polyvinyl pyrrolidone K30 0.2 kg and an antioxidant 0.5 kg;

(15) The antioxidant is Antioxidant 3125;

(16) Wherein the modified alginic acid is prepared following the steps below:

(17) 100 kg alginic acid is dissolved in 400 kg dimethyl sulfoxide, into which are added 8 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 10 kg N-hydroxy succinimide at 20° C. and reacted with stirring for 5 hours to get a reaction solution; 6 kg polyamine is added into the reaction solution and reacted with stirring at 60° C. for 15 hours to get a mixed solution; 450 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid.

Embodiment 5

(18) An algae modified pp spunbond non-woven fabric, including the following raw materials: polypropylene 95 kg, modified alginic acid 1.9 kg, Polyethylene glycol 6000 3 kg, Polyvinyl pyrrolidone K30 0.2 kg and an antioxidant 0.5 kg;

(19) The antioxidant is Antioxidant 3125;

(20) Wherein the modified alginic acid is prepared following the steps below:

(21) 100 kg alginic acid is dissolved in 400 kg dimethyl sulfoxide, into which are added 8 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 10 kg N-hydroxy succinimide at 20° C. and reacted with stirring for 5 hours to get a reaction solution; 6 kg polyamine is added into the reaction solution and reacted with stirring at 60° C. for 15 hours to get a mixed solution; 450 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid.

Embodiment 6

(22) The algae modified pp spunbond non-woven fabric described in embodiment 1 is prepared by a method including the following steps:

(23) {circle around (1)} 90 kg polypropylene and 0.2 kg modified alginic acid are added into a horizontal double helical ribbon mixer, heated to 40° C., and mixed at a medium speed for 20 minutes, into which are then added 1 kg polyethylene glycol, 0.3 kg polyvinyl pyrrolidone and 0.3 kg antioxidant, heated to 180° C. and mixed at a high speed for 20 minutes, to get a mixture liquid;
Wherein the modified alginic acid is prepared following the steps below:
100 kg alginic acid is dissolved in 300 kg N,N-dimethylformamide, into which are added 5 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 7 kg N-hydroxy succinimide at 10° C. and reacted with stirring for 10 hours to get a reaction solution; 1 kg hexamethylenediamine is added into the reaction solution and reacted with stirring at 40° C. for 10 hours to get a mixed solution; 300 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid; The antioxidant is Antioxidant 3125;
{circle around (2)} The mixture liquid obtained from step {circle around (1)} is injected into a spinning box, where it is jet spun, cooled by a quenching air case, and drawn to get a fiber mesh, the fiber mesh is hot rolled into cloth on a hot rolling machine, to get the algae modified pp spunbond non-woven fabric.

Embodiment 7

(24) The algae modified pp spunbond non-woven fabric described in embodiment 2 is prepared by a method including the following steps:

(25) {circle around (1)} 100 kg polypropylene and 0.9 kg modified alginic acid are added into a horizontal double helical ribbon mixer, heated to 80° C., and mixed at a medium speed for 40 minutes, into which are then added 5 kg polyethylene glycol, 0.1 kg polyvinyl pyrrolidone and 0.6 kg Antioxidant 2013, heated to 190° C. and mixed at a high speed for 40 minutes, to get a mixture liquid;
Wherein the modified alginic acid is prepared following the steps below:
100 kg alginic acid is dissolved in 600 kg dimethyl sulfoxide, into which are added 15 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 14 kg N-hydroxy succinimide at 35° C. and reacted with stirring for 5 hours to get a reaction solution; 10 kg tri(2-aminoethyl)amine is added into the reaction solution and reacted with stirring at 80° C. for 24 hours to get a mixed solution; 600 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid;
{circle around (2)} The mixture liquid obtained from step {circle around (1)} is injected into a spinning box, where it is jet spun, cooled by a quenching air case, and drawn to get a fiber mesh, the fiber mesh is hot rolled into cloth on a hot rolling machine, to get the algae modified pp spunbond non-woven fabric.

Embodiment 8

(26) The algae modified pp spunbond non-woven fabric described in embodiment 3 is prepared by a method including the following steps:

(27) {circle around (1)} 94 kg polypropylene and 1.2 kg modified alginic acid are added into a horizontal double helical ribbon mixer, heated to 50° C., and mixed at a medium speed for 25 minutes, into which are then added 4 kg polyethylene glycol, 15 kg polyvinyl pyrrolidone and 0.4 kg antioxidant, heated to 182° C. and mixed at a high speed for 25 minutes, to get a mixture liquid;
Wherein the modified alginic acid is prepared following the steps below:
100 kg alginic acid is dissolved in 400 kg N,N-dimethylformamide, into which are added 10 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 10 kg N-hydroxy succinimide at 25° C. and reacted with stirring for 4 hours to get a reaction solution; 5 kg hexamethylenediamine is added into the reaction solution and reacted with stirring at 50° C. for 14 hours to get a mixed solution; 400 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid;
The antioxidant is Antioxidant 3125;
{circle around (2)} The mixture liquid obtained from step {circle around (1)} is injected into a spinning box, where it is jet spun, cooled by a quenching air case, and drawn to get a fiber mesh, the fiber mesh is hot rolled into cloth on a hot rolling machine, to get the algae modified pp spunbond non-woven fabric.

Embodiment 9

(28) The algae modified pp spunbond non-woven fabric described in embodiment 4 is prepared by a method including the following steps:

(29) {circle around (1)} 95 kg polypropylene and 1.5 kg modified alginic acid are added into a horizontal double helical ribbon mixer, heated to 60° C., and mixed at a medium speed for 30 minutes, into which are then added 3 kg Polyethylene glycol 4000, 0.2 kg Polyvinyl pyrrolidone K30 and 0.5 kg antioxidant, heated to 185° C. and mixed at a high speed for 30 minutes, to get a mixture liquid;
Wherein the modified alginic acid is prepared following the steps below:
100 kg alginic acid is dissolved in 400 kg dimethyl sulfoxide, into which are added 8 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 10 kg N-hydroxy succinimide at 20° C. and reacted with stirring for 5 hours to get a reaction solution; 6 kg polyamine is added into the reaction solution and reacted with stirring at 60° C. for 15 hours to get a mixed solution; 450 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid;
The antioxidant is Antioxidant 3125;
{circle around (2)} The mixture liquid obtained from step {circle around (1)} is injected into a spinning box, where it is jet spun, cooled by a quenching air case, and drawn to get a fiber mesh, the fiber mesh is hot rolled into cloth on a hot rolling machine, to get the algae modified pp spunbond non-woven fabric.

Embodiment 10

(30) The algae modified pp spunbond non-woven fabric described in embodiment 5 is prepared by a method including the following steps:

(31) {circle around (1)} 95 kg polypropylene and 1.9 kg modified alginic acid are added into a horizontal double helical ribbon mixer, heated to 60° C., and mixed at a medium speed for 30 minutes, into which are then added 3 kg Polyethylene glycol 6000, 0.2 kg Polyvinyl pyrrolidone K30 and 0.5 kg antioxidant, heated to 185° C. and mixed at a high speed for 30 minutes, to get a mixture liquid;
Wherein the modified alginic acid is prepared following the steps below:
100 kg alginic acid is dissolved in 400 kg dimethyl sulfoxide, into which are added 8 kg 1-(3-dimethylaminopropyl)-3-ethyl carbodiimide hydrochloride and 10 kg N-hydroxy succinimide at 20° C. and reacted with stirring for 5 hours to get a reaction solution; 6 kg polyamine is added into the reaction solution and reacted with stirring at 60° C. for 15 hours to get a mixed solution; 450 kg deionized water is added into the mixed solution and dialyzed by a dialysis bag with a molecular weight of 3500 to get a dialysate; the dialysate is lyophilized to get the modified alginic acid;
The antioxidant is Antioxidant 3125;
{circle around (2)} The mixture liquid obtained from step {circle around (1)} is injected into a spinning box, where it is jet spun, cooled by a quenching air case, and drawn to get a fiber mesh, the fiber mesh is hot rolled into cloth on a hot rolling machine, to get the algae modified pp spunbond non-woven fabric.

Comparative Embodiment 11

(32) Employing the method of embodiment 10 with other parameters unchanged, the amount of alginate added is changed to 3.5 Kg.

Comparative Embodiment 12

(33) Employing the method of embodiment 10 with other parameters unchanged, the amount of alginate added is changed to 4.0 Kg.

Comparative Embodiment 13

(34) Employing the method of embodiment 10 with other parameters unchanged, the amount of alginate added is changed to 4.5 Kg.

Comparative Embodiment 14

(35) Employing the method of embodiment 10 with other parameters unchanged, the amount of alginate added is changed to 0.09 Kg.

Comparative Embodiment 15

(36) Employing the method of embodiment 10 with other parameters unchanged, the amount of alginate added is changed to 0.05 Kg.

(37) The performances of the algae modified pp spunbond non-woven fabrics in basic embodiments 6˜10 and comparative embodiments 11-13 are tested. The pp spunbond non-woven fabrics with the same gram weight as in the basic embodiments are employed in the comparative embodiments, the gram weights are both 20±0.5 g/cm.sup.2. The air permeability of materials is tested according to ISO9237-1995 standard, and the breaking strength and elongation at break are tested according to GB/T 24218.3-2010, with the results shown in Table 1.

(38) TABLE-US-00001 TABLE 1 Antibacterial Antibacterial Air Breaking rate against rate against permeability/ strength/ Elongation at Staphylococcus Escherichia mm/s N/5 cm break/% aureus/% coli/% Embodiment 6 989 60.72 51.18 99.20 99.50 Embodiment 7 962 60.70 51.17 98.20 98.70 Embodiment 8 975 60.81 51.22 98.50 99.00 Embodiment 9 984 60.88 51.23 98.80 99.20 Embodiment 10 990 60.89 51.24 99.90 99.90 Comparative 990 50.20 42.50 99.80 99.90 Embodiment 11 Comparative 989 50.30 42.60 99.90 99.80 Embodiment 12 Comparative 990 45.80 38.50 99.90 99.90 Embodiment 13 Comparative 658 60.82 51.22 84.30 83.60 Embodiment 14 Comparative 973 60.85 51.00 83.50 83.10 Embodiment 15
It can be seen from the data in Table 1 that, the algae modified pp spunbond non-woven fabrics of the invention have excellent air permeability which is more than 100% that of conventional non-woven fabric products; the breaking strength and the elongation at break are both about 20% higher than those of conventional pp spunbond non-woven fabrics. It can be seen that, the modified alginic acid with a molecular weight above 3500 and the dense interpenetrating network structure ensure the high mechanical strength and wear resistance of non-woven fabrics.

(39) Meanwhile, it can be also concluded that, when the content of alginate in the prepared non-woven fabrics is between 0.1-2%, the prepared fiber has the best antibacterial property, and its physical properties can meet the needs of production; when the content of alginate is <0.1%, the air permeability and antibacterial property of the prepared non-woven fabrics are reduced significantly; when the content of alginate is ≥2%, the physical indexes of the prepared non-woven fabrics are also reduced significantly, which cannot meet the requirements of normal production and application obviously. In conclusion, the optimal content of alginate in the algae modified pp spunbond non-woven fabrics prepared in the invention is between 0.1-2%.

(40) The hydroscopicities of the algae modified pp spunbond non-woven fabrics in embodiments 6˜10 are tested, and pp spunbond non-woven fabrics with the same gram weights are used in the comparative embodiments, with the gram weights both at 20±0.5 g/cm.sup.2. The water absorbing speed and capacity of the non-woven fabrics are determined. The water absorbing speed is determined as below: the algae modified pp spunbond non-woven fabrics in embodiments 6-10 are cut into square sheets of 10 cm*10 cm; 1 ml water is dropped onto the laboratory bench; the non-woven fabric sheets are allowed to approach water slowly; the time for the non-woven fabrics to absorb water completely, i.e., to be wetted absolutely, is recorded with a stop watch to determine the water absorbing speed. The water absorbing capacity is determined as below: the square sheets of 10 cm*10 cm are weighed and soaked in water for 10 s, taken out and weighed on a balance when no water drips from the non-woven fabrics, then the weights m of the non-woven fabrics are recorded, the water absorbing capacity per gram=(m−5)/5; with the results shown in Table 2.

(41) Table 2 Test results of water absorbabilities of the algae modified pp spunbond non-woven fabrics in embodiments 6˜10

(42) TABLE-US-00002 TABLE 2 Convention Water absorbing Water absorbing moisture speed capacity (fold) regain (%) Embodiment 6 2.1 13.2 12.83 Embodiment 7 1.6 12.5 8.59 Embodiment 8 1.7 12.7 9.12 Embodiment 9 1.9 13.0 12.15 Embodiment 10 2.8 14.5 14.33 Comparative 3.1 14.8 14.75 Embodiment 11 Comparative 3.1 14.4 14.78 Embodiment 12 Comparative 3.2 14.9 14.83 Embodiment 13 Comparative 3.0 3.5 3.2 Embodiment 14 Comparative 3.0 3.6 3.3 Embodiment 15
Note: In the experiments of water absorbing capacity, the surfaces of conventional non-woven fabrics in the comparative embodiments are not stained with water.

(43) It is demonstrated from the results of Table 2 that, the algae modified pp spunbond non-woven fabrics in embodiments 6˜10 of the invention can absorb water rapidly and the surface remains dry after absorbing water; moreover, they can absorb more than 12 times their mass of water, the convention moisture regain is between 0.2˜3.5%, so they have good hygroscopicity and good hydrophilcity.

(44) The alginic acid used in the invention is commercially available, and there are no additional requirements for its specific indexes, unless otherwise required in the present invention.

(45) The foregoing are only preferred embodiments of the invention, but are not limitations to the invention in any other forms. The present invention can be changed or modified to equivalent embodiments by any persons familiar with the art by using the above technical content as an inspiration. However, all the simple variations, equal changes and modifications to the above embodiments substantially according to the invention without deviating from the context of the technical scheme of the invention still fall within the protection scope of the claims of the invention.