Pressure-based liquid level detection and control for a fuel cell stack assembly
09722265 · 2017-08-01
Assignee
Inventors
Cpc classification
H01M8/247
ELECTRICITY
H01M8/04291
ELECTRICITY
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0267
ELECTRICITY
H01M8/2485
ELECTRICITY
International classification
H01M8/04
ELECTRICITY
H01M8/04223
ELECTRICITY
H01M8/247
ELECTRICITY
H01M8/04291
ELECTRICITY
Abstract
A fluid detection system and method for a fuel cell power plant is disclosed having a pressure sensor (61, 161) positioned in a fuel cell stack assembly (10) to measure pressure of fluid/liquid in a fluid/liquid flow path (40, 42, 44) therein and to provide a pressure-based signal (90, 63). The pressure-based signal (90, 63) is used to control a liquid management arrangement (53) at least during start-up and shut-down of the cell stack assembly (10) to regulate water level. The liquid management arrangement (53) may include means (50, 51) for controllably applying and releasing a vacuum to a water manifold (44, 54; 100) of the cell stack assembly (10) to regulate water flow and level therein. The pressure-based control of water level may extend across the entire operating range of the cell stack assembly (10), or may be complemented during steady state operation by voltage-based sensors (66, 166).
Claims
1. A liquid-level control system for a fuel cell power plant, the system comprising: a fuel cell stack assembly, including a fluid flow path extending therethrough; a controllable liquid management arrangement operatively connected to the fuel cell stack assembly and including said fluid flow path; a pressure sensor adapted to sense pressure of fluid in the fluid flow path of the fuel cell stack assembly and provide a fluid pressure signal commensurate therewith; and a voltage sensing arrangement adapted to measure a voltage when a liquid in the fluid flow path of the cell stack assembly attains a predetermined level and provide a voltage-based signal indicative thereof, and the liquid management arrangement being operably connected to and at least indirectly responsive to the fluid pressure signal, the liquid management arrangement being configured to regulate a level of liquid in the fuel cell stack assembly based on the fluid pressure signal at least during start-up and during shut-down of the fuel cell stack assembly, and when the fuel cell stack assembly does not provide a measurable voltage, and the liquid management arrangement being operably connected to and at least indirectly responsive to the voltage-based signal, the liquid management arrangement being configured to regulate the level of liquid in the fuel cell stack assembly based on the voltage-based signal at least during steady state operation of the fuel cell stack assembly and when the fuel cell stack assembly provides a measurable voltage, and the liquid management arrangement configured to automatically transition from regulating the level of liquid in the fuel cell stack assembly based on the fluid pressure signal to regulating the level of liquid in the fuel cell stack assembly based on the voltage-based signal when the fuel cell stack assembly provides a measurable voltage, and configured to automatically transition from regulating the level of liquid in the fuel cell stack assembly based on the voltage-based signal to regulating the level of liquid in the fuel cell stack assembly based on the fluid pressure signal when the fuel cell stack assembly does not provide a measurable voltage.
2. The liquid-level control system for a fuel cell power plant of claim 1, comprising: the liquid management arrangement being responsive at least indirectly to the fluid pressure signal additionally during normal steady state operation of the fuel cell stack assembly to regulate the level of the liquid in the fuel cell stack assembly.
3. The liquid-level control system for a fuel cell power plant of claim 1, wherein: the fuel cell stack assembly comprises a proton exchange membrane fuel cell stack, and temperature of the fuel cell stack assembly is controlled by evaporative cooling in the fuel cell stack assembly.
4. The liquid-level control system for a fuel cell power plant of claim 1, further including: a controller operably connected to and responsive to the fluid pressure signal to determine attainment of a predetermined level of liquid in the fuel cell stack assembly, said controller being operably connected to said controllable liquid management arrangement to regulate the level of liquid in the fuel cell stack assembly at least during said start-up and said shut-down of the fuel cell stack assembly.
5. The liquid-level control system for a fuel cell power plant of claim 4, wherein: the fluid flow path extending through the fuel cell stack assembly is for water and includes a water exit manifold, a vacuum pump is operatively connected to the water exit manifold of the fluid flow path to create a vacuum therein, the pressure sensor is operatively positioned in said water exit manifold to sense vacuum pressure in said water exit manifold until water contacts said pressure sensor at said predetermined level in the water exit manifold and to sense water pressure when water contacts said pressure sensor, there being a distinctive inflection in the sensed pressure at the transition from sensed vacuum to sensed water pressure, and said controller is responsive to said distinctive inflection in the sensed pressure to signal that said water has attained said predetermined level.
6. The liquid-level control system for a fuel cell power plant of claim 5, wherein: the vacuum is effectively removed from the liquid flow path in response to said controller signaling that said water has attained said predetermined level and is restored in response to a subsequent measured event, thereby to maintain a desired range of liquid level in the fuel cell stack assembly.
7. The liquid-level control system for a fuel cell power plant of claim 6, wherein: said subsequent measured event for restoring the vacuum is the lapse of a predetermined time interval.
8. The liquid-level control system for a fuel cell power plant of claim 1 wherein the pressure sensor is positioned at a neutral location that minimizes measurement variation as the fuel cell stack assembly tilts.
9. The liquid level control system for a fuel cell power plant of claim 1 wherein the pressure sensor is positioned at a neutral location that minimizes measurement variation as the fuel cell stack assembly tilts about two independent axes.
10. A liquid-level control system for a fuel cell power plant, the system comprising: a fuel cell stack assembly, including a fluid flow path extending therethrough for water, the fluid flow path including a water exit manifold; a controllable liquid management arrangement operatively connected to the fuel cell stack assembly and including said fluid flow path; a pressure sensor adapted to sense pressure of fluid in the fluid flow path of the fuel cell stack assembly and provide a fluid pressure signal commensurate therewith, and wherein the fluid pressure signal is operably connected to the liquid management arrangement such that the liquid management arrangement is configured to regulate a level of water in the fuel cell stack assembly based on the fluid pressure signal only during start-up and during shut-down of the fuel cell stack assembly and when the fuel cell stack assembly does not provide a measurable voltage; and a voltage sensing arrangement adapted to measure a voltage when water in the fluid flow path attains a predetermined level in the water exit manifold and provide a voltage-based signal indicative thereof, and wherein the voltage-based signal indicative of the water attaining said predetermined level is also operably connected to the liquid management arrangement such that the liquid management arrangement is configured to regulate the level of water in the fuel cell stack assembly based on the voltage-based signal only during steady state operation of the fuel cell stack assembly and when the fuel cell stack assembly provides a measurable voltage, and the liquid management arrangement configured to automatically transition from regulating the level of liquid in the fuel cell stack assembly based on the fluid pressure signal to regulating the level of liquid in the fuel cell stack assembly based on the voltage-based signal when the fuel cell stack assembly provides a measurable voltage, and configured to automatically transition from regulating the level of liquid in the fuel cell stack assembly based on the voltage-based signal to regulating the level of liquid in the fuel cell stack assembly based on the fluid pressure signal when the fuel cell stack assembly does not provide a measurable voltage.
11. The system of claim 10 wherein the pressure sensor is operatively positioned in said water exit manifold to sense vacuum pressure in said water exit manifold until water contacts said pressure sensor at said predetermined level in the water exit manifold and to sense water pressure when water contacts said pressure sensor, there being a distinctive inflection in the sensed pressure at the transition from sensed vacuum to sensed water pressure.
12. A method of controlling a liquid level in a fuel cell power plant comprising a liquid level control system, a fuel cell stack assembly including a fluid flow path extending therethrough, a controllable liquid management arrangement operatively connected to the fuel cell stack assembly and including said fluid flow path, a pressure sensor adapted to sense pressure of fluid in the fluid flow path of the fuel cell stack assembly and provide a fluid pressure signal commensurate therewith, a voltage sensing arrangement adapted to measure a voltage when a liquid in the fluid flow path of the fuel cell stack assembly attains a predetermined level and provide a voltage-based signal indicative thereof, the liquid management arrangement being operably connected to and at least indirectly responsive to the fluid pressure signal, the liquid management arrangement being configured to regulate a level of liquid in the fuel cell stack assembly at least during start-up and during shut-down of the fuel cell stack assembly based on the fluid pressure signal, and the liquid management arrangement being operably connected to and at least indirectly responsive to the voltage-based signal, the liquid management arrangement being configured to regulate the level of liquid in the fuel cell stack assembly at least during steady state operation of the fuel cell stack assembly based on the voltage-based signal, the method comprising: sensing pressure of fluid in the fluid flow path of the fuel cell stack assembly to provide the fluid pressure signal indicative thereof; regulating the level of liquid in the fuel cell stack assembly based at least in part on the fluid pressure signal at least during start-up and during shut-down of the fuel cell stack assembly and when the fuel cell stack assembly does not provide a measurable voltage; measuring the voltage to ascertain when the liquid in the fluid flow path of the fuel cell stack assembly reaches the predetermined level to provide the voltage-based signal indicative thereof; and regulating the level of the liquid in the fuel cell stack assembly based at least in part on the voltage-based signal at least during steady state operation of the fuel cell stack assembly and when the fuel cell stack assembly provides a measurable voltage, and automatically transitioning from regulating the level of liquid in the fuel cell stack assembly based at least in part on the fluid pressure signal to regulating the level of liquid in the fuel cell stack assembly based at least in part on the voltage-based signal when the fuel cell stack assembly provides a measurable voltage.
13. The method of claim 12 wherein the fuel cell stack assembly comprises a proton exchange membrane fuel cell stack and the method further comprises controlling temperature of the fuel cell stack assembly by evaporative cooling in the proton exchange membrane fuel cell stack.
14. The method of claim 12 wherein sensing the pressure of fluid in the fluid flow path of the fuel cell stack assembly includes sensing vacuum pressure in a water exit manifold of the fuel cell stack assembly with the pressure sensor until water contacts said pressure sensor at a predetermined level in the water exit manifold and sensing water pressure when water contacts said pressure sensor, there being a distinctive inflection in the sensed pressure at the transition from sensed vacuum to sensed water pressure.
15. The method of claim 14 wherein regulating the level of liquid in the fuel cell stack assembly at least during start-up and during shut-down of the fuel cell stack assembly based at least in part on the fluid pressure signal includes regulating the level of liquid in the fuel cell stack assembly based at least in part on the distinctive inflection in the sensed pressure.
16. The method of claim 14 wherein regulating the level of liquid in the fuel cell stack assembly includes effectively removing the vacuum from the liquid flow path in response to said water attaining said predetermined level and restoring the vacuum in response to a subsequent measured event.
17. The method of claim 16 wherein said subsequent measured event for restoring the vacuum is the lapse of a predetermined time interval.
18. The method of claim 12 wherein measuring the voltage to ascertain when the liquid in the fluid flow path of the fuel cell stack assembly reaches the predetermined level includes measuring voltage when water within a water exit manifold of the fuel cell stack assembly reaches the predetermined level.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(6) Following is described a pressure-based system and method for detecting fluid pressure in a fluid/liquid flow path of a fuel cell stack assembly (CSA) as a measure of liquid level, and to thereby control liquid level in the CSA. The disclosure is predicated in part on the determination that fluid pressure, or changes in fluid pressure, in a fluid flow path in the CSA may be used to monitor and/or control actual liquid coolant levels in the CSA not only during steady state operation, but also during start-up and shut-down transitions when other types of level detection systems may be limited. Use of a signal derived from such pressure-based measurements is then used at least during start-up and shut-down transitions to at least augment or possibly replace such other types of level detection systems.
(7) A variety of methods and systems can be used for managing the liquid balance in the CSA such that it stays sufficiently cooled and hydrated for good stack life and performance. As an example, some fuel cell power plants use a coolant loop that is physically separate from the fuel cell operations. In such systems, coolant fluid (e.g., typically water or glycol-based liquid mixtures) is actively circulated throughout the coolant loop by a pump, and is used as a heat sink to receive waste heat conducted through the solid elements or barriers separating the fuel cells from the coolant channels comprising the loop. Such systems may humidify the reactant gases prior to supplying the gas to the fuel cells to prevent membrane dry-out. In other systems, such as the one described with reference to
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(9) Fuel provided to fuel inlet manifold 30 travels through fuel flow channels 32 (detailed structure not shown) in stack 16, then through fuel turn manifold 34 and back through more fuel flow channels 32 before exiting into fuel exit manifold 36 for recycling or proper disposal as is known in the art.
(10) Water 22 in reservoir 24 flows through water conduit 38 and into water inlet manifold 40. The water then passes into a series of water channels 42 (detailed structure not shown) distributed throughout stack 16. Water channels 42 may terminate at water exit manifold 44, into which a quantity, or level, of water 46 may be present, depending on the operational status of the power plant. Attached to water exit manifold 44 is conduit 48 that provides a fluid communication to pump 50. In systems where evaporative cooling via water vapor in oxidant flow channels 14 is used for managing the temperature of stack 16, as in the embodiments depicted and described herein, water does not exit the CSA conduit 48 or pump 50. Rather, pump 50 is used to draw a controlled vacuum pressure for ensuring that water will rise through all of the water channels 42 of stack 16, with just enough water entering through water inlet manifold 40 to replace that which evaporated into oxidant flow channels 14. In other systems where stack temperature is managed at least in part with circulating water or other fluid, conduit 48 may act as a water outlet, with pump 50 acting to circulate water through conduit 52 into reservoir 24 and eventually back into water channels 42.
(11) In the depicted embodiment in which vacuum pump 50 may be a constant speed device used to control vacuum pressure to draw water through stack 16 and into the water exit manifold 44, there is also provided a vacuum-break conduit 49 and valve 51 extending from the conduit 48 for selectively altering or breaking the vacuum to regulate water level, as will be described. For purposes of the present disclosure, the CSA 10 is viewed as having a fluid flow path for water through the stack 16, which flow path includes the water inlet manifold 40, the water channels 42 and the water exit manifold 44. Moreover, the CSA 10 may be viewed as including a liquid management arrangement, generally designated 53, associated with the water flow path for supplying water to the flow path and for regulating the flow or level therein. This liquid management arrangement 53 not only includes the water inlet manifold 40, the water channels 42 and the water exit manifold 44, but may also include reservoir 24 associated with the water inlet manifold 40 and includes a controllable delivery/exhaust arrangement such as pump 50 and vacuum-break valve 51 associated with the water exit manifold 44.
(12) In further accord with the disclosed system,
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(14) In accordance with the present disclosure, a pressure sensor element 61 is mounted in the stack 16, conveniently in the water exit manifold 44 in communication with the water exit manifold space 54. The pressure sensor element 61 may be of conventional design capable of sensing pressure of a fluid, either liquid, e.g., water, or gas, e.g., air, in the water exit manifold 44, and is mounted through the wall of the water exit manifold 44 in fluid sealed relation therewith, as at the distal end of a mounting stalk. The pressure sensor element 61 in the depicted embodiments is capable of sensing sub-atmospheric pressures normally associated with the vacuum pressures that may be present in water exit manifold 44 and its space 54. The pressure sensor element 61 is positioned in a region of space 54 normally not occupied by water to sense manifold fluid (normally gas) pressure, yet is positioned such that when the coolant liquid (water) rises to a predetermined level in the water exit manifold 44, it contacts the pressure sensor element 61 and causes an abrupt change in the sensed pressure because of the change in fluid medium from gas (air) to liquid (water), as is depicted in
(15) In further accordance with the embodiment depicted in
(16) The controller 82 of
(17) Prior to a further discussion of the manner in which pressure sensor element 61, and optionally also voltage sensor elements 66, operate(s) to regulate water level in water exit manifold space 54, it is instructive to view and consider time-based traces of several parameters associated with the operation of the CSA 10. Referring first to
(18) Reference is made now to the traces of
(19) Brief consideration is now given to the manner in which the controller 82 and the water management system 53 regulate the water level in water exit manifold space 54. The master controller (not shown, but see “state” signal CS) serves to initiate start-up by turning on the vacuum pump 50 to draw water/coolant through the stack 16, then turns on the fuel supply and shortly thereafter turns on the air supply. The pressure signal P from the pressure sensor element 61 reflects the sensed vacuum pressure in the water exit manifold space 54, and has been depicted for convenience in
(20) A notable benefit of a system of water level control based on sensed pressure/vacuum to provide the CLC signal, especially during start-up, as contrasted with sensed voltage providing that signal, exists because of the desire/need to prevent gas cross-over resulting from a pressure differential exceeding the so-called bubble pressure of the stack 16. If that critical bubble pressure were to be exceeded, gases within the system may cross otherwise impenetrable barriers with undesirable consequences. If one assumes a coolant water flow-blocking condition, such as a start-up from a frozen condition in the system, the pressure-based CLC signal will repeatedly apply the vacuum of pump 50 and the vacuum will increase (a pressure decrease) until the vacuum-break valve 51 opens at the predetermined safe threshold, and the cycle is safely repeated.
(21) Although the embodiments of the present disclosure thus far have been generally discussed with reference to the system shown in
(22) Although the disclosure has been described and illustrated with respect to the exemplary embodiments thereof, it should be understood by those skilled in the art that the foregoing and various other changes, omissions and additions may be made without departing from the spirit and scope of the disclosure. For example, it will be understood that multiple, spaced pressure sensor elements may be used to accommodate for variations in actual water levels that may result from inclination or tilt of the fuel cell. All such modifications and variations are intended to be included herein within the scope of this disclosure and protected by the accompanying claims.