Organic optoelectronic component with a light emitting element and a light detecting element and method for operating such an organic optoelectronic component
09721992 · 2017-08-01
Assignee
Inventors
Cpc classification
H05B45/60
ELECTRICITY
International classification
Abstract
An organic optoelectronic component and a method for operating an organic optoelectronic component are disclosed. In an embodiment an organic optoelectronic component includes an organic light emitting element including an organic functional layer stack having an organic light emitting layer between two electrodes and an organic light detecting element including a first organic light detecting element including a first organic light detecting layer, and a second organic light detecting element including a second organic light detecting layer, wherein the organic light emitting element and the organic light detecting element are arranged laterally adjacent on a common substrate, wherein the first organic light detecting element is configured to detect ambient light, wherein the second organic light detecting layer of the second organic light detecting element is arranged between two non-transparent layers, the non-transparent layers shade the second organic light detecting layer of the second organic light detecting element from ambient light.
Claims
1. An organic optoelectronic component comprising: at least one organic light emitting element comprising an organic functional layer stack having at least one organic light emitting layer between two electrodes; and at least one organic light detecting element comprising at least one first organic light detecting element comprising at least one first organic light detecting layer, and at least one second organic light detecting element comprising at least one second organic light detecting layer, wherein the at least one organic light emitting element and the at least one organic light detecting element are arranged laterally adjacent on a common substrate, wherein the at least one first organic light detecting element is configured to detect ambient light, wherein the at least one second organic light detecting layer of the at least one second organic light detecting element is permanently arranged between two non-transparent layers, the two non-transparent layers shade the at least one second organic light detecting layer of the at least one second organic light detecting element from ambient light, wherein the two non-transparent layers reduce a portion of ambient light radiated onto the at least one second organic light detecting element by at least 90%, and wherein the at least one organic light emitting element is transparent and configured to emit light through the substrate and in a direction facing away from the substrate.
2. The component according to claim 1, wherein at least one of the two non-transparent layers comprises a non-transparent covering layer, the non-transparent covering layer being arranged on a side of the common substrate that faces away from the at least one second organic light detecting layer of the at least one second light detecting element.
3. The component according to claim 1, wherein at least one of the two non-transparent layers comprises a non-transparent covering layer, the non-transparent covering layer being arranged on a side of the common substrate that faces the at least one second organic light detecting layer of the at least one second light detecting element.
4. The component according to claim 1, wherein at least one of the two non-transparent layers comprises a non-transparent covering layer, the non-transparent covering layer, as viewed from the substrate, is arranged above the at least one second organic light detecting layer of the at least one second light detecting element.
5. The component according to claim 1, wherein at least one of the non-transparent layers comprises an electrode of the at least one second organic light detecting element.
6. The component according to claim 5, wherein the electrode is a non-transparent layer and is arranged on that side of the at least one second organic light detecting layer of the at least one second light detecting element which faces away from the common substrate.
7. The component according to claim 1, wherein the common substrate forms an optical waveguide, the optical waveguide guides light from the at least one organic light emitting element internally in the optoelectronic component to the at least one second light detecting element.
8. The component according to claim 1, wherein light generated during operation in the at least one organic light emitting layer of the at least one organic light emitting element is radiated internally in the optoelectronic component directly onto the at least one organic light detecting layer of the at least one organic second light detecting element.
9. The component according to claim 1, wherein the at least one first organic light detecting element is configured to detect ambient light through the substrate.
10. The component according to claim 1, wherein the at least one first organic light detecting element is configured to detect ambient light which is radiated onto the organic optoelectronic component from an opposite side of the organic optoelectronic component relative to the substrate.
11. The component according to claim 1, wherein the at least one first organic light detecting element and/or the at least one second organic light detecting element are/is an organic photodiode, an organic photoconductor and/or an organic photoresistor.
12. The component according to claim 1, wherein a plurality of first organic light detecting elements each configured to detect ambient light is arranged on the common substrate.
13. The component according to claim 1, wherein a plurality of second organic light detecting elements is arranged on the common substrate, wherein each of the plurality of second organic light detecting elements comprises at least one second organic light detecting layer arranged between two non-transparent layers, the two non-transparent layers shade the respective at least one second organic light detecting layer from ambient light.
14. A method for operating the organic optoelectronic component according to claim 1, the method comprising: applying a current and/or voltage to the organic optoelectronic component; measuring the light by the at least one organic light detecting element; and regulating the at least one organic light emitting element by regulating the current and/or voltage based on the light measurement.
15. The method according to claim 14, wherein the first organic light detecting element detects ambient light, and the second organic light detecting element detects light guided internally in the optoelectronic component from the at least one organic light emitting element to the at least one second organic light detecting element.
16. An organic optoelectronic component comprising: at least one organic light emitting element comprising an organic functional layer stack having at least one organic light emitting layer between two electrodes; and at least one organic light detecting element comprising at least one first organic light detecting element comprising at least one first organic light detecting layer, wherein the at least one organic light emitting element and the at least one organic light detecting element are arranged laterally adjacent on a common substrate, wherein the at least one first organic light detecting layer of the at least one first organic light detecting element is permanently arranged between two non-transparent layers, the two non-transparent layers shade the at least one first organic light detecting layer of the at least one first organic light detecting element from ambient light, wherein the two non-transparent layers reduce a portion of ambient light radiated onto the at least one first organic light detecting element by at least 90%, and wherein the at least one organic light emitting element is transparent and is configured to emit light through the substrate and in a direction facing away from the substrate.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Further advantages, advantageous embodiments and developments will become apparent from the exemplary embodiments described below in association with the figures.
(2) In the figures:
(3)
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(9) In the exemplary embodiments and figures, elements that are identical, of identical type or act identically may be provided in each case with the same reference signs. The illustrated elements and their size relationships among one another should not be regarded as true to scale; rather, individual elements such as, for example, layers, component parts, components and regions may be illustrated with an exaggerated size in order to enable better illustration and/or in order to afford a better understanding.
DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS
(10)
(11) The organic light emitting element 100, which may also be designated as OLED 100 hereinafter, comprises a substrate 101, on which an organic functional layer stack 103 having at least one organic light emitting layer is arranged between transparent electrodes 102 and 104, such that light generated in the organic functional layer stack 103 during the operation of the OLED 100 can be radiated through the transparent electrodes 102, 104. Furthermore, the substrate 101 is embodied as transparent, for example, in the form of a glass plate or glass layer. As an alternative thereto, the substrate 101 can, for example, also comprise a transparent plastic or a glass-plastic laminate.
(12) At least one of the transparent electrodes 102, 104 comprises a transparent conductive oxide, for example. Transparent conductive oxides (TCO) are transparent conductive materials, generally metal oxides, such as, for example, zinc oxide, tin oxide, cadmium oxide, titanium oxide, indium oxide and indium tin oxide (ITO). Alongside binary metal-oxygen compounds, such as, for example, ZnO, SnO.sub.2 or In.sub.2O.sub.3, ternary metal-oxygen compounds, such as, for example, Zn.sub.2SnO.sub.4, CdSnO.sub.3, ZnSnO.sub.3, MgIn.sub.2O.sub.4, GaInO.sub.3, Zn.sub.2In.sub.2O.sub.5 or In.sub.4Sn.sub.3O.sub.12, or mixtures of different transparent conductive oxides, also belong to the group of TCOs. Furthermore, the TCOs do not necessarily correspond to a stoichiometric composition and can also be p- or n-doped.
(13) The further of the transparent electrodes 102, 104 can comprise a metal, for example, which can be selected from aluminum, barium, indium, silver, gold, magnesium, calcium and lithium, and compounds, combinations and alloys therewith, and which has a thickness small enough to be light-transmissive. In particular, a metal-comprising electrode can comprise Ag, Al or alloys or layer stacks comprising these, for example, Ag/Mg, Ag/Ca, Mg/Al or Mo/Al/Mo or Cr/Al/Cr.
(14) Alternatively or additionally, it is also possible for both electrodes 102, 104 to comprise a TCO material mentioned above. Furthermore, a transparent electrode can, for example, also comprise metallic network structures or conductive networks or metallic meshes, for example, comprising or composed of silver, and/or graphene or carbon-containing layers. Furthermore, one or both electrodes 102, 104 can comprise a layer stack comprising at least one TCO and at least one metal and/or one of the further materials mentioned.
(15) In the exemplary embodiment shown, the bottom electrode 102 is embodied as an anode, while the top electrode 104 is embodied as a cathode. With an appropriate choice of materials, however, a construction reversed with respect to the polarity is also possible.
(16) The electrodes 102, 104 are preferably embodied in large-area and continuous fashion, such that the organic light emitting element 100 is shaped as a luminous source, in particular as a surface light source. In this case, “large-area” can mean that the organic light emitting element 100 has an area of greater than or equal to a few square millimeters, preferably greater than or equal to one square centimeter and particularly preferably greater than or equal to one square decimeter. As an alternative thereto, it may also be possible that at least one of the electrodes 102, 104 of the organic light emitting element 100 between which the organic functional layer stack 103 is situated is embodied in a structured fashion, as a result of which a spatially and/or temporally structured and/or variable luminous impression, for example, for structured lighting or for a display device, can be made possible by means of the organic light emitting element 100.
(17) For electrically contacting the electrodes 102 and 104, as is shown in
(18) The organic functional layer stack 103 can comprise, in addition to the at least one organic light emitting layer, further organic layers, for example, one or more selected from a hole injection layer, a hole transport layer, an electron blocking layer, a hole blocking layer, an electronic transport layer, an electron injection layer and a charge generation layer (CGL), which are suitable for conducting holes or electrons to the organic light emitting layer or for blocking the respective transport. The layers of the organic functional layer stack 103 can comprise organic polymers, organic oligomers, organic monomers, organic small, non-polymeric molecules (“small molecules”), or combinations thereof. In particular, it may be advantageous if the organic functional layer stack 103 comprises a functional layer embodied as a hole transport layer in order to enable an effective injection of holes into the organic light emitting layer. By way of example, tertiary amines, carbazole derivatives, conductive polyaniline or polyethylene dioxythiophene may prove to be advantageous as materials for a hole transport layer. Suitable materials for the light emitting layer include electroluminescent materials which exhibit radiation emission on account of fluorescence or phosphorescence, for example, polyfluorene, polythiophene or polyphenylene or derivatives, compounds, mixtures or copolymers thereof.
(19) Furthermore, as shown in
(20) An encapsulation 107 for protecting the organic functional layer stack 103 and the electrodes 102, 104 is arranged above the organic functional layer stack 103 and the electrodes 102, 104. In this case, the encapsulation 107 is particularly preferably embodied as a transparent thin-film encapsulation.
(21) In the present case, an encapsulation embodied as a thin-film encapsulation is understood to mean a device suitable for forming a barrier with respect to atmospheric substances, in particular with respect to moisture and oxygen and/or with respect to further damaging substances such as, for instance, corrosive gases, for example, hydrogen sulfide. In other words, the thin-film encapsulation is embodied in such a way that at most very small portions of atmospheric substances can penetrate through it. This barrier effect in the case of the thin-film encapsulation is substantially produced by barrier layers and/or passivation layers which are embodied as thin layers and which are part of the encapsulation. The layers of the encapsulation generally have a thickness of less than or equal to a few 100 nm.
(22) In particular, the thin-film encapsulation can comprise or consist of thin layers which are responsible for the barrier effect of the encapsulation. The thin layers can be applied, for example, by means of an atomic layer deposition (ALD) method or molecular layer deposition (MLD) method. Suitable materials for the layers of the encapsulation arrangement are, for example, aluminum oxide, zinc oxide, zirconium oxide, titanium oxide, hafnium oxide, lanthanum oxide, tantalum oxide. The encapsulation preferably comprises a layer sequence having a plurality of the thin layers, each having a thickness of between one atomic layer and a few 100 nm.
(23) As an alternative or in addition to thin layers produced by means of ALD or MLD, the encapsulation can comprise at least one or a plurality of further layers, that is to say in particular barrier layers and/or passivation layers, which are deposited by a thermal vapor deposition or by means of a plasma-assisted process, for instance sputtering, chemical vapor deposition (CVD) or plasma-enhanced chemical vapor deposition (PECVD). Suitable materials therefor may be the abovementioned materials and silicon nitride, silicon oxide, silicon oxynitride, indium tin oxide, indium zinc oxide, aluminum-doped zinc oxide, aluminum oxide, and mixtures and alloys of the materials mentioned. The one or the plurality of further layers can have, for example, in each case a thickness of between 1 nm and 5 μm and preferably between 1 nm and 400 nm, inclusive of the limits.
(24) As an alternative or in addition to a thin-film encapsulation, the encapsulation 107 can also comprise a glass lid which, for example, in the form of a glass substrate having a cavity, is adhesively bonded on the substrate 101 by means of an adhesive layer. Furthermore, a moisture-absorbing substance (getter), for example, composed of zeolite, can be adhesively bonded into the cavity in order to bind moisture, oxygen or other damaging gases which can penetrate through the adhesive. Furthermore, the adhesive layer for fixing the lid on the substrate may also itself be absorbent for damaging substances and/or adhesive layer structures may be present.
(25) Furthermore, as shown in
(26) In order to improve the coupling out of light, as shown in
(27) With regard to further features of the organic light emitting element 100, for example, with regard to the construction, the layer composition and the materials of the organic functional layer stack, of the electrodes and of the encapsulation, reference is made to International Application Publication No. WO 2010/066245 A1, which is hereby expressly incorporated by reference with regard to the construction of an organic light emitting component and also with regard to modifications and variations of the organic light emitting element shown in
(28) The exemplary embodiments shown hereinafter have in each case an organic light emitting element 100 which may be embodied in accordance with the exemplary embodiment in
(29)
(30) The first organic light detecting element 200 comprises an organic functional layer stack 203 between two electrodes 202, 204, wherein the organic functional layer stack 203 comprises at least one organic light detecting layer. In the exemplary embodiment shown, the organic light detecting layer is embodied as a pn junction for generating charge carriers.
(31) In particular, the organic light detecting element 200 in the exemplary embodiment shown, with regard to the electrodes 202, 204 and the organic functional layer stack 203, has the same construction as the organic light emitting element 100 with regard to the electrodes 102, 104 and the organic functional layer stack 103 and can be operated inversely with respect to the organic light emitting element 100, that is to say with opposite electrical polarity. As a result, the manufacture of the organic optoelectronic component shown may cause no or only low additional costs in comparison with an exclusively light emitting component. In particular, the first organic light detecting element 200 in the exemplary embodiment shown is embodied as transparent and can detect ambient light, as is also explained in association with
(32) The organic optoelectronic component furthermore comprises an encapsulation 107, which is embodied as a thin-film encapsulation and which forms a common encapsulation for the organic light emitting element 100 and the first organic light detecting element 200. In other words, the encapsulation 107 extends with large area and continuously over the functional layers of the organic light emitting element 100 and of the first organic light detecting element 200. A common cover 109 is fixed on the common encapsulation 107 by means of an adhesive layer 108.
(33) Furthermore, electrode connection pieces 205 are present, which serve for electrically contacting the electrodes 202, 204 and which can be embodied like the electrode connection pieces 105 of the organic light emitting element 100. The electrode connection pieces 105, 205 extend from the elements 100, 200 out of the encapsulation 107, such that the elements 100, 200 can be contacted externally.
(34) An electrical insulator layer 112 is arranged between the organic light emitting element 100 and the organic light detecting element 200 directly on the substrate 101, said electrical insulator layer being covered by the common encapsulation 107. The electrical insulator layer 112, which can comprise or be composed of polyimide or some other electrically insulating material, for example, serves for electrically insulating the first organic light detecting element 200 from the organic light detecting element 100, such that the electrode connection pieces 105, 205 of the elements 100, 200 can also be arranged at a small distance from one another on the common substrate 101, without the occurrence of an electrical crosstalk between the elements 100, 200.
(35) As an alternative to the first organic light detecting element 200, the organic optoelectronic component shown in
(36)
(37) In the exemplary embodiment shown, purely by way of example, the second organic light detecting element 300 like the first organic light detecting element 200 is embodied and usable as organic photodiode. The second organic light detecting element 300 comprises an organic functional layer stack 303 between two electrodes 302, 304, wherein the organic functional layer stack 303 has at least one organic light detecting layer.
(38) The at least one organic light detecting layer of the second organic light detecting element 300 is arranged between two non-transparent layers 311. One of the two non-transparent layers 311, which is arranged above the organic functional layer stack 303 as viewed from the common substrate 101, is formed by the top electrode 304, which comprises a non-transparent material, for example, a metal described above in connection with the electrodes 102, 104, such as aluminum, for instance, which has a sufficient thickness, typically greater than or equal to 100 nm, to be light-nontransmissive. The other of the two non-transparent layers 311 is formed by a non-transparent covering layer 301, which, in the exemplary embodiment shown, is arranged on that side of the common substrate 101 which faces away from the organic functional layer stack 303, and comprises a non-transparent metal and/or a non-transparent plastic. The non-transparent layers 311, as explained in greater detail in association with
(39) The second organic light detecting element 300 can alternatively have a different construction, as is explained, for example, in association with
(40) The encapsulation 107 is embodied as in the previous exemplary embodiment as a common encapsulation for the organic light emitting element 100 and the organic light detecting elements 200, 300. As an alternative thereto, it is also possible to provide mutually separate encapsulations for the organic light emitting element and the organic light detecting elements.
(41) Furthermore, electrode connection pieces 305 are present, which serve for electrically contacting the electrodes 302, 304 and which can be embodied like the electrode connection pieces 105 of the organic light emitting element 100. Furthermore, an electrical insulator layer 112 is arranged between the organic light emitting element 100 and the second organic light detecting element 300 directly on the substrate 101.
(42)
(43) The organic light emitting element 100 in
(44) Through the transparent substrate, part of the light generated by the organic light emitting element 100 is guided internally in the organic optoelectronic component to the organic light detecting elements 200, 300 on account of scattering and waveguiding effects, as indicated by the arrows having the reference signs 2. Furthermore, depending on the embodiment of the electrodes, insulator layers and other layers and elements, alternatively or additionally it may also be possible for light to be guided in other layers internally from the organic light emitting element 100 to one or both organic light detecting elements 200, 300, for example, through the common encapsulation.
(45) If the second organic light detecting element 300, as in the exemplary embodiment in
(46) By means of a targeted adaptation of the respective distance between the organic light emitting element 100 and each of the organic light detecting elements 200, 300 and in this case in particular with regard to an absorption in the common substrate, by means of a suitable arrangement of one or a plurality of coupling-out layers on one or both sides of the common substrate and by means of a suitable choice of materials with regard to the electrodes, the insulator layers and the encapsulation, for example, with regard to a suitable refractive index for setting the total internal reflection in the substrate or the cover, the proportion of the light 2 guided internally from the organic light emitting element 100 in each case to the organic light detecting element 200 and to the organic light detecting element 300, can be set in a targeted manner. A complete suppression or at least a greatest possible reduction of the internally guided light 2 to the first organic light detecting element 200 may be desirable and advantageous in particular if the intention is for only ambient light detection, that is to say detection of external light, to be effected by the second organic light detecting element 200.
(47) As is furthermore shown in
(48) The first organic light detecting element 200 is designed to detect ambient light 3, 4 from the substrate side and/or from the side of the cover and for this purpose, as explained in greater detail in particular in the exemplary embodiments in
(49) By means of the non-transparent layers 311 described in association with
(50) The organic optoelectronic component in accordance with the exemplary embodiment in
(51) Variations and modifications of the organic optoelectronic component are possible in addition to the exemplary embodiments shown. By way of example, it is possible to vary the respective type of the organic light detecting elements with regard to the construction and the functioning and/or the electrical circuitry, the number of organic light detecting elements, the position of one or more organic light detecting elements in relation to the luminous area of the organic light emitting element, the respective detection area of the organic light detecting elements, for example, in relation to an adaptation to the organic light emitting element in terms of geometry, stack and/or circuitry, the respective distance between the organic light detecting elements and the organic light emitting element, the arrangement and number of one or more coupling-out layers and/or the waveguide properties in the substrate or the rest of the layer structure and thus the signal transmission between the organic light emitting element and the organic light detecting elements. Furthermore, the coupling-out direction of the organic light emitting element embodied as transparent can be influenced by suitable choice of materials and/or coupling-out layers, such that in the case where the organic optoelectronic component is used as part of a window, for example, different proportions can be emitted toward the inside and outside, that is to say approximately 40% toward the outside and 60% toward the inside. Provision can furthermore be made of additional functional layers for influencing the coupling-out direction.
(52) By way of example,
(53) Furthermore, it may also be possible to provide a plurality of second organic light detecting elements 300 or a plurality of first and second organic light detecting elements 200, 300.
(54)
(55) The interconnection possibility shown in
(56) In the exemplary embodiment shown, the electronic component is embodied as a regulatable current and/or voltage source 400, which measures the electrical signal provided by the at least one organic light detecting element and regulates the organic light emitting element 100 depending on the measurement. In particular, the electronic component measures the electrically measurable signal which is provided by the at least one first organic light detecting element 200 and which is generated by light comprising ambient light. Furthermore, the electronic component measures the electrically measurable signal which is provided by the at least one second organic light detecting element 300 and which is generated by the light guided internally in the organic optoelectronic component from the organic light emitting element 100 to the organic light detecting element 300. The exemplary embodiment shown in
(57) As is shown in
(58)
(59)
(60) In the exemplary embodiment in
(61)
(62) The top electrode 204 can comprise, for example, a transparent material such as, for instance, a TCO or some other transparent material mentioned above. Alternatively or additionally, it may also be possible for the top electrode 204 to be embodied as a ring contact and to have, for example, an opening above the organic functional layer stack of the first organic light detecting element 200, as is indicated by the dashed lines. Such an opening can be enclosed completely by electrode material in a lateral direction, such that the electrode 204 can be embodied as a complete ring. Furthermore, it is also possible for an electrode 204 embodied as a ring contact to enclose the opening only in a partial region in a lateral direction and thus to be embodied in a U-shaped fashion, for example.
(63) As an alternative to non-transparent electrode materials in the exemplary embodiments in
(64)
(65)
(66) Photoconductive organic materials can be embodied in one layer on an electrically conductive layer, for example, as in the exemplary embodiments shown, for example, on an electrode or on the electrode connection pieces 205 shown in
(67) The first organic light detecting element 200 in accordance with the exemplary embodiment in
(68) The exemplary embodiments shown in
(69) Depending on materials and construction of the organic light detecting elements 200, 300 shown, the latter can also be constructed simultaneously as photoconductor and photodiode. Such an organic light detecting element can be usable as a photodiode with an electrical bias voltage and as a photoconductor without an electrical bias voltage.
(70) Furthermore, depending on materials and construction, the electrical resistance of the organic light detecting elements 200, 300 can also be measured, such that the first and/or second organic light detecting element 200, 300 can be embodied and usable as organic photoresistor. By way of example, an organic light detecting element for this purpose can comprise an organic functional layer based on pentacene.
(71)
(72) In the exemplary embodiment shown, a first organic light detecting element 200 is provided, which detects ambient light 4 on the exterior side, while a further organic light detecting element is provided, which is embodied, for example, as a further first organic light detecting element 200′ for detecting ambient light in the interior or as a second organic light detecting element 300 for detecting light emitted by the at least one organic light emitting element 100.
(73) In the case of a sufficient brightness in the exterior space, for example, as a result of insolation as shown in
(74) In the case of a lower brightness in the exterior space and thus in the case of an ambient light 4 having a lower intensity, for example, owing to clouds, overcast sky, rain or darkness as indicated in
(75)
(76) By way of example, the organic light emitting component 100 can also be designed only partly as an OLED and/or be structured in strips, for example, such that an individual configuration of the interior and exterior lighting, for example, in the form of a pattern or name representation may be possible. The operation of the organic light emitting element 100 enables an effect as a so-called two-way mirror, which makes it more difficult to look through from the outside to the inside if the interior space is kept darker than the exterior space. Furthermore, the organic light emitting element 100 can additionally be coupled to a proximity sensor, such that automatic illumination of the exterior door region is possible.
(77) The features and exemplary embodiments described in association with the figures can be combined with one another in accordance with further exemplary embodiments, even if such combinations are not explicitly described with the individual figures. Furthermore, the exemplary embodiments shown in the figures can have further or alternative features in accordance with the general description.
(78) The invention is not restricted to the exemplary embodiments by the description on the basis of said exemplary embodiments. Rather, the invention encompasses any novel feature and also any combination of features, which in particular includes any combination of features in the patent claims, even if this feature or this combination itself is not explicitly specified in the patent claims or exemplary embodiments.