Apparatus for molecular adhesion bonding with compensation for radial misalignment
09818614 · 2017-11-14
Assignee
Inventors
Cpc classification
B32B38/1866
PERFORMING OPERATIONS; TRANSPORTING
B32B2309/72
PERFORMING OPERATIONS; TRANSPORTING
H01L2224/80948
ELECTRICITY
H01L2224/80896
ELECTRICITY
H01L24/75
ELECTRICITY
H01L2224/75901
ELECTRICITY
H01L25/50
ELECTRICITY
H01L2224/75702
ELECTRICITY
H01L24/80
ELECTRICITY
B32B38/1808
PERFORMING OPERATIONS; TRANSPORTING
H01L2224/80
ELECTRICITY
H01L2224/80895
ELECTRICITY
H01L2224/94
ELECTRICITY
B32B2041/04
PERFORMING OPERATIONS; TRANSPORTING
B32B37/144
PERFORMING OPERATIONS; TRANSPORTING
H01L2224/75756
ELECTRICITY
H01L2224/80
ELECTRICITY
H01L24/94
ELECTRICITY
H01L2224/94
ELECTRICITY
H01L21/185
ELECTRICITY
H01L2224/08146
ELECTRICITY
B32B37/18
PERFORMING OPERATIONS; TRANSPORTING
B32B41/00
PERFORMING OPERATIONS; TRANSPORTING
Y10T156/1092
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T156/1089
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T156/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
B29C65/00
PERFORMING OPERATIONS; TRANSPORTING
H01L21/18
ELECTRICITY
B32B37/14
PERFORMING OPERATIONS; TRANSPORTING
B32B37/18
PERFORMING OPERATIONS; TRANSPORTING
B32B38/18
PERFORMING OPERATIONS; TRANSPORTING
B32B41/00
PERFORMING OPERATIONS; TRANSPORTING
H01L25/065
ELECTRICITY
Abstract
A method for bonding a first wafer onto a second wafer by molecular adhesion where the wafers have an initial radial misalignment between them. The method includes bringing the two wafers into contact so as to initiate the propagation of a bonding wave between the two wafers while a predefined bonding curvature is imposed on at least one of the two wafers during the contacting step as a function of the initial radial misalignment.
Claims
1. An apparatus for bonding a first wafer onto a second wafer by molecular adhesion, the apparatus comprising: a microprocessor for calculating a predefined bonding curvature of the first wafer as a function of an initial radial misalignment between the first wafer and the second wafer, wherein the initial radial misalignment occurs as a result of different radial expansions of the first and second wafers; a first holding support for holding the first wafer, wherein the first holding support comprises a jack for imposing the predefined bonding curvature on the first wafer; a second holding support for holding the second wafer; and a microcontroller for controlling the apparatus so that the second wafer is released from the second support before or while being brought in contact with the first wafer, so that the second wafer adapts to the bonding curvature imposed on the first wafer during the propagation of a bonding wave.
2. The apparatus of claim 1, wherein the microprocessor calculates a radius of curvature corresponding to the predefined bonding curvature as the function of the initial radial misalignment.
3. The apparatus of claim 2, wherein the microprocessor comprises a microprocessor system.
4. The apparatus of claim 1, wherein the jack is driven according to a radius of curvature corresponding to the predefined bonding curvature.
5. The apparatus of claim 1, wherein the first holding support has a curvature corresponding to the predefined bonding curvature.
6. The apparatus of claim 1, further comprising a membrane interposed between the first wafer and the first holding support, the membrane having a curvature corresponding to the predefined bonding curvature.
7. The apparatus of claim 1, wherein the initial radial misalignment is determined by bonding two wafers from a same wafer batch as the first wafer and the second wafer and measuring the misalignment between the two bonded wafers.
8. The apparatus of claim 7, further comprising: a sensor to measure the misalignment between the two bonded wafers at a plurality of positions on the two bonded wafers using infrared microscopy.
9. The apparatus of claim 8, wherein the sensor carries out the measurement of the misalignment with alignment marks at centers and at peripheral portions of the two bonded wafers.
10. The apparatus of claim 9, wherein the alignment marks at the peripheral portions are about half the distance between the centers and edges of the two bonded wafers.
11. The apparatus of claim 1, further comprising: a sensor to measure the misalignment between the two bonded wafers, and wherein the microprocessor determines a compensation radial misalignment in dependence at least in part on the initial radial misalignment between the first wafer and the second wafer.
12. The apparatus of claim 1, wherein the predefined bonding curvature is calculated by K.sub.B=(8K.sub.F−(K.sub.1+K.sub.2))/6, where K.sub.B is the predefined bonding curvature, K.sub.F is a post-bonding curvature of the combined structure of the first and second wafers, K.sub.1 is the initial curvature of the first wafer, and K.sub.2 is the initial curvature of the second wafer.
13. The apparatus of claim 1, wherein the predefined bonding curvature is selected such that a desired post-bonding curvature of the combined structure of the first and second wafers is achieved.
14. The apparatus of claim 13, wherein the desired post-bonding curvature is calculated by K.sub.F=(2(K.sub.1+K.sub.2)+12K.sub.B)/16, where K.sub.F is the desired post-bonding curvature, K.sub.1 is the initial curvature of the first wafer, K.sub.2 is the initial curvature of the second wafer, and K.sub.B is the predefined bonding curvature.
15. An apparatus for bonding a first wafer onto a second wafer by molecular adhesion, the apparatus comprising: a first holding support for holding the first wafer, wherein the first holding support comprises a jack for imposing a predefined bonding curvature on the first wafer; a second holding support for holding the second wafer; a microcontroller or logic elements to control the apparatus so that the second wafer is released from the second support before or while being brought in contact with the first wafer, so that the second wafer adapts to the bonding curvature imposed on the first wafer during the propagation of a bonding wave; and a microprocessor or microprocessor system for calculating the predefined bonding curvature or a radius of curvature corresponding to the predefined bonding curvature as the function of the initial radial misalignment, wherein the predefined bonding curvature is a function of an initial radial misalignment between the first wafer and the second wafer, wherein the initial radial misalignment occurs as a result of different radial expansions of the first and second wafers, wherein the microprocessor or microprocessor system receives sensor information that defines radial wafer misalignments between two bonded wafers from a same wafer batch as the first wafer and the second wafer and computes therefrom bonding curvature information and wafer displacement information, which information is sent to the microcontroller or logic elements, and wherein the microprocessor or the microprocessor system uses the radial wafer misalignments between the two bonded wafers as the initial radial misalignment.
16. A wafer bonding apparatus for bonding a first wafer onto a second wafer by molecular adhesion, the apparatus comprising: a microprocessor for calculating a predefined bonding curvature of the first wafer as a function of an initial radial misalignment between the first wafer and the second wafer, wherein the initial radial misalignment occurs as a result of different radial expansions of the first and second wafers; a first holding support assembly including a first holding support configured to hold the first wafer, the first holding support assembly configured to impose the predefined bonding curvature on the first wafer; and a second holding support configured to hold the second wafer, wherein the apparatus is configured to release the second wafer from the second support before or while being brought into contact with the first wafer such that the second wafer adapts to the bonding curvature imposed on the first wafer by the first holding support while a bonding wave propagates between the first wafer and the second wafer.
17. The wafer bonding apparatus of claim 16, wherein the first holding support assembly includes a jack, actuation of the jack imposing the predefined bonding curvature on the first wafer held by the first holding support.
18. The wafer bonding apparatus of claim 16, wherein the first holding support assembly includes a membrane interposed between the first wafer and the first holding support, the membrane having a curvature corresponding to the predefined bonding curvature.
19. The wafer bonding apparatus of claim 16, wherein the predefined bonding curvature is imposed on the first wafer by the first holding support, the first holding support having a curvature corresponding to the predefined bonding curvature.
20. The wafer bonding apparatus of claim 16, wherein the wafer bonding apparatus comprises a controller including a microcontroller or logic elements configured to receive sensor information defining radial wafer misalignments between the first wafer and the second wafer, the controller configured to compute bonding curvature information and wafer displacement information at least in part from the sensor information, the controller configured to control at least one of the first holding support and the second holding support using the bonding curvature information and the wafer displacement information.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) The present invention may be understood more fully by reference to the following detailed description of the preferred embodiment of the present invention, illustrative examples of specific embodiments of the invention, and the appended figures in which:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
DETAILED DESCRIPTION
(9) The present invention applies in general to the bonding by molecular adhesion between two wafers that have different radial expansions, leading to a radial misalignment between them after bonding.
(10) The invention applies more particularly, but not exclusively, to the bonding by molecular adhesion between at least two wafers, each comprising components in which at least some of the components of each of the wafers are intended to be aligned after bonding.
(11) In order to compensate for the phenomenon of radial misalignment of the wafers after bonding, the present invention proposes to impose a bonding curvature, which has been defined beforehand as a function of the initial radial misalignment, on the wafers during their bonding.
(12) More precisely, before bonding, each of the two wafers has its own curvature, which may be concave, as in the case of the wafer 30 in
(13)
(14) Once the bonding has been carried out and the wafers have been released from their respective holding supports, the structure constituted by the combination of the bonded wafers 50 and 60 has a curvature K.sub.F, referred to as the “post-bonding curvature.”
(15) The post-bonding curvature K.sub.F may be calculated with the following Formula (1):
K.sub.F=(2(K.sub.1+K.sub.2)+12K.sub.B)/16 (1)
This Formula (1) was determined on the basis of Formula (12) given in the document T. Turner et al., entitled “Mechanics of wafer bonding: Effect of clamping,” Journal of Applied Physics, Vol. 95, No. 1, Jan. 1, 2004.
(16) On the basis of this Formula (1), it can be seen that the influence of the bonding curvature K.sub.B on the post-bonding curvature K.sub.F predominates (by a factor of 6) over that of the initial curvatures K.sub.1 and K.sub.2, respectively, of the wafers 50 and 60.
(17) Furthermore, the radial misalignment D.sub.R resulting between the two wafers after bonding may be determined by the following Formula (2):
D.sub.R=−2(ϵR) (2)
where R is the distance from the center of the wafer at the measurement point of the radial misalignment and ϵ is the strain exerted on the surface of the first wafer 50 (top).
(18) There is, furthermore, a relationship between the strain exerted on the surface of the first wafer and the post-bonding curvature K.sub.F, which is given by the following Formula (3):
ϵ=K.sub.F(h/2) (3)
where h is the thickness of the first wafer.
(19) By introducing the elements of Formula (3) corresponding to the strain ϵ into Formula (2), the relationship between the radial misalignment D.sub.R resulting after bonding and the post-bonding curvature K.sub.F is established by the following Formula (4):
D.sub.R=−K.sub.F h R (4)
It can be seen that the radial misalignment D.sub.R is a function of the post-bonding curvature K.sub.F.
(20) Consequently, by knowing the initial radial misalignment D.sub.Ri, a compensation radial misalignment D.sub.Rc is determined such that: D.sub.Rc=−D.sub.Ri, which, with Formula (4), gives: D.sub.Rc=K.sub.F h R.
(21) The initial radial alignment may be measured by carrying out bonding between two wafers of the same batch of wafers and measuring the misalignment of the two wafers in order to deduce the initial radial component therefrom. The two wafers have alignment marks, such as simple crosses (measurement methods by means of Vernier or Moiré structures, which make it possible to measure the misalignment in microns by infrared microscopy or confocal infrared microscopy, and to do so at a plurality of positions on the wafer, which generally lie at its center and periphery. The various misalignment components and, in particular, the radial misalignment, can be extracted from these measurements. These measurements are generally carried out level with alignment marks arranged at the center and periphery of the wafer, for example, at 147 mm from the center of a 300 mm wafer. At the periphery, the radial misalignment is maximal and may exceed one micron, as presented in
(22) In this way, the initial radial alignment is known for an entire batch of wafers, to which it is possible to apply the bonding method of the invention and compensate for the initial radial misalignment. The pair of wafers used for measuring the initial radial misalignment may be withdrawn from the batch or separated in order to re-bond the wafers with the bonding curvature predetermined according to the invention.
(23) This initial radial misalignment could also be determined by precisely measuring the distance between two microcomponents (to within 0.33 ppm) on each of the two wafers taken separately, and by comparing these two differences.
(24) On the basis of this last Formula (4), the target post-bonding curvature K.sub.Fc allowing the compensation radial misalignment to be obtained, is calculated according to Formula (5):
K.sub.Fc=D.sub.Rc/(h.Math.R) (5)
(25) Formula (1) shows that the post-bonding curvature K.sub.F is determined as a function of the initial curvatures K.sub.1 and K.sub.2 of the two wafers and the bonding curvature K.sub.B. Since the curvatures K.sub.1 and K.sub.2 correspond to the intrinsic curvatures of the two wafers, only the curvature K.sub.B represents the variable parameter, making it possible to adjust the value of the post-bonding curvature K.sub.F.
(26) Thus, the target value of the post-bonding curvature K.sub.Fc making it possible to obtain the compensation radial misalignment having been calculated on the basis of Formula (5) and the curvatures K.sub.1 and K.sub.2 having been measured beforehand, for example, by means of optical measurement tools such as KLA-Tencor Flexus from KLA-Tencor Corp (or by any measurement by a capacitive gauge, optical profilometry or mechanical profilometry, which makes it possible to determine the bow), the bonding curvature K.sub.B to be imposed to the wafers in order to obtain the target post-bonding curvature K.sub.Fc is calculated such that:
K.sub.B=(8K.sub.F−(K.sub.1+K.sub.2))/6 (6)
(27) An exemplary production of a three-dimensional structure by transferring a layer of microcomponents that is formed on a first wafer 100 onto a second wafer 200, using a method of bonding with compensation for the radial misalignment according to an embodiment of the invention, will now be described with reference to
(28) The production of the three-dimensional structure starts with the formation of a first series of microcomponents 110 on the surface of the first wafer 100 (
(29) The second wafer 200 is preferably a silicon wafer with a diameter of 300 mm.
(30) The microcomponents 110 and 210 are formed by photolithography by means of a mask, making it possible to define the regions for formation of patterns corresponding to the microcomponents to be produced.
(31) The microcomponents 110 and 210 are intended to interact with one another, for example, in order to form finished components by joining microcomponents 110 and 210 in pairs, each constituting apart of the component to be produced, or in order to form interconnect circuits for corresponding microcomponents 110 and 210. It is, therefore, important to be able to ensure good alignment between the microcomponents 110 and 210 after bonding of the wafers.
(32) According to the invention, a bonding machine is used that, during the bonding, imposes a bonding curvature K.sub.B on one of the wafers while allowing the other wafer to adapt to the imposed curvature by propagation of the bonding wave between the two wafers. This operation makes it possible to obtain a target post-bonding curvature K.sub.Fc, which introduces between the two wafers the compensation radial misalignment D.sub.Rc, which will compensate for the initial radial misalignment D.sub.Ri existing between the two wafers and induced (differential radial expansions between the wafers) during the various treatment steps carried out beforehand on each of the wafers before their bonding (lithography, layer deposition, heat treatments, etc.).
(33) As illustrated in
(34) At the start of the bonding, the two wafers 100 and 200 are each held pressed on the holding surfaces of their respective support plate (
(35) Next, according to the invention, a curvature corresponding to the bonding curvature K.sub.B, which was calculated by means of Formula (6) given above, and which makes it possible to obtain the target post-bonding curvature K.sub.Fc determined beforehand, is imposed on the first wafer 100 (or, alternatively, the second wafer) in order to induce a compensation radial misalignment D.sub.Rc as described above (
(36) To this end, the first support plate 310 comprises a jack or linear actuator 312 provided with a rod 313 that, when the jack is actuated, extends beyond the holding surface 311 of the plate 310 on which the first wafer 100 is pressed. As illustrated in
(37) The bonding machine 300 controls the distance d.sub.t over which the rod 313 projects beyond the holding surface 311, this distance d.sub.t being determined as a function of the bonding curvature K.sub.B to be imposed on the wafers. More precisely, the jack 312 is equipped with a servocontrol (not represented), which controls the linear position of the rod 313 as a function of a setpoint position defined by the bonding machine 300.
(38) The bonding machine 300 is equipped with processing means, such as a programmable microprocessor, which are capable of calculating the bonding curvature K.sub.B or a radius of curvature equivalent to the bonding curvature K.sub.B, in the case of using a jack as in the machine 300 described here. More precisely, the initial curvatures K.sub.1 and K.sub.2, respectively, of the wafers 100 and 200, as well as the target post-bonding curvature K.sub.Pc are entered into the bonding machine, and the processing means of the bonding machine then calculates the bonding curvature K.sub.B to be imposed by using Formula (6) given above and invert this value in order to obtain the corresponding target radius of curvature R.sub.cb (R.sub.cb=1/K.sub.B).
(39) The final parameter to be defined, which needs to be sent to the servocontrol of the jack 312, is the bow ΔZ corresponding to the radius of curvature R.sub.cb, because, as indicated above, the bow of a wafer corresponds to the distance taken at the center of the wafer between a reference plane, here, the holding surface 311, and the surface of the wafer, here, the surface of the wafer facing the holding surface 311. The bow ΔZ corresponds to the distance dt over which the rod 313 must be extended when imposing the bonding curvature.
(40) The target bow Δzc as a function of the target radius of curvature R.sub.cb may be calculated with the following Formula (7):
Δzc=R.sub.cb−√(R.sub.cb.sup.2−(D/2).sup.2) (7)
where D is the diameter of the wafer to be curved.
(41) Once calculated, the numerical value of the target bow Δzc is transmitted to the servocontrol of the jack 312, which actuates the rod in order to position it at the equivalent distance d.sub.t (d.sub.t=Δzc).
(42) When the bonding curvature K.sub.B is applied to the first wafer 100, the support plates 310 and 320 are moved toward one another so that the foremost portion 100a (apex) of the wafer 100 is delicately placed in contact with the exposed surface of the second wafer 200 so as to thus initiate the propagation of a bonding wave (
(43) As an alternative, the two wafers may be placed at a distance Δzc from one another and one of the two wafers may subsequently be deformed until the surfaces are brought in intimate contact by actuating the rod 313 over a distance d.sub.t=Δzc. Imposition of the bonding curvature K.sub.B and initiation of the propagation of the bonding wave are thus performed simultaneously. In this case as well, the wafer that is not deformed to the predefined bonding curvature must be free to adapt to the bonding curvature imposed on the other wafer during the propagation of the bonding wave.
(44) Molecular adhesion bonding is a technique well known in the art. As a reminder, the principle of molecular adhesion bonding is based on bringing two surfaces in direct contact, that is to say, without using a specific material (adhesive, wax, braze, etc.). Such an operation requires that the surfaces to be bonded are sufficiently smooth, and free of particles or contamination, and that they are brought sufficiently close together in order to make it possible to initiate contact, typically at a distance of less than a few nanometers. In this case, the attractive forces between the two surfaces are high enough to cause the propagation of a bonding wave that leads to molecular adhesion (bonding induced by all the attractive forces (van der Waals' forces) of electronic interaction between atoms or molecules of the two surfaces to be bonded).
(45) Once the propagation of the bonding wave has been initiated, the second wafer 200, then released from its support plate 320, adapts to the curvature imposed on the first wafer 100 during the progression of the bonding wave (
(46) When the two wafers are completely bonded, the first wafer 100 is completely freed from its support (
(47) It has thus been possible to compensate for the radial misalignment existing between the two wafers 100 and 200 by applying a predetermined bonding curvature. After the bonding, the microcomponents 110 remain correctly aligned with the microcomponents 210, despite the radial misalignment initially existing before bonding.
(48) The curve in
(49) After the bonding, the structure 450 may be subjected to a moderate heat treatment (less than 500° C.) so as to increase the bonding energy between the two wafers and allow one of them to be subsequently thinned.
(50) As represented in
(51) A three-dimensional structure 500 is then obtained, formed by the second wafer 200 and a layer 100a corresponding to the remaining portion of the first wafer 100.
(52) According to an alternative embodiment, after formation of the microcomponents, an oxide layer, for example, of SiO.sub.2, may be deposited on the surface of the first and/or lower wafer with a view to preparation for the bonding. This oxide layer, or these oxide layers, may furthermore be prepared by forming metal zones in them, for example, of copper, in contact with all or some of the microcomponents in order to be able to bring the microcomponents of one wafer in contact with those of the other wafer.
(53) The bonding faces of the wafers may furthermore be treated. The treatments employed for the surface preparation vary according to the bonding energy, which is intended to be obtained. If the intention is to obtain a standard bonding energy, that is to say, a relatively low one, the surface may be prepared by carrying out chemical-mechanical polishing followed by cleaning. Otherwise, if the intention is to obtain a high bonding energy between the two substrates, the preparation of the surface comprises cleaning of the RCA type (i.e., the combination of an SC1 bath (NH.sub.4OH, H.sub.2O.sub.2, H.sub.2O) adapted to remove the particles and the hydrocarbons and an SC2 bath (HCl, H.sub.2O.sub.2, H.sub.2O) adapted to remove the metallic contaminants), surface activation by a plasma, and additional cleaning followed by brushing.
(54) The bonding is preferably carried out at a controlled temperature in order to reduce the temperature difference between the two wafers.
(55) The imposition of the bonding curvature may also be carried out with a bonding machine comprising a membrane interposed between the first wafer and the support for holding it, the membrane having a curvature corresponding to the predefined bonding curvature, or with a bonding machine comprising a holding support for the first wafer having a curvature corresponding to the predefined bonding curvature, in which case, the holding support may, in particular, be deformable and driven by the machine in order to adapt to the bonding curvature calculated by it beforehand. The contacting of the second wafer with the first wafer and the release of the second wafer before initiation of the propagation of a bonding wave will be carried out as described above.
(56) By virtue of the bonding method of the invention with compensation for the radial misalignment, it has been possible to bond the first wafer 100 (top) onto the second wafer 200 (base) without significant offsets between the microcomponents 110 and 210. It is thus possible to limit the radial misalignments to negligible values homogeneously over the entire surface of the wafers. The microcomponents 110 and 210, even if they are of very small sizes (for example, <1 μm), can then be formed easily in alignment with one another. This makes it possible, for example, to interconnect the microcomponents with one another by means of metallic connections, while minimizing the risks of bad interconnection.
(57)
(58) The preferred embodiments of the invention described above do not limit the scope of the invention, since these embodiments are illustrations of several preferred aspects of the invention. Any equivalent embodiments are intended to be within the scope of this invention. Indeed, various modifications of the invention in addition to those shown and described herein, such as alternate useful combinations of the elements described, will become apparent to those skilled in the art from the subsequent description. Such modifications are also intended to fall within the scope of the appended claims. In the following (and in the application as a whole), headings and legends are used for clarity and convenience only.
(59) The words “significant” and “likely” (and similar words of degree) are used herein to mean within acceptable and expected limits, usually commercially acceptable limits. It should be understood that this invention is not limited to commercial uses; intended uses include research uses, special purpose uses, and so forth.