Wet paper web transfer belt

Abstract

The object of the present invention is to provide a wet paper web transfer belt wherein the adhesive properties and releasing properties of the wet paper web with the wet paper web contacting surface of conventional wet paper web transfer belts have been further improved and paper robbing and floating edges do not occur. This is achieved by a wet paper web transfer belt in which a polyurethane is integrated with a reinforcing base material comprising a wet paper web-side surface and a machine-side surface, at least the wet paper web-side surface of the reinforcing base material is embedded in the polyurethane, an outer circumferential layer comprising a wet paper web contacting surface is constituted by some of the polyurethane; wherein, at least the outer circumferential layer comprises two different types of fillers including a high-roundness filler with a relatively high roundness and a low-roundness filler with a relatively low roundness.

Claims

1. A wet paper web transfer belt in which a reinforcing base material comprises: a wet paper web-side surface and a machine-side surface and a thermosetting polyurethane integrated with each other, at least the wet paper web-side surface of the reinforcing base material embedded in the polyurethane, an outer circumferential layer comprising a wet paper web contacting surface constituted by some of the polyurethane; wherein at least the outer circumferential layer comprises two different types of fillers including a high-roundness filler with a relatively high roundness and a low-roundness filler with a relatively low roundness, and a difference between the high-roundness filler and the low-roundness filler is 0.1 or more, and wherein the roundness of the high-roundness filler is 0.6 or more and the roundness of the low-roundness filler is less than 0.6.

2. The wet paper web transfer belt according to claim 1, wherein a specific surface area of the high-roundness filler is 10 m.sup.2/g or less.

3. The wet paper web transfer belt according to claim 1, wherein a specific surface area of the low-roundness filler is 12 m.sup.2/g or more.

4. The wet paper web transfer belt according to claim 1, wherein the high-roundness filler comprises one or more filler(s) selected from inorganic fillers.

5. The wet paper web transfer belt according to claim 1, wherein the low-roundness filler comprises one or more filler(s) selected from inorganic fillers or carbon-based fillers.

6. The wet paper web transfer belt according to claim 1, wherein the two different fillers are only comprised in the outer circumferential layer.

7. The wet paper web transfer belt according to claim 1, wherein a content of the high-roundness filler is from 5 wt % or more to 55 wt % or less in relation to a total weight of the outer circumferential layer equal to a total weight of the polyurethane, the filler(s) and other additives, and a content of the low-roundness filler is from 5 wt % or more to 55 wt % or less in relation to the total weight of the outer circumferential layer equal to the total weight of the polyurethane, the filler(s) and other additives.

8. The wet paper web transfer belt according to claim 1, wherein a total content of the two different fillers is from 10 wt % or more to 60 wt % or less in relation to a total weight of the outer circumferential layer equal to a total weight of the polyurethane, the fillers and other additives.

9. The wet paper web transfer belt according to claim 1, wherein the low-roundness filler is one or more types of filler selected from amorphous particulate fillers, needle-like fillers, fibrous fillers, plate-like fillers.

10. The wet paper web transfer belt according to claim 1, wherein an average particle diameter of the high-roundness filler is 1.0 to 100 μm.

11. The wet paper web transfer belt according to claim 1, wherein an average particle diameter of the low-roundness filler is 1.0 to 100 μm.

12. The wet paper web transfer belt according to claim 1, wherein the reinforcing base material is a composite reinforcing base material in which short fibers have been intertwiningly integrated by needle punching with at least the machine-side surface of the reinforcing base material.

13. The wet paper web transfer belt according to claim 12, wherein an inner circumferential layer comprising a machine contacting surface is constituted by some of the short fibers integrated with the machine-side surface.

14. The wet paper web transfer belt according to claim 1, wherein an inner circumferential layer comprising a machine contacting surface is constituted by some of the polyurethane.

15. A wet paper web transfer belt in which a reinforcing base material comprises: a wet paper web-side surface and a machine-side surface and a thermosetting polyurethane integrated with each other, at least the wet paper web-side surface of the reinforcing base material embedded in the polyurethane, an outer circumferential layer comprising a wet paper web contacting surface constituted by some of the polyurethane: wherein at least the outer circumferential layer comprises two different types of fillers including a high-roundness filler with a relatively high roundness and a low-roundness filler with a relatively low roundness, and a difference between the high-roundness filler and the low-roundness filler is 0.1 or more, and wherein the roundness of the high-roundness filler is 0.7 or more and the roundness of the low-roundness filler is less than 0.7.

16. A wet paper web transfer belt in which a reinforcing base material comprises: a wet paper web-side surface and a machine-side surface and a thermosetting polyurethane integrated with each other, at least the wet paper web-side surface of the reinforcing base material embedded in the polyurethane, an outer circumferential layer comprising a wet paper web contacting surface constituted by some of the polyurethane; wherein at least the outer circumferential layer comprises two different types of fillers including a high-roundness filler with a relatively high roundness and a low-roundness filler with a relatively low roundness, and a difference between the high-roundness filler and the low-roundness filler is 0.1 or more, and wherein the roundness of the high-roundness filler is 0.8 or more and the roundness of the low-roundness filler is less than 0.8.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a sectional view showing a wet paper web transfer belt according to the present invention.

(2) FIG. 2 is a sectional view showing another embodiment of a wet paper web transfer belt according to the present invention.

(3) FIG. 3 is a sectional view showing another embodiment of a wet paper web transfer belt according to the present invention.

(4) FIG. 4 is a sectional view showing another embodiment of a wet paper web transfer belt according to the present invention.

(5) FIG. 5 is a sectional view showing another embodiment of a wet paper web transfer belt according to the present invention.

(6) FIG. 6 are schematic diagrams showing a method for impregnating and layering a wet paper web transfer belt according to the present invention with polyurethane.

(7) FIG. 7 is a schematic diagram showing an example of the press part of a papermaking machine.

(8) FIG. 8 is a schematic diagram relating to a wet paper web transfer test device.

BEST MODES FOR CARRYING OUT THE INVENTION

(9) Hereinafter, the embodiments of the present invention will be explained in detail while referring to the drawings. The present invention is a wet paper web transfer belt 1 used in the press part of the papermaking machine shown in FIG. 7. The wet paper web transfer belt 1 is an endless belt supported by guide rollers 8.

(10) FIG. 1 is a sectional view in the width direction (in the Cross Machine Direction: CMD) of the wet paper web transfer belt 1 according to the present invention. The wet paper web transfer belt 1 is constituted by integrating a reinforcing base material 24 and a polyurethane 25 by impregnating with the polyurethane 25 and by layering and curing the polyurethane 25 so that the reinforcing base material 24 comprising a wet paper web-side surface 22 and a machine-side surface 23 is embedded in the thermosetting polyurethane 25, and so that an outer circumferential layer 27 comprising a wet paper web contacting surface 26 and an inner circumferential layer 28 comprising a machine contacting surface 30 are formed by some of the water-impermeable resin 25. A high-roundness filler 29 of a relatively high roundness and a low-roundness filler 29′ of a relatively low roundness are included in the polyurethane 25 constituting the outer circumferential layer 27.

(11) FIGS. 2 to 5 are sectional views in the width direction showing another embodiment of the wet paper web transfer belt 1 according to the present invention. A wet paper web transfer belt 1 shown in FIG. 2 is constituted by integrating a reinforcing base material 24 and a polyurethane 25 by impregnating with the polyurethane 25 and by layering and curing the polyurethane 25 so that the reinforcing base material 24 comprising a wet paper web-side surface 22 and a machine-side surface 23 is embedded in the polyurethane 25, and so that an outer circumferential layer 27 comprising a wet paper web contacting surface 26 and an inner circumferential layer 28 comprising a machine contacting surface 30 are formed by some of the polyurethane 25. A high-roundness filler 29 and a low-roundness filler 29′ are included in the polyurethane 25 constituting the outer circumferential layer 27 and the inner circumferential layer 28 and the polyurethane 25 impregnating the reinforcing base material 24. In this way, due to the filler contained in the inner circumferential layer 28, it is possible to improve the wear resistance of the machine contacting surface 30 while also improving the crack resistance of the polyurethane.

(12) A wet paper web transfer belt 1 shown in FIG. 3 is constituted by integrating a reinforcing base material 24 and a polyurethane 25 by impregnating with the polyurethane 25 and by layering and curing the polyurethane 25 so that the reinforcing base material 24 comprising a wet paper web-side surface 22 and a machine-side surface 23 is embedded in the polyurethane 25, and so that an outer circumferential layer 27 comprising a wet paper web contacting surface 26, an intermediate layer 31 formed between the outer circumferential layer 27 and the wet paper web contacting surface 22 of the reinforcing base material 24, and an inner circumferential layer 28 comprising a machine contacting surface 30 are formed by some of the polyurethane 25. A high-roundness filler 29 and a low-roundness filler 29′ are included in the polyurethane 25 constituting the outer circumferential layer 27. In this way, it is possible to prevent the wear of the reinforcing base material 24 due to a filler by not including a filler in the polyurethane 25 impregnating the reinforcing base material 24, the inner circumferential layer 28 and the intermediate layer 31 adjacent to the reinforcing base material 24.

(13) A wet paper web transfer belt 1 shown in FIG. 4 is constituted by integrating a composite reinforcing base material 32, in which short fibers 33 have been intertwiningly integrated by needle punching in a machine-side surface 23 of a reinforcing base material 24 comprising a wet paper web-side surface 22 and a machine-side surface 23, and a polyurethane 25 by impregnating with the polyurethane 25 and by layering and curing the polyurethane 25 so that the composite reinforcing base material 32 is embedded in the polyurethane 25, and so that an outer circumferential layer 27 comprising a wet paper web contacting surface 26 and an inner circumferential layer 28 comprising a machine contacting surface 30 are formed by some of the polyurethane 25. A high-roundness filler 29 and a low-roundness filler 29′ are included in the polyurethane 25 constituting the outer circumferential layer 27. In this way, by using the composite reinforcing base material 32, it is possible to improve the strength of the wet paper web transfer belt, adjust the impregnation speed of the polyurethane during manufacturing and also improve operability.

(14) A wet paper web transfer belt 1 shown in FIG. 5 is constituted by integrating a composite reinforcing base material 32, in which short fibers 33 have been intertwiningly integrated by needle punching in a machine-side surface 23 of a reinforcing base material 24 comprising a wet paper web-side surface 22 and a machine-side surface 23, and a polyurethane 25 by impregnating with the polyurethane 25 and by layering and curing the polyurethane 25 so that at least the wet paper web-side surface 22 of the composite reinforcing base material 32 is embedded in the polyurethane 25, and so that an outer circumferential layer 27 comprising a wet paper web contacting surface 26 is formed by some of the polyurethane 25, and the inner circumferential layer 28 comprising a machine contacting surface 30 is formed by some of the short fibers 33. A high-roundness filler 29 and a low-roundness filler 29′ are included in the polyurethane 25 constituting the outer circumferential layer 27. In this way, due to the use of short fibers in the inner circumferential layer 28, the flexibility of the wet paper web transfer belt is improved; the installation of the belt in a papermaking machine is made easy, while the wear of the guide rollers 8 is reduced.

(15) The reinforcing base material 24 is generally a fabric woven with a weaving machine, or the like, from warp and weft yarns; however, a grid-like structure made by superposing warp and weft columns can also be used.

(16) Examples of materials for the reinforcing base material 24 and the short fibers 33 include polyester (polyethylene terephthalate, polybutylene terephthalate, and the like), aliphatic polyamide (polyamide 11, polyamide 12, polyamide 612, and the like), aromatic polyamide (aramid), polyvinylidene fluoride, polypropylene, polyether ether ketone, polytetrafluoroethylene, polyethylene, wool, cotton, metal, and the like.

(17) Examples of alternative materials for the polyurethane 25 include thermosetting resins such as epoxy, acrylic, and the like, or thermoplastic resins such as polyamide, polyarylate, polyester, and the like; preferably urethane resin is used.

(18) The roundness (X) of the filler particles can be expressed by formula (1) below; wherein, A and C are respectively the particle projected area and the perimeter measured on an image taken of a filler particle by an electron microscope, B is the area of a perfect circle corresponding to the perimeter C, r is the particle radius, and π is the circular constant.
X=A/B=A/(πr.sup.2)=A/{π×(C/2π).sup.2}=A×4 π/C.sup.2  (1)

(19) Examples of materials for the high-roundness filler 29 include inorganic fillers such as silica, glass, calcium carbonate, iron, stainless steel, alumina, aluminum, zinc, tin, titanium and the like; the average particle diameter can be in the range from 1.0 μm to 300 μm. The specific surface area of the high-roundness filler 29 can be 10 m.sup.2/g or less.

(20) Examples of materials for the low-roundness filler 29′ include inorganic fillers such as silica, glass, kaolin, calcium carbonate, iron, stainless steel, alumina, aluminum, zinc, tin, titanium and the like, and carbon-based fillers such as carbon black. The specific surface area of the low-roundness filler 29′ can be 12 m.sup.2/g or more. Moreover, in view of giving the surface of the wet paper web transfer belt a degree of roughness via the shape of the low-roundness filler 29′, it is also possible to use amorphous particulate fillers, needle-like fillers, fibrous fillers and plate-like fillers.

(21) In case only one type of filler with a relatively high roundness (for example, a roundness of 1) is used as filler added to the outer circumferential layer of the wet paper web transfer belt, the surface of the wet paper web transfer belt may become too smooth because it is difficult to give the surface of the wet paper web transfer belt roughness by this filler, and the adhesive properties of the wet paper web may become excessive. Moreover, in case only one type of filler with a relatively low roundness (for example, a roundness of less than 0.6) is used as filler added to the outer circumferential layer of the wet paper web transfer belt, the surface of the wet paper web transfer belt may become too rough because this filler gives the surface of the wet paper web transfer belt too much roughness, and the adhesive properties of the wet paper web may be insufficient.

(22) In the wet paper web transfer belt according to the present invention, the amount of high-roundness filler and low-roundness filler varies according to the type of paper to be made and according to the papermaking conditions; however, in order to ensure the sheet adhesion properties, it is preferred to introduce, into the outer circumferential layer 27, between 5 wt % or more and 55 wt % or less of the high-roundness filler and between 5 wt % or more and 55 wt % or less of the low-roundness filler in relation to at least the total weight of the outer circumferential layer (the total weight of the polyurethane, the fillers and other additives). Moreover, in order to prevent contamination in parts where lipophilic contaminants (from pitch, sizing agents, and the like) are abundant, it is necessary to make the surface hydrophilic by introducing a relatively large amount of fillers; however, if the amount of fillers exceeds 60% of the total weight (the total weight of the polyurethane, the fillers and other additives), the wet paper web transfer belt becomes too hard and there is the risk of cracks occurring. Further, in parts where fine pulp fibers with high adhesiveness are used, there is the risk of malfunctioning occurring in which the fine pulp fibers adhere to the surface of the wet paper web transfer belt if too much filler is introduced. Consequently, the total amount of the high-roundness filler 29 and the low-roundness filler 29′ in each layer is preferably 10 wt % to 60 wt % of the total weight of the layer (the total weight of the polyurethane, the fillers and other additives). Other additives such as pigments and anti-foaming agents can be appropriately added according to design.

(23) Thus, by adopting the above-described constitution in the wet paper web transfer belt 1, it is possible to provide a wet paper web transfer belt in which the adhesive and releasing properties of the wet paper web with the wet paper web contacting surface of conventional wet paper web transfer belts are further improved and in which paper robbing and floating edges do not occur.

(24) Hereinafter, a specific example of a production method of a wet paper web transfer belt according to the present invention will be explained.

(25) FIG. 6 is a schematic diagram showing the layering of polyurethane of the wet paper web transfer belt 1 shown in FIG. 1. As shown in FIG. 6 (a), the reinforcing base material 24 is installed so that the machine-side surface 23 of the reinforcing base material 24 is in contact with the rolls 40, which are arranged in parallel. Then, the inner circumferential layer 28 of the wet paper web transfer belt 1 can be formed by coating polyurethane from a resin discharge opening 42 onto the wet paper web-side surface 22 of the reinforcing base material 24 while rotating the rolls 40, and by allowing the polyurethane to penetrate by a coater bar 41 from the wet paper web-side surface 22 of the reinforcing base material 24 to the machine-side surface 23 thereof and by curing the polyurethane (FIG. 6 (b)). The semi-finished product obtained in this step is installed so that the wet paper web-side surface 22 of the reinforcing base material 24 is in contact with the two rolls 40, which are arranged in parallel; then, the inner circumferential layer 28 of the wet paper web transfer belt 1 can be formed by coating polyurethane from the resin discharge opening 42 onto the machine-side surface 23 of the reinforcing base material 24 while rotating the rolls 40, and by layering the polyurethane onto the machine-side surface 23 of the reinforcing base material 24 by the coater bar 41 and by curing the polyurethane; it is also possible to perform this process by inversing the front and the back.

(26) Next, the outer circumferential layer 27 of the wet paper web transfer belt 1 can be formed by again coating polyurethane from the resin discharge opening 42 onto the wet paper web-side surface 22 of the reinforcing base material 24 while rotating the rolls 40, and by layering the polyurethane by the coater bar 41 and by curing the polyurethane (FIG. 6 (c)). Now, the wet paper web transfer belt 1 shown in FIG. 1 can be obtained by including the two types of fillers, i.e., the high-roundness filler 29 with a relatively high roundness and the low-roundness filler 29′ with a relatively low roundness, in the polyurethane constituting the outer circumferential layer 27. Further, the wet paper web contacting surface 26 and the machine contacting surface 30 of the wet paper web transfer belt 1 can be polished according to need and the desired surface roughness can be obtained.

(27) Moreover, the wet paper web transfer belts 1 shown in FIGS. 2 to 5 can be obtained by optionally setting the constitution of the intermediate layer 31, not comprising the high-roundness filler 29 and the low-roundness filler 29′, and the use of the composite reinforcing base material 32 as substitute for the reinforcing base material 24.

(28) Hereinafter, the present invention will be described by means of the Examples and Comparative Examples.

(29) The Reinforcing Base Material

(30) The reinforcing base materials of the wet paper web transfer belts according to Examples 1 to 9 and Comparative Examples 1 to 8 used the following constitution. Upper warp yarn: twisted monofilament of 2000 dtex made from polyamide 6 Lower warp yarn: twisted monofilament of 2000 dtex made from polyamide 6 Weft yarn: twisted monofilament of 1400 dtex made from polyamide 6 Weave: double warp weave of 40 upper/lower warp yarns/5 cm and 40 weft yarns/5 cm

(31) The Polyurethane

(32) The polyurethane of the wet paper web transfer belts of Examples 1 to 9 and Comparative Examples 1 to 8 was obtained by reacting a mixture of tolylenediisocyanate (TDI) and polytetramethylene glycol (PTMG), as urethane prepolymer, with dimethylthiotoluenediamine (DMTDA), as curing agent.

(33) In Examples 1 to 9, the wet paper web transfer belt shown in FIG. 1 was obtained by using the above-described reinforcing base material and polyurethane. Moreover, in Comparative Examples 1 to 8, the wet paper web transfer belt was produced by changing the filler shown in FIG. 1. The polyurethane curing conditions were identical for all wet paper web transfer belts; after curing the polyurethane, the wet paper web contacting surface was polished and the surface roughness Ra (arithmetic average surface roughness) of the wet paper web contacting surface was fixed at 1.5 μm for all belts.

(34) The conditions of the fillers included in the outer circumferential layer of the wet paper web transfer belts of Examples 1 to 9 and Comparative Examples 1 to 8 are shown in Table 1.

(35) The floating edges condition of the wet paper web after passing the nip and the occurrence of paper robbing due to the felt 6 or due to the wet paper web transfer belt after the wet paper web W had passed the press nip 12 under the conditions listed hereinafter and by using the device shown in FIG. 8 was evaluated regarding the wet paper web transfer belts of Examples 1 to 9 and Comparative Examples 1 to 8. The evaluation device shown in FIG. 8 has the constitution of the press part 3 shown in FIG. 7, in which the constitution upstream of the press felt 6 has been omitted. The press conditions, the constitution of the press felt 6 and the constitution of the wet paper web were as listed hereinafter.

(36) The Pressing Conditions Papermaking speed: 1600 m/min Pressing pressure: 1050 kN/m

(37) The Constitution of the Press Felt 6

(38) Base Fabric Upper warp yarn: twisted monofilament of 2000 dtex made from polyamide 6 Lower warp yarn: twisted monofilament of 2000 dtex made from polyamide 6 Weft yarn: twisted monofilament of 1400 dtex made from polyamide 6 Weave: double warp weave of 40 upper/lower warp yarns/5 cm and 40 weft yarns/5 cm

(39) The Batt Fibers needle-punched to the Base Fabric Front layer batt fibers: 300 g/m.sup.2 batt fibers of 6 dtex made from polyamide 6 Rear layer batt fibers: 100 g/m.sup.2 batt fibers of 6 dtex made from polyamide 6

(40) The Wet Paper Web (Handsheet) Pulp: LBKP 100% csf 550 mL Basis weight: 40 g/m.sup.2 Wet paper web moisture before pressing: wet paper web moisture weight before pressing/(wet paper web moisture weight before pressing+wet paper web bone dry weight)=adjusted to 60% (moisture control through a filter paper, wet paper web moisture after pressing about 50%) Wet paper size: 700 mm length by 700 mm width

(41) Further, the paper robbing due to the felt 6 or the wet paper web transfer belt after passing the nip was evaluated with the help of a video camera. The evaluation results are shown in Table 2.

(42) TABLE-US-00001 TABLE 1 High-roundness filler Low-roundness filler Average Added Average Added Material Roundness diameter amount Material Roundness diameter amount Example 1 Silica 0.75 5 5 Silica 0.55 5 55 Example 2 Silica 0.75 5 15 Silica 0.55 5 15 Example 3 Silica 0.75 5 55 Silica 0.55 5 5 Example 4 Silica 0.75 1 15 Silica 0.55 5 15 Example 5 Silica 0.75 100 15 Silica 0.55 5 15 Example 6 Silica 0.75 5 15 Silica 0.55 1 15 Example 7 Silica 0.75 5 15 Silica 0.55 100 15 Example 8 Silica 0.75 5 15 Kaolin 0.55 5 15 Example 9 Silica 0.85 5 15 Silica 0.55 5 15 Comparative Silica 0.75 5 10 — — — — Example 1 Comparative Silica 0.75 5 30 — — — — Example 2 Comparative Silica 0.75 5 55 — — — — Example 3 Comparative Silica 0.75 100 15 — — — — Example 4 Comparative — — — — Silica 0.55 5 10 Example 5 Comparative — — — — Silica 0.55 5 30 Example 6 Comparative — — — — Silica 0.55 5 55 Example 7 Comparative — — — — Silica 0.55 100 15 Example 8

(43) TABLE-US-00002 TABLE 2 Wet paper web Evaluated items transfer belt Paper robbing Floating edges paper robbing Observed Observed Observed Example 1 No No No Example 2 No No No Example 3 No No No Example 4 No No No Example 5 No No No Example 6 No No No Example 7 No No No Example 8 No No No Example 9 No No No Comparative No No Sometimes Example 1 Comparative No No Yes Example 2 Comparative No No Yes Example 3 Comparative No No Yes Example 4 Comparative No Sometimes No Example 5 Comparative No Sometimes No Example 6 Comparative No — No Example 7 Comparative No Sometimes No Example 8

(44) As shown in Table 2, the adhesive and releasing properties of the wet paper web on the wet paper web contacting surface was further improved in the wet paper web transfer belts of Examples 1 to 9, in which paper robbing and floating edges did not occur.

(45) Explanation of the Reference Characters

(46) W: wet paper web, 1: wet paper web transfer belt, 2: closed-draw papermaking machine, 3: press part, 4: dryer part, 5, 6: press felt, 7: dryer fabric, 8: guide rolls, 9: shoe, 10: press roll, 11: shoe press belt, 12: press section, 13: shoe press mechanism, 14: suction roll, 22: wet paper web-side surface, 23: machine-side surface, 24: reinforcing base material, 25: polyurethane, 26: wet paper web contacting surface, 27: outer circumferential layer, 28: inner circumferential layer, 29: high-roundness filler, 29′: low-roundness filler, 30: machine contacting surface, 31: intermediate layer, 32: composite reinforcing base material, 33: short fibers, 40: rolls, 41: coater bar, 42: resin discharge opening