Composition comprising (2,5-diaminophenyl)ethanol and a cellulose polymer or carboxylic anionic polymer in a medium rich in fatty substances, dyeing process and device

Abstract

The present invention relates to a composition for dyeing keratin fibers, comprising a) one or more fatty substances, which are preferably liquid and non-silicone, b) one or more cellulose polymers and/or one or more carboxylic anionic, c) (2,5-diaminophenyl)ethanol, d) optionally, one or more couplers, e) optionally, one or more basifying agents, and f) one or more chemical oxidizing agents such as hydrogen peroxide, and the content of fatty substances in the composition representing in total at least 10%, in particular at least 15%, more particularly at least 20% and preferably at least 25% by weight relative to the total weight of the composition resulting from the mixing of (A′)+(B′)+(C′). The present invention also relates to a process using this composition and to a multi-compartment device suitable for the use of said process.

Claims

1. A cosmetic composition comprising: a) at least one fatty substance; b) at least one polymer chosen from cellulose polymers and carboxylic anionic polymers; c) at least one oxidation base chosen from (2,5-diaminophenyl)ethanol, and the acid salts, solvates, and hydrates thereof; d) optionally at least one coupler; e) optionally at least one basifying agent; and f) at least one chemical oxidizing agent; wherein the cosmetic composition comprises a total fatty substance content of at least about 10% by weight, relative to the total weight of the cosmetic composition; wherein said cosmetic composition is prepared by mixing a composition (A) and a composition (B), wherein composition (A) comprises: c) the at least one oxidation base; d) optionally, the at least one coupler; and e) optionally, the at least one basifying agent; and wherein composition (B) comprises: f) the at least one chemical oxidizing agent; and wherein compositions (A) and (B) are mixed in a weight ratio of (A)/(B) ranging from 0.2 to 10.

2. A cosmetic composition according to claim 1, wherein the at least one fatty substance is chosen from C.sub.6-C.sub.16 hydrocarbons, hydrocarbons comprising more than 16 carbon atoms, non-silicone oils of animal origin, vegetable oils of triglyceride type, synthetic triglycerides, fluoro oils, fatty alcohols, esters of fatty acids and/or of fatty alcohols other than triglycerides, plant waxes, non-silicone waxes, silicones, and mixtures thereof.

3. A cosmetic composition according to claim 1, wherein the at least one fatty substance is liquid at ambient temperature and at atmospheric pressure.

4. A cosmetic composition according to claim 1, wherein the at least one fatty substance is chosen from liquid petroleum jelly, polydecenes, liquid fatty alcohols, liquid esters of fatty acids and/or of fatty alcohols, and mixtures thereof.

5. A cosmetic composition according to claim 1, wherein the cosmetic composition comprises a total fatty substance content ranging from about 10% to about 80% by weight, relative to the total weight of the cosmetic composition.

6. A cosmetic composition according to claim 1, wherein the at least one polymer is chosen from associative polymers.

7. A cosmetic composition according to claim 1, wherein the at least one polymer is chosen from non-associative polymers.

8. A cosmetic composition according to claim 1, wherein the at least one polymer is chosen from cellulose ethers and hydroxyalkylcelluloses.

9. A cosmetic composition according to claim 1, wherein the at least one polymer is chosen from non-ionic, cationic, and anionic cellulose polymers.

10. A cosmetic composition according to claim 1, wherein the at least one polymer is chosen from anionic polymers comprising at least one optionally salified, unsaturated carboxylic acid monomer.

11. A cosmetic composition according to claim 1, wherein the carboxylic anionic polymers comprise at least one monomer chosen from acrylic acid and methacrylic acid monomers, which are optionally salified.

12. A cosmetic composition according to claim 1, wherein the carboxylic anionic polymers are associative and are chosen from the following polymers and salts thereof: (A) polymers comprising at least one hydrophilic unit, and at least one fatty-chain allyl ether unit, wherein the hydrophilic unit comprises a vinylcarboxylic acid, and wherein the fatty-chain allyl ether unit is chosen from monomers of formula (A1) below:
H.sub.2C═C(R′)—CH.sub.2—O-(B).sub.n-R  (A1) wherein: R′ is chosen from H and (C.sub.1-C.sub.6)alkyl groups; B is chosen from divalent radicals -(alk-O)—, wherein alk is chosen from linear or branched (C.sub.1-C.sub.6)alkylene groups; n is zero or an integer ranging from 1 to 100; R is a hydrocarbon-based radical chosen from alkyl, arylalkyl, aryl, alkylaryl, cycloalkyl, cycloalkylalkyl, and alkylcycloalkyl radicals comprising from 8 to 30 carbon atoms; (B) maleic anhydride/C.sub.30-C.sub.38 α-olefin/alkyl maleate terpolymers; (C) acrylic terpolymers comprising: (i) from about 20% to about 70% by weight of an α,β-monoethylenically unsaturated carboxylic acid, (ii) from about 20% to about 80% by weight of a non-surfactant α,β-monoethylenically unsaturated monomer other than (i), and (iii) from about 0.5% to about 60% by weight of a non-ionic monourethane which is the product of reaction of a monohydric surfactant with a monoethylenically unsaturated monoisocyanate; (D) copolymers comprising at least one monomer chosen from α,β-monoethylenically unsaturated carboxylic acids and esters of α,β-monoethylenically unsaturated carboxylic acids and of oxyalkylenated fatty alcohols; and (E) copolymers comprising at least one hydrophilic unit of unsaturated olefinic carboxylic acid type and at least one hydrophobic unit of C.sub.10-C.sub.30 alkyl ester of unsaturated carboxylic acid type.

13. A cosmetic composition according to claim 1, wherein the carboxylic anionic polymers are non-associative and are chosen from homopolymers and copolymers of acrylic or methacrylic acid which are optionally crosslinked, and salts thereof.

14. A cosmetic composition according to claim 1, wherein the at least one polymer is present in the cosmetic composition in an amount ranging from about 0.05% to about 10% by weight, relative to the total weight of the cosmetic composition.

15. A cosmetic composition according to claim 1, wherein the at least one chemical oxidizing agent is hydrogen peroxide.

16. A cosmetic composition according to claim 1, further comprising at least one surfactant chosen from non-ionic surfactants, anionic surfactants, zwitterionic surfactants, and combinations thereof.

17. A cosmetic composition according to claim 16, wherein the at least one surfactant is present in the cosmetic composition in an amount ranging from about 0.1% to about 50% by weight, relative to the total weight of the cosmetic composition.

18. A cosmetic composition according to claim 1, wherein the at least one oxidation base is present in the cosmetic composition in an amount ranging from about 0.0001% to about 20% by weight, relative to the total weight of the cosmetic composition.

19. A cosmetic composition according to claim 1, wherein the at least one coupler is chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers, heterocyclic couplers, and the addition salts thereof.

20. A cosmetic composition according to claim 1, wherein the at least one basifying agent is chosen from aqueous ammonia, alkali metal carbonates and bicarbonates, sodium hydroxide, potassium hydroxide, organic amines, amino acids in neutral or ionic form, compounds of formula (A11) below, and mixtures thereof: ##STR00018## wherein: W is chosen from divalent C.sub.1-C.sub.6 alkylene radicals optionally substituted with at least one hydroxyl group or C.sub.1-C.sub.6 alkyl radical, and/or optionally interrupted with at least one heteroatom, and NR.sub.u; and R.sub.x, R.sub.y, R.sub.z, R.sub.t and R.sub.u, which may be identical or different, are chosen from hydrogen and C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 hydroxyalkyl, and C.sub.1-C.sub.6 aminoalkyl radicals.

21. A process for dyeing keratin fibers comprising applying to the keratin fibers a cosmetic composition comprising: a) at least one fatty substance; b) at least one polymer chosen from cellulose polymers and carboxylic anionic polymers; c) at least one oxidation base chosen from (2,5-diaminophenyl)ethanol, and the acid salts, solvates, and hydrates thereof; d) optionally at least one coupler; e) optionally at least one basifying agent; and f) at least one chemical oxidizing agent; wherein said cosmetic composition is prepared by mixing a composition (A) and a composition (B), wherein composition (A) comprises: c) the at least one oxidation base; d) optionally, the at least one coupler; and e) optionally, the at least one basifying agent; and wherein composition (B) comprises: f) the at least one chemical oxidizing agent; wherein compositions (A) and (B) are mixed in a weight ratio of (A)/(B) ranging from 0.2 to 1; and wherein the cosmetic composition comprises a total fatty substance content of at least about 10% by weight, relative to the total weight of the cosmetic composition.

22. A process according to claim 21, wherein composition (A) comprises: at least one oxidation base c); at least one coupler d); optionally at least one basifying agent e); and wherein at least one of the compositions (A) and (B) comprises: at least one fatty substance a), and at least one polymer b).

23. A process according to claim 21, wherein the cosmetic composition results from the mixing of three compositions, wherein the three compositions are aqueous or wherein at least one of the three compositions is anhydrous.

24. A process according to claim 23, wherein of the cosmetic composition results from the mixing of two aqueous compositions A and B and an anhydrous composition (A′), wherein: composition (A′) comprises at least one fatty substance a), composition A comprises at least one oxidation base c) and at least one coupler d); composition B comprises at least one chemical oxidizing agent f); compositions (A′) and/or A optionally comprise at least one basifying agent e); at least one of compositions (A′), A, or B comprise at least one polymer b); and wherein the total fatty substance content of the cosmetic composition resulting from the mixing of the three compositions (A′)+A+B is at least about 10% by weight, relative to the total weight of the cosmetic composition.

25. A multi-compartment device comprising: either i) a first compartment containing composition (A) comprising: at least one oxidation base chosen from (2,5-diaminophenyl)ethanol, and the acid salts, solvates, and hydrates thereof c); at least one coupler d); optionally at least one basifying agent e); and ii) at least a second compartment containing composition (B) comprising: at least one chemical oxidizing agent f); wherein at least one of the compositions (A) and (B) comprises: at least one fatty substance a), and at least one polymer b); and, wherein a cosmetic composition resulting from mixing compositions (A)+(B) comprises a total fatty substance content of at least about 10% by weight, relative to the total weight of the cosmetic composition resulting from the mixing of (A)+(B); or i) a first compartment containing an anhydrous composition (A′) comprising at least one fatty substance a); ii) a second compartment containing a cosmetic composition A comprising at least one oxidation base c) and at least one coupler d); and iii) at least a third compartment containing composition B comprising at least one chemical oxidizing agent f); wherein a cosmetic composition resulting from the mixing of (A′)+A+B comprises a total fatty substance content of at least about 10% by weight, relative to the total weight of the cosmetic composition resulting from the mixing of (A′)+A+B.

Description

EXAMPLES

Example 1

(1) TABLE-US-00001 Ingredients A1 A2 Liquid petroleum jelly (fatty substance a) 60 59.7 Safflower oil (triglycerides of palmitic-oleic- — 0.1 linoleic acids 6/12/78) (fatty substance a) Tamanu kernel oil (fatty substance a) — 0.1 Argan oil (fatty substance a) — 0.1 Hydroxyethylcellulose (MW: 1.300.000) 2.5 — (polymer b) Cationic hydroxyethylcellulose (Softcat SL 0.2 100 from Amerchol) (polymer b) 6-hydroxybenzomorpholine 0.033 0.033 1--Hydroxyethyloxy-2,4-diaminobenzene 0.02 0.02 dihydrochloride (coupler d) 1,3-Dihydroxybenzene (resorcinol) (coupler d) 0.67 0.67 1-Hydroxy-3-aminobenzene (coupler d) 0.12 0.12 2-(2,5-Diaminophenyl)ethanol sulfate 1.58 1.58 (oxidation base c) Pure monoethanolamine (basifying agent e) 5.16 4.39 Cocoylbetaine at 30% as an aqueous solution 10 — Oxyethylenated (2 OE) stearyl alcohol 0.1 1.13 Oxyethylenated (20 OE) stearyl alcohol 0.1 3.88 Oxyethylenated (40 OE) hydrogenated castor oil 1 — Sodium lauryl ether sulfate (2.2 OE) at 70% as 2.5 an aqueous solution (50/50 C.sub.8/C.sub.10) Alkyl polyglucoside as an aqueous — 4 60% solution Oxyethylenated (4 OE) sorbitan monolaurate — 2.4 Sequestrant 2.2 Reducing agent 0.5 0.45 Fragrance — 0.72 Deionized water q.s. for 100 q.s. for 100

(2) The following compositions are prepared in which the amounts are expressed in grams of materials in their given state.

(3) TABLE-US-00002 Ingredients A3 Liquid petroleum jelly (fatty substance a) 60 Oxyethylenated (40 OE) hydrogenated castor oil 1 6-hydroxybenzomorpholine 0.033 1-β-Hydroxyethyloxy-2,4-diaminobenzene 0.02 dihydrochloride 1,3-Dihydroxybenzene (resorcinol) 0.67 1-Hydroxy-3-aminobenzene 0.12 2-(2,5-Diaminophenyl)ethanol sulfate 1.58 (oxidation base c) Diethylenetriaminepentaacetic acid, pentasodium salt as an 2 aqueous 40% solution Hydroxyethylcellulose (MW: 1.300.000) 2.5 Powdered sodium metabisulfite 0.5 Cocoylbetaine at 30% as an aqueous solution 10 Oxyethylenated (2 OE) stearyl alcohol 0.1 Oxyethylenated (20 OE) stearyl alcohol 0.1 Sodium lauryl ether sulfate (2.2 OE) at 70% as an aqueous 2.5 solution Antioxidant 0.5 Deionized water q.s. for 100
Oxidizing Compositions B1, B2 and B3:

(4) TABLE-US-00003 Ingredients B1 B2 Liquid petroleum jelly (fatty substance a) — 20 Hydrogen peroxide as an aqueous 50% solution (200 vol. 15 12 aqueous hydrogen peroxide solution) (oxidizing agent f) Poly[(dimethyliminio)-1,3-propanediyl(dimethyliminio)-1,6- 0.25 hexanediyl dichloride] as an aqueous 60% solution Polydimethyldiallylammonium chloride at 40% in water 0.5 Dimethyldiallylammonium chloride/acrylic acid copolymer 0.74 (80/20) at 40.5 as an aqueous solution Glycerol 4 0.5 Cetylstearyl alcohol (30/70 C.sub.16/C.sub.18) 6 Oxyethylenated (20 OE) stearyl alcohol 5 (50/50 C.sub.8/C.sub.10) alkyl polyglucoside (2) as an aqueous 60% 3 solution Tetrasodium pyrophosphate decahydrate 0.04 0.03 Sodium salicylate 0.035 Protected oxyethylenated (4 OE) rapeseed acid amide 1.3 Vitamin E DL-Alpha-Tocopherol 0.1 Disodium tin hexahydroxide 0.04 Sequestrant 0.06 0.15 Deionized water q.s. for 100 q.s. for 100

(5) TABLE-US-00004 Ingredients B3 Hydrogen peroxide as a 50% solution (200 vol. aqueous 6 hydrogen peroxide solution) (oxidizing agent f) Etidronic acid, tetrasodium salt, as an aqueous 30% 0.2 solution Tetrasodium pyrophosphate decahydrate 0.04 Sodium salicylate 0.035 Dimethyldiallylammonium chloride/acrylic acid copolymer 0.74 (80/20) at 40.5 as an aqueous solution (50/50 C.sub.8/C.sub.10)Alkyl polyglucoside (2) as an aqueous 60% 3 solution Glycerol 4 Deionized water q.s. for 100

(6) The dyeing compositions A1, A2 or A3 are mixed, respectively, with the oxidizing formulations B1, B2 or B3 respectively according to the ratio of 1 part of dyeing composition for 1 part of oxidizing composition.

(7) The mixtures A1+B1, A2+B1 and A3+B3 obtained are then applied to hair comprising 90% white hairs. The “mixture/lock” bath ratio is 10/1 (g/g). The leave-on time is 35 minutes at 27° C.

(8) After the leave-on time, the hair is rinsed with clear water and a shampoo is applied.

(9) After drying, a light chestnut-brown shade of good strength and coverage is obtained on the hair.

Example 2

(10) The following compositions are prepared in which the amounts are expressed in grams of materials in their given state.

(11) 2.1 Dyeing Compositions

(12) a. Dyeing Composition A4:

(13) TABLE-US-00005 Composition A4 Liquid petroleum jelly (fatty substance a) 60 Cetyl palmitate (fatty substance a) 2 2-(2,5-Diaminophenyl)ethanol sulfate (oxidation base c) 1.58 6-Hydroxybenzomorpholine (coupler d) 0.033 1-β-Hydroxyethyloxy-2,4-diaminobenzene dihydrochloride 0.02 (coupler d) 1,3-Dihydroxybenzene (resorcinol) (coupler d) 0.67 1-Hydroxy-3-aminobenzene (coupler d) 0.12 Monoethanolamine 4.28 Mixture of linear C.sub.18 to C.sub.24 alcohols (C.sub.18/C.sub.20/C.sub.22/ 4.6 C.sub.24/(7/58/30/6)) Carboxyvinyl polymer (Carbopol 980 from Lubrizol) 0.1 Glycerol 5 Oxyethylenated (10 OE) oleyl alcohol 1 Oxyethylenated (20 OE) oleyl alcohol 4 Oxyethylenated (5 OE) decyl alcohol 1.2 Oxyethylenated (60 OE) cetylstearyl (C.sub.16/C.sub.18) alcohol ether 0.01 of myristyl glycol Sequestrant 0.2 Reducing agent 0.22 Antioxidant 0.12 Deionized water q.s. for 100

(14) b. Dyeing Composition A5:

(15) TABLE-US-00006 Composition A5 Liquid petroleum jelly (fatty substance a) 50 Cetylstearyl alcohol (50/50 C.sub.16/C.sub.18) (fatty substance a) 2 2-(2,5-Diaminophenyl)ethanol sulfate (oxidation base c) 1.58 6-Hydroxybenzomorpholine (coupler d) 0.033 1-β-Hydroxyethyloxy-2,4-diaminobenzene dihydrochloride 0.02 (coupler d) 1,3-Dihydroxybenzene (resorcinol) (coupler d) 0.67 1-Hydroxy-3-aminobenzene (coupler d) 0.12 Disodium ethylenediaminetetraacetate dihydrate 0.2 Monoethanolamine 5.4 Carboxyvinyl polymer (Carbopol 980 from Lubrizol) 0.4 Sodium cetostearyl sulfate (50/50 C.sub.16/C.sub.18) 2 Oxyethylenated (20 OE) stearyl alcohol 2 Oxyethylenated (4 OE) sorbitan monolaurate 5 Antioxidant 0.3 Deionized water q.s. for 100

(16) 2.2 Oxidizing Composition B4:

(17) TABLE-US-00007 Composition B4 Hydrogen peroxide as an aqueous 50% solution 12 (200 vol. aqueous hydrogen peroxide solution) (chemical oxidizing agent f) Disodium tin hexahydroxide 0.04 Tetrasodium pyrophosphate decahydrate 0.03 Liquid petroleum jelly 20 Poly[(dimethyliminio)-1,3-propanediyl(dimethyliminio)-1,6- 0.25 hexanediyl dichloride] as an aqueous 60% solution Polydimethyldiallylammonium chloride at 40% in water, 0.5 non-stabilized Glycerol 0.5 Cetylstearyl alcohol (30/70 C.sub.16/C.sub.18) 6 Oxyethylenated (20 OE) stearyl alcohol 5 Protected oxyethylenated (4OE) rapeseed acid amide 1.3 Vitamin E: DL-α-Tocopherol 0.1 Sequestrant 0.15 Deionized water q.s. for 100

(18) 2.3 Procedure

(19) The dyeing compositions A4, A5 are mixed separately with the oxidizing composition B4, in proportions of one part of dyeing composition for one part of oxidizing composition.

(20) The mixtures A4+B4, A5+B4 are then applied to locks of hair comprising 90% white hairs, in a proportion of 10 grams of mixture for one gram of lock.

(21) After a leave-on time of 35 minutes at 27° C., the hair is rinsed with clear water and then a conditioning shampoo is applied to the hair.

(22) After drying, a light chestnut-brown shade of good strength and coverage is obtained on the hair.