METHOD FOR PRODUCING FUEL CELL MEMBRANE ELECTRODE ASSEMBLY

Abstract

A method for producing a fuel cell membrane electrode assembly includes: a step of bonding a polymer electrolyte membrane and a first catalyst layer-including substrate; a step of making a cut by way of a laser beam so that the first catalyst layer-including substrate bonded with the polymer electrolyte membrane becomes a predetermined shape; a step of peeling an unwanted portion of the first catalyst layer-including substrate from the polymer electrolyte membrane; and a step of forming a second catalyst layer on the other face of the polymer electrolyte membrane, and punching out the polymer electrolyte membrane and second catalyst layer so that the first catalyst layer-including substrate of the predetermined shape bonded on one face is surrounded, in which the laser beam has a wavelength that penetrates the polymer electrolyte membrane without penetrating the first catalyst layer-including substrate.

Claims

1. A method for producing a fuel cell membrane electrode assembly comprising the steps of: preparing an electrolyte membrane; preparing a catalyst layer-including substrate in which a first catalyst layer is formed on one face of a sheet-like substrate; laminating the catalyst layer-including substrate so that the first catalyst layer opposes one face of the electrolyte membrane; bonding the electrolyte membrane and the catalyst layer-including substrate; making a cut by way of energy rays so that the catalyst layer-including substrate bonded with the electrolyte membrane becomes a predetermined shape; peeling an unwanted portion of the catalyst layer-including substrate other than a portion of the predetermined shape from the electrolyte membrane; forming a second catalyst layer on one other face of the electrolyte membrane, and punching out the electrolyte membrane and the second catalyst layer so that the catalyst layer-including substrate of the predetermined shape bonded to the one face is surrounded, wherein the energy rays penetrate the electrolyte membrane without penetrating the catalyst layer-including substrate.

2. A method for producing a fuel cell membrane electrode assembly comprising the steps of: preparing an electrolyte membrane; preparing a catalyst layer-including substrate in which a first catalyst layer is formed on one face of a sheet-like substrate; laminating the catalyst layer-including substrate so that the first catalyst layer opposes one face of the electrolyte membrane; bonding the electrolyte membrane and the catalyst layer-including substrate; removing, so that the catalyst layer-including substrate bonded with the electrolyte membrane becomes a predetermined shape, an unwanted portion other than a portion of the predetermined shape by way of energy rays; forming a second catalyst layer on one other face of the electrolyte membrane, and punching out the electrolyte membrane and the second catalyst layer so that the catalyst layer-including substrate of the predetermined shape bonded to the one face is surrounded, wherein the energy rays penetrate the electrolyte membrane without penetrating the catalyst layer-including substrate.

3. The method for producing a fuel cell membrane electrode assembly according to claim 1, wherein the energy rays have a transmittance relative to the electrolyte membrane of at least 80%.

4. The method for producing a fuel cell membrane electrode assembly according to claim 2, wherein the energy rays have a transmittance relative to the electrolyte membrane of at least 80%.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0021] FIG. 1 is a schematic view showing a production line 1 for a fuel cell membrane electrode assembly MEA according to a first embodiment of the present invention;

[0022] FIG. 2 is a graph showing the relationship between wavelength and transmittance of a laser beam LB of a laser device 14;

[0023] FIG. 3 is a cross-sectional view of a fuel cell membrane electrode assembly MEA produced; and

[0024] FIG. 4 is a schematic view showing a production line 2 for a fuel cell membrane electrode assembly MEA according to a second embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0025] Embodiments of the present invention will be explained in detail while referencing the drawings. It should be noted that, in the explanation of a second embodiment, the same reference symbols will be assigned for configurations, functions and effects shared with the first embodiment, and explanations thereof will be omitted as appropriate.

First Embodiment

[0026] FIG. 1 is a schematic view showing a production line 1 of a membrane electrode assembly MEA for a fuel cell according to the embodiment of the present invention. FIG. 2 is a graph showing a relationship between wavelength and transmittance of a laser beam LB of a second laser device 14. FIG. 3 is a cross-sectional view of a fuel cell membrane electrode assembly MEA produced.

[0027] The production line 1 of the fuel cell membrane electrode assembly (Membrane Electrode Assembly) MEA shown in FIG. 1 raises the production efficiency of the fuel cell membrane electrode assembly MEA by making continuous with a roll-to-roll method. More specifically, the production line 1 of the fuel cell membrane electrode assembly MEA includes: an electrolyte membrane roll 10; a first substrate roll 11; a pair of upper/lower temporary bonding rolls 12, 13; a laser device 14; a recovery roll 15; a second substrate roll 17; a pair of upper/lower bonding rolls 18, 19; a cutter 20; etc.

[0028] The electrolyte membrane roll 10 is a roll that prepares a continuous sheet-like (belt-like) polymer electrolyte membrane PEM, and rotates around a horizontal shaft at the upstream of the production line 1. This electrolyte membrane roll 10 draws the polymer electrolyte membrane PEM to downstream by rotating. The polymer electrolyte membrane PEM that is drawn to travel downstream from the electrolyte membrane roll 10 is laminated so that a first catalyst layer 111 (refer to FIG. 3), in which a lower face that is one face of the first catalyst layer-including substrate GDE1 that is drawn to travel downstream from the first substrate roll 11 is formed on the lower face of the first catalyst layer including substrate GDE1, opposes a top face which is one face of the polymer electrolyte membrane PEM.

[0029] The first substrate roll 11 is a roll that prepares a continuous sheet-like (belt-like) first catalyst layer-including substrate (Gas Diffusion Electrode) GDE1, and rotates around a horizontal shaft at the upstream of the production line 1. This first substrate roll 11 draws the first catalyst layer-including substrate GDE1 from above the electrolyte membrane roll 10 to downstream by rotating. In the first catalyst layer-including substrate GDE1 that is drawn to travel downstream from the first substrate roll 11, the first catalyst layer 11 (refer to FIG. 3) is formed on the lower face, which is one side thereof. In addition, regarding the first catalyst layer-including substrate GDE1 that is drawn out to travel downstream from the first substrate roll 11, the first catalyst layer 111 which is at the bottom face that is one face thereof is laminated so as to oppose the top face which is one face of the polymer electrolyte membrane PEM that is drawn out to travel downstream from the electrolyte membrane roll 10.

[0030] The pair of upper/lower temporary bonding rolls 12, 13 is provided so that each is rotatable around a horizontal shaft, and the circumferences substantially contact each other at the downstream of the electrolyte membrane roll 10 and first substrate roll 11. This pair of upper/lower temporary bonding rolls 12, 13 is configured to be heatable and, by causing the polymer electrolyte membrane PEM and the first catalyst layer-including substrate GDE1 laminated vertically to pass therethrough, applies a vertical external force and heat to this polymer electrolyte membrane PEM and first catalyst layer-including substrate GDE1 while rotating, and bonds this polymer electrolyte membrane PEM and first catalyst layer-including substrate GDE1.

[0031] The laser device 14 is provided downstream of the pair of upper/lower temporary bonding rolls 12, 13, so as to be movable in a horizontal direction above the first catalyst layer-including substrate GDE1 bonding to the top face of the polymer electrolyte membrane PEM by passing through this pair of upper/lower temporary bonding rolls 12, 13, and irradiates a laser beam LB towards the first catalyst layer-including substrate GDE1. This laser device 14, by irradiating the laser beam LB towards the first catalyst layer-including substrate GDE1 while moving in the horizontal direction, makes cuts CL so that the first catalyst layer-including substrate GDE1 bonding with the polymer electrolyte membrane PEM becomes a predetermined shape (for example, rectangle).

[0032] The laser beam LB of the laser device 14 is a wavelength that penetrates the polymer electrolyte membrane PEM without penetrating the first catalyst layer-including substrate GDE1. The laser beam LB of this laser device 14 preferably has transmittance relative to the polymer electrolyte membrane PEM of at least 80%, and more preferably at least 90%. In other words, as shown in FIG. 2, the wavelength of the laser beam LB of the laser device 14 is preferably at least 400 nm, and more preferably at least 600 nm. More specifically, it is possible to use a YAG laser (wavelength 1064 nm).

[0033] In addition, as is evident from FIG. 2, the laser beam LB of the laser device 14 has transmittance relative to carbon-based material of about 0% irrespective of the wavelength. As described later, since the catalyst layer-including substrate is configured by carbon-based material, the laser beam LB of the laser device 14 will be absorbed without penetrating the first catalyst layer-including substrate GDE1. Cutting or removal relative to the first catalyst layer-including substrate GDE1 thereby becomes possible by the laser beam LB of the laser device 14.

[0034] The recovery roll 15 is a roll that recovers an unwanted portion GDE12 of the first catalyst layer-including substrate GDE1, and rotates around a horizontal shaft above the first catalyst layer-including substrate GDE1 downstream of the laser device 14. This recovery roll 15 peels, from the polymer electrolyte membrane PEM, the unwanted portion GDE12 other than the portion GDE 11 of a predetermined shape (for example, rectangle) of the first catalyst layer-including substrate GDE1 in which the cuts CL were made by the laser beam LB of the laser device 14, to recover this unwanted portion GDE 12 while winding up by rotating.

[0035] For the polymer electrolyte membrane PEM from which the unwanted portion GDE12 of the first catalyst layer-including substrate GDE1 was peeled off by the recovery roll 15, opposing a lower face which is one face thereof, is a second catalyst layer 121 (refer to FIG. 3), in which a top face that is one face of the second catalyst layer-including substrate GDE2 that is drawn to travel downstream from the second substrate roll 17 is formed on the top face of the second catalyst layer including substrate GDE2.

[0036] The second substrate roll 17 is a roll that prepares the continuous sheet-like (belt-like) second catalyst layer-including substrate (Gas Diffusion Electrode) GDE2, and rotates around a horizontal shaft below the polymer electrolyte membrane PEM downstream of the laser device 14. By rotating, this second substrate roll 17 draws out to downstream the second catalyst layer-including substrate GDE2 from below the polymer electrolyte membrane PEM, which is traveling. In the second catalyst layer-including substrate GDE2 that is drawn out to travel downstream from the second substrate roll 17, the second catalyst layer 121 (refer to FIG. 3) is formed on the top face which is one side thereof. In addition, regarding the second catalyst layer-including substrate GDE2 that is drawn out to travel downstream from the second substrate roll 17, the second catalyst layer 121 which is at the top face that is one face thereof is laminated so as to oppose the bottom face which is the other face of the polymer electrolyte membrane PEM from which the unwanted portion GDE12 the first catalyst layer-including substrate GDE1 was peeled.

[0037] The pair of upper/lower bonding rolls 18, 19 is provided so that each is rotatable around horizontal shafts, and so that the circumferences substantially contact each other at the downstream of the second substrate roll 17. This pair of upper/lower bonding rolls 18, 19 is configured to be heatable and, by causing the portion GDE 11 of a predetermined shape of the first catalyst layer-including substrate GDE1, polymer electrolyte membrane PEM and second catalyst layer-including substrate GDE2 laminated vertically to pass therethrough from upstream to downstream, applies a vertical external force and heat to this portion GDE 11 of a predetermined shape of the first catalyst layer-including substrate GDE1, polymer electrolyte membrane PEM and second catalyst layer-including substrate GDE2 while rotating, and bonds this portion GDE 11 of a predetermined shape of the first catalyst layer-including substrate GDE1, polymer electrolyte membrane PEM and second catalyst layer-including substrate GDE2. In other words, the pair of upper/lower bonding rolls 18, 19 forms the second catalyst layer 121 on the lower face which is the other face of the polymer electrolyte membrane PEM.

[0038] The cutter 20 is provided downstream of the pair of upper/lower bonding rolls 18, 19 so as to be vertically moveable, above the portion GDE 11 of a predetermined shape of the first catalyst layer-including substrate GDE1, polymer electrolyte membrane PEM and second catalyst layer-including substrate GDE2, which are bonded together by passing through this pair of upper/lower bonding rolls 18, 19. This cutter 20 performs trimming such as cutting on the polymer electrolyte membrane PEM and second catalyst layer-containing substrate GDE2 by moving downwards. In other words, the cutter 20 punches out the polymer electrolyte membrane PEM and second catalyst layer-including substrate GDE2 on which the second catalyst layer 121 is formed, so that the first catalyst layer-including substrate GDE11 of a predetermined shape bonding to the top face which is one face of the polymer electrolyte membrane PEM is surrounded. A plurality of fuel cell membrane electrolyte assemblies MEAs is thereby completed.

[0039] Next, a method for producing a fuel cell membrane electrode assembly MEA of the present embodiment executed by the production line 1 will be explained while referencing FIG. 1.

[0040] The method for producing a fuel cell membrane electrode assembly MEA on the production line 1 includes a Step 1, Step 2, Step 3, Step 4, Step 5, Step 6, Step 7, etc.

[0041] In Step 1, the polymer electrolyte membrane PEM is prepared. More specifically, the polymer electrolyte membrane PEM is drawn out to downstream from the electrolyte membrane roll 10.

[0042] In Step 2, the first catalyst layer-including substrate GDE1 on which the first catalyst layer 111 is formed on the lower face, which is one face of a continuous sheet-like (belt-like) substrate, is prepared. More specifically, in Step 2, the first catalyst layer-including substrate GDE1 is drawn out to travel downstream from the first substrate roll 11.

[0043] In Step 3, the first catalyst layer-including substrate GDE1 that is drawn out to travel from the first substrate roll 11 is laminated so that the first catalyst layer 111 opposes the top face which is one face of the polymer electrolyte membrane PEM that is drawn out to travel from the electrolyte membrane roll 10.

[0044] In Step 4, the polymer electrolyte membrane PEM and the first catalyst layer-including substrate GDE1, which are laminated to each other and travel, are bonded by the pair of upper/lower temporary bonding rolls 12, 13.

[0045] In Step 5, the cut CL is made so that the first catalyst layer-including substrate GDE1 bonding with the polymer electrolyte membrane PEM becomes a predetermined shape, by irradiating the laser beam LB of the laser device 14.

[0046] In Step 6, the unwanted portion GDE 12 other than the portion GDE 11 of a predetermined shape of the first catalyst layer-including substrate GDE1 is peeled from the polymer electrolyte membrane PEM and recovered by the recovery roll 15.

[0047] In Step 7, using the second catalyst layer-including substrate GDE2 that is drawn to travel from the second substrate roll 17, the second catalyst layer 121 is formed on the lower face which is the other face of the polymer electrolyte membrane PEM by the pair of upper/lower bonding rolls 18, 19, and the polymer electrolyte membrane PEM and the second catalyst layer-including substrate GDE2 on which the second catalyst layer 121 is formed are punched out by the cutter 20 so that the first catalyst layer-including substrate GDE11 of a predetermined shape bonding on the top face which is the one face of the polymer electrolyte membrane PEM is surrounded. A plurality of fuel cell membrane electrolyte assemblies MEA is thereby completed.

[0048] Next, the structure of the fuel cell membrane electrode assembly MEA produced by the method for producing a fuel cell membrane electrode assembly MEA of the present embodiment executed by the production line 1 will be explained while referencing FIG. 3.

[0049] As shown in FIG. 3, the fuel cell membrane electrode assembly MEA has a structure made by sandwiching the polymer electrolyte membrane PEM between the first catalyst layer-including substrate GDE11 and the second catalyst layer-including substrate GDE2. The first catalyst layer-including substrate GDE11 is configured by a first diffusion layer 113, first intermediate layer 112, and first catalyst layer 111 being laminated in this order. The first diffusion layer 113 is configured by a porous media which is perforated in the thickness direction, and carbon paper containing carbon fiber and carbon binder is used, for example. The first intermediate layer 112 is configured to include an electron conducting material and a water-repellent resin, for example. The first catalyst layer 111 is configured to include catalyst particles made by loading a catalytic metal such as platinum on a catalyst support such as carbon black, and a polymer electrolyte such as an ion-conductive polymer binder. Similarly, the second catalyst layer-including substrate GDE2 is also configured by a second diffusion layer 123, second intermediate layer 122 and second catalyst layer 121 being laminated in this order. The second diffusion layer 123 is a configuration similar to the first diffusion layer 113, the second intermediate layer 122 is a configuration similar to the first intermediate layer 112, and the second catalyst layer 121 is a configuration similar to the first catalyst layer 111.

[0050] In addition, with the fuel cell membrane electrode assembly MEA, a step is formed at the periphery by the first catalyst layer-including substrate GDE11 being a rectangular shape with an area smaller than the second catalyst layer-including substrate GDE2 and polymer electrolyte membrane PEM. For this reason, one face (top face) of the polymer electrolyte membrane PEM has the peripheral edge exposed in a rectangular frame shape. The creepage distance of the first catalyst layer 111 and second catalyst layer 121 is assumed, and the insulation is ensured. The method for producing the fuel cell membrane electrode assembly MEA of the present embodiment executed by the production line 1 is appropriate in the production of MEAs having such a step.

[0051] According to the method for producing a fuel cell membrane electrode assembly MEA of the present embodiment explained above, the following such effects are exerted.

[0052] The method for producing a fuel cell membrane electrode assembly MEA of the present embodiment, i.e. method for producing a fuel cell membrane electrode assembly MEA on the production line 1, is configured to include: Step 1 of preparing a polymer electrolyte membrane PEM; Step 2 of preparing a first catalyst layer-including substrate GDE1 made by a first catalyst layer 111 being formed on one face of a sheet-like substrate; Step 3 of laminating the first catalyst layer-including substrate GDE1 so that the first catalyst layer 111 opposes one face of the polymer electrolyte membrane PEM; Step 4 of bonding the polymer electrolyte membrane PEM and first catalyst layer-including substrate GDE1; Step 5 of making a cut CL by way of the laser beam LB of the laser device 14 so that the first catalyst layer-including substrate GDE1 bonded with the polymer electrolyte membrane PEM becomes a predetermined shape; Step 6 of peeling an unwanted portion GDE12 of the first catalyst layer-including substrate GDE1 other than a portion GDE11 of predetermined shape from the polymer electrolyte membrane PEM; Step 7 of forming a second catalyst layer 121 on one other face of the polymer electrolyte membrane PEM, and punching out the polymer electrolyte membrane PEM and second catalyst layer 121 so that the first catalyst layer-including substrate GDE11 of predetermined shape bonded at one face is surrounded, in which the laser beam LB of the laser device 14 is established as light of a wavelength that penetrates the polymer electrolyte membrane PEM without penetrating the first catalyst layer-including substrate GDE1.

[0053] In summary, the present embodiment configures to as to first bond the first catalyst layer-including substrate GDE1 only on one face of the polymer electrolyte membrane PEM, followed by cutting the unwanted portion GDE12 using a laser beam LB penetrating the electrolyte membrane without penetrating the catalyst layer-including substrate, and removing by peeling, and subsequently forming the second catalyst layer 121 on the other face. In this way, since the second catalyst layer 121 is formed on the other face after cutting into a predetermined shape and removing, this second catalyst layer 121 will not be removed by the laser beam LB having penetrated the polymer electrolyte membrane PEM. Therefore, according to the present embodiment, it is possible to prevent the required catalyst layer from being removed while suppressing damage to the electrolyte membrane.

[0054] In addition, in the present embodiment, the laser beam LB is set to have a transmissivity relative to the polymer electrolyte membrane PEM of at least 80%. It is thereby possible to more reliably suppress damage to the polymer electrolyte membrane PEM by using a high permeability laser beam.

Second Embodiment

[0055] FIG. 4 is a schematic view showing a production line 2 of a fuel cell membrane electrode assembly MEA according to a second embodiment of the present invention. It should be noted that the production line 2 according to the present embodiment is the same configuration as the production line 1 of the aforementioned first embodiment, except for the processing on the unwanted portion GDE12 of the first catalyst layer-including substrate GDE1 differing from the aforementioned production line 1.

[0056] The production line 2 of the fuel cell membrane electrode assembly MEA shown in FIG. 4 includes a first substrate roll 11, a pair of upper/lower temporary bonding rolls 12, 13, a laser device 24, a second substrate roll 17, a pair of upper/lower bonding rolls 18, 19, a cutter 20, etc. In other words, contrary from the aforementioned production line 1, the production line 2 and does not include a recovery roll 15, while including the laser device 24 in place of the laser device 14.

[0057] The laser device 24 is provided, similarly to the aforementioned laser device 14, downstream of the pair of upper/lower temporary bonding rolls 12, 13, above the first catalyst layer-including substrate GDE1 bonding on the top face of the polymer electrolyte membrane PEM passing through this pair of upper/lower temporary bonding rolls 12, 13, so as to be movable in the horizontal direction, and irradiates the laser beam LB towards this first catalyst layer-including substrate GDE1. This laser device 24, by irradiating the laser beam LB towards the first catalyst layer-including substrate GDE1 while moving in the horizontal direction, directly removes the unwanted portion GDE12 other than the predetermined shape portion GDE11, so as to make the first catalyst layer-including substrate GDE1 bonding with the polymer electrolyte membrane PEM into the predetermined shape (for example, rectangular). In other words, the unwanted portion GDE12 is directly removed by the laser device 24, by way of scanning and irradiating the laser beam LB over the entirety of the unwanted portion GDE12.

[0058] It should be noted that, as the laser beam LB of the laser device 24, a laser beam similar to the laser beam LB of the laser device 14 of the aforementioned first embodiment is used.

[0059] For the polymer electrolyte membrane PEM from which the unwanted portion GDE12 of the first catalyst layer-including substrate GDE1 was directly removed by the laser device 24, opposing a lower face which is one face thereof, is a second catalyst layer 121 (refer to FIG. 3), in which a top face that is one face of the second catalyst layer-including substrate GDE2 that is drawn to travel downstream from the second substrate roll 17 is formed on the top face of the second catalyst layer including substrate GDE2.

[0060] The second substrate roll 17 rotates about a horizontal shaft under the polymer electrolyte membrane PEM downstream of the laser device 24.

[0061] Next, the method for producing the fuel cell membrane electrode assembly MEA of the present embodiment executed by the production line 2 will be explained while referencing FIG. 4. It should be noted that the production method on the production line 2 according to the present embodiment is the same process as the production method on the aforementioned production line 1, except for the processing on the unwanted portion GDE12 of the first catalyst layer-including substrate GDE1 differing from the production method on the aforementioned production line 1.

[0062] The method for producing a fuel cell membrane electrode assembly MEA on the production line 2 includes Step 1, Step 2, Step 3, Step 4, Step 15, Step 7, etc. In other words, contrary to the production method on the aforementioned production line 1, the production line 2 includes Step 15 in place of Step 5, while not including Step 6.

[0063] In Step 15, the unwanted portion GDE12 is removed so that the first catalyst layer-including substrate GDE1 bonding with the polymer electrolyte membrane PEM becomes a predetermined shape, by irradiating the laser beam LB of the laser device 24.

[0064] According to the method for producing a fuel cell membrane electrode assembly MEA of the present embodiment explained above, the following such effects are exerted.

[0065] The method for producing a fuel cell membrane electrode assembly MEA of the present embodiment, i.e. method for producing a fuel cell membrane electrode assembly MEA on the production line 2, is configured to include: Step 1 of preparing a polymer electrolyte membrane PEM; Step 2 of preparing a first catalyst layer-including substrate GDE1 made by a first catalyst layer 111 being formed on one face of a sheet-like substrate; Step 3 of laminating the first catalyst layer-including substrate GDE1 so that the first catalyst layer 111 opposes one face of the polymer electrolyte membrane PEM; Step 4 of bonding the polymer electrolyte membrane PEM and first catalyst layer-including substrate GDE1; Step 15 of removing an unwanted portion GDE12 other than a portion GDE11 of predetermined shape by way of the laser beam LB of the laser device 24 so that the first catalyst layer-including substrate GDE1 bonded with the polymer electrolyte membrane PEM becomes a predetermined shape; and Step 7 of forming a second catalyst layer 121 on one other face of the polymer electrolyte membrane PEM, and punching out the polymer electrolyte membrane PEM and second catalyst layer 121 so that the first catalyst layer-including substrate GDE11 of predetermined shape bonded at one face is surrounded, in which the laser beam of the laser device 24 is established as light of a wavelength that penetrates the polymer electrolyte membrane PEM without penetrating the first catalyst layer-including substrate GDE1.

[0066] In summary, the present embodiment configures so as to use the laser beam LB penetrating the electrolyte membrane without penetrating the catalyst layer-including substrate to directly remove the unwanted portion GDE12, after bonding the first catalyst layer-including substrate GDE1 only to one face of the polymer electrolyte membrane PEM, and subsequently form the second catalyst layer 121 on the other face. Due to forming the second catalyst layer 121 on the other face after removing in a predetermined shape in this way, the second catalyst layer 121 will not be removed by the laser beam LB penetrating the polymer electrolyte membrane PEM. Therefore, according to the present embodiment, it is possible to prevent the required catalyst layer from being removed, while suppressing damage to the electrolyte membrane.

[0067] In addition, since the laser beam LB is set to have transmittance relative to the polymer electrolyte membrane PEM of at least 80% also in the present embodiment, it is possible to more reliably suppress damage to the polymer electrolyte membrane PEM by using a high transmittance laser beam.

[0068] The present invention is not to be limited to the above-mentioned embodiment, and modifications, improvements, etc. in a scope that can achieve the object of the present invention are also included in the present embodiment.

EXPLANATION OF REFERENCE NUMERALS

[0069] 1, 2 production line

[0070] 10 electrolyte membrane roll

[0071] 11 first substrate roll

[0072] 12, 13 temporary bonding roll

[0073] 14, 24 laser device

[0074] 15 recovery roll

[0075] 17 second substrate roll

[0076] 18, 19 bonding roll

[0077] 20 cutter

[0078] 111 first catalyst layer

[0079] 121 second catalyst layer

[0080] MEA fuel cell membrane electrode assembly

[0081] LB laser beam (energy ray)

[0082] PEM polymer electrolyte membrane

[0083] GDE1 first catalyst layer-including substrate

[0084] GDE11 portion of predetermined shape of first catalyst layer-including substrate

[0085] GDE12 unwanted portion of first catalyst layer-including substrate

[0086] CL cut

[0087] GDE2 second catalyst layer-including substrate