METALLIC SULFIDE COATED TRAVELERS, METHODS OF COATING TRAVELERS, AND SYSTEMS FOR USE OF METALLIC SULFIDE COATED TRAVELERS
20170260656 · 2017-09-14
Inventors
- Richard Kennedy Craig (Belmont, NC, US)
- Fred Pearson Rankin (Gastonia, NC, US)
- Behzad Abedi-Asl (Charlotte, NC, US)
- Gereon Elmer Poquette (Johnstown, CO, US)
- Taylor Ross Hopkins (Belmont, NC, US)
Cpc classification
C23C24/06
CHEMISTRY; METALLURGY
C23C28/044
CHEMISTRY; METALLURGY
C09D1/00
CHEMISTRY; METALLURGY
International classification
D01H7/60
TEXTILES; PAPER
C23C24/06
CHEMISTRY; METALLURGY
C09D1/00
CHEMISTRY; METALLURGY
C23C28/04
CHEMISTRY; METALLURGY
Abstract
Provided are metallic sulfide coated travelers, particularly tungsten disulfide coated travelers, methods of forming metallic sulfide coated travelers, and systems for use of metallic sulfide coated travelers. The metallic sulfide coating results in reduced yarn loading on the coated travelers, reduced heat generation during the spinning operation, and reduced wear of the traveler.
Claims
1. A textile spinning traveler or spinning ring comprising: a base material, and a metallic sulfide coating, wherein the metallic sulfide coating directly coats the base material.
2. The textile spinning traveler or spinning ring of claim 1, wherein the metallic sulfide coating comprises tungsten disulfide.
3. The textile spinning traveler or spinning ring of claim 1, wherein the base material comprises alloy steel.
4. The textile spinning traveler or spinning ring of claim 1, wherein the metallic sulfide coating coats each side of the traveler or spinning ring.
5. The textile spinning traveler or spinning ring of claim 1, wherein the base material comprises an elongate body with a first end and a second end wherein the first end and the second end are bent towards each other.
6. A textile spinning traveler or spinning ring comprising: a base material, an undercoat layer deposited on the base material, and a metallic sulfide coating deposited on the undercoat layer, wherein the metallic sulfide coating comprises tungsten disulfide.
7. The textile spinning traveler or spinning ring of claim 6, wherein the undercoat layer comprises one or more of black oxide, nickel, nitrided steel, manganese phosphate, and chromium.
8. The textile spinning traveler or spinning ring of claim 6, wherein the metallic sulfide coating consists essentially of tungsten disulfide.
9. A textile spinning traveler or spinning ring comprising: a base material, a binder deposited on the base material, and a metallic sulfide material, wherein the metallic sulfide material comprises tungsten disulfide.
10. The textile spinning traveler or spinning ring of claim 9, wherein the binder comprises one or more metals, polymers, and phosphates.
11. The textile spinning traveler or spinning ring of claim 9, wherein the binder is a matrix and the metallic sulfide material is dispersed throughout the matrix.
12. The textile spinning traveler or spinning ring of claim 9, wherein the metallic sulfide material consists essentially of tungsten disulfide.
13. A system for spinning yarn on a bobbin comprising: a bobbin, a spinning ring positioned around the bobbin, and a traveler disposed along the spinning ring, wherein the traveler comprises a base material and a metallic sulfide coating, wherein the metallic sulfide coating directly coats the base material.
14. The system for spinning yarn on a bobbin according to claim 13, wherein the metallic sulfide coating consists essentially of tungsten disulfide.
15. The system for spinning yarn on a bobbin according to claim 13, wherein the spinning ring is coated with the metallic sulfide coating.
16. A method of preparing a metallic sulfide coated traveler or spinning ring comprising: applying metallic sulfide on the traveler or spinning ring to prepare a coated traveler or coated spinning ring.
17. The method of preparing a metallic sulfide coated traveler or spinning ring according to claim 16, wherein the metallic sulfide is a dry powder of tungsten disulfide.
18. The method of preparing a metallic sulfide coated traveler or spinning ring according to claim 16, further comprising applying an undercoat layer to the traveler or spinning ring prior to applying metallic sulfide.
19. The method of preparing a metallic sulfide coated traveler or spinning ring according to claim 16, further comprising applying a binder to the traveler or spinning ring prior to applying metallic sulfide.
20. The method of preparing a metallic sulfide coated traveler or spinning ring according to claim 16, further comprising applying a binder with the metallic sulfide.
21. The method of preparing a metallic sulfide coated traveler or spinning ring according to claim 16, wherein the metallic sulfide is applied via impingement.
22. The method of preparing a metallic sulfide coated traveler or spinning ring according to claim 16, wherein the metallic sulfide is applied via burnishment.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING(S)
[0019] Having thus described the invention in general terms, reference will now be made to the accompanying drawings, which are not necessarily drawn to scale, and wherein:
[0020]
[0021]
[0022]
[0023]
[0024]
[0025]
[0026]
DETAILED DESCRIPTION
[0027] The present invention now will be described more fully hereinafter with reference to the accompanying drawings, in which some, but not all embodiments of the invention is shown. Indeed, the invention may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will satisfy applicable legal requirements. Like numbers refer to like elements throughout.
[0028] As used in the specification and in the appended claims, the singular forms “a”, “an”, and “the” include plural referents unless the context clearly indicates otherwise. For example, reference to “a traveler” includes a plurality of such travelers, unless the context clearly indicates otherwise.
[0029] “Consisting essentially of” or “consists essentially of,” as used herein, refers to embodiments where the respective element includes the recited material or step and minor materials or steps that do not materially affect the disclosed benefits of the respective element. “Consisting of” or “consists of,” as used herein, refers to the respective element limited to the recited material or step and trace impurities.
[0030] “Traveler” as used herein refers to spinning travelers used in the textile industry to wind yarn on a bobbin. As generally known in the art, a “traveler” may also be referred to as “travellers,” “spinning travelers,” and “ring travelers.”
[0031] The present inventors have found that application of the disclosed metallic sulfide coating to a traveler provides an improved traveler with reduced yarn loading, reduced heat generation, and reduced wear. The metallic sulfide coating reduces friction between the yarn and the traveler, as well as between the traveler and the ring, thereby reducing friction, yarn loading, and heat generation. This in turn, may help reduce traveler wear, increase traveler life, and help achieve increased spinning speeds. Yarn loading (e.g., loose fibers, lint, etc.) on the traveler adds weight to the traveler, which increases the centrifugal force and results in premature traveler wear and fly off. Yarn loading on the traveler can also increase tension in the yarn, which can change yarn properties or break the yarn (referred to as “end down”). Such change in properties or breakage may lead to stops in production and loss in efficiency. With reduced heat generation, micro welding may be reduced between the traveler and associated ring. Micro welding is caused by high temperatures induced when the traveler moves across asperities or rough areas on the surface of the traveler and ring. Application of the disclosed metallic sulfide coatings to a traveler may reduce the occurrence of micro welding. For instance, the inventors have found that sulfides react with metals at high temperatures, such as the high temperatures experienced during operation of the traveler, and, thus, prevent cohesion or welding with an associated spinning ring. By limiting or controlling the degree of wear experienced by the traveler, the overall reliability of the spinning operation results in consistent spinning performance over the life of the traveler.
[0032] Another significant advantage of the present metallic sulfide coating is the elimination of the need for additional or natural lubricants in the spinning process. In many temperature sensitive spinning operations a lubricating fluid may be required to impart the necessary lubricity to the spinning operation. In conventional spinning operations, loose cotton fibers may help provide a natural lubricant. In some spinning operations, such as compact spinning, there is a lack of loose cotton fibers, which leads to a lack of lubrication. In certain embodiments, the metallic sulfide coating provides sufficient lubrication such that natural lubricants may not be needed.
[0033]
[0034] As shown in
[0035] The traveler can have numerous and varying shapes and sizes as will be apparent to the skilled artisan. The shape and structure of the traveler will vary depending on the construction of the particular spinning equipment and yarn for spinning as is also known to the skilled artisan. In this regard,
[0036] In addition, the ends of the elongate body may be bent such that the body generally forms an open circle (such as shown in
[0037] The size of the traveler may vary and will generally be between about 1 mm to about 50 mm in length, more preferably between about 5 mm and about 30 mm in length, such as about 6 mm, 7 mm, 8 mm, 9 mm, 10 mm, 11 mm, 12 mm, 13 mm, 14 mm, 15 mm, 16 mm, 17 mm, 18 mm, 19 mm, 20 mm, 21 mm, 22 mm, 23 mm, 24 mm, 25 mm, 26 mm, 27 mm, 28 mm, and 29 mm in length.
[0038] The width of the traveler may vary as well and will generally be between about 1 mm to about 50 mm in width, more preferably between about 5 mm and about 30 mm in width, such as about 6 mm, 7 mm, 8 mm, 9 mm, 10 mm, 11 mm, 12 mm, 13 mm, 14 mm, 15 mm, 16 mm, 17 mm, 18 mm, 19 mm, 20 mm, 21 mm, 22 mm, 23 mm, 24 mm, 25 mm, 26 mm, 27 mm, 28 mm, and 29 mm in width.
[0039] The cross-section of the traveler may have various thicknesses depending on the shape and will generally be between about 1 mm to about 30 mm in thickness, such as about 2 mm, 3 mm, 4 mm, 5 mm, 6 mm, 7 mm, 8 mm, 9 mm, 10 mm, 11 mm, 12 mm, 13 mm, 14 mm, 15 mm, 16 mm, 17 mm, 18 mm, 19 mm, 20 mm, 21 mm, 22 mm, 23 mm, 24 mm, 25 mm, 26 mm, 27 mm, 28 mm, and 29 mm in thickness. For instance, the length, width, and thickness of the traveler in
[0040] As also shown in
[0041] The metallic sulfide coating of the present invention is typically formed to have a thickness up to about 0.020 mil (0.000020 in.), such as 0.001 mil, 0.002 mil, 0.003 mil, 0.004 mil, 0.005 mil, 0.006 mil, 0.007 mil, 0.008 mil, 0.009 mil, 0.01 mil, 0.011 mil, 0.012 mil, 0.013 mil, 0.014 mil, 0.015 mil, 0.016 mil, 0.017 mil, 0.018 mil, 0.019 mil, and 0.02 mil. See Dry Lubricant Smooths the Way for Space Travel, NASA Spinnoff: Technology Transfer Program (obtained Feb. 1, 2016) and A Spinoff from Mariner, Industrial Productivity and Manufacturing Technology, 108-09 (1989). The metallic sulfide coatings preferably include one or more of molybdenum sulfide, rhenium sulfide, and tungsten disulfide. Preferably, the metallic sulfide coating comprises tungsten disulfide. The coating can be applied to travelers formed from conventional base metals, such as carbon steels and steel alloys, or polymers, such as polyamides (e.g., Nylon), as well as other suitable base materials, such as fiberglass and mixtures thereof, such as fiberglass reinforced Nylon or metal inserted Nylon. For instance, in preferred embodiments, the traveler comprises a base material of steel coated with tungsten disulfide.
[0042]
[0043]
[0044] Additional additives may be used with any of the above embodiments to further improve upon the disclosed metallic sulfide coated traveler. For instance, it may be preferred to use metallic phosphate binders blended or layered with the metallic sulfide coating.
[0045] Additional embodiments of the present invention include one or more metallic sulfide coatings, such as a plurality of metallic sulfide coatings, on a traveler alone or in combination with one or more binders, metallic sulfide/binder matrixes, undercoat layers, and combinations thereof. For instance, one or more metallic sulfide coatings may be applied to a traveler with or without intervening layers of undercoats and binders.
[0046]
[0047] As explained above, various embodiments are possible for preparing metallic sulfide coated travelers (e.g., utilizing binders, metallic sulfide/binder matrixes, undercoat layers, multiple layers, etc.). Any of these metallic sulfide coated travelers may be used in embodiments of the present system. Further, the metallic sulfide coated travelers of the present invention can be used with any suitable yarns. The obtained benefits of the metallic sulfide coating, such as reduced yarn loading, reduced wear, reduced heat generation, are applicable to a variety of yarns, both natural and synthetic. For instance, the disclosed metallic sulfide coated travelers may be used with long staple yarns, continuous filament yarns, synthetics, temperature sensitive fibers, abrasive fibers, non-lubricated fibers, spin short staple, cotton, cotton-blend fibers, or the like.
[0048] The spinning ring for the system utilizing the metallic sulfide coated traveler can be any suitable spinning ring appropriate for the traveler. For example, metallic (e.g., chrome coated rings) and polymeric rings may be used with the metallic sulfide coated traveler. For instance, the spinning ring may comprise a chromium coating, such as nodular chromium, amorphous chromium or any other suitable chromium coating, or a nickel-based material, such as a nickel-diamond composite or the like. Ceramic coatings may also be used, such as alumina, titania, zirconia or the like.
[0049] In certain embodiments, the spinning ring is coated with the disclosed metallic sulfide coating as explained above in reference to travelers. For instance, in some embodiments, the spinning ring comprises one or more layers of molybdenum sulfide, rhenium sulfide, and tungsten disulfide, preferably tungsten disulfide. As shown in
[0050] The metallic sulfide coating of the present invention is typically formed to have a thickness up to about 0.060 mil (0.000060 in.), such as 0.001 mil, 0.002 mil, 0.003 mil, 0.004 mil, 0.005 mil, 0.006 mil, 0.007 mil, 0.008 mil, 0.009 mil, 0.01 mil, 0.011 mil, 0.012 mil, 0.013 mil, 0.014 mil, 0.015 mil, 0.016 mil, 0.017 mil, 0.018 mil, 0.019 mil, 0.020 mil, 0.021 mil, 0.22 mil, 0.023 mil, 0.024 mil, 0.025 mil, 0.026 mil, 0.027 mil, 0.028 mil, 0.029 mil, 0.030 mil, 0.031 mil, 0.032 mil, 0.033 mil, 0.034 mil, 0.035 mil, 0.036 mil, 0.037 mil, 0.038 mil, 0.039 mil, 0.040 mil, 0.041 mil, 0.042 mil, 0.043 mil, 0.044 mil, 0.045 mil, 0.046 mil, 0.047 mil, 0.048 mil, 0.049 mil, 0.050 mil, 0.051 mil, 0.052 mil, 0.053 mil, 0.054 mil, 0.055 mil, 0.056 mil, 0.057 mil, 0.058 mil, 0.059 mil, and 0.060 mil. See Dry Lubricant Smooths the Way for Space Travel, NASA Spinnoff: Technology Transfer Program (obtained February 1, 2016) and A Spinoff from Mariner, Industrial Productivity and Manufacturing Technology, 108-09 (1989).
[0051] The present inventors have found that application of the metallic sulfide coating to both the traveler and the spinning ring or to just the spinning ring may reduce the break-in period of the ring. During the break-in period, the spinning equipment is operated at a relatively low spinning speed because the surface of the spinning ring is initially too rough to allow operation at high speed. The low speed spinning operation allows the initially rough surface of the spinning ring to be conditioned by contact with a moving traveler. Such break-in periods can last for time periods of one month or longer, thus substantially decreasing manufacturing efficiencies. However, the presence of the metallic sulfide coating on both the traveler and the spinning ring or on just the spinning ring may reduce the break-in period to a matter of days. The metallic sulfide coating may allow for the speed to be increased to normal operating conditions earlier than previous spinning rings and thereby increase manufacturing efficiencies.
[0052] In some embodiments, the spinning ring may be coated with an undercoat layer and/or binder as described above in reference to travelers and may have additives as explained above in reference to travelers. For instance, the spinning ring may be coated with an undercoat layer comprising one or more of black oxide, nickel, nitrided steel, manganese phosphate, and chromium. The spinning ring may comprise a binder comprising one or more metals, polymers, and phosphates, and in some embodiments, the binder may be a matrix with metallic sulfide material dispersed throughout the matrix.
[0053] It will be apparent to the skilled artisan that the ring can have any of various cross-sectional shapes (e.g., circular, rectangular, square, etc.) for cooperating with the corresponding traveler and yarn. Any suitable bobbin may be used as well, such as bobbins comprising polycarbonate, ABS (acrynitril-butadien-styrol), polypropylene, and the like.
[0054] The invention has been described in detail with reference to its preferred embodiments. However, numerous variations and modifications can be made within the spirit and scope of the invention without departing from the invention as described in the foregoing detailed specification and defined in the appended claims.
EXAMPLES
[0055] In the following examples the effectiveness of the metallic coating for extending the life of the traveler was evaluated.
[0056] In a first trial, two sets of travelers, “Set A” having a metallic sulfide coating (tungsten disulfide) and “Set B” without a metallic sulfide coating, were compared. The travelers for both Sets A and B were obtained from the same production lot, and included a nickel coating. A coating of tungsten disulfide was burnished onto the travelers of Set A. The travelers had a weight of 31.5 mg as measured in accordance with ISO 96-1:2016.
[0057] Each set were run at about 16,000 RPM on a conventional spinning frame at a production facility. A group of each set of travelers were examined at 7 day intervals, and an average weight for each traveler was measured. Each group of SETS A and B included 100 travelers. The results are summarized in Table 1, below.
TABLE-US-00001 TABLE 1 Results of Comparison of WS2 coated travelers to uncoated travelers. Per- Weight centage Before After loss weight grams/100 grams/100 grams/100 loss Trial Set pieces pieces pieces (%) SET B 3.162 3.153 0.009 0.28% Group 1 (7 Days) SET B 3.167 3.152 0.015 0.48% Group 2 (14 Days) SET B 3.171 3.153 0.017 0.55% Group 3-5 (18 Days) SET A (with WS.sub.2 coating) 3.162 3.159 0.003 0.08% Group 1 (7 Days) SET A (with WS.sub.2 coating) 3.166 3.152 0.014 0.44% Group 2 (14 Days) SET A (with WS.sub.2 coating) 3.160 3.143 0.017 0.53% Group 3 (21 Days) SET A (with WS.sub.2 coating) 3.163 3.130 0.033 1.03% Group 4 (28 Days) SET A (with WS.sub.2 coating) 3.156 3.130 0.026 0.83% Group 5 (35 Days)
[0058] The travelers from Set A exhibited about 10% less wear than the corresponding travelers from Set B, through the first 14 days. The remaining travelers from Set B were removed after 18 days due to excessive ends down. The travelers from Set A that were examined after 21 days had about 10% less wear than the travelers from Set B that were removed after 18 days. The travelers from Set A ran the entirety of the planned 35 day trial. The travelers from Set A were removed after 35 days as planned and not due to poor performance. The results of the trial demonstrate that the metallic sulfide coating essentially doubled the effective life of the travelers tested. It was also noted, visually, that the travelers with a metallic sulfide coating had less yarn loading.
[0059] In a second trial, a trial having two sets of travelers, “Set A” with a metallic sulfide coating and “Set B” without a metallic sulfide coating, from the same production batch with an undercoat of nickel were evaluated. The travelers had a weight of 112 mg as measured in accordance with ISO 96-1:2016. The travelers of each set were run at about 10,500 RPM on a compact spinning frame at a production facility. The typical change cycle for the travelers currently used at this plant was 10 days. The travelers from Set B ran for 14 days. The travelers from Set A were removed after 21 days, but not due to poor performance. In several follow up trials at the same facility, travelers similar to Set A ran for 28 days. In this instance, the metallic sulfide coating essentially doubled the effective life of the travelers tested, and provided triple the life of the current traveler used. Results are summarized in TABLE 2, below.
TABLE-US-00002 TABLE 2 Evaluation of the effect of metallic sulfide coating in compact spinning Trial Results (Weight loss data was not tracked as the traveler life was the result of interest) SET SET B A Notes First Trial 14 21 Removed Nickel w/WS.sub.2 despite not failing Second Trial 14 28 Nickel w/WS.sub.2 ran 28 days without issue Third Trial 14 28 Nickel w/WS.sub.2 ran 28 days without issue
[0060] Tungsten Disulfide Coated Traveler.
[0061] Two travelers were tested, both with identical geometry, weight, and from the same production lot. The first traveler was coated with black oxide and the second traveler was coated with tungsten disulfide. The two travelers were used to wind 40 cotton count yarn at 18,400 RPM for one hour followed by 17,700 RPM for two hours on a laboratory spin test frame. The tungsten disulfide coated traveler was found to have 79.5% less wear than the black oxide coated traveler as determined by weight loss.
[0062] Tungsten Disulfide Coated Traveler with Black Oxide Undercoat Layer.
[0063] Two travelers were tested, both with identical geometry, weight, and from the same production lot. The first traveler was coated with black oxide and the second traveler was coated with black oxide and an overcoat layer of tungsten disulfide. The two travelers were used to wind 40 cotton count yarn at 18,400 RPM for one hour followed by 17,700 RPM for two hours on a laboratory spin test frame. The black oxide plus tungsten disulfide coated traveler was found to have 77% less wear than the black oxide coated traveler as determined by weight loss.
[0064] Many modifications and other embodiments of the inventions set forth herein will come to mind to one skilled in the art to which these inventions pertain having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is to be understood that the inventions are not to be limited to the specific embodiments disclosed and that modifications and other embodiments are intended to be included within the scope of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.