Method for solvent removal from a polymer solution by integrated size classification and extrusion in a plastic extruder

Abstract

The invention relates to a continuous method for removing a solvent from a suspension or solution comprising a target polymer, wherein the method comprises the steps of delivering said suspension or solution to an extruder, wherein said extruder comprises a size classification unit that is designed to be permeable for the solvent and impermeable for the target polymer; and filtration and extrusion of said suspension or solution in said extruder. The invention also relates to a plastic waste recycling system for recycling a target polymer. Furthermore, the invention also relates to a polymer material obtained by this recycling method.

Claims

1. A continuous method for removing a solvent from a suspension or solution comprising a target polymer, wherein the method comprises the following steps: (i) delivering said suspension or solution to an extruder, wherein said extruder comprises a size classification unit that is designed to be permeable for the solvent and impermeable for the target polymer; and (ii) filtration and extrusion of said suspension or solution in said extruder.

2. The method according to claim 1, wherein the size classification unit is a membrane or sieve.

3. The method according to claim 1, wherein the extruder further comprises a degassing unit.

4. The method according to claim 3, wherein the degassing unit is used for essentially complete degassing of the target polymer in solution or suspension, wherein essentially complete degassing means that ≤1 wt % (≤10000 ppm), preferably ≤0.1 wt % (≤1000 ppm) of solvent is present after the essentially complete degassing.

5. The method according to claim 1, wherein the filtration of said suspension or solution is performed during extrusion and/or degassing in said extruder comprising the classification unit.

6. The method according to claim 1, wherein the extruder comprises an inner and an outer enclosure, wherein the inner enclosure further comprises a size classification unit that is impermeable to the target polymer and therefore allows the solvent to exit the inner enclosure and the target polymer to remain inside the inner enclosure, thereby allowing filtration of the suspension or solution through said size classification unit in the extruder.

7. The method according to claim 1, wherein up to 5%, preferably up to 10%, more preferably up to 20%, more preferably up to 30%, more preferably up to 40%, even more preferably up to 50%, most preferably up to 60% of solvent is removed from said solution or suspension.

8. The method according to claim 2, wherein the membrane or sieve is designed to be impermeable for target polymers with an average molecular mass of 1000 kDa or more, in particular target polymers with an average molecular mass of 500 kDa or more, in particular preferred target polymers with an average molecular mass of 200 kDa or more.

9. The method according to claim 2, wherein the size classification unit is a membrane, and wherein a material of the membrane is selected from a group consisting of polyamide membrane, polyvinylidene difluoride membrane, polyethersulfone membrane, polysulfone membrane, polydimethylsiloxane membrane, polypropylene membrane, or a combination thereof.

10. The method according to claim 2, wherein the size classification unit is a sieve, wherein the sieve is made of a material comprising metal and/or ceramics.

11. The method according to claim 1, wherein the filtration is driven by a pressure differential across the size classification unit, wherein the pressure differential is >30 bar, preferably >50 bar, most preferred >100 bar.

12. The method according to claim 11, wherein the pressure differential is achieved by a vacuum pumping system aided with heating, wherein heating refers to a temperature not exceeding a maximal temperature of 5K, particularly 10K below the boiling point of the solvent, or the solvent with the lowest boiling point in a mixture of solvents.

13. The method according to claim 1, wherein the target polymer is a thermoplastic target polymer.

14. The method according to claim 1, wherein the target polymer is selected from the group comprising polyolefins, polyamide (PA) and combinations thereof.

15. The method according to claim 1, wherein the method is for recycling plastic waste and is carried out in a plastic waste recycling plant.

16. Plastic waste recycling plant, in particular for implementing the method according to claim 1, comprising the following stations: a) a station that comprises a downsizing device for plastic waste, that optionally is a cutting or shredding device for plastic waste, and optionally a plastic particle size classification device for classifying the downsized plastic waste; b) optionally a station for washing the downsized, optionally classified plastic waste produced in station a); c) a station that comprises a vessel, wherein the vessel comprises an agitator and/or a heating system and/or an organic solvent for dissolving the at least one target polymer derived from the downsized, optionally classified plastic waste produced in station a), or the optionally washed plastic waste produced in station b); d) optionally a station that comprises a centrifuge for solid-liquid separation; e) a station comprising an extruder with a size classification unit, wherein the size classification unit is permeable for the solvent and impermeable for the target polymer, and wherein the extruder with size classification unit is used for size classification and extrusion of the target polymer, wherein the extruder comprises a degassing unit and optionally a heating unit, wherein said extruder optionally produces plastic pellets; wherein the plastic waste recycling plant has a transfer system that transfers materials from each station to the next in the above listed order.

17. The method according to claim 3, wherein the degassing unit is used for essentially complete degassing of the target polymer in solution or suspension, wherein essentially complete degassing means that ≤0.1 wt % (≤1000 ppm) of solvent is present after the essentially complete degassing.

18. The method according to claim 2, wherein the membrane or sieve is designed to be impermeable for target polymers with an average molecular mass of 500 kDa or more.

19. The method according to claim 2, wherein the membrane or sieve is designed to be impermeable for target polymers with an average molecular mass of 200 kDa or more.

20. The method according to claim 1, wherein the filtration is driven by a pressure differential across the size classification unit, wherein the pressure differential is >50 bar.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0038] It is an object of the present invention to provide an improved method, particularly a continuous method, for solvent and/or impurity removal from a suspension or solution comprising a dissolved target polymer, particularly a dissolved thermoplastic target polymer by size classification of a target polymer that is in a suspension or solution, comprising size classification of a target polymer in a suspension or solution with a membrane and/or sieve.

[0039] The size classification of a target polymer that is in a suspension or solution may be complemented with degassing, wherein optionally degassing is performed with a degassing extruder, thereby obtaining an essentially degassed plastic material comprising the target polymer, wherein essentially degassed means that ≤1 wt % (≤10000 ppm), preferably ≤0.1 wt % (≤1000 ppm) of solvent is present after complete degassing.

[0040] The method enables solvent and/or impurity removal from a suspension or solution comprising the target polymer by at least reducing the need for heat-induced solvent evaporation, thereby reducing the loss of target polymer through decomposition of polymers by thermal instability that would occur if solvent removal were exclusively or largely conducted by heat-induced evaporation, for example at temperatures above 180° C. The method further improves the efficiency of impurity removal from a suspension or solution comprising the target polymer by performing either size classification of dissolved target polymers or solvent evaporation, that may or may not be heat-induced, or combinations thereof.

[0041] It is a further object of the present invention to integrate the step of solvent removal from a suspension or solution comprising a dissolved target polymer by size classification, comprising size classification with a membrane or sieve, with extrusion using an extruder and/or degassing with a degassing extruder, thereby forming an integrated, single step comprising size classification and extrusion, and optionally degassing with a degassing device comprising a degassing extruder, wherein the size classification unit, comprising membrane or sieve size classification, is an integral part of the extruder, optionally wherein the degassing device comprising a degassing extruder is an integral part of the extruder with size classification unit, thus providing a continuous method effectively supplanting the need for separate machines or stations during the single, integrated step comprising size classification, extrusion and optionally degassing with a degassing extruder, respectively. It is also subject of the present invention to provide an improved method of solvent and/or impurity removal from a suspension or solution comprising a dissolved target polymer, for integration into a complete plastic recycling process, thereby improving the overall energy efficiency of the complete plastic recycling process, and thus running costs, which in turn may also increase recycling throughput. It is also an object of the present invention to provide an improved plastic waste recycling system for recycling plastic waste comprising a target polymer. Such an improved plastic waste recycling system comprises a plastic recycling plant with multiple processing stations, wherein the solvent removal station or integrated solvent removal step is according to the subject matter of the present invention. The quality of the plastic material thus obtained is at least comparable to virgin polymers, or a virgin-like polymer.

[0042] Hence, provided is a continuous method for removing a solvent from a suspension or solution comprising a target polymer, wherein the method comprises the following steps: [0043] (i) delivering said suspension or solution to an extruder, wherein said extruder comprises a size classification unit that is designed to be permeable for the solvent and impermeable for the target polymer; and [0044] (ii) filtration and extrusion of said suspension or solution in said extruder.

[0045] In one embodiment, the polymer suspension or solution is provided to at least one of the following steps before step (i): [0046] A. purifying the suspension or solution comprising the target polymer, in particular by means of mechanical solid-liquid separation, optionally using a centrifuge, thereby obtaining a purified suspension or solution comprising the target polymer; [0047] B. optionally applying: a.) flash-evaporation, or b.) precipitation and mechanical solid-liquid separation, of the purified suspension or solution comprising the target polymer;

[0048] It was surprisingly discovered that integration of a size classification step, comprising filtration with a membrane or sieve, with an extrusion step, and/or a degassing step optionally using a degassing extruder, as part of a process of solvent-based recycling of plastics enables the sustainable provision of a target polymer with virgin-like quality.

[0049] It was furthermore surprisingly discovered that integrating a size classification step comprising filtration with a membrane or sieve, with an extrusion step, and/or a degassing step optionally comprising a degassing extruder, reduces energy consumption and/or duration of the recycling process such that the resulting overall recycling process allows a higher throughput of recycled plastic, thus allowing more efficient plastic recycling, which in turn more efficiently addresses the problem of plastic pollution. The integration of both extrusion and size classification, optionally combined with degassing, substantially reduces running time and costs, while maximizing the efficiency of solvent removal and minimizing the need of solvent evaporation, especially if the high pressure of the extruder is used to drive size classification.

[0050] The above steps i) to ii) and A) to B) do not necessarily signify a specific sequence or number of steps. However, preferably the steps of the method are implemented with ascending numbers and/or in alphabetical order, i.e. in the order as shown above. Some of said steps may be optional and in some embodiments optional steps are not implemented.

[0051] In one embodiment, step i) is preceded by dissolving at least part of the target polymer. According to some embodiments, adding a solvent or a mixture of solvents to plastic material comprising the target polymer in order to obtain a solution or suspension comprising said target polymer is achieved by dissolving the target polymer at an elevated temperature. In one embodiment, said elevated temperature may be above room or ambient temperature.

[0052] In one embodiment, the size classification unit is a membrane or sieve. In one embodiment, the size classification unit is either a membrane or a sieve, or a combination thereof.

[0053] In one embodiment, the extruder further comprises a degassing unit. In one embodiment the degassing unit is used for essentially complete degassing of the target polymer in solution or suspension, wherein essentially complete degassing means ≤1 wt % (≤10000 ppm), preferably ≤0.1 wt % (≤1000 ppm) of solvent is present after complete degassing.

[0054] In one embodiment, size classification, in particular filtration of said suspension or solution is performed during extrusion and/or degassing in said extruder comprising the classification unit. In one embodiment, filtration of said suspension or solution is performed during extrusion, wherein optionally degassing with a degassing extruder is performed after filtration.

[0055] In one embodiment, the size classification unit forms part of the extruder, optionally further comprising a degassing unit.

[0056] In one embodiment, the extruder comprises an inner and an outer enclosure, wherein the inner enclosure further comprises the size classification unit that is impermeable to the target polymer and therefore allows the solvent to exit the inner enclosure and the target polymer to remain inside the inner enclosure, thereby allowing filtration of the suspension or solution through said size classification unit in the extruder. In one embodiment, impurities may also exit the inner enclosure through the size classification unit of the extruder.

[0057] In one embodiment, the extruder is a screw extruder with at least one screw enclosed by the inner enclosure, wherein the spatial clearance between the inner enclosure comprising the size classification unit and the at least one screw of the screw extruder allows a spatial clearance-to-screw diameter ratio of at least >0.02%, preferably >0.2%, most preferred >2%.

[0058] In one embodiment, the inner enclosure of the extruder comprising the size classification unit encloses a volume of at least 0.01 m.sup.3, preferably up to 1.0 m.sup.3. In some embodiments, the inner enclosure of the extruder comprising the size classification unit is rectangular. Generally, the sizes (volumes) of extruders, and thus their geometry, may vary to a large extent.

[0059] In one embodiment, the inner enclosure of the extruder comprising the size classification unit is at least partially covered or formed by the size classification unit, wherein the size classification unit is covering or forming at least 80%, preferably at least 90%, most preferred up to 100% of the surface area of the inner enclosure of the extruder. In another embodiment, the inner enclosure of the extruder is not covered or formed by the size classification unit, wherein the size classification unit forms or covers less than 80% of the surface area of the inner enclosure of the extruder, particularly less than 70%, more particularly less than 60%, more particularly less than 50%, more particularly less than 40%, more particularly less than 30%, more particularly less than 20%, more particularly less than 10%, more particularly less than 5%, more particularly less than 1% of the surface area of the inner enclosure of the extruder comprising the size classification unit. In some embodiments the inner enclosure of the size classification unit comprises a multitude of tubes, in particular tubes that are installed in parallel.

[0060] In one embodiment, size classification unit may form a tube. In one embodiment, the size classification unit is a membrane that may form a tube. In some embodiments the membrane is coiled to form a tube.

[0061] In one embodiment, the extruder comprising the size classification unit is continuous with a solution or suspension provision unit through an inlet opening of the extruder comprising the size classification unit. In another embodiment, the extruder comprising the size classification unit is continuous with a polymer retrieval unit through an outlet opening of the extruder comprising a size classification unit. In yet another embodiment, the extruder comprising the size classification unit is continuous with both a solution or suspension provision and a polymer retrieval unit, through an inlet and outlet opening, respectively.

[0062] In one embodiment, up to 5%, preferably up to 10%, more preferably up to 20%, more preferably up to 30%, more preferably up to 40%, even more preferably up to 50%, most preferably up to 60% of solvent is removed from said solution or suspension.

[0063] In one embodiment, the size classification unit is a membrane or sieve, wherein the membrane or sieve is designed to be impermeable for target polymers with an average molecular mass of 1000 kDa or more, in particular target polymers with an average molecular mass of 500 kDa or more, in particular preferred target polymers with an average molecular mass of 200 kDa or more. In one embodiment, the membrane or sieve is designed to be impermeable for target polymers with an average molecular mass of 100 kDa or more.

[0064] Preferably, the size classification or filtration, comprising sieving or membrane filtration, uses micro-, ultra- and/or nanofiltration, in particular microfiltration. Preferably the pore size of filtration corresponds to a molecular weight cut-off in a range of 10 kDa to 500 kDa, in particular 100 kDa to 300 kDa, in particular for the used solvent. Also, combinations are preferred in some embodiments, e.g. a pre-treatment by a first filter having a first pore size and a subsequent second filter having a second pore size was found to be suitable.

[0065] In some embodiments the size classification unit comprises a membrane that forms a multi-layered membrane wall, in particular with at least two, at least three or at least four layers of membrane. In some embodiments, the size classification unit is a multilayered sieve, in particular with at least two, at least three or at least four layers of sieve. In some embodiments, the multilayered sieve or membrane has a gradually decreasing cut-off size in the flow direction of the solvent.

[0066] In one embodiment, the size classification unit is a membrane, and wherein the membrane material is selected from a group consisting of polyamide membrane, polyvinylidene difluoride membrane, polyethersulfone membrane, polysulfone membrane, polydimethylsiloxane membrane, polypropylene membrane, or a combination thereof.

[0067] In some embodiments the membrane is an inorganic membrane, in particular a ceramic membrane.

[0068] In some embodiments the membrane is an organic membrane, in particular an organic membrane that is selected from a group consisting of polyamide membrane, polyvinylidene difluoride membrane, polyethersulfone membrane, polysulfone membrane, polydimethylsiloxane membrane, polypropylene membrane. The organic membrane should be made from or comprise a polymer that does not dissolve in the solvent that is selected to implement the method, i.e. the choice of membrane depends on the selected solvent. If the target polymer is low-density polyethylene (LDPE) and/or the solvent is heptane, polyvinylidene difluoride membranes were found to be particularly suitable. If the target polymer is low-density polyethylene (LDPE) and/or the solvent is heptane, polyamide membranes were also found to be particularly suitable. Also mixtures of polyamide and polyvinylidene difluoride may be used for membranes for low-density polyethylene (LDPE) with heptane as a solvent. If the target polymer is polypropylene and/or the solvent is octane, polysulfone membranes were found to be particularly suitable. If the thermoplastic target polymer is polyamide (PA), in particular polycaprolactam (PA6), and/or the solvent is propylene glycol, polypropylene membranes were found to be particularly suitable. If the thermoplastic target polymer is polyvinyl chloride (PVC) and/or the solvent is acetone, polypropylene membranes were again found to be particularly suitable.

[0069] In some embodiments the membrane, in particular one of the above named membranes, is chemically modified to have an increased polarity.

[0070] The membrane is preferably a solvent permeable porous membrane with respect to said solvent for the thermoplastic target polymer. Preferably the pore sizes are in the range of 0.1 to 0.001 microns.

[0071] In some embodiments the membrane is designed for retaining a thermoplastic target polymer with a molecular weight cut-off selected from a range of 10 kDa to 2000 KDa, in particular of 100 kDa to 1000 kDa, wherein molecules with a weight that is higher than a selected weight from said ranges do not pass the membrane, in particular when said molecule is within the solvent, preferably dissolved in said solvent. In a preferred embodiment, impurities are not retained by the membrane, wherein impurity refers to any molecules different from the target polymer or plurality of target polymers.

[0072] In some embodiments the membrane is permeable for molecules with a molecular weight of 0.1 kDa. In some embodiments the membrane is permeable for molecules with a molecular weight of 1 kDa. Although solvents usually have a much lower molecular weight, it was found that it is advantageous, when the membrane has pores that are significantly larger than the solvent molecules.

[0073] In one embodiment, the size classification unit is a sieve, wherein the sieve is made of material comprising metal and/or ceramics.

[0074] In one embodiment, the sieve is a motorized sieve. The motorized sieve may be moved circularly or circularly, or by combinations or circular and linear movement.

[0075] In one embodiment, the filtration is driven by a pressure differential across the size classification unit, wherein the pressure differential is >30 bar, preferably >50 bar, most preferred >100 bar.

[0076] In one embodiment, the pressure differential is achieved by a vacuum pumping system aided with heating, wherein heating refers to a temperature not exceeding a maximal temperature of 5K, particularly 10K below the boiling point of the solvent, or the solvent with the lowest boiling point in a mixture of solvents.

[0077] In one embodiment, the plastic waste comprising the target polymer is at least partially dissolved in the solvent, in particular using an agitator and/or a heating system, wherein heating refers to a temperature not exceeding a maximal temperature of 5K, particularly 10K below the boiling point of the solvent, or the solvent with the lowest boiling point in a mixture of solvents.

[0078] In one embodiment, the method for at least partially removing a solvent is for recycling plastic waste comprising a target polymer, and the plastic waste is at least partially dissolved in the solvent, in particular using an agitator and/or a heating system, wherein heating refers to a temperature not exceeding a maximal temperature of 5K, particularly 10K below the boiling point of the solvent, or the solvent with the lowest boiling point in a mixture of solvents.

[0079] In one embodiment, the method for at least partially removing a solvent is for recycling plastic waste comprising a target polymer, wherein the target polymer is at least partially dissolved in the solvent, in particular using an agitator and/or a heating system, wherein heating refers to a temperature not exceeding a maximal temperature of 5K, particularly 10K below the boiling point of the solvent, or the solvent with the lowest boiling point in a mixture of solvents. In another embodiment, the method for at least partially removing a solvent is for integration into a solvent-based recycling process. The solvent-based recycling process preferably is a continuous solvent-based recycling process.

[0080] s According to some embodiments adding a solvent or a mixture of solvents to said plastic material to obtain a solution or suspension comprising said target polymer comprises dissolving said target polymer at least partially in said solvent or said mixture of solvents in a, in particular closed and/or gastight, vessel comprising the solvent, wherein an agitator for stirring the suspension or solution is provided. The agitator may be connected to said vessel and/or it may be disposed in said vessel. It is in some embodiments possible to dispose the agitator within the vessel without connection to the vessel, e.g. by hanging the agitator into the vessel from above. However, often the agitator is connected to the, in particular closed and/or gastight, vessel. The suspension or solution is preferably stirred for at least 15 min, in particular for at least 30 min. Preferably, the suspension or solution is stirred for less than 6 h, in particular for less than 2 h (120 min). It was found that stirring expedites dissolving the target polymer in the solvent.

[0081] In one embodiment, the target polymer is at least partially dissolved in the solvent at a temperature that is lower by more than 5 K, in particular by more than 10 K than the boiling point of said solvent, or the solvent with the lowest boiling point in a mixture of solvents.

[0082] In some embodiments the target polymer is a thermoplastic polymer. In some embodiments, the target polymer is derived from plastic material selected from the group comprising post-consumer use polymers, post-industrial use polymers and combinations thereof.

[0083] In some embodiments said thermoplastic polymer is selected from the group comprising polyolefins, polyamide (PA) and combinations thereof.

[0084] In some embodiments the target polymer is selected from the group consisting of polystyrene (PS), in particular expanded polystyrene (EPS), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polyamide (PA), Styrene-acrylonitrile resin (SAN), acrylonitrile styrene acrylate (ASA), polyoxymethylene (POM), polybutylene terephthalate (PBT), polycarbonate (PC), acrylonitrile butadiene styrene (ABS) and polyethylene terephthalate (PET). A particularly suitable target polymer is polyethylene (PE), in particular low-density polyethylene (LDPE) and/or high-density polyethylene (HDPE), Polyvinylfluoride (PVF).

[0085] In some embodiments the target polymer is selected from the group comprising polystyrene (PS), in particular expanded polystyrene (EPS), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polyamide (PA), Styrene-acrylonitrile resin (SAN), acrylonitrile styrene acrylate (ASA), polyoxymethylene (POM), polybutylene terephthalate (PBT), polycarbonate (PC), acrylonitrile butadiene styrene (ABS) and polyethylene terephthalate (PET). A particularly suitable target polymer is polyethylene (PE), in particular low-density polyethylene (LDPE) and/or high-density polyethylene (HDPE). The method was found to be particularly suitable for recycling low-density polyethylene (LDPE).

[0086] In one embodiment, the target polymer is a polyolefin. In one embodiment, the target polymer is low-density polyethylene (LDPE). In one embodiment, the target polymer is polypropylene (PP). In one embodiment, the target polymer is polyamide (PA).

[0087] The suspension or solution preferably comprises one or more at least partially dissolved thermoplastic target polymers selected from the group consisting of polystyrene (PS), in particular expanded polystyrene (EPS), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polyamide (PA), Styrene-acrylonitrile resin (SAN), acrylonitrile styrene acrylate (ASA), polyoxymethylene (POM), polybutylene terephthalate (PBT), polycarbonate (PC), acrylonitrile butadiene styrene (ABS) and polyethylene terephthalate (PET). Polyethylene (PE) is preferably selected from high-density polyethylene (HDPE) and low-density polyethylene (LDPE) or contains both. The method was found to be particularly suitable for recycling polyethylene (PE), in particular low-density polyethylene (LDPE).

[0088] In some embodiments the target polymer has an average molecular mass of 50 to 20000 kDa, in particular of 100 to 4000 kDa, in particular preferred of 200 to 2000 kDa. In some embodiments the target polymer has a number average molecular weight of 50 to 20000 kDa, in particular of 100 to 4000 kDa, in particular preferred of 200 to 2000 kDa.

[0089] In one embodiment, the solvent or mixture of solvents in which the target polymer is dissolved, form a solution or suspension that is saturated with the dissolved target polymer.

[0090] In some embodiments the target polymer is dissolved in said solvent or said mixture of solvents in an amount not less than 5 wt %, more preferably not less than 7 wt %, in particular not less than 10 wt %, with respect to the total weight of said solvent or mixture of solvents and the polymer that is dissolved.

[0091] In some embodiments the target polymer is dissolved in said solvent or said mixture of solvents in an amount not less than 5 wt %, more preferably not less than 7 wt %, in particular not less than 10 wt %, with respect to the total weight of said solvent or mixture of solvents and the polymer that is dissolved, wherein said solvent or mixture of solvents in which the target polymer is dissolved, form a solution or suspension that is saturated with the dissolved target polymer. Besides the target polymer, other non-target polymers may be present. Preferably non-target polymers do not dissolve in the solvent or have a lower solubility under said conditions than the target polymer. If for example plastic waste is recycled the non-target polymers are preferably present to a lesser degree than the target polymer. Preferably non-target polymers are dissolved in an amount of less than 1 wt %, in particular less than 0.5 wt %, with respect to the total weight of the solvent and the polymer that is dissolved.

[0092] It is preferred if the suspension or solution is heated to an average temperature above 20° C., in particular to an average temperature above room temperature of 25° C., in particular preferred to an average temperature of more than 40° C.

[0093] In some embodiments, the suspension or solution has an average temperature of at least 50° C., in particular of at least 80° C. In some embodiments during dissolving of the target polymer in the solvent, the solvent is heated to an average temperature of 20 to 160° C., in particular of 40 to 140° C., preferably of 50 to 100° C. In some embodiments, the suspension or solution is heated to an average temperature of 60 to 180° C. For low-density polyethylene (LDPE) as a target polymer an average temperature of 80 to 120° C. was found to be particularly suitable for dissolving said polymer. For high-density polyethylene (HDPE) as a target polymer an average temperature of 100 to 140° C. was found to be particularly suitable for dissolving said polymer. For polypropylene (PP) as a target polymer an average temperature of 120 to 160° C. was found to be particularly suitable for dissolving said polymer. In some embodiments the average temperature in the above described vessel of the suspension or solution, in particular when dissolving the target polymer, is above 20° C., preferably above 40° C., in particular above 60° C., in particular preferred above 80° C. This may also be the average temperature of the suspension or solution in said vessel comprising said solvent or suspension. In some embodiments, dissolving the target polymer is conducted under temperature which is lower by more than 5 K, in particular by more than 10 K than the boiling point of said solvent.

[0094] In some embodiments the peak temperature of the suspension or solution, in particular when dissolving the target polymer, is above 20° C., preferably above 40° C., in particular above 60° C., in particular preferred above 80° C. This may also be the peak temperature of the solvent and/or suspension or solution in said vessel comprising said solvent or suspension. It is to be understood that the average temperature is preferably selected in such a way that a most—if not all—of the target polymer is dissolved and/or remains dissolved in said solvent.

[0095] In one embodiment, the suspension or solution comprising the target polymer is heated in the above mentioned step ii) to an average temperature above 20° C., in particular to an average temperature above room temperature of 25° C., in particular preferred to an average temperature of more than 40° C., and/or maintained at said average temperature. In some embodiments in step ii) the suspension or solution has an average temperature of at least 50° C., in particular of at least 80° C. In some embodiments size classification is conducted at an average temperature of 20 to 160° C., in particular of 40 to 140° C., preferably of 50 to 100° C. In some embodiments in step ii) the suspension or solution is heated to an average temperature of 60 to 180° C. For low-density polyethylene (LDPE) as a thermoplastic target polymer an average temperature of 80 to 120° C. in step ii) was found to be particularly suitable. For high-density polyethylene (HDPE) as a thermoplastic target polymer an average temperature of 100 to 140° C. in step ii) was found to be particularly suitable. For polypropylene (PP) as a thermoplastic target polymer an average temperature of 120 to 160° C. was found to be particularly suitable in step ii). This may also be the average temperature of the suspension or solution in a filtration unit

[0096] In some embodiments the peak temperature of the suspension or solution during the above mentioned step ii) is above 20° C., preferably above 40° C., in particular above 60° C., in particular preferred above 80° C. This may also be the peak temperature of the solvent and/or suspension or solution in a size classification unit comprising said solvent or suspension. In some embodiments in step ii) the suspension or solution has a peak temperature of at least 50° C., in particular of at least 80° C. In some embodiments, size classification is conducted at a peak temperature of 20 to 160° C., in particular of 40 to 140° C., preferably of 50 to 100° C. In some embodiments in the above mentioned step ii) the suspension or solution is heated to a peak temperature of 60 to 180° C.

[0097] In some embodiments purifying said suspension or solution comprises removing undissolved components of said suspension or solution by mechanical solid-liquid separation. In some embodiments the mechanical solid-liquid separation is achieved by a centrifuge. In some embodiments a sieve, in particular a metal sieve or ceramic sieve, may be used alternatively or additionally for mechanical solid-liquid separation.

[0098] In some embodiments said solid-liquid separation removes any particles that weigh more than 1000 mg, in particular more than 100 mg, preferably more than 10 mg. In some embodiments the solid-liquid separation removes any particles that weigh more than 50 mg, in particular more than 5 mg, preferably more than 1 mg. After solid-liquid separation the suspension preferably becomes a solution comprising the target polymer and solid particles.

[0099] In some embodiments said solid-liquid separation comprises removing at least 50% by weight (wt %), in particular at least 90% by weight, preferably 99% by weight, of any substances that have not been dissolved, preferably by centrifugation.

[0100] In some embodiments the centrifuge is a gastight centrifuge, in particular wherein the suspension may be centrifuged under gastight conditions. In some embodiments, solvent removal is performed under gastight conditions. In yet another embodiment, the recycling process is conducted under gastight conditions.

[0101] In some embodiments the oxygen content within the centrifuge is below 15% by weight, in particular below 10% by weight, preferably below 7% by weight, in particular preferred with respect to the total weight of the suspension within the centrifuge and/or with respect to the gas composition within the centrifuge.

[0102] In some embodiments, the solvent is a single organic solvent or a mixture comprising at least one organic solvent, preferably a mixture of two or more organic solvents.

[0103] In some embodiments, the solvent used to dissolve the target polymer is a single organic solvent or a mixture comprising at least one organic solvent, preferably a mixture of two or more organic solvents. In some embodiments, the solvent is a single organic solvent or a mixture of solvents comprising at least one organic solvent.

[0104] In some embodiments said organic solvents are aliphatic or aromatic hydrocarbons. In some embodiments, the solvent comprises aliphatic or aromatic hydrocarbons. They may be saturated or unsaturated. In some embodiments solvents comprise cyclic organic compounds. In one embodiment, solvents comprise organic acids comprising but not limited to formic acid and/or acetic acid. In one embodiment, the solvent comprises formic acid, acetic acid, ketones such as acetone or propanone and alcohols such as methanol or ethanol or polyols such as glycol or 2-propanol or mixtures thereof. In one embodiment, the solvent comprises formic acid, acetic acid, ketones such as acetone or propanone and alcohols such as methanol or ethanol or polyols such as glycol or 2-propanol, or mixtures thereof. The solvent is selected in such a way that the target polymer is dissolved. For polyethylene (PE), in particular low-density polyethylene (LDPE), heptane was found to be a particularly suitable solvent, in particular at 85 to 95° C. and/or at a pressure of 0.8 to 1.2 bar. For polyethylene (PE), in particular high-density polyethylene (HDPE), heptane was found to be a particularly suitable solvent, in particular at 105 to 115° C. and/or at a pressure of 1 to 2 bar. For polypropylene (PP) octane was found to be particularly suitable solvent, in particular at an average temperature of 125 to 135° C. For PVC acetone was found to be a particularly suitable solvent, in particular at an average temperature of 80 to 160° C. For polyamide (PA), in particular polyamide-6, propylene glycol was found to be a particularly suitable solvent, preferably at an average temperature of 80 to 160° C.

[0105] In some embodiments the solution or suspension contains 10 or more weight per cent of said target polymer with respect to the total weight of said solvent or mixture of solvents and the polymer that is dissolved.

[0106] In some embodiments a pressure which is lower than 6 bar, in particular less than 2 bar is applied to provide the solution or suspension. In some embodiments a pressure of 1 bar to 1.2 bar, in particular the atmospheric pressure (no extra pressure has to be applied in this case) is applied.

[0107] In some embodiments step ii) is conducted at a pressure of 0.5 bar to 5 bar, in particular 0.8 bar to 2 bar.

[0108] In some embodiments only a single target polymer is present. In other embodiments a blend of target polymers is produced and may be used for production of pellets.

[0109] In some embodiments the target polymer is low-density polyethylene (LDPE) and the solvent is selected from the group comprising alkanes, iso-alkanes and cyclic alkanes, and wherein if the solvent of LDPE is an alkane, said alkane preferably is n-heptane.

[0110] In some embodiments said target polymer is low-density polyethylene (LDPE) and said solvent is n-heptane.

[0111] In some embodiments the target polymer is polypropylene (PP) and said solvent is n-nonane.

[0112] In some embodiments the target polymer is polyamide (PA) and said solvent is propylene glycol.

[0113] In one embodiment, wherein the solvent is a mixture of solvents, the boiling point of the mixture of solvents may be referred to as the boiling point of the solvent with the lowest boiling point in a mixture of solvents.

[0114] In one embodiment, size classification, including filtration of the suspension or solution comprising the target polymer with said size classification unit is conducted at a temperature that is higher by >50 K, preferably higher by >75 K, most preferred higher by >100 K than the boiling point of the solvent, or the boiling point of the solvent with the lowest boiling point in a mixture of solvents. In one embodiment, filtration of the suspension or solution comprising the target polymer with said size classification unit is conducted at a temperature that is higher by >50 K, preferably higher by >75 K, most preferred higher by >100 K than the boiling point of the solvent; or the solvent with the lowest boiling point in a mixture of solvents, wherein the pressure is >30 bar, preferably >50 bar, most preferred >100 bar. In one embodiment, filtration of the suspension or solution comprising the target polymer with said size classification unit is conducted in an extruder at a temperature that is higher by >50 K, preferably higher by >75 K, most preferred higher by >100 K than the boiling point of the solvent, or the solvent with the lowest boiling point in a mixture of solvents, wherein the pressure is >30 bar, preferably >50 bar, most preferred >100 bar.

[0115] Preferably the solvent for the target polymer comprises at least 80% by weight of organic solvent, in particular at least 90% by weight of organic solvent, in particular preferred at least 95% by weight of organic solvent. The content of water in said solvent—if any—is preferably below 20% by weight, in particular below 10% by weight. In some embodiments the suspension or solution may also comprise a solvent with the above described composition.

[0116] Preferably the solvent for the target polymer comprises at least 60% by weight of organic solvent, in particular at least 80% by weight of organic solvent, in particular preferred at least 90% by weight of organic solvent. The content of water in said solvent—if any—is preferably below 40% by weight, in particular below 20% by weight, better below 10% by weight. In some embodiments the suspension or solution may also comprise a solvent with the above described composition.

[0117] In one embodiment, the method is a post-treatment step of a solvent-based recycling process for recycling plastic waste. In one embodiment, the method is a post-treatment step of a solvent-based recycling process for recycling plastic waste.

[0118] In one embodiment, the method is for recycling plastic waste and is carried out in a plastic waste recycling plant.

[0119] In some embodiments, the solvent obtained after step ii) is at least partially reused for dissolving target polymer to provide more suspension or solution comprising the dissolved target polymer. In some embodiments the solvent for reuse is purified by evaporation of the solvent and condensation and/or by distillation, wherein impurities are removed by evaporation and the solvent remains. Often the best approach depends on the boiling point of the solvent. However, in some embodiments purification is not necessary and the solvent may be reused directly, preferably if the same target polymer is targeted in subsequent rounds of dissolving polymers.

[0120] In some embodiments, the concentrated target polymer of step i) has the consistency of a gel. It may be then called a target polymer gel.

[0121] In some embodiments polymer pellets are formed in the above mentioned step ii). In some embodiments, products such as foils, pipes, bottles, pallets, lawn grids or building materials for houses are formed from said pellets or directly from concentrated target polymer obtained in step i) by blow molding, extrusion, pressing and/or injection molding.

[0122] In some embodiments step ii) comprises forming a polymer melt prior to extrusion and/or forming pellets or products using a pellet cutter after extrusion. Residual solvent is more efficiently removed from such a polymer melt.

[0123] In some embodiments separating said target polymer from the solution according to step ii) means that at least 50% by weight, in particular at least 75% by weight, preferably at least 90% by weight of the solvent is removed. In some embodiments at least 99% by weight of the solvent is removed. In some embodiments, if more than 60% by weight of the solvent is removed, the solvent removal up to and over 99% by weight is conducted by means of a degassing extruder.

[0124] In some embodiments of the method, wherein the method is for recycling plastic waste, at least 50% by weight, preferably at least 80%, by weight in particular 90% by weight, of the plastic waste is plastic, wherein said plastic also includes the target polymer. In some embodiments at least 50% by weight, preferably at least 80%, by weight in particular 90% by weight, of the plastic waste is the target polymer. In some embodiments at least up to 10% by weight, preferably up to 20% by weight, in particular up to 50% by weight of the plastic waste is plastic.

[0125] In a preferred embodiment the plastic waste is made to at least 80% by weight, preferably to at least 90% by weight, of said target polymer, in particular a single polymer or a mixture of two or three polymers.

[0126] Alternatively or additionally according to some embodiments providing a suspension or solution comprising a target polymer may be preceded by washing of plastic waste prior to insertion of the plastic waste into the solvent, e.g. washing with water. Washing removes some impurities. In some embodiments washing is performed by means of contacting said material with a liquid to produce a suspension with subsequent purifying the obtained suspension, in particular by means of mechanical solid-liquid separation. In some embodiments said liquid is water. In some embodiments washing may comprise washing with water at an average temperature of more than 40° C., in particular more than 80° C. Also washing with water may be conducted using a friction washer, in particular wherein a rotor transports plastic waste and/or water is transported in opposite direction to the plastic waste. Friction by rotors and water remove impurities. In some embodiments there is no such step with a friction washer and the shredded plastic waste is used directly. This may be the case if plastic waste from post-industrial residues is recycled. With plastic waste from consumer products often said washing step is advantageous.

[0127] According to some embodiments, providing a suspension or solution comprising the target polymer is achieved by downsizing plastic waste comprising the target polymer prior to insertion of said plastic material into said solvent or said mixture of solvents. Downsizing improves speed and/or completeness of dissolving of the target polymer, if the target polymer is obtained from plastic waste. In one embodiment, downsizing is shredding or cutting, or combinations thereof. Devices for downsizing plastic waste are known in the state of the art. In one embodiment, downsizing may be dust-poor or dust-free downsizing, wherein dust-poor means that up to 99 wt % of the plastic waste to be dissolved may be >100 μm, particularly >300 μm in diameter.

[0128] In some embodiments said plastic waste contains polyethylene (PE) and aluminum, preferably polyethylene, aluminum and paper. In some embodiments at least 60% by weight, in particular at least 80% by weight, preferably at least 90% by weight, of the plastic waste consists of said materials.

[0129] In some embodiments the plastic waste is at least partially obtained from packaging materials and/or foils. In some embodiments at least 60% by weight, in particular at least 80% by weight, preferably at least 90% by weight, of the plastic waste consists of packaging materials and/or foils.

[0130] In some embodiments said plastic waste is at least partially obtained from car parts. In some of said embodiments at least 60% by weight, in particular at least 80% by weight, preferably at least 90% by weight, of the plastic waste consists of car parts.

[0131] In some further embodiments the plastic waste comprises at least one type of object selected from a group consisting of cans, cups, foils, collapsible tubes, plastic bags. In some embodiments the plastic waste is mixed waste comprising at least two or three types of objects selected from a group consisting of cans, cups, foils, collapsible tubes, plastic bags. Said types of objects preferably constitute at least 20% by weight, in particular at least 40% by weight, preferably at least 60% by weight, of the total weight of said plastic waste.

[0132] In one embodiment, the invention relates to an integrated size classification and extrusion step, optionally comprising degassing with a degassing unit that is integrated into a plastic waste recycling method comprising a plastic waste recycling plant.

[0133] In one embodiment, the plastic waste recycling plant comprises the following stations: [0134] a. a station that comprises a downsizing device for plastic waste, that optionally is a cutting or shredding device for plastic waste, and optionally a plastic particle size classification device for classifying the downsized plastic waste; [0135] b. optionally a station for washing the downsized, optionally classified plastic waste produced in station a.); [0136] c. a station that comprises a vessel, wherein the vessel comprises an agitator and/or a heating system and/or an organic solvent for dissolving the at least one target polymer derived from the downsized, optionally classified plastic waste produced in station a.), or the optionally washed plastic waste produced in station b.); [0137] d. optionally a station that comprises a centrifuge for solid-liquid separation; [0138] e. a station comprising an extruder with a size classification unit, wherein the size classification unit is permeable for the solvent and impermeable for the target polymer, and wherein the extruder with size classification unit is used for size classification and extrusion of the target polymer, wherein the extruder comprises a degassing unit and optionally a heating unit, wherein said extruder optionally produces plastic pellets; [0139] wherein the plastic waste recycling plant has a transfer system that transfers materials from each station to the next in the above listed order.

[0140] Optional stations are not implemented in some embodiments and if they are not, the transfer system transfers to the next station that is implemented. Also additional stations that are not described explicitly may be implemented.

[0141] The vessel comprises a solvent and/or an agitator for stirring the waste. The agitator may be connected to said vessel and/or it may be disposed in said vessel. The vessel may in some embodiments be a tank, in particular a closed tank. The vessel may be a tank with a volume of 1 m.sup.3 to 100 m.sup.3, in particular of 5 m.sup.3 to 50 m.sup.3, in particular preferred of 20 m.sup.3 to 40 m.sup.3.

[0142] Preferably, the plastic waste recycling system is adapted for implementing the method as described above.

[0143] Preferably, the vessel comprises an organic solvent for dissolving plastic waste at least partially.

[0144] In one embodiment, the vessel comprises a mixture of solvents, comprising at least one organic solvent for dissolving plastic waste at least partially.

[0145] Any devices that are used for the method as described above may preferably be also part of the plastic waste recycling system.

[0146] The invention also relates to the use of the above described plastic waste recycling system for implementing the method as described above.

[0147] In some embodiments the thermoplastic target polymer precipitates during size classification.

[0148] In some embodiments only a single thermoplastic target polymer is present. In other embodiments a blend of thermoplastic target polymers is produced and may be used for production of pellets.

[0149] In some embodiments the pressure differential across the inner enclosure that comprises the size classification unit is at least 0.1 to 5 bar, preferably 1 to 4 bar, in particularly preferred 2 to 3 bar. In another embodiment, the pressure differential across the inner enclosure that comprises the size classification unit is determined by the pressure that is present in the plastic extruder during extrusion. In another embodiment, the pressure differential across the inner enclosure that comprises the size classification unit is >30 bar, preferably >50 bar, most preferred >100 bar.

[0150] Preferably size classification is conducted at an average temperature of less than 180° C. In some embodiments, size classification is conducted at an average temperature of 20 to 180° C., in particular of 60 to 160° C., in particular preferred of 80 to 120° C.

[0151] In some embodiments, size classification is performed by using progressively more retentive membranes, in particular microfiltration membranes and ultrafiltration membranes. In one embodiment a microfiltration membrane with a pore size of 100-300 kDa may be used.

[0152] In some further embodiments the size classification is a continuous process, wherein continuous means that the size classification step that is part of a solvent removal process of a solution or suspension comprising a target polymer, does not require the temporal or spatial interruption of any preceding or following process that is part of a polymer recycling method, particularly a recycling method that is subject matter of the present invention.

[0153] In some further embodiments the size classification is a continuous process, wherein several membranes are used in series, in particular at least one microfiltration membrane and at least one ultrafiltration membrane.

[0154] In some further embodiments the size classification is a variable pressure filtration by using a single membrane or several membranes and varying the applied pressures, in particular by using a single membrane, preferably an ultrafiltration membrane.

[0155] These techniques sometimes also can be combined, e.g. a cross-size classification technique that uses several membranes in series and with variable pressures.

[0156] In some embodiments the above mentioned steps i) and/or ii) are conducted in an environment containing less than 15% by weight of oxygen, in particular less than 5% by weight of oxygen, preferably less than 1% by weight of oxygen, in particular within the liquid and/or gaseous phase. Not all steps have to contain a gaseous and a liquid phase environment.

[0157] In some embodiments the solvent that is obtained after performing step ii) is at least partially reused for dissolving target polymer with the objective to provide more suspension or solution comprising the dissolved target polymer. In some embodiments, the solvent for reuse is purified by evaporation of the solvent and condensation and/or by distillation, wherein impurities are removed by evaporation and the solvent remains. Often the best approach depends on the boiling point of the solvent. However, in some embodiments purification is not necessary and the solvent may be reused directly, without evaporation of the solvent and condensation and/or by distillation, wherein optionally the solvent purification for solvent reuse in subsequent recycling is omitted if the dissolved target polymer used in a previous cycle of size classification is identical to the dissolved target polymer in a subsequent cycle of size classification, wherein a cycle of size classification consists of the provision of the suspension or solution comprising the target polymer, the delivery of the suspension or solution comprising the target polymer to an extruder, the size classification of the suspension or solution comprising the target polymer in an extruder comprising a size classification unit, optionally degassing using a degassing unit, and solvent retrieval by a solvent retrieval unit.

[0158] The solvent retrieval unit collects the solvent traversing the pores of the size classification unit of the extruder, and optionally, if the filtered solvent is to be purified by evaporating and/or distilling the collected solvent using a solvent purification unit, passes it to said solvent purification unit.

[0159] In one embodiment, solvent removal, collection and purification are performed in a continuous mode. In one embodiment, solvent removal, collection and purification are performed in a continuous mode, wherein continuity of the process is ensured by immediate transfer of solvents from one station to the next, without the need for physical interruption. In some embodiments, at least partially removing solvent means that at least 50% by weight, in particular at least 75% by weight, preferably at least 90% by weight of the solvent is removed, wherein if a solvent removal of more than 60% is to be performed, solvent removal further includes the use of a degassing unit, comprising a degassing extruder.

[0160] In some embodiments at least 99% by weight of the solvent is removed by the method in accordance with the invention, wherein said method comprises a degassing step, optionally performed with a degassing extruder.

[0161] The method may be used for at least partially removing of solvent from any kind of solution comprising the target polymer. However, it was found that the method is very robust with respect to removing impurities and may be adapted to isolate a target polymer from plastic waste, i.e. for recycling plastic waste comprising target polymer. Therefore, in some embodiments the method for at least partially removing a solvent is part of a method for recycling plastic waste comprising a target polymer and plastic waste comprising the target polymer is at least partially dissolved in the solvent, in particular using an agitator and/or a heating system. The plastic waste may be immersed in the solvent dissolving the target polymer in said solvent. Surprisingly impurities that are present in said plastic waste do not prevent that size classification can be efficiently conducted. Said method for recycling plastic waste is suitable for any kind of plastic waste comprising a thermoplastic target polymer.

[0162] It is possible that the plastic waste is sorted before dissolving in a solvent in and providing a target polymer in a suspension or solution may comprise sorting said plastic waste. However, in some embodiments mixed plastic waste is used and little or no sorting is done.

[0163] In one embodiment, removing solvent in step ii) by size classification and extrusion, optionally comprising degassing with a degassing unit such as a degassing extruder, does not preclude the presence of small residues of solvent in the polymer product. However, most of the remaining solvent is removed, in particular at least 70% by weight, preferably at least 85% by weight, in particular preferred at least 95% by weight of any remaining solvent, more particularly at least 99% by weight of any remaining solvent.

[0164] Preferably the plastic waste recycling plant is adapted for implementing the method as described above.

[0165] Preferably the vessel comprises an organic solvent for dissolving plastic waste at least partially.

[0166] Any devices that are used for the method as described above may preferably be also part of the plastic waste recycling plant, e.g. the vessel as described for the method of the specifics of the membrane.

[0167] The invention also relates to the use of the above described plastic waste recycling plant for recycling a target polymer from plastic waste by dissolving said target polymer in a solvent comprising at least one organic solvent, and retrieval of said target polymer from the solvent comprising at least one organic solvent.

[0168] The invention also relates to the use of a size classification unit with an extruder for at least partially removing solvent from a suspension or solution comprising dissolved polymer, preferably using the type size classification unit with an extruder that is described in this disclosure.

[0169] The invention also relates to the use of a size classification unit with an extruder and/or size classification unit with an extruder for recycling of plastic waste, in particular municipal solid waste, preferably using the type of size classification unit that is described in this disclosure and/or for the type and/or composition of plastic waste that is described in this disclosure.

[0170] With the above context, the following consecutively numbered embodiments provide further specific aspects of the invention: [0171] 1. A continuous method for removing a solvent from a suspension or solution comprising a target polymer, wherein the method comprises the following steps: [0172] (i) delivering said suspension or solution to an extruder, wherein said extruder comprises a size classification unit that is designed to be permeable for the solvent and impermeable for the target polymer; and [0173] (ii) filtration and extrusion of said suspension or solution in said extruder. [0174] 2. The method according to embodiment 1, wherein the size classification unit is a membrane or sieve. [0175] 3. The method according to embodiment 1 or 2, wherein the extruder further comprises a degassing unit. [0176] 4. Method according to embodiment 3, wherein the degassing unit is used for essentially complete degassing of the target polymer in solution or suspension, wherein essentially complete degassing means that ≤1 wt % (≤10000 ppm), preferably ≤0.1 wt % (≤1000 ppm) of solvent is present after the essentially complete degassing. [0177] 5. The method according to any one of embodiments 1 to 4, wherein the filtration of said suspension or solution is performed during extrusion and/or degassing in said extruder comprising the classification unit. [0178] 6. The method according to any one of embodiments 1 to 5, wherein the extruder comprises an inner and an outer enclosure, wherein the inner enclosure further comprises a size classification unit that is impermeable to the target polymer and therefore allows the solvent to exit the inner enclosure and the target polymer to remain inside the inner enclosure, thereby allowing filtration of the suspension or solution through said size classification unit in the extruder. [0179] 7. The method according to any one of embodiments 1 to 6, wherein up to 5%, preferably up to 10%, more preferably up to 20%, more preferably up to 30%, more preferably up to 40%, even more preferably up to 50%, most preferably up to 60% of solvent is removed from said solution or suspension. [0180] 8. The method according to embodiment 2, wherein the membrane or sieve is designed to be impermeable for target polymers with an average molecular mass of 1000 kDa or more, in particular target polymers with an average molecular mass of 500 kDa or more, in particular preferred target polymers with an average molecular mass of 200 kDa or more. [0181] 9. The method according to embodiment 2 or 8, wherein the size classification unit is a membrane, and wherein a material of the membrane is selected from a group consisting of polyamide membrane, polyvinylidene difluoride membrane, polyethersulfone membrane, polysulfone membrane, polydimethylsiloxane membrane, polypropylene membrane, or a combination thereof. [0182] 10. The method according to embodiment 2 or 8, wherein the size classification unit is a sieve, wherein the sieve is made of a material comprising metal and/or ceramics. [0183] 11. The method according to any one of embodiments 1 to 10, wherein the filtration is driven by a pressure differential across the size classification unit, wherein the pressure differential is >30 bar, preferably >50 bar, most preferred >100 bar. [0184] 12. The method according to embodiment 11, wherein the pressure differential is achieved by a vacuum pumping system aided with heating, wherein heating refers to a temperature not exceeding a maximal temperature of 5K, particularly 10K below the boiling point of the solvent, or the solvent with the lowest boiling point in a mixture of solvents. [0185] 13. The method according to any one of embodiments 1 to 12, wherein the target polymer is a thermoplastic target polymer. [0186] 14. The method according to any one of embodiments 1 to 13, wherein the target polymer is derived from polymers selected from the group comprising post-consumer use polymers, post-industrial use polymers and combinations thereof. [0187] 15. The method according to any one of embodiments 1 to 14, wherein the target polymer is selected from the group comprising polyolefins, polyamide (PA) and combinations thereof. [0188] 16. The method according to any of embodiments 1 to 15, wherein the target polymer is a polyolefin. [0189] 17. The method according to embodiment 16, wherein the target polymer is low-density polyethylene (LDPE). [0190] 18. The method according to embodiment 16, wherein the target polymer is polypropylene (PP). [0191] 19. The method according to embodiment 16, wherein the target polymer is polyamide (PA). [0192] 20. The method according to any of embodiments 1 to 19, wherein the solvent is a single organic solvent or a mixture of solvents comprising at least one organic solvent. [0193] 21. The method according to any one of embodiments 1 to 20, wherein the solvent comprises aliphatic or aromatic hydrocarbons. [0194] 22. The method according to any one of embodiments 1 to 21, wherein the solvent comprises formic acid, acetic acid, ketones such as acetone or propanone and alcohols such as methanol or ethanol or polyols such as glycol or 2-propanol or mixtures thereof. [0195] 23. The method according to any one of embodiments 1 to 22, wherein the target polymer is low-density polyethylene (LDPE) and the solvent is selected from the group comprising alkanes, iso-alkanes and cyclic alkanes, and wherein if the solvent of LDPE is an alkane, said alkane preferably is n-heptane. [0196] 24. The method according to any one of embodiments 1 to 23, wherein the target polymer is polypropylene (PP) and the solvent is n-nonane. [0197] 25. The method according to any one of embodiments 1 to 24, wherein the target polymer is polyamide (PA) and the solvent is propylene glycol. [0198] 26. The method according to any one of embodiments 1 to 25, wherein filtration of the suspension or solution comprising the target polymer with said size classification unit is conducted at a temperature that is higher by >50 K, preferably higher by >75 K, most preferred higher by >100 K than the boiling point of the solvent, or the solvent with the lowest boiling point in a mixture of solvents. [0199] 27. The method according to any one of embodiments 1 to 26, wherein the method is a post-treatment step of a solvent-based recycling process for recycling plastic waste. [0200] 28. The method according to any one of embodiments 1 to 27, wherein the method is for recycling plastic waste and is carried out in a plastic waste recycling plant. [0201] 29. Plastic waste recycling plant, in particular for implementing the method according to any of embodiments 1 to 28, comprising the following stations: [0202] a) a station that comprises a downsizing device for plastic waste, that optionally is a cutting or shredding device for plastic waste, and optionally a plastic particle size classification device for classifying the downsized plastic waste; [0203] b) optionally a station for washing the downsized, optionally classified plastic waste produced in station a); [0204] c) a station that comprises a vessel, wherein the vessel comprises an agitator and/or a heating system and/or an organic solvent for dissolving the at least one target polymer derived from the downsized, optionally classified plastic waste produced in station a), or the optionally washed plastic waste produced in station b); [0205] d) optionally a station that comprises a centrifuge for solid-liquid separation; [0206] e) a station comprising an extruder with a size classification unit, wherein the size classification unit is permeable for the solvent and impermeable for the target polymer, and wherein the extruder with size classification unit is used for size classification and extrusion of the target polymer, wherein the extruder comprises a degassing unit and optionally a heating unit, wherein said extruder optionally produces plastic pellets; [0207] wherein the plastic waste recycling plant has a transfer system that transfers materials from each station to the next in the above listed order.

Definitions

[0208] Listed below are definitions of various terms used to describe this invention. These definitions apply to the terms as they are used throughout this specification and claims unless otherwise limited in specific instances either individually or as part of a larger group. Unless defined otherwise all technical and scientific terms used herein generally have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.

[0209] As used herein the articles “a” and “an” refer to one or to more than one (i.e. to at least one) of the grammatical object of the article. By way of example, “an element” means at least one element, i.e. an element or more than one element. This applies in particular also for “a target polymer” and “a solvent” as discussed below.

[0210] As used herein the term “average temperature” refers to a temperature that is averaged over time, preferably over the duration of the corresponding step. In a continuous system the duration of a step refers to the average time of the waste material under the conditions as described for said step. There may be location dependent variations within the solvent that can be reduced by stirring. In said case the temperature should also be averaged over said locations to determine the average temperature. With sufficient stirring the average temperature usually is only location dependent to a small degree and the average temperature can be determined by measuring in one spot for the duration of a step.

[0211] As used herein the term “peak temperature” refers to a maximum temperature that is achieved during a step. It may be determined by continuously monitoring the temperature and selecting the maximum temperature. For example with a batchwise implementation of steps the temperature may drop, e.g. when cold plastic waste is inserted into the solvent. A heating system may heat the vessel to achieve said peak temperature before the solvent is lead to the next step. In a continuous system the temperature may be constant and there often is no difference between “average temperature” and “peak temperature”. There also may be location dependent variations within the solvent and in said case the temperature may be averaged over said locations (not over time) to determine the peak temperature.

[0212] As used herein the term “solvent” refers to a single solvent or a mixture of different solvents. A single solvent may facilitate recovery whereas a mixture may reduce the use of toxic solvents or accelerate dissolution of a polymer.

[0213] As used herein the term “target polymer” refers to a single polymer or a mixture of different polymers. Polymers also include copolymers and block polymers. Often a mixture of polymers cannot be avoided completely. Preferably the term “target polymer” refers to a single polymer or a mixture of different polymers that are dissolvable in the solvent and may be used for producing polymer pellets. In some instances “target polymer” refers to a mixture of one, two or three polymers as a major component, wherein impurities are possible that have a weight of less than 5% by weight (wt %) compared to the total weight of the target polymer. Furthermore, use of the term “target polymer” is to be understood in the above way also when “a target polymer”, “the target polymer” or “said target polymer” is mentioned unless it is explicitly stated that it is only a single polymer or a mixture of different polymers, i.e. “a target polymer” is “at least one target polymer”; “the target polymer” is “the at least one target polymer” and “said target polymer” is “said at least one target polymer” unless stated otherwise. A non-target polymer may also be a polymer that is not dissolvable in the used solvent and it may be removed by solid-liquid separation.

[0214] As used herein the term “several” refers to two, three, four or more entities, preferably two or three entities.

[0215] As used herein the term “plastic waste” refers to waste comprising plastic. Preferably plastic waste is any substance that is discarded after primary use, and/or has been discarded, e.g. because it is defective. In some embodiments the “plastic waste” is solid. In some embodiments “plastic waste” refers to municipal solid waste, in particular comprising everyday items that are discarded by the public. In some embodiments “plastic waste” refers to post-consumer use polymers, post-industrial use polymers and combinations thereof.

[0216] As used herein the term “mixed plastic waste” refers to plastic waste containing different kinds of plastic objects. Often plastic is sorted before it is used, e.g. only plastic bags are provided or only plastic foils. This usually requires a sorting of plastic. In some instances mixed plastic waste is municipal plastic waste as obtained from households, i.e. plastic bags, plastic packaging, plastic tubes and such can be mixed. It was found that mixed plastic waste can be used to produce polymer in accordance with the invention without need of collection in groups of identical materials and/or objects.

[0217] As used herein the term “essentially soluble” with respect to the target polymer refers to the solubility of said target polymer in said solvent or said mixture of solvents in an amount not less than 5 wt %, more preferably not less than 7 wt %, in particular not less than 10 wt %, with respect to the total weight of said solvent or mixture of solvents and the of polymer that is dissolved.

[0218] As used herein the term “essentially insoluble” with respect to the additive refers to the solubility of said target polymer in said solvent or said mixture of solvents an amount of less than 1 wt %, in particular less than 0.1 wt %, with respect to the total weight of said solvent or mixture of solvents and the of polymer that is dissolved.

[0219] As used herein the term “non-solvent” with respect to said extractant refers to the solubility of said target polymer in said extractant an amount of less than 1 wt %, in particular less than 0.5 wt %, with respect to the total weight of the extractant and the polymer that is dissolved.

[0220] As used herein the term “extractant” refers to a liquid which is a non-solvent for the target polymer.

[0221] As used herein the term “alkanes” refers to straight chain hydrocarbons having from 5 to 20 carbon atoms, typically from 5 to 12 carbon atoms. Examples include, but are not limited to n-hexane, n-heptane, n-octane and n-nonane.

[0222] As used herein the term “iso-alkanes” refers to branched chain hydrocarbons having from 5 to 20 carbon atoms, typically from 5 to 12 carbon atoms. Examples include, but not limited to isooctane.

[0223] As used herein the term “cyclic alkanes” refers to cyclic, saturated hydrocarbons wherein each of the atoms forming the ring (i.e. skeletal atoms) is a carbon atom. Cyclic alkanes may be optionally substituted by an alkyl group having from 1 to 4 carbon atoms. Examples include, but not limited to cyclohexane, methylcyclohexane.

[0224] As used herein the term “ketones” refers to organic compounds having a carbonyl group linked to a carbon atom. Examples include, but not limited to acetone, butanone.

[0225] As used herein the term “organic acids” refers to organic compounds having a functional group of formula C(═O)OH. Examples include, but not limited to formic acid, acetic acid.

[0226] As used herein the term “ester” refers to organic compounds having a functional group of formula C(═O)OR, wherein R represents an alkyl group. Examples include, but not limited to ethylacetate, benzylacetate.

[0227] The “number average molecular weight” is preferably the total weight of the respective polymer sample, e.g. the target polymer, divided by the number of polymer molecules in the sample. The “average molecular mass” may be determined according to ISO 16014-1:2012 and/or ISO 16014-2:2012, preferably by ISO 16014-1:2012.

[0228] The terms “virgin polymer”, “virgin-like” or “virgin-grade polymer” refer to different grades of purity of a solid polymer, or plastic product comprising a certain target polymer. In the context of the present invention, the term “virgin polymer” or “virgin-grade polymer” refers to >95 wt %, preferably >99 wt %, most preferred 100 wt % of target polymer. The term “virgin-like polymer” refers to >90 wt %, preferably >95 wt %, most preferred >99 wt % target polymer.

[0229] The terms “filtration” and “size classification” in general refer to a process that separates larger entities from smaller entities, or vice-versa, by passing entities with a size distribution across a barrier with defined size exclusion properties, allowing smaller entities to pass, whereas larger entities are retained by the barrier. In the context of the present invention, size classification refers to classification of polymer entities with a certain size distribution, wherein it is one objective of the present invention to separate target polymer from non-target polymer entities, based on size, thereby allowing solvents and impurities to be separated from the polymer. The terms “filtration” and “size classification” may be used interchangeably according to the subject matter of the invention, if a solution or suspension is passed across a barrier with defined size exclusion properties. Another example of size classification is the process of “solid-liquid separation”, in which undissolved entities are mechanically separated from dissolved entities, wherein undissolved entities are larger than dissolved entities, thereby representing a size classification process.

[0230] In the context of the present invention “impurity” refers to any molecule or entity that is not meant to be a part of the product produced by the method that is subject matter of the present invention. More specifically, if the product is meant to be a polymer, then anything apart from the polymer is classified as an impurity. If the product is meant to be a polymer with certain additives, then anything apart from the polymer with certain additives is classified as an impurity. Another example would be if the product is meant to contain a polymer of certain length, and/or branching, or a certain distribution thereof, optionally further comprising certain additives, then anything that does not form part of polymer of certain length, and/or branching, or a certain distribution thereof, optionally further comprising certain additives, is to be considered as “impurity”. The definition as to what is considered an impurity thus depends on what the person skilled in the art does not consider a defining constituent of the particular product.

[0231] The term “size classification unit” refers to a physical unit or entity used in a size classification process, wherein the size classification unit is capable of mediating the process of size classification, as defined above.

[0232] “Polymer stabilizers” are chemical molecules capable of increasing the strength, resilience, durability, or resistance to external factors, wherein said polymer stabilizers specifically prevent the disintegration of polymer chains within a polymer structure.

[0233] “Gastight” means that at least 95%, preferably at least 99%, most preferred 100% of volume remains enclosed in a particular enclosure that is sealed from the surrounding environment. In the context of the present invention, a pipe comprising an organic solution or suspension with a highly volatile and flammable solvent may be enclosed in a gastight enclosure with low oxygen concentration, in order to prevent contact with the oxygen of the atmosphere that is surrounding said enclosure, in order to reduce the risk of combustion.

[0234] An “extruder” means any plastic extruder known from the prior art. This may also include degassing extruders. However, if the term “degassing extruder” is used, then plastic extruders without the capability for degassing are excluded. Degassing extruders are also known from the prior art.

[0235] The term “downsizing” refers to any process that reduces the size of a physical entity. In the context of the present invention, downsizing specifically refers to the size reduction of plastic material, and in some examples comprises shredding or cutting of plastic material.

EXAMPLES

Example 1

[0236] Equipment (depicted on FIG. 2): [0237] a. Twin screw extruder [0238] i. 4 heatable segments equipped with heating tapes [0239] ii. Temperature sensors [0240] iii. Dosing stations: between Segment 1 and Segment 2, Segment 2 and Segment 3. [0241] iv. Screw design, that enables the melt to seal between the segments [0242] v. Segment 1 is melting zone [0243] vi. Segment 2 is the membrane segment [0244] vii. Segment 3 is mixing zone [0245] viii. Segment 4 is degassing zone [0246] ix. Each segment is equipped with sight glass [0247] x. 3-way melt valve [0248] xi. Pelletizing unit [0249] xii. Electric motor [0250] xiii. Dosing funnel [0251] b. 2 melt pumps [0252] c. 2 solvent pumps [0253] d. Vacuum system [0254] i. Vacuum pump [0255] ii. Condenser [0256] iii. Vessel [0257] iv. Valve

[0258] Process: [0259] a. The extruder was pre-heated for standard LDPE extrusion (210-220° C., each segment). [0260] b. The vacuum pump was switched on and the pressure of 300 mbar was reached in segment 4 with a closed valve. [0261] c. 10 kg of LDPE virgin granulates were weighed and transferred to the extruder via the dosing funnel. [0262] d. 4.3 kg of n-heptane were weighed and transferred into a vessel. [0263] e. Extrusion was started and LDPE was melted within Segment 1 of the extruder. Melt was observed via sight glasses. [0264] f. When the melt reached Segment 2, observed via sight glass, solvent pump 2 was switched on. [0265] g. LDPE-melt and n-heptane were mixed in Segment 3. [0266] h. The 3-way melt valve was opened to the position which enabled transporting the polymer solution obtained in step g to melt pump 1. [0267] i. Melt pump 1 was switched on to transfer the polymer solution into Segment 2. [0268] j. Solvent pump 1 was switched on. The permeate was collected into a vessel. [0269] k. The valve of the vacuum system was opened to enable degassing the melt in Segment 4. [0270] l. The 3-way-melt valve was switched to the position which enabled transporting the melt to melt pump 2. [0271] m. Melt pump 2 was switched on to transport the melt to the pelletizing unit. [0272] n. LDPE was pelletized and collected into an octabin. [0273] o. When no further pelletized material was observed, the system was shut down. [0274] The amount of collected permeate (n-heptane) was 1.9 kg what corresponds to 19 mol. The evaporation enthalpy of n-heptane is 32 kJ/mol. The amount of saved energy is hence 608 kJ.

Example 2

[0275] Equipment (depicted on FIG. 3): [0276] a. Twin screw extruder [0277] i. 2 heatable segments equipped with heating tapes [0278] ii. Temperature sensors [0279] iii. Screw design, that enables the melt to seal between the segments [0280] iv. Segment 1 is the membrane segment [0281] v. Segment 2 is degassing zone [0282] vi. Each segment is equipped with sight glass [0283] vii. Pelletizing unit [0284] viii. Electric motor [0285] b. Melt pump [0286] c. Solvent pump [0287] d. Vacuum system [0288] i. Vacuum pump [0289] ii. Condenser [0290] iii. Vessel [0291] iv. Valve

[0292] Process: [0293] a. The extruder is pre-heated for standard LDPE extrusion (210-220° C., each segment). [0294] b. The vacuum pump is switched on and the pressure of 300 mbar is reached in segment 2 with a closed valve. [0295] c. The LDPE solution in n-heptane is transferred into Segment 1 of the extruder via the dosing funnel. [0296] d. The solvent pump is switched on. The permeate is collected into a vessel. [0297] e. The valve of the vacuum system is opened to enable degassing the melt in Segment 2. [0298] f. The melt pump is switched on to transport the melt to the pelletizing unit. [0299] g. LDPE is pelletized and collected into an octabin.

Example 3

[0300] Tested Membranes

[0301] The polyvinylidene difluoride (PVDF) membrane from Carl Roth, the polyethersulfone (PES) MF membrane from Millipore, and the polyamide (PA) membrane from Whatman were used.

[0302] Concentrating the LDPE Solution

[0303] The LDPE solutions in methylcyclohexane (2 mL) were filtered in various membrane reactors with the selected membranes. The temperature control (95° C.) was carried out by means of a suitably heated water bath into which the reactor was immersed. The filtration time was 1 hour and the pressure (nitrogen) applied was 5 bar. After one hour, the residual concentration of the solvent in the retentate was determined and the concentration of the solution was calculated. The results for 10 wt % LDPE solutions are shown in Table 1.

TABLE-US-00001 TABLE 1 Results of concentrating the 10 wt % LDPE solutions Membrane Final concentration of the LDPE (+ modification) solution in the retentate [% by weight] PA 26 ± 2 PVDF 27 ± 3 PES 38 ± 1

[0304] The results show that a starting 10% LDPE solution can be concentrated to a final concentration of up to 38%.

[0305] In addition, the filtration experiments with LDPE solutions with a lower concentration (2 or 5% by weight) were carried out using the membranes. The results are summarized in Table 2.

TABLE-US-00002 TABLE 2 Results of concentrating the 10 wt %, 5 wt % and 2 wt % LDPE solutions Final concentration of the LDPE solution in the retentate [% by weight] Start conc. Start conc. Start conc. 10% by 5% by 2% by Membrane weight weight weight PA 26 13 11 PVDF 27 24 28 PES 38 39 20

DESCRIPTION OF FIGURES

[0306] FIG. 1 shows a plastic waste recycling plant 100 comprising several stations. The plastic waste recycling plant is only a possible implementation for the method. Also plastic production plants for producing polymers by polymerization may use the described method. A shredding device 108 for plastic waste 109 is comprised in a first station 101. Said plastic waste may be transported by a first conveyor belt 110 into the shredding device 108 and by a second conveyor belt 112 shredded plastic wastes 111 may be transported out of the shredding device 108. Preferably in some embodiments the plastic waste recycling plant 100 comprises a second station 102 for washing the shredded plastic waste 111. Said second station 102 may comprise a container 113 with a washing liquid 114 such as water, wherein shredded plastic waste 111 is purified. The purified shredded plastic waste 111 may be transported, e.g. by another conveyor belt 124, to a third station 103 comprising a vessel 115, wherein the vessel 115 comprises an agitator 117 and/or a heating system, e.g. as part of the vessel 115. In some embodiments the shredded plastic waste 111 is directly transported from the first station 101 to the third station 103. The third station preferably contains a solvent 116, wherein the target polymer is dissolved in said solvent thus forming a solution or a suspension 119. A fourth station 104 may comprise a centrifuge 118 for solid-liquid separation. A fifth station 105 comprises an extruder with membrane 120 for extrusion of the liquefied polymer mass comprising the target polymer optionally for the production of polymer pellets 123.

[0307] FIG. 2 shows unit 120 (a twin-screw extruder with a membrane) as of Example 1 in a more detail.

[0308] FIG. 3 shows unit 120 (a twin-screw extruder with a membrane) as of Example 2 in a more detail.