PHOTOACOUSTIC GAS SENSOR DEVICE
20220236230 · 2022-07-28
Inventors
- Christophe SALZMANN (Stäfa, CH)
- Werner HUNZIKER (US)
- Stephan BRAUN (Stäfa, CH)
- David PUSTAN (Stäfa, CH)
- Thomas UEHLINGER (Stäfa, CH)
Cpc classification
G01N29/42
PHYSICS
G01N2291/02809
PHYSICS
G01N29/30
PHYSICS
G01N29/32
PHYSICS
G01N21/1702
PHYSICS
International classification
G01N29/22
PHYSICS
G01N21/17
PHYSICS
G01N29/32
PHYSICS
Abstract
A photoacoustic gas sensor device for deter-mining a value indicative of a presence or a concentration of a component in a gas comprises a substrate and a measurement cell body, the substrate and the measurement cell body defining a measurement cell enclosing a measurement volume. A reflective shield divides the measurement volume into a first volume and a second volume. An opening in the measurement cell is provided for a gas to enter the measurement volume. In the first volume and on a front side of the substrate are arranged: An electromagnetic radiation source for emitting electromagnetic radiation through an aperture in the reflective shield into the second volume; and a pressure transducer communicatively coupled to the second volume for measuring a sound wave generated by the component in response to an absorption of electromagnetic radiation by the component. At least a portion of a surface of the reflective shield facing the second volume is made of a material reflecting electromagnetic radiation.
Claims
1. Photoacoustic gas sensor device, for determining a value indicative of a presence or a concentration of a component in a gas, the photoacoustic gas sensor device comprising: a substrate, a measurement cell body, the substrate and the measurement cell body defining a measurement cell enclosing a measurement volume, a reflective shield dividing the measurement volume into a first volume and a second volume, an opening in the measurement cell for a gas to enter the measurement volume, arranged in the first volume and on a front side of the substrate: an electromagnetic radiation source for emitting electromagnetic radiation through an aperture in the reflective shield into the second volume, a pressure transducer communicatively coupled to the second volume for measuring a sound wave generated by the component in response to an absorption of electromagnetic radiation by the component, wherein at least a portion of a surface of the reflective shield facing the second volume is made of a material reflecting electromagnetic radiation.
2. Photoacoustic gas sensor device according to claim 1, wherein at least the major portion of the surface of the reflective shield facing the second volume is made of the reflective material, in particular wherein the entire surface of the reflective shield facing the second volume is made of the reflective material, in particular wherein the reflective material is coated on a core of the reflective shield, in particular wherein the reflective shield is made of the reflective material, in particular wherein an inner surface of the measurement cell body facing the second volume is made of the or another reflective material, in particular wherein the reflective material is coated on a core of the measurement cell body, in particular wherein the measurement cell body is made of the reflective material, in particular wherein the reflective material is a metal or a metal-filled polymer, in particular wherein the inner surface of the measurement cell body facing the second volume and the surface of the reflective shield facing the second volume each have a reflectivity of more than 70%, in particular wherein a ratio of inner surfaces defining the second volume with a reflectivity of above 70% to inner surfaces defining the second volume with a reflectivity of below 70% is above 20.
3. Photoacoustic gas sensor device according to claim 1, wherein a ratio of the second volume to the first volume is at least 1.5, in particular wherein a thickness of the reflective shield is between 30 μm and 1 mm.
4. The photoacoustic gas sensor device according to claim 1, wherein a plane extension of the reflective shield and a plane extension of the substrate are aligned in parallel with each other, wherein the aperture is arranged in the reflective shield in vertical alignment with the electromagnetic radiation source arranged on the substrate, wherein the electromagnetic radiation source and the pressure transducer face the reflective shield, in particular wherein a distance between the aperture in the reflective shield and the electromagnetic radiation source is between 10 μm and 1 mm, in particular wherein the aperture is configured to enable a pressure equilibrium between the first volume and the second volume resulting in the communicatively coupling of the second volume and the pressure transducer to enable the pressure transducer to measure the sound wave generated by the component in the second volume.
5. Photoacoustic gas sensor device according to claim 1, comprising one or more additional apertures in the reflective shield connecting the first volume and the second volume, and/or comprising one or more gaps between the reflective shield and the measurement cell body or the substrate, the one or more gaps connecting the first volume and the second volume, in particular wherein the one or more additional apertures and/or the one or more gaps are configured to enable a pressure equilibrium between the first volume and the second volume resulting in the communicative coupling of the second volume and the pressure transducer to enable the pressure transducer to measure the sound wave generated by the component in the second volume.
6. Photoacoustic gas sensor device according to claim 1, wherein the reflective shield is made of or comprises a material of a thermal diffusivity of less than 20 mm2/s, in particular wherein the reflective shield is made of or comprises plastic material or stainless steel, in particular wherein the reflective shield is configured and arranged to reduce or shield a temperature modulation of the gas in the second volume evoked by an operation of the electromagnetic radiation source, in particular wherein the reflective shield is thermally connected to a heatsink of the substrate, in particular to a ground contact of the substrate, in particular by means of one or more legs of the reflective shield, in particular wherein the electromagnetic radiation source is in contact with the reflective shield, in particular wherein the electromagnetic radiation source comprises an emitter and an optical band pass filter between the emitter and the reflective shield, wherein the reflective shield is in contact with the optical band pass filter.
7. Photoacoustic gas sensor device according to claim 1, comprising wiring including a ground contact, wherein the reflective shield is made of or comprises an electrically conducting material, wherein the reflective shield is electrically connected to the ground contact, in particular wherein the electrically conducting material is coated on a core of the reflective shield, in particular wherein the reflective shield is made of the electrically conducting material, in particular wherein the electrically conducting material is metal or a metal-filled polymer, in particular wherein the reflective shield is an electrostatic discharge protection element for protecting the electromagnetic radiation source and/or the pressure transducer from an electrostatic discharge, in particular wherein the substrate supports the wiring including the ground contact, in particular wherein the reflective shield comprises one or more electrically conducting legs mounted on the substrate and soldered or conductively adhered to the ground contact, in particular wherein the reflective shield and the one or more legs are formed integrally, in particular wherein the reflective shield and the measurement cell body are spaced apart from each other.
8. The photoacoustic gas sensor device according to claim 1, further comprising an integrated circuit configured to receive a measurement signal from the pressure transducer and to determine the value indicative of a presence or a concentration of the component dependent on the measurement signal, in particular dependent on an amplitude of the measurement signal, in particular wherein the measurement signal is bandpass-filtered around the modulation frequency, in particular wherein the integrated circuit is arranged in the first volume together with the electromagnetic radiation source and the pressure transducer, and is arranged on the front side of the substrate, in particular wherein the integrated circuit is configured to control the electromagnetic radiation source, in particular wherein the integrated circuit is configured to control an intensity of the electromagnetic radiation to modulate with a modulation frequency, which modulation frequency is between 1 Hz and 100 kHz.
9. The photoacoustic gas sensor device according to claim 1, further comprising another transducer for sensing one or more of temperature, humidity, pressure, one or more different components in a gas, in particular wherein the other transducer is arranged in the first volume together with the electromagnetic radiation source and the pressure transducer, and is arranged on or integrated in the front side of the substrate, in particular wherein the integrated circuit is configured to compensate the value indicative of a presence or a concentration of the component dependent on measurement values of the other transducer.
10. Photoacoustic gas sensor device according to claim 1, wherein the measurement cell body is mounted on the front side of the substrate, wherein the reflective shield is supported by the measurement cell body, in particular wherein the reflective shield is attached to the measurement cell body, in particular wherein the reflective shield and the measurement cell body are formed integrally, in particular wherein the measurement cell body comprises an overhang defining a compartment outside the measurement volume between the measurement cell body and the substrate on which front side of the substrate one or more electrical components are arranged in the compartment, in particular wherein the measurement cell body comprises the opening arranged for the gas to enter the second volume.
11. Photoacoustic gas sensor device according to claim 1, wherein the measurement cell body is mounted on the front side of the substrate, wherein the reflective shield is embodied as a cap mounted on the front side of the substrate, wherein the reflective shield and the measurement cell body are spaced apart from each other, in particular wherein the measurement cell body comprises the opening arranged for the gas to enter the second volume.
12. Photoacoustic gas sensor device according to claim 1, wherein the measurement cell body includes a first cap mounted on the front side of the substrate, wherein the measurement cell body comprises a second cap mounted on top of the first cap, wherein a ceiling of the first cap represents or includes the reflective shield, in particular wherein the measurement cell body comprises the opening arranged for the gas to enter the second volume.
13. Photoacoustic gas sensor device according to claim 1, further comprising a gas permeable membrane covering the opening, wherein the gas permeable membrane is permeable for a gas exchange between the measurement volume and surroundings of the measurement cell, in particular wherein the gas permeable membrane is made of one or more of the following materials: sintered metal, ceramic, plastic.
14. Photoacoustic gas sensor device according to claim 1, wherein the substrate comprises the opening, in particular wherein the membrane is attached to the substrate, in particular wherein the membrane is attached to the front side of the substrate, in particular wherein the opening in the substrate is offset from the aperture in the reflective shield.
15. Photoacoustic gas sensor device according to claim 1, wherein the opening is formed by a gap between the measurement cell body and the substrate, in particular wherein the membrane is arranged between the measurement cell body and the substrate, in particular in the gap.
16. Photoacoustic gas sensor device according to claim 1, wherein the electromagnetic radiation source comprises an emitter including an active area for emitting the electromagnetic radiation, wherein a diameter of the aperture in the reflective shield is between 100% and 400% of a diameter of the active area of the emitter, in particular wherein a spacing between the reflective shield and the active area of the emitter is between 20% and 200% of the diameter of the active area, in particular wherein the aperture in the reflective shield is an optical aperture shielding from radiation of a wavelength or band outside a desired wavelength or band entering the second volume.
17. Photoacoustic gas sensor device according to claim 1, wherein the electromagnetic radiation source comprises: an emitter including an active area for emitting the electromagnetic radiation, a package for the emitter, the package comprising an access opening enabling the active area of the electromagnetic radiation source to to emit the electromagnetic radiation, an optical bandpass filter covering the access opening of the package, wherein the reflective shield is arranged to cover edges of the optical band pass filter, and/or wherein a diameter of the aperture in the reflective shield is between 1 and 2.5 times a diameter of the access opening in the package, in particular wherein the reflective shield is arranged at a distance between 0 μm and 200 μm from a top surface of the optical bandpass filter, in particular wherein a diameter of the aperture in the reflective shield is between 100% and 400% of a diameter of the active area of the emitter, in particular wherein the aperture in the reflective shield and the access opening in the package are optical apertures shielding the second volume from radiation of a wavelength or band outside a desired wavelength or band.
18. Photoacoustic gas sensor device according to claim 1, wherein the measurement cell body is mounted to the substrate by means of a snap fit, in particular wherein the measurement cell body comprises one or more snap arms and the substrate comprises one or more corresponding holes for the one or more snap arms to reach through, in particular wherein the snap fit is designed to mount the measurement cell body acoustically tight to the substrate, in particular wherein a footprint of the substrate and a footprint of the measurement cell body match by a tolerance of at most 10% for each dimension defining the planar extension thereof.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0082] Embodiments of the present invention, aspects and advantages will become apparent from the following detailed description thereof. The detailed description makes reference to the annexed drawings, wherein the figures show:
[0083]
[0084]
DETAILED DESCRIPTION OF THE DRAWINGS
[0085] Same elements are referred to by same reference numerals across all figures.
[0086]
[0087] The device comprises a substrate 1, e.g. a printed circuit board (PCB), with a front side 11 and a back side 12 opposite the front side 11. A measurement cell body 2 is mounted on the front side 11 of the substrate 1, which substrate 1 and measurement cell body 2 together form a measurement cell enclosing a measurement volume 3. The measurement cell has an opening 4 to allow an exchange of gas between the measurement volume 3 and surroundings of the device. In
[0088] A pressure transducer 6 such as a MEMS microphone or a pressure sensor, and an electromagnetic radiation source 7, which in this example is an infrared source, are both located on the front side 11 of the substrate inside the measurement cell. The electromagnetic radiation source includes an active area 711 emitting the electromagnetic radiation, i.e. the infrared radiation in this example, indicated by arrows 8. The infrared source emits infrared radiation of the band, wherein the intensity of the infrared radiation is modulated as described above. The infrared radiation is selectively absorbed by molecules of the gas component of interest.
[0089] A reflective shield 17 is provided in the measurement cell. The reflective shield 17 presently extends in a plane parallel to a planar extension of the substrate 1. The reflective shield 17 is attached to or formed integrally with the measurement cell body 2. The reflective shield 17 divides the measurement volume 3 into a first volume 31 between the substrate 1 and the shield 17, and a second volume 32 between the shield 17 and the measurement cell body 2. The reflective shield 17 comprises an aperture 18 which presently is aligned with the infrared source 7, such that infrared radiation 8 can emit from the infrared source 7 through the aperture 18 into the second volume 32.
[0090] It is preferred that a surface 171 of the shield 17 facing the second volume 32 is made of a material reflecting the electromagnetic radiation emitted by the electromagnetic radiation source 7. This is indicated by the various arrows representing the electromagnetic radiation 8 reflected in the second volume 32 after being emitted from the infrared source 7. A ratio of infrared radiation 8 absorbed is increased by increasing a mean optical path length of the infrared radiation 8 within the measurement volume 3. This is achieved by a material of at least the inner surface 21 of the measurement cell body 2 being chosen to be reflective. In case of a coating, the reflective coating may be made from a metal such as gold, aluminum, nickel, copper. In this way, the overall reflectivity inside the second volume 32 is increased, which leads to more accurate measurements of the concentration of the component. The increase of the mean optical path length, in particular in contrast to the linear optical path in conventional photoacoustic gas sensors, is illustrated by multiple reflections of the infrared radiation 8 in the various Figures. Here, the photoacoustic effect comes into play: Molecules of the gas component of interest, e.g. CO.sub.2, absorb the electromagnetic radiation in the second volume 32 leading to the generation of heat and hence an increase of pressure. By modulating an intensity of the electromagnetic radiation with a modulation frequency in the infrared source 7, a modulation of pressure may be achieved.
[0091] Such pressure modulation or pressure variations, i.e. sound waves, may be measured by the pressure transducer 6. In this example, the aperture 18 in the reflective shield 17 allows such sound waves generated in the second volume 32 to reach into the first volume 31 and hence to reach the pressure transducer 6. For this reason, a gap is provided between the reflective shield 17 and the electromagnetic radiation source 7. The sound waves are indicated by reference numeral 9 in
[0092] An integrated circuit 14 is arranged on the front side 11 of the substrate 1, which integrated circuit 14 may e.g. be an ASIC. In
[0093] In the present example, another transducer 13 is arranged on the front side 11 of the substrate 1. In
[0094] Further electrical components 15 may be arranged on the front side 11 of the substrate 1, preferably outside the measurement cell. Such further electrical components 15 may include passive components or auxiliary electronics, e.g. capacitors and resistors, as required.
[0095] On the back side 12 of the substrate 1, land grid array (LGA) pads 16 are arranged for SMD assembly and reflow soldering by a customer. Other contacts such as DFN, QFN or castellated holes are possible.
[0096] In one example, the component to be measured is CO.sub.2. For CO.sub.2, measurements in the range between 0 and 10,000 ppm, or between 0 and 40,000 ppm, or between 0 and 60,000 ppm CO.sub.2 are possible.
[0097] The proposed photoacoustic gas sensor device, as e.g. shown in
[0098] In the embodiment of
[0099] It is noted that the optical bandpass filter 72 is in contact with the reflective shield 17, e.g. via an O-ring or other sealing means. While such arrangement may be beneficial for several purposes such as thermal shielding etc., the acoustic coupling between the second volume 32 and the first volume 31, and the pressure transducer 6 respectively now no longer can be granted through the aperture 18 in the reflective shield 17. For this reason, gaps are provided between the reflective shield and the substrate 1 or the measurement cell body 2, for acoustically coupling the second volume 32 to the pressure transducer 6. Such gaps may better be seen from subsequent diagram 4c).
[0100] In
[0101]
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[0105] First, the embodiment of
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[0109] While above there are shown and described embodiments of the invention, it is to be understood that the invention is not limited thereto but may be otherwise variously embodied and practiced within the scope of the following claims.
[0110] It is understood, that in particular the embodiments of