1-PHENYL-5-AZINYLPYRAZOLYL-3-OXYALKYL ACIDS AND THEIR USE FOR CONTROLLING UNWANTED PLANT GROWTH

Abstract

What are described are compounds of the general formula (I) and agrochemically acceptable salts thereof

##STR00001##

and their preparation and their use in the crop protection sector.

Claims

1. A Compound of formula (I) ##STR00083## And/or an agrochemically acceptable salt thereof, where A is selected from the group consisting of A1-A15, ##STR00084## ##STR00085## R.sup.1 is selected from the group consisting of OR.sup.1a and NR.sup.9R.sup.10; where R.sup.1a is selected from the group consisting of hydrogen; (C.sub.1-C.sub.6)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, which is unsubstituted or substituted by one or more substituents selected from the group consisting of halogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.1-C.sub.6)-alkoxy, cyano and nitro; (C.sub.2-C.sub.4)-alkenyl, (C.sub.2-C.sub.4)-alkynyl; (C.sub.1-C.sub.4)-alkyl-SO—(C.sub.1-C.sub.4)—, (C.sub.1-C.sub.4)-alkyl-SO.sub.2—(C.sub.1-C.sub.4)—; heterocyclyl-(C.sub.1-C.sub.4)-alkyl, heteroaryl-(C.sub.1-C.sub.4)-alkyl and aryl-(C.sub.1-C.sub.4)-alkyl, where the aryl, heterocyclyl and heteroaryl are unsubstituted or substituted by halogen, (C.sub.1-C.sub.6)-alkyl and/or (C.sub.1-C.sub.6)-haloalkyl; R.sup.9 is selected from the group consisting of hydrogen, (C.sub.1-C.sub.12)-alkyl; R.sup.10 is selected from the group consisting of hydrogen; aryl, heteroaryl, heterocyclyl; (C.sub.1-C.sub.12)-alkyl; (C.sub.3-C.sub.8)-cycloalkyl, (C.sub.3-C.sub.7)-cycloalkyl-(C.sub.1-C.sub.7)-alkyl; (C.sub.2-C.sub.12)-alkenyl, (C.sub.5-C.sub.7)-cycloalkenyl, (C.sub.2-C.sub.12)-alkynyl; S(O).sub.nR.sup.5, cyano, nitro, OR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R, COR.sup.8, NR.sup.6R.sup.8, NR.sup.6COR.sup.8, NR.sup.6CO.sub.2R.sup.8, NR.sup.6SO.sub.2R.sup.8; which are unsubstituted or in each case independently of one another substituted by m radicals selected from the group consisting of hydrogen, halogen, cyano, nitro, OR.sup.5, S(O).sub.nR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R.sup.8, CONR.sup.6R.sup.8, COR.sup.6, NR.sup.6R.sup.8, NR.sup.6COR.sup.8, NR.sup.6CONR.sup.8R.sup.8, NR.sup.6CO.sub.2R.sup.8, NR.sup.6SO.sub.2R.sup.8, NR.sup.6SO.sub.2NR.sup.6R.sup.8, C(R.sup.6)═NOR.sup.8; or R.sup.9 and R.sup.10 together with the nitrogen atom to which they are attached form a saturated, partially or fully unsaturated five-, six- or seven-membered ring which is optionally mono- to hexasubstituted by radicals from the group consisting of halogen, (C.sub.1-C.sub.6)-alkyl, halo-(C.sub.1-C.sub.6)-alkyl, OR.sup.5, S(O).sub.nR.sup.5, CO.sub.2R, CONR.sup.6R.sup.8, COR.sup.6 and C(R.sup.6)═NOR.sup.8 and which, in addition to this nitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR.sup.7, CO and NCOR.sup.7 as ring atoms; R.sup.5 represents (C.sub.1-C.sub.8)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.1-C.sub.6)-haloalkyl or aryl; R.sup.6 represents hydrogen or R.sup.5; R.sup.7 represents hydrogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.3-C.sub.4)-alkenyl or (C.sub.3-C.sub.4)-alkynyl; R.sup.8 represents hydrogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.3-C.sub.4)-alkenyl or (C.sub.3-C.sub.4)-alkynyl; R.sup.2 is selected from the group consisting of hydrogen and cyano; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.4)-alkoxy-(C.sub.1-C.sub.4)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkoxy; (C.sub.2-C.sub.6)-alkenyl, (C.sub.2-C.sub.6)-haloalkenyl; (C.sub.2-C.sub.6)-alkynyl, (C.sub.2-C.sub.6)-haloalkynyl; (C.sub.3-C.sub.6)-cycloalkyl; R.sup.3 is selected from the group consisting of hydrogen, halogen, cyano, isocyanato, NO.sub.2; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkylcarbonyl, (C.sub.1-C.sub.6)-haloalkylcarbonyl, (C.sub.1-C.sub.4)-alkyloxycarbonyl; (C.sub.2-C.sub.3)-alkenyl, (C.sub.2-C.sub.3)-haloalkenyl; (C.sub.2-C.sub.3)-alkynyl, (C.sub.2-C.sub.3)-haloalkynyl; (C.sub.1-C.sub.2)-alkyl-S(O).sub.n and (C.sub.1-C.sub.2)-haloalkyl-S(O).sub.n; CHO; NH.sub.2; R.sup.4 represents phenyl, where the phenyl radical is unsubstituted or mono- or polysubstituted by a radical selected from the group consisting of hydrogen, halogen, cyano, isocyanato, nitro; (C.sub.1-C.sub.6)-alkyl, halo-(C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.3)-haloalkoxy; (C.sub.2-C.sub.3)-alkenyl, halo-(C.sub.2-C.sub.3)-alkenyl, (C.sub.1-C.sub.6)-alkoxy; (C.sub.2-C.sub.3)-alkynyl, halo-(C.sub.2-C.sub.3)-alkynyl, (C.sub.1-C.sub.4)-alkyl-S(O).sub.n; CHO, (C.sub.1-C.sub.4)-alkyloxycarbonyl and NH.sub.2; R.sup.12 is selected from the group consisting of hydrogen, halogen, cyano, isocyanato, NO.sub.2; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkylcarbonyl, (C.sub.1-C.sub.6)-haloalkylcarbonyl, (C.sub.1-C.sub.4)-alkyloxycarbonyl, (C.sub.1-C.sub.6)-alkoxy, (C.sub.1-C.sub.3)-haloalkoxy, (C.sub.1-C.sub.4)-alkyl-S(O).sub.n; (C.sub.2-C.sub.3)-alkenyl, (C.sub.2-C.sub.3)-haloalkenyl; (C.sub.2-C.sub.3)-alkynyl, (C.sub.2-C.sub.3)-haloalkynyl; NH.sub.2; and where the running number m is 0, 1 or 2; n is 0, 1 or 2; o is 0, 1 or 2; p is 0 or 1; q is 0 or 1; r is 3, 4, 5 or 6; and s is 0, 1 or 2.

2. The Compound according to claim 1, wherein A is selected from the group consisting of ##STR00086## ##STR00087## R.sup.1 is selected from the group consisting of OR.sup.1a and NR.sup.9R.sup.10; where R.sup.1a is selected from the group consisting of hydrogen; (C.sub.1-C.sub.6)-alkyl, which is unsubstituted or substituted by one or more substituents selected from the group consisting of halogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkoxy, cyano and nitro; (C.sub.1-C.sub.4)-alkyl-SO—(C.sub.1-C.sub.4)—, (C.sub.1-C.sub.4)-alkyl-SO.sub.2—(C.sub.1-C.sub.4)—; aryl-(C.sub.1-C.sub.4)-alkyl, where the aryl is unsubstituted or substituted by halogen, (C.sub.1-C.sub.6)-alkyl and/or (C.sub.1-C.sub.6)-haloalkyl; R.sup.9 represents hydrogen, (C.sub.1-C.sub.4)-alkyl; R.sup.10 is selected from the group consisting of hydrogen, aryl, (C.sub.1-C.sub.4)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.3-C.sub.6)-cycloalkyl-(C.sub.1-C.sub.4)-alkyl, (C.sub.2-C.sub.4)-alkenyl, S(O).sub.nRS, cyano, nitro, OR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R, COR.sup.8, NR.sup.6R.sup.8, NR.sup.6COR.sup.8; which are unsubstituted or in each case independently of one another substituted by m radicals selected from the group consisting of S(O).sub.nR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R, NR.sup.6CO.sub.2R.sup.8; or R.sup.9 and R.sup.10 together with the nitrogen atom to which they are attached form a saturated, partially or fully unsaturated five-, six- or seven-membered ring which is optionally mono- to hexasubstituted by radicals from the group consisting of halogen, (C.sub.1-C.sub.4)-alkyl, OR.sup.5, and which, in addition to this nitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR.sup.7, CO and NCOR.sup.7 as ring atoms; R.sup.5 represents (C.sub.1-C.sub.4)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl or (C.sub.1-C.sub.4)-haloalkyl; R.sup.6 represents hydrogen or R.sup.5; R.sup.7 represents hydrogen or (C.sub.1-C.sub.4)-alkyl; R.sup.8 represents hydrogen or (C.sub.1-C.sub.4)-alkyl; R.sup.2 is selected from the group consisting of hydrogen, cyano; (C.sub.1-C.sub.4)-alkyl, (C.sub.1-C.sub.4)-haloalkyl, (C.sub.1-C.sub.6)-alkoxy; (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.1-C.sub.6)-alkyl-(C.sub.1-C.sub.3)-alkoxy; R.sup.3 is selected from the group consisting of hydrogen, halogen, cyano, isocyanato, NO.sub.2; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkylcarbonyl, (C.sub.1-C.sub.6)-haloalkylcarbonyl, (C.sub.1-C.sub.2)-alkyloxycarbonyl, (C.sub.1-C.sub.3)-alkoxy, (C.sub.1-C.sub.6)-haloalkoxy; (C.sub.1-C.sub.6)-alkylthio, (C.sub.1-C.sub.6)-haloalkylthio; (C.sub.2-C.sub.3)-alkenyl, (C.sub.2-C.sub.3)-haloalkenyl; (C.sub.2-C.sub.3)-alkynyl, (C.sub.2-C.sub.3)-haloalkynyl; S(O).sub.n—(C.sub.1-C.sub.2)-alkyl where n=1 or 2; R.sup.4 represents phenyl, where the phenyl radical is unsubstituted or mono- or polysubstituted by a radical selected from the group consisting of hydrogen, fluorine, chlorine, bromine; (C.sub.1-C.sub.6)-alkyl, halo-(C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.3)-haloalkoxy; (C.sub.1-C.sub.6)-alkoxy; R.sup.12 is selected from the group consisting of hydrogen, halogen, cyano; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl; (C.sub.1-C.sub.6)-alkoxy, (C.sub.1-C.sub.3)-haloalkoxy; and where the running number m is 0 or 1; n is 0, 1 or 2; o is 0 or 1; p is 0; r is 6; and s is 0 or 1.

3. The Compound according to claim 1, wherein either A is selected from the group consisting of ##STR00088## R.sup.1 is selected from the group consisting of OR.sup.1a and NR.sup.9R.sup.10; where R.sup.1a is selected from the group consisting of hydrogen; (C.sub.1-C.sub.6)-alkyl, which is unsubstituted or substituted by one or more substituents selected from the group consisting of halogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.3-C.sub.6)-alkoxy; aryl-(C.sub.1-C.sub.4)-alkyl, where the aryl is substituted by (C.sub.1-C.sub.6)-alkyl; R.sup.9 represents hydrogen; R.sup.10 is selected from the group consisting of aryl, (C.sub.1-C.sub.12)-alkyl, (C.sub.3-C.sub.8)-cycloalkyl, (C.sub.3-C.sub.7)-cycloalkyl-(C.sub.1-C.sub.7)-alkyl, (C.sub.2-C.sub.12)-alkenyl, S(O).sub.nRS, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R, NR.sup.6R.sup.8, which are unsubstituted or where the alkyl, cycloalkyl, alkenyl, cycloalkenyl and alkynyl radicals mentioned above are in each case independently of one another substituted by m radicals selected from the group consisting of S(O).sub.nR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R, NR.sup.6CO.sub.2R.sup.8; or R.sup.9 and R.sup.10 together with the nitrogen atom to which they are attached form an unsubstituted saturated, partially or fully unsaturated five-, six- or seven-membered ring which, in addition to this nitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR.sup.7, CO and NCOR.sup.7 as ring atoms; R.sup.5 represents (C.sub.1-C.sub.8)-alkyl or (C.sub.1-C.sub.6)-haloalkyl; R.sup.6 represents hydrogen; R.sup.7 represents hydrogen or (C.sub.1-C.sub.6)-alkyl; R.sup.8 represents (C.sub.1-C.sub.6)-alkyl; R.sup.2 is selected from the group consisting of hydrogen; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.4)-alkoxy; R.sup.3 is selected from the group consisting of hydrogen, halogen, cyano, NO.sub.2; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-haloalkoxy; (C.sub.1-C.sub.6)-alkylthio; R.sup.4 represents phenyl, where the phenyl radical is unsubstituted or mono- or polysubstituted by a radical selected from the group consisting of hydrogen, fluorine, chlorine, bromine; methyl, ethyl, CF.sub.3, OCF.sub.3; R.sup.12 is selected from the group consisting of hydrogen, fluorine, chlorine, cyano; methyl, ethyl, CF.sub.3, OCF.sub.3; and where the running number m is 0 or 1; n is 0, 1 or 2; o is 1; p is 0; r is 6; and s is 0 or 1.

4. The Compound according to claim 1, wherein R.sup.1 is selected from the group consisting of OR.sup.1a and NR.sup.9R.sup.10; where R.sup.1a is selected from the group consisting of hydrogen; methyl and ethyl; allyl and propargyl; PhCH.sub.2; R.sup.9 represents hydrogen and R.sup.10 is selected from the group consisting of (C.sub.1-C.sub.12)-alkyl, S(O).sub.nR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R.sup.8, which are unsubstituted or in each case independently of one another substituted by m radicals selected from the group consisting of S(O).sub.nR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R.sup.8, NR.sup.6CO.sub.2R.sup.8; R.sup.5 represents ethyl, methyl, CF.sub.3, CH.sub.2CF.sub.3; R.sup.6 represents hydrogen or R.sup.5; R.sup.7 represents hydrogen, methyl or ethyl; R.sup.8 represents methyl or ethyl; R.sup.2 is selected from the group consisting of hydrogen; methyl, ethyl; R.sup.3 is selected from the group consisting of hydrogen, fluorine, bromine, chlorine, cyano, NO.sub.2; methyl, CF.sub.3, OCF.sub.3; R.sup.4 represents phenyl, where the phenyl radical is unsubstituted or mono- or polysubstituted by a radical selected from the group consisting of hydrogen, fluorine and chlorine; R.sup.12 is selected from the group consisting of hydrogen, fluorine, chlorine, cyano; methyl, CF.sub.3, OCF.sub.3.

5. The compound according to claim 1, wherein R.sup.3 is selected from the group consisting of fluorine, chlorine, bromine, iodine, cyano, NO.sub.2; CF.sub.3.

6. The compound according to claim 1, wherein R.sup.4 represents phenyl which is mono- or polysubstituted by fluorine and/or chlorine.

7. The compound of the general formula (I) according to claim 1, wherein R.sup.12 is selected from the group consisting of fluorine, chlorine, bromine, cyano, NO.sub.2; CF.sub.3.

8. The compound ##STR00089## according to claim 1, wherein the chiral carbon atom marked by (*) has an (R) configuration.

9. The compound ##STR00090## according to claim 1, wherein the chiral carbon atom marked by (*) has an (S) configuration.

10. A process for preparing the compound of formula (I) and/or an agrochemically acceptable salt thereof and/or agrochemically acceptable quaternized nitrogen derivative thereof ##STR00091## comprising alkylation of the compound of formula (II) ##STR00092## with a halide of formula (III) ##STR00093## in the presence of a base.

11. An herbicidal composition and/or plant growth-regulating composition, comprising one or more compounds according to claim 1.

12. A method of controlling harmful plants and/or regulating the growth of plants, comprising applying an effective amount of one or more compounds according to claim 1 to one or more plants, plant parts, plant seeds and/or an area under cultivation.

13. A product comprising the compound of according to claim 1 as an herbicide and/or as plant growth regulator.

14. A product according to claim 13, wherein the compound is used to control one or more harmful plants and/or to regulate growth of one or more plants in one or more crops of useful plants or ornamental plants.

15. The product according to claim 13, wherein the crop plants are transgenic crop plants.

16. A compound of formula (II) and/or salt thereof ##STR00094## where A is selected from the group consisting of A1-A15, ##STR00095## ##STR00096## R.sup.1 is selected from the group consisting of OR.sup.1a and NR.sup.9R.sup.10; where R.sup.1a is selected from the group consisting of hydrogen; (C.sub.1-C.sub.6)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, which is unsubstituted or substituted by one or more substituents selected from the group consisting of halogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.1-C.sub.6)-alkoxy, cyano and nitro; (C.sub.2-C.sub.4)-alkenyl, (C.sub.2-C.sub.4)-alkynyl; (C.sub.1-C.sub.4)-alkyl-SO—(C.sub.1-C.sub.4)—, (C.sub.1-C.sub.4)-alkyl-SO.sub.2—(C.sub.1-C.sub.4)—; heterocyclyl-(C.sub.1-C.sub.4)-alkyl, heteroaryl-(C.sub.1-C.sub.4)-alkyl and aryl-(C.sub.1-C.sub.4)-alkyl, where the aryl, heterocyclyl and heteroaryl are unsubstituted or substituted by halogen, (C.sub.1-C.sub.6)-alkyl and/or (C.sub.1-C.sub.6)-haloalkyl; R.sup.9 is selected from the group consisting of hydrogen, (C.sub.1-C.sub.12)-alkyl; R.sup.10 is selected from the group consisting of hydrogen; aryl, heteroaryl, heterocyclyl; (C.sub.1-C.sub.12)-alkyl; (C.sub.3-C.sub.8)-cycloalkyl, (C.sub.3-C.sub.7)-cycloalkyl-(C.sub.1-C.sub.7)-alkyl; (C.sub.2-C.sub.12)-alkenyl, (C.sub.5-C.sub.7)-cycloalkenyl, (C.sub.2-C.sub.12)-alkynyl; S(O).sub.nR.sup.5, cyano, nitro, OR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R.sup.8, COR.sup.8, NR.sup.6R.sup.8, NR.sup.6COR.sup.8, NR.sup.6CO.sub.2R.sup.8, NR.sup.6SO.sub.2R.sup.8; which are unsubstituted or in each case independently of one another substituted by m radicals selected from the group consisting of hydrogen, halogen, cyano, nitro, OR.sup.5, S(O).sub.nR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R.sup.8, CONR.sup.6R.sup.8, COR.sup.6, NR.sup.6R.sup.8, NR.sup.6COR.sup.8, NR.sup.6CONR.sup.8R.sup.8, NR.sup.6CO.sub.2R.sup.8, NR.sup.6SO.sub.2R.sup.8, NR.sup.6SO.sub.2NR.sup.6R.sup.8, C(R.sup.6)═NOR.sup.8; or R.sup.9 and R.sup.10 together with the nitrogen atom to which they are attached form a saturated, partially or fully unsaturated five-, six- or seven-membered ring which is optionally mono- to hexasubstituted by radicals from the group consisting of halogen, (C.sub.1-C.sub.6)-alkyl, halo-(C.sub.1-C.sub.6)-alkyl, OR.sup.5, S(O).sub.nR.sup.5, CO.sub.2R.sup.8, CONR.sup.6R.sup.8, COR.sup.6 and C(R.sup.6)═NOR.sup.8 and which, in addition to this nitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR.sup.7, CO and NCOR.sup.7 as ring atoms; R.sup.5 represents (C.sub.1-C.sub.8)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.1-C.sub.6)-haloalkyl or aryl; R.sup.6 represents hydrogen or R.sup.5; R.sup.7 represents hydrogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.3-C.sub.4)-alkenyl or (C.sub.3-C.sub.4)-alkynyl; R.sup.8 represents hydrogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.3-C.sub.4)-alkenyl or (C.sub.3-C.sub.4)-alkynyl; R.sup.2 is selected from the group consisting of hydrogen and cyano; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.4)-alkoxy-(C.sub.1-C.sub.4)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkoxy; (C.sub.2-C.sub.6)-alkenyl, (C.sub.2-C.sub.6)-haloalkenyl; (C.sub.2-C.sub.6)-alkynyl, (C.sub.2-C.sub.6)-haloalkynyl; (C.sub.3-C.sub.6)-cycloalkyl; R.sup.3 is selected from the group consisting of hydrogen, halogen, cyano, isocyanato, NO.sub.2; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkylcarbonyl, (C.sub.1-C.sub.6)-haloalkylcarbonyl, (C.sub.1-C.sub.4)-alkyloxycarbonyl; (C.sub.2-C.sub.3)-alkenyl, (C.sub.2-C.sub.3)-haloalkenyl; (C.sub.2-C.sub.3)-alkynyl, (C.sub.2-C.sub.3)-haloalkynyl; (C.sub.1-C.sub.2)-alkyl-S(O).sub.n and (C.sub.1-C.sub.2)-haloalkyl-S(O).sub.n; CHO; NH.sub.2; R.sup.4 represents phenyl, where the phenyl radical is unsubstituted or mono- or polysubstituted by a radical selected from the group consisting of hydrogen, halogen, cyano, isocyanato, nitro; (C.sub.1-C.sub.6)-alkyl, halo-(C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.3)-haloalkoxy; (C.sub.2-C.sub.3)-alkenyl, halo-(C.sub.2-C.sub.3)-alkenyl, (C.sub.1-C.sub.6)-alkoxy; (C.sub.2-C.sub.3)-alkynyl, halo-(C.sub.2-C.sub.3)-alkynyl, (C.sub.1-C.sub.4)-alkyl-S(O).sub.n; CHO, (C.sub.1-C.sub.4)-alkyloxycarbonyl and NH.sub.2; R.sup.12 is selected from the group consisting of hydrogen, halogen, cyano, isocyanato, NO.sub.2; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkylcarbonyl, (C.sub.1-C.sub.6)-haloalkylcarbonyl, (C.sub.1-C.sub.4)-alkyloxycarbonyl, (C.sub.1-C.sub.6)-alkoxy, (C.sub.1-C.sub.3)-haloalkoxy, (C.sub.1-C.sub.4)-alkyl-S(O) (C.sub.2-C.sub.3)-alkenyl, (C.sub.2-C.sub.3)-haloalkenyl; (C.sub.2-C.sub.3)-alkynyl, (C.sub.2-C.sub.3)-haloalkynyl; NH.sub.2; and where the running number m is 0, 1 or 2; n is 0, 1 or 2; o is 0, 1 or 2; p is 0 or 1; q is 0 or 1; r is 3, 4, 5 or 6; and s is 0, 1 or 2.

17. A process for preparing the compound of claim 16 ##STR00097## comprising a reaction of an electrophile with a 3-hydroxypyrazole of the formula (IIa) ##STR00098## and comprising reacting a compound of formula (VIII) ##STR00099## in a solvent in the presence of a metal halide.

18. A process for preparing a compound of formula (VIII) where A is ##STR00100## selected from the group consisting of A1-A15, ##STR00101## ##STR00102## R.sup.1 is selected from the group consisting of OR.sup.1a and NR.sup.9R.sup.10; where R.sup.1a is selected from the group consisting of hydrogen; (C.sub.1-C.sub.6)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, which is unsubstituted or substituted by one or more substituents selected from the group consisting of halogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.1-C.sub.6)-alkoxy, cyano and nitro; (C.sub.2-C.sub.4)-alkenyl, (C.sub.2-C.sub.4)-alkynyl; (C.sub.1-C.sub.4)-alkyl-SO—(C.sub.1-C.sub.4)—, (C.sub.1-C.sub.4)-alkyl-SO.sub.2—(C.sub.1-C.sub.4)—; heterocyclyl-(C.sub.1-C.sub.4)-alkyl, heteroaryl-(C.sub.1-C.sub.4)-alkyl and aryl-(C.sub.1-C.sub.4)-alkyl, where the aryl, heterocyclyl and heteroaryl are unsubstituted or substituted by halogen, (C.sub.1-C.sub.6)-alkyl and/or (C.sub.1-C.sub.6)-haloalkyl; R.sup.9 is selected from the group consisting of hydrogen, (C.sub.1-C.sub.12)-alkyl; R.sup.10 is selected from the group consisting of hydrogen; aryl, heteroaryl, heterocyclyl; (C.sub.1-C.sub.12)-alkyl; (C.sub.3-C.sub.8)-cycloalkyl, (C.sub.3-C.sub.7)-cycloalkyl-(C.sub.1-C.sub.7)-alkyl; (C.sub.2-C.sub.12)-alkenyl, (C.sub.5-C.sub.7)-cycloalkenyl, (C.sub.2-C.sub.12)-alkynyl; S(O).sub.nR.sup.5, cyano, nitro, OR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R.sup.8, COR.sup.8, NR.sup.6R.sup.8, NR.sup.6COR.sup.8, NR.sup.6CO.sub.2R.sup.8, NR.sup.6SO.sub.2R.sup.8; which are unsubstituted or in each case independently of one another substituted by m radicals selected from the group consisting of hydrogen, halogen, cyano, nitro, OR.sup.5, S(O).sub.nR.sup.5, SO.sub.2NR.sup.6R.sup.7, CO.sub.2R.sup.8, CONR.sup.6R.sup.8, COR.sup.6, NR.sup.6R.sup.8, NR.sup.6COR.sup.8, NR.sup.6CONR.sup.8R.sup.8, NR.sup.6CO.sub.2R.sup.8, NR.sup.6SO.sub.2R.sup.8, NR.sup.6SO.sub.2NR.sup.6R.sup.8, C(R.sup.6)═NOR.sup.8; or R.sup.9 and R.sup.10 together with the nitrogen atom to which they are attached form a saturated, partially or fully unsaturated five-, six- or seven-membered ring which is optionally mono- to hexasubstituted by radicals from the group consisting of halogen, (C.sub.1-C.sub.6)-alkyl, halo-(C.sub.1-C.sub.6)-alkyl, OR.sup.5, S(O).sub.nR.sup.5, CO.sub.2R.sup.8, CONR.sup.6R.sup.8, COR.sup.6 and C(R.sup.6)═NOR.sup.8 and which, in addition to this nitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR.sup.7, CO and NCOR.sup.7 as ring atoms; R.sup.5 represents (C.sub.1-C.sub.8)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.1-C.sub.6)-haloalkyl or aryl; R.sup.6 represents hydrogen or R.sup.5; R.sup.7 represents hydrogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.3-C.sub.4)-alkenyl or (C.sub.3-C.sub.4)-alkynyl; R.sup.8 represents hydrogen, (C.sub.1-C.sub.6)-alkyl, (C.sub.3-C.sub.6)-cycloalkyl, (C.sub.3-C.sub.4)-alkenyl or (C.sub.3-C.sub.4)-alkynyl; R.sup.2 is selected from the group consisting of hydrogen and cyano; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.4)-alkoxy-(C.sub.1-C.sub.4)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkoxy; (C.sub.2-C.sub.6)-alkenyl, (C.sub.2-C.sub.6)-haloalkenyl; (C.sub.2-C.sub.6)-alkynyl, (C.sub.2-C.sub.6)-haloalkynyl; (C.sub.3-C.sub.6)-cycloalkyl; R.sup.3 is selected from the group consisting of hydrogen, halogen, cyano, isocyanato, NO.sub.2; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkylcarbonyl, (C.sub.1-C.sub.6)-haloalkylcarbonyl, (C.sub.1-C.sub.4)-alkyloxycarbonyl; (C.sub.2-C.sub.3)-alkenyl, (C.sub.2-C.sub.3)-haloalkenyl; (C.sub.2-C.sub.3)-alkynyl, (C.sub.2-C.sub.3)-haloalkynyl; (C.sub.1-C.sub.2)-alkyl-S(O).sub.n and (C.sub.1-C.sub.2)-haloalkyl-S(O).sub.n; CHO; NH.sub.2; R.sup.4 represents phenyl, where the phenyl radical is unsubstituted or mono- or polysubstituted by a radical selected from the group consisting of hydrogen, halogen, cyano, isocyanato, nitro; (C.sub.1-C.sub.6)-alkyl, halo-(C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.3)-haloalkoxy; (C.sub.2-C.sub.3)-alkenyl, halo-(C.sub.2-C.sub.3)-alkenyl, (C.sub.1-C.sub.6)-alkoxy; (C.sub.2-C.sub.3)-alkynyl, halo-(C.sub.2-C.sub.3)-alkynyl, (C.sub.1-C.sub.4)-alkyl-S(O).sub.n; CHO, (C.sub.1-C.sub.4)-alkyloxycarbonyl and NH.sub.2; R.sup.12 is selected from the group consisting of hydrogen, halogen, cyano, isocyanato, NO.sub.2; (C.sub.1-C.sub.6)-alkyl, (C.sub.1-C.sub.6)-haloalkyl, (C.sub.1-C.sub.6)-alkylcarbonyl, (C.sub.1-C.sub.6)-haloalkylcarbonyl, (C.sub.1-C.sub.4)-alkyloxycarbonyl, (C.sub.1-C.sub.6)-alkoxy, (C.sub.1-C.sub.3)-haloalkoxy, (C.sub.1-C.sub.4)-alkyl-S(O; (C.sub.2-C.sub.3)-alkenyl, (C.sub.2-C.sub.3)-haloalkenyl; (C.sub.2-C.sub.3)-alkynyl, (C.sub.2-C.sub.3)-haloalkynyl; NH.sub.2; and where the running number m is 0, 1 or 2; n is 0, 1 or 2; o is 0, 1 or 2; P is 0 or 1; q is 0 or 1; r is 3, 4, 5 or 6; and s is 0, 1 or 2. comprising a reaction of an azine-A-substituted propynoic acid of formula (VI) ##STR00103## with a compound of formula (VII) ##STR00104## in a solvent in the presence of an amide coupling reagent.

19. A product comprising a compound of formula (II) and/or a salt thereof according to claim 16 for preparing an agrochemically active compound.

20. A product comprising a compound of according to claim 16, as intermediate for preparation of one or more fine chemicals and/or active compounds for agriculture.

Description

EXAMPLES

[0421] The present invention is illustrated in detail by the examples which follow, but these examples do not restrict the invention in any way.

A. Synthesis Examples

Synthesis of methyl {[4-bromo-1-(2-fluorophenyl)-5-(pyrimidin-5-yl)-1H-pyrazol-3-yl]oxy}acetate (VI-004)

3-(Benzyloxy)-1-(2-fluorophenyl)-1H-pyrazole

[0422] A mixture of 3 g (17.2 mmol) of 3-benzyloxypyrazole, 3.06 g (13.77 mmol) of 1-fluoro-2-iodobenzene, 0.46 g (2.41 mmol) copper(I) iodide and 7.86 g (311.93 mmol) of caesium carbonate in 25 ml of DMF is stirred at 120° C. for 8 hours and then allowed to stand at room temperature overnight. The mixture is then filtered and the DMF solution is concentrated to dryness. The residue is taken up in CH.sub.2Cl.sub.2 and washed with sat. NH.sub.4Cl solution. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated. The residue is purified by column chromatography on silica gel using heptane/ethyl acetate (1:1). This gives 2.0 g (43%) of product as a colourless oil.

[0423] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 5.30 (s, 2H), 5.95 (d, 1H), 7.20 (m, 3H), 7.35 (m, 3H), 7.50 (m, 2H), 7.85 (d, 1H), 7.90 (m, 1H).

3-(Benzyloxy)-1-(2-fluorophenyl)-5-iodo-1H-pyrazole

[0424] At −78° C., a solution of 11.9 g (44.36 mmol) of 3-(benzyloxy)-1-(2-fluorophenyl)-1H-pyrazole in 250 ml of THF is added dropwise to a solution of 75.7 mmol of LDA in 270 ml of THF and this mixture is stirred at −78° C. for a further 90 minutes. A solution of 18 g (70.97 mmol) of iodine is then added dropwise to the reaction mixture, and the reaction mixture is stirred for a further 60 minutes and subsequently allowed to warm to room temperature and allowed to stand overnight. The reaction mixture is then added to H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried over Na.sub.2SO.sub.4 and then concentrated. The crude product is purified by column chromatography on silica gel using heptane/ethyl acetate (8:2). This gives 10.6 g (60%) of product as a colourless oil.

[0425] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 5.20 (s, 2H), 6.10 (s, 1H), 7.20-7.50 (m, 9H).

3-(Benzyloxy)-1-(2-fluorophenyl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole

[0426] A reaction mixture of 1 g (2.54 mmol) of 3-(benzyloxy)-1-(2-fluorophenyl)-5-iodo-1H-pyrazole, 0.49 g (3.80 mmol) of pinacol borane ester, 0.77 g (7.61 mmol) of triethylamine and 17 mg (0.0033 mmol) of bis(tri-t-butylphosphine)palladium(0) in 10 ml of dioxane is stirred under reflux for 24 hours. The solid is then filtered off and washed with methyl t-butyl ether and the combined organic phase is concentrated. Purification of the crude product by column chromatography on silica gel using heptane/ethyl acetate (7:3) gives 0.59 g (59%) of product as a colourless oil.

[0427] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 1.20 (s, 12H), 5.25 (s, 2H), 6.30 (s, 1H), 7.10-7.55 (m, 9H).

5-[3-(Benzyloxy)-1-(2-fluorophenyl)-1H-pyrazol-5-yl]pyrimidine

[0428] 53 mg (0.075 mmol) of bis(triphenylphosphine)palladium(II) chloride, 0.24 g (1.50 mmol) of 5-bromopyrimidine, 0.62 g (4.49 mmol) of potassium carbonate and 0.6 ml of H.sub.2O are added successively to a solution of 0.59 g (1.50 mmol) of 3-(benzyloxy)-1-(2-fluorophenyl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole in 10 ml of dioxane and the reaction mixture is stirred under reflux for 4 hours. The reaction mixture is then added to H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated. Purification of the crude mixture by column chromatography gives 0.36 g (69%) of product.

[0429] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 5.30 (s, 2H), 6.18 (s, 1H), 7.10-7.55 (5m, 9H), 8.60 (s, 2H), 9.12 (s, 1H).

5-[3-(Benzyloxy)-4-bromo-1-(2-fluorophenyl)-1H-pyrazol-5-yl]pyrimidine

[0430] A mixture of 0.36 g (1.04 mmol) of 5-[3-(benzyloxy)-1-(2-fluorophenyl)-1H-pyrazol-5-yl]pyrimidine and 0.185 g (1.04 mmol) of bromosuccinimide in 10 ml of DMF is stirred at 50° C. for 4 hours and then allowed to stand overnight. The reaction mixture is then added to water and extracted repeatedly with CH.sub.2Cl.sub.2. Drying of the organic phase over Na.sub.2SO.sub.4 and subsequent concentration gives 0.44 g (100%) of crude product sufficiently pure for further reactions.

[0431] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 5.40 (s, 2H), 7.05-7.50 (4m, 9H), 8.67 (s, 2H), 9.18 (s, 1H).

4-Bromo-1-(2-fluorophenyl)-5-(pyrimidin-5-yl)-1H-pyrazol-3-ol

[0432] A solution of 0.48 g (1.13 mmol) of 5-[3-(benzyloxy)-4-bromo-1-(2-fluorophenyl)-1H-pyrazol-5-yl]pyrimidine in 18 ml of toluene and 18 ml of trifluoroacetic acid is stirred under reflux for 6 hours and then allowed to stand overnight. The mixture is then concentrated to dryness and the residue is taken up in CH.sub.2Cl.sub.2 and washed with a sat. NH.sub.4Cl solution. Drying of the organic phase over Na.sub.2SO.sub.4 and subsequent concentration gives 0.44 g of crude product sufficiently pure for further reactions.

[0433] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 7.10-7.50 (5m, 9H), 8.71 (s, 2H), 9.23 (s, 1H).

Methyl {[4-bromo-1-(2-fluorophenyl)-5-(pyrimidin-5-yl)-1H-pyrazol-3-yl]oxy}acetate (VI-004)

[0434] 0.43 g (3.13 mmol) of potassium carbonate is added to a solution of 0.35 g (1.04 mmol) of 4-bromo-1-(2-fluorophenyl)-5-(pyrimidin-5-yl)-1H-pyrazol-3-ol in 15 ml of acetonitrile and the mixture is stirred at room temperature for 10 minutes. 0.17 g (1.13 mmol) of methyl bromoacetate is then added and the reaction mixture is stirred under reflux for 5 hours and then allowed to stand at room temperature overnight. After filtration and concentration of the filtrate, the residue is taken up in H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried and concentrated. Purification by column chromatography on silica gel using heptane/ethyl acetate (1:1) gives 0.28 g (49%) of product.

[0435] .sup.1H NMR (400 MHZ, CDCl.sub.3): δ 3.70 (s, 3H), 4.95 (s, 1H), 7.05 (m, 1H), 7.20 (m, 1H), 7.38 (m, 1H), 7.45 (m, 1H), 8.70 (s, 2H), 9.20 (s, 1H).

{[4-Bromo-1-(2-fluorophenyl)-5-(pyrimidin-5-yl)-1H-pyrazol-3-yl]oxy}acetic Acid (VI-007)

[0436] A reaction mixture of 0.17 g (0.42 mmol) of methyl {[4-bromo-1-(2-fluorophenyl)-5-(pyrimidin-5-yl)-1H-pyrazol-3-yl]oxy}acetate and 14 mg (0.58 mmol) of lithium hydroxide in 3.8 ml of H.sub.2O and 1.7 ml of THF is stirred at 65° C. for 5 hours. The THF is then removed on a rotary evaporator and the aqueous phase is adjusted to pH 2 using 2N HCl solution. The resulting solid is filtered off with suction and dried. This gives 0.113 g (65%) of product as a solid.

[0437] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 5.00 (s, 2H), 7.00-7.50 (4m, 4H), 8.79 (s, 2H), 9.20 (s, 1H).

Methyl (2R)-2-{[4-bromo-1-(2-fluorophenyl)-5-(pyrimidin-5-yl)-1H-pyrazol-3-yl]oxy}propanoate (VI-011)

[0438] 0.61 g (4.47 mmol) of potassium carbonate is added to a solution of 0.50 g (1.49 mmol) of 4-bromo-1-(2-fluorophenyl)-5-(pyrimidin-5-yl)-1H-pyrazol-3-ol in 36 ml of acetonitrile and the mixture is stirred at room temperature for 10 minutes. 0.18 g (1.49 mmol) of methyl (2S)-2-chloropropanoate is then added and the reaction mixture is stirred under reflux for 5 hours and then allowed to stand at room temperature overnight. After filtration and concentration of the filtrate, the residue is taken up in H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried and concentrated. Purification by column chromatography on silica gel using heptane/ethyl acetate (1:1) gives 0.31 g (47%) of product.

[0439] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 1.70 (d, 3H), 3.80 (s, 3H), 5.20 (q, 2H), 7.00 (m, 1H), 7.22 (m, 1H), 7.35 (m, 1H), 7.40 (m, 1H), 8.65 (s, 2H), 9.15 (s, 1H).

Ethyl {[4-bromo-1-(2-fluorophenyl)-5-(6-fluoropyridin-3-yl)-1H-pyrazol-3-yl]oxy}acetate (VII-012)

[0440] A reaction mixture of 0.6 g (1.52 mmol) of 3-(benzyloxy)-1-(2-fluorophenyl)-5-iodo-1H-pyrazole, 0.21 g (1.52 mmol) of 2-fluoropyridine-5-boronic acid, 53 mg (0.076 mmol) of bis(triphenylphosphine)palladium(II) chloride and 1 ml of H.sub.2O in 10 ml of dioxane is stirred under reflux for 6 hours and then allowed to stand overnight. The reaction mixture is added to H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated. Purification by column chromatography on silica gel using heptane/ethyl acetate (1:1) gives 0.43 g (77%) of product.

[0441] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 5.30 (s, 2H), 6.10 (d, 1H), 6.85 (m, 1H), 7.10 (m, 1H), 7.20-7.50 (m, 5H), 7.60 (m, 1H), 8.10 (d, 1H).

[0442] Bromination and debenzylation are carried out as described for the preparation of Example VI-004.

Ethyl {[4-bromo-1-(2-fluorophenyl)-5-(6-fluoropyridin-3-yl)-1H-pyrazol-3-yl]oxy}acetate (VII-012)

[0443] 1.29 g (9.37 mmol) of potassium carbonate are added to a solution of 1.1 g (3.12 mmol) of 4-bromo-1-(2-fluorophenyl)-5-(6-fluoropyridin-5-yl)-1H-pyrazol-3-ol in 36 ml of acetonitrile and the mixture is stirred at room temperature for 10 minutes. 0.52 g (9.37 mmol) of ethyl bromoacetate is then added and the reaction mixture is stirred under reflux for 5 hours and then allowed to stand at room temperature overnight. After filtration and concentration of the filtrate, the residue is taken up in H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried and concentrated. Purification by column chromatography on silica gel using heptane/ethyl acetate (1:1) gives 0.36 g (26%) of product.

[0444] .sup.1H NMR (400 MHZ, CDCl.sub.3): δ 1.25 (t, 3H), 4.25 (q, 2H), 4.90 (s, 2H), 6.95 (m, 1H), 7.05 (m, 1H), 7.20 (m, 1H), 7.35 (m, 1H), 7.40 (m, 1H), 7.75 (m, 1H), 8.10 (s, 1H).

Methyl (2R)-2-{[4-bromo-1-(2-fluorophenyl)-5-(6-fluoropyridin-3-yl)-1H-pyrazol-3-yl]oxy}propanoate (VII-004)

[0445] 65 mg (0.47 mmol) of potassium carbonate are added to a solution of 0.55 g (0.156 mmol) of 4-bromo-1-(2-fluorophenyl)-5-(6-fluoropyridin-5-yl)-1H-pyrazol-3-ol in 4 ml of acetonitrile and the mixture is stirred at room temperature for 10 minutes. 19 mg (0.156 mmol) of methyl (2S)-2-chloropropanoate is then added and the reaction mixture is stirred under reflux for 5 hours and then allowed to stand at room temperature overnight. After filtration and concentration of the filtrate, the residue is taken up in H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried and concentrated. Purification by column chromatography on silica gel using heptane/ethyl acetate (1:1) gives 0.02 g (27%) of product.

[0446] .sup.1H NMR (400 MHZ, CDCl.sub.3): δ 1.70 (d, 2H), 3.80 (s, 3H), 5.20 (q, 1H), 6.92 (m, 1H), 7.05 (m, 1H), 7.20 (m, 1H), 7.35 (m, 2H), 7.75 (m, 1H), 8.10 (s, 1H).

Ethyl {[4-bromo-1-(2-fluorophenyl)-5-(2-fluoropyridin-4-yl)-1H-pyrazol-3-yl]oxy}acetate (VIII-002)

[0447] 58 mg (0.08 mmol) of bis(triphenylphosphine)palladium(II) chloride, 0.29 g (1.64 mmol) of 4-bromo-2-fluoropyridine, 0.68 g (4.94 mmol) of potassium carbonate and 0.7 ml of H.sub.2O are added successively to a solution of 0.65 g (1.64 mmol) of 3-(benzyloxy)-1-(2-fluorophenyl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole in 10 ml of dioxane and the reaction mixture is stirred under reflux for 4 hours. The reaction mixture is then added to H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated. Purification of the crude mixture by column chromatography gives 0.43 g (72%) of product.

[0448] Bromination and debenzylation are carried out as described for the preparation of Example VI-004.

Ethyl {[4-bromo-1-(2-fluorophenyl)-5-(2-fluoropyridin-4-yl)-1H-pyrazol-3-yl]oxy}acetate (VIII-002)

[0449] 0.14 g (1.02 mmol) of potassium carbonate are added to a solution of 0.12 g (0.34 mmol) of 4-bromo-1-(2-fluorophenyl)-5-(2-fluoropyridin-4-yl)-1H-pyrazol-3-ol in 8 ml of acetonitrile and the mixture is stirred at room temperature for 10 minutes. 0.057 g (0.34 mmol) of ethyl bromoacetate is then added and the reaction mixture is stirred under reflux for 5 hours and then allowed to stand at room temperature overnight. After filtration and concentration of the filtrate, the residue is taken up in H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried and concentrated. This gives 0.14 g (93%) of product.

Ethyl {[4-bromo-1-(2-fluorophenyl)-5-(pyridazin-4-yl)-1H-pyrazol-3-yl]oxy}acetate (IV-001)

[0450] 89 mg (0.12 mmol) of bis(triphenylphosphine)palladium(II) chloride, 0.61 g (2.53 mmol) of 5-bromopyridazine hydrobromide, 1.4 g (10.1 mmol) of potassium carbonate and 1.5 ml of H.sub.2O are added successively to a solution of 1.0 g (2.53 mmol) of 3-(benzyloxy)-1-(2-fluorophenyl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole in 16 ml of dioxane and the reaction mixture is stirred under reflux for 4 hours. The reaction mixture is then added to H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated. Purification of the crude mixture by column chromatography gives 0.51 g (58%) of product.

[0451] Bromination and debenzylation are carried out as described for the preparation of Example VI-004.

Ethyl {[4-bromo-1-(2-fluorophenyl)-5-(pyridazin-4-yl)-1H-pyrazol-3-yl]oxy}acetate (IV-001)

[0452] 0.21 g (1.52 mmol) of potassium carbonate are added to a solution of 0.17 g (0.50 mmol) of 4-bromo-1-(2-fluorophenyl)-5-(pyridazin-4-yl)-1H-pyrazol-3-ol in 5.5 ml of acetonitrile and the mixture is stirred at room temperature for 10 minutes. 0.085 g (0.50 mmol) of ethyl bromoacetate is then added and the reaction mixture is stirred under reflux for 5 hours and then allowed to stand at room temperature overnight. After filtration and concentration of the filtrate, the residue is taken up in H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried and concentrated. This gives 0.19 g (84%) of product.

Ethyl {[4-cyano-1-(2-fluorophenyl)-5-(pyridazin-4-yl)-1H-pyrazol-3-yl]oxy}acetate (IV-003)

[0453] A mixture consisting of 0.25 g (0.58 mmol) of ethyl {[4-bromo-1-(2-fluorophenyl)-5-(pyridazin-4-yl)-1H-pyrazol-3-yl]oxy}acetate, 0.048 g (0.41 mmol) of zinc cyanide and 0.068 g (0.05 mmol) of tetrakis(triphenylphosphine)palladium in 11 ml of dimethylacetamide is heated to 180° C. in a microwave with stirring for 40 minutes. The reaction mixture is then concentrated, taken up in H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated and the crude product thus obtained is purified on silica gel using heptane/ethyl acetate (1:1). This gives 88 mg (40%) of product.

[0454] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 5.40 (s, 2H), 7.15 (m, 1H), 7.30-7.60 (m, 4H), 9.00 (s, 1H), 9.30 (d, 1H).

Methyl (2R)-2-{[4-bromo-1-(2-fluorophenyl)-5-(5-fluoropyrimidin-2-yl)-1H-pyrazol-3-yl]oxy}propanoate (III-001)

[0455] 89 mg (0.12 mmol) of bis(triphenylphosphine)palladium(II) chloride, 0.45 g (2.53 mmol) of 2-bromo-5-fluoropyrimidine, 1.05 g (7.604 mmol) of potassium carbonate and 1 ml of H.sub.2O are added successively to a solution of 1.00 g (2.53 mmol) of 3-(benzyloxy)-1-(2-fluorophenyl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole in 16 ml of dioxane and the reaction mixture is stirred under reflux for 4 hours. The reaction mixture is then added to H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated. This gives 1 g (91%) of product sufficiently pure for further reactions.

[0456] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 5.30 (s, 2H), 6.63 (s, 1H), 7.30-7.55 (m, 4H), 8.45 (s, 2H).

[0457] Bromination and debenzylation are carried out as described for the preparation of Example VI-004.

Methyl (2R)-2-{[4-bromo-1-(2-fluorophenyl)-5-(5-fluoropyrimidin-2-yl)-1H-pyrazol-3-yl]oxy}propanoate (III-001)

[0458] 124 mg (0.89 mmol) of potassium carbonate are added to a solution of 0.105 g (0.29 mmol) of 4-bromo-1-(2-fluorophenyl)-5-(5-fluoropyrimidin-2-yl)-1H-pyrazol-3-ol in 7 ml of acetonitrile and the mixture is stirred at room temperature for 10 minutes. 55 mg (0.44 mmol) of methyl (2S)-2-chloropropanoate is then added and the reaction mixture is stirred under reflux for 5 hours and then allowed to stand at room temperature overnight. After filtration and concentration of the filtrate, the residue is taken up in H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried and concentrated. Purification by column chromatography on silica gel using heptane/ethyl acetate (1:1) gives 45 mg (35%) of product.

[0459] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 1.70 (d, 3H), 3.78 (s, 3H), 5.25 (q, 1H), 7.00 (m, 1H), 7.23 (m, 1H), 7.30 (m, 1H), 7.48 (m, 1H), 8.60 (s, 2H).

Methyl 2-{[4-chloro-5-(6-fluoropyridin-3-yl)-1-phenyl-1H-pyrazol-3-yl]oxy}propanoate (VII-023)

[0460] 2.65 g (8.13 mmol) of caesium carbonate and 1.2 g (6.51 mmol) of methyl 2-chloropropanoate are added successively to a solution of 1 g (5.42 mmol) of 5-amino-1-phenyl-1H-pyrazol-3-ol in 5 ml of DMF and the mixture is stirred at room temperature for 3 hours. The reaction mixture is concentrated and the residue is taken up in diethyl ether. The solid is filtered off with suction and the filtrate is concentrated. This gives 0.85 g (57%) of product.

[0461] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 1.60 (d, 3H), 3.75 (s, 3H), 3.80 (bs, 2H), 5.15 (q, 1H), 5.20 (s, 1H), 7.35 (m, 1H), 7.45 (m, 2H), 7.50 (m, 2H).

Methyl 2-[(5-amino-4-chloro-1-phenyl-1H-pyrazol-3-yl)oxy]propanoate

[0462] 0.44 g (3.30 mmol) of N-chlorosuccinimide is added to a solution of 8.8 g (2.75 mmol) of methyl 2-[(5-amino-1-phenyl-1H-pyrazol-3-yl)oxy]propanoate in 5 ml of DMF and the mixture is stirred at room temperature for 30 minutes. The DMF is removed and the residue is taken up in H.sub.2O and extracted repeatedly with CH.sub.2Cl.sub.2. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated.

[0463] Subsequent chromatographic purification on silica gel using heptane/ethyl acetate (4:1) gives 0.5 g (58%) of product.

[0464] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 1.70 (d, 3H), 3.70 (s, 3H), 5.25 (q, 1H), 7.15 (m, 1H), 7.40 (m, 2H), 7.80 (m, 2H), 8.20 (bs, 2H).

Methyl 2-[(4-chloro-5-iodo-1-phenyl-1H-pyrazol-3-yl)oxy]propanoate

[0465] 0.36 g (1.35 mmol) of diiodomethane and 0.79 g (0.67 mmol) of isopentyl nitrite are added successively to a solution of 0.1 g (0.34 mmol) of methyl 2-[(5-amino-4-chloro-1-phenyl-1H-pyrazol-3-yl)oxy]propanoate in 2 ml of acetonitrile and this reaction mixture is stirred at 50° C. for 30 minutes. The reaction mixture is then added to H.sub.2O and extracted repeatedly with ethyl acetate. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated and the crude product is purified by column chromatography on silica gel using heptane/ethyl acetate (4:1). This gives 102 mg (70%) of product.

[0466] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 1.69 (d, 3H), 3.79 (s, 3H), 5.20 (q, 1H), 7.40-7.50 (m, 5H).

Methyl 2-{[4-chloro-5-(6-fluoropyridin-3-yl)-1-phenyl-1H-pyrazol-3-yl]oxy}propanoate (VII-023)

[0467] 50 mg (0.36 mmol) of (6-fluoropyridin-3-yl)boronic acid, 8.36 mg (0.012 mmol) of bis(triphenylphosphine)palladium(II) chloride and 0.2 ml of a 2.5M aqueous caesium carbonate solution are added successively to a solution of 0.1 g (0.25 mmol) of methyl 2-[(4-chloro-5-iodo-1-phenyl-1H-pyrazol-3-yl)oxy]propanoate in 3 ml of dimethoxyethane and the reaction mixture is stirred at 80° C. for 3 hours. The reaction mixture is then concentrated, the residue is taken up in H.sub.2O and the aqueous phase is extracted repeatedly with ethyl acetate. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated and the residue is purified by column chromatography on silica gel using heptane/ethyl acetate (4:1). This gives 83 mg (83%) of product.

[0468] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 1.70 (d, 3H), 3.70 (s, 3H), 5.25 (q, 1H), 6.90 (dd, 1H), 7.10 (m, 2H), 7.30 (m, 2H), 7.78 (m, 1H), 8.18 (d, 1H).

{[4-Bromo-1-(2-fluorophenyl)-5-(6-fluoropyridin-3-yl)-1H-pyrazol-3-yl]oxy}acetic acid (VI-003)

[0469] A solution of 0.6 g (1.37 mmol) of ethyl 3-[4-bromo-1-(2-fluorophenyl)-5-(6-fluoropyridin-3-yl)-1H-pyrazol-3-yl]propanoate, 46 mg (1.92 mmol) of LiGH and 6 ml of THF in 14 ml of H.sub.2O is stirred at room temperature for 12 hours. The solution is concentrated and the aqueous phase that remains is adjusted to pH 2 using 2N HCl. The precipitated solid is filtered off with suction and dried. This gives 0.44 g (74%) of product.

[0470] .sup.1H NMR (400 MHz, CDCl.sub.3): δ 5.00 (s, 2H), 6.93 (dd, 1H), 7.02 (m, 1H), 7.20 (m, 1H), 7.35 (m, 1H), 7.41 (m, 1H), 7.75 (m, 1H), 8.12 (s, 1H).

N-Allyl-2-{[4-bromo-1-(2-fluorophenyl)-5-(6-fluoropyridin-3-yl)-1H-pyrazol-3-yl]oxy}acetamide (X-001)

[0471] At room temperature, a mixture of 60 mg (0.146 mmol) of {[4-bromo-1-(2-fluorophenyl)-5-(6-fluoropyridin-3-yl)-1H-pyrazol-3-yl]oxy}acetic acid, 9 mg (0.161 mmol) of allylamine and 34 mg (0.176 mmol) of 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride is stirred in a solvent mixture of 3 ml of THF and 6 ml of DMF for 12 hours. A 2N HCl solution is then added to the reaction mixture, and the reaction mixture is extracted repeatedly with CH.sub.2C.sub.2. The organic phase is dried over Na.sub.2SO.sub.4 and concentrated and the residue thus obtained is purified by column chromatography on silica gel using heptane/ethyl acetate (7/3). This gives 13 mg (19%) of product.

[0472] .sup.1H NMR (400 MHz, CDCl.sub.3) δ 4.00 (m, 2H), 4.85 (m, 2H9, 5.70 (2m, 2h), 5.90 (m, 1H9, 6.65 (bs, 1H, NH), 6.95 (m, 1H), 7.05 (m, 1H), 7.35 (m, 1H), 7.38 (m, 1H9, 7.45 (m, 1H97.73 (m, 1H9, 8.10 (s, 1H).

NMR Data of Selected Examples

[0473] NMR Peak List Method

[0474] The 1H NMR data of selected examples are noted in the form of 1H NMR peak lists. For each signal peak, first the □ value in ppm and then the signal intensity in round brackets are listed. The pairs of □ value-signal intensity numbers for different signal peaks are listed with separation from one another by semicolons.

[0475] The peak list for one example therefore takes the form of:

□.sub.1 (intensity.sub.1); □.sub.2 (intensity.sub.2); . . . ; □.sub.i (intensity.sub.i); . . . ; δ.sub.n (intensity.sub.n)

[0476] The intensity of sharp signals correlates with the height of the signals in a printed example of an NMR spectrum in cm and shows the true ratios of the signal intensities. In the case of broad signals, several peaks or the middle of the signal and the relative intensity thereof may be shown in comparison to the most intense signal in the spectrum.

[0477] For calibration of the chemical shift of 1H NMR spectra we use tetramethylsilane and/or the chemical shift of the solvent, particularly in the case of spectra measured in DMSO. Therefore, the tetramethylsilane peak may but need not occur in NMR peak lists.

[0478] The lists of the 1H NMR peaks are similar to the conventional 1H NMR printouts and thus usually contain all peaks listed in a conventional NMR interpretation.

[0479] In addition, like conventional 1H NMR printouts, they may show solvent signals, signals of stereoisomers of the target compounds, which likewise form part of the subject matter of the invention, and/or peaks of impurities.

[0480] In the reporting of compound signals in the delta range of solvents and/or water, our lists of 1H NMR peaks show the usual solvent peaks, for example peaks of DMSO in DMSO-D.sub.6 and the peak of water, which usually have a high intensity on average.

[0481] The peaks of stereoisomers of the target compounds and/or peaks of impurities usually have a lower intensity on average than the peaks of the target compounds (for example with a purity of >90%).

[0482] Such stereoisomers and/or impurities may be typical of the particular preparation process. Their peaks can thus help in identifying reproduction of our preparation process with reference to “by-product fingerprints”.

[0483] An expert calculating the peaks of the target compounds by known methods (MestreC, ACD simulation, but also with empirically evaluated expected values) can, if required, isolate the peaks of the target compounds, optionally using additional intensity filters. This isolation would be similar to the relevant peak picking in conventional 1H NMR interpretation.

[0484] Further details of 1H NMR peak lists can be found in the Research Disclosure Database Number 564025.

TABLE-US-00011 VII-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1749 (0.8); 8.1730 (1.2); 8.1709 (0.9); 8.1689 (0.9); 8.1667 (1.2); 8.1648 (0.8); 7.7044 (0.7); 7.6981 (0.7); 7.6857 (0.8); 7.6831 (0.8); 7.6794 (0.8); 7.6769 (0.8); 7.6645 (0.7); 7.6582 (0.7); 7.2622 (17.5); 7.1308 (1.4); 7.1250 (0.5); 7.1189 (1.5); 7.1135 (0.9); 7.1079 (2.2); 7.1019 (0.6); 7.0960 (2.2); 7.0309 (2.2); 7.0249 (0.6); 7.0137 (0.7); 7.0108 (2.4); 7.0080 (1.6); 7.0050 (0.6); 6.9938 (0.5); 6.9880 (1.4); 6.9779 (0.9); 6.9763 (0.9); 6.9703 (0.9); 6.9687 (0.8); 6.9566 (0.8); 6.9550 (0.8); 6.9490 (0.8); 6.9475 (0.8); 4.9307 (8.4); 3.8127 (16.0); 2.0076 (9.8); 1.5646 (0.5); −0.0002 (10.5) VII-002: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1733 (1.1); 8.1670 (1.2); 7.7036 (0.7); 7.6974 (0.6); 7.6850 (0.7); 7.6825 (0.8); 7.6788 (0.7); 7.6762 (0.8); 7.6638 (0.7); 7.6576 (0.7); 7.2606 (19.7); 7.1300 (1.4); 7.1242 (0.5); 7.1182 (1.5); 7.1128 (0.9); 7.1072 (2.2); 7.1012 (0.6); 7.0954 (2.1); 7.0309 (2.2); 7.0250 (0.6); 7.0137 (0.6); 7.0108 (2.4); 7.0081 (1.6); 7.0050 (0.7); 6.9939 (0.5); 6.9881 (1.5); 6.9775 (0.8); 6.9761 (0.8); 6.9699 (0.8); 6.9685 (0.9); 6.9563 (0.7); 6.9549 (0.8); 6.9488 (0.8); 6.9473 (0.8); 5.3002 (1.2); 4.9309 (8.3); 4.9255 (0.7); 3.9574 (0.9); 3.8131 (16.0); 1.5421 (4.7); 0.0080 (0.7); −0.0002 (26.9); −0.0085 (0.8) VII-012: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1075 (2.3); 8.1013 (2.3); 7.7699 (1.1); 7.7636 (1.1); 7.7511 (1.3); 7.7487 (1.4); 7.7449 (1.2); 7.7425 (1.3); 7.7299 (1.1); 7.7237 (1.1); 7.4268 (0.9); 7.4225 (1.0); 7.4075 (1.7); 7.4033 (1.8); 7.3888 (1.0); 7.3843 (1.2); 7.3704 (0.5); 7.3582 (0.5); 7.3515 (0.9); 7.3472 (0.8); 7.3391 (0.9); 7.3348 (0.8); 7.3308 (0.8); 7.3263 (0.6); 7.3186 (0.8); 7.3140 (0.6); 7.2613 (31.1); 7.2246 (1.2); 7.2054 (1.7); 7.1879 (0.7); 7.0479 (1.2); 7.0446 (1.1); 7.0270 (1.1); 7.0232 (1.8); 7.0195 (1.2); 7.0019 (1.0); 6.9986 (1.0); 6.9424 (1.6); 6.9349 (1.6); 6.9212 (1.5); 6.9148 (1.4); 4.9008 (16.0); 4.2971 (2.0); 4.2792 (6.2); 4.2614 (6.3); 4.2436 (2.1); 3.5057 (0.6); 3.4881 (1.8); 3.4706 (1.8); 3.4530 (0.6); 1.5542 (15.5); 1.3088 (7.4); 1.2910 (15.1); 1.2731 (7.3); 1.2262 (1.9); 1.2087 (3.8); 1.1911 (1.8); 0.0080 (0.7); −0.0002 (25.9); −0.0085 (0.8) VII-012: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 8.2014 (2.1); 8.1951 (2.3); 7.9621 (0.9); 7.9558 (0.9); 7.9426 (1.2); 7.9409 (1.3); 7.9363 (1.2); 7.9346 (1.3); 7.9215 (1.0); 7.9152 (1.0); 7.5783 (0.6); 7.5748 (0.9); 7.5599 (1.4); 7.5554 (1.9); 7.5403 (1.0); 7.5360 (1.1); 7.4994 (0.5); 7.4931 (0.8); 7.4879 (0.9); 7.4804 (0.8); 7.4759 (0.8); 7.4727 (0.8); 7.4680 (0.6); 7.4598 (0.7); 7.4554 (0.6); 7.3380 (1.0); 7.3350 (1.3); 7.3191 (1.7); 7.3156 (3.2); 7.3086 (1.0); 7.2962 (2.6); 7.2934 (1.8); 7.2905 (2.4); 7.2890 (2.5); 7.2850 (1.3); 7.2762 (1.5); 7.2748 (1.6); 7.2677 (2.2); 7.2642 (1.0); 4.9348 (11.0); 4.1956 (1.9); 4.1778 (6.1); 4.1601 (6.2); 4.1424 (1.9); 3.3210 (62.7); 2.5410 (0.8); 2.5242 (1.2); 2.5195 (1.6); 2.5107 (25.1); 2.5062 (55.3); 2.5016 (78.2); 2.4970 (54.7); 2.4924 (25.2); 2.0745 (2.3); 1.2054 (7.4); 1.1983 (0.8); 1.1877 (16.0); 1.1700 (7.2); 0.0080 (2.0); −0.0002 (70.4); −0.0085 (2.3) VII-127: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.0580 (3.4); 8.0531 (3.3); 7.4762 (2.4); 7.4701 (2.4); 7.4546 (2.6); 7.4485 (2.5); 7.3869 (1.0); 7.3826 (1.1); 7.3676 (1.9); 7.3636 (2.2); 7.3488 (1.2); 7.3443 (1.8); 7.3316 (0.7); 7.3245 (1.1); 7.3124 (1.1); 7.3044 (1.1); 7.2997 (0.8); 7.2920 (0.8); 7.2876 (0.7); 7.2613 (10.8); 7.1896 (1.4); 7.1704 (2.2); 7.1527 (0.9); 7.0516 (1.3); 7.0485 (1.3); 7.0306 (1.3); 7.0271 (2.1); 7.0236 (1.5); 7.0059 (1.1); 7.0029 (1.1); 6.6762 (3.4); 6.6546 (3.3); 4.8925 (16.0); 4.3593 (2.0); 4.3416 (6.4); 4.3239 (6.6); 4.3062 (2.1); 4.2920 (2.1); 4.2742 (6.3); 4.2563 (6.4); 4.2385 (2.1); 1.5625 (8.8); 1.3902 (6.5); 1.3725 (13.3); 1.3548 (6.4); 1.3039 (7.2); 1.2861 (14.6); 1.2682 (7.2); −0.0002 (13.1) VII-012: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.2011 (1.0); 8.1948 (1.1); 7.9422 (0.6); 7.9404 (0.6); 7.9359 (0.6); 7.9341 (0.6); 7.5594 (0.7); 7.5550 (0.9); 7.3346 (0.6); 7.3187 (0.8); 7.3151 (1.4); 7.2955 (1.2); 7.2882 (1.2); 7.2843 (0.6); 7.2739 (0.7); 7.2669 (1.1); 4.9346 (5.3); 4.1958 (0.9); 4.1781 (2.9); 4.1603 (3.0); 4.1426 (0.9); 3.3175 (16.0); 2.5240 (0.5); 2.5194 (0.7); 2.5106 (9.6); 2.5061 (20.8); 2.5014 (29.0); 2.4968 (20.2); 2.4922 (8.9); 2.0742 (12.3); 1.2057 (3.5); 1.1879 (7.6); 1.1701 (3.4); 0.0081 (0.8); −0.0002 (28.7); −0.0086 (0.8) VII-012: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1108 (1.0); 8.1091 (1.4); 8.1070 (1.1); 8.1048 (1.2); 8.1028 (1.5); 8.1008 (1.0); 7.7702 (0.8); 7.7639 (0.8); 7.7514 (0.9); 7.7490 (0.9); 7.7452 (0.9); 7.7427 (0.9); 7.7303 (0.8); 7.7240 (0.8); 7.4282 (0.6); 7.4239 (0.7); 7.4090 (1.0); 7.4046 (1.2); 7.3902 (0.7); 7.3858 (0.8); 7.3520 (0.6); 7.3501 (0.5); 7.3476 (0.5); 7.3398 (0.6); 7.3353 (0.6); 7.3334 (0.5); 7.3313 (0.6); 7.3191 (0.6); 7.2663 (6.2); 7.2284 (0.7); 7.2267 (0.8); 7.2250 (0.8); 7.2235 (0.7); 7.2078 (1.0); 7.2070 (1.1); 7.2054 (1.1); 7.1881 (0.5); 7.0482 (0.8); 7.0450 (0.8); 7.0274 (0.7); 7.0236 (1.2); 7.0198 (0.8); 7.0024 (0.7); 6.9991 (0.7); 6.9450 (1.1); 6.9434 (1.1); 6.9376 (1.1); 6.9360 (1.0); 6.9238 (1.1); 6.9222 (1.0); 6.9163 (1.1); 6.9147 (1.0); 4.9009 (11.4); 4.2962 (1.4); 4.2784 (4.5); 4.2606 (4.6); 4.2428 (1.5); 2.0072 (16.0); 1.3080 (6.0); 1.2902 (12.6); 1.2723 (5.8); −0.0002 (4.6) VII-019: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.1923 (0.7); 8.1860 (0.7); 7.5279 (0.5); 7.3088 (1.3); 7.2894 (0.9); 7.2850 (0.8); 7.2639 (0.7); 5.1129 (0.9); 5.0956 (0.9); 4.1785 (0.5); 4.1608 (1.7); 4.1431 (1.8); 4.1254 (0.6); 3.3184 (16.0); 2.5192 (0.6); 2.5105 (7.0); 2.5060 (15.0); 2.5014 (20.5); 2.4968 (14.4); 2.4922 (6.5); 2.0741 (1.4); 1.5748 (2.6); 1.5574 (2.6); 1.1724 (1.9); 1.1548 (4.1); 1.1370 (1.8); −0.0002 (12.2) VII-005: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 7.3119 (0.7); 4.8894 (2.1); 3.3183 (16.0); 2.5191 (0.5); 2.5104 (6.6); 2.5058 (14.2); 2.5012 (19.7); 2.4966 (13.7); 2.4920 (6.1); 2.0739 (1.3); 1.1962 (4.7); 1.1806 (4.7); −0.0002 (13.7) VII-029: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.1992 (0.6); 8.1929 (0.6); 7.3093 (0.9); 7.2899 (0.8); 7.2861 (0.7); 7.2648 (0.5); 4.9811 (0.6); 3.6843 (6.3); 3.3196 (16.0); 2.5107 (4.9); 2.5062 (10.6); 2.5015 (14.7); 2.4969 (10.2); 2.4924 (4.5); 1.9343 (0.5); 1.0440 (1.0); 1.0256 (2.4); 1.0070 (1.0); −0.0002 (10.0) VII-003: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.2013 (1.4); 8.1950 (1.5); 7.9639 (0.6); 7.9576 (0.6); 7.9445 (0.8); 7.9428 (0.9); 7.9381 (0.8); 7.9364 (0.8); 7.9233 (0.6); 7.9170 (0.6); 7.5898 (0.6); 7.5747 (1.0); 7.5703 (1.2); 7.5551 (0.6); 7.5508 (0.7); 7.4949 (0.5); 7.4821 (0.5); 7.4743 (0.5); 7.3406 (0.6); 7.3377 (0.8); 7.3216 (1.0); 7.3182 (1.4); 7.3106 (0.8); 7.3081 (0.6); 7.3020 (0.6); 7.2979 (1.2); 7.2902 (1.6); 7.2849 (1.0); 7.2816 (0.8); 7.2748 (1.0); 7.2692 (0.9); 7.2679 (1.0); 7.2639 (0.7); 7.2608 (0.6); 4.8400 (7.0); 3.4368 (0.7); 2.5243 (0.6); 2.5197 (0.9); 2.5109 (10.8); 2.5064 (23.1); 2.5017 (32.0); 2.4971 (22.2); 2.4926 (9.9); 2.0744 (16.0); 0.0080 (1.0); 0.0040 (0.6); −0.0002 (29.1); −0.0085 (0.8) VII-003: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.2042 (3.5); 8.1979 (3.6); 7.9673 (1.4); 7.9609 (1.4); 7.9461 (2.0); 7.9398 (1.9); 7.9266 (1.5); 7.9203 (1.4); 7.5967 (1.1); 7.5926 (1.4); 7.5775 (2.4); 7.5732 (2.8); 7.5580 (1.5); 7.5537 (1.6); 7.5154 (0.7); 7.5110 (0.7); 7.5026 (0.8); 7.4964 (1.2); 7.4910 (1.2); 7.4836 (1.2); 7.4792 (1.2); 7.4760 (1.3); 7.4712 (0.9); 7.4630 (1.0); 7.4585 (0.8); 7.3430 (1.6); 7.3401 (2.0); 7.3239 (2.6); 7.3206 (3.4); 7.3139 (2.0); 7.3013 (3.8); 7.2940 (3.4); 7.2881 (2.2); 7.2847 (1.8); 7.2799 (2.4); 7.2731 (2.2); 7.2671 (1.5); 7.2640 (1.3); 4.8417 (16.0); 3.0137 (1.0); 2.6721 (0.5); 2.5256 (1.6); 2.5210 (2.3); 2.5121 (28.3); 2.5076 (61.6); 2.5030 (85.4); 2.4984 (59.7); 2.4939 (26.4); 2.4180 (11.6); 2.3299 (0.5); 2.0774 (3.3); 1.9098 (3.2); 1.2198 (0.6); 1.1692 (0.6); 0.0081 (1.7); 0.0057 (0.6); −0.0002 (57.6); −0.0085 (1.6) VII-003: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1103 (0.5); 7.2620 (13.4); 4.9739 (3.8); 2.1111 (2.3); 2.0087 (16.0); −0.0002 (7.6) VII-003: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.2026 (7.9); 8.1966 (8.1); 7.9658 (2.6); 7.9596 (2.5); 7.9449 (4.2); 7.9391 (4.0); 7.9252 (2.8); 7.9189 (2.6); 7.5959 (2.1); 7.5921 (2.4); 7.5766 (4.5); 7.5728 (4.9); 7.5572 (2.7); 7.5533 (2.7); 7.5137 (1.2); 7.5096 (1.3); 7.5009 (1.5); 7.4945 (2.6); 7.4900 (2.6); 7.4814 (2.6); 7.4774 (2.7); 7.4700 (1.9); 7.4614 (1.8); 7.4574 (1.6); 7.3389 (3.8); 7.3194 (6.4); 7.3116 (4.2); 7.3000 (7.7); 7.2923 (6.9); 7.2860 (4.9); 7.2825 (4.3); 7.2787 (5.4); 7.2719 (4.9); 7.2648 (3.1); 7.2622 (2.7); 4.8305 (16.0); 3.6746 (0.4); 3.3398 (3.4); 2.6724 (0.4); 2.5258 (1.4); 2.5210 (2.1); 2.5122 (23.1); 2.5078 (48.1); 2.5033 (65.3); 2.4988 (46.9); 2.4944 (21.8); 2.3303 (0.4); 1.3873 (1.4); 0.0000 (8.3) VII-019: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1016 (1.2); 8.0998 (1.9); 8.0978 (1.5); 8.0957 (1.5); 8.0936 (2.0); 8.0916 (1.4); 8.0193 (0.6); 7.7611 (1.0); 7.7549 (1.0); 7.7423 (1.2); 7.7399 (1.3); 7.7361 (1.2); 7.7336 (1.2); 7.7212 (1.1); 7.7149 (1.1); 7.3960 (0.8); 7.3916 (0.9); 7.3768 (1.3); 7.3724 (1.7); 7.3576 (1.0); 7.3535 (1.2); 7.3444 (0.6); 7.3398 (0.6); 7.3376 (0.8); 7.3359 (0.7); 7.3332 (0.7); 7.3314 (0.7); 7.3254 (0.8); 7.3237 (0.7); 7.3209 (0.7); 7.3192 (0.7); 7.3170 (0.8); 7.3125 (0.6); 7.3048 (0.8); 7.3003 (0.6); 7.2621 (16.2); 7.2122 (0.9); 7.2106 (1.0); 7.2088 (1.0); 7.2074 (1.0); 7.1912 (1.4); 7.1892 (1.5); 7.1737 (0.6); 7.1720 (0.6); 7.1703 (0.6); 7.1689 (0.6); 7.0361 (1.0); 7.0328 (1.0); 7.0153 (0.9); 7.0114 (1.6); 7.0077 (1.1); 6.9901 (0.9); 6.9869 (0.9); 6.9368 (1.4); 6.9353 (1.5); 6.9294 (1.4); 6.9278 (1.4); 6.9157 (1.3); 6.9141 (1.4); 6.9082 (1.4); 6.9066 (1.4); 5.3002 (6.0); 5.2152 (0.8); 5.1978 (3.0); 5.1804 (3.0); 5.1630 (0.8); 4.2641 (1.1); 4.2623 (1.2); 4.2463 (3.6); 4.2445 (3.8); 4.2284 (3.8); 4.2268 (3.8); 4.2106 (1.3); 4.2091 (1.3); 2.9641 (5.3); 2.9567 (6.1); 2.8852 (5.2); 2.8838 (5.4); 2.7731 (3.6); 1.6903 (11.6); 1.6729 (11.6); 1.5678 (5.6); 1.2781 (7.7); 1.2603 (16.0); 1.2425 (7.4); 0.0080 (0.6); −0.0002 (21.8); −0.0084 (0.7) VII-019: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0999 (1.8); 8.0979 (1.4); 8.0956 (1.4); 8.0936 (1.9); 7.7611 (1.0); 7.7548 (0.9); 7.7423 (1.1); 7.7399 (1.2); 7.7361 (1.1); 7.7336 (1.1); 7.7212 (1.0); 7.7149 (1.0); 7.3959 (0.7); 7.3915 (0.8); 7.3767 (1.3); 7.3724 (1.6); 7.3576 (1.0); 7.3534 (1.2); 7.3441 (0.5); 7.3395 (0.5); 7.3373 (0.8); 7.3356 (0.6); 7.3329 (0.6); 7.3311 (0.6); 7.3251 (0.8); 7.3235 (0.6); 7.3206 (0.6); 7.3189 (0.6); 7.3167 (0.8); 7.3122 (0.6); 7.3045 (0.7); 7.3000 (0.6); 7.2617 (11.7); 7.2118 (0.8); 7.2103 (0.9); 7.2085 (1.0); 7.1909 (1.3); 7.1890 (1.4); 7.1733 (0.6); 7.1718 (0.6); 7.1700 (0.6); 7.1687 (0.6); 7.0359 (1.0); 7.0327 (0.9); 7.0151 (0.9); 7.0113 (1.5); 7.0075 (1.0); 6.9900 (0.9); 6.9867 (0.8); 6.9366 (1.3); 6.9352 (1.3); 6.9292 (1.3); 6.9277 (1.3); 6.9154 (1.2); 6.9139 (1.3); 6.9079 (1.3); 6.9064 (1.2); 5.2154 (0.7); 5.1980 (2.8); 5.1806 (2.8); 5.1632 (0.8); 4.2641 (1.0); 4.2623 (1.1); 4.2463 (3.4); 4.2446 (3.4); 4.2284 (3.6); 4.2269 (3.5); 4.2105 (1.2); 4.2093 (1.2); 2.0451 (1.6); 1.6903 (10.7); 1.6729 (10.7); 1.5617 (2.8); 1.2780 (7.5); 1.2603 (16.0); 1.2425 (7.1); 0.8987 (1.1); 0.8818 (3.9); 0.8641 (1.5); −0.0002 (13.6) VII-034: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0721 (1.7); 8.0692 (1.5); 8.0663 (1.8); 7.7047 (0.7); 7.7035 (0.7); 7.6984 (0.7); 7.6973 (0.7); 7.6841 (1.0); 7.6822 (0.9); 7.6800 (0.8); 7.6779 (1.0); 7.6648 (0.7); 7.6636 (0.7); 7.6586 (0.7); 7.6574 (0.6); 7.4525 (0.8); 7.4482 (0.9); 7.4333 (1.5); 7.4289 (1.7); 7.4144 (1.0); 7.4100 (1.2); 7.3948 (0.5); 7.3827 (0.5); 7.3781 (0.6); 7.3760 (0.8); 7.3742 (0.7); 7.3715 (0.7); 7.3698 (0.7); 7.3638 (0.8); 7.3621 (0.7); 7.3593 (0.8); 7.3575 (0.7); 7.3553 (0.8); 7.3508 (0.7); 7.3432 (0.8); 7.3387 (0.6); 7.2613 (16.8); 7.2544 (1.0); 7.2527 (1.1); 7.2510 (1.1); 7.2497 (1.0); 7.2316 (1.6); 7.2158 (0.7); 7.2142 (0.8); 7.2125 (0.8); 7.2112 (0.7); 7.0836 (1.1); 7.0803 (1.1); 7.0628 (1.0); 7.0589 (1.7); 7.0552 (1.2); 7.0377 (0.9); 7.0344 (0.9); 6.9405 (1.5); 6.9391 (1.5); 6.9330 (1.4); 6.9315 (1.4); 6.9192 (1.4); 6.9177 (1.4); 6.9116 (1.3); 6.9102 (1.3); 4.9025 (0.8); 4.8899 (15.7); 4.3036 (1.9); 4.2858 (6.0); 4.2679 (6.1); 4.2501 (2.0); 1.5683 (1.9); 1.3131 (7.7); 1.2953 (16.0); 1.2775 (7.6); 0.0079 (0.6); −0.0002 (19.6); −0.0085 (0.6) VII-034: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 7.7945 (3.6); 7.6603 (1.1); 7.6126 (3.6); 7.3291 (1.0); 7.3067 (0.9); 7.2605 (23.3); 5.0760 (2.8); 5.0576 (2.8); 5.0249 (2.4); 2.7476 (16.0); 1.5488 (10.5); 1.2539 (0.6); 0.0079 (0.7); −0.0002 (23.5); −0.0085 (0.7) VII-024: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.2791 (1.0); 8.2702 (1.2); 8.2638 (1.2); 8.0366 (0.5); 8.0306 (0.8); 8.0241 (0.5); 8.0111 (0.8); 8.0047 (0.6); 8.0029 (0.6); 7.6852 (0.6); 7.6819 (0.7); 7.5796 (0.7); 7.5622 (0.5); 7.4414 (0.7); 7.4217 (1.1); 7.3302 (0.8); 7.3243 (0.8); 7.3230 (0.8); 7.3153 (0.9); 7.3088 (1.4); 7.3030 (0.8); 7.3016 (0.7); 7.2939 (0.8); 7.2882 (0.7); 5.7573 (2.0); 4.9491 (4.7); 4.1981 (0.9); 4.1804 (3.0); 4.1626 (3.0); 4.1448 (1.0); 3.3209 (16.0); 2.5209 (0.7); 2.5122 (8.6); 2.5076 (18.8); 2.5030 (26.0); 2.4984 (18.2); 2.4938 (8.1); 1.2088 (3.6); 1.1911 (7.9); 1.1733 (3.5); 0.0080 (0.7); −0.0002 (21.7); −0.0085 (0.6) VII-010: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.0567 (1.8); 8.0507 (1.8); 7.7355 (0.6); 7.7292 (0.6); 7.7154 (0.9); 7.7093 (0.9); 7.6957 (0.6); 7.6895 (0.6); 7.3950 (0.6); 7.3911 (1.0); 7.3867 (0.8); 7.3763 (1.2); 7.3737 (2.3); 7.3722 (2.1); 7.3673 (1.4); 7.3616 (0.7); 7.3540 (2.5); 7.3492 (0.7); 7.3471 (0.9); 7.3426 (0.6); 7.3346 (0.8); 7.3302 (0.5); 7.2610 (21.5); 7.2165 (0.9); 7.2149 (1.0); 7.2133 (1.1); 7.2118 (1.0); 7.1956 (1.8); 7.1939 (1.7); 7.1779 (0.7); 7.1762 (0.8); 7.1746 (0.7); 7.1732 (0.6); 7.0435 (1.0); 7.0408 (0.8); 7.0226 (1.0); 7.0193 (1.6); 7.0161 (0.8); 7.0136 (0.5); 6.9973 (1.0); 6.9944 (0.6); 6.9321 (1.4); 6.9306 (1.4); 6.9246 (1.4); 6.9231 (1.4); 6.9109 (1.4); 6.9093 (1.4); 6.9034 (1.4); 6.9018 (1.4); 4.9054 (14.6); 4.2899 (1.9); 4.2720 (6.0); 4.2542 (6.1); 4.2363 (2.0); 2.6154 (1.4); 1.5563 (0.7); 1.3020 (7.7); 1.2842 (16.0); 1.2663 (7.5); 0.0080 (0.6); −0.0002 (19.2) VII-010: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0570 (1.6); 8.0510 (1.7); 7.7361 (0.5); 7.7299 (0.6); 7.7161 (0.8); 7.7100 (0.8); 7.6965 (0.6); 7.6903 (0.6); 7.3958 (0.6); 7.3919 (0.9); 7.3873 (0.7); 7.3772 (1.0); 7.3744 (2.2); 7.3729 (2.0); 7.3680 (1.2); 7.3622 (0.7); 7.3577 (0.8); 7.3546 (2.3); 7.3498 (0.7); 7.3477 (0.9); 7.3432 (0.7); 7.3353 (0.8); 7.3308 (0.5); 7.2620 (25.1); 7.2578 (0.5); 7.2172 (0.8); 7.2155 (0.9); 7.2139 (1.0); 7.2123 (0.9); 7.1985 (0.8); 7.1963 (1.6); 7.1945 (1.5); 7.1786 (0.6); 7.1769 (0.7); 7.1753 (0.7); 7.1738 (0.6); 7.0439 (0.9); 7.0412 (0.8); 7.0401 (0.7); 7.0230 (0.9); 7.0197 (1.5); 7.0165 (0.8); 7.0141 (0.6); 6.9981 (1.0); 6.9948 (0.6); 6.9331 (1.3); 6.9315 (1.4); 6.9256 (1.4); 6.9240 (1.4); 6.9119 (1.3); 6.9102 (1.4); 6.9044 (1.3); 6.9028 (1.4); 5.3001 (4.4); 4.9058 (13.8); 4.8967 (0.9); 4.2900 (1.8); 4.2722 (5.7); 4.2614 (0.5); 4.2544 (5.8); 4.2366 (1.8); 1.5630 (3.0); 1.3022 (7.6); 1.2936 (0.5); 1.2907 (0.6); 1.2892 (0.5); 1.2844 (16.0); 1.2781 (0.5); 1.2758 (1.0); 1.2666 (7.5); 1.2579 (0.6); 0.0080 (0.5); 0.0023 (0.6); −0.0002 (17.1); −0.0025 (1.0); −0.0084 (0.5) VII-015: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.4470 (2.7); 8.4401 (2.7); 8.2886 (1.7); 8.2850 (2.8); 8.2814 (1.7); 7.4433 (0.9); 7.4389 (1.0); 7.4286 (1.4); 7.4241 (2.8); 7.4214 (2.3); 7.4176 (1.6); 7.4060 (1.9); 7.4015 (2.1); 7.3950 (1.2); 7.3784 (2.6); 7.3673 (2.2); 7.3612 (1.0); 7.3593 (0.8); 7.3568 (0.8); 7.3549 (0.7); 7.3488 (0.9); 7.3445 (0.9); 7.3426 (0.8); 7.3405 (0.9); 7.3360 (0.7); 7.3282 (0.8); 7.3237 (0.7); 7.2632 (18.5); 7.2401 (0.9); 7.2386 (1.1); 7.2368 (1.2); 7.2172 (1.7); 7.2015 (0.8); 7.2000 (0.8); 7.1983 (0.8); 7.0549 (1.1); 7.0517 (1.1); 7.0341 (1.1); 7.0302 (1.8); 7.0265 (1.2); 7.0089 (1.0); 7.0057 (1.0); 5.3016 (4.1); 4.9057 (15.8); 4.7058 (2.9); 4.2992 (2.0); 4.2813 (6.3); 4.2635 (6.3); 4.2456 (2.0); 1.3104 (7.8); 1.2925 (16.0); 1.2747 (7.6); −0.0002 (13.4) VII-007: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.6067 (2.3); 8.6017 (2.2); 7.8649 (1.2); 7.8609 (1.1); 7.8446 (1.5); 7.8404 (1.4); 7.6899 (2.8); 7.6882 (2.8); 7.6694 (2.3); 7.6677 (2.2); 7.4643 (0.9); 7.4600 (1.0); 7.4450 (1.6); 7.4407 (1.8); 7.4261 (1.1); 7.4217 (1.2); 7.3903 (0.5); 7.3780 (0.6); 7.3735 (0.6); 7.3713 (0.9); 7.3669 (0.8); 7.3652 (0.7); 7.3590 (0.9); 7.3546 (0.8); 7.3527 (0.8); 7.3507 (0.8); 7.3462 (0.7); 7.3384 (0.8); 7.3339 (0.6); 7.2629 (27.9); 7.2504 (1.2); 7.2486 (1.2); 7.2289 (1.7); 7.2118 (0.7); 7.2099 (0.7); 7.0559 (1.2); 7.0527 (1.1); 7.0351 (1.1); 7.0312 (1.8); 7.0275 (1.2); 7.0100 (1.0); 7.0066 (1.0); 5.3025 (0.8); 4.9125 (16.0); 4.3021 (2.0); 4.2843 (6.4); 4.2664 (6.5); 4.2486 (2.1); 1.5622 (1.4); 1.3131 (7.8); 1.2953 (15.9); 1.2774 (7.6); 0.0079 (0.6); −0.0002 (20.2); −0.0086 (0.6) VII-030: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.2537 (4.7); 8.0545 (1.4); 8.0485 (1.5); 8.0337 (2.6); 8.0141 (1.6); 8.0082 (1.3); 7.6336 (1.8); 7.6142 (3.2); 7.5983 (1.9); 7.5270 (1.0); 7.5113 (2.1); 7.4946 (2.2); 7.4790 (1.3); 7.3241 (5.8); 7.3046 (6.8); 7.2879 (5.4); 7.2669 (3.4); 7.2606 (2.9); 7.2137 (0.5); 4.8785 (16.0); 4.8350 (0.6); 4.4919 (1.1); 2.5069 (55.5); 2.5029 (65.1); 2.4990 (48.8); 2.0748 (7.4); 1.9099 (1.4); 1.3571 (2.2); 1.2367 (1.4); −0.0002 (24.2) VII-011: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.7310 (4.0); 8.7276 (4.0); 8.0616 (1.4); 8.0573 (1.4); 8.0417 (3.4); 8.0368 (3.5); 8.0143 (5.9); 8.0125 (5.5); 7.9938 (2.6); 7.9919 (2.3); 7.6256 (1.3); 7.6216 (1.5); 7.6064 (2.7); 7.6021 (2.9); 7.5869 (1.7); 7.5826 (1.7); 7.5272 (0.7); 7.5228 (0.8); 7.5143 (0.8); 7.5082 (1.5); 7.5034 (1.4); 7.4953 (1.5); 7.4909 (1.5); 7.4832 (1.1); 7.4747 (1.1); 7.4705 (0.9); 7.3573 (1.8); 7.3546 (2.1); 7.3381 (2.9); 7.3351 (3.6); 7.3279 (2.3); 7.3191 (1.6); 7.3159 (1.7); 7.3072 (1.9); 7.3020 (2.4); 7.2989 (1.9); 7.2809 (1.6); 7.2779 (1.4); 4.8639 (16.0); 2.5264 (1.6); 2.5217 (2.4); 2.5129 (22.1); 2.5085 (45.5); 2.5039 (61.4); 2.4994 (44.4); 2.4949 (21.6); 2.0778 (15.2); 1.9105 (4.3); 1.3559 (2.4); 1.2347 (0.7); 0.0080 (1.7); −0.0002 (47.2); −0.0085 (2.0) VII-025: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 13.0301 (0.6); 8.6453 (4.6); 8.6383 (4.7); 8.3565 (2.5); 8.3524 (4.6); 8.3485 (2.2); 7.7935 (1.6); 7.7891 (1.7); 7.7865 (1.7); 7.7821 (1.5); 7.7698 (1.7); 7.7654 (1.8); 7.7628 (1.6); 7.7585 (1.5); 7.6079 (1.0); 7.6037 (1.2); 7.5885 (2.1); 7.5842 (2.3); 7.5691 (1.2); 7.5647 (1.3); 7.5190 (0.6); 7.5146 (0.6); 7.5063 (0.6); 7.5002 (1.0); 7.4955 (0.9); 7.4873 (1.0); 7.4829 (1.0); 7.4796 (1.0); 7.4749 (0.8); 7.4667 (0.8); 7.4623 (0.7); 7.3493 (1.3); 7.3465 (1.6); 7.3303 (2.0); 7.3270 (2.5); 7.3204 (0.6); 7.3112 (2.4); 7.3081 (3.5); 7.2905 (1.3); 7.2853 (1.6); 7.2820 (1.3); 7.2643 (1.2); 7.2611 (1.1); 4.8464 (14.0); 3.3201 (1.8); 2.5236 (1.3); 2.5189 (1.9); 2.5102 (25.5); 2.5056 (55.1); 2.5010 (76.8); 2.4964 (53.3); 2.4918 (23.6); 2.0730 (16.0); 1.3559 (0.8); 0.0080 (1.5); −0.0002 (52.1); −0.0086 (1.4) VII-025: .sup.1H-NMR(400.0 MHz, DMSO_5 mm): δ = 8.6467 (1.4); 8.6397 (1.4); 8.3562 (0.8); 8.3521 (1.4); 8.3484 (0.7); 7.7913 (0.5); 7.7887 (0.5); 7.7720 (0.5); 7.7677 (0.5); 7.5895 (0.6); 7.5852 (0.7); 7.3318 (0.6); 7.3286 (0.8); 7.3122 (0.7); 7.3093 (0.7); 7.2863 (0.5); 4.8449 (4.1); 3.4095 (0.6); 3.3920 (1.2); 3.3745 (1.7); 3.3374 (16.0); 2.5250 (1.0); 2.5204 (1.3); 2.5117 (9.6); 2.5071 (20.0); 2.5025 (27.2); 2.4979 (19.1); 2.4933 (8.5); 1.1083 (0.6); 1.0908 (1.3); 1.0733 (0.6); 0.0079 (0.5); −0.0002 (15.0) VII-001: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.2036 (1.5); 8.1973 (1.6); 7.9638 (0.6); 7.9575 (0.6); 7.9442 (0.9); 7.9426 (0.9); 7.9379 (0.9); 7.9363 (0.9); 7.9231 (0.7); 7.9168 (0.7); 7.5832 (0.6); 7.5681 (1.0); 7.5637 (1.3); 7.5485 (0.7); 7.5442 (0.8); 7.4947 (0.6); 7.4896 (0.6); 7.4820 (0.6); 7.4775 (0.6); 7.4743 (0.6); 7.3391 (0.7); 7.3365 (0.9); 7.3203 (1.2); 7.3168 (1.9); 7.2974 (1.8); 7.2892 (1.9); 7.2750 (1.1); 7.2678 (1.6); 5.7567 (1.9); 4.9609 (7.4); 3.7004 (16.0); 3.3183 (5.7); 2.5199 (0.7); 2.5112 (8.6); 2.5066 (18.1); 2.5021 (25.0); 2.4975 (18.2); 2.4930 (9.0); 0.0080 (0.6); −0.0002 (17.6); −0.0085 (0.8) VII-039: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.6065 (1.6); 8.6019 (1.6); 7.8612 (0.8); 7.8566 (0.8); 7.8410 (1.0); 7.8362 (1.0); 7.6852 (1.9); 7.6648 (1.5); 7.4598 (0.5); 7.4555 (0.6); 7.4404 (1.0); 7.4364 (1.2); 7.4217 (0.7); 7.4173 (0.7); 7.3707 (0.6); 7.3663 (0.5); 7.3583 (0.6); 7.3505 (0.6); 7.2608 (9.1); 7.2468 (0.8); 7.2277 (1.2); 7.2095 (0.5); 7.0566 (0.7); 7.0536 (0.7); 7.0358 (0.7); 7.0320 (1.2); 7.0284 (0.8); 7.0107 (0.6); 7.0075 (0.6); 4.9319 (9.3); 3.8108 (16.0); 1.2553 (1.5); −0.0002 (11.7) VII-040: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.0732 (1.0); 8.0703 (0.9); 8.0673 (1.0); 7.6829 (0.6); 7.6810 (0.5); 7.6766 (0.6); 7.4481 (0.6); 7.4333 (0.9); 7.4289 (1.0); 7.4143 (0.6); 7.4099 (0.7); 7.3772 (0.5); 7.3650 (0.6); 7.3565 (0.5); 7.3443 (0.5); 7.2617 (8.0); 7.2554 (0.6); 7.2537 (0.6); 7.2520 (0.6); 7.2505 (0.6); 7.2324 (0.9); 7.0852 (0.6); 7.0819 (0.6); 7.0643 (0.6); 7.0605 (1.0); 7.0567 (0.7); 7.0391 (0.6); 7.0358 (0.6); 6.9400 (1.0); 6.9384 (1.0); 6.9324 (0.9); 6.9308 (0.9); 6.9187 (0.9); 6.9171 (1.0); 6.9111 (0.9); 6.9095 (0.9); 4.9234 (0.6); 4.9116 (8.7); 3.8118 (16.0); 3.8084 (1.6); 3.8018 (1.2); 2.0057 (7.7); 1.5593 (0.7); −0.0002 (8.7) VII-031: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.0591 (1.0); 8.0531 (1.1); 7.7159 (0.6); 7.7098 (0.5); 7.3902 (0.6); 7.3880 (0.5); 7.3743 (1.3); 7.3713 (1.2); 7.3683 (0.9); 7.3547 (1.7); 7.3516 (0.7); 7.3482 (0.6); 7.3358 (0.5); 7.2611 (7.2); 7.2173 (0.6); 7.2156 (0.6); 7.2140 (0.6); 7.2126 (0.6); 7.1964 (1.1); 7.1947 (1.0); 7.0455 (0.6); 7.0247 (0.6); 7.0214 (0.9); 6.9996 (0.6); 6.9321 (0.8); 6.9306 (0.9); 6.9246 (0.9); 6.9231 (0.8); 6.9109 (0.8); 6.9093 (0.8); 6.9034 (0.8); 6.9019 (0.8); 4.9250 (8.3); 3.8009 (16.0); 3.7967 (0.8); 2.0051 (4.0); 1.2560 (0.6); −0.0002 (7.9) VII-031: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0583 (1.2); 8.0524 (1.3); 7.7167 (0.6); 7.7114 (0.6); 7.3909 (0.7); 7.3749 (1.4); 7.3722 (1.3); 7.3557 (1.8); 7.3493 (0.6); 7.3368 (0.5); 7.2605 (12.3); 7.2150 (0.7); 7.1975 (1.2); 7.0461 (0.6); 7.0430 (0.5); 7.0219 (1.0); 7.0001 (0.6); 6.9331 (1.0); 6.9257 (1.0); 6.9120 (0.9); 6.9045 (1.0); 4.9257 (9.0); 3.8021 (16.0); 1.5410 (3.4); 0.0079 (0.5); −0.0002 (19.7); −0.0084 (0.8) VII-035: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.4474 (1.4); 8.4405 (1.4); 8.2912 (0.9); 8.2876 (1.5); 8.2839 (0.9); 7.4341 (0.6); 7.4246 (0.8); 7.4200 (1.5); 7.4179 (1.3); 7.4146 (1.2); 7.4136 (1.2); 7.4022 (0.9); 7.4004 (0.8); 7.3979 (1.0); 7.3955 (1.4); 7.3909 (0.7); 7.3609 (0.5); 7.3487 (0.5); 7.3402 (0.5); 7.2612 (17.9); 7.2384 (0.6); 7.2367 (0.6); 7.2350 (0.6); 7.2335 (0.6); 7.2154 (0.9); 7.0565 (0.6); 7.0532 (0.6); 7.0357 (0.6); 7.0318 (1.0); 7.0280 (0.6); 7.0105 (0.6); 7.0072 (0.5); 4.9251 (8.6); 3.8075 (16.0); 2.0056 (3.8); −0.0002 (11.5) X-002: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.4718 (0.8); 8.1893 (1.3); 8.1830 (1.4); 7.9491 (0.6); 7.9428 (0.5); 7.9297 (0.7); 7.9279 (0.8); 7.9234 (0.7); 7.9216 (0.8); 7.9085 (0.6); 7.9022 (0.6); 7.6294 (0.6); 7.6142 (1.0); 7.6098 (1.1); 7.5947 (0.6); 7.5904 (0.6); 7.3504 (0.6); 7.3475 (0.7); 7.3313 (1.0); 7.3280 (1.2); 7.3091 (1.2); 7.2992 (0.9); 7.2935 (0.9); 7.2922 (0.9); 7.2885 (0.7); 7.2831 (0.8); 7.2794 (1.4); 7.2721 (0.8); 7.2709 (0.8); 7.2621 (0.6); 5.7546 (1.9); 4.7987 (6.1); 3.9249 (2.9); 3.9101 (2.8); 3.6297 (16.0); 3.3132 (9.4); 2.5240 (0.5); 2.5193 (0.7); 2.5106 (8.3); 2.5060 (17.9); 2.5014 (24.9); 2.4967 (17.2); 2.4921 (7.5); 1.9089 (0.8); 0.0081 (0.6); −0.0002 (19.8); −0.0086 (0.5) VII-036: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1044 (2.3); 8.0981 (2.3); 7.7584 (1.0); 7.7521 (1.0); 7.7395 (1.2); 7.7373 (1.3); 7.7333 (1.2); 7.7311 (1.2); 7.7185 (1.1); 7.7122 (1.1); 7.4086 (0.9); 7.4043 (1.0); 7.3894 (1.6); 7.3851 (1.9); 7.3705 (1.1); 7.3661 (1.2); 7.3556 (0.5); 7.3434 (0.5); 7.3366 (0.9); 7.3322 (0.8); 7.3243 (0.9); 7.3199 (0.8); 7.3180 (0.8); 7.3160 (0.9); 7.3114 (0.7); 7.3037 (0.8); 7.2992 (0.6); 7.2614 (13.2); 7.2125 (1.2); 7.2108 (1.2); 7.1914 (1.8); 7.1739 (0.8); 7.0357 (1.2); 7.0325 (1.1); 7.0149 (1.1); 7.0111 (1.8); 7.0074 (1.2); 6.9898 (1.0); 6.9866 (1.0); 6.9407 (1.6); 6.9394 (1.6); 6.9332 (1.6); 6.9194 (1.5); 6.9182 (1.5); 6.9120 (1.5); 5.2999 (1.3); 4.8940 (16.0); 4.2929 (2.0); 4.2750 (6.3); 4.2572 (6.4); 4.2394 (2.1); 1.5530 (4.5); 1.3072 (7.6); 1.2894 (15.7); 1.2715 (7.5); −0.0002 (18.1); −0.0085 (0.6) VII-021: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0711 (0.9); 8.0691 (0.7); 8.0670 (0.8); 8.0649 (1.0); 8.0630 (0.7); 7.7508 (0.5); 7.7446 (0.5); 7.7319 (0.6); 7.7297 (0.6); 7.7257 (0.6); 7.7234 (0.6); 7.7108 (0.6); 7.7045 (0.5); 7.4113 (0.7); 7.4070 (0.8); 7.3881 (0.5); 7.2610 (12.3); 7.2173 (0.5); 7.1976 (0.7); 7.0183 (0.8); 7.0144 (0.6); 6.9344 (0.7); 6.9328 (0.7); 6.9269 (0.7); 6.9254 (0.7); 6.9132 (0.6); 6.9116 (0.7); 6.9058 (0.7); 6.9042 (0.7); 4.9401 (7.2); 4.2897 (1.0); 4.2719 (2.9); 4.2540 (3.0); 4.2362 (1.0); 2.3166 (16.0); 1.5496 (2.5); 1.3066 (3.8); 1.2888 (8.0); 1.2709 (3.8); −0.0002 (16.7); −0.0085 (0.5) X-004: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 8.2053 (1.1); 8.1990 (1.2); 7.9459 (0.6); 7.9441 (0.7); 7.9396 (0.6); 7.9378 (0.6); 7.9248 (0.5); 7.5705 (0.7); 7.5669 (0.9); 7.5472 (0.5); 7.3343 (0.7); 7.3183 (1.1); 7.3156 (2.1); 7.2981 (1.2); 7.2961 (1.5); 7.2919 (1.4); 7.2785 (0.7); 7.2771 (0.8); 7.2713 (1.1); 4.9030 (4.8); 3.3275 (2.0); 3.2359 (12.0); 2.5243 (0.7); 2.5196 (0.8); 2.5109 (10.4); 2.5063 (22.7); 2.5017 (31.8); 2.4971 (22.1); 2.4925 (9.9); 2.0745 (16.0); 0.0079 (0.8); −0.0002 (28.5); −0.0027 (1.3); −0.0085 (0.8) X-003: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1208 (0.8); 8.1188 (0.6); 8.1164 (0.7); 8.1145 (0.9); 8.1127 (0.6); 7.7553 (0.5); 7.7490 (0.5); 7.4071 (0.8); 7.4041 (0.8); 7.4011 (0.7); 7.3876 (1.1); 7.2621 (5.7); 7.2590 (0.6); 7.2413 (0.8); 7.2395 (0.7); 7.0619 (0.6); 6.9760 (0.6); 6.9745 (0.6); 6.9686 (0.6); 6.9671 (0.6); 6.9547 (0.6); 6.9532 (0.6); 6.9473 (0.6); 6.9457 (0.6); 4.9362 (7.2); 4.3239 (0.7); 4.3025 (2.3); 4.2810 (2.4); 4.2595 (0.8); 2.0083 (16.0); −0.0002 (7.5) VII-027: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0709 (1.8); 8.0676 (1.6); 8.0650 (1.9); 7.7057 (0.7); 7.6994 (0.7); 7.6851 (1.0); 7.6830 (0.9); 7.6789 (1.0); 7.6659 (0.8); 7.6595 (0.8); 7.4483 (0.8); 7.4340 (0.9); 7.4267 (1.4); 7.4124 (1.4); 7.4052 (1.0); 7.3909 (0.9); 7.2613 (15.9); 6.9979 (0.7); 6.9942 (0.6); 6.9911 (0.6); 6.9874 (0.6); 6.9789 (0.6); 6.9754 (1.1); 6.9720 (1.2); 6.9686 (1.1); 6.9634 (1.7); 6.9618 (1.5); 6.9559 (1.9); 6.9542 (1.7); 6.9498 (0.7); 6.9461 (0.6); 6.9421 (1.5); 6.9406 (1.4); 6.9345 (1.5); 6.9329 (1.3); 6.8532 (0.9); 6.8464 (0.8); 6.8324 (1.0); 6.8283 (1.1); 6.8257 (1.0); 6.8216 (0.9); 6.8077 (1.0); 6.8009 (0.9); 4.8755 (15.8); 4.3013 (1.9); 4.2834 (6.0); 4.2656 (6.1); 4.2478 (2.0); 1.5511 (1.8); 1.3120 (7.7); 1.2942 (16.0); 1.2764 (7.6); 0.0080 (0.6); −0.0002 (21.0); −0.0085 (0.6) VII-037: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 8.1742 (1.5); 8.1680 (1.6); 7.9395 (0.6); 7.9332 (0.6); 7.9184 (0.9); 7.9121 (0.9); 7.8989 (0.7); 7.8926 (0.7); 7.5593 (0.6); 7.5443 (1.0); 7.5399 (1.3); 7.5248 (0.7); 7.5204 (0.7); 7.4710 (0.5); 7.4661 (0.5); 7.4583 (0.6); 7.4538 (0.5); 7.4506 (0.6); 7.3209 (0.6); 7.3179 (0.9); 7.3018 (1.0); 7.2985 (1.5); 7.2913 (0.9); 7.2888 (0.7); 7.2831 (1.5); 7.2777 (1.3); 7.2709 (0.8); 7.2653 (1.1); 7.2621 (1.7); 7.2561 (1.1); 7.2447 (0.7); 7.2416 (0.6); 4.8087 (7.0); 4.0556 (0.5); 4.0378 (1.7); 4.0201 (1.7); 4.0023 (0.6); 2.5240 (0.5); 2.5194 (0.8); 2.5106 (21.7); 2.5060 (49.6); 2.5014 (71.0); 2.4969 (50.4); 2.4923 (23.7); 1.9887 (7.9); 1.9086 (16.0); 1.3553 (3.7); 1.2356 (0.7); 1.1922 (2.3); 1.1744 (4.7); 1.1566 (2.3); 0.0080 (0.8); −0.0002 (31.9); −0.0050 (0.7); −0.0058 (0.6); −0.0085 (1.0) VII-006: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0896 (2.2); 8.0874 (1.7); 8.0852 (1.8); 8.0833 (2.3); 7.7571 (1.1); 7.7508 (1.1); 7.7384 (1.3); 7.7359 (1.4); 7.7321 (1.3); 7.7296 (1.3); 7.7172 (1.2); 7.7109 (1.1); 7.3684 (0.5); 7.3640 (0.7); 7.3579 (0.9); 7.3564 (1.0); 7.3516 (1.8); 7.3499 (1.9); 7.3453 (2.2); 7.3433 (2.5); 7.3399 (2.2); 7.3355 (3.5); 7.3328 (4.6); 7.3249 (3.6); 7.3218 (2.3); 7.3171 (9.0); 7.3142 (4.3); 7.3104 (4.7); 7.3066 (1.9); 7.3052 (1.8); 7.3005 (3.6); 7.2982 (1.8); 7.2940 (1.1); 7.2597 (34.6); 7.2103 (1.1); 7.2089 (1.2); 7.2071 (1.2); 7.1904 (1.8); 7.1889 (1.7); 7.1873 (1.5); 7.1719 (0.7); 7.1704 (0.7); 7.1686 (0.7); 7.0392 (1.1); 7.0361 (1.0); 7.0184 (1.1); 7.0145 (1.7); 7.0109 (1.0); 6.9933 (1.0); 6.9904 (0.9); 6.9439 (1.6); 6.9423 (1.5); 6.9364 (1.6); 6.9349 (1.4); 6.9227 (1.6); 6.9212 (1.4); 6.9152 (1.6); 6.9137 (1.4); 5.2489 (12.6); 4.9565 (16.0); 1.5404 (5.5); 1.2594 (0.6); 1.2556 (0.6); 0.8819 (0.7); 0.0079 (1.3); −0.0002 (46.7); −0.0085 (1.2) X-001: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1303 (2.5); 8.1283 (2.0); 8.1261 (2.0); 8.1240 (2.6); 8.1222 (1.8); 7.7599 (1.4); 7.7537 (1.4); 7.7413 (1.5); 7.7387 (1.6); 7.7350 (1.5); 7.7324 (1.6); 7.7201 (1.4); 7.7138 (1.4); 7.4635 (1.0); 7.4591 (1.2); 7.4442 (1.8); 7.4398 (2.1); 7.4254 (1.3); 7.4210 (1.4); 7.3986 (0.6); 7.3942 (0.6); 7.3864 (0.7); 7.3819 (0.7); 7.3798 (1.0); 7.3779 (0.9); 7.3754 (0.9); 7.3735 (0.9); 7.3675 (1.1); 7.3657 (0.9); 7.3631 (1.0); 7.3612 (0.9); 7.3590 (1.1); 7.3545 (0.9); 7.3468 (1.0); 7.3423 (0.8); 7.2628 (14.2); 7.2589 (1.4); 7.2572 (1.4); 7.2554 (1.4); 7.2540 (1.3); 7.2358 (1.9); 7.2203 (0.8); 7.2186 (0.9); 7.2169 (0.8); 7.2154 (0.8); 7.0645 (1.3); 7.0612 (1.3); 7.0436 (1.2); 7.0398 (2.1); 7.0361 (1.4); 7.0185 (1.2); 7.0153 (1.1); 6.9556 (1.8); 6.9540 (1.9); 6.9481 (1.9); 6.9465 (1.9); 6.9344 (1.7); 6.9328 (1.9); 6.9269 (1.8); 6.9252 (1.8); 6.6597 (0.6); 5.9488 (0.6); 5.9351 (1.4); 5.9230 (0.8); 5.9216 (0.8); 5.9094 (1.5); 5.9059 (0.8); 5.8958 (0.7); 5.8923 (1.6); 5.8801 (0.9); 5.8787 (0.9); 5.8666 (1.7); 5.8529 (0.8); 5.2999 (3.8); 5.2790 (0.9); 5.2747 (2.1); 5.2715 (2.2); 5.2672 (1.0); 5.2361 (0.8); 5.2318 (1.9); 5.2286 (1.9); 5.2244 (0.9); 5.1960 (0.9); 5.1924 (2.5); 5.1891 (2.4); 5.1855 (0.9); 5.1703 (0.8); 5.1667 (2.3); 5.1634 (2.2); 5.1598 (0.9); 4.8582 (16.0); 4.0392 (1.1); 4.0352 (2.1); 4.0312 (1.3); 4.0247 (2.1); 4.0209 (3.6); 4.0173 (2.2); 4.0108 (1.3); 4.0067 (2.1); 4.0027 (1.2); 1.5925 (0.7); 1.2543 (0.6); 0.0079 (0.5); −0.0002 (19.1); −0.0085 (0.6) X-005: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 11.7114 (0.7); 8.2113 (0.7); 8.2051 (0.8); 7.5735 (0.6); 7.3182 (1.3); 7.2985 (1.2); 7.2913 (0.8); 7.2769 (0.5); 7.2703 (0.7); 4.8803 (2.7); 3.3207 (16.0); 2.8972 (1.7); 2.7140 (14.7); 2.5193 (0.5); 2.5106 (10.5); 2.5060 (23.6); 2.5014 (33.3); 2.4968 (23.4); 2.4923 (10.6); 2.0742 (7.5); 1.9087 (1.1); −0.0002 (16.9); −0.0085 (0.5) VII-004: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1029 (0.7); 8.1010 (1.0); 8.0988 (0.7); 8.0968 (0.8); 8.0948 (1.0); 8.0927 (0.7); 7.7592 (0.6); 7.7529 (0.5); 7.7404 (0.6); 7.7380 (0.7); 7.7342 (0.6); 7.7317 (0.6); 7.7192 (0.6); 7.7130 (0.6); 7.3716 (0.7); 7.3672 (0.9); 7.3530 (0.5); 7.3485 (0.7); 7.2612 (7.5); 7.2123 (0.5); 7.2105 (0.6); 7.2091 (0.5); 7.1945 (0.7); 7.1930 (0.8); 7.1910 (0.8); 7.0410 (0.5); 7.0377 (0.5); 7.0162 (0.8); 7.0126 (0.5); 6.9375 (0.8); 6.9359 (0.7); 6.9300 (0.8); 6.9285 (0.7); 6.9163 (0.7); 6.9147 (0.7); 6.9088 (0.7); 6.9072 (0.7); 5.2998 (3.8); 5.2312 (1.5); 5.2138 (1.5); 3.7763 (16.0); 1.6951 (6.3); 1.6777 (6.2); 1.5531 (0.9); −0.0002 (10.8) VII-005: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1075 (1.0); 8.1054 (0.8); 8.1032 (0.9); 8.1013 (1.1); 7.7702 (0.6); 7.7639 (0.6); 7.7515 (0.6); 7.7490 (0.7); 7.7452 (0.6); 7.7427 (0.6); 7.7303 (0.6); 7.7240 (0.6); 7.4020 (0.8); 7.3977 (0.9); 7.3832 (0.5); 7.3788 (0.6); 7.2615 (6.6); 7.2222 (0.6); 7.2204 (0.6); 7.2192 (0.5); 7.2009 (0.8); 7.0449 (0.6); 7.0416 (0.5); 7.0241 (0.5); 7.0202 (0.9); 7.0165 (0.6); 6.9990 (0.5); 6.9430 (0.8); 6.9415 (0.8); 6.9355 (0.8); 6.9340 (0.7); 6.9218 (0.8); 6.9203 (0.7); 6.9143 (0.8); 6.9128 (0.7); 5.1486 (0.9); 5.1330 (1.2); 5.1173 (0.9); 4.8628 (9.4); 2.0074 (0.7); 1.5577 (1.0); 1.2742 (15.9); 1.2585 (16.0); −0.0002 (8.7) VII-005: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1082 (1.2); 8.1020 (1.2); 7.7704 (0.6); 7.7642 (0.6); 7.7516 (0.7); 7.7492 (0.7); 7.7454 (0.7); 7.7430 (0.7); 7.7304 (0.6); 7.7242 (0.6); 7.4172 (0.5); 7.4023 (0.9); 7.3980 (1.0); 7.3834 (0.6); 7.3790 (0.7); 7.2629 (8.5); 7.2223 (0.6); 7.2205 (0.6); 7.2012 (0.9); 7.0453 (0.6); 7.0420 (0.6); 7.0244 (0.6); 7.0205 (1.0); 7.0168 (0.6); 6.9992 (0.6); 6.9961 (0.5); 6.9432 (0.8); 6.9420 (0.8); 6.9358 (0.9); 6.9219 (0.8); 6.9207 (0.8); 6.9144 (0.8); 5.2999 (2.4); 5.1486 (1.0); 5.1329 (1.3); 5.1173 (1.0); 4.8630 (9.6); 1.5752 (0.8); 1.2742 (16.0); 1.2585 (15.9); −0.0002 (5.4) VII-117: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0431 (1.1); 8.0370 (1.2); 7.5899 (0.6); 7.5837 (0.6); 7.5708 (0.7); 7.5688 (0.8); 7.5646 (0.7); 7.5626 (0.7); 7.5498 (0.6); 7.5436 (0.6); 7.3986 (0.5); 7.3837 (0.9); 7.3794 (1.0); 7.3648 (0.6); 7.3603 (0.6); 7.2905 (0.5); 7.2784 (0.5); 7.2700 (0.5); 7.2653 (0.5); 7.2622 (5.8); 7.2579 (0.6); 7.1876 (0.6); 7.1862 (0.6); 7.1841 (0.7); 7.1676 (0.9); 7.1647 (1.0); 7.0145 (0.7); 7.0111 (0.6); 6.9937 (0.6); 6.9896 (1.0); 6.9857 (0.7); 6.9684 (0.6); 6.9650 (0.6); 6.9006 (0.9); 6.8993 (0.8); 6.8932 (0.9); 6.8918 (0.8); 6.8794 (0.8); 6.8781 (0.8); 6.8721 (0.8); 6.8707 (0.8); 5.2995 (0.7); 4.8755 (9.5); 4.2948 (1.2); 4.2770 (3.8); 4.2592 (3.9); 4.2413 (1.3); 2.0518 (16.0); 1.3125 (4.9); 1.2947 (10.1); 1.2769 (4.8); −0.0002 (8.1) VII-053: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 7.9479 (1.4); 7.9420 (1.5); 7.8614 (0.6); 7.8552 (0.5); 7.8408 (0.8); 7.8348 (0.7); 7.8214 (0.6); 7.8152 (0.6); 7.3799 (1.2); 7.3647 (1.5); 7.3603 (2.0); 7.3458 (1.4); 7.3410 (1.0); 7.3281 (0.5); 7.2609 (11.9); 7.2085 (0.8); 7.1894 (1.2); 7.0390 (0.6); 7.0148 (1.1); 6.9931 (0.6); 6.9140 (1.0); 6.9071 (1.0); 6.8927 (1.0); 6.8860 (0.9); 5.2997 (0.6); 4.9662 (9.5); 4.3106 (1.2); 4.2928 (3.6); 4.2750 (3.7); 4.2571 (1.2); 2.5702 (16.0); 1.3203 (4.3); 1.3025 (8.7); 1.2846 (4.6); 1.2550 (4.0); 0.8800 (0.6); 0.0079 (0.5); −0.0002 (15.8); −0.00084 (0.5) VII-053: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 7.9474 (1.0); 7.9412 (1.1); 7.8408 (0.6); 7.8347 (0.6); 7.3801 (1.0); 7.3649 (1.2); 7.3603 (1.5); 7.3464 (1.0); 7.3410 (0.9); 7.2604 (31.9); 7.2088 (0.6); 7.1915 (0.9); 7.1896 (0.9); 7.0178 (0.5); 7.0149 (0.9); 7.0117 (0.6); 6.9932 (0.6); 6.9154 (0.8); 6.9139 (0.8); 6.9081 (0.8); 6.9066 (0.8); 6.8941 (0.8); 6.8926 (0.8); 6.8869 (0.8); 6.8854 (0.8); 4.9662 (8.2); 4.3107 (1.0); 4.2929 (3.2); 4.2750 (3.3); 4.2572 (1.1); 2.5811 (0.7); 2.5702 (16.0); 1.5412 (4.0); 1.3205 (4.2); 1.3027 (8.6); 1.2848 (4.2); 1.2549 (0.9); 1.2009 (0.6); 1.1836 (0.6); 0.0079 (1.1); −0.0002 (44.6); −0.00061 (0.6); −0.00085 (1.4) VII-053: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 7.9491 (1.3); 7.9430 (1.5); 7.8602 (0.6); 7.8540 (0.5); 7.8393 (0.8); 7.8347 (0.7); 7.8201 (0.6); 7.8139 (0.5); 7.3797 (1.1); 7.3645 (1.5); 7.3599 (1.8); 7.3548 (0.6); 7.3458 (1.4); 7.3410 (1.0); 7.3276 (0.5); 7.2625 (4.1); 7.2082 (0.8); 7.1890 (1.2); 7.0385 (0.6); 7.0146 (1.1); 6.9928 (0.6); 6.9129 (0.9); 6.9068 (1.0); 6.8916 (0.9); 6.8855 (0.9); 5.2989 (6.0); 4.9663 (8.9); 4.3102 (1.2); 4.2924 (3.5); 4.2745 (3.5); 4.2567 (1.2); 2.5806 (0.5); 2.5698 (16.0); 1.5757 (1.8); 1.3198 (4.2); 1.3020 (8.6); 1.2841 (4.1); −0.0002 (6.1) VII-032: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.6625 (0.8); 8.6587 (0.8); 8.6500 (0.8); 8.6462 (0.7); 8.5786 (1.2); 8.5744 (1.1); 7.7219 (0.6); 7.7174 (0.8); 7.7124 (0.6); 7.7020 (0.7); 7.6973 (0.9); 7.6924 (0.6); 7.4333 (0.6); 7.4208 (0.6); 7.4135 (0.6); 7.4004 (0.6); 7.3195 (0.5); 7.3041 (2.0); 7.3003 (0.8); 7.2965 (0.7); 7.2898 (1.0); 7.2857 (3.0); 7.2814 (1.8); 7.2773 (1.2); 7.2662 (1.0); 7.2605 (17.1); 7.1267 (1.8); 7.1221 (1.9); 7.1167 (0.5); 7.1108 (0.8); 7.1059 (1.7); 7.1023 (1.6); 5.2749 (1.6); 5.2575 (1.6); 3.7934 (16.0); 1.7087 (6.5); 1.6913 (6.4); 0.0080 (0.6); −0.0002 (22.7); −0.00085 (0.7) VII-088: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1769 (1.2); 8.1749 (1.8); 8.1729 (1.4); 8.1707 (1.4); 8.1685 (1.9); 8.1666 (1.3); 7.8312 (1.1); 7.8249 (1.1); 7.8125 (1.2); 7.8099 (1.3); 7.8062 (1.2); 7.8036 (1.2); 7.7912 (1.1); 7.7849 (1.1); 7.4530 (0.7); 7.4486 (0.8); 7.4338 (1.3); 7.4294 (1.5); 7.4149 (0.9); 7.4106 (1.0); 7.3843 (0.5); 7.3798 (0.5); 7.3776 (0.8); 7.3757 (0.7); 7.3732 (0.7); 7.3713 (0.6); 7.3654 (0.8); 7.3636 (0.6); 7.3610 (0.7); 7.3591 (0.7); 7.3569 (0.8); 7.3524 (0.6); 7.3447 (0.7); 7.3403 (0.6); 7.2609 (27.9); 7.2479 (0.9); 7.2463 (1.0); 7.2446 (1.0); 7.2431 (0.9); 7.2249 (1.4); 7.2094 (0.6); 7.2077 (0.6); 7.2060 (0.6); 7.2044 (0.6); 7.0756 (1.0); 7.0724 (1.0); 7.0548 (0.9); 7.0511 (1.6); 7.0473 (1.0); 7.0298 (0.8); 7.0265 (0.8); 6.9298 (1.3); 6.9282 (1.4); 6.9223 (1.3); 6.9207 (1.4); 6.9085 (1.3); 6.9069 (1.3); 6.9010 (1.3); 6.8994 (1.3); 4.9013 (14.3); 4.2919 (1.8); 4.2741 (5.8); 4.2563 (5.9); 4.2385 (1.9); 3.2052 (11.9); 1.3021 (7.6); 1.2843 (16.0); 1.2664 (7.5); 1.2544 (0.6); 0.0080 (1.1); 0.0041 (0.6); −0.0002 (38.3); −0.00050 (0.6); −0.00058 (0.5); −0.00084 (1.1) VI-010: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1936 (1.6); 8.6598 (1.4); 7.3518 (0.5); 7.3364 (1.9); 7.3325 (0.8); 7.3288 (0.7); 7.3221 (1.0); 7.3180 (2.9); 7.3137 (1.7); 7.3096 (1.1); 7.2987 (0.7); 7.2962 (0.6); 7.2615 (17.8); 7.1388 (1.7); 7.1342 (1.9); 7.1288 (0.6); 7.1229 (0.8); 7.1180 (1.7); 7.1145 (1.6); 5.2998 (2.4); 5.2720 (1.6); 5.2545 (1.6); 3.7913 (16.0); 1.7095 (6.5); 1.6920 (6.5); −0.0002 (12.4) VII-119: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1165 (1.7); 8.1144 (1.3); 8.1122 (1.4); 8.1103 (1.7); 7.6766 (0.9); 7.6704 (0.8); 7.6576 (1.0); 7.6555 (1.1); 7.6514 (1.0); 7.6494 (1.0); 7.6365 (0.9); 7.6303 (0.9); 7.3818 (0.7); 7.3774 (0.8); 7.3625 (1.3); 7.3581 (1.5); 7.3436 (0.9); 7.3392 (1.0); 7.2955 (0.5); 7.2934 (0.7); 7.2916 (0.6); 7.2890 (0.6); 7.2871 (0.5); 7.2813 (0.7); 7.2796 (0.6); 7.2767 (0.6); 7.2749 (0.6); 7.2727 (0.7); 7.2693 (0.5); 7.2685 (0.7); 7.2670 (0.5); 7.2661 (0.6); 7.2621 (44.0); 7.2587 (1.0); 7.2579 (0.8); 7.2570 (0.8); 7.2563 (1.0); 7.1845 (0.8); 7.1830 (0.9); 7.1810 (0.9); 7.1798 (0.8); 7.1643 (1.2); 7.1615 (1.3); 7.1461 (0.5); 7.1445 (0.6); 7.1426 (0.5); 7.0180 (0.9); 7.0147 (0.9); 6.9974 (0.8); 6.9932 (1.3); 6.9893 (0.9); 6.9719 (0.8); 6.9686 (0.7); 6.8968 (1.2); 6.8953 (1.2); 6.8894 (1.3); 6.8878 (1.2); 6.8757 (1.2); 6.8742 (1.2); 6.8682 (1.2); 6.8667 (1.1); 4.8941 (0.8); 4.8515 (13.2); 4.2803 (1.6); 4.2625 (5.2); 4.2577 (0.5); 4.2447 (5.2); 4.2269 (1.7); 1.5839 (1.6); 1.5675 (4.8); 1.5569 (0.9); 1.5500 (1.3); 1.5333 (0.5); 1.3056 (6.9); 1.2878 (14.5); 1.2699 (6.7); 0.7740 (16.0); 0.7632 (1.0); 0.7566 (6.2); 0.7524 (1.1); 0.7506 (1.0); 0.0080 (0.8); −0.0002 (29.4); −0.00085 (0.8) VII-091: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1128 (2.3); 8.1107 (1.7); 8.1085 (1.8); 8.1065 (2.3); 7.7721 (1.2); 7.7658 (1.2); 7.7534 (1.4); 7.7508 (1.4); 7.7471 (1.4); 7.7446 (1.4); 7.7322 (1.3); 7.7259 (1.2); 7.4163 (0.9); 7.4120 (1.0); 7.3971 (1.6); 7.3928 (1.9); 7.3779 (1.5); 7.3736 (1.6); 7.3654 (0.6); 7.3608 (0.7); 7.3587 (1.0); 7.3569 (0.8); 7.3542 (0.8); 7.3525 (0.7); 7.3464 (1.0); 7.3448 (0.8); 7.3420 (0.8); 7.3401 (0.8); 7.3380 (0.9); 7.3335 (0.7); 7.3258 (0.8); 7.3213 (0.6); 7.2629 (14.6); 7.2303 (1.1); 7.2287 (1.2); 7.2270 (1.2); 7.2094 (1.7); 7.2075 (1.7); 7.1918 (0.7); 7.1901 (0.8); 7.1884 (0.7); 7.1870 (0.6); 7.0561 (1.2); 7.0529 (1.1); 7.0352 (1.1); 7.0314 (1.9); 7.0277 (1.2); 7.0102 (1.0); 7.0070 (1.0); 6.9490 (1.6); 6.9475 (1.6); 6.9416 (1.7); 6.9401 (1.6); 6.9278 (1.6); 6.9263 (1.6); 6.9203 (1.6); 6.9188 (1.5); 4.9162 (16.0); 4.2474 (1.4); 4.2313 (1.4); 4.2205 (2.2); 4.2043 (2.2); 4.1318 (2.3); 4.1121 (2.4); 4.1048 (1.5); 4.0851 (1.5); 3.8493 (0.7); 3.8355 (0.8); 3.8285 (1.5); 3.8146 (1.5); 3.8081 (1.2); 3.8028 (1.7); 3.7943 (1.1); 3.7849 (1.8); 3.7806 (2.0); 3.7628 (2.0); 3.7454 (1.2); 3.7278 (1.7); 3.7265 (1.7); 3.7089 (1.4); 3.7068 (1.2); 3.6877 (0.8); 3.5455 (1.9); 3.5315 (2.0); 3.5233 (1.6); 3.5093 (1.6); 2.6120 (0.6); 2.5948 (0.8); 2.5775 (0.6); 2.0243 (0.5); 2.0187 (0.6); 2.0082 (7.8); 1.9977 (0.5); 1.9930 (0.6); 1.9872 (0.8); 1.9850 (0.8); 1.9733 (0.7); 1.9664 (0.5); 1.6551 (0.5); 1.6379 (0.7); 1.6355 (0.6); 1.6231 (1.0); 1.6201 (0.7); 1.6064 (0.6); 1.6035 (0.9); 1.5912 (0.5); 1.5887 (0.6); −0.0002 (17.1) VII-090: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1014 (2.2); 8.0995 (1.7); 8.0972 (1.7); 8.0951 (2.3); 7.7655 (1.1); 7.7593 (1.1); 7.7468 (1.3); 7.7443 (1.4); 7.7405 (1.3); 7.7381 (1.4); 7.7256 (1.2); 7.7194 (1.2); 7.4364 (0.9); 7.4320 (1.0); 7.4171 (1.6); 7.4128 (1.8); 7.3983 (1.1); 7.3939 (1.2); 7.3692 (0.5); 7.3647 (0.5); 7.3570 (0.6); 7.3524 (0.6); 7.3503 (0.9); 7.3484 (0.8); 7.3459 (0.8); 7.3440 (0.7); 7.3381 (0.9); 7.3363 (0.7); 7.3336 (0.8); 7.3317 (0.7); 7.3296 (0.9); 7.3251 (0.7); 7.3174 (0.8); 7.3129 (0.7); 7.2610 (47.1); 7.2285 (1.0); 7.2269 (1.0); 7.2250 (1.2); 7.2054 (1.7); 7.1883 (0.7); 7.1866 (0.7); 7.0435 (1.1); 7.0402 (1.1); 7.0227 (1.1); 7.0189 (1.8); 7.0151 (1.2); 6.9975 (1.3); 6.9943 (1.0); 6.9448 (1.5); 6.9434 (1.6); 6.9374 (1.6); 6.9359 (1.6); 6.9237 (1.5); 6.9222 (1.6); 6.9162 (1.5); 6.9147 (1.5); 4.9517 (16.0); 4.2859 (0.5); 4.2801 (1.7); 4.2613 (2.4); 4.2554 (1.2); 4.1828 (1.7); 4.1677 (3.4); 4.1541 (1.6); 4.1496 (0.9); 4.1433 (3.7); 4.1382 (1.6); 4.1289 (0.8); 4.1223 (0.7); 3.8830 (0.8); 3.8661 (1.5); 3.8622 (1.4); 3.8496 (0.9); 3.8453 (2.3); 3.8290 (1.1); 3.7924 (1.0); 3.7749 (1.4); 3.7592 (1.2); 3.7545 (1.0); 3.7386 (0.6); 2.0080 (1.1); 1.9753 (0.5); 1.9717 (0.6); 1.9680 (0.5); 1.9544 (0.8); 1.9420 (0.7); 1.9252 (0.7); 1.9122 (0.6); 1.8972 (0.8); 1.8922 (0.8); 1.8824 (1.5); 1.8771 (1.1); 1.8657 (1.4); 1.8618 (1.4); 1.8480 (0.7); 1.8451 (1.1); 1.6389 (0.8); 1.6176 (0.8); 1.6088 (0.7); 1.6008 (0.6); 1.5887 (0.6); 1.5552 (4.2); 0.0080 (1.5); 0.0041 (0.6); −0.0002 (55.1); −0.00057 (0.8); −0.00065 (0.7); −0.00085 (1.7) VII-098: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0965 (2.0); 8.0945 (1.6); 8.0924 (1.6); 8.0902 (2.1); 8.0885 (1.4); 7.7641 (1.1); 7.7578 (1.1); 7.7454 (1.2); 7.7429 (1.4); 7.7391 (1.2); 7.7366 (1.3); 7.7242 (1.2); 7.7179 (1.2); 7.4005 (3.3); 7.3984 (3.7); 7.3959 (3.7); 7.3937 (3.9); 7.3780 (1.4); 7.3736 (1.8); 7.3679 (0.7); 7.3634 (0.6); 7.3590 (1.0); 7.3552 (1.6); 7.3511 (0.7); 7.3489 (1.0); 7.3472 (0.8); 7.3445 (0.7); 7.3427 (0.7); 7.3366 (1.0); 7.3351 (0.8); 7.3321 (0.7); 7.3305 (0.7); 7.3283 (0.9); 7.3238 (0.7); 7.3161 (0.8); 7.3116 (0.6); 7.2608 (24.0); 7.2234 (1.0); 7.2219 (1.1); 7.2200 (1.1); 7.2187 (1.0); 7.2040 (1.4); 7.2026 (1.5); 7.2005 (1.6); 7.1850 (0.6); 7.1833 (0.7); 7.1815 (0.6); 7.1801 (0.6); 7.0398 (1.1); 7.0365 (1.0); 7.0189 (1.0); 7.0152 (1.7); 7.0113 (1.1); 6.9939 (1.0); 6.9907 (0.9); 6.9445 (1.5); 6.9429 (1.5); 6.9370 (1.5); 6.9355 (1.5); 6.9232 (1.4); 6.9217 (1.5); 6.9158 (1.4); 6.9142 (1.4); 6.4352 (1.9); 6.4344 (2.0); 6.4279 (2.4); 6.4272 (2.3); 6.4262 (2.4); 6.3517 (2.2); 6.3471 (2.3); 6.3436 (2.0); 6.3389 (1.8); 5.1910 (12.7); 4.9293 (16.0); 0.0079 (0.8); −0.0002 (26.8); −0.00051 (0.5); −0.00085 (0.9) VII-103: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1052 (1.4); 8.1034 (2.1); 8.1013 (1.6); 8.0992 (1.7); 8.0971 (2.2); 8.0951 (1.5); 7.7669 (1.2); 7.7606 (1.1); 7.7481 (1.3); 7.7456 (1.4); 7.7419 (1.3); 7.7394 (1.4); 7.7269 (1.2); 7.7207 (1.2); 7.4456 (0.9); 7.4413 (1.0); 7.4263 (1.5); 7.4220 (1.7); 7.4075 (1.1); 7.4031 (1.2); 7.3701 (0.5); 7.3657 (0.5); 7.3580 (0.6); 7.3534 (0.6); 7.3513 (0.9); 7.3494 (0.8); 7.3468 (0.8); 7.3450 (0.7); 7.3391 (0.9); 7.3373 (0.7); 7.3347 (0.8); 7.3327 (0.7); 7.3306 (0.9); 7.3261 (0.7); 7.3184 (0.8); 7.3139 (0.7); 7.2617 (24.5); 7.2313 (1.0); 7.2297 (1.1); 7.2279 (1.1); 7.2265 (1.1); 7.2082 (1.6); 7.1928 (0.6); 7.1912 (0.7); 7.1894 (0.7); 7.1880 (0.6); 7.0440 (1.1); 7.0408 (1.1); 7.0232 (1.0); 7.0194 (1.8); 7.0156 (1.2); 6.9981 (1.1); 6.9949 (1.0); 6.9455 (1.5); 6.9439 (1.6); 6.9380 (1.6); 6.9364 (1.6); 6.9242 (1.4); 6.9226 (1.6); 6.9167 (1.5); 6.9151 (1.5); 5.1834 (2.3); 5.1740 (5.1); 5.1646 (2.4); 4.9639 (16.0); 4.2600 (8.8); 4.2506 (8.7); 4.0052 (1.7); 3.9920 (2.1); 3.9891 (3.2); 3.9873 (4.1); 3.9827 (3.0); 3.9775 (2.7); 3.9706 (3.6); 3.9469 (1.2); 3.9316 (1.1); 3.9078 (3.4); 3.9010 (2.5); 3.8958 (2.7); 3.8911 (4.1); 3.8893 (3.2); 3.8865 (2.1); 3.8733 (1.7); 2.0079 (3.3); 1.5997 (0.7); 0.0080 (0.8); −0.0002 (27.2); −0.00084 (0.8) VII-064: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1188 (1.4); 8.1126 (1.4); 7.7713 (0.7); 7.7651 (0.7); 7.7526 (0.8); 7.7501 (0.8); 7.7464 (0.8); 7.7439 (0.8); 7.7314 (0.7); 7.7252 (0.7); 7.4661 (0.6); 7.4617 (0.6); 7.4468 (1.0); 7.4425 (1.1); 7.4279 (0.7); 7.4235 (0.8); 7.3575 (0.5); 7.3531 (0.5); 7.3453 (0.6); 7.3409 (0.5); 7.3368 (0.5); 7.2613 (25.2); 7.2391 (0.6); 7.2376 (0.7); 7.2357 (0.7); 7.2161 (1.0); 7.0480 (0.7); 7.0447 (0.7); 7.0272 (0.7); 7.0233 (1.1); 7.0196 (0.7); 7.0020 (0.6); 6.9986 (0.6); 6.9478 (0.9); 6.9463 (1.0); 6.9403 (1.0); 6.9389 (1.0); 6.9265 (0.9); 6.9251 (1.0); 6.9192 (0.9); 6.9177 (0.9); 5.5359 (1.2); 5.5130 (1.6); 5.4913 (1.2); 5.0660 (0.7); 5.0255 (5.3); 5.0151 (5.2); 4.9745 (0.7); 4.4959 (0.5); 4.4891 (0.6); 4.4732 (1.1); 4.4663 (1.1); 4.4505 (0.7); 4.4436 (0.7); 4.3398 (0.8); 4.3234 (0.9); 4.3161 (1.4); 4.2998 (1.4); 4.2926 (0.7); 4.2762 (0.6); 2.7294 (0.5); 2.3647 (0.8); 2.3423 (0.8); 2.3320 (0.8); 2.3096 (0.7); 2.0085 (16.0); 0.0080 (0.8); −0.0002 (29.3); −0.00084 (0.9) VII-110: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1262 (1.5); 8.1199 (1.6); 7.7700 (0.8); 7.7637 (0.8); 7.7513 (1.0); 7.7488 (1.0); 7.7451 (0.9); 7.7425 (0.9); 7.7301 (0.9); 7.7239 (0.8); 7.4489 (0.7); 7.4446 (0.8); 7.4296 (1.2); 7.4252 (1.3); 7.4108 (0.8); 7.4064 (0.9); 7.3667 (0.5); 7.3645 (0.7); 7.3627 (0.6); 7.3602 (0.6); 7.3583 (0.5); 7.3523 (0.7); 7.3506 (0.6); 7.3479 (0.6); 7.3460 (0.6); 7.3439 (0.7); 7.3394 (0.5); 7.3316 (0.6); 7.2608 (39.6); 7.2575 (1.0); 7.2567 (0.8); 7.2394 (0.8); 7.2378 (0.8); 7.2360 (0.8); 7.2345 (0.8); 7.2162 (1.2); 7.2009 (0.5); 7.1991 (0.5); 7.1975 (0.5); 7.0545 (0.8); 7.0513 (0.8); 7.0336 (0.8); 7.0298 (1.4); 7.0261 (0.9); 7.0085 (0.8); 7.0053 (0.7); 6.9527 (1.1); 6.9512 (1.1); 6.9453 (1.2); 6.9438 (1.1); 6.9315 (1.1); 6.9300 (1.1); 6.9241 (1.1); 6.9225 (1.0); 5.0026 (13.1); 4.9814 (0.6); 4.8464 (16.0); 2.0089 (7.9); 0.0080 (1.3); −0.0002 (48.2); −0.00058 (0.6); −0.00085 (1.4) VII-104: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1259 (2.2); 8.1197 (2.3); 7.7773 (1.1); 7.7710 (1.1); 7.7585 (1.3); 7.7560 (1.3); 7.7523 (1.3); 7.7498 (1.2); 7.7373 (1.2); 7.7311 (1.1); 7.4245 (0.8); 7.4202 (1.0); 7.4052 (1.5); 7.4009 (1.8); 7.3864 (1.0); 7.3820 (1.3); 7.3790 (0.6); 7.3746 (0.5); 7.3668 (0.6); 7.3622 (0.6); 7.3601 (0.9); 7.3583 (0.8); 7.3557 (0.8); 7.3539 (0.7); 7.3478 (1.0); 7.3461 (0.7); 7.3433 (0.8); 7.3415 (0.8); 7.3394 (0.8); 7.3350 (0.7); 7.3272 (0.8); 7.3228 (0.6); 7.2611 (33.3); 7.2262 (1.0); 7.2245 (1.1); 7.2228 (1.1); 7.2033 (1.6); 7.1876 (0.7); 7.1860 (0.7); 7.1843 (0.7); 7.0622 (1.1); 7.0590 (1.1); 7.0414 (1.0); 7.0376 (1.8); 7.0339 (1.2); 7.0164 (1.0); 7.0131 (0.9); 6.9457 (1.5); 6.9442 (1.5); 6.9384 (1.6); 6.9369 (1.4); 6.9245 (1.5); 6.9230 (1.4); 6.9171 (1.5); 6.9156 (1.4); 4.9689 (16.0); 4.4254 (4.0); 4.4096 (8.2); 4.3939 (4.1); 2.7434 (4.8); 2.7277 (9.6); 2.7119 (4.5); 2.0090 (3.4); 0.0080 (1.0); −0.0002 (39.3); −0.00029 (1.6); −0.00053 (0.5); −0.00085 (1.2) VII-052: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1052 (0.9); 8.1010 (0.7); 8.0989 (0.9); 7.7510 (0.5); 7.7484 (0.6); 7.7447 (0.5); 7.7422 (0.6); 7.4139 (0.6); 7.4096 (0.7); 7.3907 (0.5); 7.2615 (10.4); 7.2249 (0.5); 7.2052 (0.7); 7.0209 (0.8); 6.9465 (0.6); 6.9451 (0.7); 6.9391 (0.6); 6.9377 (0.6); 6.9253 (0.6); 6.9238 (0.6); 6.9179 (0.6); 6.9164 (0.6); 4.9551 (6.9); 4.3697 (1.7); 4.3615 (0.8); 4.3580 (1.7); 4.3543 (0.8); 4.3462 (1.8); 3.6295 (2.0); 3.6215 (0.9); 3.6177 (1.8); 3.6144 (0.9); 3.6060 (1.9); 3.3589 (16.0); −0.0002 (12.0) VII-124: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1097 (1.0); 8.1076 (0.7); 8.1054 (0.8); 8.1034 (1.0); 7.7693 (0.5); 7.7631 (0.5); 7.7506 (0.6); 7.7481 (0.6); 7.7444 (0.6); 7.7418 (0.6); 7.7294 (0.6); 7.7231 (0.5); 7.4094 (0.7); 7.4050 (0.8); 7.3862 (0.6); 7.2610 (17.4); 7.2282 (0.5); 7.2085 (0.7); 7.0286 (0.8); 7.0249 (0.5); 6.9471 (0.7); 6.9455 (0.7); 6.9397 (0.7); 6.9381 (0.7); 6.9259 (0.7); 6.9243 (0.7); 6.9184 (0.7); 6.9168 (0.6); 4.9300 (7.3); 4.3973 (1.8); 4.3802 (3.8); 4.3631 (1.9); 2.7594 (2.0); 2.7423 (4.0); 2.7252 (1.9); 2.1371 (16.0); 2.0083 (1.1); 0.0079 (0.6); −0.0002 (20.9); −0.00027 (0.9); −0.00085 (0.6) VII-108: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1138 (2.0); 8.1118 (1.5); 8.1095 (1.6); 8.1075 (2.1); 7.7733 (1.0); 7.7670 (1.0); 7.7546 (1.2); 7.7520 (1.3); 7.7484 (1.2); 7.7458 (1.2); 7.7334 (1.1); 7.7271 (1.1); 7.4261 (0.8); 7.4218 (1.0); 7.4069 (1.4); 7.4025 (1.7); 7.3881 (1.0); 7.3837 (1.2); 7.3756 (0.6); 7.3712 (0.5); 7.3634 (0.6); 7.3589 (0.6); 7.3568 (0.9); 7.3549 (0.7); 7.3523 (0.7); 7.3505 (0.7); 7.3445 (0.9); 7.3427 (0.7); 7.3401 (0.7); 7.3382 (0.7); 7.3360 (0.8); 7.3316 (0.7); 7.3239 (0.8); 7.3194 (0.6); 7.2611 (28.0); 7.2299 (0.9); 7.2283 (1.0); 7.2265 (1.1); 7.2252 (1.0); 7.2069 (1.5); 7.1914 (0.6); 7.1898 (0.7); 7.1880 (0.6); 7.1866 (0.6); 7.0530 (1.1); 7.0498 (1.0); 7.0322 (1.0); 7.0284 (1.7); 7.0246 (1.1); 7.0071 (0.9); 7.0039 (0.9); 6.9508 (1.4); 6.9493 (1.4); 6.9434 (1.5); 6.9419 (1.4); 6.9295 (1.4); 6.9280 (1.4); 6.9222 (1.4); 6.9207 (1.3); 4.9635 (16.0); 4.4706 (4.0); 4.4565 (4.7); 4.4543 (3.0); 4.4419 (4.3); 3.7075 (5.1); 3.6952 (3.5); 3.6930 (5.4); 3.6915 (3.8); 3.6788 (4.8); 2.0089 (4.7); 0.0079 (0.9); −0.0002 (33.2); −0.00052 (0.5); −0.00085 (1.0) X-011: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1016 (2.8); 8.0955 (2.7); 7.7711 (1.2); 7.7647 (1.2); 7.7498 (1.6); 7.7435 (1.5); 7.7310 (1.3); 7.7247 (1.4); 7.4293 (1.1); 7.4248 (1.2); 7.4100 (1.9); 7.4057 (2.2); 7.3912 (1.3); 7.3868 (1.4); 7.3640 (0.6); 7.3595 (0.7); 7.3518 (0.6); 7.3450 (1.0); 7.3327 (1.0); 7.3244 (1.0); 7.3197 (0.8); 7.3122 (0.9); 7.3078 (0.8); 7.2604 (51.4); 7.2204 (1.4); 7.2008 (2.1); 7.1834 (0.9); 7.0410 (1.4); 7.0378 (1.4); 7.0202 (1.3); 7.0164 (2.2); 7.0126 (1.5); 6.9954 (1.4); 6.9919 (1.2); 6.9399 (1.9); 6.9324 (1.9); 6.9185 (1.9); 6.9111 (1.8); 5.4435 (16.0); 5.2998 (8.7); 4.2178 (3.8); 4.1996 (6.6); 4.1811 (4.2); 3.4017 (5.2); 3.3831 (7.6); 3.3650 (4.7); 2.2838 (1.7); 2.2264 (1.3); 2.2187 (1.0); 2.1742 (0.5); 1.2555 (2.0); 0.0080 (1.6); −0.0002 (66.1); −0.00085 (2.0) VII-056-a: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1148 (1.2); 8.1131 (1.9); 8.1109 (1.5); 8.1088 (1.5); 8.1067 (1.9); 8.1047 (1.3); 7.6692 (1.1); 7.6629 (1.1); 7.6505 (1.2); 7.6479 (1.3); 7.6442 (1.2); 7.6417 (1.3); 7.6292 (1.2); 7.6229 (1.2); 7.2954 (0.6); 7.2800 (1.4); 7.2767 (1.4); 7.2617 (13.6); 7.2583 (1.7); 7.2317 (1.3); 7.2289 (1.6); 7.2276 (1.7); 7.2126 (0.8); 7.2112 (0.8); 7.2099 (0.8); 7.2084 (0.7); 7.1836 (0.6); 7.1823 (0.7); 7.1793 (0.6); 7.1781 (0.6); 7.1641 (1.3); 7.1627 (1.2); 7.1614 (1.0); 7.1599 (1.2); 7.1461 (0.6); 7.1447 (0.7); 7.1418 (0.6); 7.1405 (0.6); 7.0685 (1.7); 7.0652 (1.8); 7.0489 (1.2); 7.0456 (1.2); 6.8843 (1.4); 6.8828 (1.4); 6.8768 (1.4); 6.8752 (1.4); 6.8630 (1.3); 6.8615 (1.4); 6.8555 (1.3); 6.8539 (1.3); 5.2997 (9.0); 4.8934 (14.4); 4.2734 (1.8); 4.2556 (5.8); 4.2378 (5.8); 4.2200 (1.9); 2.0285 (13.4); 2.0072 (4.2); 1.5621 (3.6); 1.2980 (7.7); 1.2802 (16.0); 1.2623 (7.5); −0.0002 (14.2) VII-058: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1159 (2.1); 8.1141 (1.7); 8.1097 (2.2); 7.6611 (1.1); 7.6548 (1.1); 7.6423 (1.3); 7.6399 (1.4); 7.6361 (1.3); 7.6336 (1.4); 7.6211 (1.2); 7.6148 (1.2); 7.2815 (0.5); 7.2782 (0.6); 7.2615 (14.0); 7.2445 (1.6); 7.2412 (1.7); 7.2149 (2.0); 7.1999 (0.9); 7.1958 (0.8); 7.1667 (0.7); 7.1635 (0.7); 7.1484 (1.4); 7.1472 (1.3); 7.1441 (1.3); 7.1292 (0.8); 7.1260 (0.7); 7.0489 (2.0); 7.0459 (2.0); 7.0294 (1.4); 7.0263 (1.4); 6.8821 (1.4); 6.8808 (1.5); 6.8746 (1.5); 6.8732 (1.5); 6.8608 (1.4); 6.8595 (1.5); 6.8533 (1.4); 6.8520 (1.5); 5.2996 (11.2); 4.8870 (15.6); 4.2688 (2.0); 4.2509 (6.3); 4.2331 (6.4); 4.2153 (2.1); 2.0288 (15.7); 2.0072 (2.0); 1.5635 (2.3); 1.2965 (7.7); 1.2787 (16.0); 1.2608 (7.7); 1.2552 (0.7); −0.0002 (14.2) VII-056: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 8.1520 (1.5); 8.1458 (1.6); 7.9115 (0.6); 7.9052 (0.6); 7.8906 (0.9); 7.8843 (0.9); 7.8708 (0.6); 7.8645 (0.6); 7.5684 (0.6); 7.5531 (1.0); 7.5489 (1.2); 7.5337 (0.6); 7.5294 (0.7); 7.4771 (0.6); 7.4723 (0.5); 7.4643 (0.6); 7.4571 (0.6); 7.3314 (0.7); 7.3284 (0.8); 7.3090 (2.0); 7.2967 (1.0); 7.2936 (1.1); 7.2759 (0.8); 7.2707 (1.0); 7.2634 (1.2); 7.2572 (1.1); 7.2497 (0.7); 7.2462 (0.7); 7.2421 (1.0); 7.2352 (1.0); 4.8502 (6.9); 2.5199 (0.5); 2.5110 (9.5); 2.5065 (21.4); 2.5019 (30.1); 2.4973 (21.3); 2.4928 (9.7); 2.2595 (16.0); 2.0745 (6.4); 1.9888 (1.4); 1.9092 (1.2); 1.3560 (0.8); 1.1745 (0.8); 0.0080 (0.6); −0.0002 (21.0); −0.00085 (0.6) X-007: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0770 (1.1); 8.0710 (1.2); 7.7237 (0.6); 7.7187 (0.6); 7.4453 (0.6); 7.4304 (0.8); 7.4262 (1.0); 7.4116 (0.7); 7.4075 (0.8); 7.3955 (0.6); 7.3830 (0.6); 7.3747 (0.6); 7.2623 (22.9); 7.2505 (0.6); 7.2489 (0.7); 7.2473 (0.8); 7.2278 (1.0); 7.0617 (0.8); 7.0586 (0.9); 7.0409 (1.0); 7.0373 (1.4); 7.0338 (1.0); 7.0160 (0.7); 7.0129 (0.6); 6.9491 (0.9); 6.9477 (0.9); 6.9416 (0.9); 6.9402 (0.9); 6.9278 (0.9); 6.9264 (1.0); 6.9204 (0.9); 6.9189 (0.9); 4.8956 (7.2); 4.8849 (0.6); 4.1730 (3.4); 4.1598 (3.4); 3.7990 (16.0); 1.5729 (1.6); −0.0002 (16.7); −0.00085 (0.6) VII-071: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0203 (1.0); 8.0140 (1.2); 7.8709 (0.5); 7.8691 (0.6); 7.8647 (0.5); 7.8630 (0.5); 7.3784 (0.8); 7.3766 (0.7); 7.3741 (0.9); 7.3682 (0.6); 7.3599 (0.9); 7.3577 (0.9); 7.3558 (1.1); 7.3402 (0.7); 7.3360 (0.5); 7.2617 (10.3); 7.2272 (0.5); 7.2255 (0.6); 7.2239 (0.6); 7.2227 (0.6); 7.2070 (0.9); 7.2055 (0.9); 7.2040 (0.9); 7.0626 (0.6); 7.0596 (0.5); 7.0416 (0.6); 7.0382 (1.0); 7.0349 (0.6); 7.0171 (0.5); 6.9398 (0.8); 6.9383 (0.9); 6.9325 (0.9); 6.9310 (0.8); 6.9186 (0.8); 6.9171 (0.8); 6.9112 (0.8); 6.9097 (0.8); 5.3001 (2.5); 4.9944 (8.4); 4.2982 (1.1); 4.2803 (3.6); 4.2625 (3.7); 4.2447 (1.2); 3.2838 (16.0); 1.3202 (4.7); 1.3024 (10.0); 1.2846 (4.8); −0.0002 (15.3); −0.00028 (0.6) VII-072: .sup.1H-NMR(599.6 MHz, CDCl3): δ = 8.0505 (7.4); 8.0470 (7.0); 7.8241 (2.3); 7.8200 (2.2); 7.8101 (3.8); 7.8078 (3.6); 7.7977 (2.4); 7.7937 (2.1); 7.4024 (4.6); 7.3899 (8.0); 7.3818 (3.9); 7.3773 (4.7); 7.3699 (2.1); 7.2625 (34.6); 7.2378 (3.5); 7.2245 (5.7); 7.2121 (2.6); 7.0685 (2.9); 7.0521 (5.0); 7.0376 (2.7); 6.9646 (4.2); 6.9601 (4.0); 6.9504 (4.1); 6.9459 (3.8); 5.2996 (0.4); 5.1377 (7.7); 5.1110 (9.3); 4.9934 (0.5); 4.8566 (9.2); 4.8299 (7.7); 4.2886 (3.7); 4.2767 (10.9); 4.2648 (11.1); 4.2529 (3.7); 3.2825 (0.8); 3.2281 (1.2); 3.2137 (49.4); 2.9860 (1.0); 2.6165 (50.0); 2.0753 (2.0); 1.6661 (0.7); 1.3333 (0.8); 1.3108 (13.8); 1.2989 (27.4); 1.2869 (13.8); 1.2703 (0.5); 1.2557 (1.9); 1.1891 (0.9); 1.1776 (0.9); 0.8802 (0.3); −0.00001 (36.8) VII-123: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.0733 (1.2); 8.0670 (1.2); 7.7519 (0.6); 7.7456 (0.6); 7.7329 (0.7); 7.7307 (0.7); 7.7267 (0.6); 7.7245 (0.7); 7.7118 (0.6); 7.7056 (0.6); 7.4279 (0.5); 7.4129 (0.8); 7.4086 (1.0); 7.3940 (0.6); 7.3896 (0.6); 7.2616 (7.3); 7.2211 (0.6); 7.2191 (0.6); 7.1996 (0.9); 7.0447 (0.6); 7.0414 (0.6); 7.0239 (0.6); 7.0200 (0.9); 7.0162 (0.6); 6.9986 (0.5); 6.9954 (0.5); 6.9339 (0.8); 6.9264 (0.8); 6.9125 (0.8); 6.9063 (0.8); 5.2996 (1.2); 4.9602 (7.6); 3.9240 (0.6); 3.8008 (14.1); 2.3125 (16.0); 2.3055 (0.8); 1.5601 (0.6); −0.0002 (9.6) VII-057: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0963 (1.6); 8.0943 (1.3); 8.0922 (1.4); 8.0901 (1.8); 8.0883 (1.2); 7.7494 (0.9); 7.7431 (0.9); 7.7306 (1.0); 7.7283 (1.0); 7.7244 (1.0); 7.7220 (1.0); 7.7095 (0.9); 7.7032 (0.9); 7.3777 (0.7); 7.3734 (0.8); 7.3585 (1.2); 7.3542 (1.5); 7.3398 (0.9); 7.3355 (1.1); 7.3292 (0.5); 7.3247 (0.5); 7.3225 (0.8); 7.3207 (0.6); 7.3181 (0.6); 7.3162 (0.6); 7.3102 (0.8); 7.3086 (0.6); 7.3058 (0.6); 7.3040 (0.6); 7.3018 (0.7); 7.2973 (0.6); 7.2897 (0.6); 7.2852 (0.5); 7.2613 (12.9); 7.1983 (0.8); 7.1967 (0.8); 7.1949 (0.9); 7.1936 (0.9); 7.1775 (1.2); 7.1753 (1.3); 7.1598 (0.5); 7.1582 (0.6); 7.1564 (0.6); 7.1550 (0.5); 7.0235 (0.9); 7.0202 (0.9); 7.0027 (0.8); 6.9988 (1.4); 6.9950 (0.9); 6.9775 (0.8); 6.9744 (0.8); 6.9335 (1.2); 6.9320 (1.2); 6.9261 (1.3); 6.9245 (1.3); 6.9123 (1.2); 6.9107 (1.2); 6.9049 (1.2); 6.9033 (1.2); 5.2053 (0.7); 5.1879 (2.6); 5.1705 (2.7); 5.1532 (0.7); 4.2603 (1.0); 4.2585 (1.0); 4.2425 (3.1); 4.2407 (3.3); 4.2246 (3.3); 4.2230 (3.3); 4.2068 (1.1); 4.2053 (1.1); 2.0451 (1.3); 1.6900 (0.6); 1.6856 (10.2); 1.6682 (10.1); 1.5565 (3.3); 1.5560 (3.3); 1.2772 (7.5); 1.2594 (16.0); 1.2416 (7.1); 0.8987 (0.8); 0.8818 (3.1); 0.8641 (1.1); −0.0002 (17.7); −0.00085 (0.5) VII-111: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1183 (0.7); 8.1164 (1.0); 8.1143 (0.8); 8.1122 (0.8); 8.1101 (1.1); 8.1082 (0.8); 7.7745 (0.6); 7.7683 (0.6); 7.7558 (0.6); 7.7533 (0.7); 7.7496 (0.6); 7.7471 (0.7); 7.7346 (0.6); 7.7284 (0.6); 7.4458 (0.5); 7.4309 (0.8); 7.4265 (0.9); 7.4120 (0.6); 7.4077 (0.6); 7.2625 (7.2); 7.2332 (0.5); 7.2315 (0.6); 7.2301 (0.5); 7.2145 (0.7); 7.2117 (0.8); 7.0485 (0.6); 7.0452 (0.6); 7.0277 (0.5); 7.0238 (0.9); 7.0200 (0.6); 6.9992 (0.5); 6.9447 (0.8); 6.9431 (0.8); 6.9372 (0.8); 6.9356 (0.8); 6.9234 (0.7); 6.9218 (0.8); 6.9159 (0.8); 6.9143 (0.8); 5.3004 (3.7); 4.9039 (8.1); 4.4975 (2.0); 4.4816 (4.2); 4.4657 (2.0); 3.6695 (16.0); 2.6997 (1.9); 2.6838 (3.9); 2.6679 (1.8); 1.5643 (1.6); 1.3381 (0.6); −0.0002 (9.8) VII-073: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 8.2556 (2.6); 8.2497 (2.7); 8.0425 (0.9); 8.0363 (0.9); 8.0224 (1.5); 8.0164 (1.5); 8.0021 (1.0); 7.9958 (0.9); 7.6317 (0.8); 7.6271 (1.0); 7.6112 (1.7); 7.6077 (1.9); 7.5927 (1.1); 7.5885 (1.1); 7.5309 (0.5); 7.5223 (0.6); 7.5156 (1.1); 7.5031 (1.0); 7.4987 (1.1); 7.4912 (0.7); 7.4828 (0.8); 7.4785 (0.6); 7.3285 (1.9); 7.3245 (1.6); 7.3214 (1.3); 7.3098 (2.6); 7.3037 (1.5); 7.2990 (2.0); 7.2954 (1.6); 7.2777 (1.2); 7.2292 (1.6); 7.2231 (1.7); 7.2076 (1.6); 7.2020 (1.7); 4.9285 (10.8); 3.6175 (0.6); 3.6071 (0.6); 3.6009 (1.5); 3.5949 (0.6); 3.5844 (0.7); 3.3341 (2.0); 3.3134 (20.8); 3.2786 (0.7); 2.6702 (0.6); 2.5366 (0.5); 2.5236 (2.2); 2.5102 (35.3); 2.5058 (71.2); 2.5013 (95.2); 2.4968 (68.6); 2.4924 (34.0); 2.3284 (0.6); 2.1831 (0.5); 2.0741 (16.0); 1.9085 (1.2); 1.7760 (0.6); 1.7669 (1.2); 1.7594 (1.8); 1.7505 (0.7); 1.7429 (0.6); 1.3554 (4.0); 1.2357 (1.7); 0.0080 (2.5); −0.0002 (60.3); −0.00085 (2.7) X-006: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.0838 (2.0); 8.0779 (2.0); 7.7500 (0.7); 7.7439 (0.6); 7.7288 (1.0); 7.7104 (0.7); 7.7041 (0.7); 7.4343 (0.5); 7.4216 (0.7); 7.4156 (0.9); 7.4058 (1.6); 7.4019 (1.4); 7.3950 (1.0); 7.3866 (2.1); 7.3826 (1.9); 7.3679 (1.3); 7.3638 (0.9); 7.2609 (51.2); 7.2558 (1.3); 7.2341 (1.7); 7.2153 (0.7); 7.0854 (1.1); 7.0826 (1.0); 7.0644 (1.0); 7.0610 (1.8); 7.0576 (1.0); 7.0398 (1.0); 7.0369 (0.9); 6.9671 (1.4); 6.9597 (1.4); 6.9447 (1.4); 6.9386 (1.4); 4.9602 (16.0); 4.3209 (1.7); 4.2995 (5.4); 4.2780 (5.5); 4.2566 (1.8); 2.1062 (1.4); 2.0081 (11.0); 1.2559 (0.9); 0.0080 (1.0); −0.0002 (37.5); −0.00086 (1.1) VII-074: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0561 (1.5); 8.0498 (1.5); 7.7580 (0.7); 7.7516 (0.6); 7.7396 (0.8); 7.7367 (0.8); 7.7333 (0.8); 7.7304 (0.8); 7.7185 (0.7); 7.7121 (0.7); 7.4745 (0.5); 7.4703 (0.6); 7.4553 (0.9); 7.4510 (1.1); 7.4371 (0.9); 7.4326 (1.0); 7.4185 (0.6); 7.4166 (0.5); 7.4141 (0.5); 7.4061 (0.6); 7.4044 (0.5); 7.4017 (0.5); 7.3977 (0.6); 7.3855 (0.6); 7.2732 (0.8); 7.2724 (0.8); 7.2717 (1.0); 7.2710 (1.0); 7.2701 (1.1); 7.2693 (1.1); 7.2685 (1.2); 7.2679 (1.0); 7.2670 (0.7); 7.2661 (0.9); 7.2653 (1.2); 7.2645 (1.6); 7.2613 (74.2); 7.2579 (1.7); 7.2571 (1.3); 7.2562 (1.1); 7.2554 (1.1); 7.2546 (1.2); 7.2538 (1.3); 7.2531 (1.4); 7.2523 (1.4); 7.2515 (1.2); 7.2507 (1.3); 7.2499 (1.2); 7.2492 (1.1); 7.2348 (0.6); 7.2328 (0.8); 7.2310 (0.5); 7.0884 (0.7); 7.0853 (0.7); 7.0675 (0.7); 7.0639 (1.2); 7.0605 (0.8); 7.0427 (0.7); 7.0395 (0.6); 6.9734 (1.0); 6.9720 (1.0); 6.9660 (1.0); 6.9646 (1.0); 6.9523 (1.0); 6.9508 (1.0); 6.9448 (1.0); 6.9433 (1.0); 5.0763 (1.0); 5.0424 (0.7); 5.0360 (4.7); 5.0223 (4.6); 4.9820 (0.9); 3.2521 (16.0); 2.1062 (0.6); 2.0084 (2.0); 1.4322 (3.6); 1.2843 (0.6); 1.2542 (1.0); 0.0080 (1.4); 0.0040 (0.5); 0.0024 (1.6); −0.0002 (48.1); −0.00049 (0.8); −0.00058 (0.7); −0.00085 (1.4) VII-096: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1083 (2.7); 8.1021 (3.0); 7.7660 (1.4); 7.7599 (1.5); 7.7474 (1.6); 7.7448 (1.7); 7.7412 (1.7); 7.7386 (1.7); 7.7262 (1.5); 7.7199 (1.5); 7.5187 (1.0); 7.4195 (1.1); 7.4154 (1.2); 7.4004 (1.9); 7.3960 (2.3); 7.3817 (1.3); 7.3773 (1.7); 7.3728 (0.9); 7.3683 (0.7); 7.3605 (0.8); 7.3539 (1.1); 7.3477 (1.0); 7.3416 (1.2); 7.3397 (1.0); 7.3333 (1.1); 7.3287 (0.8); 7.3209 (1.0); 7.3165 (0.7); 7.2858 (0.6); 7.2650 (0.9); 7.2643 (1.4); 7.2602 (198.8); 7.2240 (1.8); 7.2223 (1.7); 7.2026 (2.2); 7.1854 (1.1); 7.1837 (1.1); 7.0485 (1.5); 7.0453 (1.5); 7.0277 (1.4); 7.0238 (2.4); 7.0201 (1.7); 7.0026 (1.3); 6.9992 (1.3); 6.9966 (1.4); 6.9480 (2.0); 6.9465 (2.1); 6.9405 (2.1); 6.9390 (2.1); 6.9268 (1.9); 6.9251 (2.1); 6.9177 (2.1); 5.3180 (1.1); 5.3006 (4.5); 5.2831 (4.5); 5.2658 (1.2); 2.2718 (0.7); 2.1066 (8.0); 2.0459 (1.7); 1.7534 (15.8); 1.7359 (16.0); 1.5821 (0.9); 1.5647 (0.9); 1.5066 (0.6); 1.4892 (0.6); 1.4322 (7.0); 1.2775 (0.7); 1.2596 (1.7); 1.2550 (1.4); 1.2418 (0.7); 0.1456 (0.8); 0.0276 (0.8); 0.0118 (0.6); 0.0110 (0.6); 0.0101 (0.9); 0.0079 (7.2); 0.0063 (1.7); 0.0054 (1.8); 0.0046 (2.7); 0.0037 (3.8); −0.0002 (264.9); −0.00052 (5.0); −0.00060 (4.4); −0.00069 (3.8); −0.00085 (8.9); −0.0124 (1.3); −0.0132 (1.3); −0.0140 (1.4); −0.0164 (0.8); −0.0172 (0.7); −0.0188 (0.8); −0.0227 (0.5); −0.1494 (0.8) VII-066: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0469 (1.8); 8.0409 (1.9); 7.7250 (0.6); 7.7190 (0.6); 7.7043 (1.0); 7.6992 (0.9); 7.6854 (0.6); 7.6792 (0.6); 7.3698 (0.7); 7.3639 (1.1); 7.3618 (0.7); 7.3594 (1.2); 7.3574 (1.0); 7.3515 (1.2); 7.3484 (0.7); 7.3438 (1.8); 7.3401 (2.6); 7.3336 (1.2); 7.3291 (0.6); 7.3259 (1.1); 7.3210 (1.7); 7.2609 (17.8); 7.2010 (0.9); 7.1994 (1.0); 7.1978 (1.1); 7.1965 (1.0); 7.1810 (1.5); 7.1790 (1.6); 7.1771 (1.7); 7.1624 (0.6); 7.1608 (0.7); 7.1592 (0.7); 7.0324 (1.2); 7.0295 (1.1); 7.0110 (1.2); 7.0075 (2.1); 6.9861 (1.1); 6.9824 (0.7); 6.9252 (1.5); 6.9238 (1.5); 6.9177 (1.5); 6.9163 (1.5); 6.9040 (1.4); 6.9025 (1.5); 6.8965 (1.4); 6.8950 (1.4); 5.2251 (0.8); 5.2077 (2.8); 5.1903 (2.8); 5.1728 (0.8); 4.2574 (1.0); 4.2525 (1.0); 4.2396 (3.3); 4.2348 (3.3); 4.2217 (3.4); 4.2170 (3.3); 4.2039 (1.2); 4.1993 (1.1); 1.6855 (0.8); 1.6759 (11.8); 1.6683 (1.0); 1.6585 (11.7); 1.5484 (5.2); 1.2774 (0.8); 1.2696 (8.1); 1.2597 (1.7); 1.2519 (16.0); 1.2420 (0.7); 1.2341 (7.5); 0.8819 (1.8); 0.8642 (0.7); 0.0080 (0.7); −0.0002 (23.5); −0.00085 (0.7) VII-118: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1043 (2.9); 8.0980 (3.2); 7.7557 (1.4); 7.7495 (1.4); 7.7370 (1.6); 7.7346 (1.8); 7.7308 (1.7); 7.7283 (1.8); 7.7159 (1.6); 7.7096 (1.5); 7.3989 (1.2); 7.3946 (1.4); 7.3796 (2.0); 7.3753 (2.4); 7.3609 (1.4); 7.3561 (2.2); 7.3511 (0.8); 7.3433 (0.8); 7.3388 (0.8); 7.3366 (1.2); 7.3322 (1.0); 7.3244 (1.3); 7.3199 (1.0); 7.3182 (1.0); 7.3159 (1.2); 7.3115 (1.0); 7.3038 (1.1); 7.2992 (0.9); 7.2602 (89.4); 7.2323 (0.6); 7.2074 (1.4); 7.2055 (1.5); 7.1858 (2.3); 7.1688 (1.0); 7.1670 (0.9); 7.0342 (1.5); 7.0309 (1.5); 7.0134 (1.4); 7.0096 (2.4); 7.0058 (1.6); 6.9965 (0.6); 6.9882 (1.3); 6.9851 (1.3); 6.9453 (2.0); 6.9438 (2.1); 6.9380 (2.1); 6.9364 (2.1); 6.9242 (2.0); 6.9227 (2.1); 6.9167 (2.1); 6.9152 (2.0); 5.3043 (1.2); 5.2869 (4.6); 5.2694 (4.7); 5.2520 (1.2); 4.1314 (0.7); 4.1136 (0.7); 2.1076 (5.6); 2.0459 (3.5); 1.7475 (15.7); 1.7300 (16.0); 1.7133 (0.6); 1.4322 (4.4); 1.2773 (1.1); 1.2595 (2.4); 1.2417 (1.1); 0.0080 (3.0); 0.0058 (0.6); −0.0002 (121.4); −0.00085 (3.9); −0.0280 (0.7) VII-067: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1183 (1.5); 8.1166 (1.3); 8.1142 (1.2); 8.1120 (1.6); 7.6716 (0.8); 7.6653 (0.8); 7.6529 (0.8); 7.6503 (1.0); 7.6466 (0.9); 7.6440 (1.0); 7.6316 (0.8); 7.6253 (0.8); 7.2855 (1.1); 7.2823 (1.2); 7.2670 (1.1); 7.2653 (0.9); 7.2611 (31.9); 7.2207 (1.3); 7.2194 (1.4); 7.2016 (0.8); 7.1874 (0.6); 7.1846 (0.5); 7.1691 (1.0); 7.1679 (1.0); 7.1651 (1.0); 7.1497 (0.6); 7.1469 (0.6); 7.1457 (0.5); 7.0753 (1.4); 7.0722 (1.5); 7.0558 (1.0); 7.0526 (1.0); 6.8920 (1.0); 6.8905 (1.1); 6.8845 (1.0); 6.8831 (1.1); 6.8706 (0.9); 6.8692 (1.1); 6.8632 (1.0); 6.8617 (1.0); 4.9579 (10.7); 4.1499 (1.1); 4.1321 (3.3); 4.1142 (3.4); 4.0964 (1.1); 2.1098 (0.6); 2.0470 (16.0); 2.0217 (10.5); 1.4321 (0.9); 1.2773 (4.7); 1.2595 (9.5); 1.2416 (4.6); 0.0081 (0.6); −0.0002 (21.2); −0.00085 (0.7) VII-097: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1209 (1.4); 8.1147 (1.4); 7.6645 (0.7); 7.6582 (0.7); 7.6457 (0.8); 7.6432 (0.8); 7.6395 (0.8); 7.6370 (0.8); 7.6246 (0.7); 7.6183 (0.7); 7.2690 (1.1); 7.2660 (1.2); 7.2611 (13.6); 7.2506 (1.0); 7.2474 (1.0); 7.2095 (1.2); 7.1931 (0.6); 7.1538 (0.9); 7.1499 (0.8); 7.0560 (1.3); 7.0531 (1.3); 7.0366 (0.9); 7.0336 (0.8); 6.8905 (1.0); 6.8892 (0.9); 6.8831 (1.0); 6.8818 (0.9); 6.8693 (0.9); 6.8679 (0.9); 6.8618 (0.9); 4.9467 (8.6); 2.1078 (2.0); 2.0236 (9.5); 2.0081 (16.0); 1.4321 (2.0); −0.0002 (17.9); −0.00085 (0.5) VII-105: .sup.1H-NMR(599.6 MHz, CDCl3): δ = 8.1149 (0.9); 8.1109 (1.0); 8.0411 (7.5); 8.0374 (7.6); 7.6529 (0.4); 7.6487 (0.4); 7.6388 (0.6); 7.6347 (0.6); 7.6275 (2.5); 7.6235 (2.6); 7.6139 (3.8); 7.6107 (3.7); 7.6012 (2.4); 7.5971 (2.3); 7.2872 (2.4); 7.2855 (2.6); 7.2746 (6.3); 7.2730 (6.6); 7.2609 (35.5); 7.2481 (0.6); 7.2463 (0.6); 7.2172 (7.1); 7.2047 (4.6); 7.1533 (2.9); 7.1403 (5.6); 7.1280 (2.9); 7.0440 (0.9); 7.0286 (7.0); 7.0274 (7.0); 7.0154 (5.6); 6.8753 (5.4); 6.8705 (5.5); 6.8611 (5.2); 6.8563 (5.2); 5.2987 (4.0); 4.8991 (41.3); 4.8866 (5.2); 4.2580 (5.8); 4.2460 (17.6); 4.2341 (17.6); 4.2222 (5.8); 2.0396 (50.0); 2.0288 (6.4); 1.5658 (6.2); 1.2880 (19.7); 1.2761 (39.3); 1.2642 (19.4); 1.2553 (1.0); 0.0053 (1.2); −0.00001 (29.8); −0.00056 (1.0) X-026: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.0745 (2.5); 7.7356 (1.0); 7.7178 (1.4); 7.7012 (1.0); 7.5193 (1.1); 7.4390 (1.2); 7.4201 (2.2); 7.4013 (1.8); 7.3835 (1.3); 7.3632 (1.1); 7.2604 (184.7); 7.2492 (1.7); 7.2284 (2.5); 7.2099 (1.3); 7.0599 (1.3); 7.0383 (2.8); 7.0172 (2.3); 6.9965 (1.2); 6.9796 (1.0); 6.9472 (1.8); 6.9412 (1.9); 6.9261 (2.0); 6.9188 (2.0); 4.9115 (12.8); 4.2350 (5.3); 4.2214 (5.4); 2.2719 (1.2); 2.0082 (16.0); 1.4323 (12.3); 1.3327 (1.2); 1.2842 (1.3); 1.2547 (4.1); 0.0689 (1.0); 0.0080 (6.4); −0.0002 (255.5); −0.00085 (7.4); −0.1495 (0.9) X-026: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 4.8276 (1.0); 3.3165 (16.0); 2.5051 (39.9); 2.5007 (55.1); 2.4963 (40.6); 2.4921 (19.9); 0.0081 (0.6); −0.0002 (21.2);−0.00083 (1.0) VII-106: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0581 (3.1); 8.0521 (3.3); 7.7411 (1.0); 7.7349 (1.0); 7.7203 (1.6); 7.7150 (1.6); 7.7014 (1.1); 7.6952 (1.0); 7.3734 (2.9); 7.3628 (0.6); 7.3580 (3.2); 7.3538 (5.3); 7.3494 (1.4); 7.3446 (0.7); 7.3403 (2.5); 7.3374 (3.2); 7.3343 (2.6); 7.3303 (1.2); 7.3222 (1.5); 7.3178 (0.8); 7.2608 (18.0); 7.1968 (1.5); 7.1953 (1.8); 7.1937 (1.8); 7.1766 (2.6); 7.1745 (3.0); 7.1583 (1.1); 7.1568 (1.3); 7.1551 (1.2); 7.0299 (1.4); 7.0280 (1.3); 7.0252 (0.9); 7.0092 (1.7); 7.0062 (2.8); 7.0034 (2.0); 6.9969 (0.6); 6.9846 (1.6); 6.9809 (1.4); 6.9370 (2.3); 6.9357 (2.3); 6.9297 (2.4); 6.9283 (2.3); 6.9158 (2.3); 6.9144 (2.3); 6.9084 (2.3); 6.9071 (2.2); 5.3199 (1.1); 5.3025 (4.4); 5.2849 (4.6); 5.2675 (1.2); 2.1095 (1.2); 2.0468 (1.0); 1.7459 (0.7); 1.7418 (1.1); 1.7322 (16.0); 1.7245 (1.7); 1.7147 (16.0); 1.4321 (1.6); 1.2588 (0.6); 0.0079 (0.6); −0.0002 (22.9); −0.00085 (0.8) VII-065: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1740 (1.2); 8.1721 (1.8); 8.1701 (1.4); 8.1680 (1.5); 8.1658 (1.9); 8.1638 (1.4); 7.7041 (1.0); 7.6978 (1.0); 7.6854 (1.2); 7.6828 (1.3); 7.6792 (1.2); 7.6766 (1.3); 7.6642 (1.1); 7.6579 (1.1); 7.2613 (47.4); 7.2548 (0.5); 7.1290 (2.1); 7.1232 (0.8); 7.1171 (2.3); 7.1117 (1.4); 7.1061 (3.5); 7.1002 (1.0); 7.0980 (0.7); 7.0943 (3.3); 7.0281 (3.4); 7.0221 (1.0); 7.0109 (0.9); 7.0080 (3.7); 7.0052 (2.6); 7.0022 (1.1); 6.9976 (0.5); 6.9910 (0.8); 6.9852 (2.3); 6.9771 (1.4); 6.9756 (1.4); 6.9695 (1.4); 6.9680 (1.4); 6.9559 (1.2); 6.9543 (1.3); 6.9483 (1.3); 6.9468 (1.3); 4.9083 (14.3); 4.3039 (1.8); 4.2861 (5.7); 4.2683 (5.8); 4.2504 (1.9); 1.5605 (0.7); 1.3197 (7.6); 1.3019 (16.0); 1.2841 (7.4); 0.0080 (0.8); −0.0002 (31.9); −0.00085 (1.0) VII-102: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1696 (2.0); 8.1677 (1.5); 8.1655 (1.5); 8.1633 (2.0); 8.1615 (1.4); 7.6940 (1.1); 7.6877 (1.1); 7.6754 (1.2); 7.6729 (1.3); 7.6691 (1.2); 7.6666 (1.3); 7.6542 (1.2); 7.6479 (1.2); 7.2623 (23.9); 7.1111 (2.2); 7.1053 (0.8); 7.0992 (2.4); 7.0938 (1.5); 7.0882 (3.8); 7.0822 (1.0); 7.0802 (0.8); 7.0763 (3.6); 7.0144 (3.7); 7.0085 (1.1); 7.0026 (0.5); 6.9973 (1.0); 6.9944 (3.9); 6.9917 (2.7); 6.9886 (1.1); 6.9775 (2.1); 6.9714 (3.0); 6.9689 (1.7); 6.9567 (1.3); 6.9552 (1.4); 6.9492 (1.4); 6.9477 (1.4); 5.3003 (6.4); 4.9017 (14.8); 4.3002 (1.9); 4.2824 (6.0); 4.2646 (6.1); 4.2468 (2.0); 1.5681 (0.6); 1.3187 (7.7); 1.3009 (16.0); 1.2830 (7.5); −0.0002 (16.4) 11-016: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.5087 (3.3); 8.5016 (3.4); 7.9335 (0.9); 7.9262 (0.9); 7.9118 (2.1); 7.9044 (2.0); 7.8901 (1.3); 7.8828 (1.2); 7.7929 (1.9); 7.7819 (2.1); 7.7709 (1.6); 7.7599 (1.5); 7.4825 (0.8); 7.4785 (1.0); 7.4631 (1.7); 7.4591 (2.1); 7.4439 (1.4); 7.4399 (1.5); 7.4330 (0.7); 7.4262 (1.1); 7.4217 (1.0); 7.4135 (1.1); 7.4068 (1.1); 7.4018 (0.8); 7.3935 (0.8); 7.3893 (0.6); 7.2886 (1.5); 7.2720 (2.0); 7.2693 (2.3); 7.2530 (2.0); 7.2347 (1.2); 7.2289 (1.5); 7.2260 (1.3); 7.2079 (1.0); 7.2053 (1.0); 5.1311 (5.7); 3.7233 (16.0); 3.3392 (25.6); 3.1196 (15.2); 2.5117 (8.4); 2.5075 (17.5); 2.5031 (24.0); 2.4986 (17.9); 2.4944 (9.1); 2.0780 (0.5); 0.0000 (4.1) 11-003: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 11.4205 (3.2); 8.5090 (6.3); 8.5018 (6.6); 7.9290 (1.8); 7.9217 (1.7); 7.9072 (4.0); 7.8999 (3.9); 7.8856 (2.5); 7.8783 (2.4); 7.7842 (3.1); 7.7732 (3.4); 7.7623 (2.6); 7.7513 (2.4); 7.4776 (1.5); 7.4738 (2.0); 7.4579 (3.6); 7.4544 (4.8); 7.4352 (4.2); 7.4244 (2.3); 7.4184 (2.1); 7.4045 (1.4); 7.2896 (3.0); 7.2701 (5.0); 7.2637 (2.7); 7.2539 (2.2); 7.2510 (2.5); 7.2376 (2.8); 7.2162 (1.8); 6.5436 (0.4); 5.0706 (0.4); 5.0363 (0.4); 4.6709 (8.2); 3.6094 (16.0); 3.3319 (27.2); 2.9583 (0.5); 2.8407 (0.5); 2.6761 (0.4); 2.6714 (0.6); 2.6670 (0.5); 2.5113 (31.1); 2.5070 (64.9); 2.5025 (89.0); 2.4981 (67.2); 2.4939 (34.8); 2.3340 (0.4); 2.3294 (0.6); 2.3252 (0.4); 0.0081 (0.4); 0.0000 (9.8); −0.00081 (0.5) II-017: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 10.8029 (3.2); 10.2111 (0.9); 9.2275 (1.0); 8.9881 (6.4); 8.5076 (7.9); 8.5005 (8.0); 7.9292 (2.1); 7.9220 (2.0); 7.9076 (4.8); 7.9002 (4.5); 7.8859 (2.9); 7.8785 (2.7); 7.7804 (3.7); 7.7694 (3.9); 7.7585 (3.0); 7.7477 (2.7); 7.5115 (1.8); 7.4921 (3.5); 7.4726 (2.3); 7.4541 (1.5); 7.4356 (2.6); 7.4198 (2.6); 7.4061 (1.6); 7.2988 (2.8); 7.2795 (4.4); 7.2593 (4.6); 7.2327 (3.6); 7.2112 (2.3); 5.0329 (1.8); 4.6682 (16.0); 3.3336 (106.0); 3.3101 (4.4); 2.6714 (1.7); 2.5065 (208.0); 2.5023 (274.3); 2.4980 (201.8); 2.3291 (1.6); 2.3246 (1.2); 2.0769 (0.7); 1.2344 (0.4); 0.0001 (31.1); −0.00080 (1.4) VII-095: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1809 (2.1); 8.1788 (1.6); 8.1766 (1.7); 8.1746 (2.2); 7.7062 (1.1); 7.6999 (1.1); 7.6876 (1.2); 7.6850 (1.3); 7.6814 (1.2); 7.6788 (1.3); 7.6664 (1.2); 7.6602 (1.2); 7.2607 (51.3); 7.1403 (2.4); 7.1345 (0.9); 7.1285 (2.7); 7.1231 (1.6); 7.1175 (3.7); 7.1115 (1.1); 7.1093 (0.8); 7.1056 (3.5); 7.0349 (3.8); 7.0290 (1.1); 7.0231 (0.6); 7.0177 (1.2); 7.0149 (4.1); 7.0121 (2.7); 7.0091 (1.2); 6.9977 (1.2); 6.9921 (2.4); 6.9836 (1.7); 6.9821 (1.5); 6.9761 (1.5); 6.9745 (1.4); 6.9623 (1.4); 6.9608 (1.4); 6.9548 (1.5); 6.9532 (1.4); 4.9834 (16.0); 4.9586 (0.6); 4.1499 (0.9); 4.1321 (2.7); 4.1143 (2.7); 4.0964 (0.9); 2.2837 (0.8); 2.2271 (0.6); 2.2188 (0.5); 2.1108 (6.1); 2.0470 (13.2); 1.4420 (0.9); 1.4322 (1.1); 1.2776 (3.9); 1.2598 (8.0); 1.2419 (4.1); 1.2390 (1.1); 0.0080 (3.6); 0.0065 (0.6); 0.0057 (0.6); 0.0048 (0.6); −0.0002 (147.7); −0.00066 (1.7); −0.00085 (4.7) VII-051: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 11.9140 (0.6); 7.4551 (2.2); 7.3288 (2.2); 7.3222 (1.3); 7.3159 (3.0); 7.3055 (6.6); 7.2989 (2.6); 7.2928 (6.2); 7.2829 (6.9); 7.2764 (1.5); 7.2618 (7.4); 7.2556 (1.6); 7.2448 (1.1); 7.2386 (2.5); 7.1778 (1.9); 7.1713 (1.8); 7.1543 (2.0); 7.1478 (1.9); 6.3189 (2.8); 6.2953 (2.6); 4.7909 (16.0); 3.5073 (0.7); 3.3373 (60.6); 2.6792 (0.9); 2.6745 (2.1); 2.6699 (2.9); 2.6653 (2.1); 2.6607 (1.0); 2.5447 (0.7); 2.5404 (50.0); 2.5237 (7.2); 2.5190 (9.7); 2.5102 (151.3); 2.5057 (339.9); 2.5011 (483.5); 2.4965 (338.4); 2.4919 (156.0); 2.4630 (0.9); 2.4585 (0.6); 2.3375 (0.9); 2.3328 (2.0); 2.3281 (3.0); 2.3236 (2.1); 2.3189 (0.9); 2.0740 (4.4); 1.9885 (0.7); 1.3528 (1.3); 1.2980 (4.6); 1.2584 (7.4); 1.2351 (5.8); 1.1744 (0.6); 0.8537 (0.9); 0.1458 (0.8); 0.0081 (8.1); 0.0057 (0.6); 0.0049 (0.8); −0.0002 (335.8); −0.00085 (10.9); −0.0263 (1.0); −0.0338 (0.9); −0.1494 (0.9) VII-051: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 7.5188 (1.6); 7.2600 (281.3); 6.9960 (1.6); 1.6557 (2.7); 1.4274 (2.1); 1.3326 (12.3); 1.2844 (16.0); 1.2548 (10.0); 0.8799 (1.4); 0.0080 (9.4); −0.0002 (364.9); −0.00085 (11.0); -0.1490 (1.4) VII-069: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1796 (2.6); 8.1734 (2.5); 7.6980 (1.2); 7.6916 (1.2); 7.6791 (1.4); 7.6767 (1.5); 7.6730 (1.3); 7.6704 (1.4); 7.6581 (1.2); 7.6517 (1.1); 7.2603 (56.4); 7.1225 (2.5); 7.1168 (1.0); 7.1106 (2.8); 7.1053 (1.8); 7.0997 (4.1); 7.0879 (3.9); 7.0230 (4.0); 7.0171 (1.1); 7.0030 (4.5); 6.9860 (2.5); 6.9801 (3.3); 6.9638 (1.6); 6.9573 (1.5); 4.9791 (16.0); 2.0084 (4.7); 1.4274 (0.6); 1.3315 (1.9); 1.2843 (2.6); 1.2546 (3.1); 0.8801 (0.6); 0.0080 (2.8); −0.0002 (71.5); −0.00085 (2.0) VII-069: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1770 (2.3); 8.1705 (2.3); 7.6950 (1.0); 7.6887 (1.1); 7.6737 (1.3); 7.6675 (1.3); 7.6551 (1.1); 7.6489 (1.1); 7.2600 (66.0); 7.1226 (2.2); 7.1168 (1.0); 7.1108 (2.5); 7.1054 (1.5); 7.0998 (3.7); 7.0880 (3.6); 7.0227 (3.7); 7.0169 (1.0); 7.0027 (4.0); 6.9800 (3.3); 6.9763 (1.9); 6.9610 (1.5); 6.9536 (1.4); 4.9778 (16.0); 3.7699 (1.9); 3.7594 (1.6); 3.7532 (5.0); 3.7470 (1.7); 3.7366 (2.1); 2.2714 (1.0); 1.8729 (2.0); 1.8650 (2.0); 1.8563 (5.9); 1.8477 (1.9); 1.8397 (2.0); 1.4321 (9.7); 1.2543 (0.9); 1.2433 (0.7); 0.0080 (2.8); −0.0002 (104.2); −0.00085 (3.0) VII-059: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1050 (1.5); 8.0989 (1.6); 7.6864 (0.6); 7.6801 (0.6); 7.6660 (0.9); 7.6613 (0.8); 7.6598 (0.8); 7.6469 (0.7); 7.6406 (0.6); 7.2613 (16.7); 7.1043 (2.0); 7.0984 (0.8); 7.0924 (2.2); 7.0871 (1.4); 7.0813 (3.6); 7.0755 (1.1); 7.0736 (0.8); 7.0695 (3.5); 7.0214 (3.5); 7.0154 (1.0); 7.0095 (0.6); 7.0043 (1.0); 7.0015 (3.7); 6.9995 (1.9); 6.9984 (2.4); 6.9956 (1.1); 6.9845 (0.9); 6.9786 (2.2); 6.9749 (1.4); 6.9732 (1.5); 6.9673 (1.4); 6.9657 (1.4); 6.9537 (1.3); 6.9520 (1.3); 6.9461 (1.3); 6.9445 (1.3); 5.3002 (4.7); 4.9156 (13.2); 4.9088 (0.8); 4.2980 (1.8); 4.2802 (5.7); 4.2624 (5.8); 4.2446 (1.9); 1.5490 (4.4); 1.3148 (7.5); 1.3010 (0.9); 1.2970 (16.0); 1.2832 (0.5); 1.2792 (7.4); 0.0080 (0.7); 0.0024 (0.8); −0.0002 (22.7); −0.00041 (0.6); −0.00084 (0.7) VII-045: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.2324 (1.0); 8.2193 (1.7); 8.2063 (1.0); 7.4097 (11.0); 4.1033 (2.4); 4.0855 (7.2); 4.0677 (7.2); 4.0499 (2.4); 3.5001 (1.7); 3.4834 (4.5); 3.4687 (4.5); 3.4521 (1.8); 3.3456 (34.2); 3.3405 (49.0); 2.8946 (1.8); 2.7358 (1.6); 2.5809 (3.8); 2.5640 (7.7); 2.5470 (3.5); 2.5099 (22.3); 2.5055 (28.6); 2.5011 (21.6); 1.2602 (0.3); 1.2394 (1.5); 1.2057 (8.0); 1.1880 (16.0); 1.1702 (7.7); 0.8542 (0.3); −0.0002 (0.8) II-004: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 11.4010 (3.2); 8.5200 (7.2); 8.5129 (7.0); 7.9346 (2.1); 7.9273 (2.0); 7.9129 (4.6); 7.9056 (4.2); 7.8913 (2.8); 7.8840 (2.5); 7.8129 (3.8); 7.8018 (4.0); 7.7910 (2.8); 7.7799 (2.4); 7.5474 (1.7); 7.5322 (2.0); 7.5253 (3.4); 7.5103 (3.4); 7.5033 (2.0); 7.4883 (1.6); 7.3811 (1.5); 7.3745 (1.6); 7.3531 (2.5); 7.3321 (1.4); 7.3256 (1.4); 7.1948 (1.6); 7.1910 (1.5); 7.1747 (2.8); 7.1523 (1.4); 5.0611 (0.4); 4.8421 (0.3); 4.6629 (7.5); 3.6062 (16.0); 3.3140 (24.0); 2.6732 (0.9); 2.6685 (1.2); 2.6639 (1.0); 2.5082 (76.2); 2.5039 (153.2); 2.4995 (206.2); 2.4951 (150.3); 2.4909 (74.4); 2.3307 (0.9); 2.3263 (1.2); 2.3218 (0.9); 0.1446 (0.4); 0.0066 (4.0); −0.00016 (102.9); −0.00097 (5.0); −0.1509 (0.4) II-005: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.5094 (5.2); 8.5022 (5.3); 8.4479 (1.5); 8.4338 (2.7); 8.4194 (1.4); 7.9273 (1.5); 7.9200 (1.4); 7.9056 (3.3); 7.8983 (3.1); 7.8839 (2.0); 7.8766 (1.8); 7.7749 (3.0); 7.7639 (3.2); 7.7531 (2.4); 7.7420 (2.2); 7.5106 (1.5); 7.5066 (1.6); 7.4912 (3.1); 7.4872 (3.2); 7.4717 (1.9); 7.4677 (1.9); 7.4506 (0.9); 7.4463 (0.9); 7.4378 (1.1); 7.4314 (1.8); 7.4270 (1.7); 7.4188 (1.8); 7.4144 (1.8); 7.4070 (1.3); 7.3986 (1.2); 7.3944 (1.0); 7.2843 (2.2); 7.2819 (2.4); 7.2652 (3.4); 7.2625 (3.7); 7.2503 (2.7); 7.2472 (2.9); 7.2298 (2.2); 7.2242 (2.6); 7.2031 (1.7); 7.2005 (1.5); 4.7547 (16.0); 3.3906 (2.2); 3.3747 (5.6); 3.3594 (5.8); 3.3434 (2.8); 3.3281 (28.5); 3.3047 (1.0); 2.6926 (5.0); 2.6764 (10.1); 2.6601 (4.5); 2.5109 (15.9); 2.5067 (30.6); 2.5022 (39.9); 2.4978 (29.2); 2.4936 (14.4); 0.0000 (5.0) X-027: .sup.1H-NMR(599.6 MHz, CDCl3): δ = 8.1023 (5.3); 8.0984 (5.2); 7.7586 (1.9); 7.7544 (1.9); 7.7458 (2.7); 7.7445 (2.8); 7.7418 (2.7); 7.7319 (1.9); 7.7278 (1.8); 7.4430 (1.8); 7.4403 (1.9); 7.4301 (3.5); 7.4277 (3.5); 7.4175 (2.0); 7.4148 (2.0); 7.3560 (1.0); 7.3532 (1.0); 7.3478 (1.1); 7.3433 (1.9); 7.3406 (1.8); 7.3341 (1.8); 7.3323 (1.9); 7.3268 (1.2); 7.3214 (1.2); 7.3187 (1.0); 7.2638 (11.9); 7.2201 (2.6); 7.2071 (4.2); 7.1945 (1.9); 7.0385 (2.3); 7.0368 (2.2); 7.0222 (3.9); 7.0078 (2.3); 7.0062 (2.0); 6.9963 (0.5); 6.9575 (0.3); 6.9330 (3.2); 6.9283 (3.2); 6.9189 (3.1); 6.9141 (3.2); 5.2993 (3.1); 4.9996 (24.7); 3.1119 (1.2); 3.0637 (34.6); 3.0312 (1.4); 3.0288 (1.5); 3.0093 (31.2); 2.9513 (0.8); 2.7170 (2.7); 2.2917 (0.3); 2.2831 (1.6); 2.2759 (0.7); 2.2262 (1.6); 2.2181 (1.3); 2.1738 (0.5); 2.0441 (0.8); 1.6337 (17.2); 1.2752 (0.4); 1.2707 (0.3); 1.2633 (0.8); 1.2587 (0.9); 1.2514 (0.4); 1.2470 (0.3); 0.0052 (2.4); −0.00001 (50.0); −0.00056 (1.6) X-027: .sup.1H-NMR(599.6 MHz, CDCl3): δ = 8.1013 (1.2); 8.0974 (1.3); 7.7586 (0.4); 7.7545 (0.5); 7.7446 (0.7); 7.7419 (0.6); 7.7405 (0.6); 7.7320 (0.5); 7.7278 (0.4); 7.4422 (0.4); 7.4395 (0.5); 7.4292 (0.8); 7.4267 (0.9); 7.4167 (0.5); 7.4140 (0.5); 7.3419 (0.4); 7.3402 (0.4); 7.3337 (0.4); 7.3320 (0.5); 7.3263 (0.3); 7.2609 (11.9); 7.2190 (0.6); 7.2062 (1.0); 7.1933 (0.4); 7.0382 (0.5); 7.0365 (0.6); 7.0220 (0.9); 7.0076 (0.5); 7.0059 (0.5); 6.9320 (0.8); 6.9272 (0.8); 6.9178 (0.8); 6.9130 (0.8); 4.9992 (6.1); 3.0639 (8.5); 3.0293 (0.3); 3.0098 (7.7); 2.7180 (0.6); 1.5636 (20.8); 0.0053 (2.0); −0.00001 (50.0); −0.00056 (1.8) X-027: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1024 (1.6); 8.0962 (1.6); 7.7671 (0.8); 7.7609 (0.8); 7.7483 (0.9); 7.7459 (1.0); 7.7421 (0.9); 7.7396 (0.8); 7.7272 (0.8); 7.7209 (0.8); 7.4506 (0.6); 7.4463 (0.7); 7.4313 (1.2); 7.4270 (1.3); 7.4125 (0.8); 7.4080 (0.8); 7.3467 (0.6); 7.3424 (0.6); 7.3346 (0.6); 7.3261 (0.6); 7.3139 (0.6); 7.2607 (29.7); 7.2251 (0.8); 7.2057 (1.2); 7.1882 (0.5); 7.0464 (0.8); 7.0431 (0.8); 7.0254 (0.8); 7.0217 (1.3); 7.0179 (0.8); 7.0004 (0.8); 6.9970 (0.9); 6.9374 (1.1); 6.9313 (1.1); 6.9161 (1.1); 6.9086 (1.0); 5.2999 (1.9); 5.0000 (8.8); 3.0639 (13.5); 3.0304 (0.6); 3.0103 (11.2); 2.7183 (1.1); 1.5534 (16.0); 0.0080 (1.0); −0.0002 (39.0);−0.00085 (1.1) VII-012: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.2023 (4.4); 8.1969 (4.3); 7.9638 (1.3); 7.9576 (1.3); 7.9435 (2.4); 7.9379 (2.2); 7.9232 (1.5); 7.9172 (1.3); 7.5759 (1.4); 7.5566 (2.8); 7.5407 (1.6); 7.5370 (1.6); 7.5115 (0.7); 7.5075 (0.7); 7.4927 (1.6); 7.4744 (1.7); 7.4594 (1.0); 7.3366 (2.1); 7.3166 (5.3); 7.3001 (4.4); 7.2949 (5.0); 7.2795 (2.8); 7.2725 (2.9); 6.6237 (0.4); 4.9352 (14.9); 4.1926 (2.3); 4.1750 (7.2); 4.1572 (7.2); 4.1396 (2.5); 3.3408 (148.1); 3.3182 (6.1); 2.6698 (0.9); 2.5050 (122.2); 2.5010 (152.4); 2.4971 (114.5); 2.3279 (0.9); 1.2315 (0.4); 1.2029 (7.9); 1.1852 (16.0); 1.1675 (7.8); 1.1511 (0.6); −0.00021 (12.9) VII-121: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1020 (1.2); 8.1001 (1.8); 8.0980 (1.4); 8.0959 (1.4); 8.0939 (1.9); 8.0919 (1.3); 7.7612 (1.0); 7.7550 (1.0); 7.7425 (1.2); 7.7400 (1.2); 7.7362 (1.2); 7.7337 (1.2); 7.7213 (1.1); 7.7150 (1.1); 7.3961 (0.8); 7.3918 (0.9); 7.3769 (1.3); 7.3725 (1.6); 7.3578 (1.0); 7.3537 (1.2); 7.3443 (0.6); 7.3397 (0.6); 7.3375 (0.8); 7.3357 (0.7); 7.3331 (0.7); 7.3313 (0.6); 7.3253 (0.9); 7.3236 (0.6); 7.3209 (0.7); 7.3190 (0.6); 7.3169 (0.8); 7.3124 (0.6); 7.3047 (0.7); 7.3002 (0.6); 7.2621 (23.5); 7.2121 (0.9); 7.2105 (1.0); 7.2087 (1.0); 7.2072 (0.9); 7.1910 (1.4); 7.1891 (1.4); 7.1736 (0.6); 7.1719 (0.6); 7.1702 (0.6); 7.1687 (0.6); 7.0362 (1.0); 7.0329 (1.0); 7.0154 (0.9); 7.0115 (1.6); 7.0078 (1.0); 6.9902 (0.9); 6.9871 (0.8); 6.9369 (1.4); 6.9354 (1.4); 6.9295 (1.4); 6.9279 (1.4); 6.9157 (1.3); 6.9141 (1.3); 6.9082 (1.4); 6.9067 (1.3); 5.2999 (1.2); 5.2154 (0.8); 5.1980 (2.9); 5.1807 (3.0); 5.1633 (0.8); 4.2641 (1.1); 4.2623 (1.2); 4.2463 (3.6); 4.2445 (3.7); 4.2284 (3.8); 4.2268 (3.7); 4.2106 (1.3); 4.2091 (1.2); 1.6903 (11.4); 1.6729 (11.4); 1.2780 (7.4); 1.2602 (16.0); 1.2424 (7.4); −0.0002 (15.7) II-011: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.5190 (3.1); 8.5118 (3.1); 7.9363 (0.9); 7.9289 (0.8); 7.9146 (2.0); 7.9072 (1.8); 7.8929 (1.3); 7.8856 (1.1); 7.8187 (1.8); 7.8078 (1.9); 7.7967 (1.3); 7.7858 (1.2); 7.5518 (0.7); 7.5368 (0.8); 7.5297 (1.5); 7.5148 (1.5); 7.5077 (0.9); 7.4927 (0.8); 7.3699 (0.8); 7.3630 (0.8); 7.3471 (1.0); 7.3413 (1.2); 7.3364 (1.0); 7.3206 (0.8); 7.3138 (0.8); 7.1899 (0.7); 7.1863 (0.7); 7.1696 (1.2); 7.1503 (0.6); 7.1473 (0.6); 7.1432 (0.5); 5.1198 (5.9); 3.7175 (16.0); 3.3141 (32.9); 3.1171 (15.0); 2.9230 (0.4); 2.6731 (0.4); 2.6686 (0.5); 2.6642 (0.4); 2.5082 (29.0); 2.5040 (59.2); 2.4995 (79.6); 2.4951 (57.5); 2.4910 (27.4); 2.3311 (0.3); 2.3264 (0.5); 2.3221 (0.3); 0.0066 (1.7); −0.00014 (41.8); −0.00097 (1.7) X-025: .sup.1H-NMR(300.1 MHz, d.sub.6-DMSO): δ = 8.2245 (2.2); 8.2164 (2.2); 7.9756 (0.8); 7.9672 (0.8); 7.9477 (1.2); 7.9393 (1.2); 7.9216 (0.8); 7.9132 (0.8); 7.6967 (0.7); 7.6766 (0.8); 7.6672 (1.4); 7.6472 (1.4); 7.6378 (0.8); 7.6178 (0.7); 7.4355 (0.7); 7.4262 (0.8); 7.4052 (0.9); 7.4000 (1.0); 7.3967 (1.0); 7.3911 (0.9); 7.3703 (0.7); 7.3610 (0.8); 7.3152 (1.4); 7.3064 (1.4); 7.2867 (1.3); 7.2774 (1.3); 7.2668 (0.5); 7.2619 (0.6); 7.2571 (0.5); 7.2352 (1.0); 7.2095 (0.5); 7.2054 (0.5); 5.1135 (5.6); 3.7149 (16.0); 3.3225 (13.2); 3.2987 (0.4); 3.1178 (14.6); 2.7277 (0.4); 2.5132 (25.0); 2.5073 (47.7); 2.5014 (62.5); 2.4955 (43.0); 2.4899 (19.8); 2.2712 (0.4); 2.0753 (0.8); 0.0109 (2.0); 0.0000 (49.7); −0.0111 (1.7) X-023: .sup.1H-NMR(300.1 MHz, d.sub.6-DMSO): δ = 10.7754 (0.4); 8.9808 (1.4); 8.1907 (2.0); 8.1828 (2.1); 7.9603 (0.6); 7.9523 (0.6); 7.9329 (1.1); 7.9250 (1.0); 7.9063 (0.7); 7.8976 (0.6); 7.6259 (0.5); 7.6050 (1.0); 7.5995 (1.1); 7.5738 (0.7); 7.5000 (0.7); 7.4744 (0.8); 7.4563 (0.5); 7.3530 (0.9); 7.3270 (1.5); 7.3193 (1.4); 7.3058 (1.9); 7.2970 (1.8); 7.2848 (1.4); 7.2785 (1.8); 7.2687 (1.3); 7.2570 (0.8); 5.0232 (0.5); 4.6580 (5.0); 3.3235 (20.9); 3.2996 (0.3); 2.7275 (0.4); 2.5134 (25.0); 2.5075 (49.4); 2.5015 (65.8); 2.4955 (44.9); 2.4897 (20.3); 2.2713 (0.4); 2.0751 (16.0); 0.0108 (2.2); −0.00001 (62.1); −0.0112 (1.8) II-018: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 10.7883 (4.0); 10.1957 (0.8); 9.2151 (0.9); 8.9768 (7.6); 8.5191 (8.0); 8.5120 (8.1); 7.9350 (2.3); 7.9276 (2.1); 7.9133 (5.1); 7.9059 (4.9); 7.8916 (3.2); 7.8843 (3.0); 7.8098 (3.8); 7.7988 (4.0); 7.7879 (2.8); 7.7769 (2.5); 7.5817 (1.2); 7.5666 (1.5); 7.5598 (2.5); 7.5448 (2.7); 7.5380 (1.8); 7.5229 (1.6); 7.3770 (1.6); 7.3704 (1.8); 7.3485 (3.0); 7.3279 (1.7); 7.3212 (1.7); 7.1993 (1.4); 7.1824 (2.7); 7.1633 (1.6); 5.0262 (1.5); 4.6599 (16.0); 3.3180 (104.8); 3.2945 (0.9); 2.6732 (0.5); 2.6688 (0.7); 2.5085 (43.8); 2.5042 (89.4); 2.4998 (120.7); 2.4953 (87.1); 2.4911 (41.3); 2.3313 (0.5); 2.3267 (0.7); 2.3223 (0.5); 2.0728 (0.9); 0.1446 (0.4); 0.0064 (4.1); −0.00016 (103.0); −0.00099 (3.9); −0.1512 (0.4) X-032: .sup.1H-NMR(300.1 MHz, d.sub.6-DMSO): δ = 8.4432 (1.1); 8.4249 (2.3); 8.4067 (1.2); 8.1857 (4.1); 8.1775 (4.3); 7.9500 (1.5); 7.9416 (1.5); 7.9218 (2.3); 7.9136 (2.2); 7.8958 (1.7); 7.8874 (1.6); 7.6173 (1.6); 7.5967 (2.5); 7.5916 (3.2); 7.5713 (1.6); 7.5655 (1.8); 7.5194 (0.7); 7.5137 (0.7); 7.5026 (0.8); 7.4940 (1.6); 7.4873 (1.5); 7.4772 (1.5); 7.4676 (1.7); 7.4611 (1.2); 7.4497 (1.2); 7.4439 (0.9); 7.3384 (2.5); 7.3128 (6.5); 7.2972 (3.1); 7.2860 (3.3); 7.2779 (4.9); 7.2699 (2.9); 7.2505 (1.5); 7.2461 (1.5); 7.0701 (0.5); 6.8998 (0.4); 4.7462 (16.0); 3.3938 (3.2); 3.3727 (6.9); 3.3522 (6.8); 3.3313 (2.5); 2.7333 (0.6); 2.7271 (0.7); 2.7212 (0.6); 2.6922 (4.8); 2.6707 (10.0); 2.6488 (4.1); 2.5133 (48.4); 2.5074 (96.8); 2.5014 (129.3); 2.4955 (89.3); 2.4897 (41.2); 2.2775 (0.6); 2.2714 (0.8); 2.2656 (0.6); 2.0749 (0.8); 0.1952 (0.5); 0.0108 (4.6); −0.00001 (128.7); −0.0112 (4.1); −0.1989 (0.5) II-008: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.5222 (5.3); 8.5151 (5.1); 8.4362 (1.5); 8.4223 (2.7); 8.4079 (1.3); 7.9354 (1.5); 7.9281 (1.4); 7.9138 (3.2); 7.9065 (2.9); 7.8921 (2.0); 7.8848 (1.7); 7.8052 (3.0); 7.7942 (3.2); 7.7834 (2.2); 7.7722 (2.1); 7.5768 (1.2); 7.5616 (1.5); 7.5546 (2.5); 7.5396 (2.4); 7.5327 (1.5); 7.5178 (1.1); 7.3675 (1.3); 7.3605 (1.4); 7.3445 (1.8); 7.3391 (2.2); 7.3183 (1.3); 7.3115 (1.2); 7.1816 (1.3); 7.1612 (2.2); 7.1386 (1.1); 4.7447 (16.0); 3.3833 (2.2); 3.3675 (5.8); 3.3522 (6.1); 3.3359 (3.6); 3.3169 (33.4); 2.6847 (4.9); 2.6685 (10.3); 2.6523 (4.4); 2.5038 (86.7); 2.4994 (114.4); 2.4951 (86.1); 2.3264 (0.7); 2.3224 (0.6); 0.9710 (1.1); 0.1442 (0.4); 0.0059 (4.6); −0.00019 (94.5); −0.00098 (5.8); −0.1512 (0.5) VII-125: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1138 (1.7); 8.1078 (1.8); 7.6923 (0.6); 7.6858 (0.7); 7.6676 (0.9); 7.6527 (0.8); 7.6466 (0.7); 7.5189 (1.4); 7.2916 (0.7); 7.2878 (0.8); 7.2701 (0.6); 7.2693 (0.6); 7.2685 (0.9); 7.2677 (1.0); 7.2669 (1.2); 7.2604 (246.8); 7.2547 (2.8); 7.2531 (1.8); 7.2491 (1.1); 7.2467 (0.6); 7.2459 (0.6); 7.2255 (0.7); 7.1166 (2.2); 7.1107 (1.0); 7.1048 (2.4); 7.0994 (1.6); 7.0937 (3.8); 7.0878 (1.1); 7.0819 (3.6); 7.0376 (0.6); 7.0297 (3.9); 7.0237 (1.1); 7.0178 (0.7); 7.0098 (4.0); 7.0067 (2.6); 7.0040 (1.2); 6.9968 (1.6); 6.9928 (1.0); 6.9869 (2.4); 6.9807 (1.9); 6.9749 (1.6); 6.9611 (1.4); 6.9536 (1.4); 6.9520 (1.4); 4.9946 (16.0); 4.9834 (0.5); 4.7418 (0.9); 2.2719 (1.2); 2.1098 (2.0); 2.0463 (1.6); 1.4322 (11.9); 1.3325 (0.6); 1.2842 (0.9); 1.2775 (0.7); 1.2598 (1.6); 1.2549 (1.4); 1.2420 (0.6); 1.2390 (0.6); 0.1458 (0.6); 0.0310 (0.6); 0.0272 (0.7); 0.0128 (0.5); 0.0080 (5.4); −0.0002 (183.8); −0.00058 (1.8); −0.00085 (5.0); −0.1494 (0.5) VII-125: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1086 (1.2); 7.6710 (0.6); 7.2600 (33.2); 7.1158 (1.2); 7.1040 (1.3); 7.0986 (1.0); 7.0930 (2.1); 7.0812 (2.0); 7.0283 (2.0); 7.0222 (0.6); 7.0084 (2.2); 6.9856 (1.4); 6.9799 (1.7); 6.9741 (1.0); 6.9590 (0.8); 6.9515 (0.8); 5.0064 (0.7); 4.9934 (7.9); 3.7544 (0.6); 2.2717 (1.8); 1.8572 (0.6); 1.4322 (16.0); 1.2544 (5.3); 0.8799 (0.8); 0.0080 (1.5); −0.0002 (51.4); −0.00085 (2.0) VII-092: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1075 (2.6); 8.1055 (2.0); 8.1033 (2.1); 8.1012 (2.8); 8.0993 (1.8); 7.7663 (1.4); 7.7601 (1.3); 7.7476 (1.5); 7.7451 (1.7); 7.7414 (1.5); 7.7389 (1.6); 7.7265 (1.5); 7.7202 (1.4); 7.4194 (1.0); 7.4151 (1.2); 7.4002 (1.8); 7.3958 (2.1); 7.3813 (1.3); 7.3770 (1.5); 7.3629 (0.7); 7.3585 (0.7); 7.3507 (0.7); 7.3462 (0.8); 7.3440 (1.1); 7.3422 (0.9); 7.3396 (1.0); 7.3377 (0.9); 7.3318 (1.1); 7.3301 (0.9); 7.3274 (1.0); 7.3255 (0.9); 7.3234 (1.1); 7.3188 (0.9); 7.3112 (1.0); 7.3067 (0.8); 7.2661 (0.6); 7.2654 (0.7); 7.2645 (1.1); 7.2611 (72.6); 7.2556 (0.9); 7.2532 (0.5); 7.2161 (1.1); 7.2144 (1.3); 7.2126 (1.4); 7.2112 (1.3); 7.1929 (2.0); 7.1775 (0.8); 7.1758 (0.9); 7.1741 (0.9); 7.1727 (0.8); 7.0402 (1.4); 7.0370 (1.3); 7.0195 (1.3); 7.0156 (2.2); 7.0119 (1.4); 6.9975 (0.5); 6.9943 (1.2); 6.9911 (1.2); 6.9466 (1.8); 6.9450 (1.9); 6.9392 (1.9); 6.9376 (1.8); 6.9254 (1.8); 6.9238 (1.8); 6.9179 (1.8); 6.9163 (1.8); 5.3159 (1.0); 5.2984 (4.0); 5.2809 (4.1); 5.2635 (1.0); 2.2717 (0.8); 2.1083 (2.3); 2.0081 (16.0); 1.7477 (13.7); 1.7302 (13.6); 1.4321 (7.8); 1.3323 (0.5); 1.2841 (0.8); 1.2541 (1.2); 0.0080 (1.1); −0.0002 (46.1); −0.0085 (1.4) X-020: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1258 (1.0); 8.1196 (1.1); 7.6723 (0.6); 7.6680 (0.5); 7.2666 (0.5); 7.2657 (0.6); 7.2607 (81.1); 7.1447 (1.3); 7.1389 (0.5); 7.1329 (1.4); 7.1274 (1.0); 7.1218 (2.2); 7.1159 (0.7); 7.1101 (2.1); 7.0481 (2.2); 7.0422 (0.8); 7.0364 (0.6); 7.0282 (2.6); 7.0253 (2.0); 7.0226 (1.0); 7.0171 (0.5); 7.0112 (0.7); 7.0055 (1.5); 6.9971 (0.7); 6.9894 (0.9); 6.9880 (0.9); 6.9819 (0.9); 6.9803 (0.9); 6.9683 (0.8); 6.9668 (0.9); 6.9607 (0.8); 6.9592 (0.8); 5.3003 (1.0); 4.9079 (6.8); 4.1721 (3.2); 4.1589 (3.2); 3.7971 (16.0); 1.5490 (2.7); 1.4322 (1.2); 0.0080 (1.2); −0.0002 (48.1); −0.00085 (1.5) X-019: .sup.1H-NMR(300.1 MHz, d.sub.6-DMSO): δ = 8.1940 (2.1); 8.1858 (2.2); 7.9649 (0.8); 7.9566 (0.8); 7.9368 (1.2); 7.9285 (1.1); 7.9108 (0.8); 7.9023 (0.8); 7.5938 (0.8); 7.5734 (1.3); 7.5679 (1.7); 7.5477 (0.9); 7.5420 (0.9); 7.5143 (0.4); 7.5085 (0.4); 7.4972 (0.4); 7.4885 (0.8); 7.4820 (0.7); 7.4719 (0.8); 7.4619 (0.8); 7.4556 (0.6); 7.4446 (0.6); 7.4387 (0.5); 7.3412 (1.2); 7.3156 (3.3); 7.3036 (1.6); 7.2946 (2.0); 7.2890 (1.8); 7.2809 (1.5); 7.2765 (2.2); 7.2672 (1.3); 7.2533 (0.8); 7.2491 (0.7); 5.1191 (5.6); 3.7166 (16.0); 3.3247 (5.8); 3.1180 (14.4); 2.5135 (11.7); 2.5076 (23.1); 2.5017 (30.5); 2.4958 (20.9); 2.4900 (9.6); 2.0755 (2.5); 0.0108 (1.3); −0.0001 (33.9);−0.0112 (1.2) VII-068: .sup.1H-NMR(300.1 MHz, d.sub.6-DMSO): δ = 11.4070 (2.8); 8.1956 (4.8); 8.1875 (5.0); 7.9635 (1.8); 7.9551 (1.6); 7.9354 (2.8); 7.9271 (2.5); 7.9094 (1.9); 7.9010 (1.8); 7.6049 (1.0); 7.5989 (1.7); 7.5777 (2.7); 7.5730 (3.6); 7.5526 (1.8); 7.5469 (2.1); 7.5238 (0.7); 7.5181 (0.7); 7.5064 (0.8); 7.4974 (1.8); 7.4811 (1.7); 7.4715 (1.9); 7.4655 (1.2); 7.4542 (1.3); 7.4482 (1.0); 7.3441 (2.7); 7.3192 (7.2); 7.3044 (3.6); 7.2944 (6.3); 7.2762 (3.2); 7.2679 (3.1); 7.2598 (1.9); 4.6607 (6.3); 3.6087 (16.0); 3.3243 (10.0); 2.7273 (0.6); 2.5132 (35.5); 2.5074 (70.6); 2.5014 (93.6); 2.4955 (64.8); 2.4898 (29.9); 2.2776 (0.4); 2.2714 (0.6); 0.1952 (0.3); 0.0108 (3.2); −0.0002 (85.8); −0.0112 (2.8); −0.1987 (0.4) X-024: .sup.1H-NMR(300.1 MHz, d.sub.6-DMSO): δ = 11.3996 (1.0); 11.3579 (0.4); 8.2248 (4.7); 8.2167 (5.3); 7.9740 (1.7); 7.9657 (1.6); 7.9462 (2.8); 7.9375 (2.6); 7.9197 (2.1); 7.9114 (1.9); 7.7030 (1.4); 7.6828 (1.5); 7.6733 (3.0); 7.6535 (3.0); 7.6441 (1.8); 7.6244 (1.6); 7.4447 (1.3); 7.4357 (1.5); 7.4147 (1.7); 7.4084 (2.1); 7.4007 (1.9); 7.3797 (1.4); 7.3704 (1.5); 7.3172 (3.1); 7.3089 (3.1); 7.2889 (3.0); 7.2792 (3.1); 7.2693 (1.4); 7.2422 (2.2); 7.2121 (1.3); 5.0676 (0.4); 4.6544 (6.3); 3.6063 (16.0); 3.3236 (43.4); 3.2993 (1.4); 2.7332 (1.0); 2.7275 (1.4); 2.5545 (0.5); 2.5133 (82.7); 2.5074 (163.6); 2.5014 (216.9); 2.4955 (148.0); 2.4896 (66.7); 2.2714 (1.3); 2.2655 (1.0); 2.0752 (0.9); 1.7524 (0.3); 0.1956 (0.8); 0.0446 (0.5); 0.0108 (9.8); −0.0002 (244.1); −0.0113 (6.4);−0.1986 (0.8) X-028: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 10.7845 (1.6); 10.1993 (0.9); 9.2209 (1.0); 8.9852 (4.4); 8.2173 (7.3); 8.2120 (7.2); 7.9608 (2.0); 7.9549 (2.0); 7.9403 (3.7); 7.9348 (3.5); 7.9202 (2.3); 7.9143 (1.9); 7.7157 (1.2); 7.7003 (1.7); 7.6937 (2.8); 7.6789 (3.0); 7.6720 (2.2); 7.6568 (1.8); 7.4305 (1.6); 7.4240 (1.9); 7.4025 (3.2); 7.3820 (1.8); 7.3757 (2.0); 7.3120 (4.4); 7.3055 (4.5); 7.2906 (4.3); 7.2842 (4.4); 7.2695 (1.6); 7.2475 (3.0); 7.2277 (1.9); 5.0178 (1.8); 4.6510 (16.0); 3.3244 (81.6); 3.3015 (1.2); 2.6735 (0.7); 2.6693 (1.0); 2.6648 (0.8); 2.5090 (63.9); 2.5047 (132.3); 2.5003 (179.2); 2.4958 (129.8); 2.4915 (61.6); 2.3315 (0.8); 2.3272 (1.0); 2.3227 (0.7); 2.0740 (5.5); 0.1445 (0.5); 0.0064 (4.3); −0.00016 (103.0); −0.00098 (3.7); −0.1509 (0.4) X-029: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.4379 (1.1); 8.4234 (2.2); 8.4089 (1.1); 8.2135 (4.0); 8.2074 (4.2); 7.9520 (1.4); 7.9456 (1.4); 7.9309 (2.2); 7.9259 (2.0); 7.9247 (2.0); 7.9113 (1.6); 7.9051 (1.5); 7.7063 (1.2); 7.6913 (1.3); 7.6842 (2.4); 7.6693 (2.4); 7.6622 (1.4); 7.6472 (1.3); 7.4212 (1.2); 7.4143 (1.3); 7.3986 (1.5); 7.3947 (1.8); 7.3920 (1.7); 7.3881 (1.6); 7.3725 (1.3); 7.3655 (1.3); 7.3125 (2.4); 7.3063 (2.4); 7.2911 (2.3); 7.2849 (2.3); 7.2519 (1.0); 7.2485 (1.0); 7.2448 (0.9); 7.2420 (0.9); 7.2284 (1.7); 7.2261 (1.6); 7.2222 (1.6); 7.2092 (0.9); 7.2058 (1.0); 7.2021 (0.8); 7.1991 (0.8); 4.7401 (16.0); 3.3819 (1.8); 3.3660 (5.1); 3.3507 (5.4); 3.3345 (3.1); 3.3254 (11.5); 2.6826 (4.8); 2.6664 (10.5); 2.6501 (4.4); 2.5097 (18.3); 2.5053 (38.6); 2.5007 (53.6); 2.4961 (37.6); 2.4916 (17.6); 2.0740 (15.9); 0.0070 (1.7); −0.00011 (52.8); −0.00095 (1.7) V-006: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.0195 (2.4); 9.0162 (2.3); 8.8404 (2.2); 8.8274 (2.3); 7.7711 (1.6); 7.7676 (1.6); 7.7581 (1.6); 7.7543 (1.6); 7.5193 (0.8); 7.5047 (1.1); 7.5008 (1.1); 7.4859 (0.7); 7.3401 (0.6); 7.3321 (0.6); 7.2602 (73.3); 7.2462 (0.8); 7.2297 (1.2); 7.0158 (0.8); 6.9959 (1.0); 6.9909 (1.0); 6.9788 (1.0); 6.9660 (0.6); 5.3368 (0.6); 5.3197 (1.9); 5.3022 (2.0); 5.2848 (0.6); 5.0075 (0.6); 3.7675 (0.7); 3.7507 (1.8); 3.7342 (0.8); 2.2716 (1.7); 1.8715 (0.7); 1.8639 (0.8); 1.8550 (2.1); 1.8385 (0.8); 1.7555 (7.1); 1.7381 (7.2); 1.4323 (16.0); 1.3328 (0.8); 1.2841 (1.1); 1.2546 (6.3); 0.8803 (1.0); 0.0080 (2.6); −0.0002 (100.5); −0.0085 (3.0) VI-014: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1946 (6.4); 8.6892 (9.9); 7.4599 (1.8); 7.4559 (1.7); 7.4403 (3.2); 7.4215 (1.9); 7.4173 (1.7); 7.3790 (1.2); 7.3642 (2.1); 7.3510 (2.0); 7.3313 (1.3); 7.2620 (17.5); 7.2413 (2.4); 7.2220 (3.4); 7.2024 (1.4); 7.0481 (2.1); 7.0234 (3.0); 7.0019 (1.8); 5.3199 (1.5); 5.3023 (4.1); 5.2847 (4.0); 5.2673 (1.2); 2.0084 (16.0); 1.7546 (14.7); 1.7371 (14.1); −0.0002 (22.9); −0.00084 (1.2) VII-076: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1891 (2.5); 8.1828 (2.4); 7.7082 (1.0); 7.7019 (1.1); 7.6895 (1.4); 7.6870 (1.4); 7.6833 (1.3); 7.6683 (1.1); 7.6621 (1.2); 7.3434 (0.8); 7.3366 (1.0); 7.3213 (3.6); 7.3028 (5.3); 7.2986 (3.2); 7.2944 (2.0); 7.2838 (1.6); 7.2602 (97.8); 7.1496 (3.3); 7.1450 (3.5); 7.1288 (3.0); 7.1253 (2.9); 6.9962 (0.5); 6.9641 (1.7); 6.9580 (1.7); 6.9440 (1.6); 6.9354 (1.5); 5.0025 (16.0); 2.0080 (2.7); 0.0079 (3.6); −0.0002 (130.2); −0.00085 (3.7) VI-015: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.2050 (8.2); 8.6671 (13.7); 7.3558 (0.9); 7.3474 (1.3); 7.3427 (1.0); 7.3334 (5.1); 7.3236 (1.8); 7.3198 (4.4); 7.3146 (11.2); 7.3103 (3.3); 7.3012 (1.9); 7.2977 (1.3); 7.2608 (50.8); 7.1463 (5.3); 7.1410 (4.6); 7.1360 (1.6); 7.1315 (2.0); 7.1258 (4.7); 7.1220 (4.2); 5.3524 (1.2); 5.3351 (4.5); 5.3175 (4.6); 5.3001 (1.2); 2.0081 (11.7); 1.7621 (16.0); 1.7446 (15.9); 0.0080 (1.9); −0.0002 (67.0); −0.00085 (2.1) VII-077: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1262 (2.7); 8.1200 (2.7); 7.6823 (1.1); 7.6761 (1.1); 7.6614 (1.5); 7.6551 (1.5); 7.6422 (1.2); 7.6361 (1.2); 7.3974 (0.9); 7.3930 (1.1); 7.3780 (1.9); 7.3738 (2.0); 7.3591 (1.2); 7.3546 (1.3); 7.3279 (0.6); 7.3236 (0.5); 7.3159 (0.6); 7.3092 (1.0); 7.3045 (0.9); 7.2968 (1.1); 7.2886 (1.0); 7.2839 (0.8); 7.2763 (0.8); 7.2720 (0.7); 7.2607 (35.8); 7.1909 (1.3); 7.1717 (2.0); 7.1545 (0.8); 7.0292 (1.3); 7.0260 (1.3); 7.0083 (1.2); 7.0044 (2.0); 7.0006 (1.3); 6.9830 (1.2); 6.9799 (1.1); 6.9054 (1.8); 6.8980 (1.7); 6.8841 (1.7); 6.8778 (1.6); 4.9148 (16.0); 2.0080 (5.9); 1.6008 (0.5); 1.5873 (1.1); 1.5798 (1.1); 1.5746 (0.7); 1.5667 (1.8); 1.5532 (1.1); 1.5458 (1.2); 1.5325 (0.6); 0.7989 (0.8); 0.7942 (0.6); 0.7854 (1.8); 0.7813 (2.8); 0.7726 (2.0); 0.7649 (2.5); 0.7595 (2.6); 0.7519 (1.9); 0.7402 (0.8); 0.7328 (1.8); 0.7236 (3.0); 0.7194 (3.8); 0.7116 (3.1); 0.7066 (2.8); 0.6931 (0.8); 0.0080 (1.2); −0.0002 (47.0); −0.00085 (1.4) VII-101: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.2339 (4.3); 8.2284 (4.4); 7.9759 (1.4); 7.9698 (1.4); 7.9553 (2.4); 7.9499 (2.3); 7.9354 (1.5); 7.9293 (1.4); 7.6786 (1.1); 7.6634 (1.4); 7.6565 (2.3); 7.6416 (2.3); 7.6346 (1.5); 7.6196 (1.2); 7.4356 (1.2); 7.4289 (1.4); 7.4086 (2.1); 7.3869 (1.3); 7.3802 (1.3); 7.3117 (2.6); 7.3054 (2.6); 7.2904 (2.5); 7.2841 (2.4); 7.2590 (1.2); 7.2553 (1.2); 7.2385 (2.1); 7.2193 (1.1); 7.2164 (1.1); 5.0762 (0.4); 4.9338 (15.0); 4.7763 (0.4); 4.1966 (2.5); 4.1789 (7.3); 4.1611 (7.4); 4.1434 (2.6); 3.3241 (9.6); 2.5524 (0.4); 2.5082 (20.8); 2.5040 (26.3); 2.4999 (20.1); 1.2361 (0.4); 1.2077 (8.0); 1.1900 (16.0); 1.1723 (7.8); 1.1618 (1.0); 1.1439 (0.4); 0.0013 (9.1) VII-100: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 13.0482 (1.4); 12.9628 (0.4); 8.2295 (11.1); 8.2240 (11.5); 7.9737 (3.3); 7.9675 (3.6); 7.9529 (6.0); 7.9477 (5.8); 7.9331 (3.8); 7.9269 (3.6); 7.6900 (2.3); 7.6679 (5.0); 7.6528 (5.0); 7.6457 (3.2); 7.6310 (2.6); 7.4280 (2.8); 7.4211 (3.2); 7.3992 (5.2); 7.3788 (3.2); 7.3721 (3.0); 7.3100 (7.0); 7.3037 (7.1); 7.2887 (6.9); 7.2821 (6.7); 7.2570 (3.2); 7.2364 (5.4); 7.2152 (2.8); 5.0206 (0.5); 4.8129 (16.0); 3.5084 (0.6); 3.4258 (0.3); 3.3208 (50.6); 2.9525 (1.1); 2.8909 (0.4); 2.8419 (1.0); 2.7318 (0.5); 2.6757 (2.3); 2.6711 (3.0); 2.6666 (2.4); 2.5110 (201.9); 2.5066 (405.8); 2.5022 (549.1); 2.4977 (396.3); 2.4935 (189.7); 2.3640 (0.3); 2.3333 (2.2); 2.3291 (3.2); 2.3245 (2.2); 2.2067 (0.4); 2.0754 (2.7); 1.7541 (7.3); 1.2369 (0.8); 0.7594 (0.5); 0.1470 (1.5); 0.1273 (0.3); 0.0700 (0.8); 0.0614 (0.7); 0.0089 (17.2); 0.0009 (369.4); −0.00074 (13.3); −0.1485 (1.6) II-014: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.5108 (4.8); 8.5038 (4.7); 7.9316 (1.3); 7.9244 (1.2); 7.9099 (2.8); 7.9026 (2.6); 7.8883 (1.7); 7.8810 (1.5); 7.7955 (2.8); 7.7844 (2.9); 7.7736 (2.2); 7.7626 (2.0); 7.4567 (2.5); 7.4398 (4.6); 7.4374 (4.6); 7.4215 (4.0); 7.4042 (1.2); 7.2880 (2.4); 7.2682 (4.8); 7.2468 (2.5); 7.2406 (2.4); 7.2189 (1.5); 5.0908 (0.3); 4.9471 (15.5); 4.7827 (0.4); 4.1976 (2.6); 4.1799 (7.5); 4.1622 (7.4); 4.1444 (2.5); 3.3408 (4.3); 3.3171 (0.5); 2.5075 (14.7); 2.5039 (17.9); 2.0789 (3.7); 1.2055 (8.2); 1.1878 (16.0); 1.1701 (7.6); 1.1557 (0.5); 0.0000 (4.9) II-015: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 13.1071 (1.8); 8.5101 (8.5); 8.5031 (8.8); 7.9317 (2.2); 7.9244 (2.1); 7.9100 (5.1); 7.9028 (4.8); 7.8883 (3.2); 7.8811 (3.0); 7.7953 (4.7); 7.7843 (5.1); 7.7735 (3.8); 7.7624 (3.6); 7.4731 (2.3); 7.4537 (5.8); 7.4350 (5.4); 7.4244 (3.4); 7.4193 (3.0); 7.4044 (2.0); 7.2909 (3.6); 7.2715 (5.7); 7.2616 (4.0); 7.2552 (3.2); 7.2354 (4.1); 7.2142 (2.8); 4.8445 (16.0); 3.3429 (1.7); 2.6725 (0.4); 2.5077 (46.9); 2.5035 (61.6); 2.4992 (46.1); 2.3305 (0.4); 2.3259 (0.3); 2.0781 (1.4); 0.0080 (0.7); 0.0000 (16.6); −0.0082 (1.0) VIII-003: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1928 (2.8); 8.1798 (2.9); 7.4342 (0.8); 7.4298 (1.0); 7.4149 (1.5); 7.4106 (1.8); 7.4029 (0.6); 7.3962 (1.0); 7.3914 (1.5); 7.3838 (0.9); 7.3795 (0.7); 7.3716 (1.0); 7.3654 (0.7); 7.3633 (0.8); 7.3588 (0.6); 7.3510 (0.8); 7.3465 (0.6); 7.2618 (29.0); 7.2497 (1.1); 7.2481 (1.2); 7.2287 (1.7); 7.2111 (0.7); 7.0741 (1.2); 7.0711 (2.3); 7.0672 (2.1); 7.0633 (1.3); 7.0581 (1.3); 7.0538 (2.8); 7.0500 (2.8); 7.0457 (1.2); 7.0282 (1.0); 7.0249 (0.9); 6.8730 (1.9); 6.8698 (3.0); 5.3000 (1.7); 4.9006 (16.0); 4.2964 (2.0); 4.2786 (6.2); 4.2607 (6.3); 4.2429 (2.1); 1.3074 (7.6); 1.2896 (15.4); 1.2718 (7.4); −0.0002 (17.4); −0.0085 (0.5) II-012: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.3057 (3.0); 8.2985 (3.0); 7.6718 (1.4); 7.6608 (1.4); 7.6489 (1.7); 7.6391 (1.8); 7.4769 (1.4); 7.4696 (1.7); 7.4531 (2.0); 7.4486 (3.1); 7.4350 (1.8); 7.4285 (1.5); 7.2979 (0.5); 7.2912 (0.8); 7.2866 (0.8); 7.2792 (0.9); 7.2707 (1.0); 7.2601 (41.3); 7.2542 (0.9); 7.1975 (1.2); 7.1780 (1.7); 7.1592 (0.7); 6.9821 (1.1); 6.9787 (1.1); 6.9614 (1.1); 6.9567 (1.5); 6.9530 (1.2); 6.9357 (1.0); 6.9322 (0.9); 5.2998 (1.2); 4.9012 (16.0); 4.2881 (1.9); 4.2703 (6.2); 4.2524 (6.3); 4.2434 (0.5); 4.2345 (2.2); 1.5404 (12.3); 1.3112 (0.6); 1.3032 (7.7); 1.2933 (1.3); 1.2854 (15.8); 1.2755 (0.8); 1.2675 (7.6); 1.2555 (0.8); 0.0690 (0.6); 0.0080 (1.4); −0.0002 (54.5); −0.00085 (1.6) X-021-a: .sup.1H-NMR(400.0 MHz, d.sub.6-DMSO): δ = 4.7863 (1.2); 3.8307 (0.6); 3.8161 (0.6); 3.3214 (16.0); 2.5102 (7.3); 2.5057 (16.0); 2.5012 (22.6); 2.4966 (16.1); 2.4921 (7.4); −0.0002 (10.8) II-013: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.3002 (2.1); 8.2932 (2.0); 7.7156 (1.0); 7.7047 (1.1); 7.6937 (1.2); 7.6830 (1.2); 7.5369 (0.6); 7.5329 (0.6); 7.5178 (1.2); 7.5134 (1.2); 7.5014 (1.0); 7.4943 (1.5); 7.4811 (1.1); 7.4740 (1.0); 7.4599 (0.6); 7.4526 (0.6); 7.3256 (0.6); 7.3091 (0.7); 7.3010 (0.5); 7.2605 (19.9); 7.2409 (0.9); 7.2211 (1.2); 7.2031 (0.5); 7.1233 (0.6); 7.0014 (0.7); 6.9982 (0.7); 6.9764 (1.0); 6.9552 (0.6); 5.2998 (2.1); 4.8952 (8.7); 4.1777 (4.1); 4.1643 (4.0); 3.7932 (16.0); 1.5459 (4.8); 1.2553 (0.8); 0.0079 (1.0); −0.0002 (26.9); −0.00085 (1.0) VIII-009: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.2091 (1.7); 8.1961 (1.8); 7.4876 (0.5); 7.4833 (0.6); 7.4683 (1.0); 7.4641 (1.1); 7.4495 (0.6); 7.4451 (0.7); 7.4083 (0.5); 7.3960 (0.5); 7.3877 (0.5); 7.2793 (0.7); 7.2622 (9.5); 7.0873 (1.0); 7.0841 (1.0); 7.0755 (1.0); 7.0716 (1.4); 7.0673 (1.2); 7.0625 (1.9); 7.0587 (1.9); 7.0548 (0.8); 7.0413 (0.6); 7.0380 (0.6); 6.8815 (1.8); 5.3001 (1.4); 4.8849 (8.0); 4.1812 (3.7); 4.1678 (3.6); 3.7985 (16.0); 1.5735 (2.1); −0.0002(10.8) VII-044: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1913 (0.6); 8.1782 (0.6); 7.2594 (55.4); 7.2497 (0.6); 7.0701 (0.5); 7.0529 (0.7); 7.0490 (0.7); 6.8677 (0.7); 4.8991 (3.6); 4.2780 (1.4); 4.2601 (1.4); 2.0048 (0.5); 1.5328 (16.0); 1.3067 (1.7); 1.2889 (3.5); 1.2711 (1.7); 0.0079 (0.9); −0.0002 (28.2); −0.00085 (1.0) VII-046: .sup.1H-NMR(400.2 MHz, d.sub.6-DMSO): δ = 8.0577 (2.5); 8.0548 (2.8); 7.9509 (2.6); 7.9480 (2.6); 7.8809 (0.7); 7.8761 (0.8); 7.8636 (0.8); 7.8588 (0.8); 7.7505 (0.4); 7.7451 (0.4); 7.7384 (0.4); 7.7304 (0.6); 7.7237 (0.5); 7.7170 (0.5); 7.7117 (0.4); 7.5583 (0.8); 7.5363 (0.7); 7.5317 (0.9); 7.5098 (0.6); 5.3171 (5.5); 3.7244 (16.0); 3.3315 (7.6); 2.5237 (0.4); 2.5149 (6.0); 2.5105 (12.3); 2.5060 (16.2); 2.5014 (11.6); 2.4968 (5.5); 0.0080 (0.4); −0.0002 (12.6); −0.00085 (0.4) VII-128: .sup.1H-NMR(400.0 MHz, DMSO_5 mm): δ = 3.3527 (16.0); 2.5212 (0.6); 2.5125 (4.3); 2.5080 (9.0); 2.5034 (12.4); 2.4987 (8.7); 2.4941 (3.8); 1.5698 (1.0); 1.5523 (0.9); −0.0002 (2.3) VII-114: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.9314 (9.5); 8.0532 (2.4); 8.0473 (2.5); 7.8830 (1.1); 7.8767 (1.0); 7.8619 (1.4); 7.8580 (1.3); 7.8557 (1.2); 7.8431 (1.1); 7.8369 (1.0); 7.4498 (0.9); 7.4455 (1.1); 7.4305 (1.7); 7.4265 (2.0); 7.4182 (0.6); 7.4112 (1.3); 7.4076 (1.6); 7.4035 (1.1); 7.3905 (1.1); 7.3831 (0.9); 7.3785 (0.6); 7.3704 (0.8); 7.3661 (0.6); 7.2625 (8.0); 7.2543 (1.4); 7.2349 (2.0); 7.2157 (0.8); 7.0739 (1.2); 7.0708 (1.2); 7.0528 (1.2); 7.0494 (2.0); 7.0460 (1.2); 7.0281 (1.1); 7.0250 (1.0); 6.9664 (1.7); 6.9592 (1.7); 6.9451 (1.6); 6.9378 (1.6); 5.2998 (2.6); 4.9546 (16.0); 4.3048 (2.1); 4.2870 (6.3); 4.2691 (6.3); 4.2513 (2.1); 1.5705 (5.3); 1.3125 (7.2); 1.2946 (14.3); 1.2768 (6.9); 0.0078 (0.5); −0.0002 (11.6) X-034: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4434 (1.3); 8.4367 (1.3); 8.2854 (1.5); 7.4463 (0.7); 7.4424 (0.8); 7.4217 (1.0); 7.4172 (0.8); 7.4148 (0.8); 7.4104 (0.7); 7.3994 (0.8); 7.3950 (0.8); 7.3925 (0.8); 7.3881 (0.7); 7.2628 (8.3); 7.2390 (0.6); 7.2197 (0.9); 7.0564 (0.5); 7.0534 (0.5); 7.0354 (0.5); 7.0318 (0.8); 7.0283 (0.6); 5.3003 (10.1); 5.0650 (0.8); 5.0588 (0.9); 4.9961 (0.6); 4.9872 (0.6); 3.6885 (16.0); 2.0452 (1.6); 1.5954 (1.2); 1.2594 (1.0); −0.0002 (12.7) X-037: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4441 (1.4); 8.4383 (1.5); 8.2841 (1.7); 7.4597 (0.7); 7.4554 (0.8); 7.4405 (1.4); 7.4364 (1.6); 7.4218 (1.4); 7.4177 (1.7); 7.4158 (1.7); 7.4128 (1.0); 7.4086 (0.7); 7.4000 (0.6); 7.3959 (0.9); 7.3931 (1.2); 7.3905 (0.9); 7.3863 (0.7); 7.3573 (0.8); 7.3529 (0.7); 7.3451 (0.8); 7.3407 (0.8); 7.3380 (0.8); 7.3327 (0.6); 7.3250 (0.6); 7.3206 (0.5); 7.2640 (9.1); 7.2396 (1.1); 7.2377 (1.2); 7.2180 (1.8); 7.2010 (0.7); 7.1992 (0.7); 7.0551 (0.9); 7.0525 (0.9); 7.0308 (1.5); 7.0091 (0.8); 7.0065 (0.8); 5.3004 (12.2); 4.9332 (2.6); 4.9226 (5.3); 3.8394 (0.9); 3.8206 (3.1); 3.8022 (3.1); 3.7834 (0.9); 3.7236 (14.2); 3.7177 (16.0); 3.6972 (0.9); 3.6218 (0.8); 3.5962 (0.7); 3.5756 (0.7); 3.1968 (0.6); 3.1780 (0.8); 3.1593 (0.6); 3.0951 (0.6); 3.0776 (0.7); 3.0583 (0.5); 2.2890 (0.8); 2.2709 (0.8); 2.2582 (0.6); 2.2436 (0.7); 2.2044 (0.6); 2.1856 (0.9); 2.1725 (0.6); 2.1646 (1.1); 2.1449 (1.0); 2.0449 (1.9); 1.6275 (1.9); 1.2770 (0.6); 1.2592 (1.3); 1.2413 (0.5); −0.0002 (14.8) X-035: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4410 (1.7); 8.4342 (1.7); 8.2798 (1.9); 8.2762 (1.4); 7.4954 (0.5); 7.4804 (0.9); 7.4762 (0.9); 7.4615 (0.6); 7.4571 (0.6); 7.4161 (0.9); 7.4117 (0.9); 7.4092 (0.8); 7.4048 (0.8); 7.3938 (0.7); 7.3894 (0.9); 7.3870 (0.8); 7.3826 (0.8); 7.3529 (0.5); 7.3406 (0.6); 7.2620 (11.4); 7.2396 (0.7); 7.2202 (1.0); 7.0464 (0.6); 7.0432 (0.6); 7.0258 (0.6); 7.0217 (1.0); 7.0179 (0.6); 7.0004 (0.5); 6.9972 (0.5); 5.3003 (6.3); 5.0301 (0.8); 4.9943 (2.8); 4.9679 (2.8); 4.9321 (1.1); 4.8970 (0.6); 4.8393 (0.5); 4.5900 (0.5); 4.5809 (0.6); 4.5698 (0.6); 4.5593 (0.6); 3.7291 (4.4); 3.7250 (16.0); 3.7143 (0.7); 3.7014 (0.6); 3.6490 (0.7); 2.1895 (0.5); 2.0453 (1.8); 2.0317 (0.8); 2.0168 (0.8); 2.0104 (0.6); 2.0012 (0.5); 1.5839 (4.0); 1.2594 (0.9); 0.0079 (0.5); −0.0002 (17.9); −0.00085 (0.6) X-036: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4437 (2.7); 8.4369 (2.8); 8.2863 (2.9); 7.4650 (0.8); 7.4606 (0.9); 7.4457 (1.5); 7.4415 (1.6); 7.4268 (1.1); 7.4227 (2.3); 7.4184 (1.5); 7.4159 (1.4); 7.4115 (1.2); 7.4005 (1.3); 7.3961 (1.5); 7.3937 (1.3); 7.3893 (1.2); 7.3651 (0.5); 7.3605 (0.7); 7.3584 (0.9); 7.3565 (0.7); 7.3540 (0.8); 7.3462 (0.9); 7.3444 (0.7); 7.3417 (0.8); 7.3398 (0.8); 7.3377 (0.8); 7.3333 (0.7); 7.3256 (0.7); 7.3211 (0.6); 7.2619 (21.1); 7.2441 (1.1); 7.2425 (1.2); 7.2408 (1.2); 7.2212 (1.7); 7.2056 (0.7); 7.2039 (0.8); 7.2022 (0.7); 7.0544 (1.1); 7.0512 (1.0); 7.0335 (1.0); 7.0298 (1.7); 7.0261 (1.1); 7.0085 (1.0); 7.0053 (0.9); 5.3002 (13.7); 4.9962 (8.7); 4.3710 (0.5); 4.1814 (2.0); 4.1636 (6.3); 4.1458 (6.5); 4.1280 (2.1); 3.8195 (0.5); 3.1929 (0.6); 2.9398 (0.6); 2.5903 (0.6); 2.5741 (0.6); 2.5639 (1.2); 2.5539 (0.7); 2.5377 (0.7); 1.9928 (0.8); 1.9620 (1.1); 1.5753 (6.6); 1.2780 (7.5); 1.2602 (16.0); 1.2424 (7.2); 0.0079 (0.9); −0.0002 (32.8); −0.00085 (0.9) X-012: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1474 (4.3); 8.1411 (4.4); 7.7714 (1.8); 7.7651 (1.8); 7.7528 (2.2); 7.7501 (2.3); 7.7465 (2.2); 7.7439 (2.2); 7.7316 (1.9); 7.7253 (1.9); 7.4918 (1.6); 7.4875 (1.8); 7.4725 (2.8); 7.4685 (3.0); 7.4537 (1.9); 7.4494 (2.0); 7.4165 (0.9); 7.4121 (0.9); 7.4042 (1.0); 7.3975 (1.5); 7.3932 (1.4); 7.3852 (1.6); 7.3808 (1.5); 7.3769 (1.4); 7.3724 (1.2); 7.3646 (1.3); 7.3602 (1.1); 7.2613 (35.0); 7.2438 (3.2); 7.2245 (1.3); 7.1147 (1.7); 7.0750 (2.0); 7.0719 (2.0); 7.0542 (2.0); 7.0505 (3.3); 7.0469 (2.1); 7.0292 (1.8); 7.0260 (1.7); 6.9790 (0.8); 6.9658 (2.7); 6.9586 (2.8); 6.9446 (2.6); 6.9374 (2.7); 6.6303 (6.4); 6.4894 (6.5); 4.2562 (8.7); 4.2430 (8.8); 4.1520 (1.1); 4.1342 (3.4); 4.1163 (3.4); 4.0985 (1.2); 3.7742 (0.7); 2.2717 (1.4); 2.0499 (16.0); 1.8712 (0.8); 1.4321 (13.4); 1.2788 (4.4); 1.2609 (9.1); 1.2548 (1.3); 1.2430 (4.5); 0.0079 (1.4); −0.0002 (50.1); −0.00084 (1.6) X-010: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 8.1932 (2.4); 8.1870 (2.5); 7.9586 (1.0); 7.9523 (1.0); 7.9391 (1.3); 7.9374 (1.4); 7.9329 (1.3); 7.9311 (1.4); 7.9180 (1.1); 7.9117 (1.1); 7.6014 (0.9); 7.5975 (0.6); 7.5859 (0.9); 7.5819 (1.8); 7.5781 (1.2); 7.5665 (0.6); 7.5625 (1.0); 7.5586 (0.7); 7.5025 (0.5); 7.4942 (0.6); 7.4880 (0.9); 7.4835 (0.8); 7.4753 (0.9); 7.4709 (0.9); 7.4675 (0.9); 7.4629 (0.7); 7.4546 (0.7); 7.4502 (0.6); 7.3392 (1.2); 7.3199 (1.9); 7.3044 (1.7); 7.3011 (1.9); 7.2981 (2.2); 7.2911 (1.7); 7.2838 (1.2); 7.2753 (2.7); 7.2699 (1.6); 7.2685 (1.5); 7.2577 (1.0); 7.2545 (0.9); 4.9436 (2.2); 4.9346 (3.8); 4.0557 (1.0); 4.0379 (3.3); 4.0202 (3.4); 4.0024 (1.1); 3.7088 (0.5); 3.7035 (0.6); 3.6839 (0.6); 3.5854 (0.9); 3.5672 (0.9); 3.5608 (0.7); 3.5551 (0.9); 3.5425 (1.0); 3.5352 (0.9); 3.5281 (0.6); 3.5232 (0.5); 3.5094 (0.7); 3.5032 (0.8); 3.4919 (1.0); 3.4864 (1.0); 3.4738 (0.8); 3.4675 (0.6); 3.4576 (0.6); 3.4494 (0.6); 3.3509 (0.8); 3.3210 (7.6); 3.1342 (0.7); 3.0445 (0.5); 3.0273 (0.6); 2.6704 (0.5); 2.5410 (2.2); 2.5242 (1.3); 2.5195 (1.6); 2.5108 (26.1); 2.5062 (59.2); 2.5016 (84.7); 2.4970 (60.2); 2.4924 (28.0); 2.3286 (0.5); 2.1828 (0.5); 2.1399 (0.5); 2.0861 (0.7); 2.0678 (0.8); 2.0540 (0.7); 1.9887 (16.0); 1.9568 (0.5); 1.9367 (0.5); 1.9086 (0.8); 1.3554 (4.7); 1.2355 (1.7); 1.1922 (4.6); 1.1745 (9.9); 1.1567 (4.8); 0.0080 (1.7); 0.0040 (0.6); −0.0002 (60.4); −0.00057 (0.9); −0.00066 (0.7); −0.00085 (1.8) X-009: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 8.1877 (2.3); 8.1833 (2.1); 8.1815 (2.4); 7.9549 (1.0); 7.9486 (1.0); 7.9352 (1.3); 7.9337 (1.4); 7.9291 (1.3); 7.9274 (1.3); 7.9143 (1.1); 7.9080 (1.0); 7.6296 (0.6); 7.6253 (0.8); 7.6101 (1.4); 7.6059 (1.5); 7.5908 (1.0); 7.5864 (0.9); 7.4879 (0.8); 7.4859 (0.8); 7.4835 (0.8); 7.4751 (0.9); 7.4707 (0.9); 7.4689 (0.8); 7.4628 (0.6); 7.4545 (0.6); 7.4501 (0.5); 7.3445 (1.0); 7.3419 (1.3); 7.3254 (1.6); 7.3225 (2.0); 7.3061 (1.0); 7.3031 (1.1); 7.2994 (2.4); 7.2914 (1.7); 7.2840 (0.5); 7.2782 (2.1); 7.2766 (2.2); 7.2735 (1.7); 7.2702 (2.4); 7.2526 (0.8); 7.2495 (0.7); 5.0419 (0.6); 5.0046 (3.4); 4.9926 (3.0); 4.9703 (0.7); 4.9552 (0.6); 4.6946 (0.6); 4.6584 (0.7); 4.2783 (1.0); 4.2682 (1.1); 4.2561 (1.1); 4.2465 (0.9); 4.0557 (1.1); 4.0380 (3.4); 4.0202 (3.4); 4.0024 (1.1); 3.6019 (0.9); 3.5844 (0.6); 3.5747 (0.7); 3.5590 (1.4); 3.5401 (1.4); 3.5222 (0.7); 3.5154 (0.5); 3.4206 (0.5); 3.3215 (8.9); 2.5410 (1.6); 2.5243 (1.2); 2.5196 (1.5); 2.5109 (22.6); 2.5063 (50.6); 2.5017 (71.5); 2.4971 (50.1); 2.4925 (22.7); 2.1828 (0.6); 2.1613 (0.6); 2.1398 (0.8); 2.1299 (0.8); 2.1203 (0.6); 2.1121 (0.7); 1.9888 (16.0); 1.9348 (1.1); 1.9176 (1.7); 1.9087 (3.2); 1.9001 (1.3); 1.8834 (0.9); 1.8721 (0.8); 1.8537 (0.6); 1.8430 (0.6); 1.8297 (0.5); 1.7594 (0.5); 1.3555 (4.5); 1.2355 (1.4); 1.1922 (4.9); 1.1744 (9.8); 1.1567 (4.6); 0.0080 (1.3); −0.0002 (49.2); −0.00052 (0.8); −0.00060 (0.6); −0.00069 (0.5); −0.00085 (1.5) X-008: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1090 (2.6); 8.1028 (2.7); 7.7660 (1.1); 7.7598 (1.1); 7.7472 (1.4); 7.7448 (1.5); 7.7410 (1.4); 7.7386 (1.4); 7.7261 (1.2); 7.7198 (1.2); 7.4453 (0.9); 7.4409 (1.1); 7.4260 (1.7); 7.4218 (2.0); 7.4072 (1.2); 7.4028 (1.2); 7.3684 (0.5); 7.3640 (0.5); 7.3562 (0.6); 7.3494 (1.0); 7.3450 (0.9); 7.3372 (1.0); 7.3328 (0.9); 7.3289 (0.9); 7.3244 (0.7); 7.3166 (0.8); 7.3122 (0.7); 7.2609 (43.2); 7.2260 (1.4); 7.2066 (1.9); 7.1894 (0.8); 7.0487 (1.2); 7.0456 (1.2); 7.0279 (1.2); 7.0242 (2.1); 7.0205 (1.3); 7.0029 (1.1); 6.9997 (1.1); 6.9423 (1.8); 6.9349 (1.8); 6.9211 (1.7); 6.9198 (1.7); 6.9137 (1.7); 4.9992 (5.1); 4.9932 (5.4); 4.9718 (0.6); 4.4127 (0.6); 4.3783 (0.6); 4.1494 (1.1); 4.1316 (3.2); 4.1138 (3.3); 4.0960 (1.1); 3.8794 (0.5); 3.8461 (0.6); 3.2176 (0.7); 2.9711 (0.7); 2.6629 (0.6); 2.6470 (0.7); 2.6368 (1.3); 2.6268 (0.7); 2.6108 (0.7); 2.2717 (0.7); 2.1073 (1.1); 2.0463 (16.0); 2.0311 (1.0); 1.9977 (1.4); 1.8560 (0.7); 1.8254 (0.6); 1.8001 (0.6); 1.7470 (0.6); 1.7225 (0.5); 1.4322 (6.8); 1.2776 (4.6); 1.2598 (9.5); 1.2420 (4.7); 0.0080 (2.0); −0.0002 (69.6); −0.00085 (2.1) X-033: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 12.4345 (0.6); 8.6443 (3.1); 8.6373 (3.1); 8.3537 (1.5); 8.3497 (2.8); 8.3459 (1.5); 7.7841 (0.6); 7.7777 (0.8); 7.7732 (0.6); 7.7606 (0.7); 7.7561 (0.8); 7.7496 (0.6); 7.6113 (0.5); 7.5954 (1.0); 7.5919 (1.0); 7.5760 (0.5); 7.5725 (0.6); 7.4941 (0.6); 7.4923 (0.6); 7.4895 (0.6); 7.4813 (0.7); 7.4769 (0.6); 7.4735 (0.7); 7.4689 (0.5); 7.4607 (0.5); 7.3476 (0.8); 7.3447 (1.0); 7.3286 (1.3); 7.3253 (1.6); 7.3064 (1.6); 7.2859 (0.8); 7.2807 (1.0); 7.2774 (0.9); 7.2597 (0.7); 7.2566 (0.6); 5.1278 (0.6); 5.0709 (0.7); 5.0539 (0.7); 5.0334 (0.8); 4.0559 (1.1); 4.0381 (3.4); 4.0203 (3.5); 4.0026 (1.2); 3.3222 (13.1); 2.5413 (1.2); 2.5245 (0.7); 2.5199 (1.0); 2.5111 (13.0); 2.5065 (29.0); 2.5019 (41.2); 2.4973 (29.1); 2.4927 (13.2); 1.9888 (16.0); 1.9090 (1.0); 1.3557 (2.8); 1.1923 (5.0); 1.1745 (9.9); 1.1567 (4.8); 0.0080 (0.8); −0.0002 (28.3); −0.00085 (0.9) X-040: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 12.5466 (0.9); 8.6455 (3.6); 8.6386 (3.6); 8.3529 (1.8); 8.3488 (3.4); 8.3451 (1.8); 7.7854 (1.1); 7.7811 (1.2); 7.7785 (1.2); 7.7742 (1.1); 7.7619 (1.2); 7.7575 (1.3); 7.7549 (1.1); 7.7506 (1.1); 7.6169 (0.8); 7.6130 (0.5); 7.6012 (0.8); 7.5974 (1.6); 7.5936 (1.0); 7.5819 (0.5); 7.5780 (0.9); 7.5741 (0.6); 7.4943 (0.8); 7.4897 (0.7); 7.4815 (0.8); 7.4771 (0.8); 7.4737 (0.8); 7.4691 (0.6); 7.4609 (0.6); 7.4564 (0.6); 7.3492 (1.1); 7.3299 (1.6); 7.3105 (0.8); 7.3064 (1.3); 7.3031 (1.0); 7.2854 (1.0); 7.2802 (1.3); 7.2769 (1.1); 7.2592 (0.9); 7.2561 (0.8); 4.9513 (2.1); 4.9429 (3.2); 4.0557 (1.1); 4.0379 (3.4); 4.0202 (3.4); 4.0024 (1.1); 3.7058 (0.6); 3.6860 (0.5); 3.5872 (0.8); 3.5689 (0.8); 3.5563 (0.8); 3.5441 (0.8); 3.5362 (0.8); 3.5105 (0.6); 3.5050 (0.8); 3.4935 (0.9); 3.4885 (0.9); 3.4757 (0.8); 3.4692 (0.6); 3.4594 (0.6); 3.3526 (0.6); 3.3212 (18.8); 3.1374 (0.6); 3.0298 (0.6); 2.5410 (1.5); 2.5242 (1.0); 2.5195 (1.5); 2.5108 (21.4); 2.5062 (47.6); 2.5016 (66.9); 2.4970 (47.0); 2.4925 (21.4); 2.0879 (0.6); 2.0697 (0.7); 2.0560 (0.7); 1.9887 (16.0); 1.9087 (0.6); 1.3555 (3.1); 1.1922 (4.7); 1.1744 (9.4); 1.1566 (4.6); 0.0080 (1.2); −0.0002 (44.3); −0.00085 (1.4) X-039: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 8.6474 (2.7); 8.6404 (2.8); 8.3478 (1.6); 8.3440 (2.6); 8.3405 (1.3); 7.7806 (0.9); 7.7763 (1.0); 7.7737 (1.0); 7.7693 (0.9); 7.7570 (1.0); 7.7526 (1.1); 7.7501 (0.9); 7.7458 (0.9); 7.6457 (0.5); 7.6414 (0.6); 7.6261 (1.1); 7.6219 (1.2); 7.6067 (0.8); 7.6024 (0.7); 7.4943 (0.6); 7.4922 (0.6); 7.4898 (0.6); 7.4815 (0.6); 7.4770 (0.6); 7.4752 (0.6); 7.3547 (0.7); 7.3523 (1.0); 7.3329 (1.5); 7.3163 (0.5); 7.3136 (0.7); 7.3007 (0.7); 7.2976 (0.6); 7.2800 (0.7); 7.2747 (0.8); 7.2713 (0.7); 7.2537 (0.6); 7.2505 (0.5); 5.0124 (2.5); 5.0018 (2.4); 4.9795 (0.5); 4.2801 (0.8); 4.2700 (0.9); 4.2580 (0.8); 4.2484 (0.7); 4.0559 (1.1); 4.0381 (3.4); 4.0203 (3.4); 4.0026 (1.1); 3.5766 (0.5); 3.5609 (1.1); 3.5414 (1.1); 3.5235 (0.5); 3.3228 (2.6); 2.5413 (0.9); 2.5246 (0.6); 2.5199 (0.9); 2.5111 (11.8); 2.5065 (26.1); 2.5020 (37.0); 2.4974 (26.0); 2.4928 (11.7); 2.1410 (0.6); 2.1312 (0.6); 2.1136 (0.5); 1.9888 (16.0); 1.9362 (0.8); 1.9191 (1.3); 1.9090 (1.1); 1.9017 (1.0); 1.8849 (0.7); 1.8736 (0.6); 1.3558 (1.8); 1.1923 (4.7); 1.1745 (9.8); 1.1567 (4.7); 0.0080 (0.7); −0.0002 (24.8); −0.00085 (0.7) X-038: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 12.2660 (1.2); 8.6440 (3.8); 8.6371 (3.9); 8.3522 (2.2); 8.3482 (3.8); 8.3445 (2.1); 7.7825 (1.2); 7.7781 (1.4); 7.7757 (1.4); 7.7713 (1.2); 7.7589 (1.3); 7.7546 (1.5); 7.7521 (1.3); 7.7477 (1.2); 7.6008 (0.8); 7.5966 (1.0); 7.5814 (1.8); 7.5772 (1.9); 7.5620 (1.0); 7.5578 (1.1); 7.4926 (0.5); 7.4864 (1.0); 7.4819 (0.9); 7.4736 (0.9); 7.4692 (1.0); 7.4614 (0.7); 7.4531 (0.7); 7.4488 (0.6); 7.3375 (1.4); 7.3210 (1.8); 7.3182 (2.1); 7.2976 (1.7); 7.2941 (1.2); 7.2760 (1.1); 7.2711 (1.5); 7.2677 (1.2); 7.2499 (1.0); 7.2469 (0.9); 5.0659 (2.2); 5.0294 (2.1); 4.1833 (0.6); 4.1525 (0.6); 4.0560 (1.3); 4.0381 (3.6); 4.0203 (3.6); 4.0026 (1.2); 3.7430 (0.6); 3.7089 (0.6); 3.3229 (20.1); 3.1042 (0.7); 2.7813 (0.7); 2.5413 (1.2); 2.5333 (0.8); 2.5244 (1.4); 2.5197 (2.0); 2.5110 (19.1); 2.5065 (39.7); 2.5020 (53.3); 2.4975 (38.3); 2.4930 (18.3); 1.9888 (16.0); 1.8447 (1.2); 1.8135 (1.4); 1.7593 (0.6); 1.5640 (0.5); 1.4032 (0.5); 1.3557 (2.8); 1.1922 (4.4); 1.1744 (8.9); 1.1567 (4.3); 0.0079 (0.9); −0.0002 (24.3); −0.00085 (1.0) VII-078: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0816 (1.9); 8.0753 (2.0); 7.7922 (0.8); 7.7859 (0.7); 7.7712 (1.0); 7.7652 (1.0); 7.7524 (0.8); 7.7461 (0.8); 7.4162 (0.8); 7.4119 (1.0); 7.3971 (1.3); 7.3928 (1.7); 7.3842 (0.6); 7.3787 (1.1); 7.3739 (1.2); 7.3673 (0.6); 7.3652 (0.9); 7.3635 (0.8); 7.3608 (0.7); 7.3590 (0.7); 7.3529 (0.9); 7.3484 (0.7); 7.3466 (0.7); 7.3446 (0.8); 7.3400 (0.6); 7.3322 (0.8); 7.3278 (0.6); 7.2606 (36.6); 7.2227 (1.0); 7.2209 (1.0); 7.2015 (1.6); 7.1841 (0.7); 7.1825 (0.7); 7.0527 (1.0); 7.0494 (1.0); 7.0318 (1.0); 7.0281 (1.8); 7.0245 (1.1); 7.0069 (0.9); 7.0037 (0.9); 6.9340 (1.3); 6.9326 (1.5); 6.9266 (1.4); 6.9252 (1.4); 6.9129 (1.3); 6.9114 (1.4); 6.9054 (1.4); 6.9040 (1.4); 6.8476 (1.8); 6.7123 (4.0); 6.5770 (2.0); 4.8949 (15.5); 4.2954 (1.9); 4.2776 (6.1); 4.2598 (6.2); 4.2420 (2.0); 2.9832 (2.0); 2.9067 (1.6); 2.9053 (1.7); 1.4050 (0.9); 1.3097 (7.8); 1.2919 (16.0); 1.2846 (0.5); 1.2740 (7.7); 1.2540 (0.7); 0.0080 (1.4); −0.0002 (54.5); −0.00085 (1.8) VII-032: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.6099 (0.9); 8.6057 (1.0); 8.5977 (1.0); 8.5935 (1.0); 8.5389 (1.0); 8.5369 (1.1); 8.5333 (1.1); 8.5312 (1.1); 7.6141 (0.6); 7.6097 (0.8); 7.6085 (0.7); 7.6042 (0.7); 7.5943 (0.8); 7.5899 (0.9); 7.5887 (0.9); 7.5844 (0.8); 7.3205 (0.8); 7.3184 (0.8); 7.3083 (0.9); 7.3063 (1.0); 7.3009 (1.2); 7.2986 (0.8); 7.2884 (0.9); 7.2863 (1.8); 7.2848 (2.0); 7.2811 (0.7); 7.2784 (0.8); 7.2702 (0.8); 7.2663 (2.3); 7.2646 (1.6); 7.2617 (6.3); 7.2574 (1.5); 7.2534 (0.9); 7.2414 (0.7); 7.2397 (0.7); 7.1293 (1.6); 7.1252 (2.0); 7.1196 (0.5); 7.1129 (0.9); 7.1102 (0.6); 7.1083 (1.7); 7.1050 (1.4); 5.2992 (4.5); 5.2760 (1.5); 5.2586 (1.5); 3.7932 (16.0); 1.7067 (6.3); 1.6893 (6.2); −0.0002 (8.6) VII-041: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.6098 (0.9); 8.6057 (0.9); 8.5976 (0.9); 8.5935 (0.9); 8.5385 (1.0); 8.5368 (1.1); 8.5331 (1.1); 8.5312 (1.1); 7.6141 (0.6); 7.6097 (0.8); 7.6087 (0.8); 7.6043 (0.6); 7.5943 (0.8); 7.5899 (0.9); 7.5889 (0.9); 7.5845 (0.7); 7.3208 (0.7); 7.3186 (0.8); 7.3085 (0.9); 7.3066 (1.1); 7.3011 (1.2); 7.2988 (0.8); 7.2864 (1.8); 7.2850 (2.0); 7.2812 (0.8); 7.2786 (0.8); 7.2703 (0.8); 7.2664 (2.3); 7.2648 (1.7); 7.2614 (7.3); 7.2576 (1.6); 7.2536 (0.9); 7.2415 (0.8); 7.2400 (0.8); 7.1292 (1.6); 7.1250 (2.1); 7.1195 (0.5); 7.1128 (0.9); 7.1082 (1.7); 7.1049 (1.4); 5.2994 (1.3); 5.2759 (1.5); 5.2585 (1.5); 3.7934 (16.0); 3.7314 (0.6); 1.7067 (6.4); 1.6893 (6.3); −0.0002 (9.8) VII-043: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 8.6229 (2.5); 8.6188 (2.7); 8.6108 (2.7); 8.6067 (2.7); 8.4928 (2.7); 8.4907 (3.0); 8.4872 (3.0); 8.4851 (2.9); 7.7553 (1.6); 7.7511 (1.9); 7.7498 (1.8); 7.7455 (1.6); 7.7355 (1.9); 7.7313 (2.0); 7.7299 (2.3); 7.7257 (1.8); 7.4963 (1.9); 7.4942 (1.9); 7.4842 (1.8); 7.4820 (1.9); 7.4765 (1.7); 7.4744 (1.7); 7.4644 (1.7); 7.4622 (1.8); 7.3988 (0.9); 7.3946 (1.6); 7.3901 (0.8); 7.3847 (0.5); 7.3821 (0.7); 7.3773 (4.6); 7.3737 (1.8); 7.3724 (2.0); 7.3624 (1.8); 7.3587 (4.8); 7.3569 (3.2); 7.3516 (0.7); 7.3455 (1.4); 7.3417 (3.0); 7.3381 (1.8); 7.3303 (0.8); 7.3242 (2.5); 7.3057 (0.8); 7.1986 (1.8); 7.1966 (3.8); 7.1928 (6.0); 7.1873 (1.2); 7.1797 (2.1); 7.1777 (1.6); 7.1755 (4.0); 7.1723 (3.4); 5.1165 (0.7); 5.0992 (3.8); 5.0818 (3.9); 5.0644 (0.8); 4.0556 (1.1); 4.0378 (3.3); 4.0201 (3.4); 4.0023 (1.1); 3.4052 (1.0); 2.5241 (1.0); 2.5195 (1.2); 2.5107 (16.2); 2.5061 (35.9); 2.5015 (50.5); 2.4969 (34.8); 2.4923 (15.4); 2.1828 (0.8); 1.9886 (16.0); 1.9089 (2.4); 1.5820 (10.2); 1.5645 (10.1); 1.3555 (7.0); 1.1921 (4.9); 1.1810 (0.5); 1.1743 (9.8); 1.1565 (4.6); 0.0024 (0.5); −0.0002 (17.3) VII-042: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 8.6217 (2.8); 8.6176 (3.0); 8.6097 (3.0); 8.6055 (3.0); 8.4913 (3.0); 8.4892 (3.2); 8.4857 (3.3); 8.4835 (3.1); 7.7530 (1.6); 7.7487 (2.1); 7.7474 (1.8); 7.7431 (1.7); 7.7332 (2.1); 7.7289 (2.2); 7.7276 (2.3); 7.7233 (2.0); 7.4941 (2.0); 7.4920 (2.0); 7.4820 (2.0); 7.4798 (1.9); 7.4744 (1.8); 7.4722 (1.8); 7.4622 (1.8); 7.4600 (1.8); 7.3987 (1.0); 7.3945 (1.7); 7.3899 (0.8); 7.3844 (0.5); 7.3820 (0.8); 7.3773 (4.8); 7.3734 (1.9); 7.3722 (2.0); 7.3623 (1.9); 7.3585 (5.0); 7.3568 (3.2); 7.3514 (0.7); 7.3453 (1.4); 7.3415 (3.1); 7.3379 (1.8); 7.3301 (0.9); 7.3240 (2.6); 7.3158 (0.5); 7.3088 (0.5); 7.3055 (0.8); 7.1983 (2.0); 7.1964 (4.0); 7.1926 (6.4); 7.1871 (1.3); 7.1795 (2.3); 7.1773 (1.6); 7.1753 (4.4); 7.1722 (3.4); 5.1164 (0.8); 5.0991 (4.1); 5.0816 (4.2); 5.0643 (0.8); 4.0556 (1.1); 4.0378 (3.4); 4.0201 (3.4); 4.0023 (1.1); 3.3876 (0.9); 2.6736 (1.4); 2.5240 (0.7); 2.5194 (1.0); 2.5106 (16.8); 2.5061 (37.1); 2.5015 (52.2); 2.4969 (35.8); 2.4923 (15.8); 2.1829 (0.6); 1.9885 (16.0); 1.9088 (1.5); 1.5819 (10.8); 1.5645 (10.8); 1.3556 (5.6); 1.1920 (4.7); 1.1743 (9.9); 1.1565 (4.8); −0.0002 (16.9); −0.00020 (0.8); −0.00029 (0.6) VII-138: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4477 (0.8); 8.4418 (0.9); 8.2940 (1.0); 7.4578 (0.5); 7.4428 (0.8); 7.4385 (1.0); 7.4301 (0.7); 7.4236 (1.2); 7.4192 (1.1); 7.4078 (0.6); 7.4035 (0.7); 7.4010 (0.7); 7.3966 (0.6); 7.2606 (27.6); 7.2424 (0.6); 7.2405 (0.6); 7.2210 (0.9); 7.0549 (0.6); 7.0517 (0.6); 7.0342 (0.6); 7.0303 (1.0); 7.0265 (0.7); 7.0091 (0.5); 7.0057 (0.5); 5.3002 (4.7); 4.9074 (8.5); 4.4992 (2.0); 4.4834 (4.3); 4.4675 (2.1); 3.6713 (16.0); 2.7003 (2.0); 2.6844 (4.2); 2.6685 (2.0); 1.5439 (4.2); 0.0080 (1.2); −0.0002 (40.4); −0.00085 (1.4) VII-138: .sup.1H-NMR(400.0 MHz, CDCl3_5 mm): δ = 8.4477 (1.6); 8.4408 (1.6); 8.2975 (1.0); 8.2939 (1.7); 8.2903 (1.0); 7.4625 (0.5); 7.4582 (0.6); 7.4432 (0.9); 7.4389 (1.0); 7.4304 (0.8); 7.4259 (1.0); 7.4237 (1.3); 7.4193 (1.2); 7.4081 (0.8); 7.4037 (0.8); 7.4012 (0.8); 7.3968 (0.7); 7.3624 (0.5); 7.3502 (0.5); 7.2625 (6.5); 7.2441 (0.6); 7.2425 (0.6); 7.2408 (0.7); 7.2211 (0.9); 7.0550 (0.6); 7.0518 (0.6); 7.0342 (0.6); 7.0304 (1.0); 7.0266 (0.7); 7.0090 (0.5); 7.0058 (0.5); 4.9074 (8.3); 4.4991 (2.0); 4.4832 (4.2); 4.4673 (2.1); 3.6774 (0.7); 3.6710 (16.0); 2.7004 (2.0); 2.6845 (4.1); 2.6686 (1.9); 1.5788 (2.3); 1.2610 (1.2); 1.2596 (1.1); 1.2434 (0.6); 0.8987 (0.6); 0.8818 (1.8); 0.8640 (0.7); −0.0002 (8.5) VII-085: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1199 (1.2); 8.1178 (1.0); 8.1138 (1.2); 7.6788 (0.6); 7.6726 (0.6); 7.6597 (0.7); 7.6577 (0.7); 7.6535 (0.7); 7.6515 (0.7); 7.6387 (0.6); 7.6325 (0.6); 7.3886 (0.5); 7.3737 (0.9); 7.3693 (1.0); 7.3548 (0.6); 7.3504 (0.6); 7.2613 (41.2); 7.1898 (0.6); 7.1884 (0.6); 7.1864 (0.6); 7.1697 (0.9); 7.1669 (0.9); 7.0190 (0.6); 7.0156 (0.6); 6.9978 (0.7); 6.9942 (0.9); 6.9903 (0.6); 6.9729 (0.5); 6.9696 (0.5); 6.8974 (0.8); 6.8960 (0.8); 6.8899 (0.9); 6.8885 (0.8); 6.8763 (0.8); 6.8748 (0.8); 6.8688 (0.8); 6.8674 (0.7); 5.3002 (0.9); 4.8528 (8.4); 4.4836 (2.0); 4.4677 (4.3); 4.4518 (2.1); 3.6799 (16.0); 2.6972 (2.0); 2.6813 (4.2); 2.6654 (2.0); 1.5575 (1.4); 1.5519 (1.9); 1.5443 (0.6); 1.5412 (0.6); 1.5395 (0.6); 0.7726 (0.6); 0.7684 (2.3); 0.7659 (2.2); 0.7638 (2.3); 0.7618 (2.3); 0.7570 (0.8); 0.7479 (9.9); 0.0080 (0.7); −0.0002 (24.7); −0.00042 (0.6); −0.00050 (0.5); −0.00084 (0.7) VII-075-a: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0973 (0.7); 8.0956 (1.0); 8.0935 (0.8); 8.0913 (0.8); 8.0893 (1.1); 7.7539 (0.6); 7.7477 (0.6); 7.7352 (0.6); 7.7327 (0.7); 7.7289 (0.6); 7.7264 (0.7); 7.7140 (0.6); 7.7077 (0.6); 7.3806 (0.7); 7.3762 (0.9); 7.3618 (0.7); 7.3574 (0.6); 7.2627 (9.5); 7.2200 (0.5); 7.2182 (0.6); 7.2169 (0.5); 7.2007 (0.8); 7.1987 (0.8); 7.0490 (0.5); 7.0457 (0.5); 7.0282 (0.5); 7.0242 (0.8); 7.0205 (0.6); 6.9427 (0.7); 6.9411 (0.7); 6.9352 (0.8); 6.9337 (0.7); 6.9214 (0.7); 6.9199 (0.7); 6.9139 (0.7); 6.9124 (0.7); 5.2998 (0.9); 5.2354 (1.5); 5.2180 (1.5); 3.7781 (16.0); 1.6967 (6.3); 1.6793 (6.3); −0.0002 (5.8) VII-082: .sup.1H-NMR(400.6 MHz, d.sub.6-DMSO): δ = 13.0133 (1.7); 8.1985 (4.2); 8.1922 (4.4); 7.9606 (1.8); 7.9543 (1.7); 7.9412 (2.3); 7.9394 (2.4); 7.9349 (2.3); 7.9331 (2.3); 7.9200 (1.9); 7.9137 (1.9); 7.5830 (1.3); 7.5788 (1.7); 7.5638 (3.0); 7.5593 (3.5); 7.5442 (1.8); 7.5399 (2.0); 7.5203 (0.9); 7.5159 (0.9); 7.5076 (1.0); 7.5013 (1.6); 7.4964 (1.5); 7.4886 (1.6); 7.4842 (1.5); 7.4809 (1.6); 7.4763 (1.2); 7.4681 (1.2); 7.4636 (1.0); 7.3460 (1.8); 7.3432 (2.4); 7.3271 (3.0); 7.3237 (4.3); 7.3178 (2.5); 7.3153 (1.7); 7.3082 (1.6); 7.3021 (3.2); 7.3007 (3.2); 7.2938 (4.6); 7.2888 (2.2); 7.2807 (2.7); 7.2793 (2.8); 7.2736 (3.0); 7.2721 (3.6); 7.2681 (1.7); 5.0736 (1.2); 5.0562 (5.8); 5.0388 (5.9); 5.0215 (1.2); 3.6220 (0.8); 3.6181 (4.5); 3.6159 (2.7); 3.6118 (2.6); 3.6095 (2.1); 3.6078 (3.5); 3.6015 (10.7); 3.5993 (4.1); 3.5953 (3.6); 3.5933 (2.0); 3.5912 (2.5); 3.5870 (2.6); 3.5849 (4.8); 3.5810 (0.9); 3.3247 (4.4); 2.5252 (1.1); 2.5205 (1.4); 2.5118 (20.2); 2.5072 (45.1); 2.5026 (63.6); 2.4980 (44.6); 2.4935 (20.1); 1.7807 (0.8); 1.7760 (4.7); 1.7684 (4.0); 1.7642 (2.4); 1.7594 (13.5); 1.7548 (2.6); 1.7505 (3.8); 1.7429 (4.5); 1.7384 (0.8); 1.5749 (16.0); 1.5575 (15.9); 1.3564 (3.9); 0.0080 (1.9); 0.0065 (0.5); 0.0056 (0.5); 0.0047 (0.7); −0.0002 (69.2); −0.00066 (0.8); −0.0085 (2.0) VII-081: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1083 (1.2); 8.1062 (0.9); 8.1040 (1.0); 8.1021 (1.2); 7.7632 (0.6); 7.7569 (0.6); 7.7444 (0.7); 7.7419 (0.7); 7.7382 (0.7); 7.7357 (0.7); 7.7232 (0.6); 7.7170 (0.6); 7.4368 (0.5); 7.4218 (0.9); 7.4175 (1.0); 7.4029 (0.6); 7.3985 (0.6); 7.2617 (8.7); 7.2300 (0.6); 7.2284 (0.6); 7.2267 (0.6); 7.2071 (0.9); 7.0452 (0.6); 7.0420 (0.6); 7.0244 (0.6); 7.0206 (1.0); 7.0168 (0.6); 6.9992 (0.6); 6.9960 (0.5); 6.9418 (0.9); 6.9403 (0.8); 6.9343 (0.9); 6.9328 (0.8); 6.9205 (0.8); 6.9190 (0.8); 6.9130 (0.8); 6.9115 (0.8); 5.3001 (3.5); 5.1971 (1.7); 5.1797 (1.7); 4.4921 (0.6); 4.4802 (0.8); 4.4643 (1.4); 4.4477 (1.1); 4.4304 (1.5); 4.4148 (0.9); 4.4026 (0.6); 3.6368 (16.0); 2.6741 (1.1); 2.6710 (1.0); 2.6579 (1.8); 2.6552 (2.2); 2.6421 (1.0); 2.6394 (1.0); 1.6815 (6.3); 1.6641 (6.2); 1.5561 (2.8); −0.0002 (11.5) VII-075: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1151 (1.1); 8.1130 (0.9); 8.1108 (0.9); 8.1088 (1.2); 7.7693 (0.6); 7.7631 (0.6); 7.7506 (0.7); 7.7481 (0.7); 7.7443 (0.7); 7.7419 (0.7); 7.7294 (0.6); 7.7232 (0.6); 7.4309 (0.5); 7.4160 (0.8); 7.4117 (0.9); 7.3971 (0.6); 7.3928 (0.6); 7.2618 (8.3); 7.2229 (0.5); 7.2213 (0.6); 7.2195 (0.6); 7.1999 (0.9); 7.0371 (0.6); 7.0338 (0.6); 7.0163 (0.6); 7.0124 (0.9); 7.0086 (0.6); 6.9911 (0.5); 6.9369 (0.8); 6.9354 (0.8); 6.9295 (0.8); 6.9279 (0.8); 6.9158 (0.8); 6.9142 (0.8); 6.9083 (0.8); 6.9067 (0.8); 5.3002 (4.7); 5.1939 (1.7); 5.1765 (1.7); 4.4915 (0.6); 4.4795 (0.8); 4.4637 (1.4); 4.4471 (0.8); 4.4429 (0.8); 4.4270 (1.4); 4.4H6 (0.8); 4.3992 (0.6); 3.6371 (16.0); 2.6731 (1.0); 2.6698 (1.0); 2.6571 (1.6); 2.6539 (2.0); 2.6411 (1.0); 2.6382 (1.0); 1.6800 (6.2); 1.6626 (6.1); 1.5586 (2.5); −0.0002 (11.2) X-021: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1263 (1.3); 8.1242 (1.0); 8.1219 (1.1); 8.1201 (1.3); 7.7644 (0.6); 7.7581 (0.6); 7.7456 (0.8); 7.7431 (0.8); 7.7394 (0.8); 7.7369 (0.7); 7.7245 (0.7); 7.7182 (0.6); 7.4636 (0.5); 7.4593 (0.6); 7.4443 (0.9); 7.4400 (1.0); 7.4255 (0.6); 7.4211 (0.7); 7.3664 (0.5); 7.3541 (0.5); 7.3497 (0.5); 7.2620 (9.4); 7.2470 (0.6); 7.2454 (0.7); 7.2436 (0.7); 7.2242 (1.0); 7.0547 (0.7); 7.0515 (0.6); 7.0338 (0.6); 7.0301 (1.1); 7.0264 (0.7); 7.0087 (0.6); 7.0056 (0.6); 6.9522 (1.0); 6.9507 (0.9); 6.9447 (1.0); 6.9432 (0.9); 6.9309 (0.9); 6.9294 (0.8); 6.9234 (0.9); 6.9219 (0.8); 5.3168 (1.5); 5.3001 (8.7); 4.1408 (1.8); 4.1280 (3.1); 4.1152 (1.7); 3.7810 (16.0); 1.7135 (6.9); 1.6965 (6.8); 1.5695 (2.8); −0.0002 (12.4) VII-134: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4406 (1.8); 8.4338 (1.8); 8.2957 (1.0); 8.2921 (1.8); 8.2884 (1.0); 7.4430 (0.5); 7.4271 (1.4); 7.4228 (1.4); 7.4201 (0.9); 7.4156 (0.7); 7.4092 (0.6); 7.4047 (1.3); 7.4002 (0.8); 7.3977 (0.7); 7.3934 (0.7); 7.2618 (7.9); 7.2321 (0.6); 7.2304 (0.6); 7.2286 (0.6); 7.2116 (0.9); 7.2092 (0.9); 7.0439 (0.6); 7.0407 (0.6); 7.0231 (0.6); 7.0192 (1.0); 7.0155 (0.6); 6.9980 (0.6); 6.9947 (0.5); 5.3000 (1.3); 5.1964 (1.7); 5.1789 (1.7); 4.4923 (0.6); 4.4803 (0.8); 4.4645 (1.4); 4.4479 (0.9); 4.4447 (0.8); 4.4289 (1.4); 4.4134 (0.8); 4.4011 (0.6); 3.6390 (16.0); 2.6733 (1.1); 2.6700 (1.0); 2.6575 (1.7); 2.6541 (2.1); 2.6414 (1.0); 2.6383 (1.0); 1.6829 (6.3); 1.6655 (6.2); 1.5723 (0.9); 1.4321 (0.5); −0.0002 (11.0); −0.00028 (0.5) VII-023: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1731 (0.7); 8.1711 (1.1); 8.1690 (0.9); 8.1670 (0.9); 8.1649 (1.1); 8.1629 (0.8); 7.6936 (0.6); 7.6873 (0.6); 7.6748 (0.7); 7.6723 (0.8); 7.6686 (0.7); 7.6661 (0.8); 7.6536 (0.7); 7.6473 (0.7); 7.3239 (0.5); 7.3223 (0.6); 7.3076 (1.3); 7.3061 (2.0); 7.3024 (0.9); 7.2997 (0.9); 7.2915 (1.0); 7.2876 (2.4); 7.2858 (1.7); 7.2830 (1.0); 7.2787 (1.7); 7.2747 (1.0); 7.2684 (0.5); 7.2610 (12.3); 7.1262 (1.7); 7.1221 (2.1); 7.1165 (0.7); 7.1098 (1.0); 7.1072 (0.8); 7.1053 (1.9); 7.1019 (1.6); 6.9554 (0.8); 6.9537 (0.8); 6.9478 (0.8); 6.9461 (0.8); 6.9341 (0.8); 6.9325 (0.8); 6.9265 (0.8); 6.9249 (0.8); 5.2975 (1.8); 5.2679 (1.5); 5.2504 (1.6); 3.7882 (16.0); 1.7023 (6.4); 1.6848 (6.4); 1.5639 (2.3); −0.0002 (4.5) VII-017: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.3176 (1.5); 8.3162 (1.8); 8.3116 (1.6); 8.3101 (1.8); 7.5533 (1.3); 7.5471 (1.3); 7.5325 (1.6); 7.5263 (1.6); 7.3364 (2.6); 7.3325 (0.8); 7.3311 (0.9); 7.3265 (0.5); 7.3151 (3.8); 7.3111 (1.2); 7.3084 (1.1); 7.2998 (1.1); 7.2960 (2.5); 7.2949 (2.5); 7.2915 (1.1); 7.2871 (1.8); 7.2832 (1.1); 7.2697 (1.1); 7.2606 (13.0); 7.2517 (0.5); 7.1279 (1.9); 7.1237 (2.5); 7.1183 (0.8); 7.1114 (1.0); 7.1068 (2.0); 7.1036 (1.8); 5.2979 (1.0); 5.2637 (1.7); 5.2463 (1.7); 5.2289 (0.5); 3.7853 (16.0); 1.6997 (6.9); 1.6823 (6.8); −0.0002 (7.4) VIII-007: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.2079 (1.5); 8.1949 (1.6); 7.3302 (1.6); 7.3263 (0.9); 7.3238 (0.5); 7.3197 (1.4); 7.3172 (1.4); 7.3135 (2.9); 7.3120 (3.1); 7.3091 (1.5); 7.3036 (0.5); 7.3010 (0.7); 7.2969 (0.5); 7.2610 (9.6); 7.1389 (2.1); 7.1332 (1.5); 7.1283 (0.7); 7.1251 (0.7); 7.1220 (0.7); 7.1184 (1.7); 7.1145 (1.6); 7.0478 (0.7); 7.0439 (1.1); 7.0400 (0.8); 7.0348 (0.7); 7.0309 (1.1); 7.0270 (0.7); 6.8890 (1.1); 6.8858 (1.7); 6.8826 (1.1); 6.8812 (0.9); 5.2975 (3.0); 5.2621 (1.6); 5.2446 (1.6); 3.7850 (16.0); 1.7016 (6.6); 1.6842 (6.6); 1.5649 (1.6); −0.0002 (4.8) VIII-001: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.3653 (1.7); 8.3637 (1.6); 8.3524 (1.7); 8.3508 (1.7); 7.3498 (0.5); 7.3368 (1.7); 7.3357 (1.7); 7.3317 (1.0); 7.3258 (0.9); 7.3225 (1.6); 7.3175 (3.9); 7.3134 (1.4); 7.3110 (0.7); 7.3046 (0.8); 7.3008 (0.7); 7.2976 (1.8); 7.2958 (2.0); 7.2940 (2.1); 7.2922 (1.7); 7.2622 (6.9); 7.1393 (0.5); 7.1357 (2.0); 7.1304 (1.7); 7.1252 (0.7); 7.1214 (0.8); 7.1199 (0.7); 7.1151 (1.8); 7.1113 (1.6); 7.0553 (1.6); 7.0516 (1.6); 7.0424 (1.6); 7.0387 (1.5); 5.2970 (3.2); 5.2587 (1.6); 5.2413 (1.6); 3.7830 (16.0); 1.6999 (6.6); 1.6825 (6.6); 1.5876 (0.5); −0.0002 (2.7) VII-032: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.6079 (1.2); 8.6038 (1.2); 8.5958 (1.2); 8.5916 (1.2); 8.5382 (1.3); 8.5362 (1.4); 8.5327 (1.5); 8.5306 (1.3); 7.6123 (0.7); 7.6079 (0.9); 7.6069 (0.8); 7.6025 (0.7); 7.5925 (0.8); 7.5880 (1.0); 7.5870 (1.0); 7.5826 (0.8); 7.3174 (0.9); 7.3152 (0.9); 7.3051 (1.2); 7.3029 (1.0); 7.3008 (0.7); 7.2991 (0.8); 7.2976 (1.0); 7.2953 (1.1); 7.2849 (2.0); 7.2831 (2.8); 7.2794 (1.0); 7.2767 (0.9); 7.2684 (1.1); 7.2644 (3.1); 7.2608 (13.2); 7.2557 (1.9); 7.2517 (1.0); 7.2396 (0.8); 7.2381 (0.8); 7.1293 (1.8); 7.1252 (2.3); 7.1196 (0.6); 7.1128 (1.0); 7.1082 (1.9); 7.1050 (1.5); 5.2970 (2.9); 5.2939 (0.6); 5.2763 (1.6); 5.2588 (1.6); 3.7915 (16.0); 1.7054 (6.5); 1.6879 (6.4); −0.0002 (6.3) VI-010: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1887 (3.7); 8.6543 (8.7); 7.3569 (0.7); 7.3505 (1.1); 7.3349 (2.6); 7.3164 (3.5); 7.3123 (2.4); 7.3082 (1.7); 7.3031 (0.8); 7.2970 (1.3); 7.2948 (1.2); 7.2771 (1.0); 7.2597 (32.9); 7.1384 (2.2); 7.1339 (2.4); 7.1286 (0.9); 7.1222 (1.2); 7.1177 (2.1); 7.1143 (1.8); 5.2977 (1.6); 5.2894 (0.6); 5.2720 (1.7); 5.2546 (1.7); 5.2372 (0.5); 3.7898 (16.0); 3.7515 (1.0); 1.7082 (7.0); 1.6908 (7.0); 1.5456 (2.2); −0.0002 (18.3); −0.00083 (0.9) VI-009: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.5224 (10.9); 7.3819 (0.6); 7.3663 (2.1); 7.3624 (1.0); 7.3592 (0.8); 7.3519 (1.2); 7.3477 (3.1); 7.3428 (1.8); 7.3388 (1.1); 7.3275 (0.8); 7.3252 (0.7); 7.2601 (25.0); 7.1418 (1.8); 7.1374 (2.1); 7.1320 (0.7); 7.1258 (1.0); 7.1210 (1.9); 7.1176 (1.7); 5.2981 (1.2); 5.2612 (1.6); 5.2438 (1.6); 3.7834 (16.0); 1.7031 (6.6); 1.6857 (6.5); 1.5407 (4.8); −0.0002 (12.0) VII-014: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1775 (1.0); 8.1753 (0.8); 8.1732 (0.9); 8.1713 (1.1); 8.1694 (0.7); 7.7853 (0.7); 7.6991 (0.6); 7.6928 (0.6); 7.6803 (0.7); 7.6779 (0.7); 7.6741 (0.7); 7.6717 (0.7); 7.6591 (0.6); 7.6529 (0.6); 7.3156 (0.5); 7.2994 (1.9); 7.2956 (0.7); 7.2930 (0.8); 7.2848 (0.9); 7.2809 (2.3); 7.2794 (1.5); 7.2766 (0.8); 7.2724 (1.5); 7.2684 (0.9); 7.2617 (10.7); 7.2564 (0.9); 7.2548 (0.8); 7.1152 (1.6); 7.1111 (2.0); 7.1054 (0.6); 7.0988 (0.9); 7.0942 (1.8); 7.0909 (1.4); 6.9552 (0.8); 6.9537 (0.8); 6.9477 (0.8); 6.9462 (0.7); 6.9340 (0.8); 6.9325 (0.7); 6.9265 (0.8); 6.9249 (0.7); 5.2990 (2.6); 5.2636 (1.5); 5.2461 (1.5); 3.7879 (16.0); 3.7703 (1.9); 1.7020 (6.3); 1.6846 (6.6); 1.6681 (0.8); −0.0002 (6.5) VII-018: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1829 (1.3); 8.1767 (1.4); 7.7062 (0.7); 7.6999 (0.7); 7.6874 (0.8); 7.6850 (0.9); 7.6811 (0.8); 7.6788 (0.8); 7.6662 (0.7); 7.6600 (0.7); 7.3300 (0.7); 7.3139 (2.4); 7.3102 (1.0); 7.3073 (1.0); 7.2994 (1.2); 7.2954 (2.9); 7.2880 (2.0); 7.2841 (1.1); 7.2781 (0.5); 7.2723 (1.0); 7.2706 (1.0); 7.2614 (14.4); 7.1394 (2.0); 7.1351 (2.4); 7.1295 (0.8); 7.1231 (1.1); 7.1184 (2.0); 7.1151 (1.7); 6.9591 (1.0); 6.9578 (1.0); 6.9516 (1.0); 6.9503 (1.0); 6.9379 (0.9); 6.9365 (1.0); 6.9303 (0.9); 6.9290 (0.9); 4.9458 (9.2); 3.8215 (0.7); 3.8143 (16.0); −0.0002 (9.0) VII-008: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.6130 (1.1); 8.6088 (1.2); 8.6008 (1.2); 8.5966 (1.1); 8.5451 (1.3); 8.5431 (1.4); 8.5395 (1.4); 8.5376 (1.3); 7.6197 (0.7); 7.6153 (0.9); 7.6099 (0.7); 7.5999 (0.8); 7.5956 (1.0); 7.5946 (1.0); 7.5901 (0.8); 7.3198 (0.9); 7.3177 (0.9); 7.3076 (0.9); 7.3055 (0.9); 7.2999 (1.0); 7.2978 (1.2); 7.2933 (0.6); 7.2919 (0.7); 7.2877 (1.2); 7.2857 (1.0); 7.2758 (2.2); 7.2719 (0.9); 7.2692 (1.0); 7.2606 (9.4); 7.2572 (2.8); 7.2534 (1.0); 7.2490 (1.7); 7.2449 (1.0); 7.2329 (0.8); 7.2314 (0.8); 7.1178 (1.8); 7.1136 (2.3); 7.1080 (0.6); 7.1014 (1.0); 7.0968 (1.8); 7.0935 (1.6); 5.2722 (1.6); 5.2548 (1.6); 3.7911 (16.0); 1.7049 (6.7); 1.6874 (6.6); 1.2552 (0.6); −0.0002 (10.1) VI-013: .sup.1H-NMR(599.6 MHz, CDCl3): δ = 9.1912 (13.2); 8.6642 (27.2); 7.3393 (1.9); 7.3367 (2.9); 7.3335 (1.6); 7.3252 (8.5); 7.3226 (4.2); 7.3125 (8.2); 7.3077 (1.6); 7.3042 (2.9); 7.3020 (4.8); 7.2997 (3.0); 7.2943 (1.5); 7.2904 (4.2); 7.2848 (0.8); 7.2799 (0.9); 7.2779 (1.2); 7.2641 (9.0); 7.1239 (7.0); 7.1215 (9.6); 7.1180 (2.5); 7.1124 (4.5); 7.1097 (7.8); 7.1031 (0.6); 5.2774 (1.7); 5.2658 (5.6); 5.2542 (5.7); 5.2426 (1.7); 3.7889 (50.0); 3.4853 (3.5); 1.7045 (22.4); 1.6929 (22.2); 1.6444 (0.4); 1.6315 (0.5); 1.6182 (1.2); 1.3662 (0.5); 1.3537 (0.6); 1.3414 (0.4); 1.3103 (0.6); 1.2967 (0.6); 1.2887 (0.4); 1.2838 (0.7); 1.2769 (0.5); 1.2649 (0.5); 1.2557 (1.6); 0.9354 (1.0); 0.9231 (1.9); 0.9109 (0.9); 0.8796 (0.3); 0.0052 (0.3); −0.00001 (6.3) VII-020: .sup.1H-NMR(599.7 MHz, CDCl3): δ = 8.1762 (5.0); 8.1721 (4.9); 7.7835 (0.4); 7.6907 (1.8); 7.6866 (1.9); 7.6780 (2.5); 7.6767 (2.6); 7.6740 (2.5); 7.6726 (2.4); 7.6641 (1.9); 7.6599 (1.8); 7.3115 (1.8); 7.3092 (3.0); 7.3062 (1.4); 7.2976 (8.2); 7.2949 (4.0); 7.2871 (3.0); 7.2847 (7.0); 7.2803 (1.0); 7.2713 (2.3); 7.2692 (4.3); 7.2670 (2.8); 7.2604 (26.3); 7.2574 (5.0); 7.2524 (0.9); 7.2469 (0.8); 7.2449 (1.2); 7.1114 (6.0); 7.1090 (9.2); 7.1055 (2.1); 7.0971 (6.6); 7.0962 (6.6); 7.0906 (0.6); 6.9481 (3.0); 6.9436 (3.0); 6.9339 (2.9); 6.9294 (2.9); 5.2725 (1.6); 5.2609 (5.4); 5.2492 (5.4); 5.2376 (1.6); 3.7877 (50.0); 3.7702 (1.1); 1.6988 (21.5); 1.6871 (21.4); 1.6709 (0.5); 1.5508 (7.9); 1.2556 (0.8); 0.0697 (1.6); 0.0053 (0.9); −0.00001 (23.4); −0.0056 (0.8) VII-026: .sup.1H-NMR(599.7 MHz, CDCl3): δ = 8.1741 (12.4); 7.7835 (2.0); 7.6882 (3.6); 7.6751 (6.8); 7.6620 (3.6); 7.5061 (1.6); 7.4931 (2.0); 7.4100 (1.0); 7.3977 (1.8); 7.3851 (0.9); 7.3090 (5.3); 7.2970 (13.9); 7.2847 (11.3); 7.2601 (24.2); 7.2458 (2.2); 7.2304 (0.7); 7.2185 (1.0); 7.2061 (0.4); 7.1095 (15.5); 7.0971 (13.7); 6.9457 (6.6); 6.9316 (6.2); 5.2985 (0.4); 5.2723 (2.1); 5.2608 (6.2); 5.2494 (6.2); 5.2377 (2.1); 5.2097 (0.8); 5.1977 (0.8); 3.7876 (50.0); 3.7701 (6.4); 1.6987 (24.9); 1.6869 (25.7); 1.6709 (3.4); 1.5548 (9.4); 1.4271 (0.4); 1.2830 (0.6); 1.2565 (2.9); 0.8812 (0.5); 0.8414 (0.3); 0.0706 (0.8); −0.00001 (16.0) VII-107: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1085 (1.2); 8.1066 (0.9); 8.1044 (1.0); 8.1023 (1.2); 7.7792 (0.6); 7.7729 (0.6); 7.7605 (0.7); 7.7580 (0.7); 7.7543 (0.7); 7.7518 (0.7); 7.7393 (0.6); 7.7331 (0.6); 7.2617 (6.7); 7.1488 (0.7); 7.1422 (0.5); 7.0336 (0.5); 7.0247 (0.6); 7.0152 (0.5); 6.9966 (0.6); 6.9847 (0.6); 6.9723 (1.1); 6.9706 (1.0); 6.9626 (1.5); 6.9507 (1.1); 6.9432 (0.8); 6.9417 (0.9); 5.2145 (1.5); 5.1971 (1.6); 3.7871 (16.0); 1.6992 (6.4); 1.6818 (6.4); 1.5554 (2.8); 1.2643 (0.6); 1.2596 (0.6); 0.8818 (1.1); −0.0002 (8.7) VII-089: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1168 (1.2); 8.1146 (0.9); 8.1124 (1.0); 8.1105 (1.2); 7.7892 (0.6); 7.7829 (0.6); 7.7705 (0.7); 7.7680 (0.8); 7.7642 (0.7); 7.7617 (0.7); 7.7494 (0.7); 7.7431 (0.6); 7.2615 (9.2); 7.2016 (0.5); 7.1950 (0.5); 7.1878 (0.7); 7.1815 (0.5); 7.1671 (0.5); 7.0477 (0.5); 7.0464 (0.5); 7.0377 (0.6); 7.0295 (0.5); 7.0063 (0.6); 6.9944 (0.7); 6.9835 (1.0); 6.9788 (1.0); 6.9773 (0.9); 6.9714 (1.8); 6.9576 (0.9); 6.9561 (0.9); 6.9499 (1.0); 6.9486 (1.1); 4.9174 (8.5); 3.8160 (16.0); 2.0454 (0.9); 1.5529 (5.0); 1.2596 (0.8); 0.8819 (1.0); −0.0002 (12.0) VII-062: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 12.9997 (1.4); 12.9934 (1.5); 12.7492 (0.6); 12.7429 (0.5); 12.7281 (0.8); 12.7219 (0.8); 12.7086 (0.6); 12.7023 (0.6); 12.2687 (0.7); 12.1477 (0.5); 12.1411 (1.1); 12.1363 (0.6); 12.1292 (1.4); 12.1251 (1.1); 12.1201 (0.9); 12.1081 (0.8); 12.0723 (0.9); 12.0660 (0.9); 12.0509 (0.9); 12.0448 (0.8); 9.9323 (1.7); 9.9150 (1.8); 8.4482 (15.2); 8.0735 (10.4); 7.2662 (8.0); 7.2617 (17.9); 7.2571 (25.1); 7.2525 (17.9); 7.2479 (8.1); 6.3407 (5.6); 6.3234 (5.6); 6.0021 (0.6); 5.6129 (1.1); 4.7547 (16.0) VII-063: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1212 (1.2); 8.1192 (0.9); 8.1166 (1.0); 8.1148 (1.3); 7.8944 (0.6); 7.8880 (0.6); 7.8762 (0.7); 7.8730 (0.8); 7.8698 (0.7); 7.8666 (0.7); 7.8550 (0.7); 7.8485 (0.6); 7.2636 (7.5); 7.2552 (0.6); 7.2414 (0.6); 7.2359 (0.5); 7.2217 (0.5); 7.1344 (0.6); 7.0801 (0.6); 7.0685 (0.6); 7.0573 (0.9); 7.0492 (0.9); 7.0477 (1.1); 7.0459 (1.1); 7.0418 (0.9); 7.0404 (0.9); 7.0280 (0.8); 7.0266 (0.8); 7.0206 (0.9); 7.0191 (0.8); 4.9218 (8.2); 3.8192 (16.0); 2.0451 (1.5); 1.5738 (1.7); 1.2775 (0.5); 1.2597 (1.1); 0.8820 (0.8); −0.0002 (5.6) VII-099: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1100 (1.2); 8.1037 (1.2); 7.8855 (0.6); 7.8791 (0.6); 7.8673 (0.7); 7.8641 (0.7); 7.8609 (0.7); 7.8577 (0.7); 7.8460 (0.6); 7.8396 (0.6); 7.2615 (28.8); 7.2149 (0.6); 7.2012 (0.7); 7.1955 (0.6); 7.1813 (0.5); 7.1317 (0.6); 7.1227 (0.6); 7.1134 (0.5); 7.0713 (0.6); 7.0598 (0.6); 7.0484 (1.0); 7.0413 (0.9); 7.0364 (1.3); 7.0200 (0.8); 7.0135 (1.1); 5.2059 (1.6); 5.1884 (1.6); 3.7869 (16.0); 1.7019 (6.4); 1.6844 (6.4); 1.5523 (6.0); 0.8819 (0.5); 0.0079 (0.5); −0.0002 (17.6); −0.00085 (0.5) VII-132: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.4735 (1.7); 8.4666 (1.7); 8.2823 (1.0); 8.2786 (1.7); 8.2751 (1.0); 7.4408 (0.6); 7.4363 (0.7); 7.4339 (0.7); 7.4295 (0.6); 7.4186 (0.7); 7.4142 (0.7); 7.4118 (0.7); 7.4073 (0.6); 7.2609 (22.8); 7.1601 (0.8); 7.1535 (0.5); 7.0410 (0.5); 7.0320 (0.6); 7.0025 (0.6); 6.9905 (0.6); 6.9795 (0.9); 6.9677 (0.9); 5.2169 (1.6); 5.1995 (1.6); 3.7885 (16.0); 1.7019 (6.3); 1.6845 (6.3); 1.5757 (0.5); 1.2650 (0.5); 0.8822 (0.9); −0.0002 (12.9) VII-147: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.5489 (1.4); 8.5422 (1.4); 8.2971 (1.5); 7.4966 (0.7); 7.4920 (0.8); 7.4899 (0.8); 7.4852 (0.6); 7.4755 (0.7); 7.4708 (0.8); 7.4688 (0.7); 7.4641 (0.6); 7.2615 (7.8); 7.2237 (0.6); 7.2100 (0.7); 7.2043 (0.6); 7.1902 (0.5); 7.1382 (0.5); 7.1292 (0.6); 7.0751 (0.6); 7.0635 (0.6); 7.0523 (0.9); 7.0407 (0.9); 5.2109 (1.6); 5.1934 (1.6); 3.7892 (16.0); 1.7061 (6.4); 1.6886 (6.3); 1.5560 (0.9); 1.2646 (0.6); 1.2598 (0.6); 0.8819 (1.1); −0.0002 (10.3) VII-149: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 7.8335 (1.0); 7.8289 (1.6); 7.8244 (1.1); 7.5784 (0.5); 7.5733 (0.5); 7.5562 (0.7); 7.5552 (0.7); 7.5511 (0.7); 7.5501 (0.7); 7.5331 (0.5); 7.5280 (0.5); 7.3925 (0.7); 7.3880 (1.0); 7.3743 (0.6); 7.3696 (0.9); 7.3556 (0.5); 7.2613 (9.5); 7.2407 (0.5); 7.2389 (0.6); 7.2376 (0.5); 7.2229 (0.7); 7.2214 (0.8); 7.2194 (0.8); 7.0650 (0.5); 7.0617 (0.5); 7.0402 (0.8); 7.0365 (0.5); 5.2252 (1.5); 5.2078 (1.5); 3.7756 (16.0); 1.6949 (6.2); 1.6775 (6.2); 1.5569 (4.9); 1.5545 (6.0); −0.0002 (13.4) VII-148: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 7.8417 (1.8); 7.8371 (2.7); 7.8326 (2.0); 7.5873 (1.0); 7.5822 (0.9); 7.5652 (1.2); 7.5642 (1.3); 7.5601 (1.2); 7.5590 (1.2); 7.5421 (1.0); 7.5370 (0.9); 7.4473 (0.7); 7.4430 (0.8); 7.4281 (1.3); 7.4237 (1.5); 7.4093 (0.9); 7.4049 (1.1); 7.3978 (0.5); 7.3856 (0.5); 7.3811 (0.5); 7.3790 (0.8); 7.3771 (0.6); 7.3745 (0.7); 7.3727 (0.6); 7.3667 (0.8); 7.3649 (0.6); 7.3622 (0.7); 7.3604 (0.6); 7.3582 (0.8); 7.3538 (0.6); 7.3460 (0.7); 7.3415 (0.6); 7.2613 (22.9); 7.2555 (1.0); 7.2538 (1.1); 7.2521 (1.1); 7.2507 (1.0); 7.2347 (1.3); 7.2323 (1.3); 7.2169 (0.6); 7.2153 (0.6); 7.2135 (0.6); 7.2121 (0.6); 7.0720 (1.0); 7.0687 (0.9); 7.0512 (0.9); 7.0474 (1.5); 7.0436 (1.0); 7.0260 (0.9); 7.0228 (0.8); 4.8983 (14.4); 4.2967 (1.8); 4.2788 (5.7); 4.2610 (5.8); 4.2433 (2.1); 4.2325 (0.7); 1.5546 (9.6); 1.5531 (11.2); 1.3085 (7.6); 1.2996 (0.5); 1.2907 (16.0); 1.2729 (7.5); 0.0080 (0.8); −0.0002 (28.6); −0.00084 (0.9) VII-109: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1443 (1.3); 8.1382 (1.3); 7.8118 (0.6); 7.8056 (0.6); 7.7931 (0.7); 7.7907 (0.8); 7.7869 (0.7); 7.7845 (0.7); 7.7720 (0.6); 7.7657 (0.6); 7.3767 (0.6); 7.3704 (0.5); 7.3553 (1.2); 7.3400 (0.5); 7.3339 (0.6); 7.2608 (11.7); 6.9679 (0.7); 6.9645 (1.7); 6.9561 (1.0); 6.9461 (2.3); 6.9429 (2.2); 6.9363 (1.0); 6.9273 (1.1); 6.9247 (1.6); 6.9211 (0.6); 4.9047 (9.0); 3.7951 (16.0); 1.5463 (4.8); −0.0002 (14.7) VIII-010: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.2300 (1.6); 8.2171 (1.7); 7.2618 (17.8); 7.2188 (0.6); 7.2123 (0.5); 7.2052 (0.8); 7.1988 (0.6); 7.1921 (0.5); 7.1844 (0.5); 7.0805 (1.0); 7.0767 (1.7); 7.0728 (1.0); 7.0676 (1.3); 7.0635 (1.3); 7.0596 (1.2); 7.0299 (0.7); 7.0181 (0.7); 7.0069 (1.0); 6.9951 (1.0); 6.8866 (1.8); 4.9178 (8.9); 3.8161 (16.0); 1.2595 (0.5); 0.8818 (0.7); −0.0002 (10.5) VII-061: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1472 (1.1); 8.1408 (1.2); 7.9059 (0.6); 7.8995 (0.6); 7.8878 (0.7); 7.8846 (0.7); 7.8814 (0.7); 7.8782 (0.7); 7.8665 (0.7); 7.8601 (0.6); 7.4662 (0.6); 7.4447 (1.1); 7.4233 (0.6); 7.2626 (15.7); 7.0316 (1.4); 7.0304 (1.4); 7.0275 (1.6); 7.0243 (1.0); 7.0227 (1.0); 7.0092 (2.7); 7.0059 (2.1); 7.0031 (1.3); 7.0016 (1.1); 6.9878 (1.2); 6.9840 (0.7); 4.9104 (8.4); 3.8003 (16.0); 2.0454 (0.7); 1.5634 (1.1); 1.2596 (0.6); 0.8818 (0.6); −0.0002 (9.6) VDI-008: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.3101 (1.6); 8.2971 (1.7); 7.2765 (0.5); 7.2689 (0.8); 7.2612 (40.1); 7.2495 (0.7); 7.2431 (0.5); 7.2354 (0.6); 7.1754 (0.6); 7.1665 (0.6); 7.1570 (0.5); 7.1497 (1.0); 7.1462 (1.4); 7.1424 (0.8); 7.1369 (0.8); 7.1331 (1.4); 7.1294 (0.7); 7.1039 (0.6); 7.0923 (0.6); 7.0811 (1.0); 7.0696 (1.0); 6.8648 (1.1); 6.8611 (1.7); 4.9268 (8.6); 3.8211 (16.0); 2.0455 (0.5); 1.5511 (5.3); 0.0079 (0.7); −0.0002 (24.4); −0.0085 (0.7) VII-116: .sup.1H-NMR(400.0 MHz, CDCl3_5 mm): δ = 8.1822 (2.0); 8.1802 (1.6); 8.1780 (1.6); 8.1760 (2.0); 8.1741 (1.4); 7.7065 (1.1); 7.7002 (1.1); 7.6877 (1.2); 7.6852 (1.4); 7.6815 (1.3); 7.6790 (1.3); 7.6665 (1.2); 7.6602 (1.1); 7.3329 (0.7); 7.3286 (0.9); 7.3270 (1.0); 7.3226 (0.7); 7.3188 (0.5); 7.3164 (0.6); 7.3110 (3.5); 7.3072 (1.4); 7.3044 (1.4); 7.2964 (1.7); 7.2925 (4.4); 7.2909 (3.1); 7.2850 (3.1); 7.2811 (1.7); 7.2752 (0.8); 7.2694 (1.6); 7.2675 (1.5); 7.2654 (0.8); 7.2612 (15.4); 7.1383 (3.1); 7.1341 (3.6); 7.1285 (1.0); 7.1221 (1.6); 7.1174 (3.2); 7.1140 (2.7); 6.9588 (1.4); 6.9573 (1.4); 6.9513 (1.4); 6.9497 (1.4); 6.9376 (1.4); 6.9361 (1.4); 6.9300 (1.4); 6.9285 (1.3); 5.2998 (1.2); 4.9232 (14.8); 4.3064 (1.9); 4.2886 (5.9); 4.2707 (6.0); 4.2529 (1.9); 2.0452 (1.3); 1.5611 (5.1); 1.3332 (0.7); 1.3215 (7.7); 1.3037 (16.0); 1.2933 (0.6); 1.2858 (7.9); 1.2773 (0.8); 1.2593 (2.2); 1.2551 (2.2); 1.2441 (0.8); 1.2416 (0.9); 0.0079 (0.6); −0.0002 (19.6); −0.00085 (0.6) VII-132: .sup.1H-NMR(400.0 MHz, CDCl3_5 mm): δ = 8.4736 (2.2); 8.4668 (2.1); 8.2822 (1.4); 8.2786 (2.2); 8.2750 (1.3); 7.4407 (0.8); 7.4362 (0.9); 7.4339 (0.9); 7.4294 (0.7); 7.4186 (0.8); 7.4141 (0.9); 7.4118 (0.8); 7.4073 (0.7); 7.2612 (8.1); 7.1818 (0.5); 7.1741 (0.6); 7.1675 (0.6); 7.1605 (0.9); 7.1540 (0.6); 7.1474 (0.6); 7.1396 (0.5); 7.0501 (0.6); 7.0451 (0.5); 7.0421 (0.7); 7.0324 (0.7); 7.0238 (0.6); 7.0029 (0.7); 6.9909 (0.7); 6.9799 (1.0); 6.9681 (1.0); 5.2346 (0.5); 5.2172 (1.7); 5.1997 (1.7); 3.7886 (16.0); 1.7021 (6.8); 1.6847 (6.6); 1.5562 (5.0); 0.0078 (0.8); −0.0002 (12.3) VII-135: .sup.1H-NMR(400.0 MHz, CDCl3_5 mm): δ = 8.4716 (2.0); 8.4647 (2.0); 8.2834 (1.2); 8.2797 (2.0); 8.2761 (1.1); 7.4260 (0.7); 7.4216 (0.8); 7.4192 (0.8); 7.4147 (0.7); 7.4040 (0.7); 7.3995 (0.8); 7.3971 (0.8); 7.3927 (0.6); 7.2627 (3.6); 7.1542 (0.6); 7.1476 (0.5); 7.1404 (0.8); 7.1340 (0.5); 7.0274 (0.6); 7.0261 (0.6); 7.0174 (0.6); 7.0092 (0.5); 7.0077 (0.5); 6.9896 (0.6); 6.9777 (0.7); 6.9667 (0.9); 6.9548 (0.9); 5.3001 (2.2); 5.2041 (1.6); 5.1867 (1.6); 3.7849 (16.0); 1.6974 (6.5); 1.6800 (6.4); 1.5841 (1.4); −0.0002 (5.3) VII-136: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4722 (2.1); 8.4654 (2.2); 8.2823 (1.4); 8.2788 (2.3); 8.2753 (1.4); 7.4419 (1.1); 7.4375 (1.2); 7.4351 (1.2); 7.4307 (1.1); 7.4199 (1.2); 7.4155 (1.2); 7.4130 (1.2); 7.4086 (1.1); 7.2610 (21.0); 7.1881 (0.7); 7.1806 (0.8); 7.1740 (0.8); 7.1669 (1.2); 7.1604 (0.8); 7.1537 (0.8); 7.1461 (0.8); 7.0517 (0.5); 7.0468 (0.7); 7.0420 (0.6); 7.0390 (0.8); 7.0376 (0.8); 7.0288 (1.0); 7.0208 (0.7); 7.0192 (0.8); 7.0114 (0.6); 6.9975 (1.1); 6.9858 (1.0); 6.9747 (1.4); 6.9629 (1.4); 6.9517 (0.6); 6.9400 (0.5); 5.1999 (0.8); 5.1825 (2.9); 5.1651 (3.0); 5.1478 (0.8); 4.2753 (2.0); 4.2575 (6.5); 4.2397 (6.6); 4.2219 (2.1); 1.6974 (11.2); 1.6800 (11.1); 1.5533 (7.9); 1.2922 (7.6); 1.2744 (16.0); 1.2679 (1.2); 1.2642 (1.3); 1.2566 (7.6); 0.8988 (0.6); 0.8819 (2.4); 0.8642 (0.9); 0.0080 (0.8); −0.0002 (30.5); −0.00084 (0.9) VII-137: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4896 (2.9); 8.4829 (3.3); 8.2894 (3.3); 7.5187 (0.5); 7.4545 (1.8); 7.4501 (1.8); 7.4477 (1.9); 7.4433 (1.7); 7.4326 (1.8); 7.4282 (2.0); 7.4257 (1.8); 7.4213 (1.7); 7.2603 (93.5); 7.2024 (1.1); 7.1947 (1.3); 7.1882 (1.3); 7.1810 (1.8); 7.1747 (1.4); 7.1680 (1.3); 7.1604 (1.4); 7.0776 (0.6); 7.0684 (0.8); 7.0601 (0.9); 7.0547 (1.1); 7.0500 (1.0); 7.0467 (1.4); 7.0422 (0.8); 7.0368 (1.6); 7.0272 (1.3); 7.0193 (0.9); 7.0036 (1.6); 6.9966 (0.7); 6.9917 (1.6); 6.9805 (2.6); 6.9687 (2.4); 6.9576 (0.9); 6.9459 (0.9); 5.3057 (1.1); 5.2882 (4.8); 5.2767 (0.7); 5.2708 (4.9); 5.2593 (0.7); 5.2533 (1.2); 2.2718 (0.5); 1.7598 (16.0); 1.7544 (2.9); 1.7423 (16.0); 1.7369 (2.9); 1.6972 (0.5); 1.4322 (5.2); 1.2917 (0.7); 1.2740 (1.4); 1.2651 (2.0); 0.8990 (1.1); 0.8820 (3.9); 0.8643 (1.4); 0.0080 (3.6); −0.0002 (136.5); −0.00085 (4.2) VII-080: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.2290 (0.6); 8.2220 (5.8); 8.2165 (1.9); 8.2044 (1.8); 8.1989 (6.4); 8.1919 (0.8); 8.1504 (2.0); 8.1486 (1.6); 8.1462 (1.6); 8.1441 (2.2); 7.9076 (1.0); 7.9013 (1.0); 7.8895 (1.2); 7.8864 (1.3); 7.8832 (1.2); 7.8800 (1.2); 7.8682 (1.1); 7.8619 (1.1); 7.3289 (0.7); 7.3218 (6.1); 7.3163 (1.9); 7.3043 (1.8); 7.2988 (6.2); 7.2917 (0.7); 7.2611 (32.0); 7.1092 (1.4); 7.1077 (1.5); 7.1016 (1.4); 7.1002 (1.4); 7.0880 (1.3); 7.0865 (1.4); 7.0804 (1.3); 7.0789 (1.4); 5.0340 (13.4); 5.0212 (0.8); 4.3238 (1.8); 4.3060 (5.9); 4.2882 (6.0); 4.2704 (2.0); 2.0453 (1.0); 1.5441 (16.0); 1.3340 (7.4); 1.3162 (15.5); 1.3024 (1.0); 1.2984 (7.2); 1.2917 (0.6); 1.2846 (0.5); 1.2596 (0.7); 0.0081 (1.2); −0.0002 (47.4); −0.00085 (1.4) VII-079: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1094 (1.9); 8.1074 (1.5); 8.1052 (1.5); 8.1031 (2.0); 8.1012 (1.3); 7.8474 (1.1); 7.8411 (1.1); 7.8290 (1.2); 7.8261 (1.3); 7.8227 (1.2); 7.8199 (1.2); 7.8077 (1.2); 7.8015 (1.1); 7.5192 (0.6); 7.3638 (0.5); 7.3590 (0.7); 7.3562 (0.9); 7.3525 (6.2); 7.3483 (4.8); 7.3401 (2.4); 7.3347 (3.0); 7.3336 (2.7); 7.3309 (0.8); 7.3277 (0.6); 7.3233 (1.1); 7.2674 (0.6); 7.2608 (103.1); 7.1284 (3.2); 7.1240 (2.8); 7.1178 (1.0); 7.1153 (1.9); 7.1110 (1.9); 7.1093 (1.3); 7.1039 (3.0); 7.0183 (1.4); 7.0167 (1.4); 7.0108 (1.4); 7.0092 (1.4); 6.9971 (1.9); 6.9955 (1.4); 6.9895 (1.4); 6.9880 (1.4); 5.3002 (7.3); 5.0215 (14.2); 4.3130 (1.8); 4.2951 (5.9); 4.2773 (6.0); 4.2595 (1.9); 1.5456 (2.7); 1.3203 (7.5); 1.3025 (16.0); 1.2847 (7.5); 0.0080 (1.8); −0.0002 (62.7); −0.00085 (1.7) VII-145: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4727 (1.3); 8.4659 (1.3); 8.2780 (0.7); 8.2742 (1.3); 8.2706 (0.8); 7.4389 (0.6); 7.4345 (0.6); 7.4321 (0.6); 7.4276 (0.5); 7.4169 (0.6); 7.4124 (0.6); 7.4100 (0.6); 7.4056 (0.5); 7.2613 (25.4); 7.1938 (0.6); 6.9715 (0.7); 6.9597 (0.7); 5.2352 (1.4); 5.2177 (1.4); 4.3523 (1.0); 4.3505 (1.0); 4.3426 (1.1); 4.3411 (1.1); 4.3381 (1.1); 4.3362 (1.0); 4.3287 (1.1); 4.3267 (1.1); 3.6095 (1.9); 3.5998 (1.1); 3.5977 (1.7); 3.5955 (1.1); 3.5858 (1.8); 3.3342 (16.0); 1.7149 (5.1); 1.6975 (5.0); −0.0002 (16.1) VII-144: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4729 (1.1); 8.4661 (1.2); 8.2976 (1.2); 7.4547 (0.6); 7.4503 (0.7); 7.4478 (0.7); 7.4434 (0.6); 7.4326 (0.6); 7.4282 (0.7); 7.4257 (0.7); 7.4213 (0.6); 7.2610 (51.1); 7.2519 (0.6); 7.2439 (0.5); 7.2370 (0.5); 7.2299 (0.6); 7.0332 (0.5); 6.9977 (0.7); 6.9866 (0.6); 6.9755 (0.8); 6.9637 (0.8); 5.1811 (1.6); 5.1637 (1.7); 4.4858 (0.8); 4.4706 (1.1); 4.4692 (1.0); 4.4536 (1.4); 4.4375 (1.2); 4.4226 (0.8); 3.6447 (16.0); 2.6792 (0.9); 2.6745 (0.9); 2.6643 (1.2); 2.6627 (1.2); 2.6588 (1.7); 2.6477 (0.9); 2.6434 (0.9); 1.6869 (6.0); 1.6695 (6.0); 0.0080 (0.8); −0.0002 (31.9); −0.00085 (0.9) VII-143: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.5473 (2.7); 8.5406 (2.8); 8.2997 (1.6); 8.2962 (2.6); 8.2927 (1.6); 7.5192 (0.6); 7.4975 (1.2); 7.4928 (1.3); 7.4907 (1.3); 7.4860 (1.2); 7.4764 (1.3); 7.4717 (1.4); 7.4695 (1.3); 7.4650 (1.2); 7.2607 (115.7); 7.2559 (1.6); 7.2551 (1.3); 7.2348 (0.5); 7.2336 (0.5); 7.2269 (0.9); 7.2205 (0.8); 7.2129 (1.1); 7.2073 (0.9); 7.2010 (0.8); 7.1932 (0.9); 7.1579 (0.6); 7.1492 (0.6); 7.1443 (0.7); 7.1396 (0.7); 7.1350 (0.8); 7.1263 (0.9); 7.1167 (0.8); 7.1088 (0.5); 7.0706 (1.0); 7.0590 (1.0); 7.0478 (1.5); 7.0362 (1.5); 7.0249 (0.6); 7.0133 (0.6); 6.9971 (0.6); 5.1916 (0.8); 5.1742 (2.9); 5.1568 (3.0); 5.1394 (0.8); 4.2746 (1.9); 4.2568 (6.2); 4.2390 (6.4); 4.2213 (2.1); 1.7010 (11.2); 1.6836 (11.1); 1.5478 (5.6); 1.2907 (7.5); 1.2730 (16.0); 1.2597 (0.8); 1.2552 (7.5); 0.8821 (0.8); 0.0080 (2.0); −0.0002 (71.8); −0.00085 (2.0) VII-086: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.2243 (0.9); 8.2221 (0.7); 8.2200 (0.7); 8.2180 (1.0); 8.1733 (2.9); 8.1679 (0.8); 8.1557 (0.9); 8.1502 (3.0); 7.7546 (0.5); 7.7484 (0.5); 7.7362 (0.6); 7.7335 (0.6); 7.7299 (0.6); 7.7272 (0.6); 7.7150 (0.5); 7.7087 (0.5); 7.2804 (3.1); 7.2750 (0.9); 7.2607 (48.3); 7.2582 (3.4); 7.2574 (3.6); 7.0583 (0.6); 7.0567 (0.6); 7.0507 (0.7); 7.0491 (0.6); 7.0371 (0.6); 7.0355 (0.6); 7.0295 (0.6); 7.0279 (0.6); 5.2544 (1.3); 5.2370 (1.3); 3.8009 (14.1); 2.0456 (0.7); 1.7233 (5.2); 1.7058 (5.2); 1.5414 (16.0); 1.2639 (0.5); 1.2598 (0.7); 0.8820 (1.1); 0.0080 (1.3); −0.0002 (41.0); −0.00085 (1.0) VII-087: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.2282 (1.7); 8.2261 (1.3); 8.2239 (1.4); 8.2219 (1.8); 8.1881 (0.5); 8.1809 (5.2); 8.1755 (1.5); 8.1633 (1.6); 8.1578 (5.4); 8.1506 (0.6); 7.7600 (0.9); 7.7537 (0.9); 7.7415 (1.0); 7.7388 (1.1); 7.7352 (1.0); 7.7325 (1.0); 7.7204 (1.0); 7.7141 (1.0); 7.3122 (0.6); 7.3051 (5.5); 7.2996 (1.5); 7.2874 (1.5); 7.2820 (5.0); 7.2748 (0.5); 7.2610 (48.3); 7.0615 (1.2); 7.0600 (1.2); 7.0539 (1.2); 7.0524 (1.1); 7.0403 (1.2); 7.0388 (1.1); 7.0327 (1.2); 7.0312 (1.1); 4.9364 (12.0); 4.3214 (1.6); 4.3036 (5.0); 4.2858 (5.1); 4.2680 (1.6); 4.1310 (0.5); 4.1132 (0.5); 2.7762 (0.8); 2.0455 (2.5); 1.5447 (16.0); 1.3362 (6.3); 1.3184 (13.2); 1.3006 (6.3); 1.2776 (1.0); 1.2598 (2.0); 1.2419 (0.8); 0.8820 (1.7); 0.8644 (0.6); 0.0080 (1.0); −0.0002 (40.6); −0.00085 (1.2) VII-142: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.5599 (3.4); 8.5533 (3.5); 8.3115 (4.0); 7.5190 (2.8); 7.5142 (2.2); 7.5120 (2.0); 7.5074 (1.7); 7.4978 (1.9); 7.4932 (2.4); 7.4911 (2.0); 7.4865 (1.7); 7.2688 (0.5); 7.2606 (196.2); 7.2550 (1.7); 7.2542 (1.4); 7.2534 (1.4); 7.2527 (1.2); 7.2519 (1.0); 7.2510 (0.7); 7.2502 (0.7); 7.2494 (0.6); 7.2414 (1.5); 7.2338 (2.0); 7.2268 (1.3); 7.2217 (2.1); 7.2142 (1.5); 7.2078 (1.3); 7.2001 (1.4); 7.1694 (0.8); 7.1602 (0.9); 7.1515 (1.1); 7.1463 (1.4); 7.1417 (1.5); 7.1383 (1.6); 7.1285 (1.8); 7.1202 (1.4); 7.1110 (1.0); 7.0725 (1.6); 7.0609 (1.7); 7.0496 (2.5); 7.0382 (2.5); 7.0267 (1.0); 7.0153 (1.0); 6.9970 (1.1); 5.3003 (2.4); 5.2962 (1.2); 5.2785 (4.9); 5.2610 (5.0); 5.2550 (0.8); 5.2435 (1.2); 5.2374 (0.6); 1.7637 (16.0); 1.7462 (15.9); 1.7340 (2.0); 1.2541 (0.7); 0.0080 (3.6); 0.0063 (1.1); −0.0002 (121.8); −0.00050 (1.6); −0.00059 (1.5); −0.00067 (1.6); −0.00084 (3.5); −0.0106 (0.5) VII-146: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4331 (1.1); 8.4265 (1.2); 8.2991 (1.3); 7.3374 (0.5); 7.3330 (0.6); 7.3308 (0.6); 7.3265 (0.5); 7.3149 (0.5); 7.3105 (0.7); 7.3083 (0.6); 7.3040 (0.5); 7.2615 (18.3); 7.1089 (0.8); 6.9795 (0.5); 6.9775 (0.5); 6.9692 (0.8); 6.9637 (0.8); 6.9591 (0.6); 6.9515 (1.0); 6.9415 (0.8); 6.9293 (0.8); 5.1951 (1.6); 5.1777 (1.6); 3.7717 (16.0); 1.6400 (6.5); 1.6226 (6.5); 1.5866 (0.5); 1.5672 (0.9); 1.2643 (0.7); 0.8818 (1.2); 0.8181 (0.9); 0.8137 (1.0); 0.8081 (1.7); 0.8022 (0.8); 0.7963 (2.1); 0.7911 (1.8); 0.7857 (0.8); 0.7784 (0.9); 0.7728 (1.3); 0.7646 (0.6); −0.0002 (10.9) VII-141: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4552 (1.6); 8.3167 (1.8); 7.5193 (0.8); 7.3575 (1.3); 7.3534 (1.5); 7.3510 (1.6); 7.3468 (1.4); 7.3353 (1.4); 7.3312 (1.6); 7.3288 (1.5); 7.3246 (1.2); 7.2665 (0.6); 7.2607 (149.3); 7.2543 (2.3); 7.2503 (0.8); 7.2495 (0.8); 7.2336 (0.7); 7.1557 (1.0); 7.1484 (1.2); 7.1415 (1.3); 7.1343 (2.2); 7.1278 (1.3); 7.1207 (1.3); 7.1134 (1.3); 7.0127 (0.7); 7.0046 (0.8); 6.9994 (1.3); 6.9971 (1.6); 6.9919 (1.5); 6.9899 (1.5); 6.9816 (2.1); 6.9719 (3.0); 6.9639 (1.3); 6.9602 (1.9); 6.9496 (2.3); 6.9375 (2.3); 6.9267 (0.8); 6.9148 (0.7); 5.2607 (1.2); 5.2433 (4.8); 5.2259 (4.9); 5.2085 (1.2); 1.6962 (16.0); 1.6788 (16.0); 1.6001 (0.7); 1.5871 (0.7); 1.5821 (1.5); 1.5735 (1.0); 1.5658 (2.6); 1.5594 (1.0); 1.5532 (1.1); 1.5477 (1.6); 1.5318 (0.9); 1.4322 (3.4); 1.2642 (1.2); 0.8989 (0.6); 0.8820 (2.2); 0.8642 (0.9); 0.8168 (0.5); 0.8006 (1.8); 0.7957 (3.4); 0.7933 (4.7); 0.7825 (3.2); 0.7763 (9.2); 0.7681 (4.2); 0.7639 (6.1); 0.0080 (2.0); −0.0002 (88.7); −0.00066 (1.9); −0.00085 (3.2); −0.0273 (0.5) VII-140: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.4317 (3.0); 8.4249 (3.1); 8.3030 (1.8); 8.2991 (3.2); 8.2953 (1.8); 7.3395 (1.2); 7.3352 (1.3); 7.3326 (1.3); 7.3283 (1.2); 7.3170 (1.2); 7.3126 (1.4); 7.3102 (1.3); 7.3058 (1.2); 7.2613 (47.8); 7.1389 (0.7); 7.1317 (0.8); 7.1247 (0.8); 7.1175 (1.5); 7.1115 (0.8); 7.1038 (0.8); 7.0966 (0.8); 6.9974 (0.6); 6.9891 (0.5); 6.9840 (0.8); 6.9765 (0.9); 6.9745 (0.9); 6.9662 (1.4); 6.9590 (1.9); 6.9562 (1.0); 6.9479 (1.6); 6.9368 (1.5); 6.9247 (1.4); 5.1841 (0.8); 5.1668 (3.1); 5.1495 (3.1); 5.1321 (0.8); 4.2559 (2.0); 4.2381 (6.6); 4.2204 (6.8); 4.2026 (2.2); 1.6358 (12.0); 1.6185 (12.1); 1.6009 (0.8); 1.5875 (0.8); 1.5836 (0.9); 1.5801 (0.7); 1.5736 (0.7); 1.5670 (2.1); 1.5590 (0.7); 1.5529 (0.7); 1.5497 (0.9); 1.5458 (0.6); 1.5326 (0.6); 1.2871 (7.6); 1.2693 (16.0); 1.2515 (7.5); 0.8525 (0.7); 0.8475 (0.6); 0.8422 (0.8); 0.8381 (1.3); 0.8290 (0.9); 0.8247 (1.5); 0.8190 (1.2); 0.8095 (1.6); 0.8060 (1.5); 0.7976 (3.1); 0.7893 (2.4); 0.7815 (1.3); 0.7799 (1.4); 0.7755 (2.1); 0.7677 (1.6); 0.7607 (1.3); 0.7496 (0.6); 0.7475 (0.6); 0.0080 (0.9); −0.0002 (27.3); −0.00084 (0.8) VII-084: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1549 (2.0); 8.1527 (1.5); 8.1505 (1.6); 8.1485 (2.0); 7.8130 (1.1); 7.8066 (1.1); 7.7948 (1.2); 7.7917 (1.3); 7.7884 (1.2); 7.7853 (1.2); 7.7735 (1.2); 7.7671 (1.1); 7.3902 (1.5); 7.3868 (6.0); 7.3832 (2.6); 7.3792 (4.6); 7.3756 (2.0); 7.3702 (4.4); 7.3638 (1.1); 7.2614 (46.0); 7.1942 (3.0); 7.1908 (1.5); 7.1879 (2.2); 7.1833 (1.8); 7.1791 (2.7); 7.1755 (1.1); 7.1726 (1.3); 7.1698 (2.3); 7.0135 (1.4); 7.0120 (1.4); 7.0059 (1.5); 7.0044 (1.4); 6.9922 (1.4); 6.9907 (1.3); 6.9846 (1.4); 6.9830 (1.3); 4.9209 (14.6); 4.3057 (1.8); 4.2878 (5.8); 4.2700 (5.9); 4.2522 (1.9); 1.5586 (2.6); 1.3209 (7.6); 1.3031 (16.0); 1.2852 (7.5); 0.0080 (0.8); −0.0002 (27.5); −0.00085 (0.8) VII-083: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1668 (2.6); 8.1604 (2.6); 7.8170 (1.2); 7.8106 (1.2); 7.7988 (1.4); 7.7956 (1.5); 7.7924 (1.4); 7.7893 (1.4); 7.7775 (1.3); 7.7711 (1.2); 7.4014 (0.7); 7.3912 (6.8); 7.3842 (5.4); 7.3797 (2.4); 7.3765 (4.0); 7.3742 (4.6); 7.3700 (1.0); 7.3667 (1.2); 7.2614 (33.3); 7.2101 (0.5); 7.2037 (3.7); 7.2000 (2.0); 7.1977 (3.2); 7.1920 (2.2); 7.1883 (3.2); 7.1849 (1.3); 7.1815 (1.6); 7.1793 (2.6); 7.0180 (1.7); 7.0116 (1.6); 7.0105 (1.6); 6.9977 (1.7); 6.9903 (1.6); 6.9891 (1.6); 4.9994 (16.0); 1.4319 (0.9); 1.2644 (1.1); 0.8986 (0.6); 0.8818 (2.1); 0.8641 (0.8); 0.0080 (0.5); −0.0002 (19.1); −0.00085 (0.6) VIII-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.3893 (2.4); 8.3763 (2.5); 8.1937 (2.3); 8.1808 (2.4); 7.4278 (2.7); 7.4246 (2.6); 7.4118 (4.0); 7.3902 (2.0); 7.3668 (1.7); 7.3516 (1.1); 7.2611 (25.4); 7.2315 (3.2); 7.2118 (1.6); 7.1631 (3.7); 7.0663 (2.2); 7.0533 (3.5); 7.0298 (1.3); 6.9982 (0.5); 6.9762 (0.7); 6.8684 (3.0); 4.9213 (10.0); 4.8550 (1.8); 4.8443 (2.7); 3.8054 (16.0); 3.7706 (6.4); 2.7718 (1.7); 1.5614 (1.9); 1.2563 (0.7); 0.0701 (2.2); −0.0002 (9.6) II-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 7.8797 (0.6); 7.8605 (1.8); 7.8404 (2.0); 7.8208 (0.8); 7.7214 (1.1); 7.7064 (1.2); 7.6264 (1.7); 7.6210 (1.7); 7.6077 (1.6); 7.6027 (1.5); 7.4974 (0.9); 7.4814 (1.8); 7.4622 (1.2); 7.4157 (0.7); 7.3947 (1.6); 7.3772 (1.2); 7.3496 (0.5); 7.3300 (1.1); 7.3122 (1.3); 7.2973 (0.8); 7.2606 (30.8); 7.2594 (32.3); 7.2265 (1.6); 7.2083 (2.2); 7.1893 (1.0); 7.0181 (1.1); 6.9944 (1.7); 6.9716 (1.0); 6.8799 (1.5); 6.8727 (1.6); 6.8593 (1.5); 6.8522 (1.5); 4.9271 (10.2); 4.0990 (0.9); 3.7969 (16.0); 2.7707 (0.7); 1.5460 (1.5); 1.2473 (2.6); 1.0708 (7.2); 1.0014 (0.7); 0.0009 (11.2); −0.0002 (12.0) VII-001: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1087 (1.2); 8.1066 (0.9); 8.1043 (1.0); 8.1024 (1.2); 7.7681 (0.6); 7.7619 (0.6); 7.7494 (0.7); 7.7469 (0.8); 7.7431 (0.8); 7.7407 (0.8); 7.7282 (0.7); 7.7219 (0.7); 7.4251 (0.5); 7.4207 (0.6); 7.4058 (0.9); 7.4014 (1.1); 7.3870 (0.6); 7.3826 (0.7); 7.3525 (0.5); 7.3402 (0.5); 7.3318 (0.5); 7.2603 (36.9); 7.2284 (0.6); 7.2268 (0.6); 7.2250 (0.7); 7.2056 (1.0); 7.0499 (0.7); 7.0467 (0.7); 7.0291 (0.6); 7.0253 (1.1); 7.0215 (0.7); 7.0040 (0.6); 7.0007 (0.6); 6.9424 (0.9); 6.9410 (0.9); 6.9349 (0.9); 6.9335 (0.9); 6.9212 (0.8); 6.9197 (0.8); 6.9136 (0.9); 6.9122 (0.8); 5.2988 (0.5); 4.9216 (8.8); 3.8059 (16.0); 2.7731 (4.4); 1.5444 (1.8); 1.4213 (0.5); −0.0002 (16.0) VII-009: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1060 (3.0); 8.1001 (3.2); 7.7767 (1.1); 7.7704 (1.1); 7.7578 (1.6); 7.7554 (1.8); 7.7516 (1.7); 7.7369 (1.3); 7.7306 (1.2); 7.3576 (0.9); 7.3378 (1.3); 7.3204 (1.2); 7.3159 (1.4); 7.2961 (1.0); 7.2600 (42.8); 6.9958 (2.1); 6.9883 (2.0); 6.9744 (1.9); 6.9670 (2.0); 6.9390 (0.9); 6.9217 (1.0); 6.9154 (1.8); 6.8981 (1.8); 6.8918 (1.1); 6.8746 (0.9); 5.2983 (0.6); 4.8822 (16.0); 4.3049 (2.0); 4.2870 (6.3); 4.2692 (6.5); 4.2513 (2.3); 1.5399 (1.0); 1.3180 (7.1); 1.3002 (14.5); 1.2823 (7.3); 1.2569 (0.8); −0.0002 (15.5) VII-016: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1020 (2.2); 8.0957 (2.2); 7.7648 (1.1); 7.7585 (1.1); 7.7461 (1.3); 7.7435 (1.3); 7.7398 (1.3); 7.7373 (1.3); 7.7249 (1.2); 7.7186 (1.2); 7.4295 (0.9); 7.4151 (1.0); 7.4078 (1.5); 7.3935 (1.5); 7.3864 (1.0); 7.3720 (1.0); 7.2609 (34.4); 6.9779 (0.7); 6.9714 (2.2); 6.9673 (1.0); 6.9642 (1.8); 6.9629 (1.6); 6.9588 (0.9); 6.9553 (1.3); 6.9504 (2.3); 6.9488 (2.6); 6.9429 (1.7); 6.9415 (1.5); 6.9366 (0.6); 6.9328 (0.6); 6.9298 (0.7); 6.9260 (0.6); 6.8261 (1.0); 6.8193 (0.9); 6.8053 (1.1); 6.8012 (1.2); 6.7986 (1.1); 6.7944 (1.0); 6.7805 (1.0); 6.7737 (0.9); 5.2988 (1.0); 4.8874 (16.0); 4.8733 (0.8); 4.2972 (2.1); 4.2794 (6.5); 4.2616 (6.6); 4.2437 (2.2); 1.3088 (7.8); 1.2909 (15.9); 1.2731 (7.6); −0.0002 (12.9) VI-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1759 (0.7); 8.6525 (1.6); 8.0189 (1.6); 7.3464 (0.6); 7.3342 (0.6); 7.3268 (0.5); 7.3199 (1.0); 7.3130 (0.7); 7.2609 (39.3); 5.2512 (1.6); 4.9621 (2.0); 2.9556 (16.0); 2.8842 (13.9); 2.8828 (13.9); 2.8079 (0.9); 1.5840 (0.9); 0.0079 (0.6); −0.0002 (17.1) VII-028: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.0183 (1.6); 7.2632 (17.6); 4.9366 (1.7); 3.8155 (3.2); 2.9557 (16.0); 2.8842 (13.1); 2.8828 (13.5); −0.0002 (7.6) VII-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1724 (1.4); 8.1704 (1.2); 8.1683 (1.2); 8.1663 (1.4); 7.7025 (0.7); 7.6962 (0.7); 7.6838 (0.8); 7.6812 (0.9); 7.6775 (0.9); 7.6750 (0.9); 7.6626 (0.8); 7.6563 (0.7); 7.2597 (69.4); 7.1295 (1.5); 7.1238 (0.7); 7.1177 (1.7); 7.1124 (1.2); 7.1067 (2.4); 7.1006 (1.0); 7.0948 (2.6); 7.0866 (0.7); 7.0826 (0.6); 7.0748 (0.8); 7.0521 (0.5); 7.0295 (2.4); 7.0236 (0.8); 7.0176 (0.5); 7.0094 (2.7); 7.0068 (1.9); 7.0037 (1.0); 6.9957 (0.8); 6.9924 (0.8); 6.9866 (1.6); 6.9751 (1.2); 6.9735 (1.2); 6.9675 (1.2); 6.9660 (1.2); 6.9538 (1.0); 6.9523 (1.0); 6.9462 (1.1); 6.9447 (1.1); 4.9297 (8.8); 3.8121 (16.0); 1.5389 (1.1); 1.0075 (0.9); 0.3184 (0.6); 0.0691 (6.8); 0.0080 (1.1); −0.0002 (31.4); −0.00085 (1.4) VIII-005: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.2338 (1.6); 8.2208 (1.6); 7.2598 (57.1); 7.1415 (1.3); 7.1356 (0.6); 7.1296 (1.5); 7.1242 (1.0); 7.1186 (2.3); 7.1127 (0.7); 7.1106 (0.5); 7.1068 (2.2); 7.0497 (2.5); 7.0437 (1.8); 7.0397 (1.0); 7.0344 (1.0); 7.0299 (3.4); 7.0269 (2.4); 7.0127 (0.5); 7.0070 (1.4); 6.9004 (1.1); 6.8970 (1.8); 5.2985 (0.5); 4.9278 (8.7); 3.8109 (16.0); 3.8059 (1.4); 1.5438 (2.2); 0.0079 (0.8); −0.0002 (24.4); −0.00085 (0.7) VI-004: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1760 (4.0); 8.6700 (8.6); 7.5186 (0.6); 7.4670 (0.5); 7.4625 (0.6); 7.4476 (1.0); 7.4434 (1.1); 7.4287 (0.6); 7.4244 (0.7); 7.3752 (0.5); 7.3629 (0.5); 7.3546 (0.5); 7.3423 (0.5); 7.2597 (111.1); 7.2347 (1.1); 7.2172 (0.5); 7.0621 (0.7); 7.0589 (0.7); 7.0412 (0.7); 7.0374 (1.1); 7.0336 (0.8); 7.0161 (0.6); 7.0128 (0.6); 6.9957 (0.6); 4.9286 (9.3); 3.8101 (16.0); 2.9555 (1.3); 2.8832 (1.1); 2.7734 (2.2); 1.5597 (4.5); 0.0080 (1.5); −0.0002 (48.2); −0.00085 (1.6) VIII-003: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1913 (0.6); 8.1782 (0.6); 7.2594 (55.4); 7.2497 (0.6); 7.0701 (0.5); 7.0529 (0.7); 7.0490 (0.7); 6.8677 (0.7); 4.8991 (3.6); 4.2780 (1.4); 4.2601 (1.4); 2.0048 (0.5); 1.5328 (16.0); 1.3067 (1.7); 1.2889 (3.5); 1.2711 (1.7); 0.0079 (0.9); −0.0002 (28.2); −0.00085 (1.0) VIII-004: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.2034 (2.8); 8.1904 (3.0); 7.5187 (0.6); 7.4485 (0.8); 7.4441 (1.0); 7.4291 (1.5); 7.4248 (1.8); 7.4105 (1.3); 7.4062 (1.5); 7.3992 (0.7); 7.3925 (1.0); 7.3880 (0.9); 7.3802 (1.0); 7.3718 (1.0); 7.3674 (0.8); 7.3598 (0.7); 7.3551 (0.6); 7.2756 (0.7); 7.2729 (0.6); 7.2705 (1.1); 7.2672 (1.4); 7.2598 (119.1); 7.2551 (5.9); 7.2503 (2.2); 7.2474 (1.7); 7.2448 (1.3); 7.2417 (1.5); 7.2384 (2.2); 7.2367 (2.5); 7.2312 (1.0); 7.2272 (0.7); 7.2256 (0.7); 7.2237 (0.7); 7.2215 (0.9); 7.2182 (1.1); 7.2165 (1.2); 7.0793 (1.2); 7.0759 (1.3); 7.0738 (1.6); 7.0695 (2.1); 7.0659 (1.6); 7.0606 (1.8); 7.0561 (2.8); 7.0333 (1.0); 7.0301 (1.0); 6.9958 (0.6); 6.8751 (2.0); 6.8718 (3.2); 4.9783 (16.0); 4.1315 (0.6); 4.1137 (0.5); 2.0448 (2.5); 1.2766 (0.8); 1.2587 (1.8); 1.2409 (0.9); 0.0691 (0.6); 0.0080 (1.8); −0.0002 (61.1); −0.00085 (2.6); −0.0126 (1.0); −0.0183 (0.8); −0.0217 (0.5); −0.0234 (0.5) VII-012: .sup.1H-NMR(600.4 MHz, d.sub.6-DMSO): δ = 8.1973 (3.1); 8.1933 (3.2); 7.9509 (1.0); 7.9467 (1.0); 7.9370 (1.7); 7.9336 (1.6); 7.9239 (1.1); 7.9197 (1.0); 7.5684 (1.0); 7.5658 (1.1); 7.5555 (2.1); 7.5528 (2.2); 7.5426 (1.2); 7.5398 (1.3); 7.5006 (0.5); 7.4978 (0.6); 7.4921 (0.7); 7.4879 (1.2); 7.4851 (1.1); 7.4794 (1.2); 7.4766 (1.2); 7.4714 (0.8); 7.4658 (0.8); 7.4631 (0.7); 7.3277 (1.6); 7.3148 (2.7); 7.3033 (2.6); 7.3020 (2.5); 7.2874 (3.6); 7.2840 (3.3); 7.2729 (2.6); 7.2698 (2.8); 5.7520 (1.5); 4.9321 (14.8); 4.9120 (0.6); 4.8902 (0.6); 4.8850 (0.4); 4.8806 (0.3); 4.1869 (2.2); 4.1751 (6.9); 4.1690 (0.7); 4.1633 (7.0); 4.1573 (0.6); 4.1514 (2.3); 3.3062 (196.4); 2.6151 (1.2); 2.6121 (1.7); 2.6091 (1.2); 2.5211 (4.0); 2.5181 (5.2); 2.5149 (5.4); 2.5061 (97.2); 2.5032 (198.9); 2.5001 (269.5); 2.4971 (201.7); 2.4942 (100.3); 2.3871 (1.2); 2.3841 (1.7); 2.3811 (1.2); 1.1998 (7.8); 1.1947 (0.8); 1.1879 (16.0); 1.1829 (1.3); 1.1761 (7.7); 1.1492 (0.4); 1.1373 (0.7); 1.1255 (0.4); 1.1096 (0.6); 0.0052 (1.2); −0.0002 (32.4); −0.00057 (1.3) VII-003: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1127 (1.7); 8.1066 (1.7); 7.7664 (0.7); 7.7601 (0.7); 7.7476 (0.9); 7.7451 (1.0); 7.7413 (0.9); 7.7389 (0.9); 7.7264 (0.8); 7.7202 (0.7); 7.4356 (0.6); 7.4313 (0.7); 7.4163 (1.2); 7.4122 (1.3); 7.3975 (0.8); 7.3932 (0.8); 7.3536 (0.7); 7.3493 (0.6); 7.3413 (0.7); 7.3370 (0.6); 7.3331 (0.7); 7.3285 (0.5); 7.3207 (0.6); 7.3163 (0.5); 7.2602 (34.6); 7.2233 (0.9); 7.2043 (1.2); 7.1847 (0.6); 7.0471 (0.8); 7.0439 (0.8); 7.0264 (1.1); 7.0225 (1.4); 7.0188 (1.0); 7.0047 (0.9); 7.0013 (0.9); 6.9980 (0.9); 6.9918 (0.8); 6.9428 (1.1); 6.9367 (1.1); 6.9215 (1.1); 6.9155 (1.1); 6.8509 (0.8); 6.8441 (0.5); 6.7617 (0.6); 5.2980 (16.0); 4.9464 (5.8); 4.5515 (2.3); 4.1388 (1.9); 4.1325 (1.3); 4.1288 (1.1); 4.1197 (0.6); 4.1140 (0.5); 4.0728 (0.6); 4.0561 (0.9); 4.0522 (1.0); 4.0383 (1.1); 2.0454 (0.9); 1.5666 (6.8); 1.3316 (0.6); 1.2840 (1.0); 1.2761 (0.5); 1.2581 (1.8); 0.0080 (0.7); −0.0002 (19.6); −0.00085 (0.8) VII-009: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1005 (3.4); 7.8839 (0.8); 7.8782 (0.9); 7.7772 (1.1); 7.7710 (1.1); 7.7559 (1.9); 7.7524 (1.9); 7.7499 (1.8); 7.7374 (1.2); 7.7312 (1.2); 7.3582 (0.9); 7.3385 (1.6); 7.3346 (1.4); 7.3169 (1.5); 7.2970 (0.9); 7.2612 (24.1); 6.9953 (2.1); 6.9887 (2.0); 6.9740 (1.9); 6.9675 (1.8); 6.9395 (0.9); 6.9221 (1.0); 6.9160 (1.8); 6.8986 (1.7); 6.8751 (0.8); 5.2988 (2.7); 4.8824 (16.0); 4.8745 (4.1); 4.8077 (4.4); 4.3048 (2.2); 4.2870 (6.6); 4.2691 (7.2); 4.2514 (3.9); 4.2336 (1.7); 4.2158 (0.6); 1.5494 (5.7); 1.3250 (1.7); 1.3181 (6.8); 1.3072 (3.4); 1.3003 (13.6); 1.2873 (3.4); 1.2825 (7.1); 1.2696 (3.8); 1.2517 (1.8); −0.0002 (13.6) VII-033: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1164 (2.8); 8.1101 (2.9); 7.7824 (1.2); 7.7761 (1.2); 7.7638 (1.5); 7.7611 (1.6); 7.7575 (1.6); 7.7548 (1.5); 7.7426 (1.3); 7.7363 (1.3); 7.5185 (0.6); 7.3671 (0.9); 7.3476 (1.2); 7.3431 (1.1); 7.3303 (1.0); 7.3259 (1.2); 7.3062 (0.9); 7.2596 (106.1); 7.0024 (1.8); 6.9957 (2.3); 6.9823 (1.7); 6.9810 (1.7); 6.9749 (1.8); 6.9469 (0.8); 6.9298 (0.9); 6.9233 (1.7); 6.9061 (1.6); 6.8997 (0.9); 6.8825 (0.8); 5.2982 (5.6); 4.9625 (16.0); 4.9571 (2.6); 4.8874 (4.5); 3.8607 (0.7); 2.6567 (0.8); 2.5992 (0.8); 2.5857 (0.6); 2.5776 (0.6); 1.5763 (0.7); 0.0080 (1.9); −0.0002 (60.0); −0.00085 (2.1) VIII-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1928 (1.7); 8.1798 (1.8); 7.4319 (0.5); 7.4276 (0.6); 7.4127 (0.9); 7.4084 (1.2); 7.3937 (0.7); 7.3897 (1.0); 7.3869 (0.6); 7.3846 (0.7); 7.3829 (0.6); 7.3801 (0.5); 7.3784 (0.5); 7.3722 (0.7); 7.3678 (0.5); 7.3661 (0.5); 7.3639 (0.6); 7.3517 (0.5); 7.2607 (18.6); 7.2514 (0.9); 7.2497 (0.9); 7.2481 (0.9); 7.2287 (1.1); 7.2110 (0.5); 7.0758 (0.7); 7.0724 (0.8); 7.0701 (1.0); 7.0661 (1.3); 7.0622 (0.9); 7.0568 (1.1); 7.0525 (1.9); 7.0298 (0.7); 7.0268 (0.6); 6.8715 (1.3); 6.8683 (2.0); 6.8650 (1.3); 5.2983 (0.9); 4.9210 (8.8); 3.8052 (16.0); 1.5535 (1.1); −0.0002 (10.0) VI-004: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1758 (3.6); 8.6697 (5.4); 7.4668 (0.6); 7.4625 (0.6); 7.4475 (1.0); 7.4432 (1.1); 7.4287 (0.7); 7.4243 (0.7); 7.3749 (0.5); 7.3626 (0.6); 7.3581 (0.5); 7.3541 (0.5); 7.2605 (28.6); 7.2341 (1.0); 7.0619 (0.7); 7.0587 (0.7); 7.0411 (0.7); 7.0372 (1.1); 7.0335 (0.7); 7.0159 (0.6); 7.0126 (0.6); 4.9286 (8.7); 3.8098 (16.0); 1.5567 (1.2); −0.0002 (14.9); −0.00084 (0.5) VIII-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1926 (1.8); 8.1796 (1.8); 7.4321 (0.5); 7.4278 (0.6); 7.4128 (1.0); 7.4088 (1.3); 7.3940 (0.7); 7.3901 (1.0); 7.3868 (0.6); 7.3843 (0.7); 7.3799 (0.5); 7.3719 (0.6); 7.3660 (0.6); 7.3638 (0.6); 7.2621 (4.9); 7.2480 (0.8); 7.2287 (1.2); 7.2108 (0.5); 7.0755 (0.8); 7.0705 (1.1); 7.0662 (1.4); 7.0625 (1.0); 7.0531 (2.0); 7.0296 (0.7); 7.0265 (0.6); 6.8687 (2.0); 5.2980 (4.5); 4.9209 (9.3); 3.8046 (16.0); 1.5765 (1.1); −0.0002(4.0) VII-012: .sup.1H-NMR(600.4 MHz, d.sub.6-DMSO): δ = 8.1973 (3.2); 8.1933 (3.2); 7.9509 (1.0); 7.9467 (1.0); 7.9371 (1.7); 7.9335 (1.6); 7.9238 (1.1); 7.9197 (1.0); 7.5684 (1.0); 7.5658 (1.2); 7.5555 (2.1); 7.5528 (2.3); 7.5426 (1.2); 7.5399 (1.2); 7.5006 (0.6); 7.4979 (0.6); 7.4921 (0.7); 7.4879 (1.2); 7.4851 (1.2); 7.4793 (1.2); 7.4767 (1.2); 7.4714 (0.8); 7.4658 (0.8); 7.4631 (0.7); 7.3277 (1.7); 7.3148 (2.7); 7.3034 (2.5); 7.3019 (2.5); 7.2874 (3.6); 7.2840 (3.3); 7.2729 (2.6); 7.2698 (2.8); 5.7521 (1.7); 4.9322 (15.1); 4.8431 (0.6); 4.1869 (2.2); 4.1751 (7.0); 4.1632 (7.1); 4.1514 (2.3); 4.1228 (0.3); 3.3052 (127.1); 2.6151 (1.2); 2.6121 (1.7); 2.6091 (1.2); 2.6062 (0.6); 2.5211 (4.1); 2.5180 (5.2); 2.5149 (5.6); 2.5060 (98.8); 2.5031 (200.8); 2.5001 (271.8); 2.4970 (203.1); 2.4941 (100.6); 2.3870 (1.3); 2.3840 (1.7); 2.3810 (1.2); 1.2369 (0.4); 1.1998 (7.8); 1.1879 (16.0); 1.1761 (7.7); 1.1653 (0.4); 1.1534 (0.7); 1.1416 (0.4); 0.0052 (1.3); −0.0002 (31.9); −0.0057 (1.3) VI-004: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1767 (3.0); 8.6698 (6.8); 7.4489 (0.7); 7.4449 (0.8); 7.4259 (0.5); 7.2603 (21.4); 7.2362 (0.9); 7.0378 (0.8); 4.9296 (6.4); 3.8109 (10.5); 2.0447 (1.4); 1.5401 (16.0); 1.2772 (0.6); 1.2593 (1.1); 0.8821 (0.9); 0.0078 (1.2); −0.0002 (26.5); −0.00079 (0.8) VI-007: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.2020 (5.1); 8.7056 (7.6); 7.4740 (1.0); 7.4697 (1.1); 7.4546 (1.9); 7.4506 (2.0); 7.4357 (1.2); 7.4315 (1.3); 7.4016 (0.5); 7.3973 (0.6); 7.3893 (0.6); 7.3827 (1.0); 7.3784 (1.0); 7.3702 (1.0); 7.3659 (1.0); 7.3622 (1.0); 7.3576 (0.8); 7.3497 (0.8); 7.3454 (0.7); 7.2610 (23.3); 7.2388 (2.1); 7.2211 (0.9); 7.0642 (1.3); 7.0611 (1.3); 7.0433 (1.3); 7.0396 (2.1); 7.0359 (1.4); 7.0181 (1.1); 7.0151 (1.1); 4.9785 (16.0); 3.7772 (0.8); 3.7666 (0.8); 3.7605 (2.0); 3.7545 (0.8); 3.7440 (0.9); 1.8765 (0.8); 1.8684 (0.8); 1.8600 (2.3); 1.8513 (0.8); 1.8434 (0.8); 1.4320 (0.7); 0.0079 (1.2); −0.0002 (26.8); −0.00084 (1.0) VII-003: .sup.1H-NMR(600.4 MHz, d.sub.6-DMSO): δ = 13.0358 (0.6); 8.1959 (6.6); 8.1926 (5.8); 7.9519 (2.1); 7.9477 (2.2); 7.9381 (3.6); 7.9343 (3.5); 7.9249 (2.3); 7.9207 (2.2); 7.5830 (1.6); 7.5804 (1.8); 7.5701 (3.5); 7.5675 (3.6); 7.5631 (1.9); 7.5602 (2.0); 7.5572 (2.2); 7.5545 (2.1); 7.5502 (1.1); 7.5475 (1.0); 7.5010 (1.3); 7.4985 (1.4); 7.4927 (1.5); 7.4884 (2.6); 7.4859 (2.6); 7.4774 (2.6); 7.4665 (1.7); 7.4642 (1.4); 7.3298 (3.4); 7.3170 (5.6); 7.3040 (3.7); 7.2993 (2.7); 7.2874 (5.9); 7.2836 (7.4); 7.2734 (4.9); 7.2690 (5.4); 5.7520 (10.0); 4.9574 (8.4); 4.8674 (0.4); 4.8263 (11.5); 4.7841 (0.4); 4.7371 (0.5); 3.8434 (1.0); 3.6996 (16.0); 3.6851 (0.4); 3.6606 (0.7); 3.3055 (116.8); 3.1727 (0.5); 3.1648 (0.5); 2.6151 (2.8); 2.6121 (3.8); 2.6091 (2.8); 2.5984 (0.3); 2.5211 (10.1); 2.5180 (13.9); 2.5148 (17.2); 2.5060 (233.1); 2.5031 (462.2); 2.5001 (624.6); 2.4971 (470.2); 2.4942 (237.8); 2.3899 (1.4); 2.3870 (2.8); 2.3840 (3.8); 2.3811 (2.8); 2.2915 (0.3); 1.9077 (0.7); 1.2364 (1.1); 0.0051 (3.3); −0.0002 (68.1); −0.00056 (3.0) VII-123-a: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1022 (1.2); 8.0960 (1.2); 7.7606 (0.6); 7.7543 (0.6); 7.7418 (0.7); 7.7394 (0.8); 7.7355 (0.7); 7.7331 (0.7); 7.7206 (0.6); 7.7143 (0.6); 7.3865 (0.6); 7.3716 (0.8); 7.3673 (1.0); 7.3528 (0.6); 7.3481 (0.8); 7.3404 (0.5); 7.3281 (0.5); 7.2614 (16.3); 7.2124 (0.6); 7.2107 (0.6); 7.1912 (0.9); 7.0412 (0.6); 7.0379 (0.6); 7.0203 (0.6); 7.0165 (1.0); 7.0127 (0.6); 6.9952 (0.5); 6.9920 (0.5); 6.9385 (0.8); 6.9373 (0.8); 6.9311 (0.8); 6.9299 (0.8); 6.9174 (0.8); 6.9160 (0.8); 6.9099 (0.8); 6.9086 (0.8); 5.2312 (1.6); 5.2138 (1.6); 3.7764 (16.0); 1.6951 (6.6); 1.6776 (6.5); −0.0002 (9.9) VII-038: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.0970 (0.6); 8.0951 (1.0); 8.0930 (0.8); 8.0909 (0.8); 8.0888 (1.0); 8.0868 (0.7); 7.7540 (0.6); 7.7477 (0.6); 7.7352 (0.6); 7.7327 (0.7); 7.7290 (0.6); 7.7264 (0.7); 7.7140 (0.6); 7.7077 (0.6); 7.3803 (0.7); 7.3759 (0.9); 7.3617 (0.7); 7.3572 (0.6); 7.2610 (48.0); 7.2202 (0.5); 7.2184 (0.6); 7.2170 (0.5); 7.2009 (0.7); 7.1990 (0.8); 7.0492 (0.5); 7.0459 (0.5); 7.0245 (0.8); 7.0207 (0.5); 6.9425 (0.7); 6.9408 (0.8); 6.9350 (0.8); 6.9333 (0.8); 6.9212 (0.7); 6.9196 (0.7); 6.9137 (0.7); 6.9121 (0.7); 6.4172 (0.7); 5.2352 (1.4); 5.2178 (1.5); 3.9793 (2.4); 3.9293 (3.0); 3.7786 (16.0); 2.5560 (2.4); 2.5461 (1.5); 1.6970 (6.2); 1.6796 (6.2); 1.5468 (1.7); 1.2844 (0.5); 1.2548 (0.6); 0.0080 (0.8); −0.0002 (29.0); −0.00084 (0.9) VI-011: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1701 (3.8); 8.6612 (9.1); 7.4283 (0.5); 7.4134 (0.8); 7.4091 (0.9); 7.3946 (0.6); 7.3902 (0.6); 7.2621 (18.0); 7.2419 (0.6); 7.2400 (0.6); 7.2204 (0.9); 7.0534 (0.6); 7.0502 (0.6); 7.0326 (0.6); 7.0287 (0.9); 7.0249 (0.6); 7.0073 (0.5); 5.2346 (1.5); 5.2172 (1.6); 3.7804 (16.0); 1.7019 (6.4); 1.6845 (6.3); 1.5722 (3.3); 1.2643 (0.8); 0.8818 (1.5); 0.8641 (0.6); −0.0002 (10.4) VI-008: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1700 (4.0); 8.6613 (9.7); 7.4286 (0.5); 7.4136 (0.8); 7.4094 (0.9); 7.3948 (0.6); 7.3904 (0.6); 7.2634 (10.8); 7.2418 (0.6); 7.2400 (0.6); 7.2205 (0.9); 7.0534 (0.6); 7.0502 (0.6); 7.0326 (0.6); 7.0287 (0.9); 7.0249 (0.6); 7.0073 (0.5); 5.2998 (1.2); 5.2347 (1.5); 5.2173 (1.6); 3.7802 (16.0); 1.7018 (6.3); 1.6844 (6.3); 1.5952 (1.9); −0.0002 (6.2) IV-001: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.2187 (2.6); 9.2157 (2.7); 9.2054 (2.7); 9.2023 (2.7); 9.0675 (2.5); 9.0644 (2.7); 9.0616 (2.8); 9.0585 (2.4); 7.4826 (0.9); 7.4782 (1.0); 7.4633 (1.6); 7.4590 (1.8); 7.4516 (2.8); 7.4455 (3.3); 7.4383 (3.1); 7.4323 (2.7); 7.4182 (0.5); 7.4138 (0.5); 7.4059 (0.6); 7.3992 (0.9); 7.3948 (0.8); 7.3869 (0.9); 7.3825 (0.8); 7.3807 (0.8); 7.3786 (0.9); 7.3740 (0.7); 7.3663 (0.8); 7.3618 (0.6); 7.2755 (1.2); 7.2627 (11.7); 7.2384 (0.8); 7.0682 (1.2); 7.0650 (1.1); 7.0473 (1.1); 7.0435 (1.8); 7.0397 (1.2); 7.0222 (1.0); 7.0189 (1.0); 5.3000 (2.2); 4.9087 (16.0); 4.2997 (2.0); 4.2819 (6.2); 4.2640 (6.3); 4.2462 (2.1); 1.3106 (7.4); 1.2928 (15.2); 1.2750 (7.3); −0.0002 (15.3); −0.00085 (0.5) VI-012: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.1872 (8.6); 8.6773 (16.0); 7.4584 (1.2); 7.4541 (1.4); 7.4391 (2.3); 7.4348 (2.4); 7.4202 (1.5); 7.4159 (1.6); 7.3839 (0.8); 7.3795 (0.7); 7.3717 (0.8); 7.3650 (1.2); 7.3606 (1.1); 7.3527 (1.3); 7.3484 (1.2); 7.3444 (1.2); 7.3399 (0.9); 7.3321 (1.0); 7.3277 (0.9); 7.2602 (50.1); 7.2495 (0.8); 7.2392 (1.7); 7.2196 (2.5); 7.2006 (1.7); 7.1876 (0.9); 7.1813 (0.9); 7.1687 (0.6); 7.1577 (1.4); 7.1499 (0.9); 7.1296 (0.6); 7.1088 (0.6); 7.0840 (2.3); 7.0498 (1.6); 7.0465 (1.5); 7.0289 (1.6); 7.0250 (2.5); 7.0212 (1.6); 7.0037 (1.5); 7.0005 (1.4); 5.3209 (1.1); 5.3035 (4.4); 5.2860 (4.4); 5.2684 (1.2); 3.9880 (1.4); 3.9421 (1.8); 2.3115 (3.3); 2.2419 (3.2); 1.7562 (15.0); 1.7387 (14.8); 1.7255 (0.7); 1.7084 (0.6); 1.7006 (0.5); 0.0080 (2.1); −0.0002 (65.4); −0.00085 (1.9) III-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.7084 (9.5); 8.6962 (9.7); 7.5202 (1.0); 7.5158 (1.0); 7.5008 (1.8); 7.4965 (1.8); 7.4818 (1.1); 7.4773 (1.1); 7.3175 (0.5); 7.3128 (0.6); 7.3107 (0.9); 7.3062 (0.8); 7.2986 (0.9); 7.2941 (0.9); 7.2902 (0.9); 7.2856 (0.8); 7.2782 (0.8); 7.2736 (0.8); 7.2612 (11.9); 7.2277 (1.2); 7.2253 (1.3); 7.2132 (2.8); 7.2089 (1.8); 7.2058 (2.0); 7.2010 (5.2); 7.1888 (3.2); 7.0058 (1.2); 7.0024 (1.2); 6.9851 (1.1); 6.9803 (1.4); 6.9764 (1.2); 6.9593 (1.0); 6.9558 (1.0); 5.2992 (2.3); 4.9201 (16.0); 4.2930 (2.0); 4.2751 (6.2); 4.2573 (6.4); 4.2395 (2.1); 1.5582 (4.8); 1.3019 (7.5); 1.2840 (15.2); 1.2662 (7.3); 0.0080 (0.6); −0.0002 (15.9); −0.00085 (0.5) III-005: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.7074 (5.3); 8.6952 (5.3); 7.4919 (0.6); 7.4874 (0.6); 7.4725 (1.2); 7.4682 (1.2); 7.4535 (0.7); 7.4490 (0.7); 7.2982 (0.6); 7.2938 (0.6); 7.2861 (0.6); 7.2817 (0.6); 7.2779 (0.6); 7.2732 (0.6); 7.2619 (4.6); 7.2113 (1.9); 7.1988 (3.7); 7.1866 (1.5); 7.1776 (0.5); 6.9954 (0.7); 6.9921 (0.7); 6.9747 (0.8); 6.9698 (1.0); 6.9660 (0.8); 6.9488 (0.6); 6.9455 (0.6); 5.2990 (2.3); 5.2782 (0.5); 5.2608 (1.7); 5.2434 (1.7); 5.2260 (0.5); 3.7666 (16.0); 1.7001 (7.0); 1.6827 (6.9); 1.5708 (1.7); −0.0002 (5.8) IV-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 9.2346 (1.5); 9.2240 (1.6); 9.0730 (2.3); 7.5189 (1.3); 7.5004 (0.9); 7.4960 (0.8); 7.4770 (2.9); 7.4709 (1.8); 7.4629 (2.3); 7.4576 (2.3); 7.4124 (0.9); 7.4001 (0.8); 7.2886 (1.0); 7.2600 (230.4); 7.0755 (0.9); 7.0510 (1.6); 7.0264 (0.8); 6.9960 (1.0); 4.9934 (16.0); 4.9092 (1.9); 4.2823 (0.7); 4.2646 (0.7); 1.7043 (0.6); 1.3109(1.1); 1.2932 (2.0); 1.2753 (1.0); 0.1460 (1.0); 0.0080 (8.2); −0.0002 (305.3); −0.00085 (8.9); −0.1496 (1.0) III-003: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.7204 (14.6); 8.7081 (14.7); 7.5187 (1.6); 7.5138 (1.3); 7.4989 (2.3); 7.4945 (2.4); 7.4799 (1.4); 7.4754 (1.4); 7.3262 (0.6); 7.3218 (0.7); 7.3142 (0.7); 7.3074 (1.2); 7.3030 (1.1); 7.2953 (1.2); 7.2909 (1.2); 7.2868 (1.2); 7.2824 (1.1); 7.2748 (1.4); 7.2704 (1.5); 7.2601 (102.9); 7.2285 (4.0); 7.2163 (8.5); 7.2040 (3.8); 7.1985 (2.2); 7.1786 (1.0); 6.9998 (1.5); 6.9962 (1.9); 6.9792 (1.5); 6.9743 (1.8); 6.9704 (1.5); 6.9533 (1.3); 6.9497 (1.2); 5.3399 (1.1); 5.3225 (4.6); 5.3050 (4.6); 5.2877 (1.2); 1.7547 (16.0); 1.7372 (15.9); 0.0080 (4.5); −0.0002 (140.3); −0.00085 (3.8) IV-003: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.3232 (2.4); 9.3201 (2.5); 9.3098 (2.6); 9.3066 (2.6); 8.9834 (2.3); 8.9803 (2.5); 8.9774 (2.5); 8.9743 (2.2); 7.5749 (2.7); 7.5688 (2.7); 7.5615 (2.7); 7.5554 (2.7); 7.5289 (0.6); 7.5248 (0.9); 7.5145 (0.6); 7.5101 (1.4); 7.5057 (1.7); 7.5021 (0.9); 7.4976 (0.6); 7.4953 (1.0); 7.4937 (0.9); 7.4909 (1.2); 7.4877 (1.4); 7.4826 (1.2); 7.4770 (0.7); 7.4747 (0.8); 7.4703 (0.6); 7.4623 (0.8); 7.4579 (0.5); 7.3438 (0.8); 7.3421 (0.9); 7.3406 (1.0); 7.3391 (0.9); 7.3245 (1.2); 7.3227 (1.4); 7.3211 (1.4); 7.3052 (0.6); 7.3033 (0.7); 7.2612 (48.2); 7.1370 (0.9); 7.1336 (0.9); 7.1161 (0.9); 7.1126 (1.5); 7.1093 (1.0); 7.0911 (0.8); 7.0878 (0.9); 5.3003 (6.8); 5.0012 (0.6); 4.9176 (13.4); 4.8635 (0.5); 4.3037 (1.8); 4.2859 (5.7); 4.2680 (5.9); 4.2502 (2.0); 2.3118 (0.6); 1.5557 (4.7); 1.3175 (0.9); 1.3137 (7.6); 1.2995 (0.8); 1.2959 (16.0); 1.2780 (7.7); 0.0080 (1.4); −0.0002 (52.1); −0.00050 (1.1); −0.00067 (0.7); −0.00084 (1.8) V-003: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 7.6633 (4.1); 7.6462 (4.3); 7.5423 (0.8); 7.5379 (0.9); 7.5229 (1.6); 7.5186 (1.6); 7.5039 (1.0); 7.4994 (1.0); 7.4015 (1.1); 7.3346 (0.6); 7.3325 (0.8); 7.3280 (0.7); 7.3203 (0.8); 7.3157 (0.8); 7.3120 (0.8); 7.3074 (0.7); 7.2998 (0.8); 7.2952 (0.7); 7.2613 (47.5); 7.2478 (1.0); 7.2453 (1.1); 7.2290 (1.5); 7.2258 (1.5); 7.2091 (0.6); 7.2068 (0.6); 7.0659 (1.1); 7.0626 (1.0); 7.0453 (1.0); 7.0401 (1.2); 7.0364 (1.0); 7.0192 (0.9); 7.0158 (0.8); 6.8462 (4.7); 6.8292 (4.6); 5.3594 (0.8); 4.8947 (14.0); 4.5902 (11.8); 4.2801 (2.0); 4.2698 (2.0); 4.2623 (6.1); 4.2519 (6.0); 4.2444 (6.2); 4.2340 (6.0); 4.2266 (2.1); 4.2161 (1.9); 1.3330 (1.1); 1.3003 (7.4); 1.2931 (7.8); 1.2824 (15.5); 1.2753 (16.0); 1.2699 (1.3); 1.2645 (7.4); 1.2574 (8.6); 0.0080 (1.0); −0.0002 (35.6); −0.00085 (1.1) X-001: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1305 (2.3); 8.1244 (2.3); 7.7600 (1.3); 7.7538 (1.3); 7.7413 (1.6); 7.7388 (1.6); 7.7351 (1.6); 7.7325 (1.5); 7.7202 (1.4); 7.7139 (1.3); 7.4636 (1.1); 7.4592 (1.2); 7.4442 (1.9); 7.4400 (2.0); 7.4255 (1.3); 7.4211 (1.4); 7.3989 (0.6); 7.3945 (0.7); 7.3866 (0.7); 7.3820 (0.9); 7.3800 (1.1); 7.3781 (1.0); 7.3756 (1.0); 7.3737 (0.8); 7.3677 (1.2); 7.3659 (0.9); 7.3633 (1.0); 7.3613 (1.0); 7.3593 (1.0); 7.3548 (0.9); 7.3471 (1.0); 7.3426 (0.8); 7.2613 (68.3); 7.2577 (2.1); 7.2562 (1.7); 7.2395 (1.8); 7.2329 (0.8); 7.2206 (0.9); 7.2189 (1.0); 7.2173 (0.9); 7.0648 (1.4); 7.0617 (1.3); 7.0440 (1.3); 7.0402 (2.1); 7.0365 (1.3); 7.0189 (1.2); 7.0157 (1.1); 6.9558 (1.6); 6.9483 (1.7); 6.9346 (1.6); 6.9271 (1.6); 6.6563 (0.6); 5.9493 (0.6); 5.9357 (1.3); 5.9235 (0.9); 5.9221 (0.7); 5.9099 (1.5); 5.9064 (0.8); 5.8963 (0.7); 5.8928 (1.5); 5.8806 (1.0); 5.8792 (0.8); 5.8671 (1.6); 5.8534 (0.8); 5.2795 (0.9); 5.2752 (2.1); 5.2720 (2.3); 5.2677 (0.9); 5.2366 (0.8); 5.2323 (1.8); 5.2292 (2.0); 5.2248 (0.8); 5.1968 (1.0); 5.1932 (2.4); 5.1899 (2.3); 5.1863 (0.9); 5.1711 (0.9); 5.1675 (2.2); 5.1642 (2.2); 5.1606 (0.9); 4.8586 (16.0); 4.7735 (0.5); 4.0397 (1.2); 4.0358 (2.2); 4.0318 (1.3); 4.0217 (3.8); 4.0180 (2.1); 4.0113 (1.3); 4.0073 (2.1); 4.0033 (1.1); 1.3333 (0.5); 1.2845 (0.7); 1.2548 (0.9); 0.0080 (1.5); −0.0002 (53.8); −0.00085 (1.4) VII-006: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.0897 (2.2); 8.0834 (2.2); 7.7569 (1.1); 7.7506 (1.1); 7.7381 (1.3); 7.7356 (1.4); 7.7318 (1.2); 7.7294 (1.3); 7.7169 (1.2); 7.7106 (1.1); 7.3684 (0.5); 7.3639 (0.7); 7.3564 (1.0); 7.3515 (1.8); 7.3497 (2.0); 7.3432 (2.4); 7.3397 (2.2); 7.3357 (3.4); 7.3326 (4.7); 7.3247 (3.8); 7.3218 (2.2); 7.3169 (9.1); 7.3141 (4.5); 7.3101 (4.8); 7.3057 (3.3); 7.3003 (3.5); 7.2981 (2.0); 7.2938 (1.2); 7.2599 (34.4); 7.2087 (1.2); 7.2068 (1.2); 7.1901 (1.6); 7.1886 (1.7); 7.1701 (0.7); 7.0393 (1.1); 7.0361 (1.0); 7.0185 (1.0); 7.0146 (1.7); 7.0109 (1.1); 6.9933 (1.0); 6.9903 (0.9); 6.9434 (1.5); 6.9420 (1.6); 6.9360 (1.5); 6.9346 (1.5); 6.9222 (1.4); 6.9208 (1.5); 6.9147 (1.4); 6.9133 (1.4); 5.2488 (12.6); 4.9564 (16.0); 4.8824 (0.6); 1.5459 (7.1); 1.4321 (0.9); 1.2844 (0.6); 1.2553 (1.4); 0.0080 (1.4); −0.0002 (47.2); −0.00085 (1.3) I-001: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.9579 (1.9); 8.9541 (1.9); 8.5086 (1.8); 8.5024 (2.0); 8.4138 (1.4); 8.4099 (1.5); 8.4076 (1.4); 8.4036 (1.2); 7.4746 (0.5); 7.4596 (0.9); 7.4553 (0.9); 7.4406 (0.6); 7.4362 (0.6); 7.2784 (0.5); 7.2597 (32.1); 7.2172 (0.7); 7.1974 (0.9); 6.9898 (0.6); 6.9865 (0.6); 6.9691 (0.6); 6.9644 (0.7); 6.9606 (0.6); 6.9432 (0.5); 5.2990 (0.7); 5.2554 (1.5); 5.2380 (1.5); 3.7950 (4.3); 3.7747 (16.0); 3.7679 (0.5); 3.7377 (1.7); 2.7544 (2.1); 1.7080 (2.4); 1.7032 (6.4); 1.6905 (2.5); 1.6858 (6.4); 1.5824 (0.9); 1.5642 (1.0); 1.5401 (1.3); 0.0080 (1.1); −0.0002 (41.6); −0.00085 (1.2) I-004: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.9676 (3.9); 8.9638 (3.8); 8.5126 (3.7); 8.5063 (4.0); 8.4160 (2.8); 8.4121 (2.9); 8.4097 (2.6); 8.4058 (2.3); 7.5094 (1.0); 7.5049 (1.0); 7.4900 (1.7); 7.4857 (1.7); 7.4710 (1.1); 7.4665 (1.1); 7.3409 (0.5); 7.3364 (0.6); 7.3288 (0.6); 7.3221 (0.9); 7.3175 (0.8); 7.3099 (0.9); 7.3054 (0.9); 7.3014 (0.9); 7.2970 (0.8); 7.2893 (0.9); 7.2848 (0.9); 7.2596 (66.1); 7.2309 (1.0); 7.2286 (1.1); 7.2121 (1.6); 7.1923 (0.7); 6.9982 (1.1); 6.9951 (1.3); 6.9775 (1.0); 6.9729 (1.4); 6.9690 (1.1); 6.9518 (0.9); 6.9484 (0.9); 5.2989 (1.4); 4.9193 (15.7); 4.2984 (2.0); 4.2805 (6.2); 4.2627 (6.4); 4.2539 (1.9); 4.2448 (2.2); 4.2315 (1.0); 4.2229 (0.9); 4.2049 (0.8); 3.8281 (0.5); 2.8026 (4.5); 1.5397 (3.3); 1.3083 (8.1); 1.3014 (1.5); 1.2905 (16.0); 1.2835 (2.7); 1.2727 (7.7); 1.2656 (1.5); 0.0080 (2.5); −0.0002 (87.0); −0.00085 (2.4) III-001: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.5636 (8.8); 8.4513 (1.6); 7.4864 (0.7); 7.4821 (0.6); 7.4671 (1.0); 7.4628 (1.0); 7.4481 (0.6); 7.4436 (0.6); 7.3140 (0.6); 7.3095 (0.5); 7.3019 (0.5); 7.2623 (7.1); 7.2290 (0.6); 7.2258 (0.7); 7.2104 (0.9); 7.2071 (0.9); 7.0079 (0.6); 7.0045 (0.6); 6.9873 (0.6); 6.9821 (0.8); 6.9783 (0.7); 6.9612 (0.6); 6.9577 (0.5); 6.6254 (1.0); 5.3013 (3.7); 5.2537 (1.6); 5.2363 (1.6); 3.7727 (3.9); 3.7694 (16.0); 1.7008 (6.5); 1.6834 (6.4); 1.6527 (1.3); 1.6354 (1.3); 1.5623 (1.2); −0.0002 (9.5) I-002: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.9713 (4.9); 8.9678 (4.9); 8.5315 (4.0); 8.5252 (4.7); 8.4708 (3.0); 8.4669 (3.4); 8.4609 (2.5); 7.5189 (0.5); 7.5020 (1.4); 7.4976 (1.5); 7.4825 (2.5); 7.4782 (2.6); 7.4635 (1.6); 7.4591 (1.6); 7.3294 (0.7); 7.3250 (0.8); 7.3172 (0.9); 7.3105 (1.4); 7.3062 (1.4); 7.2984 (1.5); 7.2899 (1.4); 7.2854 (1.3); 7.2778 (1.4); 7.2733 (1.5); 7.2600 (93.1); 7.2419 (0.6); 7.2253 (1.0); 7.2146 (2.3); 7.1953 (2.9); 7.1784 (1.5); 6.9960 (0.7); 6.9840 (1.6); 6.9809 (1.7); 6.9634 (1.6); 6.9587 (2.1); 6.9550 (1.7); 6.9375 (1.4); 6.9342 (1.4); 5.3351 (1.2); 5.3176 (4.8); 5.3001 (4.8); 5.2827 (1.2); 4.1489 (1.6); 2.1033 (0.5); 1.7562 (16.0); 1.7387 (15.9); 1.6251 (0.8); 1.5943 (4.9); 1.5785 (0.5); 1.3324 (0.6); 1.2841 (0.9); 1.2745 (0.7); 1.2551 (2.4); 1.2221 (0.8); 1.2180 (0.6); 1.1303 (2.2); 1.1093 (4.9); 1.0918 (2.9); 1.0520 (3.6); 0.0693 (4.0); 0.0080 (2.9); −0.0002 (93.4); −0.00085 (2.6) I-003: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.9694 (2.2); 8.5279 (1.8); 8.5220 (2.0); 8.4307 (1.6); 7.5216 (1.1); 7.5183 (2.1); 7.5028 (1.5); 7.4879 (1.0); 7.4837 (1.0); 7.3230 (0.9); 7.2594 (375.5); 7.2449 (1.3); 7.2211 (1.6); 7.2027 (0.9); 7.0088 (1.0); 6.9955 (2.1); 6.9837 (1.2); 6.9625 (0.8); 5.0007 (16.0); 1.8963 (1.1); 0.1459 (1.4); 0.0688 (2.2); 0.0080 (11.1); −0.0002 (373.0); −0.00085 (10.7); −0.1495 (1.2) III-006: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.5633 (15.6); 8.4520 (2.6); 7.4223 (1.3); 7.4186 (1.2); 7.4032 (2.3); 7.3993 (2.1); 7.3839 (1.4); 7.3799 (1.3); 7.3543 (3.3); 7.3407 (3.9); 7.3260 (6.3); 7.3161 (6.4); 7.3109 (8.8); 7.3024 (6.7); 7.2931 (3.9); 7.2598 (49.3); 7.2145 (1.9); 7.1961 (2.6); 7.1772 (1.0); 7.0097 (1.4); 6.9849 (1.9); 6.9630 (1.2); 6.6624 (1.3); 5.2990 (4.2); 5.2497 (16.0); 5.1926 (1.7); 4.9711 (15.0); 4.9170 (2.6); 4.2859 (1.8); 1.5457 (5.4); 1.2565 (2.7); −0.0002 (33.9) V-002: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.5201 (4.9); 8.5173 (4.8); 7.5071 (0.9); 7.5026 (0.9); 7.4878 (1.6); 7.4834 (1.7); 7.4687 (1.0); 7.4643 (1.0); 7.3322 (0.6); 7.3300 (0.8); 7.3255 (0.7); 7.3179 (0.8); 7.3134 (0.8); 7.3095 (0.8); 7.3050 (0.7); 7.2975 (0.8); 7.2930 (0.7); 7.2602 (62.6); 7.2317 (1.4); 7.2119 (1.6); 7.1949 (0.7); 7.1356 (5.3); 7.1328 (5.3); 7.0282 (1.0); 7.0249 (1.0); 7.0076 (1.0); 7.0032 (1.4); 6.9991 (1.1); 6.9819 (0.9); 6.9785 (0.9); 6.4011 (0.8); 5.3000 (1.4); 4.9015 (15.1); 4.8521 (1.1); 4.4659 (1.8); 4.4482 (6.1); 4.4305 (6.2); 4.4128 (1.9); 4.4074 (0.5); 4.2881 (1.9); 4.2772 (0.6); 4.2702 (6.2); 4.2594 (0.7); 4.2524 (6.4); 4.2344 (2.5); 4.2330 (2.4); 3.8297 (3.3); 1.5394 (14.2); 1.4409 (6.4); 1.4232 (13.9); 1.4055 (6.2); 1.3977 (0.6); 1.3800 (1.1); 1.3623 (0.5); 1.3241 (1.3); 1.3113 (0.5); 1.3062 (3.2); 1.2999 (7.8); 1.2934 (1.2); 1.2882 (2.6); 1.2821 (16.0); 1.2756 (0.8); 1.2701 (0.9); 1.2643 (7.7); 1.2538 (0.8); 0.0079 (2.7); −0.0002 (101.4); −0.00085 (2.9); −0.0284 (0.7) V-005: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.0097 (2.0); 9.0062 (2.0); 8.8261 (2.2); 8.8131 (2.2); 7.7661 (1.4); 7.7625 (1.4); 7.7530 (1.4); 7.7494 (1.4); 7.6977 (0.6); 7.6805 (0.7); 7.6768 (0.6); 7.6678 (0.6); 7.6506 (0.7); 7.6469 (0.6); 7.4915 (0.6); 7.4867 (0.5); 7.4766 (1.0); 7.4720 (1.2); 7.4677 (0.8); 7.4637 (0.6); 7.4602 (0.8); 7.4578 (0.7); 7.4534 (0.7); 7.2607 (19.0); 7.2432 (0.6); 7.2410 (0.7); 7.2215 (1.0); 7.0110 (0.6); 7.0077 (0.6); 6.9904 (0.5); 6.9855 (0.7); 6.9818 (0.6); 6.9645 (0.5); 6.9611 (0.5); 5.2997 (1.9); 5.2501 (1.5); 5.2327 (1.5); 3.7955 (1.1); 3.7691 (16.0); 1.7084 (0.6); 1.6984 (6.4); 1.6911 (0.8); 1.6810(6.4); 1.5641 (0.6); 0.0080 (0.7); −0.0002 (26.0); −0.00085 (0.8) V-001: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.0117 (3.7); 9.0083 (3.7); 8.8317 (3.8); 8.8186 (4.0); 7.7764 (2.6); 7.7728 (2.7); 7.7634 (2.6); 7.7597 (2.7); 7.7010 (0.6); 7.6978 (0.8); 7.6806 (1.0); 7.6769 (0.9); 7.6711 (0.6); 7.6678 (0.8); 7.6506 (1.0); 7.6470 (0.9); 7.5513 (0.6); 7.5469 (0.6); 7.5325 (0.6); 7.5288 (0.6); 7.5254 (1.1); 7.5211 (1.0); 7.5061 (1.6); 7.5018 (1.7); 7.4870 (1.7); 7.4828 (1.5); 7.4795 (0.8); 7.4712 (0.6); 7.4678 (1.0); 7.4638 (0.8); 7.4605 (1.0); 7.3662 (0.6); 7.3618 (0.6); 7.3541 (0.6); 7.3494 (0.7); 7.3474 (0.9); 7.3430 (0.9); 7.3352 (1.0); 7.3307 (0.9); 7.3269 (1.0); 7.3223 (0.8); 7.3148 (0.9); 7.3102 (0.8); 7.2606 (50.3); 7.2565 (1.8); 7.2542 (1.6); 7.2525 (1.5); 7.2327 (2.0); 7.2157 (0.9); 7.2122 (1.0); 7.0194 (1.1); 7.0161 (1.1); 6.9987 (1.1); 6.9941 (1.4); 6.9902 (1.2); 6.9730 (1.2); 6.9696 (1.0); 5.3000 (6.4); 5.0533 (0.9); 4.9144 (15.7); 4.8358 (0.7); 4.7153 (0.9); 4.2935 (2.0); 4.2757 (6.2); 4.2579 (6.6); 4.2401 (2.3); 4.2326 (1.2); 4.2257 (0.6); 2.8043 (1.5); 1.5543 (2.8); 1.3110 (1.0); 1.3083 (1.2); 1.3043 (7.8); 1.2982 (0.8); 1.2932 (1.8); 1.2865 (16.0); 1.2754 (1.1); 1.2687 (7.7); 1.2638 (1.4); 1.2542 (1.3); 1.2460 (0.6); 0.0080 (1.7); −0.0002 (69.8); −0.00085 (2.4); −0.0282 (0.6) V-004: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.0251 (2.8); 9.0218 (2.9); 8.8497 (1.3); 8.8366 (1.4); 7.7826 (2.0); 7.7791 (2.0); 7.7695 (2.0); 7.7659 (2.0); 7.5413 (0.8); 7.5370 (0.9); 7.5220 (1.5); 7.5178 (1.7); 7.5030 (1.0); 7.4986 (1.0); 7.3547 (0.8); 7.3502 (0.7); 7.3425 (0.8); 7.3380 (0.8); 7.3341 (0.8); 7.3296 (0.7); 7.3219 (0.7); 7.3175 (0.6); 7.2603 (67.2); 7.2380 (1.7); 7.2210 (0.8); 7.0229 (1.0); 7.0196 (1.0); 7.0022 (1.1); 6.9970 (1.6); 6.9937 (1.2); 6.9764 (1.0); 6.9730 (1.0); 4.9911 (16.0); 4.9658 (0.5); 4.9178 (0.8); 4.9112 (0.8); 1.2549 (0.6); 0.0691 (0.7); 0.0272 (0.6); 0.0080 (2.4); −0.0002 (92.1); −0.00085 (3.0) III-001: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.5602 (8.8); 8.4480 (0.6); 7.4832 (0.6); 7.4788 (0.5); 7.4639 (1.0); 7.4595 (1.0); 7.4448 (0.6); 7.4404 (0.6); 7.3123 (0.5); 7.2609 (6.9); 7.2257 (0.6); 7.2233 (0.7); 7.2070 (0.9); 7.2039 (1.0); 7.0072 (0.6); 7.0039 (0.6); 6.9866 (0.6); 6.9815 (0.8); 6.9777 (0.6); 6.9605 (0.5); 6.9571 (0.5); 5.2995 (1.0); 5.2538 (1.6); 5.2364 (1.6); 3.7678 (16.0); 1.6992 (6.5); 1.6818 (6.5); 1.5513 (1.6); −0.0002 (9.2) III-004: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.5613 (16.0); 8.4503 (1.0); 7.5115 (1.0); 7.5072 (1.0); 7.4922 (1.8); 7.4878 (1.9); 7.4731 (1.1); 7.4687 (1.1); 7.3431 (0.5); 7.3386 (0.5); 7.3310 (0.5); 7.3242 (0.9); 7.3197 (0.8); 7.3120 (0.9); 7.3076 (0.9); 7.3037 (0.9); 7.2991 (0.7); 7.2916 (0.8); 7.2871 (0.7); 7.2612 (10.2); 7.2364 (1.1); 7.2341 (1.2); 7.2176 (1.7); 7.2146 (1.8); 7.1978 (0.7); 7.1958 (0.7); 7.0171 (1.1); 7.0137 (1.1); 6.9965 (1.1); 6.9915 (1.4); 6.9877 (1.2); 6.9705 (1.0); 6.9671 (1.0); 6.6674 (0.6); 5.2994 (1.9); 4.9162 (16.0); 4.8608 (1.1); 4.2930 (2.0); 4.2802 (0.6); 4.2751 (6.2); 4.2573 (6.3); 4.2394 (2.1); 4.2326 (1.2); 1.5558 (1.9); 1.3108 (0.6); 1.3075 (0.7); 1.3019 (7.5); 1.2929 (1.4); 1.2898 (1.4); 1.2840 (15.3); 1.2750 (0.8); 1.2720 (0.9); 1.2662 (7.3); −0.0002 (13.4) VIII-003: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1927 (2.4); 8.1797 (2.5); 7.4335 (0.6); 7.4291 (0.8); 7.4145 (1.2); 7.4101 (1.5); 7.4025 (0.6); 7.3956 (0.8); 7.3909 (1.3); 7.3858 (0.6); 7.3836 (0.8); 7.3818 (0.7); 7.3791 (0.6); 7.3774 (0.6); 7.3713 (0.8); 7.3669 (0.6); 7.3651 (0.6); 7.3629 (0.8); 7.3584 (0.6); 7.3507 (0.7); 7.3463 (0.6); 7.2728 (0.8); 7.2685 (1.1); 7.2598 (70.0); 7.2496 (2.0); 7.2319 (1.8); 7.2110 (0.7); 7.2094 (0.7); 7.1992 (0.6); 7.1877 (0.9); 7.1817 (1.0); 7.1690 (0.7); 7.1674 (0.7); 7.1580 (1.7); 7.1502 (1.1); 7.1452 (0.5); 7.1348 (0.6); 7.1297 (0.8); 7.1124 (0.6); 7.1090 (0.7); 7.0838 (2.6); 7.0737 (1.1); 7.0705 (2.1); 7.0664 (1.8); 7.0627 (1.4); 7.0575 (1.2); 7.0532 (2.5); 7.0495 (2.5); 7.0455 (1.1); 7.0278 (0.8); 7.0247 (0.8); 6.9962 (0.5); 6.8724 (1.5); 6.8691 (2.6); 6.8659 (1.6); 6.8643 (1.4); 4.9004 (14.2); 4.8356 (1.4); 4.2965 (1.8); 4.2787 (5.6); 4.2609 (5.7); 4.2431 (2.1); 3.9882 (1.6); 3.9423 (1.8); 2.3118 (3.6); 2.2421 (3.8); 1.5379 (16.0); 1.3076 (7.5); 1.2956 (0.6); 1.2898 (15.3); 1.2720 (8.1); 1.2542 (2.1); 1.2364 (0.8); 0.8820 (0.6); 0.0080 (2.3); −0.0002 (96.2); −0.00085 (3.0); −0.0280 (0.7) VIII-006: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.1861 (1.5); 8.1731 (1.5); 7.3921 (0.7); 7.3771 (1.1); 7.3740 (1.1); 7.3722 (1.2); 7.3584 (1.4); 7.3543 (0.8); 7.3523 (0.6); 7.2681 (0.6); 7.2602 (22.6); 7.2372 (0.6); 7.2338 (0.7); 7.2165 (1.0); 7.2147 (0.9); 7.1987 (0.6); 7.1580 (0.7); 7.0839 (1.2); 7.0673 (0.6); 7.0645 (0.5); 7.0609 (0.8); 7.0569 (1.1); 7.0530 (0.7); 7.0476 (1.1); 7.0434 (1.7); 7.0400 (1.2); 7.0212 (0.6); 6.8666 (1.0); 6.8634 (1.6); 6.8602 (1.0); 5.2997 (1.4); 5.2262 (1.5); 5.2088 (1.6); 3.9881 (0.7); 3.9422 (0.8); 3.7753 (16.0); 3.7382 (1.4); 3.7145 (0.6); 2.7559 (1.8); 2.3117 (1.6); 2.2420 (1.6); 1.6962 (6.4); 1.6788 (6.3); 1.5824 (0.8); 1.5642 (0.9); 1.5479 (2.5); 1.2543 (0.7); 0.0079 (0.8); −0.0002 (30.0); −0.00085 (0.9) VI-001: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.1753 (1.4); 8.6702 (3.5); 7.2626 (7.1); 5.3007 (1.1); 4.9081 (3.3); 4.2832 (1.3); 4.2654 (1.3); 2.9641 (16.0); 2.7740 (3.3); 1.5691 (1.7); 1.3122 (1.7); 1.2944 (3.5); 1.2766 (1.7); −0.0002 (9.6) VI-003: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.1767 (2.9); 8.6628 (6.4); 7.4762 (0.5); 7.4717 (0.6); 7.4568 (0.8); 7.4525 (0.8); 7.4336 (0.5); 7.2622 (13.5); 7.2431 (0.7); 7.2414 (0.7); 7.0449 (0.8); 7.0411 (0.5); 5.3004 (1.8); 4.9097 (7.2); 4.3034 (1.0); 4.2856 (3.0); 4.2677 (3.0); 4.2499 (1.0); 2.9220 (16.0); 2.7733 (5.8); 1.3136 (4.0); 1.2958 (8.3); 1.2780 (4.0); 1.2581 (0.7); 0.0022 (0.8); −0.0002 (17.3); −0.00026 (0.9); −0.00084 (0.6) VI-005: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.2205 (6.7); 8.8682 (0.7); 8.7213 (0.6); 8.6968 (11.2); 7.4636 (0.6); 7.4611 (1.8); 7.4459 (2.2); 7.4414 (3.2); 7.4368 (0.7); 7.4278 (1.6); 7.4255 (1.7); 7.4219 (1.7); 7.4177 (0.6); 7.4096 (0.9); 7.2860 (0.9); 7.2843 (1.0); 7.2828 (1.0); 7.2812 (0.9); 7.2678 (0.8); 7.2633 (15.2); 7.2473 (0.7); 7.2456 (0.7); 7.2442 (0.7); 7.2426 (0.6); 7.0825 (0.9); 7.0796 (0.8); 7.0769 (0.5); 7.0607 (1.0); 7.0578 (1.7); 7.0550 (1.1); 7.0362 (1.0); 7.0326 (0.7); 5.3008 (2.8); 5.0164 (0.6); 5.0054 (14.3); 4.3088 (1.9); 4.2910 (6.0); 4.2731 (6.1); 4.2553 (2.0); 2.9222 (2.8); 1.3165 (0.9); 1.3116(7.6); 1.3052(1.0); 1.2938(16.0); 1.2874 (0.8); 1.2760 (7.6); 1.2538 (0.6); 1.2359 (0.7); 0.0079 (0.5); −0.0002 (18.5); −0.00085 (0.5) VI-006: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.2464 (4.0); 8.7607 (0.5); 8.7448 (6.7); 7.4477 (0.6); 7.4436 (1.4); 7.4289 (1.1); 7.4246 (1.4); 7.4107 (0.7); 7.4096 (0.7); 7.4079 (0.7); 7.2896 (0.6); 7.2881 (0.6); 7.2867 (0.5); 7.2710 (0.9); 7.2700 (0.8); 7.2678 (0.8); 7.2661 (0.5); 7.2625 (8.3); 7.0849 (0.6); 7.0629 (0.7); 7.0596 (0.8); 7.0567 (0.5); 5.3143 (1.5); 5.3005 (6.3); 5.2968 (1.6); 3.7997 (1.2); 3.7926 (16.0); 3.7387 (0.6); 1.7712 (6.1); 1.7648 (0.7); 1.7537 (6.1); 0.1728 (0.5); 0.0944 (5.4); 0.0791 (1.7); 0.0770 (0.9); −0.0002 (10.8) VI-017: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 7.2641 (2.4); 3.7820 (1.0); 2.9235 (16.0); −0.0002 (3.1) VI-017: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.5682 (0.8); 7.2618 (6.2); 6.1762 (0.9); 3.7820 (2.6); 2.9225 (16.0); 1.6573 (1.0); 1.6399 (1.0); 1.5498 (0.7); −0.0002(8.1) VI-007: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.1867 (6.6); 8.6820 (14.1); 7.6936 (0.6); 7.6764 (0.7); 7.6728 (0.7); 7.6634 (0.6); 7.6462 (0.8); 7.6426 (0.7); 7.5202 (0.5); 7.4870 (0.5); 7.4797 (1.3); 7.4756 (1.0); 7.4680 (0.8); 7.4605 (2.0); 7.4562 (1.6); 7.4416 (1.1); 7.4372 (1.1); 7.3892 (0.5); 7.3826 (0.8); 7.3781 (0.7); 7.3702 (0.8); 7.3658 (0.7); 7.3619 (0.8); 7.3573 (0.6); 7.3495 (0.7); 7.3451 (0.6); 7.2666 (0.6); 7.2616 (90.5); 7.2394 (1.4); 7.2335 (0.8); 7.2205 (0.7); 7.0646 (1.0); 7.0613 (1.0); 7.0437 (0.9); 7.0399 (1.5); 7.0362 (1.0); 7.0186 (0.9); 7.0154 (0.8); 6.9980 (0.6); 4.9775 (16.0); 4.9101 (0.6); 4.9063 (0.6); 1.9555 (1.0); 1.4321 (0.8); 1.2222 (0.9); 0.0079 (3.2); −0.0002 (127.9); −0.00052 (1.9); −0.00060 (1.6); −0.00085 (3.8); −0.0117 (0.6); −0.0284 (1.0) VI-016: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.2235 (9.0); 8.7018 (13.3); 7.5206 (0.9); 7.4630 (1.0); 7.4582 (1.7); 7.4432 (3.2); 7.4406 (2.9); 7.4382 (2.7); 7.4326 (1.1); 7.4242 (3.9); 7.4207 (1.8); 7.4181 (1.4); 7.4136 (0.9); 7.4054 (1.2); 7.4010 (0.8); 7.2780 (1.7); 7.2621 (148.6); 7.2410 (1.0); 7.2340 (1.2); 7.0751 (1.3); 7.0513 (2.1); 7.0295 (1.2); 7.0262 (0.8); 6.9985 (0.8); 5.4007 (1.0); 5.3832 (4.4); 5.3656 (4.5); 5.3481 (1.1); 5.3406 (1.0); 5.3231 (0.9); 1.9551 (4.2); 1.8578 (2.4); 1.8218 (16.0); 1.8042 (15.8); 1.7908 (3.9); 1.7820 (1.8); 1.7733 (3.6); 1.7647 (1.6); 1.7457 (1.1); 1.7289 (0.9); 1.2222 (0.7); 0.1458 (0.6); 0.0080 (5.2); 0.0057 (1.4); 0.0049 (1.4); 0.0040 (2.2); −0.0002 (203.0); −0.00085 (6.0); −0.0283 (1.6); −0.1493 (0.6) IX-001: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.1924 (6.1); 9.1774 (1.0); 8.6770 (16.0); 8.6661 (2.4); 7.7000 (0.6); 7.6966 (0.8); 7.6795 (1.1); 7.6758 (1.0); 7.6700 (0.6); 7.6667 (0.8); 7.6495 (1.0); 7.6459 (0.9); 7.5332 (0.6); 7.5293 (0.6); 7.5080 (0.7); 7.5036 (0.8); 7.4888 (1.7); 7.4841 (1.7); 7.4816 (0.8); 7.4797 (0.9); 7.4764 (0.5); 7.4695 (1.4); 7.4681 (1.3); 7.4649 (1.4); 7.4608 (1.1); 7.4047 (0.5); 7.4026 (0.7); 7.4008 (0.6); 7.3982 (0.7); 7.3963 (0.6); 7.3903 (0.8); 7.3885 (0.6); 7.3859 (0.7); 7.3840 (0.6); 7.3819 (0.8); 7.3774 (0.7); 7.3696 (0.8); 7.3651 (0.7); 7.2889 (0.9); 7.2872 (0.9); 7.2854 (1.0); 7.2840 (0.9); 7.2679 (1.6); 7.2672 (1.7); 7.2663 (1.7); 7.2656 (1.9); 7.2623 (31.3); 7.2598 (1.3); 7.2582 (0.7); 7.2502 (0.8); 7.2486 (0.9); 7.2469 (0.9); 7.2454 (0.8); 7.0762 (0.9); 7.0730 (0.9); 7.0554 (0.9); 7.0516 (1.4); 7.0478 (1.0); 7.0302 (0.9); 7.0271 (0.9); 5.9377 (1.0); 5.9256 (0.6); 5.9241 (0.6); 5.9120 (1.0); 5.9086 (0.6); 5.8983 (0.6); 5.8948 (1.2); 5.8827 (0.6); 5.8812 (0.7); 5.8691 (1.2); 5.8555 (0.6); 5.3003 (7.2); 5.2817 (0.9); 5.2774 (1.9); 5.2743 (1.8); 5.2700 (0.8); 5.2389 (0.6); 5.2345 (1.3); 5.2314 (1.4); 5.2271 (0.6); 5.2015 (0.7); 5.1978 (1.7); 5.1945 (1.6); 5.1910 (0.7); 5.1758 (0.6); 5.1722 (1.5); 5.1689 (1.6); 5.1653 (0.7); 4.8662 (10.6); 4.0432 (0.8); 4.0392 (1.4); 4.0352 (0.9); 4.0287 (1.4); 4.0250 (2.5); 4.0212 (1.5); 4.0147 (0.9); 4.0107 (1.5); 4.0067 (1.0); 2.7881 (0.7); 2.7339 (0.6); 2.2717 (0.6); 1.4322 (5.5); 1.2539 (1.1); 1.2218 (1.1); 1.2107 (0.6); 1.1927 (1.4); 1.1745 (0.6); 0.0695 (1.4); 0.0080 (1.1); 0.0030 (0.6); 0.0022 (1.3); −0.0002 (41.4); −0.00027 (2.3); −0.00034 (1.7); −0.00043 (1.0); −0.00051 (0.7); −0.00060 (0.6); −0.00068 (0.5); −0.00085 (1.4) IX-002: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 9.2343 (9.6); 9.2134 (0.5); 8.9495 (0.5); 8.7205 (0.7); 8.7044 (16.0); 7.5197 (0.6); 7.5016 (0.9); 7.4972 (1.2); 7.4838 (1.8); 7.4794 (2.2); 7.4714 (1.1); 7.4646 (2.0); 7.4601 (2.3); 7.4522 (1.9); 7.4477 (1.2); 7.4441 (1.3); 7.4397 (0.9); 7.4316 (1.3); 7.4271 (0.8); 7.3123 (1.6); 7.2961 (1.8); 7.2927 (2.3); 7.2882 (0.5); 7.2749 (1.0); 7.2612 (92.2); 7.2531 (1.0); 7.2331 (0.9); 7.1928 (0.5); 7.1879 (0.5); 7.0966 (1.4); 7.0933 (1.4); 7.0757 (1.8); 7.0721 (2.7); 7.0683 (1.9); 7.0508 (1.7); 7.0482 (1.6); 6.9976 (0.6); 5.9459 (0.6); 5.9322 (1.4); 5.9201 (0.9); 5.9184 (0.9); 5.9064 (1.6); 5.9031 (0.8); 5.8926 (1.0); 5.8893 (1.7); 5.8773 (1.0); 5.8756 (1.1); 5.8635 (1.8); 5.8498 (1.0); 5.3953 (0.8); 5.3785 (3.0); 5.3616 (3.1); 5.3447 (1.0); 5.3004 (7.5); 5.2816 (1.0); 5.2774 (2.1); 5.2743 (2.4); 5.2700 (1.2); 5.2387 (0.9); 5.2345 (1.9); 5.2314 (2.0); 5.2272 (1.0); 5.2157 (0.6); 5.2126 (0.6); 5.2050 (1.2); 5.2014 (2.7); 5.1982 (2.6); 5.1947 (1.2); 5.1792 (1.2); 5.1757 (2.7); 5.1725 (2.4); 5.1690 (1.0); 5.1528 (0.5); 4.0065 (1.2); 4.0026 (2.2); 3.9986 (1.4); 3.9924 (2.4); 3.9884 (4.2); 3.9844 (2.8); 3.9784 (1.9); 3.9743 (2.6); 3.9702 (1.8); 3.9658 (1.0); 3.9519 (0.5); 3.8709 (0.5); 2.8213 (0.8); 2.8094 (0.8); 2.6167 (2.5); 2.2718 (0.8); 1.7757 (14.7); 1.7588 (14.6); 1.7375 (0.5); 1.7288 (0.9); 1.7232 (2.4); 1.7121 (1.0); 1.7063 (2.3); 1.5637 (3.8); 1.4322 (8.3); 1.2539 (3.6); 1.2225 (0.6); 1.1237 (0.7); 0.0691 (0.7); 0.0080 (3.2); −0.0002 (127.4); −0.0049 (2.9); −0.00085 (4.1); −0.0282 (1.1) VIII-003: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 8.1930 (2.5); 8.1802 (2.6); 7.5200 (0.6); 7.4878 (0.5); 7.4794 (0.6); 7.4297 (1.1); 7.4104 (1.9); 7.3911 (1.7); 7.3836 (1.3); 7.3704 (1.3); 7.3506 (0.9); 7.2609 (42.6); 7.2304 (2.0); 7.2108 (0.9); 7.1763 (1.1); 7.0703 (2.4); 7.0667 (2.4); 7.0534 (3.0); 7.0499 (2.7); 7.0279 (1.0); 6.8696 (3.4); 5.0400 (1.0); 4.9003 (11.8); 4.7181 (1.1); 4.6655 (1.7); 4.5975 (0.9); 4.2964 (1.6); 4.2786 (4.7); 4.2607 (4.8); 4.2430 (1.8); 4.2312 (1.1); 4.2130 (1.0); 2.8159 (1.4); 2.3526 (0.8); 2.3336 (0.6); 1.6401 (0.6); 1.5515 (0.8); 1.3329 (2.0); 1.3075 (6.8); 1.2897 (13.0); 1.2844 (5.8); 1.2718 (9.2); 1.2550 (16.0); 1.2201 (1.6); 0.8966 (1.1); 0.8801 (2.5); 0.8625 (1.3); 0.0696 (0.6); −0.0002 (28.3) VIII-012: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 8.2247 (1.0); 8.2117 (1.1); 7.4434 (0.8); 7.4253 (1.0); 7.4231 (0.8); 7.4054 (0.6); 7.4013 (0.6); 7.2615 (23.7); 7.0855 (0.7); 7.0744 (0.6); 7.0706 (0.9); 7.0667 (0.6); 7.0642 (0.6); 7.0612 (0.8); 7.0576 (0.9); 7.0538 (0.6); 6.8791 (0.8); 6.8758 (1.2); 6.8725 (0.8); 6.8710 (0.6); 5.3005 (4.2); 4.9202 (3.5); 3.3648 (1.9); 3.1125 (16.0); 2.2839 (1.0); 2.2267 (0.7); 2.2188 (0.6); 2.1363 (0.6); 2.0458 (1.2); 1.2594 (1.2); 1.2555 (0.9); −0.0002 (17.4); −0.00084 (0.5) VIII-003: .sup.1H-NMR(400.0 MHz, CDCl3): δ = 7.2626 (14.0); 4.9002 (1.2); 2.9654 (16.0); 2.7749 (3.4); 1.3078 (0.6); 1.2900 (1.2); 1.2722 (0.6); 1.2547 (0.6); −0.0002 (7.7) VIII-003: .sup.1H-NMR(400.6 MHz, CDCl3): δ = 7.2617 (27.2); 6.2329 (1.2); 5.3008 (12.5); 4.8545 (1.8); 4.2833 (0.7); 4.2655 (0.7); 2.9651 (16.0); 2.7752 (3.2); 1.3115 (1.0); 1.2937 (2.1); 1.2759 (1.0); −0.0002 (15.9); −0.00085 (0.5)

TABLE-US-00012 Ex. No. NMR Data (400 MHz) III-007 CDCl.sub.3: 5.0 (s, 2H), 7.0 (m, 1H), 7.3-7.4 (m, 4H), 7.5 (m, 1H), 8.7 (m, 2H) III-008 CDCl.sub.3: 5.0 (s, 2H), 7.0 (m, 1H), 7.4 (m, 2H), 7.5 (m, 1H), 8.6 (s, 2H) III-009 CDCl.sub.3: 1.6 (d, 3H), 5.4 (q, 1H), 7.0 (m, 1H), 7.4 (m, 2H), 7.5 (m, 1H), 8.5 (s, 2H) IX-001 CDCl.sub.3: 4.0 (dd, 2H), 4.8 (s, 2H), 5.2-5.4 (qd, 2H), 6.0 (m, 1H), 6.7 (br, 1H), 7.0 (m, 1H), 7.4-7.5 (m, 3H), 86 (s, 2H), 9.2 (s, 1H) V-007 CDCl.sub.3: 1.4 (t, 3H), 4.4 (q, 2H), 5.0 (s, 1H), 7.0 (t, 1H), 7.3-7.4 (m, 3H), 7.5 (m, 1H), 8.5 (s, 1H) VI-018 DMSO-d.sub.6: 1.5 (d, 3H), 5.0 (q, 1H), 7.4 (m, 2H), 7.5 (m, 2H), 8.7 (s, 2H), 9.3 (s, 1H) VII-001 DMSO-d.sub.6: 3.7 (s, 3H), 5.0 (s, 2H), 7.4 (m, 3H), 7.5 (m, 1H), 7.55 (m, 1H), 8.0 (t, 1H), 8.4 (s, 1H) VII-013 CDCl3: 1.6 (d, 3H), 3.7 (s, 3H), 5.2 (q, 1H), 7.1 (m, 3H), 7.2 (m, 3H), 7.5 (m, 1H), 8.4 (s, 1H) VII-020 CDCl3: 1.6 (d, 3H), 3.8 (s, 3H), 5.3 (q, 1H), 7.1 (m, 3H), 7.2 (m, 3H), 7.7 (m, 1H), 8.3 (s, 1H) VII-022 CDCl3: 2.9 (s, 3H), 3.9 (s, 3H), 4.9 (s, 2H), 7.1 (m, 1H), 7.2 (m, 1H), 7.4 (m, 3H), 7.5 (m, 1H), 8.1 (s, 1H) VII-025 DMSO-d.sub.6: 4.88 (s, 2H), 7.4 (m. 2H), 7.5 (m, 1H), 7.6 (m, 1H), 7.8 (m, 1H), 8.4 (s, 1H), 8.6 (s, 1H) VII-031 CDCl.sub.3: 3.8 (s, 3H), 4.9 (s, 2H), 6.9 (m, 1H), 7.0 (m, 1H), 7.2 (m, 1H), 7.4 (m, 2H), 7.8 (m 1H), 8.1 (s, 1H) VII-035 CDCl.sub.3: 3.8 (s, 3H), 4.9 (s, 2H), 7.0 (t, 1H), 7.4 (m, 2H), 7.4 (m, 2H), 8.4 (s, 1H), 8.5 (s, 1H) VII-040 CDCl.sub.3: 3.7 (s, 3H), 4.9 (s, 2H), 6.9 (m, 1H), 7.1 (m, 1H), 7.3 (m, 1H), 7.5 (m, 2H), 7.6 (m, 1H), 8.1 (s, 1H) VII-047 DMSO-d.sub.6: 3.4 (s, 3H), 4.8 (s, 2H), 7.4 (m, 3H), 7.5 (m, 3H), 8.4 (s, 1H) VII-048 CDCl.sub.3: 1.4 (t, 3H), 2.5 (s, 3H), 4.2 (q, 2H), 4.9 (s, 2H), 7.1-7.5 (m, 6H), 8.4 (s, 1H) VII-049 CDCl.sub.3: 3.7 (s, 3H), 3.8 (s, 3H), 4.9 (s, 2H), 6.6 (d, 1H), 7.0 (m, 1H), 7.1 (m, 1H), 7.4 (m, 1H), 7.5 (m, 1H), 8.0 (s, 1H) VII-050 CDCl.sub.3: 3.6 (s, 3H), 3.8 (s, 3H), 4.9 (s, 2H), 6.7 ((m, 1H), 7.0 (m, 1H), 7.2 (m, 1H), 7.4.- 7.5 (m, 2H), 7.7 (m, 1H), 8.1 (s, 1H) VII-057-a DMSO-d.sub.6: 6.5 (d, J = 4 Hz, 1H), 6.9 (m, 1H), 7.0 (m, 3H), 7.5-7.6 (m, 2H), 8.0 (m, 2H), 8.4 (s, 1H) VII-060 CDCl.sub.3: 1.6 (d, 3H), 3.8 (s, 3H), 5.2 (q, 1H), 5.4 (s, 2H), 6.9 (m, 1H), 7.0 (m, 1H), 7.2 (m, 1H), 7.4 (m, 2H), 7.7 (m, 1H), 8.1 (s, 1H) VII-071-a CDCl.sub.3: 1.4 (t, 3H), 4.4 (q, 2H), 6.5 (d, J = 4 Hz, 1H), 6.9 (m, 1H), 7.0 (m, 1H), 7.2-7.5 (m, 4H), 7.7 (m, 1H), 8.1 (s, 1H) VII-092 DMSO-d.sub.6; 1.5 (d, 3H), 5.0 (q, 1H), 7.2-7.3 (m, 3H), 7.5 (m; 2H), 8.0 (m, 1H), 8.1 (s, 1H) VII-111 CDCl.sub.3: 2.6 (t, 2H), 3.6 (s, 3H), 4.1 (q, 2H), 4.5 (t, 2H), 5.0 (s, 2H), 6.9 (m 1H), 7.0 (m, 1H), 7.4 (m, 1H), 7.5 (m, 1H), 7.8 (m, 1H), 8.1 (s, 1H) VII-113 CDCl.sub.3: 3.8 (s, 3H), 4.9 (s, 2H), 6.9 (m, 1H), 7.1 (m, 1H), 7.2 (m, 1H), 7.4.-7.5 (m, 2H), 7.7 (m, 1H), 8.1 (s, 1H) VII-115 DMSO-d.sub.6: 4.8 (s, 2H), 7.4 (m, 3H), 7.5 (m, 2H), 7.9 (m, 1H), 8.2 (s, 1H) VII-119 CDCl.sub.3: 0.8 (m, 4H), 1.4 (t, 3H), 4.2 (q, 2H), 4.9 (s, 1H), 6.9 (m, 1H), 7.0 (m, 1H), 7.2 (m, 1H), 7.4 (m, 2H), 7.6 (m, 1H), 8.1 (s, 1H) VII-121 CDCl.sub.3: 1.4 (t, 3H), 1.6 (2, 3H), 4.3 (q, 2H), 5.2 (t, 1H), 6.9 (m 1H), 7.0 (m, 1H), 7.4 (m, 1H), 7.5 (m, 2H), 7.8 (m, 1H), 8.1 (s, 1H) VII-130 CDCl.sub.3:1.4 (t, 3H), 1.6 (d, 3H), 4.3 (q, 2H), 5.2 (q, 1H), 7.0 (m, 1H), 7.2-7.5 (m, 5H), 8.4 (s, 1H), 8.5 (s, 1H) VIII-011 CDCl.sub.3: 1.6 (m, 1H), 2.0 (m, 1H), 2.6 (m, 1H), 3.6 (m, 1H), 3.7-3.8 (m, 2H), 4.1 (t, 1H), 4.3 (t, 1H), 4.9 (s, 2H) 6.9 (m, 1H), 7.1 (m, 2H), 7.4-7.5 (m, 4H), 8.2 (s, 1H) X-005 CDCl.sub.3: 3.0 (s, 3H), 4.9 (s, 2H), 6.9 (m, 1H), 7.1 (m, 1H), 7.2 (m, 1H), 7.5 (m, 1H), 7.7 (m, 1H), 8.1 (s, 1H), 8.6 (s, 1H) X-006 CDCl.sub.3: 4.4 (q, 2H), 5.0 (s, 2H), 6.9 (m, 1H), 7.1 (m, 1H), 7.4 (m, 1H), 7.5 (m, 1H), 7.6 (m, 1H), 8.1 (s, 1H), 9.0 (s, 1H) X-013 CDCl.sub.3: 2.2-2.3 (m, 2H), 3.0-3.1 (m, 1H), 3.5 (m, 1H), 3.6 (s, 3H), 3.9 (m, 2H), 5.0 (s, 2H), 6.9 (m, 1H), 7.0 (m, 1H), 7.2-7.5 (m, 4H), 7.7 (m, 1H), 8.1 (s, 1H) X-015 CDCl.sub.3: 1.3 (t, 3H), 1.9 (m, 2H), 2.0 (m, 2H), 2.5 (m, 1H), 2.9-3.1 (m, 2H), 3.9 (m, 1H), 4.1 (q, 2H), 4.5 (m, 1H( ), 5.0 (s, 2H), 6.9 (m, 1H), 7.0 (m, 1H), 7.2 -7.5 (m, 4H), 7.7 (m, 1H), 8.1 (s, 1H) X-016 CDCl.sub.3: 2.2 (m, 2H), 3.4 (m, 2H), 3.6 (s, 3H), 1.5 (m, 1H), 5.0 (m, 2H), 6.9 (m, 1H), 7.0 (m, 1H), 7.2 (m, 1H), 7.4-7.5 (m, 2H), 7.8 (m, 1H), 8.1 (s, 1H) X-018 CDCl.sub.3: 1.9 (m, 1H), 2.0 (m, 1H), 2.5 (m, 1H), 3.0 (m, 1H), 3.5 (m, 1H), 3.6 (s, 3H), 3.7 (m, 1H), 5.0 (m, 2H), 5.4 (s, 2H); 6.9 (m, 1H), 7.0 (m, 1H), 7.2-7.5 (m, 4H), 7.7 (m, 1H), 8.1 (m, 1H) X-022 CDCl.sub.3: 4.4 (q, 2H), 5.0 (s, 2H), 7.0-7.2 (m, 5H), 7.6 (m, 1H), 8.1 (s, 1H) X-030 CDCl.sub.3: 3.1 (s, 3H), 3.7 (s, 3H), 4.2 (s, 2H), 5.1 (s, 2H), 6.9 (m, 1H), 7.1 (m, 1H), 7.4 (m, 2H), 7.5 (m, 2H), 7.7 (m, 1H), 8.1 (s, 1H) X-031 CDCl.sub.3: 1.4 (t, 3H), 3.1 (s, 3H), 4.1 (s, 2H), 4.2 (q, 2H), 4.9 (s, 2H), 6.9 (m, 1H), 7.1 (m, 1H), 7.4 (m, 2H), 7.7 (m, 1H), 8.1 (s, 1H), 9.1 (s, 1H) X-041 CDCl.sub.3: 1.4 (t, 3H), 3.1 (s, 3H), 4.1 (s, 2H), 4.2 (q, 2H), 4.9 (s, 2H), 7.0 (m, 1H), 7.5 (m, 3h), 8.4 (s, 1H), 8.5 (s, 1H), 9.2 (s, 1H)

B. Formulation Examples

[0485] a) A dusting product is obtained by mixing 10 parts by weight of a compound of the formula (I) and/or salts thereof and 90 parts by weight of talc as inert substance and comminuting the mixture in an impact mill.
b) A readily water-dispersible, wettable powder is obtained by mixing 25 parts by weight of a compound of the formula (I) and/or salts thereof, 64 parts by weight of kaolin-containing quartz as inert substance, 10 parts by weight of potassium lignosulfonate and 1 part by weight of sodium oleoylmethyltaurate as wetting agent and dispersant and grinding in a pinned-disc mill.
c) A readily water-dispersible dispersion concentrate is obtained by mixing 20 parts by weight of a compound of the formula (I) and/or salts thereof with 6 parts by weight of alkylphenol polyglycol ether (@Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight of paraffinic mineral oil (boiling range e.g. about 255 to more than 277° C.) and grinding to a fineness of below 5 microns in an attrition ball mill.
d) An emulsifiable concentrate is obtained from 15 parts by weight of a compound of the formula (I) and/or salts thereof, 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of oxethylated nonylphenol as emulsifier.
e) Water-dispersible granules are obtained by mixing
75 parts by weight of a compound of the formula (I) and/or salts thereof,
10 parts by weight of calcium lignosulfonate,
5 parts by weight of sodium laurylsulfate,
3 parts by weight of polyvinyl alcohol and
7 parts by weight of kaolin,
grinding the mixture in a pinned-disc mill, and granulating the powder in a fluidized bed by spray application of water as a granulating liquid.
f) Water-dispersible granules are also obtained by homogenizing and precomminuting, in a colloid mill,
25 parts by weight of a compound of the formula (I) and/or salts thereof,
5 parts by weight of sodium 2,2′-dinaphthylmethane-6,6′-disulfonate,
2 parts by weight of sodium oleoylmethyltaurate,
1 part by weight of polyvinyl alcohol,
17 parts by weight of calcium carbonate and
50 parts by weight of water,
then grinding the mixture in a bead mill and atomizing and drying the resulting suspension in a spray tower by means of a one-phase nozzle.

C. Biological Examples

[0486] In Tables 1 to 39 below, the following abbreviations are used:

[0487] Undesired Plants/Weeds:

TABLE-US-00013 ALOMY: Alopecurus myosuroides SETVI: Setaria viridis ABUTH: Abutilon theophrasti HORMU: Hordeum murinum AMARE: Amaranthus retroflexus KCHSC: Bassia scoparia DIGSA. Digitaria sanguinalis ECHCG: Echinochloa crus-galli LOLRI: Lolium rigidum STEME: Stellaria media VERPE: Veronica persica MATIN: Tripleurospermum inodorum Matricaria inodora POAAN: Poa annua POLCO: Fallopia convolvulus Polygonum convolvulus VIOTR: Viola tricolor

[0488] 1. Pre-Emergence Herbicidal Effect and Crop Plant Compatibility

a) Seeds of mono- and dicotyledonous weed plants are placed in plastic pots in sandy loam soil (doubly sown with one species each of mono- or dicotyledonous weed plants per pot) and covered with soil. The compounds of the invention, formulated in the form of wettable powders (WP) or as emulsion concentrates (EC), are then applied onto the surface of the covering soil as aqueous suspension or emulsion with addition of 0.5% additive at a water application rate equivalent to 600 litres per hectare. After the treatment, the pots are placed in a greenhouse and kept under good growth conditions for the trial plants. After about 3 weeks, the effect of the preparations is scored visually in comparison with untreated controls as percentages. For example, 100% activity=the plants have died, 0% activity=like control plants.

[0489] 1. Pre-Emergence Effectiveness

[0490] Tables 1 to 12 below show the effects of selected compounds of the general formula (I) according to Tables 1 and 2 on various harmful plants and at an application rate corresponding to 1280 g/ha, which were obtained by the experimental procedure mentioned above.

TABLE-US-00014 TABLE 1 Pre-emergence action against ALOMY Example number Dosage [g/ha] ALOMY I-001 1280 90 I-002 1280 90 II-004 1280 100 II-012 1280 90 II-013 1280 90 II-014 1280 100 VI-001 1280 90 VI-003 1280 90 VI-005 1280 90 VI-007 1280 90 VI-011 1280 90 VI-012 1280 90 VI-013 1280 90 VI-016 1280 90 VI-017 1280 90 VI-018 1280 100 VII-003 1280 90 VII-008 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 90 VII-014 1280 90 VII-015 1280 90 VII-018 1280 100 VII-019 1280 90 VII-025 1280 100 VII-026 1280 100 VII-029 1280 90 VII-031 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056-a 1280 90 VII-057 1280 100 VII-058 1280 90 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-098 1280 100 VII-099 1280 90 VII-101 1280 100 VII-102 1280 90 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 90 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-132 1280 100 VII-147 1280 100 VII-149 1280 100 VIII-006 1280 100 VIII-010 1280 100 VIII-011 1280 90 VIII-012 1280 100 X-001 1280 90 X-002 1280 100 X-003 1280 90 X-004 1280 90 X-005 1280 100 X-007 1280 100 X-009 1280 100 X-019 1280 100 X-020 1280 100 X-021-a 1280 100 X-023 1280 90 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 100 X-028 1280 90 X-032 1280 100 X-033 1280 90 X-039 1280 90

TABLE-US-00015 TABLE 2 Pre-emergence action against DIGSA Example number Dosage [g/ha] DIGSA I-001 1280 90 I-002 1280 100 I-003 1280 90 I-004 1280 90 II-003 1280 100 II-004 1280 100 II-012 1280 100 II-013 1280 100 II-014 1280 100 II-017 1280 100 IV-002 1280 90 IX-001 1280 100 VI-001 1280 90 VI-003 1280 100 VI-005 1280 100 VI-006 1280 100 VI-007 1280 100 VI-008 1280 100 VI-011 1280 100 VI-012 1280 90 VI-013 1280 100 VI-016 1280 100 VI-018 1280 100 VII-003 1280 100 VII-008 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-013 1280 90 VII-014 1280 100 VII-015 1280 90 VII-017 1280 90 VII-018 1280 100 VII-019 1280 100 VII-023 1280 90 VII-025 1280 100 VII-026 1280 100 VII-027 1280 90 VII-029 1280 100 VII-030 1280 90 VII-031 1280 100 VII-032 1280 90 VII-035 1280 90 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 100 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-069 1280 100 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 90 VII-101 1280 100 VII-102 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 100 VII-132 1280 100 VII-147 1280 100 VII-148 1280 100 VII-149 1280 100 VIII-001 1280 90 VIII-006 1280 100 VIII-007 1280 90 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 90 VIII-012 1280 100 X-001 1280 100 X-002 1280 100 X-003 1280 100 X-004 1280 90 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 90 X-011 1280 100 X-019 1280 100 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 100 X-028 1280 100 X-032 1280 100 X-033 1280 90 X-038 1280 90 X-039 1280 90 X-040 1280 90

TABLE-US-00016 TABLE 3 Pre-emergence action against ECHCG Example number Dosage [g/ha] ECHCG I-003 1280 90 I-004 1280 90 II-003 1280 100 II-012 1280 90 II-013 1280 90 II-014 1280 100 IV-001 1280 90 IV-002 1280 100 IX-001 1280 90 VI-001 1280 100 VI-002 1280 100 VI-003 1280 100 VI-004 1280 100 VI-005 1280 90 VI-006 1280 100 VI-007 1280 100 VI-011 1280 100 VI-012 1280 90 VI-013 1280 100 VI-016 1280 100 VI-018 1280 100 VII-002 1280 100 VII-003 1280 100 VII-008 1280 100 VII-009 1280 90 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-014 1280 90 VII-015 1280 100 VII-016 1280 100 VII-018 1280 100 VII-019 1280 100 VII-023 1280 100 VII-025 1280 100 VII-026 1280 90 VII-027 1280 90 VII-028 1280 100 VII-029 1280 100 VII-030 1280 90 VII-031 1280 90 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-101 1280 90 VII-102 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 90 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 100 VII-132 1280 100 VII-147 1280 100 VII-148 1280 90 VIII-001 1280 100 VIII-002 1280 100 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 100 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-001 1280 100 X-002 1280 90 X-003 1280 100 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-011 1280 100 X-019 1280 100 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 100 X-028 1280 100 X-032 1280 100 X-039 1280 90 X-040 1280 90

TABLE-US-00017 TABLE 4 Pre-emergence action against LOLRI Example number Dosage [g/ha] LOLRI I-001 1280 90 I-002 1280 90 I-003 1280 90 I-004 1280 90 II-003 1280 100 II-004 1280 90 II-012 1280 100 II-013 1280 100 II-014 1280 100 IV-001 1280 100 IX-001 1280 100 VI-001 1280 100 VI-002 1280 100 VI-003 1280 90 VI-004 1280 100 VI-005 1280 100 VI-006 1280 100 VI-007 1280 100 VI-008 1280 100 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-016 1280 100 VI-018 1280 100 VII-002 1280 100 VII-003 1280 100 VII-008 1280 100 VII-009 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-014 1280 100 VII-015 1280 100 VII-016 1280 100 VII-018 1280 100 VII-019 1280 100 VII-023 1280 100 VII-025 1280 100 VII-026 1280 90 VII-027 1280 100 VII-029 1280 100 VII-030 1280 100 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 90 VII-056-a 1280 90 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-069 1280 90 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-102 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 90 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123 1280 90 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 100 VII-132 1280 100 VII-147 1280 100 VII-148 1280 90 VII-149 1280 100 VIII-001 1280 100 VIII-002 1280 100 VIII-003 1280 90 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 100 VIII-008 1280 100 VIII-009 1280 90 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-001 1280 100 X-002 1280 100 X-003 1280 100 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-019 1280 100 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-028 1280 100 X-032 1280 100 X-038 1280 90 X-039 1280 90 X-040 1280 90

TABLE-US-00018 TABLE 5 Pre-emergence action against POAAN Example number Dosage [g/ha] POAAN I-001 1280 100 I-002 1280 100 I-003 1280 100 I-004 1280 100 II-003 1280 100 II-004 1280 100 II-012 1280 100 II-013 1280 100 II-014 1280 100 II-017 1280 100 IV-001 1280 100 IV-002 1280 100 IV-003 1280 90 IX-001 1280 100 VI-001 1280 100 VI-002 1280 100 VI-003 1280 100 VI-004 1280 100 VI-005 1280 100 VI-006 1280 100 VI-007 1280 100 VI-008 1280 100 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-016 1280 100 VI-017 1280 90 VI-018 1280 100 VII-002 1280 100 VII-003 1280 100 VII-008 1280 100 VII-009 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-013 1280 100 VII-014 1280 100 VII-015 1280 100 VII-016 1280 100 VII-017 1280 90 VII-018 1280 100 VII-019 1280 100 VII-021 1280 90 VII-023 1280 100 VII-025 1280 100 VII-026 1280 100 VII-027 1280 90 VII-028 1280 100 VII-029 1280 100 VII-030 1280 100 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 90 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-069 1280 100 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-102 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 100 VII-132 1280 100 VII-147 1280 100 VII-148 1280 100 VII-149 1280 100 VIII-001 1280 100 VIII-002 1280 100 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 100 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-001 1280 100 X-002 1280 100 X-003 1280 100 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-011 1280 100 X-019 1280 100 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 100 X-028 1280 100 X-029 1280 100 X-032 1280 100 X-033 1280 100 X-038 1280 100 X-039 1280 100 X-040 1280 90

TABLE-US-00019 TABLE 6 Pre-emergence action against SETVI Example number Dosage [g/ha] SETVI I-001 1280 90 I-002 1280 100 I-003 1280 90 I-004 1280 100 II-003 1280 100 II-012 1280 100 II-013 1280 100 II-014 1280 90 II-017 1280 100 IV-001 1280 100 IV-002 1280 100 IV-003 1280 100 IX-001 1280 100 VI-001 1280 100 VI-002 1280 100 VI-003 1280 100 VI-004 1280 100 VI-005 1280 100 VI-006 1280 100 VI-007 1280 100 VI-008 1280 100 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-016 1280 100 VI-018 1280 100 VII-002 1280 100 VII-003 1280 100 VII-008 1280 100 VII-009 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-014 1280 100 VII-015 1280 100 VII-016 1280 100 VII-018 1280 100 VII-019 1280 100 VII-023 1280 100 VII-025 1280 100 VII-026 1280 100 VII-027 1280 90 VII-028 1280 100 VII-029 1280 100 VII-030 1280 100 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 90 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-069 1280 100 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 90 VII-101 1280 100 VII-102 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 100 VII-132 1280 100 VII-147 1280 100 VII-148 1280 90 VII-149 1280 90 VIII-001 1280 100 VIII-002 1280 100 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 100 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-001 1280 100 X-002 1280 100 X-003 1280 100 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-011 1280 100 X-019 1280 100 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 100 X-028 1280 100 X-032 1280 100 X-033 1280 90 X-038 1280 100 X-039 1280 90 X-040 1280 90

TABLE-US-00020 TABLE 7 Pre-emergence action against ABUTH Example number Dosage [g/ha] ABUTH IX-001 1280 100 VI-001 1280 90 VI-003 1280 90 VI-004 1280 90 VI-007 1280 90 VI-011 1280 90 VI-012 1280 90 VI-013 1280 90 VI-018 1280 90 VII-008 1280 90 VII-010 1280 100 VII-015 1280 90 VII-016 1280 100 VII-018 1280 90 VII-019 1280 90 VII-025 1280 90 VII-026 1280 90 VII-029 1280 90 VII-030 1280 90 VII-031 1280 90 VII-035 1280 90 VII-036 1280 90 VII-052 1280 100 VII-057 1280 90 VII-061 1280 90 VII-062 1280 90 VII-064 1280 90 VII-064 1280 90 VII-091 1280 90 VII-099 1280 90 VII-103 1280 90 VII-104 1280 90 VII-106 1280 90 VII-108 1280 90 VII-109 1280 90 VII-110 1280 90 VII-111 1280 90 VII-117 1280 90 VII-123-a 1280 90 VII-124 1280 90 VII-132 1280 90 VII-147 1280 90 VII-149 1280 90 VIII-006 1280 90 X-003 1280 90 X-007 1280 90 X-027 1280 90 X-039 1280 90

TABLE-US-00021 TABLE 8 Pre-emergence action against AMARE Example number Dosage [g/ha] AMARE I-001 1280 100 I-002 1280 100 I-003 1280 90 I-004 1280 100 II-003 1280 100 II-005 1280 90 II-012 1280 90 II-013 1280 90 II-014 1280 90 II-017 1280 100 IV-001 1280 90 IV-002 1280 100 IV-003 1280 90 IX-001 1280 100 VI-001 1280 100 VI-002 1280 100 VI-003 1280 100 VI-004 1280 100 VI-005 1280 100 VI-006 1280 90 VI-007 1280 100 VI-008 1280 100 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-016 1280 100 VI-017 1280 100 VI-018 1280 100 VII-002 1280 100 VII-003 1280 100 VII-008 1280 100 VII-009 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-014 1280 100 VII-015 1280 100 VII-016 1280 100 VII-017 1280 90 VII-018 1280 100 VII-019 1280 100 VII-021 1280 90 VII-023 1280 100 VII-025 1280 100 VII-026 1280 100 VII-027 1280 90 VII-028 1280 90 VII-029 1280 100 VII-030 1280 100 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 90 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-069 1280 100 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-102 1280 90 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123 1280 90 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 90 VII-132 1280 100 VII-147 1280 100 VII-148 1280 100 VII-149 1280 100 VIII-001 1280 90 VIII-002 1280 100 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 100 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-001 1280 100 X-002 1280 100 X-003 1280 100 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-011 1280 100 X-019 1280 100 X-020 1280 90 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 100 X-028 1280 100 X-029 1280 100 X-032 1280 100 X-033 1280 90 X-038 1280 100 X-039 1280 100 X-040 1280 90

TABLE-US-00022 TABLE 9 Pre-emergence action against KCHSC Example number Dosage [g/ha] KCHSC I-002 1280 100 II-017 1280 100 IV-002 1280 90 IX-001 1280 100 VI-005 1280 90 VI-006 1280 100 VI-008 1280 90 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-016 1280 100 VI-018 1280 100 VII-008 1280 90 VII-014 1280 100 VII-018 1280 90 VII-019 1280 100 VII-025 1280 90 VII-026 1280 100 VII-029 1280 90 VII-030 1280 90 VII-035 1280 90 VII-057 1280 100 VII-058 1280 90 VII-059 1280 100 VII-062 1280 100 VII-064 1280 100 VII-064 1280 90 VII-065 1280 100 VII-095 1280 100 VII-096 1280 100 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-104 1280 90 VII-108 1280 90 VII-110 1280 90 VII-118 1280 100 VII-123-a 1280 100 VII-124 1280 90 VII-125 1280 100 VII-132 1280 100 VII-147 1280 100 VIII-006 1280 100 X-003 1280 90 X-005 1280 90 X-009 1280 90 X-020 1280 90 X-021-a 1280 90 X-024 1280 100 X-025 1280 100 X-028 1280 100 X-039 1280 100 X-040 1280 90

TABLE-US-00023 TABLE 10 Pre-emergence action against MATIN Example number Dosage [g/ha] MATIN I-001 1280 90 I-002 1280 100 I-003 1280 90 I-004 1280 90 II-003 1280 100 II-012 1280 90 II-013 1280 90 II-014 1280 100 II-017 1280 90 IV-001 1280 90 IV-002 1280 100 IV-003 1280 90 IX-001 1280 100 VI-001 1280 100 VI-002 1280 90 VI-003 1280 100 VI-004 1280 100 VI-005 1280 100 VI-006 1280 100 VI-007 1280 100 VI-008 1280 90 VI-011 1280 90 VI-012 1280 90 VI-013 1280 90 VI-016 1280 100 VI-017 1280 100 VI-018 1280 100 VII-002 1280 90 VII-003 1280 100 VII-008 1280 100 VII-009 1280 100 VII-010 1280 90 VII-012 1280 100 VII-012 1280 100 VII-014 1280 90 VII-015 1280 100 VII-016 1280 90 VII-018 1280 90 VII-019 1280 90 VII-023 1280 90 VII-025 1280 100 VII-026 1280 90 VII-027 1280 90 VII-028 1280 100 VII-029 1280 100 VII-030 1280 90 VII-031 1280 100 VII-032 1280 90 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 90 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 90 VII-061 1280 100 VII-062 1280 100 VII-063 1280 90 VII-064 1280 100 VII-064 1280 100 VII-065 1280 90 VII-066 1280 90 VII-067 1280 100 VII-068 1280 100 VII-069 1280 90 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 90 VII-096 1280 100 VII-097 1280 90 VII-098 1280 90 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-102 1280 90 VII-103 1280 100 VII-104 1280 100 VII-105 1280 90 VII-106 1280 90 VII-107 1280 90 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 90 VII-132 1280 100 VII-147 1280 100 VII-148 1280 90 VII-149 1280 90 VIII-001 1280 90 VIII-002 1280 100 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 90 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-001 1280 90 X-002 1280 90 X-003 1280 100 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-011 1280 90 X-019 1280 100 X-020 1280 90 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 90 X-028 1280 100 X-032 1280 100 X-033 1280 90 X-038 1280 90 X-039 1280 100 X-040 1280 90

TABLE-US-00024 TABLE 11 Pre-emergence action against STEME Example number Dosage [g/ha] STEME I-001 1280 100 I-002 1280 100 I-003 1280 100 I-004 1280 100 II-003 1280 90 II-012 1280 100 II-013 1280 100 II-014 1280 90 II-017 1280 90 IV-001 1280 90 IV-002 1280 100 IV-003 1280 100 IX-001 1280 100 VI-001 1280 100 VI-002 1280 100 VI-003 1280 90 VI-004 1280 100 VI-005 1280 100 VI-006 1280 90 VI-007 1280 100 VI-008 1280 100 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-016 1280 100 VI-017 1280 90 VI-018 1280 100 VII-002 1280 100 VII-003 1280 100 VII-008 1280 100 VII-009 1280 100 VII-010 1280 100 VII-012 1280 90 VII-012 1280 100 VII-014 1280 100 VII-015 1280 100 VII-016 1280 100 VII-018 1280 100 VII-019 1280 100 VII-023 1280 100 VII-025 1280 100 VII-026 1280 90 VII-027 1280 100 VII-028 1280 100 VII-029 1280 100 VII-030 1280 100 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 90 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-069 1280 100 VII-088 1280 100 VII-089 1280 90 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-102 1280 90 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 90 VII-118 1280 100 VII-119 1280 100 VII-123 1280 90 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 90 VII-127 1280 90 VII-132 1280 100 VII-147 1280 100 VII-148 1280 90 VII-149 1280 100 VIII-001 1280 90 VIII-002 1280 90 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 90 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 X-001 1280 100 X-002 1280 100 X-003 1280 100 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-019 1280 90 X-020 1280 90 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 90 X-028 1280 100 X-029 1280 90 X-032 1280 100 X-033 1280 90 X-038 1280 90 X-039 1280 90 X-040 1280 90

TABLE-US-00025 TABLE 12 Pre-emergence action against VERPE Example number Dosage [g/ha] VERPE I-001 1280 100 I-002 1280 100 I-003 1280 90 I-004 1280 90 II-012 1280 90 II-013 1280 100 II-014 1280 100 IV-003 1280 100 IX-001 1280 100 VI-001 1280 100 VI-002 1280 90 VI-003 1280 100 VI-004 1280 90 VI-005 1280 100 VI-006 1280 100 VI-007 1280 90 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-016 1280 100 VI-017 1280 100 VI-018 1280 100 VII-003 1280 90 VII-008 1280 100 VII-009 1280 90 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-013 1280 100 VII-014 1280 90 VII-015 1280 100 VII-016 1280 90 VII-017 1280 100 VII-018 1280 100 VII-019 1280 100 VII-022 1280 90 VII-023 1280 100 VII-025 1280 100 VII-026 1280 100 VII-028 1280 90 VII-029 1280 100 VII-030 1280 90 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-069 1280 100 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-102 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123 1280 90 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 90 VII-132 1280 100 VII-147 1280 100 VII-148 1280 90 VII-149 1280 100 VIII-001 1280 100 VIII-002 1280 90 VIII-003 1280 90 VIII-004 1280 90 VIII-006 1280 100 VIII-007 1280 100 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-001 1280 100 X-002 1280 100 X-003 1280 100 X-004 1280 90 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-011 1280 100 X-019 1280 90 X-020 1280 90 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 100 X-028 1280 90 X-032 1280 100 X-033 1280 90 X-038 1280 90 X-039 1280 100 X-040 1280 90

[0491] As shown by the results, compounds of the general formula (I) of the invention, in post-emergence treatment, have very good herbicidal efficacy (90% to 100% herbicidal action) against harmful plants such as Abutilon theophrasti, Digitaria sanguinalis, Echinochloa crus-galli, Matricaria inodora, Poa annua, at an application rate of 1.28 kg of active substance per hectare. The compounds of the invention are therefore suitable for control of unwanted plant growth by the pre-emergence method. b) Seeds of monocotyledonous and dicotyledonous weed plants and crop plants are placed in plastic or organic planting pots and covered with soil. The compounds of the invention, formulated in the form of wettable powders (WP) or as emulsion concentrates (EC), are then applied onto the surface of the covering soil as aqueous suspension or emulsion with addition of 0.5% additive at a water application rate of 600 l/ha (converted). After the treatment, the pots are placed in a greenhouse and kept under good growth conditions for the trial plants. After about 3 weeks, the effect of the preparations is scored visually in comparison with untreated controls as percentages. For example, 100% activity=the plants have died, 0% activity=like control plants.

[0492] Tables 13 to 26 below show the effects of selected compounds of the general formula (I) on various harmful plants and at an application rate corresponding to 320 g/ha, which were obtained by the experimental procedure mentioned above.

TABLE-US-00026 TABLE 13 Pre-emergence action at 320 g/ha against ALOMY in % Example number Dosage [g/ha] ALOMY VI-004 320 100 VI-007 320 80 VI-011 320 100 VI-012 320 90 VI-013 320 90 VI-016 320 100 VI-018 320 100 VII-001 320 100 VII-002 320 90 VII-003 320 100 VII-004 320 90 VII-005 320 100 VII-008 320 100 VII-010 320 100 VII-012 320 100 VII-012 320 90 VII-014 320 100 VII-015 320 100 VII-016 320 100 VII-018 320 100 VII-019 320 100 VII-023 320 100 VII-025 320 100 VII-026 320 100 VII-028 320 100 VII-029 320 90 VII-031 320 100 VII-032 320 100 VII-034 320 90 VII-035 320 100 VII-036 320 100 VII-037 320 100 VII-040 320 100 VII-041 320 90 VII-042 320 90 VII-044 320 90 VII-052 320 100 VII-056-a 320 100 VII-057 320 100 VII-060 320 100 VII-062 320 100 VII-064 320 100 VII-064 320 100 VII-066 320 100 VII-071-a 320 80 VII-078 320 80 VII-089 320 100 VII-091 320 100 VII-103 320 100 VII-104 320 100 VII-105 320 90 VII-107 320 80 VII-108 320 100 VII-110 320 100 VII-111 320 100 VII-113 320 90 VII-115 320 100 VII-116 320 100 VII-117 320 100 VII-118 320 100 VII-124 320 100 VII-128 320 100 VII-130 320 100 VII-132 320 100 VII-135 320 100 VII-136 320 100 VII-137 320 100 VII-147 320 100 VIII-002 320 90 VIII-003 320 100 VIII-004 320 100 VIII-006 320 100 VIII-011 320 100 X-001 320 100 X-002 320 100 X-004 320 100 X-005 320 100 X-007 320 100 X-012 320 90 X-014 320 90 X-016 320 100 X-019 320 100 X-021-a 320 100 X-030 320 90 X-031 320 90 X-041 320 100

TABLE-US-00027 TABLE 14 Pre-emergence action at 320 g/ha against AVEFA in % Example number Dosage [g/ha] AVEFA VI-001 320 90 VI-004 320 90 VI-007 320 90 VI-011 320 80 VI-012 320 80 VI-016 320 80 VI-018 320 80 VII-001 320 90 VII-002 320 80 VII-003 320 90 VII-005 320 90 VII-008 320 80 VII-010 320 90 VII-012 320 90 VII-012 320 80 VII-014 320 90 VII-015 320 90 VII-016 320 90 VII-018 320 80 VII-019 320 90 VII-023 320 90 VII-025 320 80 VII-031 320 100 VII-032 320 80 VII-034 320 90 VII-035 320 90 VII-037 320 90 VII-040 320 100 VII-041 320 80 VII-052 320 90 VII-056-a 320 90 VII-057 320 90 VII-057-a 320 80 VII-060 320 90 VII-062 320 100 VII-064 320 90 VII-066 320 90 VII-089 320 90 VII-091 320 90 VII-103 320 90 VII-104 320 90 VII-107 320 90 VII-108 320 80 VII-110 320 80 VII-111 320 90 VII-113 320 90 VII-115 320 90 VII-116 320 90 VII-117 320 100 VII-118 320 100 VII-124 320 90 VII-128 320 80 VII-130 320 90 VII-132 320 100 VII-135 320 90 VII-136 320 90 VII-137 320 90 VII-147 320 100 VIII-003 320 90 VIII-006 320 80 X-001 320 90 X-002 320 100 X-004 320 90 X-005 320 100 X-007 320 100 X-016 320 90 X-019 320 80 X-021-a 320 100 X-031 320 80 X-041 320 80

TABLE-US-00028 TABLE 15 Pre-emergence action at 320 g/ha against DIGSA in % Example number Dosage [g/ha] DIGSA VI-001 320 100 VI-004 320 100 VI-007 320 100 VI-011 320 100 VI-012 320 100 VI-013 320 100 VI-016 320 100 VI-018 320 100 VII-001 320 100 VII-002 320 100 VII-003 320 100 VII-004 320 100 VII-005 320 100 VII-008 320 90 VII-010 320 100 VII-012 320 100 VII-012 320 100 VII-014 320 100 VII-015 320 100 VII-016 320 100 VII-018 320 100 VII-019 320 100 VII-023 320 100 VII-025 320 100 VII-026 320 100 VII-028 320 90 VII-029 320 100 VII-031 320 100 VII-032 320 90 VII-034 320 100 VII-035 320 100 VII-036 320 100 VII-037 320 100 VII-040 320 100 VII-052 320 100 VII-056-a 320 100 VII-057 320 100 VII-057-a 320 100 VII-060 320 100 VII-062 320 100 VII-064 320 100 VII-064 320 100 VII-066 320 100 VII-071-a 320 90 VII-089 320 100 VII-091 320 100 VII-103 320 100 VII-104 320 100 VII-105 320 100 VII-107 320 100 VII-108 320 100 VII-110 320 100 VII-111 320 100 VII-115 320 100 VII-116 320 100 VII-117 320 100 VII-118 320 100 VII-124 320 100 VII-128 320 100 VII-130 320 100 VII-132 320 100 VII-147 320 100 VIII-001 320 100 VIII-002 320 100 VIII-003 320 100 VIII-004 320 100 VIII-006 320 100 VIII-011 320 100 X-001 320 100 X-002 320 100 X-004 320 100 X-005 320 100 X-007 320 100 X-019 320 100 X-030 320 100 X-031 320 100

TABLE-US-00029 TABLE 16 Pre-emergence action at 320 g/ha against ECHGC in % Example number Dosage [g/ha] ECHCG VI-011 320 80 VI-012 320 80 VI-013 320 90 VII-001 320 100 VII-002 320 90 VII-003 320 100 VII-005 320 100 VII-008 320 80 VII-010 320 100 VII-012 320 100 VII-014 320 80 VII-015 320 90 VII-016 320 100 VII-018 320 90 VII-019 320 100 VII-023 320 90 VII-025 320 100 VII-028 320 80 VII-031 320 90 VII-032 320 90 VII-034 320 90 VII-035 320 90 VII-036 320 90 VII-037 320 80 VII-040 320 90 VII-041 320 80 VII-052 320 90 VII-057-a 320 80 VII-060 320 90 VII-064 320 100 VII-064 320 90 VII-066 320 90 VII-089 320 80 VII-103 320 80 VII-104 320 100 VII-108 320 100 VII-110 320 100 VII-111 320 100 VII-113 320 90 VII-117 320 90 VII-118 320 90 VII-124 320 100 VII-128 320 90 VII-130 320 90 VII-132 320 90 VII-135 320 90 VII-136 320 90 VII-137 320 90 VII-147 320 100 VIII-003 320 90 VIII-004 320 90 VIII-011 320 90 X-001 320 100 X-002 320 100 X-004 320 90 X-005 320 90 X-016 320 90 X-019 320 100 X-021-a 320 100 X-031 320 80 X-041 320 80

TABLE-US-00030 TABLE 17 Pre-emergence action at 320 g/ha against LOLRI in % Example number Dosage [g/ha] LOLRI VI-004 320 90 VI-007 320 100 VI-011 320 100 VI-012 320 90 VI-013 320 90 VI-016 320 100 VI-018 320 100 VII-001 320 100 VII-003 320 100 VII-004 320 80 VII-005 320 100 VII-008 320 100 VII-010 320 100 VII-012 320 90 VII-012 320 80 VII-014 320 100 VII-015 320 90 VII-016 320 100 VII-018 320 100 VII-019 320 100 VII-023 320 100 VII-025 320 90 VII-026 320 80 VII-029 320 90 VII-031 320 100 VII-032 320 100 VII-034 320 90 VII-035 320 90 VII-037 320 100 VII-040 320 100 VII-041 320 90 VII-042 320 100 VII-052 320 100 VII-056-a 320 90 VII-057 320 90 VII-057-a 320 90 VII-060 320 100 VII-062 320 100 VII-064 320 100 VII-064 320 100 VII-066 320 90 VII-071-a 320 100 VII-089 320 100 VII-091 320 100 VII-103 320 100 VII-104 320 100 VII-107 320 80 VII-108 320 100 VII-110 320 100 VII-111 320 100 VII-113 320 100 VII-115 320 90 VII-116 320 100 VII-117 320 100 VII-118 320 100 VII-124 320 100 VII-128 320 100 VII-130 320 100 VII-132 320 100 VII-135 320 100 VII-136 320 90 VII-137 320 100 VII-147 320 100 VIII-003 320 90 VIII-004 320 90 VIII-006 320 100 VIII-011 320 90 X-001 320 100 X-002 320 100 X-004 320 100 X-005 320 100 X-007 320 100 X-014 320 90 X-016 320 90 X-019 320 100 X-021-a 320 100 X-031 320 80 X-041 320 90

TABLE-US-00031 TABLE 18 Pre-emergence action at 320 g/ha against SETVI in % Example number Dosage [g/ha] SETVI VI-004 320 90 VI-007 320 100 VI-011 320 100 VI-012 320 100 VI-013 320 100 VI-016 320 100 VI-018 320 100 VII-001 320 100 VII-002 320 90 VII-003 320 100 VII-004 320 100 VII-005 320 100 VII-008 320 100 VII-010 320 100 VII-012 320 100 VII-012 320 90 VII-014 320 100 VII-015 320 100 VII-016 320 100 VII-018 320 100 VII-019 320 100 VII-023 320 100 VII-025 320 100 VII-026 320 80 VII-028 320 100 VII-029 320 90 VII-031 320 100 VII-032 320 90 VII-034 320 100 VII-035 320 100 VII-036 320 100 VII-037 320 100 VII-040 320 100 VII-052 320 100 VII-057 320 90 VII-057-a 320 100 VII-060 320 90 VII-062 320 100 VII-064 320 100 VII-064 320 100 VII-066 320 80 VII-089 320 100 VII-091 320 100 VII-103 320 100 VII-104 320 100 VII-105 320 80 VII-107 320 100 VII-108 320 100 VII-110 320 100 VII-111 320 100 VII-113 320 90 VII-115 320 100 VII-116 320 100 VII-117 320 100 VII-118 320 90 VII-124 320 100 VII-128 320 100 VII-130 320 100 VII-132 320 100 VII-135 320 100 VII-136 320 100 VII-137 320 100 VII-147 320 100 VIII-001 320 100 VIII-002 320 100 VIII-003 320 100 VIII-004 320 90 VIII-006 320 100 VIII-011 320 90 X-001 320 100 X-002 320 100 X-004 320 100 X-005 320 100 X-007 320 100 X-012 320 90 X-014 320 90 X-016 320 100 X-019 320 100 X-021-a 320 100 X-030 320 80 X-031 320 100 X-041 320 90

TABLE-US-00032 TABLE 11 Pre-emergence action at 320 g/ha against ABUTH in % Example number Dosage [g/ha] ABUTH VI-004 320 80 VI-011 320 80 VI-012 320 80 VI-013 320 80 VI-018 320 80 VII-008 320 80 VII-015 320 80 VII-028 320 90 VII-035 320 90 VII-104 320 80 VII-130 320 90 VII-132 320 90 VII-135 320 80 VII-136 320 80 VII-137 320 90 X-019 320 80 X-031 320 80

TABLE-US-00033 TABLE 19 Pre-emergence action at 320 g/ha against AMARE in % Example number Dosage [g/ha] AMARE VI-001 320 100 VI-004 320 100 VI-007 320 100 VI-011 320 100 VI-012 320 100 VI-013 320 90 VI-016 320 100 VI-018 320 100 VII-001 320 100 VII-002 320 100 VII-003 320 100 VII-004 320 90 VII-005 320 100 VII-008 320 100 VII-010 320 100 VII-012 320 100 VII-012 320 100 VII-014 320 90 VII-015 320 100 VII-016 320 100 VII-018 320 100 VII-019 320 100 VII-023 320 100 VII-025 320 100 VII-026 320 100 VII-028 320 90 VII-029 320 100 VII-031 320 100 VII-032 320 100 VII-034 320 100 VII-035 320 100 VII-036 320 100 VII-037 320 100 VII-040 320 100 VII-041 320 100 VII-042 320 100 VII-044 320 90 VII-047 320 90 VII-048 320 80 VII-052 320 100 VII-056-a 320 100 VII-057 320 100 VII-057-a 320 100 VII-060 320 100 VII-062 320 100 VII-064 320 100 VII-064 320 100 VII-066 320 100 VII-071-a 320 100 VII-078 320 100 VII-089 320 100 VII-091 320 100 VII-103 320 100 VII-104 320 100 VII-105 320 90 VII-107 320 100 VII-108 320 100 VII-110 320 100 VII-111 320 100 VII-113 320 100 VII-115 320 100 VII-116 320 100 VII-117 320 100 VII-118 320 100 VII-124 320 100 VII-128 320 100 VII-130 320 100 VII-132 320 100 VII-135 320 100 VII-136 320 100 VII-137 320 100 VII-147 320 100 VIII-001 320 90 VIII-002 320 100 VIII-003 320 90 VIII-004 320 100 VIII-006 320 100 VIII-011 320 100 X-001 320 90 X-002 320 100 X-004 320 90 X-005 320 100 X-007 320 100 X-012 320 100 X-014 320 100 X-016 320 100 X-019 320 100 X-021-a 320 100 X-030 320 90 X-031 320 90 X-037 320 100 X-041 320 90

TABLE-US-00034 TABLE 20 Pre-emergence action at 320 g/ha against MATIN in % Example number Dosage [g/ha] MATIN VI-001 320 90 VI-004 320 100 VI-007 320 100 VI-011 320 90 VI-012 320 90 VI-013 320 90 VI-016 320 100 VI-018 320 90 VII-001 320 90 VII-002 320 100 VII-003 320 90 VII-004 320 80 VII-005 320 100 VII-008 320 100 VII-010 320 100 VII-012 320 90 VII-012 320 90 VII-015 320 100 VII-016 320 80 VII-018 320 90 VII-019 320 100 VII-023 320 90 VII-025 320 100 VII-026 320 90 VII-028 320 80 VII-029 320 90 VII-031 320 100 VII-032 320 90 VII-035 320 100 VII-036 320 90 VII-037 320 80 VII-040 320 100 VII-041 320 100 VII-042 320 90 VII-052 320 90 VII-056-a 320 80 VII-057 320 90 VII-057-a 320 90 VII-060 320 90 VII-062 320 100 VII-064 320 100 VII-064 320 100 VII-066 320 100 VII-071-a 320 90 VII-089 320 90 VII-091 320 90 VII-103 320 90 VII-104 320 100 VII-105 320 100 VII-107 320 90 VII-108 320 100 VII-110 320 100 VII-111 320 90 VII-113 320 90 VII-116 320 90 VII-117 320 90 VII-118 320 90 VII-124 320 100 VII-128 320 90 VII-130 320 100 VII-132 320 90 VII-135 320 90 VII-136 320 90 VII-137 320 90 VII-147 320 90 VIII-003 320 90 VIII-004 320 90 VIII-006 320 90 VIII-011 320 90 X-001 320 90 X-002 320 100 X-004 320 90 X-005 320 100 X-007 320 100 X-012 320 90 X-014 320 90 X-016 320 90 X-019 320 100 X-021-a 320 90 X-031 320 80 X-041 320 90

TABLE-US-00035 TABLE 21 Pre-emergence action at 320 g/ha against PHBPU in % Example number Dosage [g/ha] PHBPU VI-007 320 90 VI-011 320 90 VI-012 320 90 VI-018 320 90 VII-001 320 100 VII-003 320 90 VII-005 320 80 VII-008 320 80 VII-010 320 90 VII-012 320 90 VII-012 320 80 VII-015 320 90 VII-016 320 90 VII-019 320 90 VII-025 320 90 VII-028 320 100 VII-031 320 80 VII-032 320 100 VII-035 320 90 VII-064 320 90 VII-089 320 80 VII-104 320 100 VII-110 320 90 VII-115 320 90 VII-124 320 90 VII-128 320 90 VII-135 320 90 VII-136 320 90 VIII-006 320 90 X-002 320 80 X-005 320 90 X-031 320 90 X-041 320 90

TABLE-US-00036 TABLE 22 Pre-emergence action at 320 g/ha against POLCO in % Example number Dosage [g/ha] POLCO VI-001 320 100 VI-004 320 90 VI-007 320 100 VI-011 320 80 VI-012 320 80 VI-013 320 90 VI-016 320 90 VI-018 320 90 VII-001 320 90 VII-002 320 100 VII-003 320 90 VII-004 320 90 VII-005 320 100 VII-008 320 100 VII-010 320 90 VII-012 320 90 VII-012 320 80 VII-014 320 90 VII-015 320 100 VII-016 320 90 VII-018 320 100 VII-019 320 100 VII-023 320 100 VII-025 320 100 VII-026 320 100 VII-028 320 90 VII-029 320 100 VII-031 320 100 VII-032 320 90 VII-034 320 90 VII-035 320 90 VII-036 320 100 VII-037 320 100 VII-040 320 90 VII-042 320 100 VII-044 320 100 VII-052 320 100 VII-056-a 320 90 VII-057 320 90 VII-057-a 320 80 VII-060 320 90 VII-062 320 100 VII-064 320 90 VII-064 320 90 VII-066 320 90 VII-071-a 320 90 VII-089 320 100 VII-091 320 100 VII-103 320 100 VII-104 320 90 VII-105 320 90 VII-107 320 100 VII-108 320 100 VII-110 320 100 VII-111 320 90 VII-113 320 90 VII-115 320 80 VII-116 320 90 VII-117 320 100 VII-118 320 100 VII-124 320 100 VII-128 320 90 VII-130 320 100 VII-132 320 100 VII-135 320 100 VII-136 320 100 VII-137 320 90 VII-147 320 100 VIII-001 320 90 VIII-002 320 90 VIII-003 320 100 VIII-004 320 90 VIII-006 320 90 X-001 320 90 X-002 320 100 X-004 320 90 X-005 320 90 X-007 320 90 X-012 320 90 X-016 320 80 X-019 320 90 X-021-a 320 100 X-031 320 80 X-037 320 90 X-041 320 90

TABLE-US-00037 TABLE 23 Pre-emeraence action at 320 g/ha against STEME in % Example number Dosage [g/ha] STEME VI-004 320 90 VI-007 320 100 VII-002 320 90 VII-003 320 90 VII-005 320 90 VII-012 320 100 VII-016 320 90 VII-019 320 90 VII-023 320 90 VII-028 320 90 VII-029 320 90 VII-032 320 90 VIII-001 320 90 VIII-003 320 80 VIII-004 320 90

TABLE-US-00038 TABLE 24 Pre-emergence action at 320 g/ha against VERPE in % Example number Dosage [g/ha] VERPE VI-001 320 100 VI-004 320 100 VI-007 320 100 VI-011 320 90 VI-012 320 100 VI-016 320 100 VI-018 320 80 VII-001 320 100 VII-002 320 100 VII-003 320 100 VII-005 320 100 VII-008 320 100 VII-010 320 100 VII-012 320 100 VII-012 320 100 VII-014 320 100 VII-015 320 100 VII-016 320 90 VII-018 320 100 VII-019 320 100 VII-023 320 80 VII-025 320 100 VII-026 320 80 VII-028 320 100 VII-029 320 100 VII-031 320 100 VII-032 320 100 VII-034 320 80 VII-035 320 100 VII-036 320 100 VII-037 320 100 VII-040 320 100 VII-041 320 100 VII-042 320 90 VII-052 320 90 VII-056-a 320 100 VII-060 320 100 VII-062 320 100 VII-064 320 100 VII-064 320 100 VII-066 320 100 VII-071-a 320 80 VII-078 320 80 VII-089 320 100 VII-091 320 100 VII-103 320 100 VII-104 320 100 VII-105 320 90 VII-107 320 80 VII-108 320 100 VII-110 320 100 VII-111 320 100 VII-113 320 90 VII-115 320 90 VII-116 320 100 VII-117 320 90 VII-118 320 90 VII-124 320 100 VII-128 320 100 VII-130 320 100 VII-132 320 100 VII-135 320 100 VII-136 320 100 VII-137 320 100 VII-147 320 100 VIII-002 320 80 VIII-003 320 90 VIII-004 320 100 X-001 320 80 X-002 320 100 X-004 320 100 X-005 320 100 X-007 320 100 X-016 320 100 X-019 320 100 X-021-a 320 100 X-031 320 90 X-034 320 90 X-037 320 100 X-041 320 100

TABLE-US-00039 TABLE 25 Pre-emergence action at 320 g/ha against VIOTR in % Example number Dosage [g/ha] VIOTR VI-001 320 100 VI-004 320 100 VI-007 320 100 VI-011 320 100 VI-012 320 100 VI-013 320 100 VI-016 320 100 VI-018 320 90 VII-001 320 100 VII-003 320 100 VII-004 320 100 VII-005 320 100 VII-008 320 100 VII-010 320 100 VII-012 320 100 VII-012 320 100 VII-014 320 100 VII-015 320 100 VII-016 320 90 VII-018 320 90 VII-019 320 100 VII-023 320 100 VII-025 320 100 VII-026 320 100 VII-028 320 100 VII-029 320 100 VII-031 320 100 VII-032 320 100 VII-034 320 100 VII-035 320 100 VII-036 320 100 VII-037 320 100 VII-040 320 100 VII-041 320 80 VII-042 320 100 VII-044 320 100 VII-052 320 100 VII-056-a 320 100 VII-057 320 100 VII-057-a 320 100 VII-060 320 100 VII-062 320 100 VII-064 320 100 VII-064 320 100 VII-066 320 100 VII-071-a 320 100 VII-078 320 90 VII-089 320 100 VII-091 320 100 VII-103 320 100 VII-104 320 100 VII-105 320 90 VII-107 320 100 VII-108 320 100 VII-110 320 100 VII-111 320 100 VII-113 320 100 VII-115 320 100 VII-116 320 90 VII-117 320 100 VII-118 320 100 VII-124 320 100 VII-128 320 100 VII-130 320 100 VII-132 320 100 VII-135 320 100 VII-136 320 100 VII-137 320 100 VII-147 320 100 VIII-001 320 90 VIII-002 320 100 VIII-003 320 100 VIII-004 320 90 VIII-006 320 100 VIII-011 320 100 X-001 320 100 X-002 320 100 X-004 320 100 X-005 320 100 X-007 320 100 X-012 320 100 X-014 320 100 X-016 320 100 X-018 320 90 X-019 320 100 X-021-a 320 100 X-030 320 90 X-031 320 90 X-034 320 90 X-041 320 100

TABLE-US-00040 TABLE 26 Pre-emergence action at 320 g/ha against HORMU in % Example number Dosage [g/ha] HORMU VI-004 320 100 VI-007 320 100 VII-002 320 80 VII-003 320 90 VII-005 320 100 VII-012 320 80 VII-016 320 90 VII-019 320 100 VII-023 320 100 VII-029 320 90 VII-032 320 80 VIII-003 320 90

[0493] As shown by the results, compounds of the general formula (I) of the invention, in post-emergence treatment, have very good herbicidal efficacy (90% to 100% herbicidal action) against harmful plants such as Abutilon theophrasti, Digitaria sanguinalis, Echinochloa crus-galli, Matricaria inodora, Poa annua, Stellaria media, at an application rate of 320 g of active substance per hectare.

[0494] Accordingly, the compounds of the invention have good herbicidal action against a broad spectrum of weed grasses and broad-leaved weeds and are therefore suitable for controlling unwanted vegetation by the pre-emergence method. 2. Post-emergence herbicidal effect and crop plant compatibility [0495] a) Seeds of mono- and dicotyledonous weed plants are placed in plastic pots in sandy loam soil (twin sowing with one species each of mono- or dicotyledonous weed plants per pot), covered with soil and cultivated in a greenhouse under controlled growth conditions. 2 to 3 weeks after sowing, the test plants are treated at the one-leaf stage. The compounds of the invention, formulated in the form of wettable powders (WP) or as emulsion concentrates (EC), are applied to the green parts of the plants as aqueous suspension or emulsion with addition of 0.5% additive at a water application rate equivalent to 600 litres per hectare. After the test plants have been kept in the greenhouse under optimum growth conditions for about 3 weeks, the activity of the preparations is rated visually in comparison to untreated controls. For example, 100% activity=the plants have died, 0% activity=like control plants.

[0496] As shown by the results from Tables 27 to 38, compounds of the invention have good herbicidal post-emergence efficacy against a broad spectrum of weed grasses and broad-leaved weeds.

TABLE-US-00041 TABLE 27 Post-emergence action against ALOMY Example number Dosage [g/ha] ALOMY I-004 1280 100 II-003 1280 100 II-004 1280 100 II-012 1280 100 II-013 1280 90 II-017 1280 100 IV-001 1280 100 IV-003 1280 100 VI-005 1280 90 VI-007 1280 90 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-018 1280 100 VII-003 1280 90 VII-008 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-014 1280 100 VII-015 1280 100 VII-018 1280 100 VII-019 1280 100 VII-025 1280 100 VII-026 1280 100 VII-027 1280 100 VII-029 1280 100 VII-030 1280 100 VII-031 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 100 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-068 1280 100 VII-069 1280 100 VII-089 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-102 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-119 1280 100 VII-123 1280 90 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 100 VII-132 1280 100 VII-147 1280 100 VII-148 1280 100 VII-149 1280 100 VIII-006 1280 100 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-002 1280 90 X-003 1280 100 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-011 1280 90 X-019 1280 100 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-028 1280 100 X-032 1280 100 X-033 1280 100 X-038 1280 90 X-039 1280 90 X-040 1280 100

TABLE-US-00042 TABLE 28 Post-emergence action against DIGSA Example number Dosage [g/ha] DIGSA II-004 1280 100 II-012 1280 90 II-014 1280 90 IV-002 1280 100 IX-001 1280 100 VI-001 1280 100 VI-003 1280 100 VI-006 1280 90 VI-007 1280 100 VI-008 1280 100 VI-011 1280 100 VI-012 1280 90 VI-013 1280 90 VI-018 1280 100 VII-003 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-013 1280 90 VII-015 1280 100 VII-017 1280 90 VII-018 1280 100 VII-019 1280 100 VII-023 1280 90 VII-025 1280 100 VII-026 1280 100 VII-027 1280 100 VII-029 1280 100 VII-031 1280 100 VII-032 1280 90 VII-035 1280 100 VII-036 1280 100 VII-037 1280 90 VII-040 1280 100 VII-052 1280 100 VII-056 1280 90 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-069 1280 100 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 90 VII-101 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-124 1280 100 VII-125 1280 100 VII-132 1280 100 VII-147 1280 100 VII-148 1280 100 VII-149 1280 100 VIII-001 1280 90 VIII-006 1280 90 VIII-007 1280 90 VIII-008 1280 90 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-002 1280 100 X-003 1280 100 X-004 1280 100 X-006 1280 90 X-007 1280 100 X-009 1280 90 X-019 1280 90 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-033 1280 90 X-038 1280 90 X-039 1280 90 X-040 1280 90

TABLE-US-00043 TABLE 29 Post-emergence action against ECHCG Example number Dosage [g/ha] ECHCG I-003 1280 90 I-004 1280 90 II-012 1280 100 IV-001 1280 90 IX-001 1280 90 VI-001 1280 100 VI-002 1280 100 VI-003 1280 100 VI-004 1280 90 VI-005 1280 90 VI-007 1280 100 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-018 1280 100 VII-002 1280 90 VII-003 1280 90 VII-008 1280 100 VII-009 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-014 1280 90 VII-015 1280 100 VII-016 1280 90 VII-018 1280 90 VII-019 1280 100 VII-023 1280 90 VII-025 1280 100 VII-026 1280 90 VII-028 1280 90 VII-029 1280 100 VII-030 1280 100 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 90 VII-037 1280 90 VII-040 1280 100 VII-052 1280 100 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-088 1280 100 VII-089 1280 90 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 90 VII-097 1280 100 VII-098 1280 90 VII-100 1280 90 VII-101 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 90 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 90 VII-132 1280 100 VII-147 1280 100 VIII-002 1280 100 VIII-003 1280 100 VIII-004 1280 90 VIII-006 1280 90 VIII-007 1280 90 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-002 1280 90 X-003 1280 90 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-019 1280 100 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-027 1280 90 X-028 1280 100 X-038 1280 90 X-039 1280 90

TABLE-US-00044 TABLE 30 Post-emergence action against LOLRI Example number Dosage [g/ha] LOLRI VI-002 1280 100 VI-004 1280 100 VI-006 1280 100 VI-011 1280 100 VI-012 1280 90 VI-013 1280 90 VI-018 1280 90 VII-003 1280 100 VII-008 1280 100 VII-012 1280 100 VII-012 1280 100 VII-014 1280 90 VII-015 1280 100 VII-016 1280 90 VII-018 1280 90 VII-019 1280 100 VII-023 1280 100 VII-028 1280 90 VII-029 1280 100 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 90 VII-056-a 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-064 1280 100 VII-064 1280 90 VII-065 1280 90 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-089 1280 100 VII-090 1280 90 VII-091 1280 100 VII-095 1280 100 VII-097 1280 90 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-103 1280 100 VII-104 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 90 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-147 1280 100 VII-149 1280 100 VIII-001 1280 90 VIII-002 1280 100 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 100 VIII-010 1280 100 X-005 1280 100 X-006 1280 90 X-007 1280 100 X-019 1280 90 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-026 1280 90

TABLE-US-00045 TABLE 31 Post-emereence action aeainst POAAN Example number Dosage [g/ha] POAAN I-003 1280 100 II-003 1280 100 II-012 1280 100 II-013 1280 90 II-014 1280 90 II-017 1280 100 IV-001 1280 100 IV-002 1280 100 VI-001 1280 100 VI-002 1280 100 VI-003 1280 100 VI-004 1280 100 VI-005 1280 100 VI-006 1280 100 VI-007 1280 100 VI-008 1280 100 VI-011 1280 100 VI-012 1280 100 VI-013 1280 100 VI-016 1280 100 VI-018 1280 100 VII-002 1280 100 VII-003 1280 100 VII-008 1280 100 VII-009 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-014 1280 100 VII-015 1280 100 VII-016 1280 100 VII-018 1280 100 VII-019 1280 100 VII-023 1280 100 VII-025 1280 100 VII-026 1280 100 VII-028 1280 90 VII-029 1280 100 VII-030 1280 100 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 100 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-067 1280 100 VII-068 1280 100 VII-088 1280 100 VII-089 1280 100 VII-090 1280 100 VII-091 1280 100 VII-095 1280 100 VII-096 1280 100 VII-097 1280 100 VII-098 1280 100 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-102 1280 100 VII-103 1280 100 VII-104 1280 100 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 100 VII-132 1280 100 VII-147 1280 100 VII-148 1280 100 VII-149 1280 100 VIII-001 1280 100 VIII-002 1280 100 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 100 VIII-008 1280 100 VIII-009 1280 100 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-001 1280 100 X-002 1280 100 X-003 1280 100 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-011 1280 100 X-019 1280 100 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 100 X-027 1280 100 X-028 1280 100 X-032 1280 100 X-033 1280 100 X-038 1280 100 X-039 1280 100 X-040 1280 100

TABLE-US-00046 TABLE 32 Post-emergence action against SETVI Example number Dosage [g/ha] SETVI II-012 1280 90 IV-001 1280 100 VI-001 1280 100 VI-002 1280 90 VI-003 1280 100 VI-004 1280 90 VI-007 1280 90 VI-011 1280 100 VI-012 1280 90 VI-013 1280 90 VII-002 1280 90 VII-003 1280 90 VII-008 1280 90 VII-009 1280 90 VII-010 1280 90 VII-012 1280 100 VII-012 1280 90 VII-015 1280 90 VII-016 1280 90 VII-018 1280 100 VII-019 1280 90 VII-025 1280 90 VII-027 1280 90 VII-028 1280 90 VII-031 1280 90 VII-032 1280 90 VII-035 1280 90 VII-036 1280 90 VII-037 1280 90 VII-040 1280 90 VII-052 1280 90 VII-056-a 1280 100 VII-057 1280 100 VII-061 1280 90 VII-064 1280 100 VII-064 1280 90 VII-065 1280 90 VII-066 1280 90 VII-068 1280 90 VII-088 1280 90 VII-091 1280 90 VII-095 1280 100 VII-096 1280 90 VII-097 1280 90 VII-100 1280 100 VII-101 1280 100 VII-103 1280 90 VII-104 1280 90 VII-106 1280 90 VII-107 1280 90 VII-108 1280 90 VII-109 1280 100 VII-110 1280 90 VII-111 1280 100 VII-119 1280 100 VII-123-a 1280 100 VII-124 1280 90 VII-132 1280 90 VII-147 1280 90 VIII-001 1280 90 VIII-002 1280 90 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 90 VIII-009 1280 90 VIII-010 1280 100 VIII-011 1280 100 X-002 1280 100 X-004 1280 90 X-005 1280 90 X-007 1280 100 X-009 1280 100 X-021-a 1280 100 X-023 1280 90 X-024 1280 90 X-026 1280 100 X-028 1280 90 X-038 1280 90 X-039 1280 100

TABLE-US-00047 TABLE 33 Post-emergence action against ABUTH Example number Dosage [g/ha] ABUTH I-003 1280 90 I-004 1280 90 II-003 1280 90 II-012 1280 90 II-014 1280 90 IV-002 1280 90 IX-001 1280 90 VI-002 1280 90 VI-003 1280 90 VI-004 1280 90 VI-005 1280 90 VI-008 1280 90 VI-013 1280 90 VI-018 1280 90 VII-002 1280 90 VII-008 1280 90 VII-009 1280 90 VII-010 1280 90 VII-012 1280 100 VII-015 1280 90 VII-016 1280 90 VII-018 1280 90 VII-025 1280 90 VII-026 1280 90 VII-028 1280 90 VII-030 1280 90 VII-031 1280 90 VII-032 1280 90 VII-035 1280 90 VII-036 1280 90 VII-037 1280 90 VII-040 1280 90 VII-052 1280 90 VII-056-a 1280 90 VII-058 1280 90 VII-061 1280 90 VII-064 1280 90 VII-064 1280 90 VII-065 1280 90 VII-066 1280 90 VII-068 1280 100 VII-069 1280 90 VII-088 1280 90 VII-089 1280 90 VII-091 1280 90 VII-098 1280 90 VII-099 1280 90 VII-100 1280 90 VII-101 1280 90 VII-104 1280 90 VII-107 1280 90 VII-108 1280 90 VII-109 1280 100 VII-110 1280 90 VII-111 1280 90 VII-119 1280 90 VII-123 1280 90 VII-123-a 1280 90 VII-124 1280 90 VII-132 1280 90 VII-147 1280 90 VIII-001 1280 90 VIII-003 1280 90 VIII-007 1280 90 VIII-011 1280 90 X-002 1280 90 X-003 1280 90 X-005 1280 90 X-006 1280 90 X-007 1280 90 X-009 1280 100 X-019 1280 90 X-020 1280 90 X-021-a 1280 100 X-023 1280 90 X-024 1280 100 X-026 1280 90 X-029 1280 90 X-038 1280 90 X-039 1280 100 X-040 1280 90

TABLE-US-00048 TABLE 34 Post-emergence action against AMARE Example number Dosage [g/ha] AMARE I-001 1280 90 I-003 1280 100 I-004 1280 90 II-012 1280 100 II-014 1280 90 II-018 1280 100 IV-002 1280 100 IV-003 1280 90 VI-001 1280 90 VI-002 1280 90 VI-003 1280 90 VI-004 1280 100 VI-005 1280 90 VI-012 1280 90 VI-013 1280 90 VI-016 1280 100 VI-017 1280 90 VI-018 1280 90 VII-003 1280 100 VII-008 1280 90 VII-009 1280 100 VII-012 1280 100 VII-012 1280 90 VII-014 1280 90 VII-015 1280 90 VII-016 1280 90 VII-019 1280 90 VII-025 1280 90 VII-026 1280 90 VII-027 1280 90 VII-028 1280 100 VII-029 1280 90 VII-030 1280 90 VII-031 1280 90 VII-032 1280 100 VII-035 1280 90 VII-036 1280 100 VII-037 1280 90 VII-040 1280 90 VII-052 1280 90 VII-056 1280 100 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 100 VII-059 1280 100 VII-061 1280 90 VII-063 1280 100 VII-064 1280 90 VII-064 1280 100 VII-065 1280 90 VII-066 1280 90 VII-067 1280 100 VII-068 1280 100 VII-088 1280 100 VII-089 1280 90 VII-091 1280 90 VII-095 1280 90 VII-096 1280 100 VII-099 1280 100 VII-100 1280 100 VII-101 1280 90 VII-102 1280 100 VII-103 1280 90 VII-104 1280 90 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 90 VII-111 1280 90 VII-117 1280 100 VII-119 1280 100 VII-123 1280 90 VII-123-a 1280 90 VII-124 1280 90 VII-125 1280 90 VII-132 1280 100 VII-147 1280 100 VII-148 1280 100 VII-149 1280 100 VIII-001 1280 90 VIII-002 1280 100 VIII-003 1280 90 VIII-004 1280 90 VIII-006 1280 100 VIII-007 1280 100 VIII-008 1280 90 VIII-009 1280 90 VIII-010 1280 100 VIII-011 1280 100 VIII-012 1280 100 X-001 1280 90 X-002 1280 90 X-003 1280 90 X-004 1280 100 X-005 1280 100 X-006 1280 100 X-007 1280 90 X-009 1280 100 X-011 1280 90 X-019 1280 90 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-026 1280 90 X-029 1280 90 X-033 1280 100 X-039 1280 90

TABLE-US-00049 TABLE 35 Post-emergence action against KCHSC Example number Dosage [g/ha] KCHSC II-004 1280 90 II-012 1280 100 IV-001 1280 90 IV-002 1280 90 IX-001 1280 90 VI-003 1280 90 VI-005 1280 90 VI-006 1280 90 VI-008 1280 90 VI-011 1280 90 VI-012 1280 90 VI-013 1280 100 VI-018 1280 90 VII-008 1280 90 VII-012 1280 90 VII-018 1280 90 VII-019 1280 90 VII-026 1280 90 VII-029 1280 90 VII-030 1280 90 VII-040 1280 90 VII-057 1280 90 VII-059 1280 100 VII-061 1280 90 VII-062 1280 90 VII-064 1280 90 VII-064 1280 90 VII-065 1280 100 VII-066 1280 90 VII-068 1280 90 VII-069 1280 90 VII-095 1280 100 VII-096 1280 90 VII-099 1280 100 VII-100 1280 90 VII-101 1280 90 VII-102 1280 90 VII-106 1280 100 VII-108 1280 90 VII-109 1280 90 VII-118 1280 90 VII-123-a 1280 90 VII-124 1280 90 VII-125 1280 90 VII-132 1280 100 VII-147 1280 90 VIII-006 1280 90 VIII-009 1280 90 VIII-010 1280 90 X-009 1280 90 X-020 1280 100 X-021-a 1280 100 X-024 1280 90 X-025 1280 90 X-028 1280 90 X-029 1280 90 X-032 1280 90 X-039 1280 90

TABLE-US-00050 TABLE 36 Post-emergence action against MATIN Example number Dosage [g/ha] MATIN I-003 1280 90 II-003 1280 90 II-012 1280 90 II-013 1280 90 II-014 1280 90 II-017 1280 90 II-018 1280 90 IV-002 1280 90 IX-001 1280 90 VI-001 1280 90 VI-002 1280 100 VI-003 1280 100 VI-004 1280 100 VI-005 1280 90 VI-006 1280 100 VI-007 1280 90 VI-008 1280 90 VI-013 1280 100 VI-016 1280 90 VI-018 1280 100 VII-002 1280 90 VII-003 1280 100 VII-008 1280 90 VII-009 1280 100 VII-010 1280 90 VII-012 1280 100 VII-012 1280 90 VII-015 1280 100 VII-016 1280 100 VII-018 1280 90 VII-023 1280 90 VII-025 1280 90 VII-026 1280 90 VII-028 1280 90 VII-031 1280 100 VII-032 1280 90 VII-035 1280 90 VII-036 1280 100 VII-037 1280 90 VII-040 1280 90 VII-052 1280 100 VII-056 1280 100 VII-056-a 1280 100 VII-057 1280 100 VII-058 1280 90 VII-059 1280 100 VII-061 1280 100 VII-063 1280 90 VII-064 1280 100 VII-064 1280 90 VII-065 1280 100 VII-066 1280 90 VII-067 1280 90 VII-068 1280 90 VII-069 1280 90 VII-088 1280 100 VII-089 1280 90 VII-090 1280 90 VII-091 1280 90 VII-095 1280 100 VII-096 1280 90 VII-097 1280 90 VII-098 1280 100 VII-099 1280 100 VII-100 1280 90 VII-101 1280 100 VII-102 1280 100 VII-103 1280 90 VII-104 1280 100 VII-105 1280 100 VII-106 1280 90 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-117 1280 90 VII-118 1280 90 VII-119 1280 100 VII-123 1280 90 VII-123-a 1280 90 VII-124 1280 100 VII-125 1280 90 VII-132 1280 90 VII-147 1280 100 VII-148 1280 100 VII-149 1280 100 VIII-001 1280 90 VIII-002 1280 90 VIII-004 1280 90 VIII-006 1280 100 VIII-007 1280 90 VIII-008 1280 90 VIII-009 1280 90 VIII-010 1280 100 VIII-011 1280 90 VIII-012 1280 100 X-003 1280 100 X-004 1280 90 X-005 1280 100 X-006 1280 100 X-007 1280 90 X-009 1280 90 X-011 1280 100 X-020 1280 90 X-021-a 1280 90 X-023 1280 100 X-024 1280 90 X-025 1280 90 X-026 1280 100 X-028 1280 100 X-032 1280 90 X-033 1280 100 X-038 1280 100 X-039 1280 100 X-040 1280 100

TABLE-US-00051 TABLE 37 Post-emergence action against STEME Example number Dosage [g/ha] STEME IV-002 1280 100 IX-001 1280 100 VI-001 1280 100 VI-002 1280 90 VI-004 1280 90 VI-005 1280 100 VI-006 1280 100 VI-007 1280 100 VI-008 1280 90 VI-011 1280 100 VI-012 1280 90 VI-013 1280 100 VI-018 1280 90 VII-002 1280 90 VII-003 1280 100 VII-008 1280 100 VII-009 1280 100 VII-010 1280 100 VII-012 1280 100 VII-012 1280 100 VII-014 1280 90 VII-015 1280 100 VII-016 1280 100 VII-018 1280 100 VII-019 1280 100 VII-023 1280 100 VII-025 1280 100 VII-026 1280 100 VII-028 1280 100 VII-029 1280 100 VII-030 1280 100 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-058 1280 90 VII-059 1280 100 VII-061 1280 100 VII-062 1280 100 VII-063 1280 100 VII-064 1280 100 VII-064 1280 100 VII-065 1280 100 VII-066 1280 100 VII-069 1280 90 VII-088 1280 90 VII-089 1280 100 VII-091 1280 90 VII-095 1280 90 VII-096 1280 100 VII-097 1280 90 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-104 1280 90 VII-105 1280 100 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 100 VII-118 1280 100 VII-119 1280 100 VII-123-a 1280 100 VII-124 1280 100 VII-125 1280 90 VII-147 1280 100 VIII-001 1280 100 VIII-002 1280 100 VIII-003 1280 100 VIII-004 1280 100 VIII-006 1280 100 VIII-007 1280 100 VIII-008 1280 90 VIII-010 1280 100 VIII-012 1280 90 X-002 1280 90 X-003 1280 90 X-004 1280 100 X-005 1280 90 X-006 1280 100 X-007 1280 100 X-009 1280 100 X-020 1280 100 X-023 1280 100 X-024 1280 100 X-026 1280 100 X-028 1280 90 X-039 1280 100

TABLE-US-00052 TABLE 38 Post-emergence action against VERPE Example number Dosage [g/ha] VERPE I-002 1280 90 I-003 1280 90 I-004 1280 100 II-003 1280 100 II-004 1280 100 II-012 1280 100 II-013 1280 90 II-014 1280 90 II-017 1280 90 IV-001 1280 90 IV-002 1280 90 IV-003 1280 90 IX-001 1280 100 VI-001 1280 100 VI-002 1280 90 VI-003 1280 90 VI-004 1280 90 VI-005 1280 90 VI-006 1280 90 VI-007 1280 90 VI-012 1280 90 VI-013 1280 100 VI-016 1280 90 VI-018 1280 100 VII-003 1280 90 VII-008 1280 100 VII-009 1280 90 VII-010 1280 90 VII-012 1280 90 VII-012 1280 90 VII-013 1280 100 VII-014 1280 90 VII-015 1280 100 VII-016 1280 90 VII-017 1280 100 VII-018 1280 90 VII-019 1280 90 VII-022 1280 90 VII-023 1280 100 VII-025 1280 100 VII-026 1280 100 VII-027 1280 90 VII-028 1280 90 VII-029 1280 90 VII-030 1280 90 VII-031 1280 100 VII-032 1280 100 VII-035 1280 100 VII-036 1280 100 VII-037 1280 100 VII-040 1280 100 VII-052 1280 100 VII-056 1280 90 VII-056-a 1280 100 VII-057 1280 90 VII-058 1280 90 VII-059 1280 90 VII-061 1280 100 VII-062 1280 100 VII-063 1280 90 VII-064 1280 100 VII-064 1280 100 VII-065 1280 90 VII-066 1280 90 VII-068 1280 100 VII-069 1280 100 VII-089 1280 90 VII-090 1280 100 VII-091 1280 100 VII-095 1280 90 VII-096 1280 90 VII-097 1280 100 VII-098 1280 90 VII-099 1280 100 VII-100 1280 100 VII-101 1280 100 VII-102 1280 100 VII-103 1280 100 VII-104 1280 90 VII-105 1280 90 VII-106 1280 100 VII-107 1280 100 VII-108 1280 100 VII-109 1280 100 VII-110 1280 100 VII-111 1280 90 VII-117 1280 100 VII-119 1280 100 VII-123 1280 90 VII-123-a 1280 90 VII-124 1280 100 VII-125 1280 100 VII-132 1280 90 VII-147 1280 100 VII-149 1280 90 VIII-001 1280 100 VIII-002 1280 90 VIII-003 1280 90 VIII-004 1280 90 VIII-006 1280 90 VIII-007 1280 100 VIII-008 1280 90 VIII-009 1280 100 VIII-010 1280 90 VIII-011 1280 100 VIII-012 1280 90 X-001 1280 100 X-002 1280 90 X-003 1280 90 X-004 1280 100 X-005 1280 100 X-006 1280 90 X-007 1280 90 X-009 1280 100 X-011 1280 90 X-019 1280 90 X-020 1280 100 X-021-a 1280 100 X-023 1280 100 X-024 1280 100 X-025 1280 100 X-026 1280 90 X-027 1280 100 X-028 1280 100 X-029 1280 100 X-032 1280 100 X-033 1280 100 X-038 1280 100 X-039 1280 100 X-040 1280 100

[0497] As shown by the results, compounds of the general formula (I) of the invention, in post-emergence treatment, have very good herbicidal efficacy (90% to 100% herbicidal action) against harmful plants such as Abutilon theophrasti, Digitaria sanguinalis, Echinochloa crus-galli, Matricaria inodora, Poa annua, at an application rate of 1.28 kg of active substance per hectare.

[0498] Accordingly, the compounds of the invention have good herbicidal action against a broad spectrum of weed grasses and broad-leaved weeds and are therefore suitable for controlling unwanted vegetation by the post-emergence method. [0499] b) Seeds of monocotyledonous and dicotyledonous weeds and crop plants are placed in sandy loam in plastic or organic planting pots, covered with soil and cultivated in a greenhouse under controlled growth conditions. 2 to 3 weeks after sowing, the test plants are treated at the one-leaf stage. The compounds of the invention, formulated in the form of wettable powders (WP) or as emulsion concentrates (EC), are then sprayed onto the green parts of the plants as aqueous suspension or emulsion with addition of 0.5% additive at a water application rate of 600 l/ha (converted). After the test plants have been kept in the greenhouse under optimum growth conditions for about 3 weeks, the activity of the preparations is rated visually in comparison to untreated controls. For example, 100% activity=the plants have died, 0% activity=like control plants.

[0500] Tables 39 to 49 below show the effects of selected compounds of the general formula (I) according to Tables 1 and 2 on various harmful plants and at an application rate corresponding to 320 g/ha, which were obtained by the experimental procedure mentioned above.

TABLE-US-00053 TABLE 39 Post-emergence action against ALOMY Example number Dosage [g/ha] ALOMY VI-001 320 90 VI-011 320 90 VI-013 320 80 VII-001 320 90 VII-002 320 100 VII-003 320 80 VII-004 320 90 VII-005 320 100 VII-008 320 100 VII-010 320 90 VII-012 320 90 VII-012 320 90 VII-014 320 90 VII-015 320 90 VII-016 320 90 VII-018 320 90 VII-019 320 100 VII-023 320 90 VII-025 320 100 VII-026 320 100 VII-028 320 80 VII-029 320 100 VII-031 320 100 VII-032 320 90 VII-034 320 90 VII-035 320 90 VII-036 320 90 VII-037 320 100 VII-040 320 100 VII-052 320 90 VII-056-a 320 90 VII-057 320 80 VII-062 320 90 VII-066 320 90 VII-089 320 90 VII-091 320 90 VII-103 320 100 VII-105 320 90 VII-107 320 90 VII-111 320 100 VII-117 320 90 VII-118 320 90 VII-132 320 90 VII-147 320 90 VIII-001 320 90 VIII-002 320 90 VIII-003 320 90 VIII-004 320 90 VIII-006 320 100 X-001 320 90 X-002 320 100 X-004 320 100 X-005 320 90 X-007 320 100

TABLE-US-00054 TABLE 40 Post-emergence action at 320 g/ha against DIGSA in % Example number Dosage [g/ha] DIGSA VI-001 320 90 VI-004 320 90 VI-007 320 80 VI-011 320 90 VI-013 320 90 VII-001 320 90 VII-003 320 90 VII-004 320 90 VII-005 320 90 VII-008 320 80 VII-010 320 90 VII-012 320 80 VII-012 320 90 VII-014 320 80 VII-015 320 100 VII-019 320 90 VII-023 320 90 VII-025 320 100 VII-026 320 90 VII-031 320 100 VII-032 320 90 VII-034 320 90 VII-035 320 100 VII-036 320 90 VII-037 320 90 VII-052 320 90 VII-057 320 90 VII-062 320 90 VII-066 320 90 VII-089 320 90 VII-091 320 90 VII-103 320 90 VII-107 320 90 VII-111 320 90 VII-117 320 90 VII-118 320 90 VII-132 320 90 VIII-003 320 80 VIII-004 320 90 X-001 320 80 X-002 320 100 X-004 320 90 X-005 320 90

TABLE-US-00055 TABLE 41 Post-emergence action at 320 g/ha against ECHCG in % Example number Dosage [g/ha] ECHCG VI-007 320 80 VII-001 320 100 VII-002 320 90 VII-003 320 90 VII-004 320 90 VII-005 320 90 VII-008 320 90 VII-010 320 90 VII-012 320 90 VII-012 320 90 VII-014 320 80 VII-015 320 90 VII-016 320 80 VII-019 320 90 VII-023 320 80 VII-025 320 90 VII-028 320 80 VII-029 320 80 VII-031 320 90 VII-032 320 90 VII-034 320 90 VII-035 320 90 VII-036 320 80 VII-037 320 80 VII-040 320 80 VII-056-a 320 80 VII-062 320 80 VII-066 320 80 VII-103 320 80 VII-107 320 80 VII-111 320 90 VII-132 320 80 VII-147 320 80 VIII-003 320 80 VIII-004 320 90 VIII-006 320 90 X-001 320 80 X-002 320 100 X-004 320 90 X-005 320 80 X-007 320 80

TABLE-US-00056 TABLE 42 Post-emergence action at 320 g/ha against ABUTH in % Example number Dosage [g/ha] ABUTH VI-001 320 80 VI-004 320 80 VI-007 320 90 VI-011 320 90 VI-012 320 80 VI-013 320 80 VII-001 320 80 VII-002 320 80 VII-003 320 80 VII-005 320 80 VII-008 320 90 VII-010 320 80 VII-012 320 80 VII-015 320 90 VII-016 320 90 VII-018 320 80 VII-019 320 80 VII-023 320 90 VII-025 320 90 VII-026 320 80 VII-028 320 80 VII-029 320 80 VII-031 320 90 VII-032 320 80 VII-034 320 80 VII-035 320 90 VII-040 320 90 VII-111 320 80 X-001 320 80 X-002 320 90 X-004 320 80

TABLE-US-00057 TABLE 43 Post-emergence action at 320 g/ha against AMARE in % Example number Dosage [g/ha] AMARE VI-004 320 90 VI-007 320 80 VI-011 320 80 VI-012 320 80 VI-013 320 90 VII-001 320 90 VII-003 320 90 VII-004 320 90 VII-008 320 90 VII-010 320 90 VII-012 320 90 VII-012 320 80 VII-014 320 90 VII-015 320 90 VII-016 320 90 VII-018 320 90 VII-019 320 80 VII-023 320 90 VII-025 320 90 VII-026 320 90 VII-028 320 80 VII-031 320 90 VII-032 320 90 VII-034 320 80 VII-035 320 90 VII-040 320 90 VII-089 320 80 VII-111 320 90 VII-132 320 90 VIII-002 320 80 VIII-004 320 90 VIII-006 320 80 X-001 320 80 X-002 320 100 X-004 320 90 X-005 320 80

TABLE-US-00058 TABLE 44 Post-emergence action at 320 g/ha against SETVI in % Example number Dosage [g/ha] SETVI VI-001 320 80 VI-004 320 80 VI-011 320 90 VI-012 320 90 VI-013 320 90 VII-001 320 90 VII-002 320 80 VII-004 320 90 VII-005 320 80 VII-008 320 100 VII-010 320 90 VII-012 320 100 VII-012 320 80 VII-014 320 100 VII-015 320 100 VII-016 320 80 VII-018 320 80 VII-019 320 80 VII-025 320 100 VII-026 320 90 VII-028 320 80 VII-031 320 90 VII-032 320 80 VII-034 320 90 VII-035 320 90 VII-036 320 90 VII-037 320 80 VII-040 320 100 VII-056-a 320 80 VII-057 320 80 VII-091 320 80 VII-103 320 80 VII-107 320 80 VII-111 320 90 VII-117 320 80 VII-118 320 80 VII-147 320 80 VIII-001 320 80 VIII-004 320 80 VIII-006 320 90 X-001 320 90 X-002 320 90 X-004 320 90 X-005 320 90 X-007 320 80

TABLE-US-00059 TABLE 45 Post-emergence action at 320 g/ha against PHBPU in % Example number Dosage [g/ha] PHBPU VI-004 320 80 VI-007 320 90 VI-012 320 80 VI-013 320 80 VII-001 320 90 VII-002 320 90 VII-003 320 90 VII-005 320 90 VII-008 320 80 VII-010 320 90 VII-012 320 90 VII-012 320 80 VII-015 320 90 VII-016 320 90 VII-018 320 90 VII-019 320 90 VII-023 320 90 VII-025 320 90 VII-028 320 90 VII-031 320 90 VII-032 320 90 VII-034 320 90 VII-035 320 100 VII-036 320 80 VII-037 320 80 VII-040 320 90 VII-052 320 80 VII-062 320 80 VII-089 320 80 VII-103 320 80 VII-111 320 80 VII-132 320 90 VII-147 320 90 VIII-003 320 80 VIII-004 320 90 X-001 320 80 X-002 320 90 X-004 320 90 X-005 320 80

TABLE-US-00060 TABLE 46 Post-emergence action at 320 g/ha against POLCO in % Example number Dosage [g/ha] POLCO VI-001 320 90 VI-004 320 80 VI-007 320 80 VI-011 320 80 VII-001 320 80 VII-002 320 80 VII-003 320 90 VII-004 320 80 VII-005 320 80 VII-010 320 80 VII-012 320 90 VII-012 320 80 VII-014 320 80 VII-015 320 100 VII-016 320 90 VII-018 320 90 VII-019 320 90 VII-023 320 90 VII-025 320 90 VII-026 320 90 VII-029 320 80 VII-031 320 90 VII-032 320 80 VII-034 320 80 VII-035 320 90 VII-040 320 90 VII-111 320 90 VIII-001 320 90 VIII-002 320 80 VIII-003 320 80 VIII-004 320 80 X-001 320 80 X-002 320 90 X-004 320 80 X-005 320 80

TABLE-US-00061 TABLE 47 Post-emergence action at 320 g/ha against VIOTR in % Example number Dosage [g/ha] VIOTR VI-004 320 80 VI-007 320 90 VI-011 320 90 VI-012 320 100 VI-013 320 90 VII-001 320 80 VII-002 320 90 VII-003 320 90 VII-004 320 90 VII-005 320 100 VII-008 320 90 VII-010 320 80 VII-012 320 90 VII-012 320 90 VII-014 320 90 VII-015 320 90 VII-016 320 80 VII-018 320 90 VII-019 320 90 VII-023 320 80 VII-025 320 90 VII-026 320 90 VII-028 320 80 VII-029 320 100 VII-031 320 90 VII-032 320 90 VII-034 320 80 VII-035 320 90 VII-036 320 80 VII-037 320 80 VII-040 320 90 VII-052 320 80 VII-057 320 80 VII-062 320 80 VII-066 320 80 VII-107 320 80 VII-111 320 90 VII-117 320 80 VII-132 320 80 VIII-001 320 80 VIII-002 320 80 VIII-003 320 80 VIII-004 320 90 X-002 320 90 X-004 320 80 X-005 320 80 X-007 320 80

TABLE-US-00062 TABLE 48 Post-emergence action at 320 g/ha against AVEFA in % Example number Dosage [g/ha] AVEFA VI-001 320 80 VI-004 320 100 VI-007 320 100 VI-011 320 90 VI-012 320 90 VI-013 320 80 VI-016 320 90 VII-001 320 90 VII-002 320 100 VII-003 320 80 VII-004 320 90 VII-005 320 100 VII-008 320 90 VII-010 320 100 VII-012 320 90 VII-012 320 90 VII-014 320 90 VII-015 320 90 VII-016 320 80 VII-018 320 80 VII-019 320 100 VII-023 320 80 VII-025 320 90 VII-026 320 80 VII-028 320 80 VII-029 320 90 VII-031 320 90 VII-032 320 100 VII-034 320 90 VII-035 320 90 VII-036 320 80 VII-037 320 80 VII-040 320 90 VII-052 320 90 VII-062 320 90 VII-089 320 80 VII-091 320 80 VII-103 320 80 VII-111 320 90 VII-117 320 90 VII-132 320 80 VII-147 320 80 VIII-001 320 80 VIII-002 320 90 VIII-003 320 90 VIII-004 320 100 VIII-006 320 80 X-001 320 90 X-002 320 100 X-004 320 90 X-005 320 90 X-007 320 80

TABLE-US-00063 TABLE 49 Post-emergence action at 320 g/ha against HORMU in % Example number Dosage [g/ha] HORMU VI-004 320 90 VI-007 320 90 VII-002 320 90 VII-003 320 90 VII-005 320 90 VII-012 320 90 VII-016 320 80 VII-019 320 100 VII-023 320 90 VII-028 320 80 VII-029 320 90 VII-032 320 90 VIII-001 320 80 VIII-004 320 90

[0501] As shown by the results, compounds of the general formula (I) of the invention, in post-emergence treatment, have very good herbicidal efficacy (90% to 100% herbicidal action) against harmful plants such as Abutilon theophrasti, Digitaria sanguinalis, Echinochloa crus-galli, Matricaria inodora, Poa annua, at an application rate of 320 g of active substance per hectare.

[0502] Accordingly, the compounds of the invention have good herbicidal action against a broad spectrum of weed grasses and broad-leaved weeds and are therefore suitable for controlling unwanted vegetation by the post-emergence method.