PHOTODETECTOR ARRAY AND METHOD OF MANUFACTURING THE SAME, AS WELL AS AN IMAGING DEVICE INCLUDING THE PHOTODETECTOR ARRAY
20210408125 · 2021-12-30
Assignee
Inventors
- Gerwin Hermanus GELINCK (Valkenswaard, NL)
- Auke Jisk KRONEMEIJER (Eindhoven, NL)
- Jan-Laurens Pieter Jacobus VAN DER STEEN (Zaltbommel, NL)
Cpc classification
International classification
Abstract
A photodetector array (1) is provided comprising a plurality of pixels (10.sub.ij) between a supply line (4j) and a common electrode (2). Respective pixels (10.sub.ij) comprise a photon radiation sensitive element (11.sub.ij) arranged in a series connection with a switching element (20.sub.ij) characterized in that the series connection further includes a resistive element (30ij).
Claims
1. A photodetector array, comprising a plurality of pixels between a supply line and a common electrode, respective pixels comprising a photon radiation sensitive element arranged in a series connection with a switching element characterized in that the series connection further includes a resistor, which has a resistive value in the range of 0.05 to 0.4 times a reference resistive value, being defined as the median value of the resistive values of the switching elements of the respective pixels in the array in their conductive state.
2. The photodetector array according to claim 1, wherein the resistive value is in the range of 0.05 to 0.2 times the reference resistive value.
3. The photodetector array according to claim 1, wherein the resistor is a thin film resistor.
4. The photodetector array according to claim 3, wherein each thin-film resistor is provided in a vertical interconnect area of each photon radiation sensitive element.
5. The photodetector array according to claim 1, wherein a controllable channel of the switching element and the thin-film resistor respectively are formed in a first and a second regions of a continuous portion of a layer of semiconductor material and wherein these regions are mutually differently doped to provide that a resistive value of the first region has a resistive value that is higher than a resistive value of the second region in a conductive state of the switching element, and lower than a resistive value of the second region in a non-conductive state of the switching element.
6. The photodetector array according to one claim 1 wherein the resistor is formed as a portion with a restricted cross-section in an electrically conductive element in said series connection.
7. The photodetector array according to claim 1, wherein the photon radiation sensitive elements include a photon radiation sensitive layer of an organic material.
8. The photodetector array according to claim 1, wherein the photon radiation sensitive elements are sensitive for X-ray radiation.
9. Imaging device comprising a photodetector array according to claim 1, wherein the supply line is one of a plurality of supply lines, a respective further plurality of pixels being coupled between each supply line and the common electrode, the plurality of supply lines being column lines driven by a column driver, and further comprising a plurality of row lines driven by a row driver, wherein a respective pixel of each plurality of pixels has a control electrode of their switching element coupled to a respective one of the row lines.
10. A method of manufacturing an organic photodetector array, comprising the following steps: providing a substrate, optionally with an insulating layer; providing a first stack of layers to form at least one supply line, a plurality of switching elements forming a respective controllable electrically conductive channel between the at least one supply line and respective electric contacts, and a plurality of control lines for controlling respective ones of said plurality of switching elements to control an electrical connection between said at least one supply line and said respective electric contacts; providing a second stack of layers comprising at least a photon radiation sensitive layer defining respective photon radiation sensitive zones that are electrically connected to respective ones of said electric contacts at a first side of said at least a photon radiation sensitive layer, further comprising a transparent electrically conductive layer that forms a common electrode on a second side of said at least a photon radiation sensitive layer opposite the first side; wherein a respective controllable electrically conductive path is formed between the at least one supply line and the common electrode via a respective switching element and a respective photon radiation sensitive zone, characterized by providing the controllable electrically conductive paths with a respective series resistor, which has a resistive value in the range of 0.05 to 0.4 times a reference resistive value, being defined as the median value of the resistive values of the switching elements of the respective pixels in the array in their conductive state.
11. The method according to claim 10, comprising subsequent to providing the first stack of layers and before providing the second stack of layers: providing a first intermediary patterned layer of an insulating material that defines respective openings towards said respective contacts, and a step of forming a respective series resistance for the controllable electrically conductive paths by applying a surface treatment to the respective contacts within said openings; wherein in providing the second stack of layers comprising, a first layer of said second stack protrudes into the respective openings to form an electric contact with the respective contacts exposed therein.
12. The method according to claim 11, wherein the surface treatment includes the formation of a self assembled monolayer on top of the exposed respective contacts.
13. The method according to claim 10, comprising subsequent to providing the first stack of layers and before providing the second stack of layers: providing a first intermediary patterned layer of an insulating material that defines respective openings towards said respective contacts; providing a second intermediary patterned layer of an electrically conductive material, wherein the electrically conductive material is allowed to penetrate the openings and to contact the respective contacts within said openings, wherein the electrically conductive material of the second intermediary patterned layer in the openings forms a respective series resistance for the controllable electrically conductive paths determined by the thickness of the first intermediary patterned layer and the cross-sectional area of the openings; providing a third intermediary patterned layer of an insulating material having second openings extending towards the second intermediary patterned layer, wherein in providing the second stack of layers comprising, a first layer of said second stack protrudes into the second openings to form respective electric contacts with the second intermediary patterned layer.
14. The method according to claim 10, comprising before providing the second stack of layers: selectively modifying a target layer from said first stack of layers that forms the respective controllable electrically conductive channels, wherein a respective portion of said layer that connects a respective controllable electrically conductive channel with the at least one supply line and/or a respective portion of said layer that connects a respective controllable electrically conductive channel with a respective electric contacts has a higher specific resistance as compared to that of the respective controllable electrically conductive channels.
15. The method according to claim 10, wherein the common electrode is an anode of Indium Gallium Zinc Oxide (IGZO), wherein the common electrode is selectively doped by one or more of H2 doping, deep UV illumination, Ca-based treatment outside these regions for a reduction of electrical resistance, to achieve that a local value of a resistance of the common electrode in regions defined by the photon radiation sensitive elements is higher than a value of a resistance of the common electrode outside these regions.
16. Imaging device comprising a photodetector array according to claim 3, wherein the supply line is one of a plurality of supply lines, a respective further plurality of pixels being coupled between each supply line and the common electrode, the plurality of supply lines being column lines driven by a column driver, and further comprising a plurality of row lines driven by a row driver, wherein a respective pixel of each plurality of pixels has a control electrode of their switching element coupled to a respective one of the row lines.
17. Imaging device comprising a photodetector array according to claim 4, wherein the supply line is one of a plurality of supply lines, a respective further plurality of pixels being coupled between each supply line and the common electrode, the plurality of supply lines being column lines driven by a column driver, and further comprising a plurality of row lines driven by a row driver, wherein a respective pixel of each plurality of pixels has a control electrode of their switching element coupled to a respective one of the row lines.
18. Imaging device comprising a photodetector array according to claim 5, wherein the supply line is one of a plurality of supply lines, a respective further plurality of pixels being coupled between each supply line and the common electrode, the plurality of supply lines being column lines driven by a column driver, and further comprising a plurality of row lines driven by a row driver, wherein a respective pixel of each plurality of pixels has a control electrode of their switching element coupled to a respective one of the row lines.
19. Imaging device comprising a photodetector array according to claim 6, wherein the supply line is one of a plurality of supply lines, a respective further plurality of pixels being coupled between each supply line and the common electrode, the plurality of supply lines being column lines driven by a column driver, and further comprising a plurality of row lines driven by a row driver, wherein a respective pixel of each plurality of pixels has a control electrode of their switching element coupled to a respective one of the row lines.
20. Imaging device comprising a photodetector array according to claim 8, wherein the supply line is one of a plurality of supply lines, a respective further plurality of pixels being coupled between each supply line and the common electrode, the plurality of supply lines being column lines driven by a column driver, and further comprising a plurality of row lines driven by a row driver, wherein a respective pixel of each plurality of pixels has a control electrode of their switching element coupled to a respective one of the row lines
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0033] These and other aspects are described in more detail with reference to the drawing. Therein:
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
[0040]
DESCRIPTION OF EMBODIMENTS
[0041]
[0042]
[0043] In operation row driver 7 selectively activates one of the row electrodes, for example row electrode 5.sub.i, therewith setting the switching elements connected thereto, in this example including switching element 20ij, in a conductive state. This enables the column driver 6 to detect a magnitude of a current through its column electrodes, e.g. column electrode j. The current through column electrode j in this example is indicative for an intensity of radiation, e.g. X-ray radiation, impingent upon the photon radiation sensitive element 11ij. Main processing unit 8 may receive output signals from column driver 6, representative for the detected magnitudes. The plurality of signals for the detected magnitudes for each of the pixels represents image data. As is further shown in
[0044]
[0045] In the exemplary embodiment of
[0046] Various methods are available to locally dope the first regions to reduce its sheet resistance. Examples thereof are H2 doping, deep UV illumination, and Ca-based treatment. Alternatively it is possible to locally reduce a doping level. In addition to, or as an alternative for controlling the amount of doping, standard lithographic techniques may be applied to e.g. fabricate restrictions in the semiconductor material. Using one or more of these approaches, the actual resistance of the thin-film resistor can be tuned. In embodiments, the resistive value of the second region 44B is in a range of 0.05 to 0.2 times (for example 0.1 times) a normal resistive value of the switching element 20ij in its conductive state.
[0047] Another embodiment is illustrated in
[0048] In another embodiment, shown in
[0049] It is noted that the above-mentioned embodiments are not mutually exclusive. For example a protective resistive means in a path from the supply line via the switching element and via the photon radiation sensitive element to the common electrode may be provided by a combination of two or more resistive elements in various positions in the path, for example two or more of a resistive element at a position between the supply line and the switching element, at a position between the switching element and the photon radiation sensitive element and at a position between the photon radiation sensitive element and the common electrode.
[0050]
[0051] In this connection it is noted that the wording “providing a (patterned) layer” is intended to refer to any step or sequence of steps that results in the specified layer.
[0052] The inorganic layers may be provided by all kinds of physical vapour deposition methods such as thermal evaporation, e-beam evaporation, sputtering, magnetron sputtering, reactive sputtering, reactive evaporation, etc. and all kinds of chemical vapour deposition methods such as thermal chemical vapour deposition (CVD), photo assisted chemical vapour deposition (PACVD), plasma enhanced chemical vapour deposition (PECVD), etc.
[0053] Organic layers may be applied by all kinds of coatings techniques, such spin coating, slot-die coating, kiss-coating, hot-melt coating, spray coating, etc. and all kinds of printing techniques, such as inkjet printing, gravure printing, flexographic printing, screen printing, rotary screen printing, etc.
[0054] For example a layer may be provided by printing, coating, sputtering, chemical vapor deposition, physical vapor deposition and the like. Providing a layer may further include subsequent steps like curing and drying. A patterned layer may be provided by a subsequent patterning stage of an initially homogeneously deposited layer, but alternatively a deposition method may be used that directly provides a patterned layer, e.g. by printing or a deposition method using a shadow mask. Also it may be contemplated to apply a further patterning step to an already patterned layer.
[0055] Depending on specific requirements the materials to be used may be of an organic or of an inorganic nature. Often use of organic materials may be preferred, as this allows relatively simple deposition and processing methods.
[0056] The substrate may for example be of an organic material, such as a polymer, but may alternatively be of an inorganic material, such as a glass or a metal.
[0057] Metals, e.g. Al, Au, Cu, Mo, or alloys thereof may be used as an electrically conductive material, but alternatively conducting polymers may be used for this purpose, also conducting compositions of organic and inorganic components may be used. Transparent electrically conductive structures may be provided from a material such as polyaniline, polythiophene, polypyrrole or doped polymers. Apart from organic materials, various inorganic transparent, electrically conducting materials are available like ITO (Indium Tin Oxide), IZO (Indium Zinc Oxide), ATO (Antimony Tin Oxide), or Tin Oxide can be used. Other metal oxides can work, including but not limited to Nickel-Tungsten-Oxide, Indium doped Zinc Oxide, Magnesium-Indium-Oxide. Insulating layers may be of an inorganic material, such as a ceramic material or of a polymer.
[0058] As a semiconductor material for the switching elements 20ij inorganic materials like IGZO (Indium Gallium Zinc Oxide) or hydrogenated amorphous silicon (a-Si:H) may be used. Alternatively semiconducting polymer materials like P3HT, IDTBT?, N2200 are suitable.
[0059] The photon radiation sensitive layer may for example be provided as a bulk-heterojunction or bilayer of a p-type and an n-type organic materials, for example bulk-heterojunction P3HT:PC61BM.
[0060] Perovskites, like organolead trihalide perovskites (CH3NH3PbI3) are also applicable as for use as a photodetector in the photon radiation sensitive layer. Ding discusses these materials in “High-quality inorganic-organic perovskite CH3NH3PbI3 single crystals for photo-detector applications”, J Mater Sci (2017) 52:276-284. See also Wei et al. “Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals” published online: 21 Mar. 2016|DOI: 10.1038/NPHOTON.2016.41
[0061] In an other embodiment the photon radiation sensitive layer comprises one or more of photosensitive materials from the groups of sulfides like PbS, InS, selenides and oxides e.g. ZnO. These materials may be either provided as a thin film or as particle/quantum dot configuration, as is for example described in Konstantatos et al. “Colloidal quantum dot photodetectors”, Infrared Physics & Technology 54 (2011) 278-282. See also Buda et al. “Characterization of high performance PbS photodetectors”
[0062] Still alternatively the photon radiation detection layer may be selenium based, see for example Pace et at: printed photodetectors, Semicond. Sci. Technol. 30 (2015) 104006.
[0063] Optionally the photon radiation sensitive layer may be provided as a combination of two or more of the above.
[0064] Therein
[0065]
[0066]
[0067] The semiconductor used for this purpose is preferably IGZO as its electrical properties can be easily modified by various processes. For example, this semiconductor can be doped in various ways (such as H2 doping, deep UV illumination, Ca-based treatment) to yield a material layer with a low sheet resistance.
[0068] In the so-called Self-Aligned IGZO TFT technology, local regions of deposited IGZO material are selectively (highly) doped, while other regions of the same material are kept ‘intrinsic’. The selective doping can be used to implement a high-resistance IGZO region in the TFT backplane to realize the thin-film resistor in the TFT pixel. By controlling the amount of doping, in combination with standard lithographic techniques to e.g. fabricate restrictions in the IGZO material, the actual resistance of the thin-film resistor can be tuned.
[0069]
[0070] As shown in
[0071] In a further improvement of this embodiment, steps 3D and 3E may be combined in a single processing step in the so-called Self-alignd IGZO TFT technology.
[0072] In step S6, shown in
[0073] In step S7, shown in
[0074] In step S8, shown in
[0075] In step S9, shown in
[0076]
[0077] Subsequently, in step S7A, shown in
[0078] In step S7B shown in
[0079] Step S7B may be succeeded by step S8 and S9 to apply the optically active layer 47 and the at least substantially transparent electrically conductive layer 48.
[0080] In summary, the present invention provides a photodetector array 1, that comprises a plurality of pixels 10.sub.ij between a supply line 4j and a common electrode 2. The pixels 10.sub.ij comprise a respective photon radiation sensitive element 11.sub.ij that is arranged in a series connection with a switching element 20ij. The series connection further includes a resistive element 30ij. Therewith it is achieved that a current through the series connection is limited, even in the inadvertent case that a defect is present in a photon radiation sensitive element. Therewith also in this inadvertent case, the photodetector array is still suitable for normal use.
[0081] The photodetector array may be part of an imaging device wherein the supply line 4j is one of a plurality of supply lines . . . , 4j−2, 4j−1, 4j, 4j+1, 4j+2, . . . and a respective plurality of pixels is coupled between each supply line and the common electrode 2. The plurality of supply lines are column lines driven by a column driver 6. The imaging device further comprises a plurality of row lines . . . , 5i−2, 5i−1, 5i, 5i+1, 5i+2, . . . driven by a row driver 7, wherein a respective pixel 10ij of each plurality of pixels has a control electrode 23ij of their switching element 20ij coupled to a respective one 5i of the row lines.
[0082] The imaging device may additionally comprise an image processing unit 8 configured to receive and process detection signals indicative for an intensity of photon radiation impingent on respective pixels in the photodetector array.
[0083] The image processing unit may be further configured to detect defect pixels in the photodetector array.
[0084] The image processing unit may be further configured to estimate respective detection signal for defect pixels, if those are inadvertently present.
[0085] Embodiments are applicable for use with all types of semiconductor integrated circuit (“IC”) chips. Examples of these IC chips include but are not limited to processors, controllers, chipset components, programmable logic arrays (PLAs), memory chips, network chips, and the like. In addition, in some of the drawings, signal conductor lines are represented with lines. Some may be different, to indicate more constituent signal paths, have a number label, to indicate a number of constituent signal paths, and/or have arrows at one or more ends, to indicate primary information flow direction. This, however, should not be construed in a limiting manner. Rather, such added detail may be used in connection with one or more exemplary embodiments to facilitate easier understanding of a circuit. Any represented signal lines, whether or not having additional information, may actually comprise one or more signals that may travel in multiple directions and may be implemented with any suitable type of signal scheme, e.g., digital or analog lines implemented with differential pairs, optical fiber lines, and/or single-ended lines.
[0086] While the present invention has been described with respect to a limited number of embodiments, those skilled in the art will appreciate numerous modifications and variations therefrom within the scope of this present invention as determined by the appended claims.