Method for producing an electronic component with double quantum dots
11398593 ยท 2022-07-26
Assignee
Inventors
Cpc classification
H01L29/66439
ELECTRICITY
G06N10/00
PHYSICS
B82Y10/00
PERFORMING OPERATIONS; TRANSPORTING
B82Y40/00
PERFORMING OPERATIONS; TRANSPORTING
H10N60/128
ELECTRICITY
H01L29/66977
ELECTRICITY
International classification
H01L29/06
ELECTRICITY
H01L29/66
ELECTRICITY
H01L29/423
ELECTRICITY
Abstract
A process for fabricating an electronic component incorporating double quantum dots and split gates includes providing a substrate surmounted with a stack of a semiconductor layer and of a dielectric layer that is formed above the semiconductor layer. The process also includes forming a mask on the dielectric layer and etching the dielectric layer and the semiconductor layer with the pattern of the mask, so as to form a stack of a semiconductor nanowire and of a dielectric hard mask. Finally, the process includes depositing a gate material on all of the wafer and carrying out a planarization, until the dielectric hard mask is reached, so as to form first and second gates that are electrically insulated from each other on either side of said nanowire.
Claims
1. A process for fabricating an electronic component incorporating double quantum dots and split gates, the electronic component comprising a substrate surmounted with a stack including a semiconductor layer and a dielectric layer that is formed above the semiconductor layer, the process comprising: forming a mask on the dielectric layer; etching the dielectric layer and the semiconductor layer with the pattern of the mask, so as to form a stack including a semiconductor nanowire and a dielectric hard mask, the semiconductor nanowire being configured to contain the double quantum dots; depositing a gate material on the stack including the semiconductor nanowire and the dielectric hard mask and on the substrate; carrying out a planarization, until the dielectric hard mask is reached, so as to form first and second gates that are electrically insulated from each other on either side of said semiconductor nanowire, the first and second gates comprising the split gates.
2. The process as claimed in claim 1, wherein said etching is carried out so that the dielectric hard mask has, on either side, an offset of at least 2 nm with respect to the semiconductor nanowire.
3. The process as claimed in claim 1, wherein said etching is carried out so as to decrease a width of the dielectric hard mask.
4. The process as claimed in claim 1, comprising forming the dielectric hard mask to be asymmetric with respect to a vertical plane passing through a center of the semiconductor nanowire.
5. The process as claimed in claim 1, wherein said semiconductor layer is formed from silicon alloy, the process further comprising forming a thermal-oxide layer by thermal oxidation of a top portion of the semiconductor layer before forming the dielectric layer.
6. The process as claimed in claim 1, wherein said semiconductor nanowire is formed from silicon alloy, and wherein the process further comprises forming lateral faces of a gate insulator by thermal oxidation of edges of the semiconductor nanowire before the deposition of the gate material.
7. The process as claimed in claim 1, wherein said substrate comprises a silicon-on-insulator substrate.
8. The process as claimed in claim 7, further comprising electrically connecting a biasing circuit to said substrate.
9. The process as claimed in claim 1, wherein said deposited gate material comprises doped polysilicon.
10. The process as claimed in claim 1, wherein said semiconductor nanowire has a width comprised between 8 and 30 nm.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Other features and advantages of the invention will become more clearly apparent from the description that is given thereof below, by way of completely nonlimiting indication, with reference to the appended drawings, in which:
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DETAILED DESCRIPTION OF THE EMBODIMENTS OF THE INVENTION
(18) The invention provides a process for fabricating an electronic component incorporating double quantum dots and split gates. The invention proposes to provide a stack of a semiconductor layer and of a dielectric layer that is formed above the semiconductor layer. After formation of a mask on the stack, the dielectric layer and the semiconductor layer are etched with the pattern of the mask to obtain a stack of a semiconductor nanowire and of a dielectric nanowire. A gate material is then deposited on all of the wafer. A chemical planarization is then carried out until the dielectric nanowire is reached, so as to form first and second gates that are electrically insulated from each other by this dielectric nanowire.
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(21) The electronic component 2 is here formed on a silicon-on-insulator substrate. The substrate thus comprises as known per se a silicon layer 10 covered with a buried insulating layer 11 (which lies in a plane including the directions X and Y). A semiconductor nanowire 120 (here made of silicon or of silicon alloy) is formed on the buried insulating layer 11 and extends in the direction X. The silicon nanowire 120 is here illustrated in cross section through its middle portion, which is a region in which quantum dots will be formed. This middle portion of the nanowire 120 is covered with a gate-insulator layer 150, on its top face and on its lateral faces. In this middle portion, a first quantum dot 21 is formed in proximity to a ridge between the top face and one lateral face of the nanowire 120, a second quantum dot 22 being formed in proximity to a ridge between the top face and the other lateral face of the nanowire 120. The quantum dots are configured to trap a single particle (an electron or a hole as appropriate) in order to allow the state of its spin to be modified or read. A hard mask made of dielectric 140 is placed plumb with the semiconductor nanowire 120, on the gate-insulator layer 150. In the middle portion of the nanowire 120, control gates 131 and 132 are produced on either side of the stack of the nanowire 120 and of the hard mask 140. The control gates 131 and 132 are thus electrically insulated from each other, by way of the gate-insulator layer 150 and of the separating hard mask 140.
(22) In the present embodiment, the stack of the nanowire 120 and of the hard mask 140 is symmetric with respect to a plane including the directions X and Z. In the present embodiment, the hard mask 140 is narrower than the stack of the nanowire 120 and of the gate-insulator layer 150. The gates 131 and 132 here extend over the gate insulator 150 and the nanowire 120. Such a configuration makes it easier to position the quantum dots 21 and 22 in proximity to the ridges between the top face and the lateral faces of the gate insulator 150. The quantum dots 21 and 22 may thus be brought closer to each other so as to improve their coupling, and their distance may be smaller than would normally be possible given the minimum photolithography width useable to define the width of the nanowire 120 by etching. Likewise, such a configuration allows a distance between the gates 131 and 132 smaller than the minimum photolithography width to be obtained, using a fabrication process that will be detailed below. Such a configuration allows a nanowire 120 of a minimum width to be used, this allowing interference between the quantum dots to be increased, and thus the potential required to read the quantum dots to be decreased and the read speed of these quantum dots to be increased.
(23) The nanowire 120 extends on either side of the gates 131 and 132 (and of the quantum dots 21 and 22) in the longitudinal direction X. The nanowire 120 thus comprises first and second conduction electrodes formed on either side of the quantum dots 21 and 22. The various electronic components 2 are here connected in series by way of conduction electrodes formed in their semiconductor nanowire 120. A conduction electrode of a first component 2 is connected to the first access 31, a conduction electrode of another component 2 being connected to the second access 32.
(24) The gates of the various components 2 are electrically insulated from one another by partitions 142 made of the same dielectric as the hard mask 140.
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(26) In the present embodiment, the stack of the nanowire 120 and of the hard mask 140 is symmetric with respect to a plane including the directions X and Z. In the present embodiment, the hard mask 140 has the same width as the stack of the nanowire 120 and of the gate-insulator layer 150. The lateral faces of the hard mask 140 are here aligned with the lateral faces of the gate-insulator layer 150. The gates 131 and 132 here do not extend over the gate insulator 150 and nanowire 120. Such a configuration makes it easier to position the quantum dots 21 and 22 toward the lateral faces of the gate insulator 150.
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(28) In the present embodiment, the stack of the nanowire 120 and of the hard mask 140 is not symmetric with respect to a plane including the directions X and Z. In the present embodiment, the hard mask 140 is narrower than the stack of the nanowire 120 and of the gate-insulator layer 150. The gate 131 here extends over the gate insulator 150 and the nanowire 120. In contrast, a lateral face of the hard mask 140 is here aligned with a lateral face of the gate-insulator layer 150, so that the gate 132 does not extend over the gate insulator 150 and nanowire 120.
(29) Such a configuration allows a different behavior to be obtained for the quantum dots 21 and 22, this possibly proving to be advantageous with respect to the operation of the electronic component 2. The quantum dot 21 may then for example be a read quantum dot, the quantum dot 22 then possibly being a manipulation quantum dot.
(30) In addition, this configuration makes it possible to bring the quantum dot 21 closer to the ridge between the upper face and one lateral face of the gate-insulator layer 150. Moreover, such a configuration makes it possible to obtain a distance between the gates 131 and 132 that is smaller than the minimum photolithography width, using a fabrication process that will be detailed below.
(31) In the various embodiments, the gate-insulator layer 150 is advantageously a single dielectric layer and advantageously a single layer made of a homogenous dielectric. It is also possible to envision the gate-insulator layer 150 being a superposition of a dielectric layer and of an interface layer. Advantageously, the gate-insulator layer 150 includes no nitride, nor a superposition of a nitride layer and of another dielectric layer.
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(34) The layer 11 may for example be made of SiO.sub.2. The layer 11 may for example have a thickness comprised between 10 and 145 nanometers. Such a layer 11 is frequently designated by the term UTBOX, this allowing the layer 10 to be biased with a view to electrostatic control of the semiconductor nanowire to be formed.
(35) The layer 12 is for example made of unintentionally doped silicon. The layer 12 may for example have a thickness at least equal to 5 nm, and preferably comprised between 8 and 12 nm.
(36) The gate-insulator layer 15 is for example made of SiO.sub.2. The layer 15 may for example have a thickness at least equal to 3 nm, and preferably equal to at least 4 nm. A gate-insulator layer 15 of relatively large thickness promotes the separation of any parasitic charge from the quantum dots to be formed. It is also possible to envision forming the gate-insulator layer 15 from a Hk material, HfO.sub.2 for example.
(37) The dielectric layer 14 is for example made of SiN. The dielectric layer 14 may also be made (nonlimitingly) of SiO2. The layer 14 may for example have a thickness at least equal to 40 nm, and preferably at least equal to 50 nm. The thickness of the layer 14 is defined so as to be able to subsequently carry out a step of planarizing (by chemical-mechanical polishing for example) and possibly of siliciding. A mask is then formed, for example by photolithography, on the dielectric layer 14, in a pattern. The gate-insulator layer 15 is advantageously formed by thermal oxidation of the top face of a layer 12 made of silicon, before the deposition of the gate-insulator layer 15, this making it possible to avoid trapping charge at the interface between this gate-insulator layer 15 and the layer 12. Thus, trapping of charge that could affect the operation of the quantum dots to be formed is avoided.
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(42) A planarization (for example by chemical-mechanical polishing) that is stopped after the hard mask 140 is reached has then been carried out. The planarization may for example be continued until a height of at least 40 nm of the hard mask 140 remains. Thus, gates 131 and 132 are obtained on either side of the stack of the nanowire 120 and of the hard mask 140. The planarization stopped on the hard mask 140 allows the joint between the gate material plumb with the hard mask 140 to be removed, and thus a short-circuit between the gates 131 and 132 to be avoided. The gates 131 and 132 are electrically insulated from each other by way of the dielectric hard mask 140 and by way of the gate-insulator layer 150. The gates 131 and 132 are electrically insulated from the nanowire 120 by way of the gate-insulator layer 150.
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(52) In a way known per se, it is then possible to deposit a passivation layer, then to make contacts to the gates 131 and 132 and the conduction electrodes 181 and 182.
(53) The process for fabricating such an electronic circuit 1 may employ technological steps and materials that are commonplace in fabricating processes in CMOS technology. Therefore, a fabrication process according to the invention may be carried out with a high level of control and at a relatively low cost.
(54) According to one variant, the fabrication process may include an electrical connection of the semiconductor layer 10 to a biasing circuit (not illustrated). If the semiconductor layer 10 is biased and if the layer 11 is sufficiently thin, it is then possible to electrostatically control the nanowire 12 with this bias.
(55) With respect to the steps described with reference to
(56) A planarization (for example by chemical-mechanical polishing) that is stopped after the hard mask 140 is reached is then carried out as described for the first embodiment.
(57) The fabrication process according to the second embodiment may then be continued as described with reference to
(58) With respect to the steps described with reference to
(59) Next, an implantation of H.sub.2 into only one of the lateral faces of the hard mask 140 is carried out. Next, selective etching, for example with HF, is carried out. Next, gate material is deposited on all the wafer as described with reference to
(60) A planarization (for example by chemical-mechanical polishing) that is stopped after the hard mask 140 is reached is then carried out, as described for the first embodiment.
(61) The fabrication process according to the third embodiment may then be continued as described with reference to
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(63) A dielectric hard mask 140 has been formed on the gate insulator 150 of the component 201. A dielectric nanowire 142 has been interposed between the gate insulator of the component 201 and the gate insulator of the component 202. Another dielectric nanowire has been interposed between the gate insulator of the component 202 and the gate insulator of the component 203. The dielectric nanowires have the same width as the nanowires 120 covered with gate insulator. The lateral faces of the dielectric nanowires (and of the hard mask 140) are therefore aligned with the lateral faces of the gate-insulator layers.
(64) In the middle portion of the nanowires 120, control gates 131 and 132 have been produced on either side of the stack of electronic components 201 to 203, over the entire height of this stack. The gates 131 and 132 here do not extend over the gate insulators and nanowires 120.
(65) Such a configuration allows the density of quantum dots for a given substrate area to be increased.
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(67) A dielectric hard mask 140 has been formed on the gate insulator 150 of the component 201 and is not as wide as this gate insulator 150. A dielectric nanowire 142 has been interposed between the gate insulator of the component 201 and the gate insulator of the component 202 and is not as wide as their gate insulators. Another dielectric nanowire has been interposed between the gate insulator of the component 202 and the gate insulator of the component 203 and is not as wide as their gate insulators. The lateral faces of the dielectric nanowires are therefore offset (in the direction Y) with respect to the lateral faces of the gate-insulator layers.
(68) In the middle portion of the nanowires 120, control gates 131 and 132 have been produced on either side of the stack of electronic components 201 to 203, over the entire height of this stack. The gates 131 and 132 here extend over the gate insulators and nanowires 120. With such a configuration of the control gates 131 and 132, it is possible to control four quantum dots for each of the electronic components 201 to 203.
(69) Such a configuration allows the density of quantum dots for a given substrate area to be increased.
(70) In the examples described and illustrated, a silicon-on-insulator substrate has been used. The invention is of course also applicable to bulk substrates.
(71) In the various examples of fabrication processes, the gate-insulator layer 150 is advantageously formed with a single dielectric layer, advantageously a single layer made of a homogenous dielectric. It is also possible to envision the gate-insulator layer 150 being formed in two steps, with a superposition of a dielectric layer and of an interface layer. Advantageously, the formed gate-insulator layer 150 includes no nitride, nor a superposition of a nitride layer and another dielectric layer.