QUARTZ FIBRE WITH HYDROGEN BARRIER LAYER AND METHOD FOR THE PRODUCTION THEREOF
20220227657 · 2022-07-21
Inventors
Cpc classification
C03B2201/20
CHEMISTRY; METALLURGY
C03B37/027
CHEMISTRY; METALLURGY
C03B37/018
CHEMISTRY; METALLURGY
C03B37/01211
CHEMISTRY; METALLURGY
C03C3/06
CHEMISTRY; METALLURGY
International classification
C03B37/012
CHEMISTRY; METALLURGY
C03B37/018
CHEMISTRY; METALLURGY
C03B37/027
CHEMISTRY; METALLURGY
C03C13/04
CHEMISTRY; METALLURGY
Abstract
A method of manufacturing a quartz glass fibre includes producing a quartz glass primary preform by modified chemical vapor deposition (MCVD) in a quartz glass substrate tube and inserting the quartz glass primary preform into a glass jacketing tube. Defect-generating UV radiation is irridiated into the cross-sectional area of the glass jacketing tube while combining the quartz glass primary preform with the glass jacketing tube in the jacketing process to form a cladding layer to a secondary preform. A quartz glass fibre is pulled from the secondary preform.
Claims
1. A method of manufacturing a quartz glass fibre, said method comprising the steps of: a) producing a quartz glass primary preform by modified chemical vapor deposition (MCVD) in a quartz glass substrate tube; b) inserting the quartz glass primary preform into a glass jacketing tube, c) irradiating defect-generating UV radiation into the cross-sectional area of the glass jacketing tube while combining the quartz glass primary preform with the glass jacketing tube in the jacketing process to form a cladding layer on the fibre core to a secondary preform; and d) pulling a quartz glass fibre from the secondary preform.
2. The method of claim 1, wherein the defect-generating UV radiation generates E′ and NBOHC defects in the cladding layer of the quartz fibre.
3. The method of claim 1, wherein the defect-generating UV radiation is irradiated into the glass jacketing tube.
4. The method of claim 1, wherein the glass jacketing tube consists of quartz glass having an OH concentration of ≤0.2 ppm, a chlorine content of 800-2000 ppm, and/or a refractive index of +0.35 to +0.5×10.sup.−3.
5. The method of claim 1, wherein the quartz glass primary preform has a fluorine-doped radial layer on the fibre core.
6. Quartz glass fibre produced or producible by the method of claim 1.
7. Quartz glass fibre, comprising: a) a fibre core of quartz glass, b) a fluorine-doped radial layer on the fibre core, c) a cladding layer of quartz glass, wherein d1) the cladding layer has E′ and NBOHC defects, or, d2) the cladding layer has Si—OH and Si—H compounds.
8. The quartz glass fibre of claim 7, wherein the cladding layer is quartz glass having an OH concentration of ≤3.2 ppm, a chlorine content 800-2000 ppm, and/or a refractive index of +0.35 to +0.5×10.sup.−3 on the fibre core, and wherein the cladding layer preferably has a higher density of E′ and NBOHC defects than the fibre core.
9. The quartz glass fibre of claim 7, wherein the quartz glass fibre has no further doped layers.
10. The quartz glass fibre of claim 7, wherein the quartz glass fibre has no hermetic coating.
Description
[0042] Further objectives, features, advantages and application possibilities result from the following description of exemplary embodiments, which are not to be understood as restrictive, with reference to the associated drawings. Here all features described and/or depicted show by themselves or in any combination the subject matter disclosed here, even independently of their grouping in the claims or their references. The dimensions and proportions of the components shown in the figures are not necessarily to scale in this case; they may diverge in embodiments to be implemented from what is shown here.
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[0052] The cable and the method are now described on the basis of exemplary embodiments.
[0053] Specific details are set out below, without being restricted thereto, to supply a complete understanding of the present disclosure. It is dear to an expert, however, that the present disclosure can be used in other exemplary embodiments that may deviate from the details set out below.
[0054]
[0055] Due to the different preferred polarisation directions, fewer electromagnetic fields can be coupled from the first waveguide element 110 into the second waveguide element 120 and at the same time a space-saving cable 100 can be provided.
[0056] In the example from
[0057] The first and the second dielectric waveguide element 110, 120 can run/be arranged in parallel along the chamber or the cable 100. According to the example from
[0058] The first and the second dielectric waveguide element 110, 120 can each be formed to transmit a high-frequency signal. For example, the first dielectric waveguide element 110 can be used as a transmitting path and the second dielectric waveguide element 120 can be used as a receiving path or vice versa. The first and the second dielectric waveguide element 110, 120 can be used in exactly the same way as transmitting path or receiving path.
[0059] In the example from
[0060] The preferred polarisation direction of the first dielectric waveguide element 110 can be predetermined by a cross section of the first dielectric waveguide element 1100 The preferred polarisation direction of the second dielectric waveguide element 120 can be predetermined by a cross section of the second dielectric waveguide element 120. The preferred polarisation direction of the first dielectric waveguide element 110 can differ from the preferred polarisation direction of the second dielectric waveguide element 120 by an angle of at least 45° (or 60° or 75° or 90°), in particular by 90°. In the example from
[0061] The cross sections of the first and second dielectric waveguide element 110, 120 are identical in
[0062] The cross section of the first and/or second dielectric waveguide element 110, 120 can be elliptical or, as shown by way of example in
[0063] The ratio of a to b can determine the preferred polarisation direction of the first and second dielectric waveguide element 110, 120. If the first and second dielectric waveguide elements 110, 120 are arranged twisted relative to one another in the cable, as is shown in
[0064] A distance between the first and second dielectric waveguides 110, 120 can be smaller than 4 times (or 3 times or 2 times) a side length a or main axis a of the first and/or second dielectric waveguide element 110, 120. Furthermore, a distance between the first and second dielectric waveguides 110, 120 can equal at least a side length a or main axis a of the first and/or second dielectric waveguide element 110, 120.
[0065] The dielectric constants of the first and second dielectric waveguide element 110, 120 can be substantially identical. The dielectric medium 150 can have a different dielectric constant than the first and second dielectric waveguide element 110, 120. The dielectric constant of the dielectric medium 150 can be lower than at least one of the dielectric constants of the first and second dielectric waveguide element 110, 120. The dielectric constants of the first and/or second dielectric waveguide element 110, 120 can deviate at most between 0.5% and 5% from one another, for example.
[0066] In the example from
[0067] The jacket 160 can likewise be conductive. Electromagnetic couplings can be avoided hereby.
[0068] The jacket 160 can also end flush with the dielectric medium 150. Water and oxygen inclusions can be avoided hereby, whereby the cable 100 is rendered more durable.
[0069] The waveguide elements 110, 120 named herein can each consist of a material with a high ε.sub.r. This can be polyethylene (PE), polypropylene (PP), ethylene-tetrafluoroethylene copolymer (ETFE), fluorinated ethylene propylene (FEP), polytetrafluoroethylene (PTFE), polyester (PES), polyethylene terephthalate (PET) or also quartz glass.
[0070] The waveguide elements 110, 120 in
[0071] The respective waveguide elements 110, 120 can be surrounded by the dielectric medium 150 with a lower ε.sub.r. This dielectric medium 150 has a lower ε.sub.r than that of the respective waveguide element 110, 120, in order to form the waveguide. Foamed materials (thus mixtures of a gas and a plastic) are preferably used for this, PE, PP, ETFE, FEP, PTFE or also PES can be used here as a polymer. The plastics can be foamed in processing. The foaming can take place here due to a chemical or physical process. The gas bubbles can be smaller than Lambda/4 of a wavelength of a useful frequency of the cable 100 in this case. Another option for the dielectric medium 150 is a banding of expanded PTFE. With this a significantly lower ε.sub.r than that of the respective waveguide elements 110, 120 can likewise be achieved.
[0072] The two waveguide elements 110, 120 (also termed wave-carrying elements or also transmission elements), which are rectangular in
[0073] Further details and aspects are mentioned in connection with the exemplary embodiments described below. The exemplary embodiment shown in
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[0075] The cable 200 further has a fourth dielectric waveguide element 140. The fourth dielectric waveguide element 140 is spaced at a distance from the first, second and third dielectric waveguide elements 110, 120, 130 according to the example from
[0076] Using several waveguides formed by the waveguide elements 110, 120, 130 and 140 and the dielectric medium 150 can provide a greater transmission rate and more throughput. At frequencies of over 100 GHz (without light), a higher bandwidth can likewise be provided.
[0077] A distance between the first and second waveguide element 110, 120, and the second and third waveguide element 120, 130, and the third and fourth waveguide element 130, 140 and also the fourth and first waveguide element 140, 110, is identical hi the example from
[0078] A distance between the first and third waveguide element 110, 130 corresponds in the example from
[0079] B can be √2*A. Even if the first and third waveguide element 110, 130 and the second and fourth waveguide element 120, 140 have the same preferred polarisation direction, a coupling to the respectively other waveguide element can be reduced by the greater distance (√2 times greater).
[0080] The respective distance between the waveguide elements can be determined starting out from a centre of a respective cross section of the waveguide elements in the same cross-sectional plane of the cable 200.
[0081] In the case of a cable 200 with four waveguides 110, 120, 130, 140 inside the cable 200 (formed by four waveguide elements and a dielectric medium 150 around the same), the conditions are comparable with the case of a cable 200 with two waveguides (formed by two waveguide elements and a dielectric medium 150 around the same, see
[0082] Further details and aspects are mentioned in connection with the exemplary embodiments described above or below. The exemplary embodiment shown in
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[0084] Further details and aspects are mentioned in connection with the exemplary embodiments described above or below. The exemplary embodiment shown in
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[0086] In addition, the method can comprise the separate embedding of the first and second (as well as third and fourth) dielectric waveguide elements in segments of the dielectric medium. Furthermore, the method can comprise stranding of the first and second (as well as third and fourth) dielectric waveguide elements embedded in this way to form a waveguide with two (four) waveguides. Sheathing can take place as a separate step to join the stranded elements together to form the cable.
[0087] Further details and aspects are mentioned in connection with the exemplary embodiments described above or below. The exemplary embodiment shown in
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[0093] If great mechanical loads act on the cable 600, it can be advantageous to strand the waveguides (formed by a respective segment of the dielectric medium and a corresponding waveguide element 110, 120, 130, 140). Here each waveguide element 110, 120, 130, 140 can be fabricated together with the dielectric medium 150 as a separate (individual) waveguide of the cable 600. Several individual waveguides of the cable 500 can then be stranded with one another. Stranding with reverse twist can be used in this case. It is thereby guaranteed that the orientations of the waveguides and also of the corresponding waveguide elements 110, 120, 130, 140 are not displaced to one another.
[0094] Moreover, a torsion of the transmission elements 110, 120, 130, 140 negatively affecting the transmission properties can be avoided. It is not absolutely necessary here, however, that the dielectric medium 150 has a round outer contour. A roughly rectangular contour has advantages in the assignment to one another here. This is because round surfaces easily twist in relation to one another, while faces brace one another. A continuation consists in a segmented outer form of the individual components.
[0095] Further details and aspects are mentioned in connection with the exemplary embodiments described above. The exemplary embodiment shown in
[0096] According to one or more of the aforesaid aspects, a cable optimised for crosstalk can be provided with two or four waveguides in a common jacket. The waveguide elements contained in the cable can each have a rectangular or oval cross section (height to width ratio between 1:1.4 to 4). The dielectric medium 150 used in the cable can be one part (common element for all waveguide elements) or a plurality of parts. Each part can then surround a respective waveguide element separately. The parts surrounding the corresponding waveguide elements can then be stranded with one another, e.g, with reverse twist during production, to retain the orientation. These individual parts can have a rectangular or segmented cross section.
[0097] The cable described above can have the following advantages. A dielectric waveguide can be very light and flexible. It does not break, for example, even in the event of maximum reverse bending demands. In addition, a transmission frequency can be extremely high, e.g. in the range of 100 GHz to 150 GHz, or also over 50 GHz, over 70 GHz, over 90 GHz, over 100 GHz, over 120 GHz, over 130 GHz or over 140 GHz. An extremely large data bandwidth can be provided thereby. Moreover, it can be made possible with the structure described to double or quadruple the transmissible bandwidth with respect to a structure with only one. transmission element without channels significantly influencing one another.
[0098] Furthermore, cables of this kind have the advantage of being able to carry no current. Since no conductor is present, therefore, there cannot be any sparks either. A damage risk can be reduced and electromagnetic compatibility improved by this.
[0099] The aspects and features that were mentioned and described together with one or more of the examples and figures described in detail above can further be combined with one or more of the other examples to replace a similar feature of the other example or to introduce the feature additionally into the other example.
[0100] The present disclosure is not limited in any way to the embodiments described previously. On the contrary, many opportunities for modifications thereto are evident to an average expert without departing from the fundamental idea of the present disclosure as defined in the enclosed claims.