Liquid-crystalline medium and high-frequency components comprising same

Abstract

Liquid-crystalline media comprising one or more compounds of formula G ##STR00001##
and one or more compounds selected from the group of compounds of formulae I, II and III, ##STR00002##
in which the parameters have the meaning indicated in claim 1, and components comprising these media, are suitable for use in high-frequency technology, in particular, in phase shifters and microwave array antennas.

Claims

1. A liquid crystal medium, comprising: one or more compounds of formula G-2 ##STR00183## wherein R.sup.1 and R.sup.2 independently of one another, denote unfluorinated alkyl or unfluorinated alkoxy, each having 1 to 15 C atoms, un-fluorinated alkenyl, unfluorinated alkenyloxy or unfluorinated alkoxyalkyl, each having 2 to 15 C atoms; one or more compounds selected from the group of compounds of formulae II-1a and II-1b ##STR00184## in which R.sup.21 and R.sup.22, independently of one another, denote H, unfluorinated alkyl or unfluorinated alkoxy having 1 to 17 C atoms or unfluorinated alkenyl, unfluorinated alkenyloxy or unfluorinated alkoxyalkyl having 2 to 15 C atoms; and one or more compounds of formula IV ##STR00185## wherein ##STR00186## Denotes ##STR00187## R.sup.41 to R.sup.42, independently of one another, denote unfluorinated alkyl or unfluorinated alkoxy, each having 1 to 15 C atoms, unfluorinated alkenyl, unfluorinated alkenyloxy or unfluorinated alkoxyalkyl, each having 2 to 15 C atoms, or cycloalkyl, alkylcycloalkyl, cycloalkenyl, alkylcycloalkenyl, alkylcycloalkylalkyl or alkylcycloalkenylalkyl, each having 3 to 15 C atoms.

2. The liquid crystal medium according to claim 1, wherein said medium further comprises one or more compounds of formula P
P.sup.a-(Sp.sup.a).sub.s1-(A.sup.1-Z.sup.1).sub.n1-A.sup.2-Q-A.sup.3-(Z.sup.4-A.sup.4).sub.n2-(Sp.sup.b).sub.s2-P.sup.b  P wherein the individual radicals have the following meanings: P.sup.a, P.sup.b each, independently of one another, are a polymerizable group, Sp.sup.a, Sp.sup.b each, independently of one another, denote a spacer group, s1, s2 each, independently of one another, denote 0 or 1, n1, n2 each, independently of one another, denote 0 or 1, Q denotes a single bond, —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH.sub.2—, —(CO)O—, —O(CO)—, —(CH.sub.2).sub.4—, —CH.sub.2—CH.sub.2—, —CF.sub.2—CF.sub.2—, —CF.sub.2—CH.sub.2—, —CH.sub.2—CF.sub.2—, —CH═CH—, —CF═CF—, —CF═CH—, —(CH.sub.2).sub.3O—, —O(CH.sub.2).sub.3—, —CH═CF—, —O—, —CH.sub.2—, —(CH.sub.2).sub.3—, or —CF.sub.2—, Z.sup.1, Z.sup.4 each, independently of one another, denote a single bond, —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH.sub.2—, —(CO)O—, —O(CO)—, —(CH.sub.2).sub.4—, —CH.sub.2—CH.sub.2—, —CF.sub.2—CF.sub.2—, —CF.sub.2—CH.sub.2—, —CH.sub.2—CF.sub.2—, —CH═CH—, —CF═CF—, —CF═CH—, —(CH.sub.2).sub.3O—, —O(CH.sub.2).sub.3—, —CH═CF—, —O—, —CH.sub.2—, —(CH.sub.2).sub.3—, —CF.sub.2—, where Z.sup.1 and Q or Z.sup.4 and Q do not simultaneously denote a group selected from —CF.sub.2O— and —OCF.sub.2—, A.sup.1, A.sup.2, A.sup.3, A.sup.4 each, independently of one another, denote a diradical group selected from the following groups: a) the group consisting of trans-1,4-cyclohexylene, 1,4-cyclohexenylene and 1,4′-bicyclohexylene, in which, in addition, one or more non-adjacent CH.sub.2 groups may each be replaced by —O— or —S— and in which, in addition, one or more H atoms may each be replaced by F, b) the group consisting of 1,4-phenylene and 1,3-phenylene, in which, in addition, one or two CH groups may each be replaced by N and in which, in addition, one or more H atoms may each be replaced by L, c) the group consisting of tetrahydropyran-2,5-diyl, 1,3-dioxane-2,5-diyl, tetrahydrofuran-2,5-diyl, cyclobutane-1,3-diyl, piperidine-1,4-diyl, thiophene-2,5-diyl and selenophene-2,5-diyl, each of which is unsubstituted or mono- or polysubstituted by L, d) the group consisting of saturated, partially unsaturated or fully unsaturated, and optionally substituted, polycyclic radicals having 5 to 20 cyclic C atoms, one or more of which may, in addition, each be replaced by heteroatoms, where, in addition, one or more H atoms in these radicals may each be replaced by L, and/or one or more double bonds may each be replaced by single bonds, and/or one or more CH groups may be replaced by N, and A.sup.3, alternatively may be a single bond, and L on each occurrence, identically or differently, denotes F, Cl, CN, SCN, SF.sub.5, straight-chain, optionally fluorinated, alkyl or alkoxy having 1 to 12 C atoms, branched, optionally fluorinated, alkyl or alkoxy having 3 to 12 C atoms, or alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 2 to 12 C atoms, in each case optionally fluorinated.

3. The liquid crystal medium according to claim 1, wherein said medium further comprises one or more compounds selected from the group of compounds of formulae CC and CP ##STR00188## wherein Alkenyl denotes unfluorinated alkenyl having 2 to 15 C atoms, R.sup.01 denotes unfluorinated alkyl having 1 to 17 C atoms or unfluorinated alkenyl having 2 to 15 C atoms, and R.sup.02 denotes unfluorinated alkyl having 1 to 17 C atoms or unfluorinated alkenyl having 2 to 15 C atoms.

4. The liquid crystal medium according to claim 1, wherein said medium comprises one or more chiral compounds having an absolute value of the HTP of 10 μm.sup.−1 or more.

5. The liquid crystal medium according to claim 1, wherein said medium further comprises one or more chiral compounds selected from the group of compounds of formulae A-I to A-VI: ##STR00189## including the (R,S), (S,R), (R,R) and (S,S) enantiomers, which are not shown, ##STR00190## in which R.sup.a11 and R.sup.a12, independently of one another, are alkyl, oxaalkyl or alkenyl having from 2 to 9 carbon atoms, and R.sup.a11 is alternatively methyl or alkoxy having from 1 to 9 carbon atoms, R.sup.a21 and R.sup.a22, independently of one another, are alkyl or alkoxy having from 1 to 9 carbon atoms, oxaalkyl, alkenyl or alkenyloxy having from 2 to 9 carbon atoms, R.sup.a31 and R.sup.a32, independently of one another, are alkyl, oxaalkyl or alkenyl having from 2 to 9 carbon atoms, and R.sup.a31 is alternatively methyl or alkoxy having from 1 to 9 carbon atoms, ##STR00191## are each, independently of one another, 1,4-phenylene, which may also be mono-, di- or trisubstituted by L, or 1,4-cyclohexylene, L is H, F, Cl, CN or optionally halogenated alkyl or alkoxy having 1 to 7 carbon atoms or alkylcarbonyl, alkoxycarbonyl or alkoxycarbonyloxy having 2 to 7 carbon atoms, c is 0 or 1, Z.sup.0 is —CO—O—, —O—CO—, —CH.sub.2CH.sub.2— or a single bond, and R.sup.0 is alkyl-carbonyloxy alkyl or alkoxy having 1 to 12 carbon atoms or alkylcarbonyl, alkoxycarbonyl or alkoxycarbonyloxy having 2 to 12 carbon atoms, X.sup.1, X.sup.2, Y.sup.1 and Y.sup.2 are each, independently of one another, F, Cl, Br, I, CN, SCN, SF.sub.5, a straight-chain alkyl having from 1 to 25 carbon atoms or a branched alkyl having 3 to 25 carbon atoms, which in each case may be monosubstituted or polysubstituted by F, Cl, Br, I or CN and in which, in addition, one or more non-adjacent CH.sub.2 groups may each, independently of one another, be replaced by —O—, —S—, —NH—, NR.sup.0—, —CO—, —CO—O—, —O—CO—, —OC(O)O—, —S—CO—, —CO—S—, —CH═CH— or —C≡C— in such a way that O and/or S atoms are not bonded directly to one another, a polymerizable group or cycloalkyl or aryl having 3 to 20 carbon atoms, which may optionally be monosubstituted or polysubstituted by halogen or by a polymerizable group, x.sup.1 and x.sup.2 are each, independently of one another, 0, 1 or 2, y.sup.1 and y.sup.2 are each, independently of one another, 0, 1, 2, 3 or 4, B.sup.1 and B.sup.2 are each, independently of one another, an aromatic or partially or fully saturated aliphatic six-membered ring in which one or more CH groups may each be replaced by N atoms and one or more non-adjacent CH.sub.2 groups may each be replaced by O or S, W.sup.1 and W.sup.2 are each, independently of one another, Z.sup.1-A.sup.1-(Z.sup.2-A.sup.2).sub.m-R, and one of the two is alternatively R.sup.1 or A.sup.3, but both are not simultaneously H, or ##STR00192## U.sup.1 and U.sup.2 are each, independently of one another, CH.sub.2, O, S, CO or CS, V.sup.1 and V.sup.2 are each, independently of one another, (CH.sub.2).sub.n, in which from one to four non-adjacent CH.sub.2 groups may each be replaced by O or S, and, in the case where ##STR00193## both of V.sup.1 and V.sup.2 are a single bond, Z.sup.1 and Z.sup.2 are each, independently of one another, —O—, —S—, —CO—, —COO—, —OCO—, —O—COO—, —CO—NR.sup.0—, —NR.sup.0—CO—, —O—CH.sub.2—, —CH.sub.2—O—, —S—CH.sub.2—, —CH.sub.2—S—, —CF.sub.2—O—, —O—CF.sub.2—, —CF.sub.2—S—, —S—CF.sub.2—, —CH.sub.2—CH.sub.2—, —CF.sub.2—CH.sub.2—, —CH.sub.2—CF.sub.2—, —CF.sub.2—CF.sub.2—, —CH═N—, —N═CH—, —N═N—, —CH═CH—, —CF═CH—, —CH═CF—, —CF═CF—, —C≡C—, or a combination of two of these groups, where no two O and/or S and/or N atoms are bonded directly to one another, or a single bond, A.sup.1, A.sup.2 and A.sup.3 are each, independently of one another, 1,4-phenylene, in which one or two non-adjacent CH-groups may each be replaced by N, 1,4-cyclohexylene, in which one or two non-adjacent CH.sub.2 groups may each be replaced by O and/or S, 1,3-dioxolane-4,5-diyl, 1,4-cyclohexenylene, 1,4-bicyclo[2.2.2]octylene, piperidine-1,4-diyl, naphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl or 1,2,3,4-tetrahydro-naphthalene-2,6-diyl, where each of these groups is unsubstituted or monosubstituted or polysubstituted by L, and in addition A.sup.1 is a single bond, L is a halogen atom, CN, NO.sub.2, alkyl or alkoxy having 1 to 7 carbon atoms or alkylcarbonyl, alkoxycarbonyl or alkoxycarbonyloxy having 2 to 7 carbon atoms, in which one or more H atoms may be replaced by F or Cl, m is in each case, independently, 0, 1, 2 or 3, and R and R.sup.1 are each, independently of one another, H, F, Cl, Br, I, CN, SCN, SF.sub.5, a straight-chain alkyl having from 1 to 25 carbon atoms or a branched alkyl having 3 to 25 carbon atoms, which in each case may optionally be monosubstituted or polysubstituted by F, Cl, Br, I or CN, and in which one or more non-adjacent CH.sub.2 groups may each be replaced by —O—, —S—, —NH—, —NR.sup.0—, —CO—, —CO—O—, —O—CO—, —O—C(O)O—, —S—CO—, —CO—S—, —CH═CH— or where no two O and/or S atoms are bonded directly to one another, or a polymerizable group.

6. The liquid crystal medium according to claim 1, wherein said medium further contains one or more compounds selected from formulae I-1, I-2, and I-3: ##STR00194## wherein R.sup.11 denotes unfluorinated alkyl having 1 to 7 C atoms or unfluorinated alkenyl having 2 to 7 C atoms, R.sup.12 denotes unfluorinated alkyl having 1 to 7 C atoms or unfluorinated alkenyl having 2 to 7 C atoms or unfluorinated alkoxy having 1 to 7 C atoms, X.sup.11 and X.sup.12, independently of one another, denote F, Cl, —OCF.sub.3, —CF.sub.3, —CN, —NCS or —SF.sub.5, and ##STR00195## independently of one another, denote ##STR00196##

7. The liquid crystal medium according to claim 1, wherein said medium further contains one or more compounds of the formula III: ##STR00197## in which L.sup.31 denotes R.sup.31 or X.sup.31, L.sup.32 denotes R.sup.32 or X.sup.32, R.sup.31 and R.sup.32, independently of one another, denote H, unfluorinated alkyl or unfluorinated alkoxy having 1 to 17 C atoms or unfluorinated alkenyl, unfluorinated alkenyloxy or unfluorinated alkoxyalkyl having 2 to 15 C atoms, X.sup.31 and X.sup.32, independently of one another, denote H, F, Cl, —CN, —NCS, —SF.sub.5, fluorinated alkyl having 1 to 7 C atoms or fluorinated alkenyl, unfluorinated or fluorinated alkenyloxy or unfluorinated or fluorinated alkoxyalkyl having 2 to 7 C atoms, Z.sup.31 to Z.sup.33, independently of one another, denote trans-CH═CH—, trans —CF═CF—, —C≡C— or a single bond, and ##STR00198## independently of one another, denote ##STR00199##

8. The liquid crystal medium according to claim 1, wherein said medium further comprises a polymerization initiator.

9. A method for improving the response time of a liquid-crystal medium according to claim 1 comprising adding one or more chiral compounds.

10. A composite system comprising a liquid-crystal medium according to claim 2 wherein said medium contains a polymer obtained or obtainable from the polymerization of said one or more compounds of formula P.

11. A component for high-frequency technology, comprising a liquid crystal medium according to claim 1.

12. The component according to claim 11, wherein said component is suitable for operation in the microwave range.

13. The component according to claim 11, wherein said component is a phase shifter or a liquid crystal based antenna element operable in the microwave region.

14. A process for preparation of a liquid-crystal medium according to claim 2, said process comprising mixing one or more polymerizable compounds of formula P with one or more compounds of formula G-2, one or more compounds selected from the group of the compounds of the formulae II-1a and II-1b, one or more compounds of formula IV, and optionally with one or more further compounds and/or with one or more additives.

15. A microwave antenna array comprising one or more components according to claim 11.

16. The liquid crystal medium according to claim 1, wherein R.sup.21 and R.sup.22, independently of one another, denote unfluorinated alkyl having 3 to 10 C atoms or unfluorinated alkenyl having 3 to 10 C atoms.

17. The liquid crystal medium according to claim 2, wherein, in formula P, n1 are n2 each 0 and Q is —CF.sub.2O—.

18. The liquid crystal medium according to claim 2, wherein, in formula P, the groups A.sup.1, A.sup.2, A.sup.3, A.sup.4 are each, independently of one another, denote a diradical group selected from the following groups: a) the group consisting of trans-1,4-cyclohexylene, 1,4-cyclohexenylene and 1,4′-bicyclohexylene, in which, in addition, one or more non-adjacent CH.sub.2 groups may each be replaced by —O— or —S— and in which, in addition, one or more H atoms may each be replaced by F, b) the group consisting of 1,4-phenylene and 1,3-phenylene, in which, in addition, one or two CH groups may each be replaced by N and in which, in addition, one or more H atoms may each be replaced by L, c) the group consisting of tetrahydropyran-2,5-diyl, 1,3-dioxane-2,5-diyl, tetrahydrofuran-2,5-diyl, cyclobutane-1,3-diyl, piperidine-1,4-diyl, thiophene-2,5-diyl and selenophene-2,5-diyl, each of which is unsubstituted or mono- or polysubstituted by L, d) the group consisting of bicyclo[1.1.1]pentane-1,3-diyl, bicyclo[2.2.2]octane-1,4-diyl, spiro[3.3]heptane-2,6-diyl, ##STR00200## where, in addition, one or more H atoms in these radicals may each be replaced by L, and/or one or more double bonds may each be replaced by single bonds, and/or one or more CH groups may be replaced by N,  and A.sup.3, alternatively may be a single bond, wherein R.sup.03, R.sup.04 each, independently of one another, denote H, F, a straight-chain alkyl having 1 to 12 C atoms, in which, in addition, one or more H atoms may each be replaced by F, or a branched alkyl having 3 to 12 C atoms, in which, in addition, one or more H atoms may each be replaced by F M denotes —O—, —S—, —CH.sub.2—, —CHY.sup.1— or —CY.sup.1Y.sup.2—, and Y.sup.1 and Y.sup.2 each, independently of one another, denote H, F, Cl, CN, a straight-chain alkyl having 1 to 12 C atoms, in which, in addition, one or more H atoms may each be replaced by F, or a branched alkyl having 3 to 12 C atoms, in which, in addition, one or more H atoms may each be replaced by F, and one of the groups Y.sup.1 and Y.sup.2 alternatively denotes —OCF.sub.3.

19. The liquid crystal medium according to claim 18, Y.sup.1 and Y.sup.2 wherein are each independently H, F, Cl, CN or CF.sub.3.

20. A composite system comprising a polymer obtained or obtainable from polymerization of polymerizable compounds within a liquid-crystal medium according to claim 2.

21. A process for the preparation of a liquid-crystal medium according to claim 3, said process comprising mixing one or more compounds of formula G-2, one or more compounds selected from formulae CC and CP, one or more compounds selected from formulae II-1a and II-1b, one or more compounds of formula IV, and optionally with one or more further compounds and/or with one or more additives.

22. The liquid crystal medium according to claim 1, wherein said medium has a material quality, η, of 17 or more measured at 20° C. and 19 GHz.

23. The liquid crystal medium according to claim 1, wherein R.sup.41 and R.sup.42, independently of one another, denote unfluorinated alkyl or unfluorinated alkoxy, each having 1 to 7 C atoms, or unfluorinated alkenyl, unfluorinated alkenyloxy or unfluorinated alkoxyalkyl, each having 2 to 7 C atoms.

24. The liquid crystal medium according to claim 1, wherein said medium further comprises one or more compounds of the following formula ##STR00201## wherein n is an integer of 1 to 7.

25. The liquid crystal medium according to claim 1, wherein R.sup.1 and R.sup.2 are each independently methyl, ethyl, propyl, butyl, pentyl, hexyl or heptyl.

26. The liquid crystal medium according to claim 1, wherein R.sup.1 and R.sup.2 are each butyl.

Description

EXAMPLES

(1) The following examples illustrate the present invention without limiting it in any way.

(2) However, it is clear to the person skilled in the art from the physical properties what properties can be achieved and in what ranges they can be modified. In particular, the combination of the various properties which can preferably be achieved is thus well defined for the person skilled in the art.

Comparative Example 1

(3) A liquid-crystal mixture C-1 having the composition and properties as indicated in the following table is prepared and characterized with respect to its general physical properties and its applicability in microwave components at 19 GHz.

(4) TABLE-US-00007 TABLE 1 Composition and properties of the mixture C-1 Composition Compound No. Abbreviation 1 PPTUI-3-2 20.0 2 PPTUI-3-4 36.0 3 GGP-3-CL 10.0 4 GGP-5-CL 20.0 5 CPGP-5-2 7.0 6 CPGP-5-2 7.0 Σ 100.0 Physical properties T (N, I) = 173° C. n.sub.e (20° C., 589.3 nm) = 1.855 Δn (20° C., 589.3 nm) = 0.335 ε.sub.|| (20° C., 1 kHz) = 8.1 Δε (20° C., 1 kHz) = 4.6 γ.sub.1 (20° C.) = 746 mPa .Math. s V.sub.0 = 2.42 V tan δ.sub.ε r,⊥ (20° C., 19 GHz) = 0.0143 tan δ.sub.ε r,|| (20° C., 19 GHz) = 0.0038 τ (20° C., 19 GHz) = 0.252 η (20° C., 19 GHz) = 17.6

(5) This mixture is suitable for applications in the microwave range, in particular for phase shifters or LC based antenna elements in the micro wave (MW) region. In comparison to the Example this mixture clearly exhibits inferior properties. In particular, it is not very stable against storage at deep temperatures.

Example 1

(6) A liquid-crystal mixture M-1 having the composition and properties as indicated in the following table is prepared.

(7) TABLE-US-00008 TABLE 1 Composition and properties of the mixture M-1 Composition Compound No. Abbreviation 1 PPTUI-3-2 20.0 2 PPTUI-3-4 32.0 3 GGP-3-CL 18.0 4 PGUQU-5-F 3.0 5 CC-3-V 12.0 6 PP-1-2V1 5.0 7 PTGTP-4-4 10.0 Σ 100.0 Physical properties T (N, I) = 131° C. n.sub.e (20° C., 589.3 nm) = t.b.d. Δn (20° C., 589.3 nm) = t.b.d. ε.sub.|| (20° C., 1 kHz) = 6.3 Δε (20° C., 1 kHz) = 3.1 γ.sub.1 (20° C.) = 311 mPa .Math. s V.sub.0 = 2.51 V tan δ.sub.ε r,⊥(20° C., 19 GHz) = 0.0127 τ (20° C., 19 GHz) = 0.250 η (20° C., 19 GHz) = 19.7 Remarks: t.b.d.: to be determined.
This mixture is comparatively stable against storage at deep temperatures.

(8) Further, this mixture is very highly suitable for applications in the microwave range, in particular for phase shifters or LC based antenna elements in the micro wave (MW) region.

Example 2

(9) A liquid-crystal mixture M-2 having the composition and properties as indicated in the following table is prepared.

(10) TABLE-US-00009 TABLE 2 Composition and properties of the mixture M-2 Composition Compound No. Abbreviation 1 PPTUI-3-2 20.0 2 PPTUI-3-4 32.0 3 GGP-3-CL 20.0 4 CC-3-V 12.0 5 PP-1-2V1 5.0 6 PTGTP-4-4 10.0 Σ 100.0 Physical properties T (N, I) = t.b.d. ° C. n.sub.e (20° C., 589.3 nm) = t.b.d. Δn (20° C., 589.3 nm) = t.b.d. ε.sub.|| (20° C., 1 kHz) = t.b.d. Δε (20° C., 1 kHz) = t.b.d. γ.sub.1 (20° C.) = t.b.d. mPa .Math. s V.sub.0 = t.b.d. V tan δ.sub.ε r,⊥(20° C., 19 GHz) = 0.0132 τ (20° C., 19 GHz) = 0.229 η (20° C., 19 GHz) = 17.3 Remarks: t.b.d.: to be determined.

(11) This mixture is very highly suitable for applications in the microwave range, in particular for phase shifters or LC based antenna elements in the micro wave (MW) region.

(12) It is also comparatively stable against storage at deep temperatures.

Example 3

(13) A liquid-crystal mixture M-3 having the composition and properties as indicated in the following table is prepared.

(14) TABLE-US-00010 TABLE 3 Composition and properties of the mixture M3 Composition Compound No. Abbreviation 1 PPTUI-3-2 20.0 2 PPTUI-3-4 32.0 3 GGP-3-CL 18.0 4 PGUQU-5-F 3.0 5 CC-3-V 12.0 6 PP-1-2V1 5.0 7 PTG(CL)TP-4-4 10.0 Σ 100.0 Physical properties T (N, I) = 132° C. n.sub.e (20° C., 589.3 nm) = t.b.d. Δn (20° C., 589.3 nm) = t.b.d. ε.sub.|| (20° C., 1 kHz) = 6.3 Δε (20° C., 1 kHz) = 3.3 γ.sub.1 (20° C.) = 359 mPa .Math. s V.sub.0 = 2.47 V tan δ.sub.ε r,⊥(20° C., 19 GHz) = 0.0126 τ (20° C., 19 GHz) = 0.230 η (20° C., 19 GHz) = 18.3 Remarks: t.b.d.: to be determined.
This mixture is comparatively stable against storage at deep temperatures. It is stable against storage at a temperature of −20° C. in the bulk for at least 1000 hours.

(15) Further it is very highly suitable for applications in the microwave range, in particular for phase shifters or LC based antenna elements in the micro wave (MW) region.

Example 4

(16) A liquid-crystal mixture M-4 having the composition and properties as indicated in the following table is prepared.

(17) TABLE-US-00011 TABLE 4 Composition and properties of the mixture M-4 Composition Compound No. Abbreviation 1 PPTUI-3-2 20.0 2 PPTUI-3-4 30.0 3 PGUQU-3-F 3.0 4 PGUQU-5-F 3.0 5 PTP(2)TP-6-3 30.0 6 PTGTP-4-4 14.0 Σ 100.0 Physical properties T (N, I) = 124° C. n.sub.e (20° C., 589.3 nm) = t.b.d. Δn (20° C., 589.3 nm) = t.b.d. ε.sub.|| (20° C., 1 kHz) = 5.5 Δε (20° C., 1 kHz) = 2.6 γ.sub.1 (20° C.) = t.b.d. mPa .Math. s V.sub.0 = 2.38 V tan δ.sub.ε r,⊥(20° C., 19 GHz) = 0.0113 τ (20° C., 19 GHz) = 0.256 η (20° C., 19 GHz) = 22.7 Remarks: t.b.d.: to be determined.

(18) This mixture is very highly suitable for applications in the microwave range, in particular for phase shifters or LC based antenna elements in the micro wave (MW) region.

(19) It is also comparatively stable against storage at deep temperatures.

Example 5

(20) A liquid-crystal mixture M-5 having the composition and properties as indicated in the following table is prepared.

(21) TABLE-US-00012 TABLE 5 Composition and properties of the mixture M-5 Composition Compound No. Abbreviation 1 PPTUI-3-2 20.0 2 PPTUI-3-4 30.0 3 PGUQU-3-F 3.0 4 PGUQU-5-F 3.0 5 PTP(2)TP-6-3 30.0 6 PTG(CL)TP-4-4 14.0 Σ 100.0 Physical properties T (N, I) = 121° C. n.sub.e (20° C., 589.3 nm) = t.b.d. Δn (20° C., 589.3 nm) = t.b.d. ε.sub.|| (20° C., 1 kHz) = 5.5 Δε (20° C., 1 kHz) = 2.6 γ.sub.1 (20° C.) = t.b.d. mPa .Math. s V.sub.0 = 2.34 V tan δ.sub.ε r,⊥(20° C., 19 GHz) = 0.0104 τ (20° C., 19 GHz) = 0.259 η (20° C., 19 GHz) = 24.9 Remarks: t.b.d.: to be determined.

(22) This mixture is very highly suitable for applications in the microwave range, in particular for phase shifters or LC based antenna elements in the micro wave (MW) region.

(23) It is Also Comparatively Stable Against Storage at Deep Temperatures.