POLYKETONE COMPOUND

Abstract

An aliphatic polyketone compound including 85.0 to 99.5 wt % aliphatic polyketone and 0.5 to 15.0 wt % ultra-high molecular weight polyethylene. An aliphatic polyketone compound described where the ultra-high molecular weight polyethylene is 2.0 to 8.0 wt %. An aliphatic polyketone compound where the ultra-high molecular weight polyethylene has a molecular weight greater than 1.0 million g/mol.

Claims

1: An aliphatic polyketone compound comprising: 85.0 to 99.5 wt % aliphatic polyketone, and 0.5 to 15.0 wt % ultra-high molecular weight polyethylene.

2: The aliphatic polyketone compound of claim 1, wherein a proportion of the ultra-high molecular weight polyethylene is 2.0 to 8.0 wt %.

3: The aliphatic polyketone compound of claim 1, wherein the ultra-high molecular weight polyethylene has a molecular weight greater than 1.0 million g/mol.

4: The aliphatic polyketone compound of claim 1, wherein the ultra-high molecular weight polyethylene has an average particle size in the range from 10 μm to 300 μm.

5: The aliphatic polyketone compound according to of claim 1, wherein the aliphatic polyketone has at least one of a melting point, measured according to DIN EN 11357-1, of 210 to 230° C., a glass transition point in a range from 5° C. to 20° C., a density in a range from 1.1 to 1.3 g/cm.sup.3, a moisture absorption of 0.3 to 1.2%, or an MVR in a range from 2 to 80 cm.sup.3/10 min.

6: The aliphatic polyketone compound of claim 1, wherein the aliphatic polyketone is comprises a terpolymer.

7: The aliphatic polyketone compound of claim 1, wherein the aliphatic polyketone is produced from ethylene, carbon monoxide, and an alkene having from 3 to 5 carbon atoms.

8: The aliphatic polyketone compound of claim 1, wherein, during production thereof, the arrangement of carbon monoxide and olefin in a polymeric chain takes place in a strictly alternating manner.

9: The aliphatic polyketone compound of claim 1, wherein the aliphatic polyketone has at least one of a mean molecular weight Mn (number-average molecular weight) of between 60,000 and 100,000 or an Mw (weight-average molecular weight) of between 132,000 and 320,000.

10: A method for producing an aliphatic polyketone compound, comprising: combining 99.5 to 85.0 wt % aliphatic polyketone with 0.5 to 15 wt % ultra-high molecular weight polyethylene.

11: A molded body, comprising: at least one of seals, wiper elements, coupling elements, baking rings (anti-extrusion rings), wear bands, guides or structural parts, wherein the molded body contains the aliphatic polyketone compound according to claim 1.

12: The molded body of claim 11, wherein the molded body comprises a rotationally symmetrical molded body.

13: The molded body of claim 11, wherein the molded body comprises an injection molded part having only one injection point.

14: A method, comprising: using the aliphatic polyketone compound of claim 1 to produce molded bodies, wherein the molded bodies comprise at least one of seals, rod seals, piston seals, structural parts (with and/or without sealing function), wiper elements, coupling elements, toothed wheels, sliding bearings, baking rings, anti-extrusion rings, wear bands, or guides.

15: The method of claim 14, wherein the molded bodies comprise injection molded parts each having only one injection point.

16: The aliphatic polyketone compound of claim 2, wherein the ultra-high molecular weight polyethylene is 5.0 to 7.5 wt %.

17: The aliphatic polyketone compound of claim 3, wherein the molecular weight is from 3.0 to 7.0 million g/mol.

18: The aliphatic polyketone compound of claim 7, wherein the alkene having from 3 to 5 carbon atoms comprises propylene.

19: The aliphatic polyketone compound of claim 5, wherein the aliphatic polyketone has a density of 1.24 g/cm.sup.3.

20: The aliphatic polyketone compound of claim 9, wherein the aliphatic polyketone has a polydispersity index between 2.2 and 3.2.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0027] The present invention will be described in even greater detail below based on the exemplary figures. The invention is not limited to the exemplary embodiments. Other features and advantages of various embodiments of the present invention will become apparent by reading the following detailed description with reference to the attached drawings which illustrate the following:

[0028] FIG. 1 is a diagram of a polyketone terpolymer.

[0029] FIG. 2 is a diagram of a hydraulic test bench, including the following components: Extrusion gap (1), test seal (2), guide (3), and pressure chamber (4). The rod movement (5) is horizontal.

DETAILED DESCRIPTION

[0030] In an embodiment, the present invention provides a polyketone compound which can be processed by injection molding and is characterized by a high weld line strength. Moreover, the polyketone compound should exhibit the good tribological properties necessary for sealing applications, and a high extrusion resistance.

[0031] In an embodiment, the present invention provides an aliphatic polyketone compound comprising 85.0 to 99.5 wt % aliphatic polyketone and 0.5 to 15.0 wt % ultra-high molecular weight polyethylene.

[0032] The term “compound” is understood according to the invention in the conventional sense as a plastic which contains at least two polymers which cannot be blended together or as a plastic which, in addition to the polymer, contains fillers, reinforcing substances or other additives, for example tribological additives, which form a polyphase system with the polymer. The polyketone compound according to the invention contains, with the aliphatic polyketone and the ultra-high molecular weight polyethylene, at least two polymers which cannot be blended together.

[0033] In contrast thereto, blends have a combination of two or more polymers that are physically mixed (blended). Homogeneous blends have a single phase. Heterogeneous blends have at least two phases. Homogeneous blends no longer exhibit the properties of the separate polymers, but rather have their own, new properties, which can sometimes differ considerably from those of the original polymers (see Kulshreshtha, A. K. (2002) “Handbuch zu Polymermischungen und Verbundstoffen (Vol. 1)” [Handbook of polymer blends and composite materials], iSmithers Rapra Publishing, or Sperling, L. H. (2005) “Einführung in die physikalische Polymerwissenschaft” [Introduction to physical polymer science], John Wiley & Sons).

[0034] According to the invention, it was found that incorporating 0.5 to 15 wt % ultra high-molecular weight polyethylene into aliphatic polyketones made it possible to improve the tribological properties thereof in terms of friction and wear in such a way that they are comparable to those of the commercially available friction-modified polyketone compounds, but at the same time have a significantly better weld line strength and a high extrusion resistance.

[0035] As explained above, the weld line strength of the polyketone compound according to the invention, which is improved compared with the commercially available PTFE friction-modified aliphatic polyketone compounds, is particularly advantageous since it makes it possible, for example, to produce seals by means of a modern and cost-effective variant of the injection molding process in which only one injection point is used. The products obtained in the process are characterized by a high extrusion resistance. This is advantageous in particular for dynamic sealing applications, since otherwise extrusion barbs form over the service life of the seals and leakage or premature failure of the seal can occur as a result. At the same time, the aliphatic polyketone compounds according to the invention have sliding and frictional properties which are virtually comparable to those of PTFE, PTFE/bronze compounds or those of commercially available PTFE friction-modified polyketone compounds. Surprisingly, it has been found that 0.5 to 15 wt %, more preferably 2.0 to 8.0 wt % and in particular 5.0 to 7.5 wt % of the ultra-high molecular weight polyethylene, in each case based on the total weight of the polyketone compound, is already sufficient to match up to the sliding and frictional properties of an aliphatic polyketone filled with 20 wt % PTFE. Furthermore, it was surprising that the aliphatic polyketone compound according to the invention does not break during deformation loading, as occurs, for example, when a rigid piston seal is installed in a piston chamber by means of mounting pliers, while structurally identical seals made of a commercial polyketone compound modified with 20 wt % PTFE break at the weld line in 75 to 90% of the installation tests. The improved weld line strength can presumably be explained by the proportion of tribological additive which is lower by 5 to 19.5 wt %, preferably 12 to 18 wt %, and in particular 12.5 to 15 wt %. It is surmised that during the injection molding of seals with only one injection point, the rather apolar tribological additives migrate to the interface between polar polyketone and mold wall during the injection process. Therefore, a particularly high concentration of these additives is present in the region of the weld line where the two flow fronts converge, which, in the commercial polyketone compounds modified with 20 wt % PTFE, leads to adhesion problems and hence to subsequent weld line breakages. The polyketone compounds according to the invention, which have less than 15 wt % ultra-high molecular weight polyethylene do not exhibit this problem due to the lower additive content.

[0036] Thus, in a preferred embodiment of the invention, the aliphatic polyketone according to the invention has a total proportion of tribological additives, i.e. of ultra-high molecular weight polyethylene and optionally further tribological additives present, such as silicone oils, PTFE powder, graphite, molybdenum sulfide, boron nitride, of less than 20 wt %, preferably of less than 5 wt % and in particular of less than 2.5 wt %. Nevertheless, the above-mentioned additives may be present, for example in quantities of 0.1 wt % to 19.5 wt %.

[0037] An ultra-high molecular weight polyethylene, often abbreviated to UHMWPE, is to be understood according to the invention as meaning polyethylene having a molecular weight of greater than 1.0 million g/mol, preferably from 3.0 to 7.0 million g/mol and in particular from 3.0 to 5.0 million g/mol, measured by means of Ubbelohde viscometry (dilute solution in decahydronaphthalene at 140° C.). Due to this high molecular weight, ultra-high molecular weight polyethylene is not fusible. This is advantageous compared to fusible plastics, such as LDPE or HDPE, since UHMWPE does not itself melt on compounding into an aliphatic polyketone melt, but continues to be present in the polymer matrix in the form of solid particles. The UHMWPE particles are apolar, therefore incompatible with the polar aliphatic polyketone matrix, and therefore accumulate at the interfaces. As a result, the surface of the polyketone compounds has wear-resistant particles which, on the one hand, reduce friction resistance and, on the other hand, reduce material abrasion.

[0038] In contrast to UHMWPE, LDPE and HDPE are fusible polyethylenes having melting ranges around approximately 110° C. and around approximately 135° C., respectively, which completely melt on mixing into an aliphatic polyketone melt, are distributed in the polymer matrix and thereby form a blend (as described for example in DE 695 13 864 T2, WO 96/06889). In this case, discrete PE particles are no longer present in the finished material blend, and so the advantages mentioned in the previous paragraph afforded by the solid UHMWPE particles cannot be achieved.

[0039] Furthermore, due to the significantly higher molecular weight and the higher intermolecular interactions associated therewith, UHMWPE has a significantly better wear resistance and impact strength than LDPE and HDPE.

[0040] Ultra-high molecular weight polyethylene can be recovered from monomeric ethylene by metallocene-catalyzed synthesis, with polymer chains consisting of from 100,000 to 250,000 monomeric units typically being formed. Thus, according to the invention, preference is given to ultra-high molecular weight polyethylene which has polymer chains consisting of from 100,000 to 250,000 monomeric units.

[0041] Preferably, the average particle size of the ultra-high molecular weight polyethylene is in the range from 10 μm to 300 μm, more preferably from 20 μm to 50 μm and in particular is 38 μm. In a further preferred embodiment, the particles of the ultra-high molecular weight polyethylene are smaller than 75 μm. Thus, the D50 value of the polyethylene is preferably less than 75 μm and/or the D95 is preferably less than 75 μm. The specific density of the ultra-high molecular weight polyethylene is preferably 0.93 to 0.94 g/cm.sup.3. The bulk density is preferably 0.3 to 0.6 g/cm.sup.3 and more preferably 0.32 to 0.5 g/cm.sup.3. The molar weight is preferably 3.0 to 7.0 million g/mol and more preferably 3.0 to 5.0 million g/mol.

[0042] According to the invention, aliphatic polyketone and ultra-high molecular weight polyethylene are the main constituents of the aliphatic polyketone compound of the invention. In this case, according to the invention, the proportion of aliphatic polyketone in the polyketone compound is 85.0 to 99.5 wt %, preferably 90.0 to 99.5 wt %, more preferably 92.0 to 98.0 wt % and in particular 92.5 to 95.0 wt %, in each case based on the total weight of the polyketone compound. Furthermore, according to the invention, the proportion of ultra-high molecular weight polyethylene in the polyketone compound is 0.5 to 15 wt %, preferably from 0.5 to 10 wt %, more preferably from 2.0 to 8.0 wt % and in particular from 5.0 to 7.5 wt %, in each case based on the total weight of the polyketone compound.

[0043] In a preferred embodiment of the invention, the aliphatic polyketone has a proportion of further tribological additives, for example of silicone oils, of 0.1 wt % to 2.0 wt %, in particular 0.5 wt % to 1.5 wt %.

[0044] In a preferred embodiment of the invention, the aliphatic polyketone has a melting point, measured according to the method of DIN EN 11357-1, of 210 to 230° C. and in particular of 220 to 222° C. The glass transition point is in the range from 5° C. to 20° C., preferably 10° C. to 15° C. and in particular 11° C. to 13° C. The density of the aliphatic polyketone, measured according to the method of ISO 1183, is preferably in the range from 1.1 t0 1.3 g/cm.sup.3 and is in particular 1.24 g/cm.sup.3. The moisture absorption of the aliphatic polyketone, as measured according to the method of ISO 1110, is from 0.3 to 1.2% and in particular from 0.8 to 0.9%, at 70° C. and 62% RH. The MVR thereof, measured according to the method of ISO 1133, is preferably in the range from 2 to 80 cm.sup.3/10 min and in particular in the range from 6 to 60 cm.sup.3/10 min at 240° C. and 2.16 kg of test weight.

[0045] In a preferred embodiment of the invention, the aliphatic polyketone is a terpolymer, preferably produced from ethylene, carbon monoxide and an alkene having from 3 to 5 carbon atoms, preferably propylene and/or butylene, in particular propylene. Here, the arrangement of carbon monoxide and olefin in the polymeric chain takes place in a strictly alternating manner.

[0046] In a preferred embodiment of the invention, the aliphatic polyketone has a mean molecular weight M.sub.n(number-average molecular weight) of between 60,000 and 100,000 and/or MW (weight-average molecular weight) of between 132,000 and 320,000. The polydispersity index here is preferably between 2.2 and 3.2.

[0047] The polyketone compound according to the invention may contain silicone oil and other liquid or solid lubricants. Furthermore, further customary polymer additives such as, inter alia, aging inhibitors, fillers, flame retardants and pigments, as well as other polymeric materials, may be included in order to improve or otherwise alter the properties of the composition. The content of liquid lubricants, such as silicone oils, is preferably from 0.0 to 2.0 wt % and particularly preferably 0.0 to 1.5 wt % and in particular 0.0 to 1.0 wt %.

[0048] In a preferred embodiment of the invention, the aliphatic polyketone compound has a coefficient of friction μ, measured on a Lewis test bench at a speed of v=0.84 m/s, a pressure of p=0.84 MPa and in the unlubricated state, of from 0.1 to 0.4, more preferably from 0.1 to 0.3 and in particular from 0.1 to 0.25. Furthermore, in a preferred embodiment of the invention, the aliphatic polyketone has an average wear coefficient, measured on a Lewis test bench at a speed of v=0.84 m/s, a pressure of p=0.84 MPa and in the unlubricated state, of from 1*10.sup.−7 to 1*10.sup.−4 mm.sup.3/Nm and more preferably from 1*10.sup.−7 to 1*10−5 mm.sup.3/Nm.

[0049] Moreover, the aliphatic polyketone compound according to the invention preferably has a tensile modulus of elasticity, measured according to DIN EN ISO 527-2/1A/50, of 1600 MPa to 1850 MPa, a tensile strength, measured according to DIN EN ISO 527-2/1A/50, of 55 MPa to 65 MPa and/or an elongation at break, measured according to DIN EN ISO 527-2/1A/50, of 20% to 40%.

[0050] Furthermore, the aliphatic polyketone compound according to the invention, in a tribological test as described in example 2, preferably has a coefficient of friction of p=0.38 to 0.42 over the entire duration of the test, a coefficient of friction of p=0.38 to 0.40 over the “steady state”, a wear coefficient of 10*10.sup.−6 to 20*10.sup.−6 over the entire duration of the test and/or a wear coefficient of 2*10.sup.−6 to 5*10.sup.−6 over the “steady state”.

[0051] A further subject matter of the present invention is a method for producing the aliphatic polyketone compound, comprising combining 99.5 to 85.0 wt % aliphatic polyketone with 0.5 to 15 wt % ultra-high molecular weight polyethylene, more preferably 98.0 to 92.0 wt % aliphatic polyketone with 2.0 to 8.0 wt % ultra-high molecular weight polyethylene, and in particular 95.0 to 92.5 wt % aliphatic polyketone with 5.0 to 7.5 wt % ultra-high molecular weight polyethylene. The weight data here relate to the total weight of the aliphatic polyketone compound.

[0052] The components of the aliphatic polyketone compounds are preferably combined by means of extrusion technology. Extruders used here are preferably co-rotating twin-screw extruders, but counter-rotating twin-screw extruders, planetary roller extruders and co-kneaders are also used. Single-screw extruders are more suitable for conveying and not for compounding and are therefore less suitable for the production of the aliphatic polyketone compounds according to the invention. In one embodiment, aliphatic polyketone is pre-dried at 70° C. to 90° C. for a period of four hours and metered into a twin screw extruder by means of a metering device, preferably a gravimetric metering device. The temperature of the feed zone here is preferably in the range from 50° C. to 100° C., while the temperature of the extruder zones is preferably 225° C. to 254° C. The ultra-high molecular weight polyethylene is preferably supplied to the polymer melt via a further metering device, preferably a gravimetric metering device. After exiting the extruder nozzle, the strand is preferably deposited on a conveyor belt and cooled by means of water and/or air before it is comminuted in a downstream granulator. It is advantageous to dry the granules produced in order to remove the moisture introduced by the cooling process.

[0053] According to the invention, aliphatic polyketone and ultra-high molecular weight polyethylene are combined with one another and the further optionally present components in such a proportion that they form the main constituents of the aliphatic polyketone compound. The polyketone is preferably supplied to the compound in a quantity of 99.5 to 90.0 wt %, more preferably from 98.0 to 92.0 wt % and in particular from 95.0 to 92.5 wt %. Furthermore, the ultra-high molecular weight polyethylene is preferably supplied to the compound in a quantity of 0.5 to 10.0 wt %, more preferably from 2.0 to 8.0 wt % and in particular from 5.0 to 7.5 wt %. Quantities below 10 wt % ultra-high molecular weight polyethylene are advantageous since clogging of the extruder nozzles can thus be prevented in a particularly simple manner.

[0054] This is because ultra-high molecular weight polyethylene tends to agglomerate, accumulate in the region of the extruder nozzle and clog it. However, compounds having more than 10 wt % ultra-high molecular weight polyethylene can also be produced with the method described above, in particular in small batches, but it is advantageous to take special technical precautions for continuous production on account of the agglomeration of UHMWPE and the associated clogging of the extruder nozzle.

[0055] The aliphatic polyketone compound according to the invention can be processed by conventional shaping methods, such as extrusion, compression molding and injection molding, to give various products which are particularly suitable for applications requiring good tribological properties.

[0056] A further subject matter of the present invention is molded bodies, preferably rotationally symmetrical molded bodies, in particular seals, such as rod and/or piston seals, structural parts (with and/or without a sealing function), wiper elements, coupling elements, baking rings (anti-extrusion rings), wear bands and/or guides, which contain the polyketone compound according to the invention.

[0057] In a preferred embodiment, the molding body has a weld line strength of greater than 120 N in a bending test as described in example 2. Furthermore, the molded body preferably does not break on the weld line in a bending test with maximum crosshead travel (43.31 mm), as described in example 2.

[0058] The aliphatic polyketone compound according to the invention is particularly suitable for molded bodies which are produced by means of injection molding methods, in particular by means of injection molding methods using only one injection point, for example pin-point or tunnel gates.

[0059] The invention further relates to the use of the aliphatic polyketone compound according to the invention for the production of molded bodies, preferably of rotationally symmetrical molded bodies, in particular seals such as rod and/or piston seals, structural parts (with and/or without sealing function), wiper elements, coupling elements, toothed wheels, sliding bearings, baking rings, in particular anti-extrusion rings, wear bands and/or guides.

[0060] The invention is explained in more detail below using examples.

Example 1: Production of a Polyketone Compound According to the Invention

[0061] A tribologically modified polyketone compound according to the invention was produced on a 27 mm twin-screw extruder from Leistritz of the ZSE 27 iMAXX type (screw diameter: 28.3 mm, channel depth: 5.6 mm (no clearance), D.sub.a/D.sub.i=1.66, maximum torque: 256 Nm, screw speed: 600-1200 rpm), equipped with a solids metering device from SCHOLZ Dosiertechnik GmbH of the BASIC 401 type for metering the aliphatic polyketone, a solids metering device from SCHOLZ Dosiertechnik GmbH of the BASIC 300 type for metering the ultra-high molecular weight polyethylene, a conveyor belt for strand deposition, water cooling for cooling the deposited polymer strand and a downstream granulator from Maag Automatik GmbH of the PRIMO 60E type for comminuting the deposited strand.

[0062] AKROTEK® PK-VM natural (4774) from AKRO-PLASTIC GmbH was used as aliphatic polyketone. AKROTEK® PK-VM natural (4774) is a non-reinforced polyketone type with high flowability. The melting point thereof, measured according to the method of DIN EN 11357-1, is 220° C., the density thereof, measured according to the method of ISO 1183, is 1.24 g/cm.sup.3, the moisture absorption thereof, measured according to the method of ISO 1110, at 70° C. and 62% RH, is between 0.8 and 0.9% and the MVR thereof, measured according to the method of ISO 1133, is 60 cm.sup.3/10 min.

[0063] INHANCE UH-1700 from Nordmann Rassmann was used as ultra-high molecular weight polyethylene. The mean particle size of the UHMWPE particles is 38 μm and all particles are smaller than 75 μm. INHANCE UH-1700 is a UHMWPE type with surface-treated particles to allow better dispersibility and better adhesion of same in the surrounding polymer. The material has a specific density of 0.93 to 0.94 g/cm.sup.3, a bulk density of 0.32 to 0.5 g/cm.sup.3 and a molar weight of 3.0 to 5.0 million g/mol.

[0064] The aliphatic polyketone was conveyed into the feed zone of the extruder by means of the solids metering device of BASIC 401 type. The temperature of the feed zone was set at 50° C. The twelve heating zones of the extruder were set at temperatures in the range from 230° C. to 245° C. The temperature of the nozzle was 230° C. The measured melt temperature of the polymer was 238° C. The overall throughput of material was 19.97 kg/h. The throughput of AKROTEK® PK-VM was 18.97 kg/h, the throughput of Inhance UH-1700 was 1.0 kg/h. The finished compound was discharged via a single-jet nozzle onto the conveyor belt, cooled with spray water and supplied to the granulator. Since the granules still contain much adherent residual moisture as a result of cooling with water, they were dried at 80° C. for 30 to 45 minutes.

[0065] Prior to extruding the compound to give test specimens, the granules were again dried for four hours at 80° C.

Example 2: Mechanical and Tribological Tests of the Polyketone Compound from Example 1

[0066] Test specimens for the mechanical and tribological tests were produced on an injection molding machine from Arburg GmbH & Co. KG of the 320C 600-100 Allrounder type. An AIM™ Quick Change Mold from Axxicon Moulds was used as injection mold. S1A tensile bars were produced for mechanical tests and Lewis test specimens were produced for tribological tests.

[0067] The results of mechanical tests on the compound gave a tensile modulus of elasticity, measured according to DIN EN ISO 527-2/1A/50, of 1725±10 MPa, a tensile strength, measured according to DIN EN ISO 527-2/1A/50, of 58.7±0.2 MPa and an elongation at break, measured according to DIN EN ISO 527-2/1A/50, of 28.2±7.1%.

[0068] The tribological tests were carried out on a Lewis test bench from Lewis Research Inc. of LRI-1a type. A D2 steel/52100 with the chemical composition 100Cr6 served as counterface. The test was conducted in the unlubricated state. The speed was v=0.84 m/s and the contact pressure p was 0.84 MPa. Both parameters were chosen such that the temperature in the continuous operation state was between 54° C. and 58° C. Under these test conditions, the compound exhibited a coefficient of friction of μ=0.275 over the entire duration of the test, a coefficient of friction of μ=0.269 over the “steady state”, a wear coefficient of 6.556*10-6 over the entire duration of the test and a wear coefficient of 1.862*10-6 over the “steady state”. For comparison to the compound according to the invention, the PTFE-modified AKROTEK® PK-VM™ and the unmodified AKROTEK® PK-VM were measured. Under analogous test conditions, the unmodified AKROTEK® PK-VM exhibited a coefficient of friction of μ=0.412 over the entire duration of the test, a coefficient of friction of μ=0.390 over the “steady state”, a wear coefficient of 15.641*10-6 over the entire duration of the test and a wear coefficient of 3.814*10-6 over the “steady state”. Under analogous test conditions, the tribologically modified AKROTEK® PK-VM™ exhibited a coefficient of friction of μ=0.221 over the entire duration of the test, a coefficient of friction of μ=0.214 over the “steady state”, a wear coefficient of 2.087*10-6 over the entire duration of the test and a wear coefficient of 1.670*10-6 over the “steady state”. It is clear that, although the PTFE-modified benchmark AKROTEK® PK-VM™, with 20 wt % PTFE, contains considerably more tribological additives than the compound according to the invention (5 wt % tribological additive), it only performs slightly better.

[0069] To evaluate the weld line strength, five rod seals of the geometry shown in FIG. 1 (1: rod diameter of 50 mm) were produced from the compound produced in example 1 using the injection molding method with only one injection point and were subsequently subjected to a bending test. The seals were each arranged in experimental equipment in such a way that the weld line and the injection point opposite thereto were aligned horizontally and the compression die (diameter of the punch: 25 mm) applied pressure to the seal at an angle of 90° to the weld line and injection point. One contact point was used. The compression dies were loaded with an initial load of 5 N and were subsequently run at 5 mm/minute. The maximum crosshead travel was 43.3 cm. The tribologically modified polyketone compound produced in example 1 exhibited no breakage at the weld line in this experimental setup. In all five rod seals tested, the compression die was moved to the maximum crosshead travel without a seal breaking (see table 1).

TABLE-US-00001 TABLE 1 Results of the bending tests on rod seals produced from the polyketone compound according to the invention described in example 1. No.: F1 mm: F2 mm: F3 mm: F4 mm: F max: Max travel: Observation: 1 12.31 N 19.12 N 25.25 N 30.65 N 124.8 N 42.97 mm Ring not broken 2 12.35 N 19.31 N 25.57 N 31.06 N 113.2 N 43.31 mm Ring not broken 3 12.45 N 19.37 N 25.59 N 31.03 N 121.7 N 43.30 mm Ring not broken 4 12.39 N 19.32 N 25.55 N 31.00 N 114.9 N 32.29 mm Ring not broken 5 12.29 N 19.20 N 25.41 N 30.87 N 113.3 N 43.29 mm Ring not broken

[0070] In comparison to the polyketone compound according to the invention, rod seals made of a commercially available polyketone compound friction-modified with approximately 20 wt % PTFE were tested under analogous test conditions. Of four rod seals tested, three broke after a crosshead travel of 32.3 to 35.4 mm and a compressive force of 96.7 to 105.4 N (see table 2).

TABLE-US-00002 TABLE 2 Results of the bending tests on rod seals produced from commercially available AKROTEK ® PK-VM TM with the approximately 20 wt % modified polyketone compound. No.: F1 mm: F2 mm: F3 mm: F4 mm: F max: Max travel: Observation: 1 12.47 N 19.20 N 25.20 N 30.36 N  96.7 N 32.34 mm Ring broken 2 12.30 N 19.04 N 25.03 N 30.25 N 112.8 N 43.16 mm Ring not broken 3 12.42 N 19.21 N 25.22 N 30.45 N 105.4 N 35.36 mm Ring broken 4  9.60 N 16.74 N 23.13 N 28.71 N 103.3 N 34.20 mm Ring broken

[0071] Furthermore, the rod seals made of the compound according to the invention were tested several times on a hydraulic test bench under application-oriented conditions against the current benchmark, a rod seal made of a PTFE/bronze compound. A diagram of the test bench is shown in FIG. 2. The test bench has the following components: Extrusion gap (1), test seal (2), guide (3), pressure chamber (4). The rod movement (5) is horizontal. The settings of the test bench were as follows: [0072] Stroke 400 mm [0073] Speed 0.3 m/s [0074] Pressure 400 bar (40 MPa) [0075] Temperature 100° C. [0076] Test duration 50,000 double strokes [0077] Oil Shell Tellus 46

[0078] Leakage and extrusion stability were evaluated in continuous use. It was clear here that the PTFE/bronze compound is damaged after approximately 40,000 strokes due to gap extrusion, whereupon the leakage more than quadruples to the end of the run time after 50,000 strokes, from 20 drops to 90 drops. The seals made from the polyketone compound according to the invention, produced according to the description from example 1, is extrusion stable over the whole run time of 50,000 strokes (approximately 20 drops of leakage up to the end).

[0079] While the invention has been illustrated and described in detail in the drawings and foregoing description, such illustration and description are to be considered illustrative or exemplary and not restrictive. It will be understood that changes and modifications may be made by those of ordinary skill within the scope of the following claims. In particular, the present invention covers further embodiments with any combination of features from different embodiments described above and below. Additionally, statements made herein characterizing the invention refer to an embodiment of the invention and not necessarily all embodiments.

[0080] The terms used in the claims should be construed to have the broadest reasonable interpretation consistent with the foregoing description. For example, the use of the article “a” or “the” in introducing an element should not be interpreted as being exclusive of a plurality of elements. Likewise, the recitation of “or” should be interpreted as being inclusive, such that the recitation of “A or B” is not exclusive of “A and B,” unless it is clear from the context or the foregoing description that only one of A and B is intended. Further, the recitation of “at least one of A, B and C” should be interpreted as one or more of a group of elements consisting of A, B and C, and should not be interpreted as requiring at least one of each of the listed elements A, B and C, regardless of whether A, B and C are related as categories or otherwise. Moreover, the recitation of “A, B and/or C” or “at least one of A, B or C” should be interpreted as including any singular entity from the listed elements, e.g., A, any subset from the listed elements, e.g., A and B, or the entire list of elements A, B and C.