Method for actively treating mining wastewater for pigment production

Abstract

Systems and methods for actively treating mining wastewater, such as acid mine drainage, using a mixed culture of iron oxidizing bacteria, in a manner that results in both remediation of the water and the production of a useful end product. Exemplary systems and methods employ a reaction vessel where the bacteria can oxidize the iron in the mining wastewater for some amount of time, and a settling tank into which reacted water may be transferred and retained to permit iron oxyhydroxide contained in the water to settle as iron oxyhydroxide sludge. The iron oxyhydroxide sludge may be dried to produce iron oxyhydroxide solids that can be employed in the manufacture of a usable pigment.

Claims

1. A method for producing pigment by actively treating iron oxyhydroxide-containing mining wastewater, comprising: providing a series of vessels for treating the iron oxyhydroxide containing mining wastewater, the series of vessels including a reaction vessel as a first vessel and a settling tank as a second vessel; inoculating the reaction vessel with a mixed culture of iron oxidizing bacteria; directing the iron oxyhydroxide-containing mining wastewater into the reaction vessel and allowing the iron oxidizing bacteria to oxidize the iron in the iron oxyhydroxide-containing mining wastewater for an amount of time between about 2-8 hours while maintaining the pH level in the reaction vessel between about 3.5-4.5; discharging the iron oxyhydroxide-containing mining wastewater from the reaction vessel into the settling tank, and retaining the iron oxyhydroxide-containing mining wastewater in the settling tank while the iron oxyhydroxide in the mining wastewater settles as an iron oxyhydroxide sludge; draining the resulting water from the settling tank; removing the settled iron oxyhydroxide sludge from the settling tank; neutralizing the removed iron oxyhydroxide sludge; drying the neutralized iron oxhydroxide sludge to produce iron oxyhydroxide solids; and manufacturing a pigment from the iron oxyhydroxide solids.

2. The method of claim 1, wherein the mining wastewater is retained in the settling tank for between about 4-8 hours.

3. The method of claim 1, further comprising neutralizing the mining wastewater drained from the settling tank.

4. The method of claim 3, wherein the mining wastewater is neutralized to a pH level of about 7.5.

5. The method of claim 3, further comprising returning the neutralized mining wastewater to the environment.

6. The method of claim 1, further comprising returning a portion of the iron oxyhydroxide sludge removed from the settling tank to the reaction vessel, before the sludge is neutralized.

7. The method of claim 1, wherein the total dissolved metals content in the mining wastewater is greater than 70 weight % iron.

8. The method of claim 1, wherein the iron oxidizing bacteria are sourced from the same relative locale as the mining wastewater.

9. The method of claim 1, wherein the iron oxidizing bacteria are provided as a mixed culture sourced from a number of mine drainage sites.

10. The method of claim 1, further comprising using the pigment in the manufacture of paint.

11. A method for producing pigment by actively treating iron oxyhydroxide-containing acid mine water, comprising: providing a series of vessels for treating the acid mine water, the series of vessels including a reaction vessel as a first vessel and a settling tank as a second vessel; inoculating the reaction vessel with a mixed culture of iron oxidizing bacteria; directing the iron oxyhydroxide-containing acid mine water into the reaction vessel and allowing the iron oxidizing bacteria to oxidize the iron in the iron oxyhydroxide-containing acid mine water for an amount of time between about 2-8 hours at a temperature of between 12° C.-21° C. while maintaining the pH level in the reaction vessel between about 3.5-4.5; discharging the acid mine water from the reaction vessel into the settling tank, and retaining the iron oxyhydroxide-containing acid mine water in the settling tank for some amount of time sufficient to permit the iron oxyhydroxide in the acid mine water to settle in the settling tank as iron oxyhydroxide sludge; draining the resulting water from the settling tank; optionally, neutralizing the water drained from the settling tank; optionally, returning the neutralized water to the environment; removing the settled iron oxyhydroxide sludge from the settling tank; optionally, returning a portion of the iron oxyhydroxide sludge to the reaction vessel; neutralizing the iron oxyhydroxide sludge not returned to the reaction vessel; dewatering and drying the neutralized iron oxyhydroxide sludge to produce iron oxyhydroxide solids; and manufacturing a pigment from the iron oxyhydroxide solids.

12. The method of claim 11, wherein the acid mine water is retained in the settling tank for between about 4-8 hours.

13. The method of claim 11, wherein the total dissolved metals content in the acid mine water is greater than 70 weight % iron.

14. The method of claim 11, wherein the source of the iron oxidizing bacteria is selected from the group consisting of the same relative locale as the acid mine water and the combination of a number of different acid mine drainage sites.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) In the following descriptions of the drawings and exemplary embodiments, like reference numerals across the several views refer to identical or equivalent features, and:

(2) FIG. 1 is a block process diagram indicating the general steps of one exemplary method of treating mining wastewater;

(3) FIGS. 2A-2D show tables of various operating conditions, bacterial cultures, and reaction rates associated with an exemplary system and method of treating mining wastewater;

(4) FIG. 3 is a graph showing the ferric oxide content vs. pH of a pigment synthesized using an exemplary system and method of treating mining wastewater;

(5) FIGS. 4A-4B are powdered x-ray diffraction graphs showing the match between pure pigment goethite and iron oxyhydroxides synthesized using an exemplary system and method of treating mining wastewater; and

(6) FIG. 5 shows drawdowns of several paints produced from pigments synthesized using an exemplary system and method of treating mining wastewater.

DETAILED DESCRIPTION OF THE EXEMPLARY EMBODIMENTS

(7) As described above, exemplary system and method embodiments of the general inventive concept may be used to treat mining wastewater associated with both abandoned and active coal mines. It is believed that this is the first developed process to treat highly contaminated, high volume acid mine drainage, using iron oxidizing bacteria in an active, rapid process, with a small footprint, while simultaneously producing a saleable pigment.

(8) Generally speaking, exemplary active treatment methods operate to remove the iron and neutralize any acid present in mining wastewater, so the water can be subsequently released to streams and/or other waterways without any harmful effects. For example, exemplary treatment methods have been shown to be effective in treating acid mine drainage water whose total dissolved metals content is greater than 70% iron.

(9) FIG. 1 depicts the steps of one exemplary method for actively treating mining wastewater to produce a saleable pigment. In this process, wastewater in the form of acid mine drainage is initially directed from a wastewater source (e.g., a mine seep) into a mixed reactor (e.g., a reaction vessel) of an exemplary treatment system 5 that has been inoculated with a (e.g., locally collected) mixed culture of iron oxidizing bacteria. The bacteria is then allowed to oxidize the iron present in the wastewater within the reactor for some period of time 10. Reaction times may vary based on the temperature and the concentration of iron in the wastewater, but are generally between 2-8 hours. During reaction of the water and bacteria in the reactor, the pH value within the reactor is preferably maintained within a range of 3.5-4.5.

(10) Upon conclusion of the reaction phase of the treatment process, the water is discharged from the reactor into a settling tank or similar device and the iron oxyhydroxide present within the water is allowed to settle 15 for a period of time that is generally between 4-8 hours. During the settling phase, the iron oxyhydroxide within the water settles to the bottom of the settling tank as sludge.

(11) Upon conclusion of the settling phase, clear water is drained from the settling tank and may be neutralized 20 to a pH level of, for example, about 7.5. Neutralization may be accomplished by a variety of methods, including but not limited to the addition of lime and/or the use of steel slag leach beds. The neutralized, metal free water may be subsequently returned to the environment 25.

(12) The iron oxyhydroxide sludge that settles to the bottom of the settling tank has been found to be generally about 1% solids. The sludge may be removed 30 from the settling tank, and a portion thereof may optionally be recirculated 35 to the reaction vessel to maintain the biological culture and increase reaction rates. The remaining portion of the removed sludge may be neutralized (e.g., to a pH of about 7.5), and washed 40. The neutralized sludge may then be (optionally) dewatered 45, and dried 50 by any suitable technique known in the art, to produce iron oxyhydroxide solids. The oxyhydroxide solids may then be employed in the manufacture of a usable pigment 55.

(13) Exemplary mining wastewater treatment processes have been performed many times on a laboratory scale. Optimal processing conditions (e.g., pH, temperature, and different bacterial cultures) have been determined in these lab-scale studies. Various ones of these processing conditions are indicated in the tables of FIGS. 2A-2D.

(14) Pigments have been manufactured using iron oxyhydroxide solids obtained from laboratory-scale mining wastewater treatment as described herein, such as via the treatment process represented in the diagram of FIG. 1. These pigments have been subjected to various testing to determine the effects of different processing conditions thereon. Pigments manufactured using iron oxyhydroxide solids obtained from mining wastewater treatment as described herein have also been subjected to various testing to determine their suitability for use in paints and other products. For example, pigments have been tested for quality by industry standards such as iron oxide content, mineral structure by x-ray diffraction, and hiding power by drawdowns.

(15) The results of one exemplary ferric (iron) oxide content test on an exemplary pigment sample are graphically presented in FIG. 3. As shown, the results of the iron oxide content test are presented as a comparison of the iron oxide content of the pigment to the pH level at which the pigment was synthesized. Notably, the iron oxide content of the pigment drops as the pH level at synthesis increases.

(16) The results of one exemplary x-ray diffraction (XRD) test on exemplary seeded and unseeded pigment samples are respectively presented graphically in FIGS. 4A-4B. As shown, the results of the XRD tests are presented as a comparison of the diffraction intensity of the tested pigments to the goethite standard intensity.

(17) The results of yet another pigment test are presented in FIG. 5. More particularly, FIG. 5 shows four separate drawdowns of paints made from pigments characterized as, from left-to-right respectively, unseeded 3.5, unseeded 5.0, unseeded 5.5 and unseeded 6.3—where the numeral associated with each designation represents the pH level at which the pigment was synthesized. All show excellent hiding power and the best color when produced at the lowest pH.

(18) The use of exemplary mining wastewater treatment systems and methods allows for both the remediation of the wastewater and the production of useable iron oxyhydroxide. It is believed that income from the sale of pigments manufactured using said iron hydroxide could exceed the overall operation and treatment costs of an exemplary system. Such a reduction in overall remediation costs is a benefit to active mining operations and may enable the cleanup of waters that have been polluted for decades and continue to be polluted without any mitigation.

(19) While certain exemplary embodiments are described in detail above, the scope of the general inventive concept is not considered limited by such disclosure, and modifications are possible without departing from the spirit thereof as evidenced by the following claims: