WAFER CARRIER FOR METAL ORGANIC CHEMICAL VAPOR DEPOSITION
20210384065 · 2021-12-09
Inventors
Cpc classification
H01L21/68771
ELECTRICITY
C23C16/4581
CHEMISTRY; METALLURGY
C23C16/46
CHEMISTRY; METALLURGY
C23C16/4404
CHEMISTRY; METALLURGY
International classification
Abstract
A wafer carrier for metal organic chemical vapor deposition includes at least one wafer sub-carrier that is in a groove structure and that is configured to place an epitaxial wafer substrate. A first space in the wafer sub-carrier is filled with a first thermally conductive material. The first space is a space between a flat edge of the epitaxial wafer substrate and a side wall of the wafer sub-carrier when the epitaxial wafer substrate is placed on the wafer sub-carrier. A thermal conductivity of the first thermally conductive material is not lower than a thermal conductivity of the wafer sub-carrier.
Claims
1. A wafer carrier for metal organic chemical vapor deposition, comprising: at least one wafer sub-carrier that is in a groove structure and that is configured to place an epitaxial wafer substrate; and a space in the wafer sub-carrier is filled with a first thermally conductive material, the space being between a flat edge of the epitaxial wafer substrate and a side wall of the wafer sub-carrier when the epitaxial wafer substrate is placed on the wafer sub-carrier, and a thermal conductivity of the first thermally conductive material is not lower than a thermal conductivity of the wafer sub-carrier.
2. The wafer carrier according to claim 1, wherein a height of the first thermally conductive material filled in the space is not higher than a height of the side wall of the wafer sub-carrier.
3. The wafer carrier according to claim 1, wherein a material of the wafer sub-carrier is graphite, and the first thermally conductive material is any one or a combination of at least two of the following: graphite, silicon carbide, graphene, titanium metal, and tungsten metal.
4. The wafer carrier according to claim 3, wherein a surface of the wafer sub-carrier is coated with silicon carbide, and a surface of the first thermally conductive material filled in the space is coated with silicon carbide.
5. The wafer carrier according to claim 1, wherein a thermal conductivity of the side wall of the wafer sub-carrier is higher than a thermal conductivity of a bottom wall of the wafer sub-carrier.
6. The wafer carrier according to claim 5, wherein a material of the bottom wall of the wafer sub-carrier is graphite, and a material of the side wall of the wafer sub-carrier is graphene.
7. The wafer carrier according to claim 5, wherein the side wall of the wafer sub-carrier comprises a first layer and a second layer, and a thermal conductivity of the second layer is higher than the thermal conductivity of the bottom wall of the wafer sub-carrier.
8. The wafer carrier according to claim 7, wherein the second layer comprises a second thermally conductive material attached to an inner periphery of the first layer, and a thermal conductivity of the second thermally conductive material is higher than the thermal conductivity of the bottom wall of the wafer sub-carrier.
9. The wafer carrier according to claim 7, wherein a material of the second layer is graphene, a material of the first layer is graphite, and a material of the bottom wall of the wafer sub-carrier is graphite.
10. The wafer carrier according to claim 1, wherein the wafer carrier is a graphite carrier, and the wafer sub-carrier is a groove on the graphite carrier.
11. The wafer carrier according to claim 1, wherein the wafer carrier is a graphite carrier, and the wafer sub-carrier is a graphite carrier disposed on the graphite carrier forming the wafer carrier, and the graphite carrier forming the wafer sub-carrier is smaller than the graphite carrier forming the wafer carrier.
12. The wafer carrier according to claim 1, wherein a diameter of the epitaxial wafer is greater than or equal to 6 inches.
13. A wafer carrier for metal organic chemical vapor deposition, comprising: at least one wafer sub-carrier that is in a groove structure and that is configured to place an epitaxial wafer substrate; and a thermal conductivity of a side wall of the wafer sub-carrier is higher than a thermal conductivity of a bottom wall of the wafer sub-carrier.
14. The wafer carrier according to claim 13, wherein a material of the bottom wall of the wafer sub-carrier is graphite, and a material of the side wall of the wafer sub-carrier is graphene.
15. The wafer carrier according to claim 13, wherein the side wall of the wafer sub-carrier comprises a first layer and a second layer, and a thermal conductivity of the second layer is higher than the thermal conductivity of the bottom wall.
16. The wafer carrier according to claim 15, wherein the second layer comprises a second thermally conductive material attached to an inner periphery of the first layer, and a thermal conductivity of the second thermally conductive material is higher than the thermal conductivity of the bottom wall of the wafer sub-carrier.
17. The wafer carrier according to claim 16, wherein the wafer carrier is a graphite carrier, the wafer sub-carrier is a groove on the graphite carrier, and the second thermally conductive material is graphene.
18. The wafer carrier according to claim 15, wherein a material of the second layer is graphene, a material of the first layer is graphite, and a material of the bottom wall of the wafer sub-carrier is graphite.
19. The wafer carrier according to claim 13, wherein a space in the wafer sub-carrier is filled with a first thermally conductive material, the space is between a flat edge of the epitaxial wafer substrate and the side wall of the wafer sub-carrier when the epitaxial wafer substrate is placed on the wafer sub-carrier, and a thermal conductivity of the first thermally conductive material is not lower than a thermal conductivity of the wafer sub-carrier.
20. The wafer carrier according to claim 19, wherein a height of the first thermally conductive material filled in the space is not higher than a height of the side wall of the wafer sub-carrier.
21. The wafer carrier according to claim 19, wherein a material of the wafer sub-carrier is graphite; and the first thermally conductive material is any one or a combination of at least two of the following: graphite, silicon carbide, graphene, titanium metal, and tungsten metal.
22. The wafer carrier according to claim 21, wherein a surface of the wafer sub-carrier is coated with silicon carbide, and a surface of the first thermally conductive material filled in the space is coated with silicon carbide.
23. The wafer carrier according to claim 13, wherein the wafer carrier is a graphite carrier, and the wafer sub-carrier is a graphite carrier disposed on the graphite carrier forming the wafer carrier, and the graphite carrier forming the wafer sub-carrier is smaller than the graphite carrier forming the wafer carrier.
24. The wafer carrier according to claim 13, wherein a diameter of the epitaxial wafer is greater than or equal to 6 inches.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0054]
[0055]
[0056]
[0057]
[0058]
[0059]
[0060]
[0061] In the figures: 100. Wafer carrier; 101. Shaft hole; 102. Wafer sub-carrier; 103. Epitaxial wafer substrate; 104. First space; 1021. Wafer sub-carrier bottom wall; 1022. Wafer sub-carrier side wall; 10221. First layer; 10222. Second layer.
DESCRIPTION OF EMBODIMENTS
[0062] The following describes technical solutions of embodiments in this application with reference to accompanying drawings. Apparently, the described embodiments are merely some but not all of the embodiments of this application. In addition, it should be noted that, in the embodiments of this application, unless otherwise specified, “a plurality of” means two or more.
[0063]
[0064] The wafer sub-carrier 102 is in a groove structure and is configured to place the epitaxial wafer substrate 103. The wafer carrier 100 may be a large graphite carrier, and the wafer sub-carrier 102 may be a small graphite carrier. A surface of the large graphite carrier and a surface of the small graphite carrier are both coated with a silicon carbide material. The small graphite carrier can rotate in the growing process of the epitaxial wafer.
[0065] The small graphite carrier is usually circular, and when an epitaxial wafer substrate is placed on the small graphite carrier, a relatively large gap is left between a flat edge of the epitaxial wafer substrate and a side wall of the small graphite carrier. During growth of the epitaxial wafer, because an airflow of a carrier gas can quickly take away heat, a temperature at a position of the flat edge of the epitaxial wafer substrate is lower than a temperature at a position of a center of the epitaxial wafer substrate. In other words, a flat edge and a center of the epitaxial wafer may be unevenly heated. Consequently, crystal quality of the flat edge of epitaxial wafer is poor, and a large quantity of defects such as black spots, blurred edges, and cracks occur.
[0066] In addition, for epitaxial wafer substrates of larger sizes (for example, 6 inches, 8 inches, and 12 inches), warpage of an epitaxial wafer grown on the epitaxial wafer substrate is relatively large. Consequently, a border of the epitaxial wafer is warped by a particular height, causing a temperature of the border of the epitaxial wafer to be lower than that of a center of the epitaxial wafer, and resulting in poor crystal quality of the border of the epitaxial wafer and a large quantity of defects such as black spots, blurred edges, and cracks.
[0067] An embodiment of this application provides a wafer carrier for metal organic chemical vapor deposition. As shown in
[0068] The wafer carrier may be a graphite carrier, and the wafer sub-carrier 102 is a groove on the graphite carrier. A structure of the wafer sub-carrier 102 is shown in
[0069] Alternatively, the wafer carrier may be a large graphite carrier, and the wafer sub-carrier 102 is a small graphite carrier disposed on the large graphite carrier. Specifically, as shown in FIG. 4, it can be learned that the wafer sub-carrier 102 and the wafer carrier are independent of each other, and the wafer sub-carrier 102 is located on the wafer carrier. In an example, the wafer sub-carrier 102 can rotate during growth of an epitaxial wafer.
[0070] The epitaxial wafer substrate 103 may be a substrate with a diameter greater than or equal to 6 inches. Specifically, the epitaxial wafer substrate 103 may be a substrate with a diameter of 6 inches, or may be a substrate with a diameter of 8 inches, or may be a substrate with a diameter of 12 inches.
[0071] As shown in
[0072] In an example, a height of the first thermally conductive material filled in the first space 104 is not higher than a height of the side wall of the wafer sub-carrier 102.
[0073] To avoid a risk of the first thermally conductive material being thrown off due to rotation of the wafer carrier and rotation of the wafer sub-carrier 102, the height of the filled first thermally conductive material is not higher than that of the side wall of the wafer sub-carrier 202.
[0074] In a case of this example, the height of the first thermally conductive material filled in the first space 104 is equal to the height of the side wall of the wafer sub-carrier 102.
[0075] In another case of this example, the height of the first thermally conductive material filled in the first space 104 is not higher than the height of the side wall of the wafer sub-carrier 102, and is not lower than a thickness of the epitaxial wafer substrate 103.
[0076] In an example, a material of the wafer sub-carrier 102 is graphite, and the first thermally conductive material is any one or a combination of at least two of the following:
[0077] graphite, silicon carbide, graphene, titanium metal, and tungsten metal.
[0078] In a case of this example, the first thermally conductive material may be coated or bonded to the first space 104.
[0079] In another case of this example, a surface of the wafer sub-carrier 102 is coated with silicon carbide, and a surface of the first thermally conductive material filled in the first space 104 is coated with silicon carbide. Coating silicon carbide can increase strength and hardness of the surface of the wafer sub-carrier 102 and the surface of the first thermally conductive material, and can mitigate gas corrosion.
[0080] In an example, the wafer sub-carrier 102 has a side wall whose thermal conductivity is higher than a thermal conductivity of the bottom wall of the wafer sub-carrier 102.
[0081] In this example, the thermal conductivity of the side wall of the wafer sub-carrier 102 is relatively high, so that during growth of an epitaxial wafer, a thermal radiation heating effect on a border of the epitaxial wafer is better, thereby avoiding poor crystal quality at the border of the epitaxial wafer, and a large quantity of defects such as black spots, blurred edges, and cracks.
[0082] In a first case of this example, a material of the bottom wall of the wafer sub-carrier 102 may be graphite, and a material of the side wall of the wafer sub-carrier 102 is graphene.
[0083] Specifically, a structure of the wafer sub-carrier 102 may be shown in
[0084] In a second case of this example, the side wall of the wafer sub-carrier includes a first layer and a second layer, and a thermal conductivity of the second layer is higher than the thermal conductivity of the bottom wall of the wafer sub-carrier.
[0085] In a specific implementation solution of the second example, the structure of the wafer sub-carrier 102 may be shown in
[0086] Composition materials of the bottom wall 1021 and the first layer 10221 may be graphite, and a composition material of the second layer 10222 may be graphene. A surface of the bottom wall 1021, a surface of the first layer 10221, and a surface of the second layer 10222 are coated with silicon carbide, to increase strength and hardness, and to mitigate gas corrosion.
[0087] In another specific implementation solution of the second example, the structure of the wafer sub-carrier 202 may be shown in
[0088] A composition material of the wafer carrier may be graphite. To be specific, composition materials of the bottom wall 1021 and the first layer 10221 may be graphite, and a composition material of the second layer 10222 may be graphene. A surface of the bottom wall 1021 and a surface of the second layer 10222 are coated with silicon carbide, to increase strength and hardness, and to mitigate gas corrosion.
[0089] In still another specific implementation solution of the second example, referring to
[0090] Materials of the first layer and the bottom wall may be graphite, and the second thermally conductive material may be graphene. A surface of the second layer 10222 and a surface of the bottom wall are coated with silicon carbide, to increase strength and hardness, and to mitigate gas corrosion.
[0091] In a third case of this example, the first thermally conductive material and the second thermally conductive material may be the same, for example, both may be graphene, and may be filled at the same time during filling, thereby improving production efficiency, and a process flow is simple.
[0092] According to the wafer carrier provided in this embodiment of this application, the thermal radiation heating effect at the position of the flat edge or the border of the epitaxial wafer substrate can be improved, and the temperature at the position of the flat edge of the epitaxial wafer substrate can be compensated for, so that a temperature of the entire epitaxial wafer substrate can be more even. In this way, generation of defects such as black spots, blurred edges, and cracks on the flat edge of the epitaxial wafer is avoided, and the crystal quality of the flat edge of the epitaxial wafer is improved, thereby improving an overall yield of the epitaxial wafer.
[0093] An embodiment of this application provides a wafer carrier for metal organic chemical vapor deposition. As shown in
[0094] The wafer carrier may be a large graphite carrier, and the wafer sub-carrier 102 is a small graphite carrier disposed on the large graphite carrier. Specifically, as shown in
[0095] The epitaxial wafer substrate 103 may be a substrate with a diameter greater than or equal to 6 inches. Specifically, the epitaxial wafer substrate 103 may be a substrate with a diameter of 6 inches, or may be a substrate with a diameter of 8 inches, or may be a substrate with a diameter of 12 inches.
[0096] In an example, a material of the bottom wall of the wafer sub-carrier 102 may be graphite, and a material of the side wall of the wafer sub-carrier 102 is graphene.
[0097] Specifically, a structure of the wafer sub-carrier 102 may be shown in
[0098] In an example, the side wall of the wafer sub-carrier includes a first layer and a second layer, and a thermal conductivity of the second layer is higher than the thermal conductivity of the bottom wall of the wafer sub-carrier.
[0099] In a case of this example, the structure of the wafer sub-carrier 102 may be shown in
[0100] Composition materials of the bottom wall 1021 and the first layer 10221 may be graphite, and a composition material of the second layer 10222 may be graphene. A surface of the bottom wall 1021, a surface of the first layer 10221, and a surface of the second layer 10222 are coated with silicon carbide, to increase strength and hardness, and to mitigate gas corrosion.
[0101] In another case of this example, the structure of the wafer sub-carrier 102 may be shown in
[0102] In a specific implementation of this example, the wafer carrier is a graphite carrier, the wafer sub-carrier 102 is a groove on the graphite carrier, and the second thermally conductive material is graphene. In other words, composition materials of the bottom wall 1021 and the first layer 10221 are both graphite, and a composition material of the second layer 10222 is graphene. A surface of the bottom wall 1021 and a surface of the second layer 10222 are coated with silicon carbide, to increase strength and hardness, and to mitigate gas corrosion.
[0103] In still another case of this example, referring to
[0104] Materials of the first layer and the bottom wall may be graphite, and the second thermally conductive material may be graphene. A surface of the second layer 10222 and a surface of the bottom wall are coated with silicon carbide, to increase strength and hardness, and to mitigate gas corrosion.
[0105] In an example, as shown in
[0106] In a first case of this example, a height of the first thermally conductive material filled in the first space 104 is not higher than a height of the side wall of the wafer sub-carrier 102.
[0107] To avoid a risk of the first thermally conductive material being thrown off due to rotation of the wafer carrier and rotation of the wafer sub-carrier 102, the height of the filled first thermally conductive material is not higher than that of the side wall of the wafer sub-carrier 202.
[0108] In a specific implementation solution of the first example, the height of the first thermally conductive material filled in the first space 104 is equal to the height of the side wall of the wafer sub-carrier 102.
[0109] In another specific implementation solution of the first example, the height of the first thermally conductive material filled in the first space 104 is not higher than the height of the side wall of the wafer sub-carrier 102, and is not lower than a thickness of the epitaxial wafer substrate 103.
[0110] In a second case of this example, a material of the wafer sub-carrier 102 is graphite, and the first thermally conductive material is any one or a combination of at least two of the following:
[0111] graphite, silicon carbide, graphene, titanium metal, and tungsten metal.
[0112] In this example, the first thermally conductive material may be coated or bonded to the first space 104. A surface of the wafer sub-carrier 102 may be coated with silicon carbide, and a surface of the first thermally conductive material filled in the first space 104 may be coated with silicon carbide. Coating silicon carbide can increase strength and hardness of the surface of the wafer sub-carrier 102 and the surface of the first thermally conductive material, and can mitigate gas corrosion.
[0113] In a third case of this example, the first thermally conductive material and the second thermally conductive material may be the same, for example, both may be graphene, and may be filled at the same time during filling, thereby improving production efficiency, and a process flow is simple.
[0114] According to the wafer carrier provided in this embodiment of this application, the thermal radiation heating effect at the position of the border of the epitaxial wafer substrate can be improved, and the temperature at the position of the border of the epitaxial wafer substrate can be compensated for, so that a temperature of the entire epitaxial wafer substrate can be more even. In this way, generation of defects such as black spots, blurred edges, and cracks on the border of the epitaxial wafer is avoided, the crystal quality of the flat edge of the epitaxial wafer is improved, and an overall yield of the epitaxial wafer is improved.