REFLECTIVE GLITTER HEAT TRANSFER SHEET COMBINED WITH A RETROREFLECTIVE STRUCTURE AND METHOD OF MANUFACTURING SAME

Abstract

Provided is a reflective glitter heat transfer sheet combined with a retroreflective structure, the reflective glitter heat transfer sheet including: a reflective glitter layer having glass beads and glitter particles arranged in an adhesive attached to a carrier film. The glass beads and the glitter particles are held in a state of being arranged in the adhesive by the adhesive, each of the glass beads is a retroreflector for achieving retroreflection, and each of the glitter particles is a reflector for achieving diffuse reflection. A primer layer is disposed on the reflective glitter layer, and a hot melt layer is formed on the primer layer for conducting heat transfer to an article to which the reflective glitter heat transfer sheet is to be applied.

Claims

1. A reflective glitter heat transfer sheet combined with a retroreflective structure, the reflective glitter heat transfer sheet comprising: a reflective glitter layer comprising glass beads, glitter particles, and an adhesive, the glass beads and the glitter particles being held in a state of being arranged in the adhesive by the adhesive, each of the glass beads being a retroreflector for achieving retroreflection, and each of the glitter particles being a reflector for achieving diffuse reflection; a primer layer disposed on the reflective glitter layer; and a hot melt layer formed on the primer layer for conducting heat transfer to an article to which the reflective glitter heat transfer sheet is to be applied.

2. The reflective glitter heat transfer sheet of claim 1, wherein the glass beads are first sprayed on and attached to the adhesive and then the glitter particles are sprayed on the glass beads attached to the adhesive, thereby arranging the glass beads and the glitter particles in the adhesive.

3. The reflective glitter heat transfer sheet of claim 2, wherein some of light rays originated from a light source are refracted while entering as incident light through front surfaces of some of the glass beads and refracted again while exiting through rear surfaces of some of the glass beads, thereby colliding with some of the glitter particles, some of the light rays collided with the glitter particles are reflected and then refracted again while entering through the rear surfaces of the glass beads and refracted once again while exiting through the front surfaces of the glass beads, thereby being retrospectively reflected toward the light source, and some of the light rays transferred from the light source are refracted while being incident through the front surfaces of some of the glass beads, reflected again on surfaces of rear sides of the glass beads, and then refracted while exiting through the front surface of the glass beads, thereby being retrospectively reflected toward the light source.

4. The reflective glitter heat transfer sheet of claim 1, wherein the glass beads and the glitter particles are mixed with each other and then sprayed in the adhesive so that the glass beads and the glitter particles are arranged in the adhesive in a state of being presented together.

5. The reflective glitter heat transfer sheet of claim 4, wherein some of the light rays originated from the light source are reflected and/or refracted between the glass beads and the glitter particles, between the glass beads and glass beads, or between the glitter particles and glitter particles, wherein some of the light rays originated from the light source are retroreflected through the glass beads; and some of the light rays originated from the light source are reflected by the glitter particles.

6. The reflective glitter heat transfer sheet of claim 1, further comprising: a carrier film, wherein the adhesive arranges the glass beads and the glitter particles therein, in a state of being attached to one entire surface of the carrier film according to a shape of the carrier film.

7. A method of manufacturing a reflective glitter heat transfer sheet combined with a retroreflective structure, the method comprising: preparing a carrier film coated with an adhesive; forming a reflective glitter layer comprising the adhesive which glass beads and glitter particles are attached to and arranged in by spraying and attaching the glass beads and the glitter particles on the adhesive; forming a primer layer on the reflective glitter layer; and forming a hot melt layer on the primer layer.

8. The method of claim 7, wherein the forming the reflective glitter layer further comprises: arranging the glass beads in the adhesive formed on the carrier film while moving the carrier film; and arranging the glitter particles on the adhesive to which the glass beads are attached while continuously moving the carrier film to which the glass beads are attached.

9. The method of claim 7, wherein the forming the reflective glitter layer mixes the glass beads and the glitter particles to each other and then sprays and attaches the glass beads and the glitter particles to the adhesive.

10. The method of claim 7, further comprising: passing the reflective glitter layer between two rollers, thereby allowing the glass beads and the glitter particles to be attached to the adhesive more stably.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0023] The above and other objectives, features, and other advantages of the present invention will be more clearly understood from the following detailed description when taken in conjunction with the accompanying drawings, in which:

[0024] FIG. 1 is a schematic process diagram showing an overall process of manufacturing a reflective glitter heat transfer sheet combined with a retroreflective structure (system) according to an embodiment of the present invention;

[0025] FIG. 2 is an enlarged sectional view showing the reflective glitter heat transfer sheet combined with the retroreflective structure according to the present invention;

[0026] FIG. 3 is a schematic partially enlarged sectional view showing a process in which reflection occurs between glass beads and glitter particles when the heat transfer sheet of the present invention is applied to a desired product;

[0027] FIG. 4 is a schematic process diagram showing an overall process of manufacturing a reflective glitter heat transfer sheet combined with a retroreflective structure (system) according to another embodiment of the present invention; and

[0028] FIG. 5 shows a state in which the carrier film is removed when applied to a desired product as a partially enlarged sectional view showing the heat transfer sheet of the present invention made according to the process of FIG. 4.

DETAILED DESCRIPTION OF THE INVENTION

[0029] Hereinbelow, the present invention will be described in detail with reference to the accompanying drawings.

[0030] With reference to FIG. 1, there is shown a schematic process diagram showing an overall process of manufacturing a reflective glitter heat transfer sheet combined with a retroreflective structure (system) according to the present invention. The reflective glitter heat transfer sheet according to the present invention starts to be provided from preparing a carrier film (base film) 10. A sheet-like adhesive 12 (see FIG. 2) is provided on one entire surface of the carrier film 10 along with the carrier film having a release layer (delamination layer). While a process of unwinding and winding the carrier film 10 from a right side (winder 14) to a left side (winder 14′) proceeds, the carrier film 10 provided with the adhesive 12 above moves at a constant speed between two winders 14 and 14′. The carrier film 10 is usually prepared by molding 75 pm thick polyethylene terephthalate (PET) in a shape of a fabric sheet, and the adhesive 12 using silicone or acrylic is applied or attached to one surface (front surface or top surface in FIG. 1) of the carrier film 10 in the form of a thin film. The release layer that is attached to an opposite surface of the adherend surface where the carrier film 10 and the adhesive 12 are in contact with each other is removed for further work. The carrier film 10 may also replace polyethylene (PE), which is generally used for retroreflective heat transfer films, with a film laminated with PET and an adhesive.

[0031] While the carrier film 10 is moved between the winders 14 and 14′, the glass beads 20 contained in a hopper 16 are dropped onto the adhesive 12 attached to the carrier film 10. The glass beads are filtered through a filter mesh 17 of 200-250 meshes and then sprayed on the adhesive 12 attached to the carrier film 10 to be settled.

[0032] While the carrier film 10 on which the glass beads 20 are provided is continuously moved, the glitter powder is added subsequently right away. The glitter powder 22 is dropped from a hopper 18 onto the glass beads 20 attached to the adhesive 12 through a filter mesh 19 of 200 to 250 meshes.

[0033] As such, while the carrier film 10 provided with the adhesive 12 is moved between the winders 14 and 14 ‘, the carrier film 10 to which the glass beads 20 and glitter powders are attached continues passing between a pair of rollers 24 and 24’ through a continuous process. While passing between the rollers 24 and 24′ like this, the glass beads 20 and glitter powders 22 provided on the carrier film 10 are more stably attached to the adhesive 12 provided on the carrier film 10.

[0034] When remaining layers 34 and 36 (see FIG. 2) such as the primer layer and the like are provided, the operation proceeds in the same way as providing a usual plastic or resin layer without using glass beads or particles such as the glitter.

[0035] FIG. 2 is an enlarged sectional view showing the reflective glitter heat transfer sheet combined with the retroreflective structure according to the present invention. The reflective glitter heat transfer sheet 30 is combined with a retroreflective system (that is, glass beads 20), and when the reflective glitter heat transfer sheet 30 is finally applied to an application product, the carrier film 10 is removed from the reflective glitter heat transfer sheet 30. According to a feature according to an embodiment of the present invention, as described with reference to FIG. 1, using the adhesive 12 attached to the carrier film 10, the glass beads 20 are first sprayed on and attached to the adhesive 12 and the glitter powders 22 are subsequently sprayed right away on and attached to the glass beads 20, whereby the reflective glitter layer 32 is obtained. The glass beads 20 and the glitter powder 22 attached to the adhesive 12 are more stably attached to the adhesive 12 by passing through the rollers 24 and 24′. Through such a process, the glass beads 20 are arranged in the adhesive 12 portion adjacent to the carrier film 10, and the glitter particles 22 are arranged in the adhesive 12 portion away from the carrier film 10.

[0036] As the primer layer 34 is provided under the reflective glitter layer 32 (based on the drawing), even though the glitter particles (that is, glitter powders 22) are not sufficiently attached to the adhesive 12 due to a relation with the glass beads 20 when obtaining the reflective glitter layer 32 by spraying the glitter powders 22 over the glass beads 20, such defects are compensated later by providing the primer layer 34 through a primer coating operation.

[0037] A skin resin layer (not shown) using a skin resin may be further provided on the primer layer 34. Whereas the primer layer 34 is focused on stably attaching the glass beads 20 and the glitter powders 22 to the adhesive 12, the skin resin layer may be provided to maintain an overall shape of the components constituting the sheet when the reflective glitter heat transfer sheet 30 is applied to the clothing or shoes. Of course, by providing the primer layer 34 to a predetermined thickness, the role of the skin resin layer may be obtained together. Lastly, the hot melt layer 36 is provided, thereby obtaining a reflective glitter heat transfer sheet 30 capable of conducting heat transfer.

[0038] When the reflective glitter heat transfer sheet 30 manufactured as described above is applied to the final desired product such as clothing or shoes, a desired pattern or design is cut along the edge of the hot melt layer 36 through a cutting process, thereby allowing the reflective glitter heat transfer sheet to conduct heat transfer to the clothing or shoes. Here, the cutting process may include: CAD cutting using a knife; laser cutting; or the like. When conducting the cutting process, cutting is performed according to a desired pattern to have depth, extending from the hot melt layer 36 up to a portion just before the carrier film 10. Subsequently, the cut portion is separated from the carrier film 10 and is applied to the clothing or shoes by being pressed at 150° C. for 10 seconds.

[0039] With reference now to FIG. 3, when the heat transfer sheet of the present invention is applied to the desired product such as the clothing or shoes, it shows a process in which reflection occurs between the glass beads and the glitter particles. In the case of the glitter sheet, typically, a plurality of fine particles is usually applied to a substrate surface, the diffuse reflection occurs on the surface of these fine particles, deposited and coated with aluminum, whereby an effect in which the coated substrate surface is shiny is obtained. At this time, a slight luminance is produced but a satisfactory reflection effect is not obtained. Therefore, by placing glass beads with a high refractive index of at least 1.9 ND in front of the glitter particles, the incident light obtained from the light source is refracted toward the glitter particles located at the rear side of the glass beads, and the light reflected from the glitter particles is refracted through the glass beads, whereby the retroreflective effect may be maximized. The glass bead is a retroreflector typically functions such that the light (light ray) originated from the light source is refracted while entering into the inside of the glass bead, then reflected at the rear surface of the glass bead, then refracted again while exiting the glass bead, and then reflected toward the light source in a direction parallel to the incident light. Having such characteristics, the retroreflector exhibits excellent visibility even at night or in a dark place, thereby greatly contributing to the safety of workers and the like.

[0040] With reference to FIG. 3, the carrier film 10 is removed from the reflective glitter heat transfer sheet 30 immediately before or after conducting heat transfer. Since the glass beads 20 constituting the reflective glitter layer 32 are disposed adjacent to the carrier film 10, when the carrier film 10 is removed, the adhesive 12 attached around the upper hemisphere portion of each of the glass beads 20 is removed together with the carrier film 10. Meanwhile, the adhesive 12 that is attached to the remaining lower hemisphere portion of each of the glass beads 20 and to the glitter powders 22 remains. The difference in the particle size of each of the glass beads 20 and the glitter powders 22 arranged in the adhesive 12 is due to a phenomenon that occurred because, when the size of the mesh is constant, particles having sizes smaller than the size of the mesh pass through the mesh.

[0041] As described above, according to the present invention, the glass beads 20 and the glitter particles (glitter powders 22) are arranged using the adhesive 12 evenly attached to the entire surface of the carrier film 10, thereby obtaining a result of being arrayed in one adhesive layer. As such, the glass beads 20 and the glitter particles 22 (glitter powders 22) are provided to be present together in the adhesive 12 providing one layer, whereby homogeneity of the medium in between the glass beads 20 and the glitter particles (glitter powder 22) may be obtained. Accordingly, the change in refractive index of light occurring in the adhesive 12 excluding the glass beads 20 and the glitter particles (glitter powder 22) may be kept constant.

[0042] When the reflective glitter heat transfer sheet 30 of the present invention is applied to an application product such as the clothing or shoes, some of the light (light rays) originated from the light source (not shown) is refracted while entering as the incident light 44 through the front surface of the glass bead 40 constituting the reflective glitter layer 32 and refracted again while exiting through the rear surface of the glass bead 40, thereby colliding with the glitter particle 42. The light collided with the glitter particles 42 is reflected and then refracted while entering again through the rear surface of the glass bead 40, and refracted once again while exiting through the front surface of the glass bead 40, thereby being retrospectively (reversely) reflected (reflected light 45) toward the light source in a direction parallel to the incident light 44. Here, some of the light collided with the glitter particles 42 is reflected (so-called diffuse reflection) at various angles, so that a glitter effect may be obtained.

[0043] On the other hand, some of the light (incident light 46) transferred from the light source is: refracted while being incident through the front surface of the glass bead 40′ constituting the reflective glitter layer 32; reflected on a surface of rear side of the glass bead 40′; and then refracted again while exiting through the front surface of the glass bead 40′, thereby being retrospectively (reversely) reflected (reflected light 47) toward the light source in a direction parallel to the incident light 46. At this time, the light rays (incident light 46) do not reach the glitter particle 42′, and retroreflection is performed in the glass bead 40′. However, even in this case, since the visibility due to retroreflection is significantly increased, the reflection associated with the glitter particles is significantly improved as a result.

[0044] As described above, since the reflective glitter heat transfer sheet 30 combined with the retroreflective system according to the present invention is able to obtain a retroreflective effect through both glass beads on the one hand and glass beads and glitter particles on the other hand. Accordingly, it is possible to obtain a reflective glitter sheet having excellent visibility by maximizing the retroreflective effect.

[0045] FIG. 4 is a schematic process diagram showing an overall process of manufacturing a reflective glitter heat transfer sheet combined with a retroreflective structure (system) according to another embodiment of the present invention. Hereinafter, similar components having the same configuration or structure as the reflective glitter heat transfer sheet according to one embodiment of the present invention described above with reference to FIGS. 1 to 3 will be referred to by the same reference numerals. The difference in the implementation of the present invention according to FIG. 4 is that the glass beads and glitter particles are mixed, thereby being simultaneously arranged in the carrier film.

[0046] The reflective glitter heat transfer sheet starts with preparing the carrier film (base film) 10. A sheet-like adhesive 12 (see FIGS. 2 and 5) is provided on the one entire surface of the carrier film 10 along with a carrier film to which a release layer (delamination layer) is attached. While a process of unwinding and winding the carrier film 10 from a right side (winder 14) to a left side (winder 14′) proceeds, the carrier film 10 provided with the adhesive 12 like this moves at a constant speed between two winders 14 and 14′. The release layer that is attached to an opposite surface of the adherend surface where the carrier film 10 and the adhesive 12 are in contact with each other is removed for further work.

[0047] While the carrier film 10 is moved between the winders 14 and 14′, the glass beads 20 and the glitter particles 22 contained in two hoppers 16 and 18, respectively, are mixed and then dropped onto the adhesive 12 attached to the carrier film 10. A mixture 50, of the glass beads 20 and the glitter particles 22, is filtered through a filter mesh 19 of 200 to 250 meshes, and then sprayed on the adhesive 12 attached to the carrier film 10 to be settled.

[0048] As such, while the carrier film 10 provided with the adhesive 12 is moved between the winders 14 and 14′, the carrier film 10 to which the glass beads 20 and the glitter particles are attached continues passing between a pair of rollers 24 and 24′. While passing between the rollers 24 and 24′ like this, the glass beads 20 and the glitter particles 22 provided on the carrier film 10 are more stably adhered to the adhesive 12 provided on the carrier film 10.

[0049] Here, with reference to FIG. 5 together, as the primer layer 34 is provided under the reflective glitter layer 54 (based on the drawing), even though the particles (that is, glass beads 20 and the glitter particles 22) are not sufficiently attached to the adhesive 12 when obtaining the reflective glitter layer 54 by mixing and then spraying the glass beads 20 and the glitter particles 22 on the adhesive 12, such defects are compensated later by providing the primer layer 34 through a primer coating operation. Lastly, the hot melt layer 36 is provided, thereby obtaining a reflective glitter heat transfer sheet 52 capable of conducting heat transfer.

[0050] FIG. 5 shows a state in which the carrier film is removed when applied to a desired product as a partially enlarged sectional view showing the heat transfer sheet of the present invention made according to the process of FIG. 4. The carrier film 10 is removed from the reflective glitter heat transfer sheet 30 immediately before or after conducting heat transfer. In another embodiment of the present invention, the reflective glitter layer 54 is obtained by mixing the glass beads 20 and the glitter particles 22 and then placing the glass beads 20 and the glitter particles 22 in a state of a mixture in the adhesive 12 of the carrier film 10. Accordingly, the glass beads 20 and the glitter particles 22 are mixed with each other and present together in the adhesive 12. Therefore, when the carrier film 10 is removed, the adhesive 12 attached to the upper hemisphere portion of each of the glass beads 20 that are disposed adjacent to the carrier film 10 is removed together with the carrier film 10. Meanwhile, the adhesive 12 that is attached to the upper portion of each of the glitter particles that are disposed adjacent to the carrier film 10 by being mixed in between the glass beads 20 is also removed together with the carrier film 10. However, the adhesive 12 attached to the lower hemisphere portion of each of the glass beads 20 and the lower portion of each of the glitter particles 22 remains as it is. The difference in the particle size of each of the glass beads 20 and the glitter powders 22 arranged in the adhesive 12 is what reflects a phenomenon that occurred because, when the size of the mesh is constant, particles having sizes smaller than the size of the mesh pass through the mesh.

[0051] According to another embodiment of the present invention, the glass beads 20 and the glitter particles 22 are arranged using the adhesive 12 evenly attached to the entire surface of the carrier film 10, thereby obtaining a result of being arrayed in one adhesive layer. As such, the glass beads 20 and the glitter particles 22 are provided to be present together in the adhesive 12 providing one layer, whereby homogeneity of the medium in between the glass beads 20 and the glitter particles 22 may be obtained. In addition, accordingly, the change in refractive index of light occurring in the adhesive 12 excluding the glass beads 20 and the glitter particles 22 may be kept constant.

[0052] In the reflective glitter thermal transfer sheet 52 according to another embodiment of the present invention, the light transfer path occurs in a complex manner. First, looking at one possible light transfer path, when the reflective glitter heat transfer sheet 52 of the present invention is applied to an application product such as clothing or shoes, some of the light (light rays) originated from the light source (not shown) is refracted while entering as the incident light through the front surface of the glass bead 20 constituting the reflective glitter layer 54 and refracted again while exiting through the rear surface of the glass bead 20, thereby colliding with the glitter particle 22. The light collided with the glitter particle 22 is reflected and then refracted while entering again through the rear surface of the glass bead 20, and refracted once again while exiting through the front surface of the glass bead 20, thereby being retrospectively (reversely) reflected toward the light source in a direction parallel to the incident light. The transfer path of light (light ray) may occur between the glass bead 20 and the glass bead 20, between the glitter particle 22 and the glitter particle 22, and between the glitter particle 22 and the glass bead 20. Here, for light (light rays) that reached through whatever paths, some of the light collided with the glitter particle 22 is reflected (diffuse reflection) at various angles, so that a glitter effect may be obtained.

[0053] On the other hand, some of the light transferred from the light source is: refracted while being incident through the front surface of the glass bead 20 having the upper hemisphere portion exposed above the front surface (based on the drawing) of the reflective glitter layer 54; reflected on the surface of the rear side of the glass bead 20; and then refracted again while exiting through the front surface of the glass bead 20, thereby being retrospectively reflected toward the light source in a direction parallel to the incident light. At this time, the light rays do not reach the glitter particle 22, and retroreflection is performed in the glass beads 20. However, even in this case, since the visibility due to retroreflection is significantly increased, the reflection associated with the glitter particles is significantly improved as a result.

[0054] In contrast, some of the light transferred from the light source may be reflected on the surface of the glitter 22 having the upper hemisphere portion exposed above the front surface (based on the drawing) of the reflective glitter layer 54. At this time, it is possible to obtain only the result (glitter) due to the diffuse reflection by the glitter particles.

[0055] As described above, the reflective glitter heat transfer sheet 52 combined with the retroreflective system according to still another embodiment of the present invention may obtain both retroreflective effect and normal reflection (diffuse reflection) because the path of light propagation occurs in a complex manner between the glass beads and the glitter particles, whereby the reflective glitter sheet having excellent visibility may be obtained.

[0056] Although a preferred embodiment of the present invention has been described for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims.