INFRARED DEVICE AND A METHOD OF MANUFACTURING THE SAME
20220209035 · 2022-06-30
Assignee
Inventors
Cpc classification
H01L31/09
ELECTRICITY
H01L31/02161
ELECTRICITY
H01L33/44
ELECTRICITY
H01L33/24
ELECTRICITY
H01L33/20
ELECTRICITY
International classification
H01L31/0352
ELECTRICITY
H01L31/09
ELECTRICITY
H01L31/18
ELECTRICITY
H01L33/00
ELECTRICITY
Abstract
An infrared device comprises a first mesa portion. The lateral surface of the first mesa portion includes a first lateral surface located on a side close to a bottom surface of the first mesa portion, a second lateral surface located above the first lateral surface, and a third lateral surface located above the second lateral surface. A first angle θ.sub.1 formed by the first lateral surface and one face of the substrate is 0.6° or more and less than 45°, a second angle formed by the second lateral surface and one face of the substrate is 45° or more and 90° or less, and a third angle θ.sub.3 formed by a third lateral surface and one face of the substrate is 0.6° or more and less than 45°. W.sub.3/W.sub.2 is 0.15 or more and W.sub.1/W.sub.2 is 0.2 or more and 3.0 or less.
Claims
1. An infrared device comprising a first mesa portion that includes a first semiconductor layer of first conductive type provided on one face side of a substrate, a second semiconductor layer serving as an active layer stacked on the first semiconductor layer, and a third semiconductor layer of second conductive type stacked on the second semiconductor layer, wherein: a lateral surface of the first mesa portion includes a first lateral surface located on a side close to a bottom surface of the first mesa portion, a second lateral surface located above the first lateral surface, and a third lateral surface located above the second lateral surface; a first angle formed by the first lateral surface and one face of the substrate is 0.6° or more and less than 45°, a second angle formed by the second lateral surface and one face of the substrate is 45° or more and 90° or less, and a third angle formed by the third lateral surface and one face of the substrate is 0.6° or more and less than 45°; and when a length in the direction parallel to a surface of the substrate formed by the first lateral surface is defined as W.sub.1, a length in the direction parallel to the surface of the substrate formed by the second lateral surface is defined as W.sub.2, and a length in the direction parallel to the surface of the substrate formed by the third lateral surface is defined as W.sub.3, W.sub.3/W.sub.2 is 0.15 or more and W.sub.1/W.sub.2 is 0.2 or more and 3.0 or less.
2. The infrared device according to claim 1, wherein the first lateral surface is a part of a lateral surface of an upper side portion of the first semiconductor layer; the second lateral surface is the other part of the lateral surface of the upper side portion of the first semiconductor layer, entire the lateral surface of the second semiconductor layer, and a part of the lateral surface of the third semiconductor layer; and the third lateral surface is the other part of the lateral surface of the third semiconductor layer.
3. The infrared device according to claim 1, wherein the W.sub.3/W.sub.2 is 0.15 or more and 1 or less.
4. The infrared device according to claim 1, wherein the second angle is 45° or more and 75° or less.
5. The infrared device according to claim 1, wherein the first semiconductor layer, the second semiconductor layer and the third semiconductor layer include Al, P, Ga, As, In or Sb.
6. The infrared device according to claim 1, wherein the first semiconductor layer, the second semiconductor layer and the third semiconductor layer are an In compound.
7. The infrared device according to claim 1, wherein no corrosion hole with a diameter of 1 μm or more is present in a first flat portion provided on a lower side portion of the first semiconductor layer.
8. A method of manufacturing an infrared device, comprising: a step of forming a first semiconductor layer of first conductive type on one face side of a substrate; a step of forming a second semiconductor layer serving as an active layer on the first semiconductor layer; a step of forming a third semiconductor layer of second conductive type on the second semiconductor layer; a first etching step of forming a first mesa portion including an upper side portion of the first semiconductor layer, the second semiconductor layer and the third semiconductor layer by applying a dry etching process with an interelectrode voltage 330V or higher; and a second etching step of applying a dry etching process with an interelectrode voltage less than 330V.
9. The method of manufacturing an infrared device according to claim 8, wherein the second etching step applies a dry etching process with an interelectrode voltage 120V or more and less than 330V.
10. The method of manufacturing an infrared device according to claim 8, further comprising a mask step of forming a mask of resist pattern on the third semiconductor layer between the step of forming the third semiconductor layer and the first etching step.
11. The method of manufacturing an infrared device according to claim 10, further comprising a step of forming a hard mask on the third semiconductor layer 13.
12. The method of manufacturing an infrared device according to claim 8, wherein an etching gas in the first etching process and the second etching process is either one of halogen gas or halogen-based gas, or a mixture thereof.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0020] In the accompanying drawings:
[0021]
[0022]
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031]
[0032]
[0033]
DETAILED DESCRIPTION
[0034] An infrared light receiving element 100 according to an embodiment of this disclosure will be described below using drawings. Here, an infrared light emitting element 200 can be configured with the same configuration as the infrared light receiving element 100 described below. That is, the configuration of the infrared light receiving element 100 described in this embodiment can be a structure of the infrared light emitting element 200 as it is. In other words, in this embodiment, each configuration of these infrared devices will be described by using the infrared light receiving element 100 as a representative. Further, the infrared light emitting element 200 can be manufactured by the same method as a method of manufacturing the infrared light receiving element 100 described below. That is, the method of manufacturing the infrared light receiving element 100 described below can be a method of manufacturing the infrared light emitting element 200 as it is, and together a method of manufacturing the infrared device is described.
[0035] In each of the figures described below, the parts corresponding to each other are designated by the same reference signs, and descriptions of the duplicating parts will be omitted as appropriate. Further, this embodiment exemplifies a configuration for embodying the technical idea of this disclosure, and does not specify the material, shape, structure, arrangement, dimensions, etc. of each part to the following. The technical idea of this disclosure can be modified in various ways within the technical scope defined by the claims.
[0036] <Infrared Light Receiving Element>
[0037] (1) Configuration
[0038]
[0039]
[0040] The materials of the first semiconductor layer 11, the second semiconductor layer 12 and the third semiconductor layer 13 are not limited. The first semiconductor layer 11, the second semiconductor layer 12 and the third semiconductor layer 13 may contain materials such as Al, P, Ga, As, In and Sb. In addition, the ratio of each element can be adjusted as appropriate. As an example, the first semiconductor layer 11, the second semiconductor layer 12 and the third semiconductor layer 13 may be an In compound, which is a compound containing at least In.
[0041] The first mesa portion 10 of this infrared light receiving element 100 includes, in order from the substrate 1 side to the top, a first flat portion 101a, a first lateral surface 101b, a second lateral surface 102b, a third lateral surface 103b, and a second flat portion 102a.
[0042] The angle formed by the first flat portion 101a and the surface 1a of the substrate 1 is 0° or more and less than 0.6°. The extension of the first flat portion 101a is the boundary between the upper side portion 111 and the lower side portion 112 of the first semiconductor layer 11.
[0043] It is preferable that the first flat portion 101a does not have any corrosion holes with a diameter of 1 μm or more, from a viewpoint of coating properties of the insulating film 30 and the first electrode 41.
[0044] When the angle formed by the first lateral surface 101b and the surface 1a of the substrate 1 is defined as a first angle θ.sub.1, the first angle θ.sub.1 is 0.6° or more and less than 45°. The first lateral surface 101b is composed only of a part of the lateral surface of the upper side portion 111 of the first semiconductor layer 11. The first lateral surface 101b is located on the side close to the bottom surface of the first mesa portion 10.
[0045] When the angle formed by the second lateral surface 102b and the surface 1a of the substrate 1 is defined as a second angle θ.sub.2, the second angle θ.sub.2 is 45° or more and 90° or less. The second lateral surface 102b is composed of the other part of the lateral surface of the upper side portion 111 of the first semiconductor layer 11, the entire lateral surface of the second semiconductor layer 12, and a part of the lateral surface of the third semiconductor layer 13. That is, the second semiconductor layer 12, which is an active layer, is surrounded entirely by the second lateral surface 102b.
[0046] When the angle formed by the third lateral surface 103b and the surface 1a of the substrate 1 is defined as a third angle θ.sub.3, the third angle θ.sub.3 is 0.6° or more and less than 45°. The third lateral surface 103b is composed only of the other part of the lateral surface of the third semiconductor layer 13.
[0047] The angle formed by the second flat portion 102a and the surface 1a of the substrate 1 is 0° or more and less than 0.6°. The second flat portion 102a is the top portion of the first mesa portion 10.
[0048] In this manner, the first mesa portion 10 has at least two flat portions and 3-stage tapered shape.
[0049] The length in the direction parallel to the surface 1a of the substrate 1 formed by the second lateral surface 102b is defined as W.sub.2, and the length in the direction parallel to the surface 1a of the substrate 1 formed by the third lateral surface 103b is defined as W.sub.3. Here, in order to increase the volume of the second semiconductor layer 12, which is an active layer, and improve the light receiving efficiency, θ.sub.2 should be increased and W.sub.2 should be reduced. Furthermore, in the manufacturing process of the infrared light receiving element 100, in order to improve the coating properties of the insulating film 30 and the wiring portion 43 on the upper part of the first mesa portion 10, θ.sub.3 should be reduced and W.sub.3 should be increased. Therefore, if W.sub.3/W.sub.2 is increased, the light receiving efficiency and the coating properties of the insulating film 30 and the wiring portion 43 can be improved at the same time. The W.sub.3/W.sub.2 of the infrared light receiving element 100 according to this embodiment is 0.15 or more. The upper limit is not particularly limited, but may be 1.0 or less, and may be 0.65 or less from the viewpoint of the manufacturing process.
[0050] The length in the direction parallel to the surface 1a of the substrate 1 formed by the first lateral surface 101b is defined as W.sub.1. Here, if W.sub.1 is large, the distance between the first contact hole 35 formed on the first flat portion 101a and the second semiconductor layer 12, which is an active layer, is increased, and the percentage of the volume of the active layer in the infrared light receiving element 100 is reduced, and as a result, the light receiving efficiency is reduced. Here, if W.sub.1/W.sub.2 is reduced, the percentage of the volume of the active layer in the infrared light receiving element 100 is increased, and the light receiving efficiency can be improved. On the other hand, if W.sub.1/W.sub.2 is extremely small, the coating properties of the insulating film 30 is impaired, so it is preferable that W.sub.1/W.sub.2 is 0.1 or more. The W.sub.1/W.sub.2 of the infrared light receiving element 100 according to this embodiment is 0.2 or more and 3.0 or less. Here, the above description of the light receiving efficiency is applied to the light emitting efficiency of the infrared light emitting element 200, which has the same structure as the infrared light receiving element 100.
[0051] The light receiving efficiency is improved when θ.sub.2 is increased and W.sub.2 is reduced, but when θ.sub.2 is large, the coating properties of the insulating film 30 and the wiring portion 43 on the second lateral surface 102b are reduced. Thus, it is preferable that θ.sub.2 is 45° or more and 75° or less. The θ.sub.2 of the infrared light receiving element 100 according to this embodiment may be 45° or more and 75° or less.
[0052] The shape of the second mesa portion 20 provided below the first mesa portion 10 is not particularly limited. From the second mesa portion 20 to the substrate 1 may be of any shape.
[0053] (2) Manufacturing Method
[0054] Next, a method of manufacturing the infrared light receiving element 100 illustrated in
[0055]
[0056] (2.1) Step of Stacking Semiconductors
[0057] As illustrated in
[0058] (2.2) Step of forming a first mesa portion
[0059] Next, as illustrated in
[0060] Then, the third semiconductor layer 13, the second semiconductor layer 12 and the upper side portion 111 of the first semiconductor layer 11 are dry etched in order by using the resist pattern 31 as a mask. In this dry etching process, a first etching step in which the interelectrode voltage in the dry etching apparatus is 330 V or more and a second etching step in which the interelectrode voltage is 120 V or more and less than 330 V are continuously performed. In this manner, as illustrated in
[0061] In this step of forming the first mesa portion 10, as etching gas for etching the third semiconductor layer 13, the second semiconductor layer 12, and the upper side portion 111 of the first semiconductor layer 11, either halogen gas or a gas that contains halogen in its composition (hereinafter referred to as halogen based gas), or a mixture of these gases is used. An example of halogen gas is chlorine gas (Cl.sub.2). Further, examples of halogen based gas include hydrogen chloride gas (HCl), hydrogen bromide gas (HBr), and the like.
[0062] In the method of manufacturing the infrared light receiving element 100 according to this embodiment, the etching gas does not include a gas having an oxidizing action such as oxygen gas. Thus, in the etching step of forming the first mesa portion 10, the selection ratio between the resist and the semiconductor layer is improved, and disappearance of the resist in the etching step can be prevented.
[0063]
Comparative Example 1
[0064]
[0065] The solid line in
[0066] [1] The Find Edges process for emphasizing sudden changes in brightness in the electron micrographs;
[0067] [2] Gaussian Blur process for smoothing the images. At this time, the standard deviation of the Gaussian function can be set to any value corresponding to the electron micrograph;
[0068] [3] Threshold process and Clear process for unnecessary areas other than the shape to be extracted. Only the shape to be extracted was specified as the foreground color; and
[0069] [4] Analyze Line Graph process for obtaining the coordinate information of the shape to be extracted that was specified as the foreground color.
[0070] Further, the dashed line in
[0071] Here, the first lateral surface 101b in the first mesa portion 10 is a part where the first angle θ.sub.1 is 0.6° or more and less than 45°, thus is a part located between the point where the derivative value of the shape will be 0.01 (tan (0.6°)) or more for the first time to the point where it will be 1 (tan (45°)) or more, with respect to the direction of the first mesa portion 10. Since the second lateral surface 102b in the first mesa portion 10 is a part located above the first lateral surface 101b and where the second angle θ.sub.2 is 45° or more and less than 90°, thus is a part located between the end point of the first lateral surface 101b and the point where the derivative value of the shape is less than 1. Since the third lateral surface 103b in the first mesa portion 10 is a part located above the second lateral surface 102b and where the third angle θ3 is 0.6° or more and less than 45°, thus is a part located between the end point of the second lateral surface 102b and the point where the derivative value of the shape is 0.01 or less with respect to the direction of the first mesa portion 10. In this manner, the start point and the end point of the first lateral surface 101b, the second lateral surface 102b and the third lateral surface 103b can be clearly defined using derivative values of the shape.
[0072] The ratio of the length W.sub.2 in the direction parallel to the surface 1a of the substrate 1 formed by the second lateral surface 102b and the length W.sub.3 in the direction parallel to the surface 1a of the substrate 1 formed by the third lateral surface 103b, W.sub.3/W.sub.2, obtained by the above procedure, was 0.14. Further, the ratio of W.sub.2 to the length W.sub.1 in the direction parallel to the surface 1a of the substrate 1 formed by the first lateral surface 101b, W.sub.1/W.sub.2, was 0.90.
Example 1
[0073] The infrared light receiving element 100 was obtained in the same manner as in Comparative Example 1 except that V.sub.2 was set to 190V.
[0074]
Comparative Example 2
[0075] The black triangles in
[0076] Further, the infrared light receiving element 100 was obtained by the same method as in Comparative Example 2 except that V.sub.2 was set to 450V and 330V. At this time, W.sub.3′/W.sub.2′ obtained by measurement with a laser microscope when V.sub.2 was 450 V and 330 V was 1.63 and 1.71.
Example 2
[0077] The infrared light receiving element 100 was obtained by the same method as in Comparative Example 2 except that V.sub.2 was set to 190V and 120V, and W.sub.3′/W.sub.2′ was calculated by a laser microscope in the same manner as in Comparative Example 2. In this case, W.sub.3′/W.sub.2′ was 2.29 and 2.57 when V.sub.2 was 190V and 120V.
[0078] From the results of Comparative Example 2 and Example 2 (black triangles and dashed line in
[0079]
[0080] In any of the above described embodiments, θ.sub.2 is 45° or more and 75° or less. For example, when V.sub.2 illustrated in
[0081] Further, in any of the above described embodiments, the surface of the first mesa portion 10 is flat. No corrosion hole with a diameter of 1 μm or more, called etch pit, which is introduced when forming a mesa shape by the wet etching method, is observed.
Effects of this Embodiment
[0082] The infrared light receiving element 100 according to this embodiment produces the following effects.
[0083] As illustrated in
[0084] In addition, since the third lateral surface 103b with a gentle slope is located on the top of the first mesa portion 10, the coating properties (i.e., step coverage) of the insulating film 30 and the wiring portion 43 at the top of the first mesa portion 10 can be improved.
[0085] Further, since W.sub.3/W.sub.2, which is the ratio of the length W.sub.3 in the direction parallel to the surface 1a of the substrate 1 formed by the third lateral surface 103b, which is located at the upper part of the first mesa portion 10, to the length W.sub.2 in the direction parallel to the surface 1a of the substrate 1 formed by the second lateral surface 102b is 0.15 or more and 0.65 or less, the percentage of the volume of the active layer in the infrared light receiving element 100 can be increased. Therefore, the efficiency of photoelectric conversion is increased, and the infrared light receiving efficiency can be improved.
[0086] Further, since W.sub.1/W.sub.2, which is the ratio of the length W.sub.1 in the direction parallel to the surface 1a of the substrate 1 formed by the first lateral surface 101b, which is located at the lower part of the first mesa portion 10, to the length W.sub.2 in the direction parallel to the surface 1a of the substrate 1 formed by the second lateral surface 102b is 0.2 or more and 3.0 or less, the percentage of the volume of the active layer in the infrared light receiving element 100 can be increased. Therefore, the efficiency of photoelectric conversion is increased, and the infrared light receiving efficiency can be improved.
[0087] Further, the infrared light emitting element 200 according to this embodiment having the same structure as the infrared light receiving element 100 produces the above described effects in the same manner as the infrared light receiving element 100. However, the “light receiving efficiency” in the above effect is replaced with the “light emitting efficiency.”