Semiconductor light source, operating method and spectrometer
11371883 · 2022-06-28
Assignee
Inventors
- Christopher Koelper (Regensburg, DE)
- Carola Diez (Sinzing, DE)
- Tim BOESCKE (Regensburg, DE)
- Thomas Kippes (Neumarkt, DE)
- Melanie Sternecker (Dingolfing, DE)
- Daniel Dietze (Regensburg, DE)
Cpc classification
G01J3/00
PHYSICS
H01L27/15
ELECTRICITY
G01J3/10
PHYSICS
H01L25/167
ELECTRICITY
G01J3/32
PHYSICS
International classification
H01L25/16
ELECTRICITY
H01L27/15
ELECTRICITY
H01L25/065
ELECTRICITY
G01J3/10
PHYSICS
Abstract
A semiconductor light source configured for a spectrometer may include at least one multipixel chip, at least one color setting component disposed optically downstream of at least one of emission region, and a drive unit. The color setting component may be configured for altering a spectral emission behavior of assigned emission regions. The drive unit may be configured to operate a plurality of mutually independently drivable emission regions successively, such that during operation thereof at least three spectrally narrowband individual spectra are emitted successively by the plurality of mutually independently drivable emission regions together with the associated color setting component from which individual spectra a total spectrum emitted by the semiconductor light source is constituted.
Claims
1. A semiconductor light source configured for a spectrometer comprising: at least one multipixel chip comprising a plurality of mutually independently drivable emission regions; at least one color setting component disposed optically downstream of at least one of the emission regions or is integrated into the plurality of mutually independently drivable emission regions, and wherein the at least one color setting component is configured for altering a spectral emission behavior of a corresponding emission region of the plurality of mutually independently drivable emission regions; and a drive unit configured to operate the plurality of mutually independently drivable emission regions successively, such that during operation at least three spectrally narrowband individual spectra are emitted successively by the plurality of mutually independently drivable emission regions together with the associated color setting component, from which a total spectrum is emitted by the semiconductor light source.
2. The semiconductor light source as claimed in claim 1, wherein the color setting component comprises a phosphor layer extending continuously over the plurality of mutually independently drivable emission regions, and wherein the phosphor layer is disposed downstream of the at least one multipixel chip, wherein the color setting component comprises a plurality of color filters; wherein each color filter of the plurality of color filters is assigned to each individual emission region of the plurality of mutually independently drivable emission regions; and wherein the plurality of color filters succeed the phosphor layer to where the color filters define the individual spectra, and wherein the color setting component of said multipixel chip is constituted from the phosphor layer and from the plurality of color filters.
3. The semiconductor light source as claimed in claim 1, wherein the color setting component further comprises a plurality of phosphor layers; wherein each phosphor layer of the plurality of phosphor layers is assigned to each individual emission region of the plurality of mutually independently drivable emission regions of the at least one multipixel chip, such that the plurality of phosphor layers define the individual spectra.
4. The semiconductor light source as claimed in claim 1, wherein the plurality of mutually independently drivable emission regions of the at least one multipixel chip are combined to form a plurality of groups, wherein the color setting component comprises a continuous phosphor layer assigned to each group of the plurality of groups, such that the phosphor layers are arranged next to one another across the at least one multipixel chip, wherein the color setting component comprises a plurality of color filters respectively assigned to each individual emission region of the plurality of mutually independently drivable emission regions succeed the phosphor layers of the groups, such that the plurality of color filters define the individual spectra, and wherein the color setting component of said multipixel chip comprises the phosphor layers and from the plurality of color filters.
5. The semiconductor light source as claimed in claim 1, wherein the at least one multipixel chip comprises a plurality of multipixel chips, wherein at least some of the multipixel chips of the plurality of multipixel chips are configured for emission in different wavelength ranges, wherein the color setting component comprises at least one color filter; in each case at least one color filter succeeds the plurality of mutually independently drivable emission regions of said multipixel chips, such that the at least one color filter defines the individual spectra, and wherein the color setting component comprises the at least one color filter.
6. The semiconductor light source as claimed in claim 1, wherein the at least one multipixel chip comprises a plurality of multipixel chips, wherein at least some of the multipixel chips are configured for emission in different wavelength ranges, wherein the color setting component comprises a plurality of color filters and a plurality of phosphor layers that are situated next to one another and are disposed downstream of the plurality of mutually independently drivable emission regions of said multipixel chips, and wherein the plurality of color filters are assigned to each of the phosphor layers emission region by emission region, such that the color filters define the individual spectra, and wherein the color setting component of said multipixel chips comprises the phosphor layers and the color filters.
7. The semiconductor light source as claimed in claim 1, wherein a spectral width of the individual spectra ranges from 2 nm to 10 nm inclusive and/or between 300 cm.sup.−1 and 50 cm.sup.−1, wherein the total spectrum ranges from 40 to 520 individual spectra.
8. The semiconductor light source as claimed in claim 1, wherein the at least one multipixel chip is configured for generating near infrared and short-wave infrared radiation and the total spectrum extends continuously at least over the spectral range from 650 nm to 1.3 μm inclusive, wherein a thickness of the semiconductor light source ranges from 0.1 mm to 5 mm inclusive and a basic area of the semiconductor light source as seen in plan view is at most 5 mm×5 mm.
9. The semiconductor light source as claimed in claim 1, wherein the at least one multipixel chip is configured for generating blue light and the total spectrum extends continuously at least over the spectral range from 450 nm to 580 nm inclusive.
10. The semiconductor light source as claimed in claim 1, wherein the at least one multipixel chip comprises at least two multipixel chips configured to emit in mutually different wavelength ranges, wherein within each multipixel chip all of the plurality of mutually independently drivable emission regions are provided for generating radiation in the same wavelength range.
11. The semiconductor light source as claimed in claim 1, wherein the drive unit is the mechanically carrying and supporting component, such that the drive unit contributes to a total thickness of the semiconductor light source ranging from 30% to 70%.
12. The semiconductor light source as claimed in claim 1, wherein the at least one multipixel chip comprises a semiconductor layer sequence having an active zone for generating radiation, wherein the semiconductor layer sequence and/or the active zone extend(s) continuously over the plurality of mutually independently drivable emission regions of the relevant multipixel chip.
13. The semiconductor light source as claimed in claim 1, wherein the plurality of mutually independently drivable emission regions, as seen in plan view, each have dimensions ranging from 10 μm×10 μm to 50 μm×50 μm, wherein at least 25 and at most 1000 of the plurality of mutually independently drivable emission regions are present per multipixel chip.
14. The semiconductor light source as claimed in claim 1, further comprising a light emitting diode chip having a single channel and provided for generating one of the individual spectra.
15. The semiconductor light source as claimed in claim 1, wherein the at least one multipixel chip comprises a plurality of vertically emitting laser units configured for emitting radiation of different wavelengths of maximum intensity, wherein the color setting component is formed by resonators of the laser units.
16. An operating method for a semiconductor light source as claimed in claim 1, wherein the at least one multipixel chip is operated by the drive unit such that the at least three spectrally narrowband individual spectra are emitted successively, such that the total spectrum emitted by the semiconductor light source is constituted from the individual spectra.
17. A spectrometer comprising: at least one semiconductor light source as claimed in claim 1, and at least one detector chip for sequentially detecting radiation of the individual spectra, wherein the radiation is at least partly in the near infrared spectral range, and wherein a spectral resolution of the detector chip together with the semiconductor light source is 30 nm or less.
18. The spectrometer as claimed in claim 17, wherein the at least one detector chip is a photodiode, wherein the photodiode is based on the material system InGaAs or Ge and is configured for detecting radiation up to at least 1.3 μm, and wherein the spectral resolution of the detector chip together with the semiconductor light source is 8 nm or less.
19. The spectrometer as claimed in claim 17, wherein the spectrometer is free of movable components.
20. A smartphone comprising the spectrometer as claimed in claim 17.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Further advantages and refinements of the various embodiments may be explained below in connection with the figures, in which:
(2)
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(10) Elements which are the same or of the same type, or which have the same effect, are provided with the same references in the figures. The figures are respectively schematic representations and therefore not necessarily true to scale. Rather, relatively small elements, and in particular layer thicknesses, may be represented exaggeratedly large for illustration.
DETAILED DESCRIPTION
(11)
(12) The spectrometer 10 comprises a semiconductor light source 1 for emitting a radiation R. Furthermore, the spectrometer 10 comprises one or more detector chips 6 and also evaluation electronics 7. Optical components such as lenses are not depicted separately in order to simplify the illustration.
(13) The radiation R generated by the semiconductor light source 1 is reflected diffusively or else spectrally at a reflection object 8, for example a foodstuff, medicaments or human skin. Part of the reflected light, having been altered spectrally on account of spectrally different absorption, passes to the detector chip 6 and is detected there. In this case, the detector chip 6 has a single channel and splitting of a total spectrum G into spectrally narrowband individual spectra E takes place on the part semiconductor light source 1. By way of the evaluation electronics 7, it is possible to ascertain for example whether the reflection object 8 is ripe and/or fresh fruit and/or vegetables.
(14)
(15) An active zone 22 for generating radiation by means of electroluminescence is situated in the semiconductor layer sequence 21, which extends continuously across the entire multipixel chip 2. The semiconductor layer sequence 21 is structured to form individual emission regions 20, wherein a structuring into the emission regions 20 can extend through the active zone 22. The active zone 22 is thus restricted in island-shaped fashion to the respective emission regions 20. This structuring can also result in an optical isolation between the emission regions 20. For this purpose, the regions from which the semiconductor layer sequence 21 is removed between the emission regions 20 can be provided with a radiation-nontransmissive material, not depicted.
(16) A phosphor layer 31 extends continuously across all the emission regions 20. The phosphor layer 31 is configured for full conversion of radiation generated in the emission regions 20. For this purpose, the semiconductor layer sequence 21 emits red or near infrared light, for example, such that the phosphor layer 31 generates in spectrally broadband fashion near infrared and short-wave infrared radiation.
(17) If full conversion is not effected by the phosphor layer 31, then it is possible for a filter element (not depicted) for filtering out the radiation of the semiconductor layer sequence 21 to be disposed downstream of the phosphor layer 31. Such a filter element can be transmissive in broadband fashion in the spectral range of the radiation generated by the phosphor layer 31 and, consequently, does not need to effect spectral narrowing of the radiation from the phosphor layer 31.
(18) A thickness of the phosphor layer 31 is for example between 10 μm and 150 μm inclusive. The phosphor layer 31 can comprise phosphor particles which are sintered to form a ceramic or which are embedded into a matrix material, such as a silicone or a glass.
(19) The phosphor layer 31 includes a broadband-infrared-generating phosphor, for example a phosphor as described in the document WO 2016/174236 A1. The disclosure content of said document is incorporated by reference, in particular with regard to patent claims 7 and 8 of said document.
(20) Particularly for the spectral range of 600 nm to 1100 nm, the following phosphors, for instance, are appropriate: Ga.sub.2O.sub.3, Na(Ga,Al).sub.3O.sub.5, Mg.sub.4Nb.sub.2O.sub.9, Mg.sub.2SiO.sub.4:Cr, La.sub.3(Ga.sub.0.6Al.sub.0.4).sub.5GeO.sub.14, La.sub.3Ga.sub.5GeO.sub.14. Particularly for the spectral range of 1450 nm to 1550 nm, the following phosphors, for instance, are appropriate: Gd.sub.3Ga.sub.5O.sub.12:Ni, Ni.sup.2+-doped Gd.sub.3Ga.sub.5O.sub.12 (GGG), YAlO:Ni, Ti, LGO:Ni, Ti, GGG:Ni, Gd.sub.3Ga.sub.5O.sub.12:Ni codoped with M.sup.4+, Zr.sup.4+ and/or Ge.sup.4+, Gd.sub.3Ga.sub.5O.sub.12:Ni codoped with Zr.sup.4+, Ti.sup.4+, Si.sup.4+ and/or Ge.sup.4+.
(21)
(22) A total spectrum G1 is emitted by the emission regions 20 and thus by the multipixel chip 2. Radiation from the total spectrum G1 does not pass from the semiconductor light source 1. The total spectrum G1 serves for exciting the phosphor layer 31 and can be in the red spectral range. For this purpose, the semiconductor layer sequence 21 is based on the material system AlInGaAs for instance for red or near infrared light or else on AlInGaN0 for instance for blue light.
(23) The spectrum G2 generated by the phosphor layer 31 is decomposed into a multiplicity of individual spectra E by the color filters 32, wherein the sum of the individual spectra E forms the total spectrum G. In a non-limiting embodiment, a spectrally continuous range extending over a large part or over the entirety of the spectrum G2 of the phosphor layer 31 is formed by the individual spectra E.
(24) The individual emission regions 20 are successively driven temporally sequentially, such that the individual spectra E are emitted temporally successively and the total spectrum G forms only on average over time. Thus, the single-channel detector chip 6 can record a spectrum sequentially, on account of the spectral selectivity of the semiconductor light source 1.
(25) The semiconductor light source 1 thus comprises separately addressable pixels in the form of the emission regions 20. The driving is effected by way of the drive unit 4, which is an IC. The phosphor layer 31 is deposited over the whole area, for example as an adhesively bonded lamella, as a full potting or as a layer applied by means of spray coating or by electrophoresis.
(26) Adhesive layers possibly present for the phosphor layer 31 and the color filters 32, which can also be present in all other exemplary embodiments, are not depicted in each case. Such adhesive layers are not crucial for the spectral properties since corresponding adhesives based on silicones, in particular, are transparent in the relevant spectral ranges and have in particular only small layer thicknesses for instance of at most 5 μm.
(27) The color filters 32, fashioned as filter lamellae, are for example line filters and can be arranged in a checkered manner, as seen in plan view; see also
(28) A lateral size of the color filters 32 corresponds to the size of the individual emission regions 20, for example with a tolerance of at most 20% or 10% or 5% of a lateral extent. The individual color filters 32 can be situated on a continuous, transparent carrier at a side facing away from the phosphor layer 31; see also the explanations concerning
(29) With regard to the color filters 32, simple Fabry-Perot filters are appropriate. The two mirrors of the Fabry-Perot filter can either be composed of metal or be designed as purely dielectric highly reflective mirrors. In the latter case, significantly more layers are necessary and the filter is correspondingly more expensive; in return, a higher transmission is achievable. The reflectivity of the mirrors determines the line width and the thickness of the layer in the center between the mirrors, for example composed of a transparent oxide such as SiO.sub.2, determines the center wavelength. The individual color filters 32 could all have the same mirrors and a center layer thickness adapted in each case to the target wavelength.
(30)
(31) The phosphors 31 used are for example quantum dots, for instance based on PbS or CdS, wherein an exact emission wavelength can be set by an organic shell around the semiconductor cores of the quantum dots.
(32) Such phosphors are described for example in the document Liangfeng Sun et al., Bright infrared quantum-dot light-emitting diodes through inter-dot spacing control, in Nature Nanotechnology, vol. 7, pages 369 to 373, published in 2012, doi:10.1038/nnano.2012.63. Furthermore, such phosphors are described in the document Nobuhiko Ozakil et al., Near-infrared superluminescent diode using stacked self-assembled InAs quantum dots with controlled emission wavelengths, Japanese Journal of Applied Physics, vol. 53, 04EG10, published in 2014, doi:10.7567/JJAP.53.04EG10. The disclosure content of these documents with regard to the quantum dots is incorporated by reference.
(33) Particularly for the spectral range of 600 nm to 1100 nm, the following phosphors, for instance, are appropriate: Ga.sub.2O.sub.3, Na(Ga,Al).sub.3O.sub.5, Mg.sub.4Nb.sub.2O.sub.9, Mg.sub.2SiO.sub.4:Cr, La.sub.3(Ga.sub.0.6Al.sub.0.4).sub.5GeO.sub.14, La.sub.3Ga.sub.5GeO.sub.14. Particularly for the spectral range of 1450 nm to 1550 nm, the following phosphors, for instance, are appropriate: Gd.sub.3Ga.sub.5O.sub.12:Ni, Ni.sup.2+-doped Gd.sub.3Ga.sub.5O.sub.12 (GGG), YAlO:Ni, Ti, LGO: Ni, Ti, GGG:Ni, Gd.sub.3Ga.sub.5O.sub.12:Ni codoped with M.sup.4+, Zr.sup.4+ and/or Ge.sup.4+, Gd.sub.3Ga.sub.5O.sub.12:Ni codoped with Zr.sup.4+, Ti.sup.4+, Si.sup.4+ and/or Ge.sup.4+.
(34) The phosphor layers 31 are applied for example as described in the document WO 2016/034388 A1. The disclosure content of said document is incorporated by reference, in particular with regard to claims 16 and 18 of said document.
(35) Unlike in the illustration in
(36)
(37) By way of example, the semiconductor layer sequence and the phosphor layers in
(38) Alternatively, the semiconductor layer sequence and the phosphor layers in
(39) A plurality of multipixel chips 2 are present in the exemplary embodiment in
(40) A phosphor layer 31 is applied to the multipixel chips 2 over the whole area in each case. The phosphor layers 31 of the multipixel chips 2 here differ from one another and emit in different spectral ranges G2, which can be adjacent to one another and/or overlap. As seen in plan view, the phosphor layers 31 lie next to one another and can partly or else completely cover the drive unit 4. The phosphor layers 31 are for example fashioned as a full potting or applied as lamellae or can be applied on the semiconductor layer sequence 21 by means of spray coating.
(41) In each case a plurality of color filters 32, for example filter lamellae, are subsequently applied to the individual phosphor layers 31. There is a one-to-one assignment between the color filters 32 and the associated emission regions 20. As seen in plan view, the color filters 32, also like the color filters 32 from
(42) The spectral properties of the configuration from
(43) A plurality of multipixel chips 2 are present in the exemplary embodiment in
(44) The total spectrum G is thus constituted, see
(45) Multipixel chips 2 that emit in different colors are present in the exemplary embodiment in
(46) Optionally, the color filters 32 can be applied on a larger filter plate 32a covering a plurality of the emission regions 20. By way of example, the filter plate 32a is a material filter and the color filters 32 are Fabry-Perot filters. By means of such filter grading, sidebands of the Fabry-Perot filters can easily be suppressed.
(47) At the same time, just an array of color filters 32 can be disposed in island-shape fashion downstream of another group 5 of emission regions 20, without phosphor. A further multipixel chip 2 is provided with individual, island-shaped phosphor layers 31, for example. In other words, the embodiments of the semiconductor light source 1 as illustrated in connection with
(48) As also in all other exemplary embodiments, it is possible for one or more unpixellated light emitting diode chips 29 additionally to be present, the latter respectively emitting one of the individual spectra E, depicted by dashed lines in
(49) Consequently, see
(50)
(51) In the case of the sectional illustration in
(52) The configurations in
(53)
(54) Alternatively, the phosphor layers 31 and/or color filters 32 on the intermediate carrier 34 can all be identical, such that only one of the phosphor layers 31 and/or of the color filters 32 is transferred from the intermediate carrier 34 for instance by means of the laser radiation. A dedicated intermediate carrier 34 can then be present for each of the phosphor layers 31 and/or of the color filters 32.
(55) Such transferring is described for instance in the document US 2013/0292724 A1. The disclosure content of said document is incorporated by reference, in particular with regard to paragraphs 49 to 54 of said document.
(56)
(57) The associated emission spectrum of the multipixel chip 2 and of the phosphor layer 31 is shown in
(58) The multipixel chip 2 is for example a pixelated variant of the LED chip OSRAM OS SFH 4735 or SFH 4736. The phosphor in the phosphor layer 31 is, in particular, Cr-doped lanthanum gallogermanate, La.sub.3Ga.sub.5GeO.sub.14:Cr.
(59) In the exemplary embodiment of the spectrometer in
(60) Optionally, such color filters are also situated in front of the laser units, not depicted. If an emission of the laser units is already sufficiently spectrally narrowband, for example on account of a configuration of the resonators of the laser units, then color filters directly downstream of the laser units are omitted.
(61)
(62) If the emission spectra of the VCSEL are tuned to the filter curves and the individual VCSEL units are individually driven temporally successively, then filtering can also be completely dispensed with and single-chip detectors can be used.
(63) The VCSELs are constructed for example as described in the documents DE 10 2017 130 582 A1 or DE 10 2018 104 785 A1. The disclosure content of said documents with regard to the construction of the VCSELs is incorporated by reference.
(64) As a result of the use of VCSELs for the multipixel chips 2, a significantly increased efficiency of the semiconductor light source 1 in particular in the desired IR spectral range is achievable by virtue of the avoidance of conversion losses and the Stokes shift. Moreover, a significantly more directional emission profile is possible as a result of the use of the VCSELs in contrast to a Lambertian emitter search an LED. As a result, additional optical units for beam collimation can be avoided, which entails cost advantages.
(65) A many times higher optical output power of the semiconductor light source 1 using VCSELs in the desired spectral range is achievable overall. It is thus possible to realize larger distances in the application between the semiconductor light source 1 and the reflection object to be examined. Higher market acceptance and simpler and also more reliable handling by the user are thus possible. New fields of application such as, for example, in automated plant monitoring and in foodstuffs monitoring can be opened up as a result.
(66) The components shown in the figures, unless indicated otherwise, follow one another directly in each case in the indicated order. Layers that are not touching in the figures are at a distance from one another. Insofar as lines are drawn parallel to one another, the corresponding surfaces are likewise oriented parallel to one another. Likewise, unless indicated otherwise, the relative positions of the depicted components with respect to one another are rendered correctly in the figures.
(67) The invention described here is not restricted by the description on the basis of the exemplary embodiments. Rather, the invention encompasses any novel feature and also any combination of features, which in particular includes any combination of features in the patent claims, even if this feature or this combination itself is not explicitly specified in the patent claims or exemplary embodiments.
LIST OF REFERENCE SIGNS
(68) 1 Semiconductor light source 2 Multipixel chip 20 Emission region 21 Semiconductor layer sequence 22 active zone 29 unpixelated light emitting diode chip 31 Color setting means—phosphor layer 32 Color setting means—color filter 33 optical isolation 34 Intermediate carrier 4 Drive unit 5 Group of emission regions 6 Detector chip 7 Evaluation electronics 8 Reflection object (foodstuffs, skin) 9 Smartphone 10 Spectrometer 11 Lens 12 Broadband light source 13 dispersive optical element 14 Diaphragm/spatial filter 15 Transmission object E spectrally narrowband individual spectrum G Total spectrum I Intensity L Wavelength R Radiation