DISPLAY APPARATUS, LIGHT EMITTING DEVICE, AND LIGHT EMITTING MEMBER
20220199695 · 2022-06-23
Inventors
Cpc classification
H01L2933/0091
ELECTRICITY
H01L25/18
ELECTRICITY
H10K59/38
ELECTRICITY
H01L33/504
ELECTRICITY
H05B33/12
ELECTRICITY
H10K2102/331
ELECTRICITY
G09F9/30
PHYSICS
H10K50/865
ELECTRICITY
H01L25/167
ELECTRICITY
International classification
H01L25/18
ELECTRICITY
Abstract
The display apparatus includes a plurality of light emitting device units each including: a light generating unit 11, 21, or 31; a wavelength conversion layer 12, 22, or 32 including a color conversion layer 13, 23, or 33 that includes a particulate color conversion material; and a first light emitting device 10, a second light emitting device 20, or a third light emitting device 30 including a wavelength selection layer 14, 24, or 34. The wavelength of light emitted from the third wavelength selection layer 34 is longer than the wavelength of light emitted from the second wavelength selection layer 24 and the wavelength of light emitted from the first wavelength selection layer 14. The wavelength of light emitted from the second wavelength selection layer 24 is longer than the wavelength of light emitted from the first wavelength selection layer 14. Further, T.sub.1<T.sub.2≤T.sub.3 is satisfied, where T.sub.1 denotes the thickness of the first color conversion layer 14, T.sub.2 denotes the thickness of the second color conversion layer 24, and T.sub.3 denotes the thickness of the third color conversion layer 34.
Claims
1. A display apparatus comprising a plurality of light emitting device units each including a first light emitting device, a second light emitting device, and a third light emitting device, wherein the first light emitting device includes a first light generating unit that generates light having a wavelength λ.sub.0, a first wavelength conversion layer that includes a first color conversion layer having a thickness T.sub.1 and including a particulate color conversion material, the particulate color conversion material converting a color of the light having the wavelength λ.sub.0 emitted from the first light generating unit, and a first wavelength selection layer that the light emitted from the first wavelength conversion layer enters and that emits light having a wavelength λ.sub.1′, the second light emitting device includes a second light generating unit that generates light having a wavelength λ.sub.0, a second wavelength conversion layer that includes a second color conversion layer having a thickness T.sub.2 and including a particulate color conversion material, the particulate color conversion material converting a color of the light having the wavelength λ.sub.0 emitted from the second light generating unit, and a second wavelength selection layer that the light emitted from the second wavelength conversion layer enters and that emits light having a wavelength λ.sub.2′, the third light emitting device includes a third light generating unit that generates light having a wavelength λ.sub.0, a third color conversion layer that includes a third color conversion layer having a thickness T.sub.3 and including a particulate color conversion material, the particulate color conversion material converting a color of the light having the wavelength λ.sub.0 emitted from the third light generating unit, and a third wavelength selection layer that the light emitted from the third wavelength conversion layer enters and that emits light having a wavelength λ.sub.3′ (where λ1′<λ2′<λ3′ holds), and T.sub.1<T.sub.2≤T.sub.3 is satisfied.
2. The display apparatus according to claim 1, wherein the particulate color conversion material in each of the light emitting devices includes a first quantum dot that converts light having a wavelength λ.sub.0 into light having a wavelength λ.sub.2″ (where λ.sub.2″>λ.sub.0 holds) and a second quantum dot that converts light having a wavelength λ.sub.0 into light having a wavelength λ.sub.3″ (where λ.sub.3″>λ.sub.2″>λ.sub.0 holds).
3. The display apparatus according to claim 2, satisfying T.sub.1<T.sub.2=T.sub.3.
4. The display apparatus according to claim 2, satisfying T.sub.1<T.sub.2<T.sub.3.
5. The display apparatus according to claim 1, wherein the wavelength conversion layer in each of the light emitting devices further includes a spacer layer, and a total thickness of a thickness of the spacer layer and a thickness of the color conversion layer is equal between the light emitting devices.
6. The display apparatus according to claim 1, wherein the wavelength conversion layer in each of the light emitting devices includes light scattering particles.
7. The display apparatus according to claim 1, wherein the wavelength selection layer in each of the light emitting devices includes light scattering particles.
8. The display device according to claim 1, wherein the wavelength conversion layer in each of the light emitting devices further includes a light-scattering particle layer.
9. The display device according to claim 1, wherein an on-chip micro-lens is provided on a light emitting side of the wavelength selection layer in each of the light emitting devices.
10. The display apparatus according to claim 1, wherein the light generating unit in each of the light emitting devices is coupled to drive circuitry provided on a base.
11. The display apparatus according to claim 1, wherein a transparent material member is provided between the light generating unit and the wavelength conversion layer in each of the light emitting devices.
12. The display apparatus according to claim 1, wherein a transparent material member is provided between the wavelength conversion layer and the wavelength selection layer in each of the light emitting devices.
13. The display apparatus according to claim 1, wherein the light generating unit in each of the light emitting devices comprises a light emitting diode.
14. The display apparatus according to claim 1, wherein the light generating unit in each of the light emitting devices comprises an organic electroluminescent device.
15. The display apparatus according to claim 1, wherein a light shutter means is provided between the wavelength conversion layer and the wavelength selection layer in each of the light emitting devices.
16. A light emitting device comprising: a light generating unit that generates light having a wavelength λ.sub.0; and a wavelength conversion layer that includes a color conversion layer including a particulate color conversion material, the particulate color conversion material converting a color of the light having the wavelength emitted from the light generating unit, wherein the color conversion layer has a thickness determined on a basis of the wavelength λ″ (where λ″>λ.sub.0 holds) of light emitted from the wavelength conversion layer.
17. The light emitting device according to claim 16, wherein the particulate color conversion material includes quantum dots.
18. The light emitting device according to claim 16, further comprising a wavelength selection layer that the light emitted from the wavelength conversion layer enters.
19. A light emitting member comprising a first light emitting portion, a second light emitting portion, and a third light emitting portion, wherein the first light emitting portion includes a first wavelength conversion layer including a first color conversion layer, the first color conversion layer having a thickness T.sub.1 and including a particulate color conversion material, the particulate color conversion material converting a color of light having a wavelength λ.sub.0 emitted from a light generating unit, the second light emitting portion includes a second wavelength conversion layer including a second color conversion layer, the second color conversion layer having a thickness T.sub.2 and including a particulate color conversion material, the particulate color conversion material converting a color of light having a wavelength λ.sub.0 emitted from a light generating unit, the third light emitting portion includes a third wavelength conversion layer including a third color conversion layer, the third color conversion layer having a thickness T.sub.3 and including a particulate color conversion material, the particulate color conversion material converting a color of light having a wavelength λ.sub.0 emitted from a light generating unit, T.sub.1<T.sub.2≤T.sub.3 is satisfied, and a peak wavelength of a light spectrum of light emitted from the first wavelength conversion layer is different from a peak wavelength of a light spectrum of light emitted from the second wavelength conversion layer and a peak wavelength of a light spectrum of light emitted from the third wavelength conversion layer.
Description
BRIEF DESCRIPTION OF DRAWINGS
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MODES FOR CARRYING OUT THE INVENTION
[0055] Hereinafter, the present disclosure will be described on the basis of examples with reference to the accompanying drawings. The present disclosure, however, is not limited to these examples, and various numerical values and materials in the examples are illustrative. Note that the description is made in the following order: [0056] 1. Outline description of display apparatus, light emitting device, and light emitting member of the present disclosure [0057] 2. Example 1 (display apparatus, light emitting device, and light emitting member) [0058] 3. Example 2 (Modification of Example 1) [0059] 4. Example 3 (Modification of Examples 1 and 2) [0060] 5. Example 4 (Modification of Example 1 to 3) [0061] 6. Example 5 (Modification of Examples 1 to 4) [0062] 7. Example 6 (Modification of Examples 1 to 5) [0063] 8. Example 7 (Modification of Examples 1 to 6) [0064] 9. Example 8 (Modification of Examples 1 to 7) [0065] 10. Example 9 (Modification of Examples 1 to 8) [0066] 11. Example 10 (Modification of Examples 1 to 9) [0067] 12. Other
Outline Description of Display Apparatus, Light Emitting Device, and Light Emitting Member of the Present Disclosure
[0068] Hereinafter, the display apparatus of the present disclosure and the light emitting member of the present disclosure may be collectively referred to simply as a “display apparatus and the like of the present disclosure”. In that case, the light emitting device is read as a light emitting unit as required.
[0069] The light emitting device of the present disclosure may include a particulate color conversion material that includes first quantum dots and second quantum dots. Further, the light emitting device of the present disclosure including such a preferable form may be further provided with a wavelength selection layer that the light emitted from a wavelength conversion layer enters.
[0070] The particulate color conversion material in each light emitting device in the display apparatus and the like of the present disclosure may include the first quantum dots that convert light having a wavelength λ.sub.0 into light having a wave λ.sub.2″ (specifically, λ.sub.2-peak″) (where λ.sub.2″>λ.sub.0 holds), and the second quantum dots that convert light having a wavelength λ.sub.0 into light having a wavelength λ.sub.3″ (specifically, λ.sub.3-peak″) (where λ.sub.3″>λ.sub.2″>λ.sub.0 holds). Here, it is preferable that the second quantum dots further convert light having a wave λ.sub.2″ (specifically, λ.sub.2-peak″) into light having a wave λ.sub.3″ (specifically, λ.sub.3-peak″). Further, in that case, it is preferable that T.sub.1<T.sub.2=T.sub.3 be satisfied. Here, the thicknesses T.sub.1, T.sub.2, and T.sub.3 preferably satisfy a relation represented by, but not limited to,
1≤(T.sub.2=T.sub.3)/T.sub.1,
and more preferably,
1≤(T.sub.2=T.sub.3)/T.sub.1≤100.
Alternatively, in that case, it is preferable that T.sub.1<T.sub.2<T.sub.3 be satisfied. Here, the thicknesses T.sub.1, T.sub.2, and T.sub.3 preferably satisfy a relation represented by, but not limited to,
2≤T.sub.2/T.sub.1,
3≤T.sub.3/T.sub.1, and
1.5≤T.sub.3/T.sub.2, and more preferably,
2≤T.sub.2/T.sub.1≤100,
3≤T.sub.3/T.sub.1≤100, and
1.5≤T.sub.3/T.sub.2≤10.
[0071] In the display apparatus and the like of the present disclosure including the various preferable forms described above, the wavelength conversion layer in each light emitting device may further include a spacer layer. The total thickness of the thickness of the spacer layer and the thickness of the color conversion layer may be equal between the light emitting devices. The spacer layer may be positioned on a light incident side of the color conversion layer or a light emitting side of the color conversion layer. The phrase “thickness is equal” means that
0.9≤T.sub.1-Total/T.sub.2-Total≤1.1,
0.9≤T.sub.2-Total/T.sub.3-Total≤1.1, and
0.9≤T.sub.1-Total/T.sub.3-Total≤1.1
are satisfied, where T.sub.1-Total denotes the total thickness of the thickness of the spacer layer and the thickness of the color conversion layer in the first light emitting device, T.sub.2-Total denotes the total thickness of the thickness of the spacer layer and the thickness of the color conversion layer in the second light emitting device, and T.sub.3-Total denotes the total thickness of the thickness of the spacer layer and the thickness of the color conversion layer in the third light emitting device. The same applies to the following description. It is to be noted that, in general, the state satisfying such expressions in terms of the thicknesses may be expressed as “satisfying within a range of ±10% of thickness variation”. Examples of the material of the spacer layer may include a transparent member, such as an acrylic ultraviolet curable resin, an epoxy-based ultraviolet curable resin, a silicone-based thermosetting resin, and an epoxy-based thermosetting resin.
[0072] Further, in the display apparatus and the like of the present disclosure including the various preferable forms described above, the wavelength conversion layer may include light scattering particles, or the wavelength selection layer may include light scattering particles. Alternatively, in the display apparatus and the like of the present disclosure including the various preferable forms described above, the wavelength conversion layer in each light emitting device may further include a light scattering particle layer. In this case, the total thickness of the thickness of the light-scattering particle layer and the color conversion layer may be equal between the light emitting devices. The light-scattering particle layer is preferably provided on the light emitting side of the color conversion layer. The phrase “thickness is equal” means that
0.9≤T.sub.1-Total′/T.sub.2-Total′≤1.1
0.9≤T.sub.2-Total′/T.sub.3-Total′≤1.1, and
0.9≤≤T.sub.1-Total′/T.sub.3-Total′≤1.1
are satisfied, where T.sub.1-Total′ denotes the total thickness of the thickness of a first light-scattering particle layer and the thickness of a first color conversion layer in the first light emitting device, T.sub.2-Total′ denotes the total thickness of the thickness of a second light-scattering particle layer and the thickness of a second color conversion layer in the second light emitting device, and T.sub.3-Total′ denotes the total thickness of the thickness of a third light-scattering particle layer and the thickness of a third color conversion layer in the third light emitting device.
[0073] Examples of the light scattering particles or the light scattering particles included in the light-scattering particle layer may include SiO.sub.2, Al.sub.2O.sub.3, and TiO.sub.2. Using the light scattering particles allows the light emitted from the light emitting device to be in the Lambertian light distribution state or have light distribution characteristics close to the Lambertian light distribution state.
[0074] Further, in the display apparatus and the like of the present disclosure including the various preferable forms described above, an on-chip micro-lens may be provided more adjacent to the light-emitting side of each light emitting device than the wavelength selection layer is. The on-chip micro-lens may be an on-chip micro-lens having a known configuration or structure. Examples of the material of the on-chip micro-lens may include a transparent resin material, such as an acrylic resin, an epoxy-based resin, a polycarbonate resin (PC), a polyimide-based resin, a polymethyl methacrylate resin (PMMA), a polyarylate resin (PAR), a polyethylene terephthalate resin (PET), and an ABS resin, and glass. The on-chip micro-lens may be obtained by melt-flowing or etching back a transparent resin material. Alternatively, the on-chip micro-lens may be obtained by a combination of a photolithography technique and an etching method using a gray-tone mask. Still alternatively, the on-chip micro-lens may be obtained by forming a transparent resin material into a lens shape by a nano-imprint method.
[0075] Further, in the display apparatus and the like of the present disclosure including the various preferable forms described above, a light generating unit of each light emitting device may be coupled to drive circuitry provided on a base. The drive circuitry may have a known configuration or structure to drive the light generating unit. Examples of the method of coupling the light generating unit and the drive circuitry provided on the base may include, a method using a bump including solder, indium, gold (Au) or the like, a plating method, a chip-on-chip method, a method using a through-chip via (TCV) or through-silicon via (TSV), and metal-metal junction, such as Cu—Cu junction. The base may be, for example, a silicon semiconductor base, a glass base, a GaN base, or a SiC base.
[0076] Further, in the display apparatus and the like of the present disclosure including the various preferable forms described above, a transparent material member may be provided between the light generating unit and the wavelength conversion layer in each light emitting device. Alternatively, the transparent material member may be provided between the wavelength conversion layer and the wavelength selection layer in each light emitting device. Examples of the material of the transparent material member may include an organic polymer (polymeric products such as a flexible plastic film, a plastic sheet, or a plastic base including a polymeric material), such as polymethyl methacrylate (PMMA), polyvinyl alcohol (PVA), polyvinyl phenol (PVP), polyethersulfone (PES), polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polybutylene terephthalate (PBT), acetyl cellulose, tetraacetyl cellulose, polyphenylene sulfide, polycarbonate (PC), polyethylene (PE), polypropylene (PP), polyvinylidene fluoride, brominated phenoxy, polyamide, polyimide, polystyrene, polyarylate, polysulfone such as polyester sulfone, and polyolefine. Another examples of the material of the transparent material member may include a glass base and a sapphire base. Alternatively, a space (gap) may be provided more adjacent to the light generating unit than the transparent material member is. For example, the space (gap) may be provided between the wavelength conversion layer and the wavelength selection layer, or between the light generating unit and the wavelength conversion layer. In the light emitting member of the present disclosure, the first wavelength conversion layer, the second wavelength conversion layer, and the third wavelength conversion layer may be formed on the transparent material member.
[0077] Further, in the display apparatus and the like of the present disclosure including the various preferable forms described above, the light generating unit of each light emitting device may include a light emitting diode (LED). In this case, the LED may include at least a first compound semiconductor layer, an active layer, and a second compound semiconductor layer from the wavelength conversion layer side. The first compound semiconductor layer, the active layer, and the second compound semiconductor layer are laminated into a laminated light emitting structure. The laminated light emitting structure may include, for example, a GaN-based compound semiconductor (including AlGaN mixed crystal, AlGaInN mixed crystal, or GaInN mixed crystal), an AlGaInAs-based compound semiconductor, an AlGaInP-based compound semiconductor, a ZnSe-based compound semiconductor (including ZnS, ZnSSe, or ZnMgSSe, for example), or a ZnO-based compound semiconductor. To drive the light generating unit, the laminated light emitting structure is coupled to an electrode. Examples of the material of the electrode may include Pd, ITO, a AuGe/NiAu laminated structure, a Ti/Pt/Au laminated structure, and an Ni/Au laminated structure. Alternatively, the light generating unit of each light emitting device may be an organic electroluminescent device. The organic electroluminescent (EL) device may have a known configuration or structure. The first light generating unit, the second light generating unit, and the third light generating unit that generate light having a wavelength λ.sub.0 may have the same configuration or structure.
[0078] Further, in the display apparatus and the like of the present disclosure including the various preferable forms described above, a light shutter means may be provided between the wavelength conversion layer and the wavelength selection layer in each light emitting device. The light shutter means may be, for example, a liquid crystal display of a transmission type.
[0079] In the display apparatus and the like of the present disclosure, the light emitting device unit may include a fourth light emitting device, a fifth light emitting device, . . . in addition to the first light emitting device, the second light emitting device, and the third light emitting device.
[0080] In the display apparatus and the like of the present disclosure including the various preferable forms described above, it is preferable that the light emitting devices be separated by a sidewall (partition wall). Examples of the material of the sidewall (partition wall) may include a resist material, various metals, various alloys, various resins, and insulating materials such as SiO.sub.2 and SiN. Further, the sidewall (partition wall) may surround each light generating unit and a coupling portion between each light generating unit and the drive circuitry. Optionally, a light reflection layer may be formed on an inner surface of the sidewall. Examples of the material of the light reflection layer may include Ag, Au, Al, and a multilayer film including dielectric substances such as SiO.sub.2, Al.sub.2O.sub.3, TiO.sub.2, and Ta.sub.2O.sub.5.
[0081] In the display apparatus and the like of the present disclosure including the various preferable forms described above, the total thickness of the thickness of the wavelength conversion layer and the thickness of the wavelength selection layer may be equal between the light emitting devices. The phrase “thickness is equal” means that
0.9≤T.sub.1-Total″/T.sub.2-Total″≤1.1
0.9≤T.sub.2-Total″/T.sub.3-Total″≤1.1, and
0.9≤T.sub.1-Total″/T.sub.3-Total″≤1.1
are satisfied, where T.sub.1-Total denotes the total thickness of the thickness of the wavelength conversion layer and the thickness of the wavelength selection layer in the first light emitting device, T.sub.2-Total denotes the total thickness of the thickness of the wavelength conversion layer and the thickness of the wavelength selection layer in the second light emitting device, and T.sub.3-Total denotes the total thickness of the thickness of the wavelength conversion layer and the thickness of the wavelength selection layer in the third light emitting device.
[0082] Additionally, in the display apparatus and the like of the present disclosure including the various preferable forms described above, an optical crosstalk suppression unit may be provided in a region between the light emitting devices.
[0083] Herein, the light having a wavelength λ.sub.0 is generated in the light generating unit. The light generated in the light generating unit, however, may have a narrow spectrum width (i.e., may have one or more spectral peaks) or a certain (wide) spectrum width. The wavelength range (full width half maximum (FWHM)) of the wavelength λ.sub.0 may be in a range of 10 nm to 50 nm. The light having the wavelength λ.sub.1′ emitted from the first wavelength selection layer may be blue light, specifically, light having a wavelength range (FWHM) of 430 nm to 500 nm, for example. The light having the wavelength λ.sub.2′ emitted from the second wavelength selection layer may be green light, specifically, light having a wavelength range (FWHM) of 500 nm to 570 nm, for example. The light having the wavelength λ.sub.3′ emitted from the third wavelength selection layer may be red light, specifically, light having a wavelength range (FWHM) of 610 nm to 750 nm, for example. Note that λ.sub.1′<λ.sub.2′<λ.sub.3′ is satisfied. Specifically, λ.sub.1′<λ.sub.2′<λ.sub.3′ is satisfied when λ.sub.1-peak′<λ.sub.2-peak′<λ.sub.3-peak′ holds, where λ.sub.1-peak′ denotes the peak wavelength of the light spectrum of the wavelength λ.sub.1′, λ.sub.2-peak′ denotes the peak wavelength of the light spectrum of the wavelength λ.sub.2′, and λ.sub.3-peak′ denotes the peak wavelength of the light spectrum of the wavelength λ.sub.3′.
[0084] Additionally, the light of having wavelength λ.sub.2″ emitted mainly from the second wavelength conversion layer may be green light, specifically, light having a wavelength range (FWHM) of 500 nm to 570 nm, for example. The light having the wavelength λ.sub.3″ emitted mainly from the third wavelength conversion layer may be red light, specifically, light having a wavelength range (FWHM) of 610 nm to 750 nm, for example.
[0085] The various forms of the light emitting device in the display apparatus and the like of the present disclosure including the various preferable forms described above may be applied to the light emitting device of the present disclosure as appropriate.
[0086] As the size (diameter) of a quantum dot decreases, the band gap energy increases, and the wavelength of light emitted from the quantum dot shortens. That is, a quantum dot having a smaller size emits light having a shorter wavelength (light on the blue light side), and a quantum dot having a larger size emits light having a longer wavelength (light on the red light side). Thus, quantum dots emitting light having a desired wavelength (converting the color of light into a desired color) may be produced by using the same material for the quantum dots and adjusting the size of the quantum dots. For example, the first quantum dot and the second quantum dot may be formed of different materials; however, it is desirable that the first quantum dot and the second quantum dot be formed of the same material (but having different diameters) to simplify the structure and simplify the manufacturing process. That is, it is preferable that the first color conversion layer, the second color conversion layer, and the third color conversion layer include the same particulate color conversion material. The quantum dot preferably has a core shell-structure.
[0087] Examples of the material of the first quantum dot or the second quantum dot may include, but not limited to, Si; Se; chalcopyrite-based compounds such as CIGS (CuInGaSe), CIS (CuInSe.sub.2), CuInS.sub.2, CuAlS.sub.2, CuAlSe.sub.2, CuGaS.sub.2, CuGaSe.sub.2, AgAlS.sub.2, AgAlSe.sub.2, AgInS.sub.2, and AgInSe.sub.2; perovskite-based materials; III-V group compounds such as GaAs, GaP, InP, InAs, InGaAs, AlGaAs, InGaP, AlGaInP, InGaAsP, and GaN; CdSe, CdSeS, CdS, CdTe, In.sub.2Se.sub.3, In.sub.2S.sub.3, Bi.sub.2Se.sub.3, Bi.sub.2S.sub.3, ZnSe, ZnTe, ZnS, HgTe, HgS, PbSe, PbS, and TiO.sub.2.
[0088] The color conversion layer includes the particulate color conversion material. Alternatively, the color conversion layer includes the particulate color conversion material embedded in a filler or a matrix. Examples of the filler may include a polypropylene resin, a polyethylene resin, a polystyrene resin, an AS resin, an ABS resin, a methacrylic resin, a polyvinyl chloride resin, a polyacetal resin, a polyamide resin, a polycarbonate resin, a modified polyphenylene ether resin, a polybutylene terephthalate resin, a polyethylene terephthalate resin, a polysulfone resin, a polyethersulfone resin, a polyphenylene sulfide resin, a polyamide imide resin, a polymethylpentene resin, a liquid crystal polymer resin, an epoxy resin, a phenol resin, a urea resin, a melanine resin, a diallylphthalate resin, an unsaturated polyester resin, a polyimide resin, a polyurethane resin, a silicone resin, an acrylic resin, and a mixture of these resins.
[0089] The wavelength selection layer (wavelength selection means) may be, for example, a color filter layer including a color resist material, a photonic crystal or a wavelength selection element to which a plasmon is applied (a color filter having a conductor lattice structure provided with a conductor thin film having a lattice-shaped hole structure, see, for example, Japanese Unexamined Patent Application Publication No. 2008-177191), or a thin film including an inorganic material such as amorphous silicon.
[0090] The display apparatus of the present disclosure may be applied to various display apparatuses, such as a video wall, a smart phone, a television receiver, a display or monitor for a personal computer and the like, a display for AR/VR, a projector, a head-up display, a head-mounted display, and a wearable device (a smart watch).
Example 1
[0091] Example 1 relates to the display apparatus, the light emitting device, and the light emitting member of the present disclosure.
[0092] Before the display apparatus, the light emitting device, and the light emitting member of Example 1 are described, the basic operation and the like of the display apparatus of Example 1 is described first hereinafter.
[0093] The relationship between a light absorption rate A of the color conversion layer, an absorption coefficient a standardized by the film thickness, and an optical path length L is represented by the following expression (1):
A=1−exp(−α×L) (1)
where the absorption coefficient a is substantially proportional to the concentration of the quantum dots.
[0094] The absorption spectrum “G” of the quantum dot emitting green light (referred to as “quantum dot G” for convenience) and the absorption spectrum “R” of the quantum dot emitting red light (referred to as “quantum dot R” for convenience) are illustrated in
[0095]
[0096] The following results may be derived from
[0097] If the color conversion layer of the light emitting device emitting red light, the color conversion layer of the light emitting device emitting green light, and the color conversion layer of the light emitting device emitting blue light have the same thickness, the amount and type of the quantum dots included in the color conversion layers need to be adjusted to control the ratio between the amount of red light, the amount of green light, and the amount of blue light. This results in a loss of energy, except for the color extracted using the wavelength selection layer. However, according to the present disclosure, it is possible to increase the energy utilization efficiency simply by changing the thicknesses of the color conversion layers. Further, it is possible to reduce the manufacturing costs by eliminating the necessity to form (apply) different quantum dots for each light emitting device.
[0098]
[0099] The display apparatus of Example 1 includes
[0100] a plurality of light emitting device units each including a first light emitting device 10, a second light emitting device 20, and a third light emitting device 30, in which
[0101] the first light emitting device 10 includes
[0102] a first light generating unit 11 that generates light having a wavelength λ.sub.0,
[0103] a first wavelength conversion layer 12 that includes a first color conversion layer 13 having a thickness T.sub.1 and including a particulate color conversion material, the particulate color conversion material converting the color of the light having the wavelength λ.sub.0 emitted from the first light generating unit 11, and
[0104] a first wavelength selection layer 14 that the light emitted from the first wavelength conversion layer 12 enters and that emits light having a wavelength λ.sub.1′,
[0105] the second light emitting device 20 includes
[0106] a second light generating unit 21 that generates light having a wavelength λ.sub.0,
[0107] a second wavelength conversion layer 22 that includes a second color conversion layer 23 having a thickness T.sub.2 and including a particulate color conversion material, the particulate color conversion material converting the color of the light having the wavelength λ.sub.0 emitted from the second light generating unit 21, and
[0108] a second wavelength selection layer 24 that the light emitted from the second wavelength conversion layer 22 enters and that emits light having a wavelength λ.sub.2′,
[0109] the third light emitting device 30 includes
[0110] a third light generating unit 31 that generates light having a wavelength λ.sub.0,
[0111] a third color conversion layer 32 that includes a third color conversion layer 33 having a thickness T.sub.3 and including a particulate color conversion material, the particulate color conversion material converting the color of the light having the wavelength λ.sub.0 emitted from the third light generating unit 31, and
[0112] a third wavelength selection layer 34 that the light emitted from the third wavelength conversion layer 32 enters and that emits light having a wavelength λ.sub.3′ (where λ.sub.1′<λ.sub.2′<λ.sub.3′ holds), and
[0113] T.sub.1<T.sub.2≤T.sub.3 is satisfied.
[0114] Additionally, the light emitting device of Example 1 includes
[0115] light generating units 11, 21, and 31 that generate light having a wavelength λ.sub.0, and
[0116] wavelength conversion layers 12, 22, and 32 that include color conversion layers 13, 23, or 33 including a particulate color conversion material, the particulate color conversion material converting the color of the light having the wavelength λ.sub.0 emitted from the light generating units 11, 21, and 31, in which
[0117] the color conversion layers 12, 23, and 33 each have a thickness determined on the basis of the wavelength λ″ (where λ″>λ.sub.0 holds) of light emitted from the wavelength conversion layers 12, 22, and 32.
[0118] Furthermore, a light emitting member (also referred to as a wavelength conversion member, a wavelength conversion sheet, or a quantum dot sheet) of Example 1 includes
[0119] a first light emitting portion 10′, a second light emitting portion 20′, and a third light emitting portion 30′, in which
[0120] the first light emitting portion 10′ includes a first wavelength conversion layer 12 including a first color conversion layer 13, the first color conversion layer 13 having a thickness T.sub.1 and including a particulate color conversion material, the particulate color conversion material converting the color of light having a wavelength λ.sub.0 emitted from a light generating unit,
[0121] the second light emitting portion 20′ includes a second wavelength conversion layer 22 including a second color conversion layer 23, the second color conversion layer 23 having a thickness T.sub.2 and including a particulate color conversion material, the particulate color conversion material converting the color of light having a wavelength λ.sub.0 emitted from a light generating unit,
[0122] the third light emitting portion 30′ includes the third wavelength conversion layer 32 including a third color conversion layer 33, the third color conversion layer 33 having a thickness T.sub.3 and including a particulate color conversion material, the particulate color conversion material converting the color of light having a wavelength λ.sub.0 emitted from a light generating unit,
[0123] T.sub.1<T.sub.2≤T.sub.3 is satisfied, and
[0124] the peak wavelength λ.sub.1-peak″ of the light spectrum of the light emitted from the first wavelength conversion layer 12 is different from the peak wavelength λ.sub.2-peak″ of the light spectrum of light emitted from the second wavelength conversion layer 22 and the peak wavelength λ.sub.3-peak″ of the light spectrum of light emitted from the third wavelength conversion layer 32.
[0125] The light emitting member of Example 1 includes the first wavelength selection layer 14 provided on the first wavelength conversion layer 12, the second wavelength selection layer 24 provided on the second wavelength conversion layer 22, and the third wavelength selection layer 34 provided on the third wavelength conversion layer 32. Note that the first wavelength selection layer 14, the second wavelength selection layer 24, and the third wavelength selection layer 34 are not essential components. The light emitted from the first wavelength conversion layer 12 enters the first wavelength selection layer 14, and the first wavelength selection layer 14 emits light having a wavelength λ.sub.1′. The light emitted from the second wavelength conversion layer 22 enters the second wavelength selection layer 24, and the second wavelength selection layer 24 emits light having a wavelength λ.sub.2′. The light emitted from the third wavelength conversion layer 32 enters the third wavelength selection layer 34, and the third wavelength selection layer 34 emits light having a wavelength λ.sub.3′ (where λ.sub.1′<λ.sub.2′<λ.sub.3′ holds). Additionally, the light emitting member is provided on a transparent material member 73 described below. However, in some cases, the transparent material member 73 is unnecessary.
[0126] The light emitting device of Example 1 includes the particulate color conversion material including the first quantum dots and the second quantum dots. Further, the light emitting device of Example 1 includes the wavelength selection layers 14, 24, and 34 that the light emitted from the wavelength conversion layers 12, 22, and 32 enter.
[0127] The total thickness of the thickness of the wavelength conversion layer 12 (the color conversion layer 13) and the thickness of the wavelength selection layer 14 in the light emitting device 10, the total thickness of the thickness of the wavelength conversion layer 22 (the color conversion layer 23) and the thickness of the wavelength selection layer 24 in the light emitting device 20, and the total thickness of the thickness of the wavelength conversion layer 32 (the color conversion layer 33) and the thickness of the wavelength selection layer 34 in the light emitting device 30 are equal to each other. That is,
[0128] {the thickness of the first wavelength conversion layer 12 (the first color conversion layer 13)}+{the thickness of the first wavelength selection layer 14}={the thickness of the second wavelength conversion layer 22 (the second color conversion layer 23)}+{the thickness of the second wavelength selection layer 24}={the thickness of the third wavelength conversion layer 32 (the third color conversion layer 33)}+{the thickness of the third wavelength selection layer 34}
[0129] is satisfied within a range of ±10% thickness variation.
[0130] The particulate color conversion material in the light emitting devices 10, 20, and 30 in the display apparatus of Example 1 and the light emitting member of Example 1 includes the first quantum dots that convert light having a wavelengths λ.sub.0 into light having a wavelengths λ.sub.2″ (specifically, λ.sub.2-peak″) (where λ.sub.2″>λ.sub.0 holds), and the second quantum dots that convert light having a wavelengths λ.sub.0 into light having a wavelengths λ.sub.3″ (specifically, λ.sub.3-peak″) (where λ.sub.3″>λ.sub.2″>λ.sub.0 holds). The second quantum dots further convert light having a wavelength λ.sub.2″ (specifically, λ.sub.2-peak″) into light having a wavelength λ.sub.3″ (specifically, λ.sub.3-peak″). Here, T.sub.1<T.sub.2<T.sub.3 is satisfied. The thicknesses T.sub.1, T.sub.2, and T.sub.3 preferably satisfy, but not limited to,
2≤T.sub.2/T.sub.1,
3≤T.sub.3/T.sub.1, and
1.5≤T.sub.3/T.sub.2, more preferably,
2≤T.sub.2/T.sub.1≤100,
3≤T.sub.3/T.sub.1≤100, and
1.5≤T.sub.3/T.sub.2≤10.
[0131] More specifically,
T.sub.1=1 μm,
T.sub.2=4 μm, and
T.sub.3=12 μm
were satisfied. Further, the total thickness of the thickness of the wavelength conversion layer 12 (the color conversion layer 13) and the thickness of the wavelength selection layer 14, the total thickness of the thickness of the wavelength conversion layer 22 (the color conversion layer 23) and the thickness of the wavelength selection layer 24, and the total thickness of the thickness of the wavelength conversion layer 32 (the color conversion layer 33) and the thickness of the wavelength selection layer 34 were each 14 μm. Further, [0132] the wavelength range (FWHM) of the wavelength λ.sub.0=10 nm to 50 nm, [0133] the wavelength range (FWHM) of the wavelength λ.sub.1′=430 nm to 500 nm, [0134] the wavelength range (FWHM) of the wavelength λ.sub.2=500 nm to 570 nm, [0135] the wavelength range (FWHM) of the wavelength λ.sub.3′=610 nm to 750 nm, [0136] the wavelength range (FWHM) of the wavelength λ.sub.2″=500 nm to 570 nm, [0137] the wavelength range (FWHM) of the wavelength λ.sub.3″=610 nm to 750 nm, [0138] the value of the wavelength λ.sub.1-peak′=460 nm, [0139] the value of the wavelength λ.sub.2-peak′=530 nm, [0140] the value of the wavelength λ.sub.3-peak′=630 nm, [0141] the value of the wavelength λ.sub.1-peak″=460 nm, [0142] the value of the wavelength λ.sub.2-peak″=530 nm, and [0143] the value of the wavelength λ.sub.3-peak″=630 nm [0144] were satisfied.
[0145] Further, the wavelength conversion layers 12, 22, and 32 include light scattering particles. Here, examples of the light scattering particles are SiO.sub.2, Al.sub.2O.sub.3, and TiO.sub.2.
[0146] The first quantum dot (quantum dot G) and the second quantum dot (quantum dot R) include an InP-based semiconductor material. Note that, in the drawings, the first quantum dot is indicated by a solid circle, the second quantum dot is indicated by a circle with hatching lines sloping from the upper right to the lower left, and the light scattering particle is indicated by a hollow circle. The first quantum dots, the second quantum dots, and the light scattering particle are embedded in a filler (matrix) 40 in the first color conversion layer 13, the second color conversion layer 23, and the third color conversion layer 33. To simplify the drawings, the filler 40 is not hatched in the drawings. Further, in Example 1, the first wavelength conversion layer 12 includes the first color conversion layer 13, the second wavelength conversion layer 22 includes the second color conversion layer 23, and the third wavelength conversion layer 32 includes the third color conversion layer 33. The wavelength selection layers 14, 24, and 34 each have a rectangular (square or rectangular) shape in plan view, as illustrated in
[0147] The first light generating unit 11, the second light generating unit 21, and the third light generating unit 31 that generate light having a wavelength λ.sub.0 may have the same configuration or structure. Specifically, the light generating unit 11 of the light emitting device 10, the light generating unit 21 of the light emitting device 20, and the light generating unit 31 of the light emitting device 30 each include a light-emitting diode (LED). The LED desirably has a thickness of, but not limited to, 100 μm or less. The LED includes at least a first compound semiconductor layer 51, an active layer (light emitting layer) 53, and a second compound semiconductor layer 52 from the wavelength conversion layer side. The first compound semiconductor layer 51, the active layer 53, and the second compound semiconductor layer 52 are laminated into the laminated light emitting structure. The laminated light emitting structure includes, for example, a GaN-based compound semiconductor, specifically, a AlGaInN-based compound semiconductor having a known configuration or structure. To the first compound semiconductor layer 51, a first electrode 55 is coupled. Specifically, the first electrode 55 is formed on an exposed surface of the first compound semiconductor layer 51. To the second compound semiconductor layer 52, a first electrode 56 is coupled. Specifically, the second electrode 56 is formed on an exposed surface of the second compound semiconductor layer 52. The first compound semiconductor layer 51, the active layer 53, the second compound semiconductor layer 52, a part of the first electrode 55, and a part of the second electrode 56 are covered with an insulating layer 54 including SiO.sub.2 or SiN. A light reflection film 57 is formed on a part of the region of the insulating layer 54. It is possible to prevent light generated in the active layer 53 from leaking to the outside by forming the light reflection film 57 including silver (Ag), gold (Au), aluminum (Al), or the like. Additionally, light generated in the active layer 53 is reflected from the light reflection film 57 and directed to the color conversion layers 13, 23, and 33. This improves the light extraction efficiency.
[0148] The first wavelength conversion layer 12 of the first light emitting device 10, the second wavelength conversion layer 22 of the second light emitting device 20, and the third wavelength conversion layer 32 of the third light emitting device 30 are separated from each other by a sidewall (partition wall) 60. The light reflection layer 61 is formed on an inner surface of the sidewall 60.
[0149] The first wavelength conversion layer 12 in the first light emitting device 10 emits mainly blue light based on blue light emitted from the first light generating unit 11. The blue light passes through the first wavelength selection layer 14 which passes blue light. As a result, blue light is emitted from the first light emitting device 10. The second wavelength conversion layer 22 in the second light emitting device 20 emits mainly green light and red light based on blue light emitted from the second light generating unit 21. The green light and the red light enter the second wavelength selection layer 24 which passes green light. As a result, green light is emitted from the second light emitting device 20. Further, the third wavelength conversion layer 32 in the third light emitting device 30 emits mainly red light based on blue light emitted from the third light generating unit 31. The red light passes through the third wavelength selection layer 34 that passes red light. As a result, red light is emitted from the third light emitting device 30.
[0150] Hereinafter, an outline of the manufacturing process of the light emitting device of Example 1 is described with reference to
[Step-100]
[0151] In the manufacture of the LEDs of the light generating units 11, 21, and 31, the first compound semiconductor layer 51 (including, for example, a buffer layer, an n-type contact layer, and an n-type cladding layer), the active layer (light emitting layer) 53, and the second compound semiconductor layer 52 (including, for example, a p-cladding layer and a p-contact layer) are laminated on a manufacturing base, which may be a sapphire base, by, for example, a MOCVD method. The manufacturing base is not limited to a sapphire base and may be, for example, an Si base or a GaN base. The laminated light emitting structure is then etched into a desired shape. Thereafter, an ohmic metal, such as Pd, or a transparent conductive material layer, such as ITO, is applied on the second compound semiconductor layer 52 by deposition, and shaped into a desired shape by a lift-off method. The second electrode 56 is thereby formed. Thereafter, the insulating layer 54 is formed on the laminated light emitting structure and the second electrode 56. The insulating layer 54 is then partially etched so that the first compound semiconductor layer 51 is exposed. Thereafter, the first electrode 55 including, for example, Ti/Pt/Au is formed on the exposed first compound semiconductor layer 51. Thereafter, the light reflection film 57 including silver (Ag) or aluminum (Al) is formed on a desired area of the insulating layer 54. The insulating layer 54 is then partially etched so that the second electrode 56 is exposed. Thereafter, the side of the light emitting device on which the second electrode 56 is formed is attached to a support base 80, which may be a sapphire base, for example. Thereafter, the manufacturing base is removed by a laser lift-off (LLO) method so that the first compound semiconductor layer 51 is exposed (see
[Step-110]
[0152] Next, the sidewall 60 is formed in a desired region on the exposed first compound semiconductor layer 51. The sidewall 60 includes a resist material (e.g., a black resist material) that absorbs light. Thereafter, the light reflection layer 61 including Al or Ag is formed over the entire surface by a sputtering method, and the region of the light reflection layer 61 other than the side surface of the sidewall 60 is removed by dry etching. The light reflection layer 61 is thereby formed (see
[Step-120]
[0153] Next, the region surrounded by the first compound semiconductor layer 51 and the light reflection layer 61 and in which the first light emitting device 10, the second light emitting device 20, and the third light emitting device 30 are to be formed is filled with a material obtained by dispersing the first quantum dots (quantum dots G), the second quantum dots (quantum dots R) and the light scattering particles in a filler including an ultraviolet curable resin (hereinafter, referred to as a “quantum dot dispersing material”) using a doctor blade. Thereafter, the quantum dot dispersing material is cured by irradiating with ultraviolet rays (see
[Step-130]
[0154] Thereafter, an ultraviolet curable resin material 81 for nanoimprinting is applied to the entire surface using a doctor blade. The ultraviolet curable resin material 81 is then cured while a template is pressed against the ultraviolet curable resin material 81, and thereafter, the template is removed. The ultraviolet curable resin material 81 is thereby formed into steps having thicknesses corresponding to the respective thicknesses of the color conversion layers 13, 23, and 33 (see
[Step-140]
[0155] Next, the first wavelength selection layer 14, the second wavelength selection layer 24, and the third wavelength selection layer 34 are respectively formed on the first color conversion layer 13 in the first light emitting device 10, the second color conversion layer 23 in the second light emitting device 20, and the third color conversion layer 33 in the third light emitting device 30 by a known method. The total thickness of the thickness of the wavelength conversion layer 12 and the thickness of the wavelength selection layer 14, the total thickness of the thickness of the wavelength conversion layer 22 and the thickness of the wavelength selection layer 24, and the total thickness of the thickness of the wavelength conversion layer 32 and the thickness of the wavelength selection layer 34 are equal between the light emitting devices 10, 20, and 30. After a protective layer (not illustrated) is formed on the wavelength selection layers 14, 24, and 34, or after a protective glass plate (not illustrated) is attached to the wavelength selection layers 14, 24, and 34, the support base 80 is removed. The display apparatus having the structure illustrated in
[0156] The display apparatus, the light emitting device, and the light emitting member of Example 1 satisfy T.sub.1<T.sub.2≤T.sub.3, more specifically, T.sub.1<T.sub.2<T.sub.3. The compositions of the color conversion layers (the types, proportions, and the like of the first quantum dots and the second quantum dots in the color conversion layers) of the first light emitting device, the second light emitting device, and the third light emitting device may be the same. This improves the light utilization efficiency compared with a conventional technique using, for example, YAG phosphors. Moreover, although a conventional method of manufacturing the second light emitting device and the third light emitting device requires separately applying the quantum dots G and the quantum dots R by the ink-jet printing or the like, the separate application of the quantum dots is no longer required to manufacture the second light emitting device and the third light emitting device for the display apparatus, the light emitting device, and the light emitting member of Example 1. This reduces the manufacturing costs and the manufacturing processes. Further, the amount of unnecessary quantum dots to be removed is reduced compared with a conventional technique, enhancing the material utilization efficiency of the costly quantum dots. This also reduces the manufacturing cost. Furthermore, the light generating units are arranged in an individual manner, making it possible to achieve various pixel pitches. Such a structure is suitable for a display apparatus with a large screen. In a display apparatus in which a red light emitting LED, a green light emitting LED, and a blue light emitting LED are arranged, the red light emitting LED and the green light emitting LED has light emission efficiency lower than that of the blue light emitting LED. Thus, in Example 1, the blue light emitting LED having high light emission efficiency serves as an excitation light source, and the quantum dots having high light emission efficiency convert the wavelength. This enhances the light utilization efficiency.
Example 2
[0157] Example 2 is a modification of Example 1.
[0158] Note that the configuration or structure of the light emitting member of Example 2 or Examples 3 to 10 described below may be substantially the same as the configuration or structure of the light emitting device of the display apparatus of Example 1 or Examples 3 to 10 described below, except for having no light generating unit.
[0159] In Example 2, each of the wavelength conversion layers 12, 22, and 32 in the respective light emitting devices 10, 20, and 30 further includes a spacer layer 70 including an acrylic ultraviolet curable resin, an epoxy-based ultraviolet curable resin, a silicone-based thermosetting resin, or an epoxy-based thermosetting resin.
[0160] The total thickness of the thickness of the spacer layer 70 and the thicknesses of the color conversion layer 13 in the light emitting device 10, the total thickness of the thickness of the spacer layer 70 and the thickness of the color conversion layer 23 in the light emitting device 20, and the total thickness of the thickness of the spacer layer 70 and the thickness of the color conversion layer 33 in the light emitting device 30 are equal to each other. The spacer layer 70 may be positioned on a light emitting side of the color conversion layer 13, 23, or 33 (see
[0161] Except for the above points, the configuration or structure of the display apparatus and the light emitting device of Example 2 may be the same as the configuration or structure of the display apparatus and the light emitting device of Example 1, and thus detailed descriptions thereof are omitted.
[0162] In the manufacture of the display apparatus of Example 2 illustrated in
[0163] In Example 1, a portion of the quantum dot dispersion material accumulated to the height of the sidewall 60 in [Step-120] is removed by dry etching in [Step-130]. Thus, the removed quantum dot dispersion material results in material loss. In contrast, in Example 2, using the spacer layer 70 reduces the amount of the quantum dot dispersion material to be charged. As a result, the material utilization efficiency is increased. Further, the color conversion layers 13, 23, and 33 may be positioned farther from the light generating units 11, 21, and 31 in Example 2 than in Example 1. This mitigate the influence of heat generation in the light generating units 11, 21, and 31 on the color conversion layers 13, 23, and 33. Furthermore, the color conversion layers 13, 23, and 33 serving as underlayers of the wavelength selection layers 14, 24, and 34 may be made into the same height. This improves the applicability of the wavelength selection layers 14, 24, and 34 compared with Example 1.
Example 3
[0164] Example 3 is a modification of Examples 1 and 2.
[0165] Note that, unlike in Example 1, the light scattering particles are not included in the color conversion layers 13, 23, and 33 in the modifications of Example 1 illustrated in
[0166] Except for the above points, the configuration or structure of the display apparatus and the light emitting device of Example 3 may be the same as the configurations or structures of the display apparatuses and the light emitting devices of Examples 1 and 2, and thus detailed descriptions thereof are omitted.
Example 4
[0167] Example 4 is a modification of Examples 1 to 3.
[0168] Except for the above points, the configuration or structure of the display apparatus and the light emitting device of Example 4 may be the same as the configurations or structures of the display apparatuses and the light emitting devices of Examples 1 to 3, and thus detailed descriptions thereof are omitted.
Example 5
[0169] Example 5 is a modification of Examples 1 to 4.
[0170] Specifically, the wavelength conversion layers 12, 22, and 32 and the wavelength selection layers 14, 24, and 34 are formed on the first surface 73A of the transparent material member 73 attached to a first support base through the same steps as [Step-110] to [Step-130] of Example 1. Thereafter, the wavelength selection layers 14, 24, and 34 are attached to a second support base, and the first support base is then removed. Thereafter, the exposed second surface 73B of the transparent material member 73 is attached to the light generating units 11, 21, and 31 with the adhesive layer 73′ interposed therebetween. As described above, the light generating units 11, 21, and 31, the wavelength conversion layers 12, 22, and 32, and the wavelength selection layers 14, 24, and 34 (i.e., the light emitting members) are separately manufactured before being attached. This improves the production yield.
[0171] Alternatively, as in the schematic partial end view of Modification Example-1 of Example 5 illustrated in
[0172] Alternatively, as in the schematic partial end view of Modification Example-2 of Example 5 illustrate in a
[0173] Specifically, the wavelength selection layers 14, 24, and 34 are formed on a support base. Thereafter, the transparent material member 74 is attached to the light generating units 11, 21, and 31 and the wavelength conversion layers 12, 22, and 32 (specifically, to the top surface of the sidewall 60) with an adhesive layer 74′ interposed therebetween. Alternatively, a support portion is provided on the wavelength selection layer side, and the transparent material member 74 is attached to the support portion. The support base may be removed or left as a protective member. As described above, the light generating units 11, 21, and 31, the wavelength conversion layers 12, 22, and 32, and the wavelength selection layers 14, 24, and 34 (the light emitting members) are separately manufactured before being attached. This improves the production yield. The wavelength conversion layers 12, 22, and 32 may be attached to the wavelength selection layers 14, 24, and 34 (specifically, the transparent material member 74) such that the space (gap) 75 is formed therebetween. Providing the space (gap) 75 allows a portion of the light emitted from the wavelength conversion layers 12, 22, and 32 to be totally reflected on the surfaces of the wavelength conversion layers 12, 22, and 32 exposed to the space. This reduces the light emitted from the wavelength selection layers 14, 24, and 34 and totally reflected on the protective member (e.g., a protective glass plate) provided on the wavelength selection layers 14, 24, and 34, enhancing the light extraction efficiency.
[0174] Except for the above points, the configuration or structure of the display apparatus and the light emitting device of Example 5 may be the same as the configurations or structures of the display apparatuses and the light emitting devices of Examples 1 to 4, and thus detailed descriptions thereof are omitted.
Example 6
[0175] Example 6 is a modification of Examples 1 to 5.
[0176] Except for the above points, the configuration or structure of the display apparatus and the light emitting device of Example 6 may be the same as the configurations or the structures of the display apparatuses and the light emitting devices of Examples 1 to 5, and thus detailed descriptions thereof are omitted.
Example 7
[0177] Example 7 is a modification of Examples 1 to 6.
[0178] Except for the above points, the configuration or structure of the display apparatus and the light emitting device of Example 7 may be the same as the configurations or structures of the display apparatuses and the light emitting devices of Examples 1 to 6, and thus detailed descriptions are omitted.
Example 8
[0179] Example 8 is a modification of Examples 1 to 7. In the display apparatuses of Examples 1 to 7, the first compound semiconductor layer 51 in the light generating unit 11, 21, or 31 is coupled to the adjacent light generating unit. Thus, light generated in the light generating units 11, 21, and 31 and light emitted from the color conversion layers 13, 23, and 33 propagate to the adjacent light emitting device through the first compound semiconductor layer 51. This can reduce the light extraction efficiency and cause optical crosstalk. To address this, as in the schematic partial end view illustrated in
[0180] Except for the above points, the configuration or structure of the display apparatus and the light emitting device of Example 8 may be the same as the configurations or structures of the display apparatuses and the light emitting devices of Examples 1 to 7, and thus detailed descriptions thereof are omitted.
Example 9
[0181] Example 9 is a modification of Examples 1 to 8.
[0182] Except for the above points, the configuration or structure of the display apparatus and the light emitting device of Example 9 may be the same as the configurations or structures of the display apparatuses and the light emitting devices of Examples 1 to 8, and thus detailed descriptions thereof are omitted.
Example 10
[0183] Example 10 is a modification of Examples 1 to 9.
1≤(T.sub.2=T.sub.3)/T.sub.1, more preferably,
1≤(T.sub.2=T.sub.3)/T.sub.1≤100.
Specifically,
[0184]
T.sub.1=1 μm, and
T.sub.2=T.sub.3=8 μm
are satisfied.
[0185] As illustrated in
[0186] Except for the above points, the configuration or structure of the display apparatus and the light emitting device of Example 10 may be the same as the configurations or structures of the display apparatuses and the light emitting devices of Examples 1 to 9, and thus detailed descriptions thereof are omitted.
[0187] While the present disclosure has been described above with reference to the preferred examples, the present disclosure is not limited to these examples. The configurations or structures of the light generating units 11, 21, and 31, the configurations or structures of the wavelength conversion layers 12, 22, and 32, the configurations or structures of the wavelength selection layers 14, 24, and 34, the configuration or structure of the light shutter means 95, and the connection between the light generating units 11, 21, and 31 and the drive circuitry described in the examples are mere examples and may be changed as appropriate. Although the wavelength selection layers 14, 24, and 34 each have a rectangular (square or rectangular) shape in plan view, as illustrated in
[0188] It is to be noted that the present disclosure may also have the following configurations.
<<Display Apparatus>>
[0189] A display apparatus including
[0190] a plurality of light emitting device units each including a first light emitting device,
[0191] a second light emitting device, and a third light emitting device, in which
[0192] the first light emitting device includes
[0193] a first light generating unit that generates light having a wavelength λ.sub.0,
[0194] a first wavelength conversion layer that includes a first color conversion layer having a thickness T.sub.1 and including a particulate color conversion material, the particulate color conversion material converting the color of the light having the wavelength λ.sub.0 emitted from the first light generating unit, and
[0195] a first wavelength selection layer that the light emitted from the first wavelength conversion layer enters and that emits light having a wavelength λ.sub.1′,
[0196] the second light emitting device includes
[0197] a second light generating unit that generates light having a wavelength λ.sub.0,
[0198] a second wavelength conversion layer that includes a second color conversion layer having a thickness T.sub.2 and including a particulate color conversion material, the particulate color conversion material converting the color of the light having the wavelength λ.sub.0 emitted from the second light generating unit, and
[0199] a second wavelength selection layer that the light emitted from the second wavelength conversion layer enters and that emits light having a wavelength λ.sub.2′,
[0200] the third light emitting device includes
[0201] a third light generating unit that generates light having a wavelength λ.sub.0,
[0202] a third color conversion layer that includes a third color conversion layer having a thickness T.sub.3 and including a particulate color conversion material, the particulate color conversion material converting the color of the light having the wavelength λ.sub.0 emitted from the third light generating unit, and
[0203] a third wavelength selection layer that the light emitted from the third wavelength conversion layer enters and that emits light having a wavelength λ.sub.3′ (where λ1′<λ2′<λ3′ holds), and
[0204] T.sub.1<T.sub.2≤T.sub.3 is satisfied. [0205] [A02] The display apparatus according to [A01], in which the particulate color conversion material in each of the light emitting devices includes a first quantum dot that converts light having a wavelength λ.sub.0 into light having a wavelength λ.sub.2″ (where λ.sub.2″>λ.sub.0 holds) and a second quantum dot that converts light having a wavelength λ.sub.0 into light having a wavelength λ.sub.3″ (where λ.sub.3″>λ.sub.2″>λ.sub.0 holds). [0206] [A03] The display apparatus according to [A02], in which the second quantum dot further converts light having a wavelength λ.sub.2″ into light having a wavelength λ.sub.3″. [0207] [A04] The display apparatus according to [A02] or [A03], satisfying T.sub.1<T.sub.2=T.sub.3. [0208] [A05] The display apparatus according to [A02] or [A03], satisfying T.sub.1<T.sub.2<T.sub.3. [0209] [A06] The display apparatus according to any one of [A01] to [A05], in which the wavelength conversion layer in each of the light emitting devices further includes a spacer layer, and
[0210] the total thickness of the thickness of the spacer layer and the thickness of the color conversion layer is equal between the light emitting devices. [0211] [A07] The display apparatus according to [A06], in which the spacer layer is positioned on a light incident side of the color conversion layer. [0212] [A08] The display apparatus according to [A06], in which the spacer layer is positioned on a light emitting side of the color conversion layer. [0213] [A09] The display apparatus according to any one of [A01] to [A08], in which the wavelength conversion layer in each of the light emitting devices includes light scattering particles. [0214] [A10] The display apparatus according to any one of [A01] to [A09], in which the wavelength selection layer in each of the light emitting devices includes light scattering particles. [0215] [A11] The display apparatus according to any one of [A01] to [A10], in which the wavelength conversion layer in each of the light emitting devices further increases a light-scattering particle layer. [0216] [A12] The display device according to [A11], in which the total thickness of the thickness of the light-scattering particle layer and the thickness of the color conversion layers is equal between the light emitting devices. [0217] [A13] The display apparatus according to any one of [A01] to [A12], in which an on-chip micro-lens is provided on a light emitting side of the wavelength selection layer in each of the light emitting devices. [0218] [A14] The display apparatus according to any one of [A01] to [A13], in which the light generating unit in each of the light emitting devices is coupled to drive circuitry provided on a base. [0219] [A15] The display apparatus according to any one of [A01] to [A14], in which a transparent material member is provided between the light generating unit and the wavelength conversion layer in each of the light emitting devices. [0220] [A16] The display apparatus according to any one of [A01] to [A14], in which a transparent material member is provided between the wavelength conversion layer and the wavelength selection layer in each of the light emitting devices. [0221] [A17] The display apparatus according to [A15] or [A16], in which a space (gap) is provided more adjacent to the light generating unit than the transparent material member is. [0222] [A18] The display apparatus according to [A17], in which a space (gap) is provided between the wavelength conversion layer and the wavelength selection layer. [0223] [A19] The display apparatus according to [A17], in which a space (gap) is provided between the light generating unit and the wavelength conversion layer. [0224] [A20] The display apparatus according to [A15], in which the first wavelength conversion layer, the second wavelength conversion layer, and the third wavelength conversion layer are formed on the transparent material member. [0225] [A21] The display apparatus according to any one of [A01] to [A20], in which the light generating unit in each of the light emitting devices is a light emitting diode. [0226] [A22] The display apparatus according to any one of [A01] to [A20], in which the light generating unit in each of the light emitting devices is an organic electroluminescent device. [0227] [A23] The display apparatus according to any one of [A01] to [A22], in which a light shutter means is provided between the wavelength conversion layer and the wavelength selection layer in each of the light emitting devices. [0228] [A24] The display apparatus according to [A23], in which the light shutter means is a liquid crystal display of a transmission type. [0229] [A25] The light emitting device according to any one of [A01] to [A24], in which the light emitting devices are separated from each other by a sidewall (partition wall). [0230] [A26] The display apparatus according to [A25], in which the wavelength conversion layer is surrounded by the sidewall (partition wall) in each of the light emitting devices. [0231] [A27] The display apparatus according to [A25], in which the light generating unit and the wavelength conversion layer are surrounded by the sidewall (partition wall) in each of the light emitting devices. [0232] [A28] The display apparatus according to any one of [A25] to [A27], in which a light reflection layer is formed on an inner surface of the sidewall. [0233] [A29] The display apparatus according to any one of [A01] to [A28], in which the total thickness of the thickness of the wavelength conversion layer and the thickness of the wavelength selection layer is equal between the light emitting devices. [0234] [A30] The display apparatus according to any one of [A01] to [A29], in which an optical crosstalk suppression unit is provided in a region between the light emitting devices. [0235] [A31] The display apparatus according to any one of [A01] to [A30], in which the color conversion layer includes a particulate color conversion material embedded in a filler. [0236] [B01] <<Light Emitting Device>>
[0237] A light emitting device including:
[0238] a light generating unit that generates light having a wavelength λ.sub.0; and
[0239] a wavelength conversion layer that includes a color conversion layer including a particulate color conversion material, the particulate color conversion material converting the color of the light having the wavelength λ.sub.0 emitted from the light generating unit, in which
[0240] the color conversion layer has a thickness determined on a basis of the wavelength λ″ (where λ″>λ.sub.0 holds) of light emitted from the wavelength conversion layer. [0241] [B02] The light emitting device according to [B01], in which the particulate color conversion material includes quantum dots. [0242] [B03] The light emitting device according to [B01] or [B02], further including a wavelength selection layer that the light emitted from the wavelength conversion layer enters. [0243] [C01] <<Light Emitting Member>>
[0244] A light emitting member including
[0245] a first light emitting portion, a second light emitting portion, and a third light emitting portion, in which
[0246] the first light emitting portion includes a first wavelength conversion layer including a first color conversion layer, the first color conversion layer having a thickness T.sub.1 and including a particulate color conversion material, the particulate color conversion material converting a color of light having a wavelength λ.sub.0 emitted from a light generating unit,
[0247] the second light emitting portion includes a second wavelength conversion layer including a second color conversion layer, the second color conversion layer having a thickness T.sub.2 and including a particulate color conversion material, the particulate color conversion material converting a color of light having a wavelength λ.sub.0 emitted from a light generating unit,
[0248] the third light emitting portion includes a third wavelength conversion layer including a third color conversion layer, the third color conversion layer having a thickness T.sub.3 and including a particulate color conversion material, the particulate color conversion material converting a color of light having a wavelength λ.sub.0 emitted from a light generating unit,
[0249] T.sub.1<T.sub.2≤T.sub.3 is satisfied, and
[0250] the peak wavelength of a light spectrum of light emitted from the first wavelength conversion layer is different from the peak wavelength of a light spectrum of light emitted from the second wavelength conversion layer and the peak wavelength of a light spectrum of light emitted from the third wavelength conversion layer. [0251] [C02] The light emitting member according to [C01], in which the particulate color conversion material in each of the light emitting portions includes a first quantum dot that converts light having a wavelength λ.sub.0 into light having a wavelength λ.sub.2″ (where λ.sub.2″>λ.sub.0 holds) and a second quantum dot that converts light having a wavelength λ.sub.0 into light having a wavelength λ.sub.3″ (where λ.sub.3″>λ.sub.2″>λ.sub.0 holds). [0252] [C03] The light emitting member according to [C02], in which the second quantum dot further converts light having a wavelength μ.sub.2″ into light having a wavelength λ.sub.3″.
[0253] [C04] The light emitting member according to [C02] or [C03], satisfying T.sub.1<T.sub.2=T.sub.3. [0254] [C05] The light emitting member according to [C02] or [C03], satisfying T.sub.1<T.sub.2<T.sub.3. [0255] [C06] The light emitting member according to any one of [C01] to [C05], in which
[0256] the wavelength conversion layer in each of the light emitting portions further includes a spacer layer, and
[0257] the total thickness of the thickness of the spacer layer and the thickness of the color conversion layer is equal between the light emitting portions.
[0258] [C07] The light emitting member according to [C06], in which the spacer layer is positioned on a light incident side of the color conversion layer.
[0259] [C08] The light emitting member according to [C06], in which the spacer layer is positioned on a light emitting side of the color conversion layer.
[0260] [C09] The light emitting member according to any one of [C01] to [C08], in which the wavelength conversion layer in each of the light emitting portions includes light scattering particles.
[0261] [C10] The light emitting member according to any one of [C01] to [C09], in which the wavelength conversion layer in each of the light emitting portions further includes a light-scattering particle layer.
[0262] [C11] The light emitting member according to [C10], in which the total thickness of the thickness of the light-scattering particle layer and the thickness of the color conversion layers is equal between the light emitting portions.
[0263] [C12] The light emitting member according to any one of [C01] to [C11], in which a wavelength selection layer is provided more adjacent to a light emitting side than the wavelength conversion layer is in each of the light emitting portions.
[0264] [C13] The light emitting member according to [C12], in which the wavelength selection layer in each of the light emitting portions includes light scattering particles.
[0265] [C14] The light emitting member according to [C12] or [C13], in which a transparent material member is provided between the wavelength conversion layer and the wavelength selection layer in each of the light emitting portions.
[0266] [C15] The light emitting member according to [C14], in which a space (gap) is provided more adjacent to the light generating unit than the transparent material member is.
[0267] [C16] The light emitting member according to any one of [C01] to [C13], in which the wavelength conversion layer is provided on the transparent material member in each of the light emitting portions.
[0268] [C17] The light emitting member according to any one of [C01] to [C16], in which a light shutter means is provided between the wavelength conversion layer and the wavelength selection layer in each of the light emitting portions.
[0269] [C18] The light emitting member according to [C17], in which the light shutter means is a liquid crystal display of a transmission type.
[0270] [C19] The light-emitting portion according to any one of [C01] to [C18], in which the light emitting portions are separated from each other by a sidewall (partition wall).
[0271] [C20] The light emitting member according to [C19], in which the wavelength conversion layer is surrounded by the sidewall (partition wall) in each of the light emitting portions.
[0272] [C21] The light emitting member according to [C19] or [C20], in which a light reflection layer is formed on an inner surface of the sidewall.
[0273] [C22] The light emitting member according to any one of [C01] to [C21], in which the total thickness of the thickness of the wavelength conversion layer and the thickness of the wavelength selection layer is equal between the light emitting portions.
[0274] [C23] The light emitting member according to any one of [C01] to [C22], in which an optical crosstalk suppressing unit is provided in a region between the light emitting portions.
[0275] [C24] The light emitting member according to any one of [C01] to [C23], in which the color conversion layer includes a particulate color conversion material embedded in a filler.
REFERENCE SIGNS LIST
[0276] 10 . . . first light emitting device, 11, 11′ . . . first light generating unit (light generating unit), 12 . . . first wavelength conversion layer (wavelength conversion layer), 13 . . . first color conversion layer (color conversion layer), 14 . . . first wavelength selection layer (wavelength selection layer), 20 . . . second light emitting device, 21, 21′ . . . second light generating unit (light generating unit), 22 . . . second wavelength conversion layer (wavelength conversion layer), 23 . . . second color conversion layer (color conversion layer), 24 . . . second wavelength selection layer (wavelength selection layer), 30 . . . third light emitting device, 31, 31′ . . . third light generating unit (light generating unit), 32 . . . third wavelength conversion layer (wavelength conversion layer), 33 . . . third color conversion layer (color conversion layer), 34 . . . third wavelength selection layer (wavelength selection layer), 40 . . . filler (matrix), 51 . . . first compound semiconductor layer, 52 . . . second compound semiconductor layer, 53 . . . active layer (light emitting layer), 54 . . . insulating layer, 55 . . . first electrode, 56 . . . second electrode, 57 . . . light reflection film, 58 . . . cutout, 60 . . . sidewall (partition wall), 61 . . . light reflection layer, 70 . . . spacer layer, 70′ . . . spacer forming layer, 70″ . . . template, 71 . . . light-scattering particle layer, 72 . . . on-chip micro-lens, 72′ . . . planarizing layer, 73, 74 . . . transparent material member, 73A . . . first surface of the transparent material member, 73B . . . second surface of transparent material member, 73′, 74′ . . . adhesive layer, 75 . . . space (gap), 80 . . . support base, 81 . . . ultraviolet curable resin material, 90 . . . base, 91, 92 . . . bump, 93, 94 . . . coupling portion, 95 . . . light shutter means, 96 . . . insulating film