Pneumatic tire production method

Abstract

In a pneumatic tire production method including a step of overlapping end portions of a sheet laminate and vulcanization-molding the tire, the sheet laminate being obtained by layering an elastomer layer and a sheet of a thermoplastic resin composition containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer, after the end portions of the sheet laminate are overlapped, the overlapped portion of the sheet laminate is compression-bonded at a temperature of not less than a glass transition temperature Tg of the thermoplastic resin and not greater than 120° C.

Claims

1. A pneumatic tire production method including a step of overlapping end portions of a sheet laminate and vulcanization-molding the tire, the sheet laminate consisting of two layers obtained by layering a tie rubber layer and a sheet of a thermoplastic resin composition containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer, wherein the sheet of the thermoplastic resin composition containing the thermoplastic resin or the blend of the thermoplastic resin and the elastomer contains at least nylon, the pneumatic tire production method comprising the step of: after the end portions of the sheet laminate are overlapped by contacting the sheet of the thermoplastic resin composition and the tie rubber layer with each other, compression-bonding the end portions of the sheet laminate at a temperature of not less than a glass transition temperature Tg of the thermoplastic resin and less than 80° C., at a duration of not less than 1 second and not greater than 30 seconds, and at a pressure of not less than 0.2 MPa and not greater than 1 MPa by pressing a fiber-reinforced rubber bladder onto the overlapped portion from a direction perpendicular to a plane of the overlapped portion.

2. The pneumatic tire production method according to claim 1, wherein the tire has a pair of bead portions, a bead filler is arranged on an outer peripheral side of each bead portion, and the step of compression bonding is performed at least at a position between bead filler tops positioned on an outermost side in a tire radial direction of the bead fillers.

3. The pneumatic tire production method according to claim 1, wherein the step of compression bonding is performed with the overlapped portion disposed on a heating plate.

4. The pneumatic tire production method according to claim 1, wherein the step of compression bonding is performed after overlapping the end portions of the sheet laminate obtained by layering the tie rubber layer and the sheet of the thermoplastic resin composition containing the thermoplastic resin or the blend of the thermoplastic resin and the elastomer, and before adhering a carcass layer.

5. The pneumatic tire production method according to claim 2, wherein the step of compression bonding is performed with the overlapped portion disposed on a heating plate.

6. The pneumatic tire production method according to claim 5, wherein the step of compression bonding is performed after overlapping the sheet laminate obtained by layering the tie rubber layer and the sheet of the thermoplastic resin composition containing the thermoplastic resin or the blend of the thermoplastic resin and the elastomer, and before adhering a carcass layer.

7. The pneumatic tire production method according to claim 1, comprising compression-bonding the end portions of the sheet laminate at a duration of not less than 7 seconds and not greater than 30 seconds.

8. The pneumatic tire production method according to claim 1, comprising compression-bonding the end portions of the sheet laminate at a duration of not less than 22 seconds and not greater than 30 seconds.

9. The pneumatic tire production method according to claim 1, wherein a thickness of the tie rubber layer is greater than a thickness of the sheet of the thermoplastic resin composition.

10. The pneumatic tire production method according to claim 9, wherein the thickness of the tie rubber layer is multiple times greater than the thickness of the sheet of the thermoplastic resin composition.

11. The pneumatic tire production method according to claim 9, wherein the tie rubber layer is present only on one side of the laminate and the sheet of the thermoplastic resin composition is exposed at a tire cavity side of the laminate.

12. The pneumatic tire production method according to claim 1, wherein compression-bonding the end portions of the sheet laminate by pressing the fiber-reinforced rubber bladder onto the overlapped portion comprises pressing the overlapped portion between the bladder and a heater such that heat and pressure are applied locally only to a splice portion where the end portions of the sheet laminate overlap.

Description

BRIEF DESCRIPTION OF DRAWINGS

(1) FIG. 1 is a side view schematically illustrating an embodiment of the pneumatic tire production method of the present technology.

(2) FIG. 2 is a side view schematically illustrating another embodiment of the pneumatic tire production method of the present technology.

(3) FIG. 3 is a side view schematically illustrating a state (before vulcanization molding) in which, a sheet laminate including an elastomer layer 3 and a thermoplastic resin composition sheet 2 containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer has lap splice portions S provided at the two ends thereof, and the lap splice portions S are overlapped so as to form the sheet laminate into an annular shape on a tire molding drum (not illustrated).

(4) FIG. 4 is a partially fragmented perspective view illustrating an example of a typical configuration of a pneumatic tire obtained by the production method of the present technology. FIG. 4 is a drawing for explaining the positional relationship within the tire of the lap splice portion when a sheet laminate containing a thermoplastic resin composition sheet and an elastomer layer is used in formation of an innerliner layer.

DETAILED DESCRIPTION

(5) A more detailed explanation of the pneumatic tire production method of the present technology will be given below.

(6) The pneumatic tire production method of the present technology is a method for producing a pneumatic tire including a step of overlapping end portions of a sheet laminate and vulcanization-molding the tire, the sheet laminate being obtained by layering an elastomer layer and a sheet of a thermoplastic resin composition containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer. The pneumatic tire production method is characterized in that the overlapped portion of the sheet laminate is compression-bonded at a temperature of not less than a glass transition temperature Tg of the thermoplastic resin and not greater than 120° C. after the end portions of the sheet laminate are overlapped.

(7) According to the method of the present technology, molecular movement in the thermoplastic resin is activated by compression bonding of the overlapped portion at a temperature not less than the glass transition temperature Tg of the thermoplastic resin. Therefore, during compression bonding, the elastomer of the elastomer layer and the resin tend to become closer and compression bonding force increases dramatically, and opening of the splice portion can be remarkably prevented even when it undergoes inflation in the vulcanization molding step. Note that the above temperature during compression bonding is the temperature of the “sheet of a thermoplastic resin composition containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer” when the sheet is compression-bonded. For example, when the thermoplastic resin is a nylon resin, the glass transition temperature is approximately 50° C.

(8) The compression bonding temperature higher than 120° C. is undesirable because the elastomer ends up scorching.

(9) Compression bonding may be performed on a tire molding apparatus but may also be performed by another apparatus. In that case, the methods that may be employed include a method in which the sheet laminate is continuously heated and compression-bonded by being passed between a pair of rotating heating rollers having an appropriate clearance, and a method in which the sheet laminate is heated and compression-bonded in a batch mode using a pair of heating plates having an appropriate clearance. When a pair of rollers or a pair of plates is used for heating, one of the rollers or of the plates may be unheated.

(10) FIG. 1 illustrates an example in which the splice portion of a sheet laminate 1 is placed between a heater 5 and a heating plate 7, and heat and pressure are directly applied to the splice portion between the two.

(11) FIG. 2 illustrates an example performed on a tire molding apparatus, in which a sheet laminate 1 and a carcass layer 6 are bonded, and then the splice portion of the sheet laminate 1 is placed between a heater 5 and a bladder 8, and heat and pressure are applied to the splice portion via the carcass layer between the two.

(12) When performed on a tire molding apparatus, it is preferably performed by pressing a fiber-reinforced rubber bladder, a resin die, or a metal die onto the overlapped portion of the sheet laminate 1 from a direction perpendicular to the plane of the overlapped portion.

(13) In the present technology, the used sheet laminate 1 obtained by layering an elastomer layer 3 and a sheet 2 of a thermoplastic resin composition containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer may be a layered structure of the two layers, but it may also be a layered structure of three layers in which the elastomer layers 3 are layered on the front and rear faces of the sheet 2 of a thermoplastic resin composition containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer.

(14) Furthermore, the thermoplastic resin is not limited to the case where one type is used, and a blend of two or more types may be used. In that case, the “glass transition temperature Tg of the thermoplastic resin” in the present technology is taken on the basis of the glass transition temperature Tg of a thermoplastic resin having the lowest glass transition temperature. Preferably, when a plurality of types of thermoplastic resin are used, the present technology should be implemented at a temperature not less than the glass transition temperatures Tg of all of the used thermoplastic resins and not greater than 120° C.

(15) Compression bonding should be performed at a pressure in the range of not less than 0.1 MPa and not greater than 1 MPa, and in particular, when performed by pressing a fiber-reinforced rubber bladder, a resin die, or a metal die, compression bonding is preferably performed within that range of pressure. When the pressure during compression bonding is a low value less than 0.1 MPa or the like, it is undesirable because the compression bonding effect is sometimes insufficient. When performed at a high pressure such as pressure greater than 1 MPa, it is undesirable because the sheet laminate member or other member sometimes ends up being crushed.

(16) The duration of compression bonding varies depending on the applied pressurizing force and cannot be categorically determined, but generally, it is preferably not less than 1 second and not greater than 30 seconds in order to sufficiently obtain the advantageous effect of the present technology. The duration of less than 1 second is undesirable because it is difficult to sufficiently obtain a compression bonding effect. The duration of longer than 30 seconds is undesirable because productivity decreases.

(17) Furthermore, it is preferred that compression bonding be performed at least at a position between a left and right bead filler top. In particular, this is because the splice readily opens because the position between the left and right bead filler top undergoes large lift during tire molding and there is generally no reinforced portion, and thus a great advantageous effect is obtained when that position is heated and compression-bonded.

(18) From the perspective of ease of temperature control, compression bonding is preferably performed by directly disposing the overlapped portion of the sheet laminate on a heating object such as a heating plate. Conversely, the tire itself may be compression-bonded by ambient heating, but this is generally not preferred because temperature control is difficult.

(19) In the present technology, compression bonding is preferably performed after overlapping the sheet laminate 1 and before adhering the carcass layer. This is because if heating and compression bonding is performed after the carcass is adhered to the sheet laminate, if heated all the way to the carcass when lift occurs during tire molding, the rubber between the carcass cords softens and opening readily occurs, which are undesirable.

(20) It is preferred that the sheet of a thermoplastic resin composition containing a thermoplastic resin or a blend of a thermoplastic resin and an elastomer contain at least a nylon resin. This is because a nylon resin has excellent durability and heat resistance, and is suitable for use in tires.

(21) FIG. 4 is a partially fragmented perspective view illustrating an example of an embodiment of the pneumatic tire according to the present technology.

(22) A pneumatic tire T is provided with a side wall portion 12 and a bead portion 13 that are continuously connected on the left and right of a tread portion 11. On the tire inner side of the pneumatic tire T, a carcass layer 14 that acts as a framework of the tire is provided so as to extend between the left and right bead portions 13, 13 in the tire width direction. Two belt layers 15 composed of steel cords are provided on the outer circumferential side of the carcass layer 14 corresponding to the tread portion 11. The arrow E indicates the tire width direction, and the arrow X indicates the tire circumferential direction. An innerliner layer 10 is disposed on an inner side of the carcass layer 14, and a splice portion S thereof is present extending in the tire width direction. A bead filler is denoted as 16, and the aforementioned bead filler top is the outermost position in the tire radial direction of this member 16.

EXAMPLES

(23) The present technology will be described in detail below with reference to working examples and the like.

Working Examples 1 to 7 and Comparative Examples 1 to 2

(24) As test tires, five test tires were produced for each of Working Examples 1 to 7 and Comparative Examples 1 and 2. The test tires had a tire size of 195/65R15 91H (15×6J) and had a tire structure with two belt layers and one carcass layer.

(25) In each of the test tires, the composition listed in Table 1 was used as the thermoplastic resin composition sheet 2 (thickness of 130 μm) that forms the inner liner and the composition listed in Table 2 was used as the elastomer layer 3 (thickness of 0.7 mm) that is the tie rubber. The test tire underwent vulcanization molding, and was evaluated by judging whether or not the splice portion could be molded without delaminating in the vulcanization molding step. The lap length (tire circumferential length of overlapped splice portion) was 10 mm in all the test tires. The thermoplastic resin was N6/N66, having a glass transition temperature Tg of approximately 50° C.

(26) TABLE-US-00001 TABLE 1 Parts by mass BIMS.sup.a) “Exxpro 3035” made by 100 ExxonMobil Chemical Co. Zinc oxide “Zinc Oxide III” made by Seido Chemical 0.5 Industry Co., Ltd. Stearic acid Industrial stearic acid 0.2 Zinc “Zinc stearate” made by NOF Corporation 1 stearate N6/66 “UBE Nylon 5033B” made by 100 Ube Industries, Ltd. Modified “HPR-AR201” made by Dupont-Mitsui 10 EEA.sup.b) Polychemicals Co., Ltd. Remarks: .sup.a)Brominated isobutylene-p-methylstyrene copolymer .sup.b)Maleic anhydride-modified ethylene-ethylacrylate copolymer

(27) TABLE-US-00002 TABLE 2 Parts by mass Styrene butadiene made by Zeon Corporation 50 rubber “Nipol 1502” Natural rubber SIR-20 50 Carbon black made by Tokai Carbon Co., Ltd 60 “Seast V” Stearic acid Industrial stearic acid 1 Aroma oil made by Showa Shell Sekiyu KK 7 “Desolex No. 3” Zinc oxide made by Seido Chemical 3 Industry Co., Ltd. “Zinc Oxide III” Modified resorcin made by Taoka Chemical Co., Ltd. 2 formaldehyde “Sumikanol 620” condensate Methylene donor Modified etherified methylolmelamine 6 made by Taoka Chemical Co., Ltd. “Sumikanol 507 AP” Sulfur 5% oil-extension treated sulfur 6 Vulcanization Di-2-benzothiazolyl disulfide 2.2 accelerator made by Ouchi Shinko Chemical Industrial Co., Ltd. “NOCCELER DM”

(28) The test tires were manufactured while varying the compression bonding method or the pressure, temperature, or duration thereof as shown in Table 3, and each test tire was evaluated visually on the basis of the evaluation criteria below.

(29) The evaluation results are as shown in Table 3. As the compression bonding method, for those listed as “Stitcher,” the splice portion was compression-bonded at a speed of 60 cm/minute at 0.7 MPa by rolling a metal stitcher having a cylindrical shape of 14 cm in diameter and 5 cm in height. For those listed as “Press,” a heating plate and a fiber-reinforced air-filled bladder inflated to an air pressure of 0.4 MPa were used, wherein the heating plate was disposed on the inner liner side and the air-filled bladder was disposed on the carcass side. For those in which a stitcher was used, pressure was applied by mechanical control using a hydraulic pump. Those marked as “Entire width” for the compression bonding range were compression-bonded for the entire width in the width direction of the thermoplastic resin composition sheet 2.

(30) TABLE-US-00003 TABLE 3-1 Comparative Comparative Working Working Example 1 Example 2 Example 1 Example 2 Compression Stitcher Press Stitcher Press bonding method Compression 25 25 50 50 bonding temperature (° C.) Compression 0.7 0.7 0.7 0.2 bonding pressure (MPa) Compression 1 round-trip 30 1 round-trip 3 bonding (60 sec) (60 sec) duration (seconds) Compression Entire Entire Ėntire Entire bonding width width width width range Evaluation Poor Poor Good Good of splice opening

(31) TABLE-US-00004 TABLE 3-2 Working Working Working Working Working Example 3 Example 4 Example 5 Example 6 Example 7 Compression Press Press Press Press Press bonding method Compression 50 120 120 120 120 bonding temperature (° C.) Compression 0.2 0.2 0.7 0.2 0.7 bonding pressure (MPa) Compression 30 3 30 3 30 bonding duration (seconds) Compression Entire Entire Entire Between Between bonding width width width filler tops filler tops range Evaluation Excellent Excellent Excellent Good Good of splice opening
(1) Evaluation of Opening Resistance of Splice Portion:

(32) For five test tires produced for each of Working Examples 1 to 7 and Comparative Examples 1 and 2, a three-level evaluation was performed according to the following evaluation criteria.

(33) (a) Excellent . . . No delamination was seen at the splice portion in any of the five tires

(34) (b) Good . . . Delamination measuring not greater than 1 mm×1 mm was seen in at least one of the tires (delamination was not seen in others)

(35) (c) Poor . . . Delamination measuring greater than 1 mm×1 mm was seen in at least one of the tires (delamination was not seen in others)