Back-gated quantum well heterostructure
11367786 · 2022-06-21
Assignee
Inventors
Cpc classification
H01L29/775
ELECTRICITY
H01L29/66439
ELECTRICITY
B82Y10/00
PERFORMING OPERATIONS; TRANSPORTING
H01L29/423
ELECTRICITY
H01L29/66977
ELECTRICITY
International classification
H01L29/775
ELECTRICITY
H01L29/12
ELECTRICITY
Abstract
A semiconductor device. In some embodiments, the semiconductor device includes a back gate layer; a buffer layer, on the back gate layer; a device quantum well layer, on the buffer layer; a cap layer, on the device quantum well layer; a top layer, on the cap layer; a first doped region of a first conductivity type, extending at least part-way through the device quantum well layer; a second doped region, of a second conductivity type, within the buffer layer; and a third doped region, of the second conductivity type extending from the top layer to the second doped region. The top layer may include a dielectric layer, and, in the dielectric layer, a plurality of conductive elements, including one or more dot gates, an ohmic contact, a bath gate, a supply gate, and a halo contact.
Claims
1. A semiconductor device, comprising: a back gate layer; a buffer layer, on the back gate layer; a device quantum well layer, on the buffer layer; a cap layer, on the device quantum well layer; a top layer, on the cap layer; a first doped region of a first conductivity type, extending at least part-way through the device quantum well layer; a second doped region, of a second conductivity type, within the buffer layer; and a third doped region, of the second conductivity type extending from the top layer to the second doped region, the top layer comprising: a dielectric layer, and, in the dielectric layer, a plurality of conductive elements, including: one or more dot gates; an ohmic contact; a bath gate, between the one or more dot gates and the ohmic contact; a supply gate between the bath gate and the ohmic contact; and a halo contact, the third doped region extending from the halo contact to the second doped region, the second doped region extending under the ohmic contact and under the supply gate.
2. The semiconductor device of claim 1, wherein the cap layer is undoped under the supply gate, under the bath gate, and under the one or more dot gates.
3. The semiconductor device of claim 1, wherein the buffer layer is undoped under the bath gate and under the one or more dot gates.
4. The semiconductor device of claim 1, wherein the second doped region has a dopant concentration sufficiently great to avoid freeze-out of carriers at temperatures less than 5 K.
5. The semiconductor device of claim 1, wherein the second doped region has a peak dopant concentration of at least 10.sup.18/cm.sup.3.
6. The semiconductor device of claim 1, wherein the second doped region has a vertical full width half maximum of at least 30 nm.
7. The semiconductor device of claim 1, wherein the first doped region has a peak dopant concentration of at least 10.sup.19/cm.sup.3.
8. The semiconductor device of claim 1, wherein the third doped region has a peak dopant concentration of at least 10.sup.19/cm.sup.3.
9. The semiconductor device of claim 1, wherein the first conductivity type is n-type and the second conductivity type is p-type.
10. The semiconductor device of claim 1, further comprising a back gate quantum well, on the back gate layer.
11. The semiconductor device of claim 1, further comprising a fourth doped region of the first conductivity type within the buffer layer, the fourth doped region being under the second doped region and having at least the same lateral extent as the second doped region.
12. The semiconductor device of claim 11 wherein the first doped region extends to the fourth doped region.
13. The semiconductor device of claim 11 wherein the fourth doped region has a dopant concentration sufficiently great to avoid freeze-out of carriers at temperatures less than 5 K.
14. The semiconductor device of claim 11, wherein the cap layer is undoped under the supply gate, under the bath gate, and under the one or more dot gates.
15. The semiconductor device of claim 11, wherein the buffer layer is undoped under the bath gate and under the one or more dot gates.
16. The semiconductor device of claim 11, wherein the second doped region has a dopant concentration sufficiently great to avoid freeze-out of carriers at temperatures less than 5 K.
17. The semiconductor device of claim 11, wherein the second doped region has a peak dopant concentration of at least 10.sup.18/cm.sup.3.
18. The semiconductor device of claim 11, wherein the second doped region has a vertical full width half maximum of at least 30 nm.
19. The semiconductor device of claim 11, wherein the first doped region has a peak dopant concentration of at least 10.sup.19/cm.sup.3.
20. The semiconductor device of claim 11, wherein the third doped region has a peak dopant concentration of at least 10.sup.19/cm.sup.3.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) These and other features and advantages of the present disclosure will be appreciated and understood with reference to the specification, claims, and appended drawings wherein:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
DETAILED DESCRIPTION
(11) The detailed description set forth below in connection with the appended drawings is intended as a description of exemplary embodiments of a back-gated quantum well heterostructure provided in accordance with the present disclosure and is not intended to represent the only forms in which the present disclosure may be constructed or utilized. The description sets forth the features of the present disclosure in connection with the illustrated embodiments. It is to be understood, however, that the same or equivalent functions and structures may be accomplished by different embodiments that are also intended to be encompassed within the scope of the disclosure. As denoted elsewhere herein, like element numbers are intended to indicate like elements or features.
(12)
(13) Some SiGe heterostructure designs, such as that shown in
(14) In part for this reason, an objective of some embodiments is to block the back gate to ohmic leakage path and decouple the vertical field in the supply gate region from that in the active area of the device (encompassing the gated bath and electrostatic quantum dot areas of the device) by introducing a forward biased p-n junction underneath the ohmic and supply gate areas of the device. The p-n junction screens the ohmic and supply gate areas from the back gate bias and allows independent control of the supply gate vertical field. In some embodiments an additional buried n-well region can also be deployed to block hole leakage paths. This may substantially increase the dynamic range of achievable vertical electric field in the active region of SiGe heterostructure designs. The presence of the back gate also provides a well-defined ground plane and allows for dynamic tuning of the device threshold voltage, which can be useful for controlling the operating voltage range of the device.
(15)
(16) Some embodiments are directed to a design for heterostructures to enable independent control over vertical electric fields in different lateral regions of the quantum well. Such embodiments allow a high vertical electric field to be induced in the active region of the device without inducing undesirable leakage pathways elsewhere in the heterostructure. In some embodiments, a Si.sub.0.7Ge.sub.0.3-sSi conduction electron quantum well structure is used; the general features of designs disclosed herein are applicable to other quantum well designs utilizing different heterostacks or carrier types. Independent control of the vertical electric field in these devices is desirable because it allows additional control of the vertical confining potential and hence the quantum dot wave function, which can alter the valley splitting, magnetic dephasing rate, and other relevant properties. In some embodiments, desirable vertical fields in SiGe—Si quantum wells are of the order of 1 mV/nm to 10 mV/nm. Typical SiGe cap thicknesses are of the order of 60 nm. The vertical field in the quantum dot region can be modified by the voltages applied to the dot gates; however, due to the geometry of these gates the field modulation is relatively weak and spatially nonuniform in the plane of the quantum dot. Furthermore, many other properties of the quantum dot are sensitive to the precise voltage configuration of the dot gates, so that independent control of the vertical fields is difficult to achieve.
(17) One alternative is to construct a back gate which can be biased to exert a uniform vertical electric field. This can be done in many ways; for instance, a heavily doped substrate and/or buffer region can be used, which can be contacted and biased. However, such designs induce a uniform electric field throughout the whole heterostructure, including under the baths and supply gate regions. In particular, a strong vertical field can induce MOS accumulation in the supply gate and hence throughout the device. Therefore, a method is needed to allow a back gate to induce sufficient vertical field without leading to MOS accumulation.
(18) As mentioned above, an example of a heterostructure design for quantum dots is illustrated in
(19) Furthermore, if the substrate is biased as a back gate, current can leak between the ohmic and substrate due to the applied voltage between them. This can be blocked using a potential barrier between the ohmic and the substrate. Referring to
(20) One embodiment solves this difficulty by utilizing a biased p-n junction to screen the supply gate region from the back gate 125. This allows independent control via the junction bias of the vertical field under the supply gate and hence allows accumulation in the QW 105 and depletion at the MOS interface, while the back gate bias produces a separate electric field elsewhere in the device. A schematic of such an embodiment is shown in
(21) The band bending induced by the halo doping under the supply gate region determines the vertical field and hence the conduction band diagram of the cap. In particular, the halo can be forward biased such that the MOS supply gate interface potential is near flat band, preventing MOS accumulation. Although forward-biasing a p-n junction might be expected to induce current flow between the ohmic and halo contacts, this may be exponentially suppressed and may be negligible at the cryogenic temperatures of operation for the device, when the turn-on bias for current is essentially equal to or greater than the built-in voltage of the p-n junction.
(22) In operating protocols where a positive vertical field is desired (i.e., pushing electrons in the quantum well 105 against the top interface), a negative bias is expected on the back gate 125 relative to the ohmic ground. Under these conditions, conduction electron leakage occurs by electrons flowing from the back gate 125 towards the quantum well or ohmic regions. This leakage is controlled by the field and electron barrier in the vicinity of the back gate 125 and hence can be blocked by an appropriate barrier design, for example using an SOI substrate or a buried quantum well 130 for the back gate 125. In the embodiment depicted in
(23) Therefore, in some embodiments, a design that systematically blocks this hole leakage path may be employed, as depicted in
(24) By maintaining a bias-tunable p-halo region underneath the supply gate, this embodiment preserves the independent field and density control therein. Meanwhile, the presence of the buried n-well region 170 forms a p-n barrier between the halo and the buried buffer, eliminating the possibility of hole leakage into the substrate. This is indicated in
(25)
(26) The expected maximum achievable vertical fields under the bath and active regions of the device may be directly estimated from considerations of 1-D electrostatics. For example, the estimation may proceed as follows, for the case of lightly or undoped buffers such that the depletion region and band bending associated with the doping can be neglected. Empirically, in quantum well heterostructures of the kind disclosed herein, it is known that tunneling from the well to the cap layer starts to occur past some critical field F.sub.tunn. In Si.sub.0.7Ge.sub.0.3—Si devices this field appears to be around 10 mV/nm. The maximal achievable field from the back gate is approximately
(27)
where q is the charge of the electron, n.sub.bath is the electron density in the region of the quantum well 105 underneath the bath gate 160, E is the dielectric constant of the buffer layer 135 and the cap layer 140, and the bath electron density n.sub.bath is controlled by gating (i.e., the electron density n.sub.bath in the region of the quantum well 105 underneath the bath gate 160 can be controlled by applying a suitable voltage (known as gating) to the bath gate 160). The buffer layer 135 and the cap layer 140 may consist of the same material, and, in a non-limiting embodiment, may be a SiGe alloy; for example, Si.sub.0.7Ge.sub.0.3. The dielectric constant of the quantum well 145 may be assumed to be roughly equal to that of the cap layer 140 and the buffer layer 135 (it may consist of a similar material; for example, Si). The device quantum well 105 may be much thinner than the cap and buffer, and, as a result, it may not affect the effective dielectric constant much. For typical bath densities of order 3×10.sup.11 cm.sup.−2 to 4×10.sup.11 cm.sup.−2, this sets a limit for the maximum vertical field induced by the bath gate to be approximately 6 mV/nm.
(28) This estimate assumes that supply gate accumulation is not an issue due to the biased halo design. If such a design is not used, the limit on maximum back gate field is imposed by lack of MOS accumulation under the supply gate, which can be approximated as the condition that the potential drop over the cap layer 140 is smaller than the conduction band offset of the quantum well Δ.sub.CB. As an example, for Δ.sub.CB=0.2 eV and a cap thickness t.sub.cap of 60 nm, this requires
(29)
where n.sub.supply is the electron density in the region of the quantum well 105 underneath the supply gate 120, which can be controlled by applying a suitable voltage (known as gating) to the supply gate 120. For typical supply gate densities of 10.sup.11 cm.sup.−2, this would set an upper bound on the achievable vertical field of 2 mV/nm, or 3× lower than the bound determined by the bath. By decoupling the vertical field in the supply region from that of the bath, the halo design circumvents this limitation. These calculations are in agreement with numerical 1-D simulations accounting for the quantization of electrons in the quantum well, as illustrated in
(30) In the embodiments depicted in
(31)
(32) The field under the active region, which is the relevant device quantity, depends on the top gates as well, but the contribution of the back gate can be approximated as
(33)
(34) where the denominator is the total distance between the back and top gates. The maximum achievable active field is therefore given by
(35)
(36) where t.sub.ox is the thickness of the layer 157 of dielectric material (which is part of the top layer 145) under the dot gates 155. Using these simple rules, estimates may be obtained for possible design parameters. In some heterostructure designs, the distance from the top gates to the bottom of the active quantum well t.sub.QW+t.sub.cap+t.sub.ox is about 70 nm. In order to prevent overlap of the p-type dopants with the quantum well, the halo implant may be placed 100 nm underneath the active quantum well (e.g., the peak doping concentration of the halo implant 160, in the vertical direction, may be located 100 nm underneath the quantum well 105), with a peak p-type doping concentration of about 10.sup.19 cm.sup.−3 so as to be above the MIT but not completely compensating the doping in the ohmic region. A halo layer thickness t.sub.halo of about 30 nm should ensure that it will not be fully depleted, as the depletion width of such a layer is about 13 nm. The buried n-well can be implemented as another 30 nm layer of 10.sup.19 n-type doping, so that the total extent of the halo and buried n-well below the active well is about 160 nm. For a buried back gate located t.sub.BG=500 nm underneath the active well, t.sub.leak=340 nm and F.sub.active,max reaches 6 mV/nm, close to the expected maximum due to bath gate limitations. These estimates assume simple abrupt doping profiles and may be quantitatively modified in the presence of the nonuniform straggle and diffusion of actual implanted and annealed doping profiles.
(37) The presence of a back gate allows for a well-defined ground plane underneath the active region. In addition to modifying the vertical field, changing the bias of this gate also shifts the threshold voltage of the entire device. This can be practically advantageous for altering the range of operating voltages within which device operation takes place. In the case of an undoped buffer, the threshold voltage shift (relative to the top gates) in a 1-D model can be simply approximated as
(38)
(39) In the case where reducing the threshold voltage is desired, this implies that the back gate should be forward biased, in contrast to the cases discussed previously. This tends to reduce the vertical field but changes the direction of possible leakage flow, such that electrons tend to flow towards the substrate. Therefore a single halo may be sufficient to block leakage flow from the ohmics and supply region, such as in the embodiment shown in
(40)
This suggests that the back gate depth affects the leakage onset and the achievable threshold voltage shift in the same way, e.g., ΔV.sub.th,max≤F.sub.tunnt.sub.cap, since the cap thickness may be fixed by other considerations. As an example, for a nominal cap thickness of 60 nm and F.sub.max=10 mV/nm, this sets a probable bound on ΔV.sub.th,max≤−0.6 V. The primary limitation on the back gate distance t.sub.BG may then be set by either other processing constraints, such as the need to keep the dopants used for substrate doping sufficiently far from the QW, or applied voltage constraints on the back gate bias, since
(41)
and therefore scales with t.sub.BG.
(42) As used herein, any structure or layer that is described as being “made of” or “composed of” a substance should be understood (i) in some embodiments, to contain that substance as the primary component or (ii) in some embodiments, to contain that substance as the major component. As used herein, a “conductivity type” of a semiconductor material may be n-type, or p-type (depending, for example, on doping).
(43) As used herein, “a portion of” something means at least some of the thing, and as such may mean less than all of, or all of, the thing. As such, “a portion of” a thing includes the entire thing as a special case, i.e., the entire thing is an example of a portion of the thing.
(44) As used herein, when a second number is “within Y %” of a first number, it means that the second number is at least (1−Y/100) times the first number and the second number is at most (1+Y/100) times the first number. As used herein, the word “or” is inclusive, so that, for example, “A or B” means any one of (i) A, (ii) B, and (iii) A and B.
(45) It will be understood that, although the terms “first”, “second”, “third”, etc., may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section. Thus, a first element, component, region, layer or section discussed herein could be termed a second element, component, region, layer or section, without departing from the spirit and scope of the inventive concept.
(46) Spatially relative terms, such as “beneath”, “below”, “lower”, “under”, “above”, “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. It will be understood that such spatially relative terms are intended to encompass different orientations of the device in use or in operation, in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as “below” or “beneath” or “under” other elements or features would then be oriented “above” the other elements or features. Thus, the example terms “below” and “under” can encompass both an orientation of above and below. The device may be otherwise oriented (e.g., rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein should be interpreted accordingly. In addition, it will also be understood that when a layer is referred to as being “between” two layers, it can be the only layer between the two layers, or one or more intervening layers may also be present.
(47) The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the inventive concept. As used herein, the terms “substantially,” “about,” and similar terms are used as terms of approximation and not as terms of degree, and are intended to account for the inherent deviations in measured or calculated values that would be recognized by those of ordinary skill in the art. As used herein, the term “major component” refers to a component that is present in a composition, polymer, or product in an amount greater than an amount of any other single component in the composition or product. In contrast, the term “primary component” refers to a component that makes up at least 50% by weight or more of the composition, polymer, or product. As used herein, the term “major portion”, when applied to a plurality of items, means at least half of the items.
(48) As used herein, the singular forms “a” and “an” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising”, when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items. Expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list. Further, the use of “may” when describing embodiments of the inventive concept refers to “one or more embodiments of the present disclosure”. Also, the term “exemplary” is intended to refer to an example or illustration. As used herein, the terms “use,” “using,” and “used” may be considered synonymous with the terms “utilize,” “utilizing,” and “utilized,” respectively.
(49) It will be understood that when an element or layer is referred to as being “on”, “connected to”, “coupled to”, or “adjacent to” another element or layer, it may be directly on, connected to, coupled to, or adjacent to the other element or layer, or one or more intervening elements or layers may be present. In contrast, when an element or layer is referred to as being “directly on”, “directly connected to”, “directly coupled to”, or “immediately adjacent to” another element or layer, there are no intervening elements or layers present.
(50) Any numerical range recited herein is intended to include all sub-ranges of the same numerical precision subsumed within the recited range. For example, a range of “1.0 to 10.0” or “between 1.0 and 10.0” is intended to include all subranges between (and including) the recited minimum value of 1.0 and the recited maximum value of 10.0, that is, having a minimum value equal to or greater than 1.0 and a maximum value equal to or less than 10.0, such as, for example, 2.4 to 7.6. Any maximum numerical limitation recited herein is intended to include all lower numerical limitations subsumed therein and any minimum numerical limitation recited in this specification is intended to include all higher numerical limitations subsumed therein.
(51) Although exemplary embodiments of a back-gated quantum well heterostructure have been specifically described and illustrated herein, many modifications and variations will be apparent to those skilled in the art. Accordingly, it is to be understood that a back-gated quantum well heterostructure constructed according to principles of this disclosure may be embodied other than as specifically described herein. The invention is also defined in the following claims, and equivalents thereof.