HYBRID GROWTH METHOD FOR III-NITRIDE TUNNEL JUNCTION DEVICES
20220181513 · 2022-06-09
Assignee
Inventors
- Erin C. Young (Mountain View, CA, US)
- Benjamin P. Yonkee (Goleta, CA, US)
- John T. Leonard (San Jose, CA, US)
- Tal Margalith (Santa Barbara, CA, US)
- James S. Speck (Santa Barbara, CA, US)
- Steven P. DenBaars (Goleta, CA, US)
- Shuji Nakamura (Santa Barbara, CA, US)
Cpc classification
H01S5/0262
ELECTRICITY
H01S5/34333
ELECTRICITY
H01L33/04
ELECTRICITY
Y02E10/544
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C30B25/20
CHEMISTRY; METALLURGY
H01L21/0262
ELECTRICITY
H01L33/14
ELECTRICITY
H01L21/00
ELECTRICITY
H01L21/02631
ELECTRICITY
H01S5/183
ELECTRICITY
H01L31/147
ELECTRICITY
H01L33/06
ELECTRICITY
C30B29/68
CHEMISTRY; METALLURGY
International classification
H01L33/00
ELECTRICITY
C30B25/20
CHEMISTRY; METALLURGY
C30B29/40
CHEMISTRY; METALLURGY
C30B29/68
CHEMISTRY; METALLURGY
H01L21/00
ELECTRICITY
H01L21/02
ELECTRICITY
H01L31/0304
ELECTRICITY
H01L31/147
ELECTRICITY
H01L33/04
ELECTRICITY
H01L33/06
ELECTRICITY
H01L33/14
ELECTRICITY
H01S5/30
ELECTRICITY
Abstract
A hybrid growth method for III-nitride tunnel junction devices uses metal-organic chemical vapor deposition (MOCVD) to grow one or more light-emitting or light-absorbing structures and ammonia-assisted or plasma-assisted molecular beam epitaxy (MBE) to grow one or more tunnel junctions. Unlike p-type gallium nitride (p-GaN) grown by MOCVD, p-GaN grown by MBE is conductive as grown, which allows for its use in a tunnel junction. Moreover, the doping limits of MBE materials are higher than MOCVD materials. The tunnel junctions can be used to incorporate multiple active regions into a single device. In addition, n-type GaN (n-GaN) can be used as a current spreading layer on both sides of the device, eliminating the need for a transparent conductive oxide (TCO) layer or a silver (Au) mirror.
Claims
1. A method for fabricating a III-nitride based semiconductor device, comprising: performing a first growth of a p-n junction with III-nitride based p-type material using metal-organic chemical vapor deposition (MOCVD); and performing a subsequent regrowth of III-nitride based n-type material using a different growth technique than MOCVD.
2. A III-nitride based semiconductor device, comprising: one or more light-emitting or light-absorbing structures grown by metal-organic chemical vapor deposition (MOCVD), wherein the light-emitting or light-absorbing structures include one or more p-type III-nitride layers; and one or more tunnel junctions grown by ammonia-assisted or plasma-assisted molecular beam epitaxy (MBE) on the light-emitting or light-absorbing structures, wherein the tunnel junctions include one or more n-type III-nitride layers that are grown on the p-type III-nitride layers of the light-emitting or light-absorbing structures, and a regrowth interface between the p-type III-nitride layers and the n-type III-nitride layers serves as a p-n interface in the tunnel junction.
3. A III-nitride based semiconductor device, comprising: a first growth of a III-nitride based p-n junction structure comprised of III-nitride based p-type material and III-nitride based n-type material, wherein the III-nitride based p-type material is grown using metal-organic chemical vapor deposition (MOCVD); and a subsequent regrowth of the III-nitride based p-n junction structure, wherein the III-nitride based n-type material is regrown on the III-nitride based p-type material using a different growth technique than MOCVD, and a tunnel junction is formed at an interface between the III-nitride based p-type material and the III-nitride based n-type material.
4. The device of claim 3, where the subsequent regrowth is performed under conditions that prevent passivation of the III-nitride based p-type material.
5. The device of claim 3, wherein the subsequent regrowth of the III-nitride based p-type material is highly doped to reduce contact resistance.
6. The device of claim 3, wherein the subsequent regrowth ends with the III-nitride based n-type material, allowing for buried activated III-nitride based p-type layers to be grown.
7. The device of claim 3, wherein delta-doping is used at the regrowth interface.
8. The device of claim 3, further comprising a regrown active region grown on or above the subsequent regrowth using MOCVD.
9. The device of claim 8, wherein the first growth is a light-emitting diode (LED) and the regrown active region is a second LED of similar emission wavelength, such that efficiency droop is reduced through use of multiple active regions.
10. The device of claim 8, wherein layers grown by performing another growth are of similar wavelengths and are aligned to peaks of a cavity mode in a vertical-cavity surface-emitting laser (VCSEL), such that each active region has large enhancement factors.
11. The device of claim 8, wherein the first growth is a III-nitride optoelectronic device, and the regrown active region is a longer wavelength single or multiple quantum well structure that is optically pumped by emission of shorter wavelength from the first growth.
12. The device of claim 11, wherein the longer wavelength single or multiple quantum well structure is a photodiode used to monitor the emission of shorter wavelength from the first growth or regrown active region.
13. The device of claim 8, wherein the regrown active region is a III-nitride optoelectronic device, and the first growth is a longer wavelength single or multiple quantum well structure that is optically pumped by emission of shorter wavelength from the regrown active region.
14. The device of claim 13, wherein the longer wavelength single or multiple quantum well structure is a photodiode used to monitor the emission of shorter wavelength from the first growth or regrown active region.
15. The device of claim 8, wherein the first growth is a light-emitting diode (LED), and the regrown active region is an LED of a different emission wavelength.
16. The device of claim 3, wherein the device is a III-nitride optoelectronic device and a top n-type layer of the tunnel junction serves as a current spreading layer.
17. The device of claim 3, wherein the device is a III-nitride optoelectronic device, and the tunnel junction is used to screen or enhance polarization fields in active regions.
18. The device of claim 3, wherein the device is a III-nitride optoelectronic device, and the tunnel junction allows for use of a thin p-type material to reduce electrical and optical losses in the III-nitride based p-type material.
19. The device of claim 3, wherein the device is a light-emitting diode (LED), and sheet resistance on both sides of the III-nitride based p-n junction structure is matched to reduce current crowding.
20. The device of claim 3, wherein the device is a light-emitting diode (LED), and top and bottom III-nitride layers of the LED are roughened to increase an extraction efficiency of the LED.
21. The device of claim 3, wherein the device is a vertical cavity surface-emitting laser (VCSEL) processed in a flip-chip geometry with one or more high reflectivity optical coatings to enhance light extraction or confine an optical mode in the VCSEL.
22. The device of claim 3, wherein the device is a multi junction solar cell or photodiode.
23. The device of claim 3, wherein a single metal contact deposition is used to fabricate contacts to III-nitride based n-type layers of the device.
24. The device of claim 3, wherein the subsequent regrowth is performed using ammonia-assisted or plasma-assisted molecular beam epitaxy (MBE).
25. The device of claim 3, wherein a top III-nitride layer of the tunnel junction eliminates the need for a p-contact grid.
26. The device of claim 3, wherein each buried III-nitride layer is contacted, such that current flowing through each active region is controlled individually.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0018] Referring now to the drawings in which like reference numbers represent corresponding parts throughout:
[0019]
[0020]
[0021]
[0022]
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031]
[0032]
[0033]
[0034]
[0035]
[0036]
[0037]
DETAILED DESCRIPTION OF THE INVENTION
[0038] In the following description of the preferred embodiment, reference is made to a specific embodiment in which the invention may be practiced. It is to be understood that other embodiments may be utilized and structural changes may be made without departing from the scope of the present invention.
Overview
[0039] As noted above, the present invention comprises a hybrid growth method for III-nitride tunnel junction devices that uses MOCVD to grow one or more light-emitting or light-absorbing structures and MBE is used to grow one or more tunnel junctions.
[0040] Epitaxial Structures
[0041] To demonstrate the tunnel junction design according to the present invention, 410 nm emitting LEDs were grown by MOCVD on 20-21 bulk GaN substrates with a 15 nm p.sup.+-GaN cap as the final layer. The epitaxial structure 100 is shown in
[0042] Thereafter, a mesa etch was performed (not shown) on the samples to expose the bottom n-GaN layer 108, as well as isolate the top n-GaN layer 118 from the rest of the substrate 106. A 30/500 nm Ti/Au n-contact layer (not shown) was then deposited using electron beam evaporation on the top and bottom n-GaN layers 118 and 108. The use of two n-contacts can reduce the processing complexity of LEDs by utilizing a single n-contact deposition. The top n-contact was patterned into a probing pad and a thin strip which utilized the top n-GaN layer 118 for current spreading.
[0043] An image of a sample device with an etched mesa and Ti/Au n-contacts deposited on the top and bottom of the mesa is shown in
[0044] A standard LED without a tunnel junction, used as a reference LED, was processed in a similar geometry, but without the tunnel junction, and the same mesa etch was performed on the reference LED. A ⅔ nm Pd/Au p-contact layer was put down on top of the mesa. The same Ti/Au metal stack and pattern was used. The Ti/Au on the top of the mesa served as a probing pad and assisted the current spreading in the p-contact. An image of the standard LED without the tunnel junction and with a thin Pd/Au current spreading layer is shown in
[0045]
[0046] Tunnel junctions grown by MOCVD are difficult to achieve, because the as-grown Mg-doped layers are insulating due to hydrogen passivation, and are typically activated by a post growth anneal. If a tunnel junction is grown by MOCVD, the p-GaN cannot be activated, because hydrogen will not diffuse through the top n-GaN layer. By using ammonia MBE to grow the n-GaN layer on top, the p-GaN remains activated while being buried beneath the n-GaN. This could allow for the regrowth of a second LED by MOCVD on top of the first LED, because the hydrogen cannot diffuse through the top n-GaN layer.
[0047] To demonstrate this, the epitaxial structure 100 shown in
[0048] A three contact device was fabricated to allow for contact to both MOCVD n-GaN layers 108, 204 as well as the top p-GaN layer 210. The process started with the deposition of a ⅔ nm Pd/Au layer (not shown), which serves as the p-contact and current spreading layer. A first mesa etch (not shown) was then carried out, which stopped at the top MOCVD n-GaN layer 204. A second mesa etch (not shown) was then done outside the first mesa, which exposed the bottom MOCVD n-GaN layer 108. A 30/500 nm Ti/Au contact (not shown) was deposited, which served three purposes: a large area pad formed a contact to the bottom MOCVD n-GaN layer 108, while a smaller contact was deposited in between where the first and second mesas were etched to allow for contact to the middle MBE n-GaN layer 116 or 118. A probing pad and current spreading strip (not shown) was also deposited on the thin Pd/Au p-contact.
[0049] Using this geometry, each device can be contacted individually or in series. The top LED can be operated by probing the top p-contact and the middle n-GaN contact, and the bottom LED can be operated by probing the two n-contacts. Both LEDs can be injected by probing the p-contact and the bottom n-GaN contact.
[0050]
[0051]
[0052]
[0053] To compare the current-voltage (IV) characteristics of the double LED, two reference LEDs with a p-contact were made with the 410 nm active region and the 480 nm active region, respectively.
[0054] In addition to the tunnel junction LEDs described above, the present invention can also be applied to VCSELs, which have a long history of prior art dating back to the 1970's. [5,6] III-nitride VCSELs represent a new class of VCSELs that represent a new set of unique challenges and device designs compared to conventional III-arsenide VCSELs. [7,8] The present invention provides a regrowth technique for achieving high quality III-nitride tunnel junction intracavity contacts in III-nitride VCSELs.
[0055] In [9,10,11,12,13], various structures for light-emitters employing a tunnel junction are described; however, the details of tunnel junction growth for III-nitride materials are not disclosed. Moreover, no reported III-nitride VCSELs, prior to this invention, have achieved lasing with a tunnel junction. Consequently, the method of regrowing a tunnel junction on MOCVD grown III-nitride epitaxial layers according to this invention provides a number of possible improvements for III-nitride VCSELs.
[0056] To demonstrate the improvements possible for nitride VCSELs, an MBE n.sup.++-GaN tunnel junction was regrown on an MOCVD VCSEL. This structure was processed and compared to a structure with identical MOCVD epitaxy and aperture geometry, but with an ITO intracavity contact.
[0057]
[0058]
[0059]
[0060] In this design, the VCSEL 400 includes a substrate 410, followed by n-type layers(s) 412, light-emitting layer(s) 414, and p-type layer(s) 416 grown by MOCVD 402, which are followed by n-type tunnel junction layer(s) 418 grown by MBE 406, which are followed by n-type layers(s) 420, light-emitting layer(s) 422, and p-type layer(s) 424 grown by MOCVD 404, which are followed by n-type tunnel junction layer(s) 426 grown by MBE 408. The final MOCVD 404 and MBE 408 steps may be repeated as a unit 0 to X times.
[0061] The order of the epitaxial layers shown in the design of
[0062]
[0063]
[0064] In
[0065] In
[0066]
[0067]
[0068] The order of the epitaxial layers shown in these designs makes these structures appropriate for fabricating VCSELs employing epitaxially grown DBRs on the p-side and n-side (dual epitaxial DBRs) or an epitaxial DBR on the n-side and a dielectric DBR on the p-side (hybrid DBRs). Only the layers that comprise the epitaxial growth process are shown (i.e. no dielectric or metal layers are shown). All of the designs show that one could make a cascade of active regions by increasing the identified repeat unit:
[0069]
[0070] In
[0071] The order of the epitaxial layers shown in
[0072] Fabrication Process
[0073]
[0074] Block 800 represents the step of performing a first growth of a p-n junction with III-nitride based p-type material using MOCVD.
[0075] Block 802 represents the step of performing a subsequent regrowth of III-nitride based n-type material using a different growth technique than MOCVD.
[0076] For example, the subsequent regrowth may be performed using ammonia-assisted or plasma-assisted MBE. Specifically, the subsequent regrowth is performed under conditions that prevent passivation of the III-nitride based p-type material.
[0077] In Block 802, the subsequent regrowth forms a tunnel junction. In this regard, one or more of the following alternatives are possible: [0078] The III-nitride based p-type material and the tunnel junction are grown by the different growth technique than MOCVD. [0079] The subsequent regrowth is of highly doped p-type material to reduce contact resistance, and the subsequent regrowth ends with the III-nitride based n-type material, allowing for buried activated p-type layers to be grown. [0080] The tunnel junction is formed at a regrowth interface, wherein delta-doping is used at the regrowth interface. [0081] The method further comprises performing another growth, after the subsequent regrowth, of a regrown active region using MOCVD, with or without another set of n-type and/or p-type layers. [0082] The first growth is an LED and the regrown active region is a second
[0083] LED of the same or similar emission wavelength, such that efficiency droop is reduced through use of multiple active regions. [0084] Layers grown by performing another growth are of the same or similar wavelengths and are aligned to peaks of a cavity mode in a VCSEL, such that each active region has large enhancement factors. [0085] The first growth is a III-nitride optoelectronic device, and the regrown active region is a longer wavelength single or multiple quantum well structure that is optically pumped by emission of shorter wavelength from the first growth, wherein the longer wavelength single or multiple quantum well structure is a photodiode used to monitor the emission of shorter wavelength from the first growth or regrown active region. [0086] The regrown active region is a III-nitride optoelectronic device, and the first growth is a longer wavelength single or multiple quantum well structure that is optically pumped by emission of shorter wavelength from the regrown active region, wherein the longer wavelength single or multiple quantum well structure is a photodiode used to monitor the emission of shorter wavelength from the first growth or regrown active region. [0087] The first growth is an LED, and the regrown active region is an LED of a different emission wavelength. [0088] The device is a III-nitride optoelectronic device and a top n-type layer of the tunnel junction serves as a current spreading layer. [0089] The device is a III-nitride optoelectronic device, and multiple embedded tunnel junctions therein are used to screen or enhance polarization fields in active regions. [0090] The device is a III-nitride optoelectronic device, and the tunnel junction allows for use of a thin p-type material to reduce electrical and optical losses in the III-nitride based p-type material. [0091] The device is an LED, and sheet resistance on both sides of the p-n junction is matched to reduce current crowding. [0092] The device is an LED, and top and bottom III-nitride layers of the LED are roughened to increase an extraction efficiency of the LED. [0093] The device is a VCSEL processed in a flip-chip geometry with one or more high reflectivity optical coatings to enhance light extraction or confine an optical mode in the VCSEL. [0094] The device is a multi junction solar cell or photodiode. [0095] A single metal contact deposition is used to fabricate contacts to n-type layers of the device. [0096] A top III-nitride layer of the tunnel junction eliminates the need for a p-contact grid. [0097] Each buried III-nitride layer is contacted, such that current flowing through each active region is controlled individually.
[0098] Block 804 represents other steps being performed, which may include the repeating of units for 0 to X times, as described above.
[0099] Block 806 represents the final result of the method, namely a III-nitride based semiconductor device fabricated by the method, and comprising: one or more light-emitting or light-absorbing structures grown by MOCVD, wherein the light-emitting or light-absorbing structures include one or more p-type III-nitride layers; and one or more tunnel junctions grown by ammonia or plasma-assisted MBE on the light-emitting or light-absorbing structures, wherein the tunnel junctions include one or more n-type III-nitride layers that are grown on the p-type III-nitride layers of the light-emitting or light-absorbing structures, and a regrowth interface between the p-type III-nitride layers and the n-type III-nitride layers serves as a p-n interface in the tunnel junction.
REFERENCES
[0100] The following publications, referenced above are relevant to this disclosure: [0101] [1] L. Esaki, Physical Review 109, (1958). [0102] [2] J. Simon et al. Science 327 (5961): 60-64. [0103] [3] S. Krishnamoorthy et al., Appl. Phys. Lett. 105, 141104 (2014). [0104] [4] S. Krishnamoorthy et al., Nano Lett. 13, 2570-2575 (2013). [0105] [5] K. Iga, “Surface-Emitting Laser—Its Birth and Generation of New Optoelectronics Field,” IEEE J. Sel. Top. Quantum Electron., Vol. 6, No. 6, pp. 1201-1215, 2000. [0106] [6] K. Iga, “Vertical-cavity surface-emitting laser: Its conception and evolution,” Jpn. J. Appl. Phys., Vol. 47, pp. 1-10, 2008. [0107] [7] D. Feezell, “The Evolving GaN VCSEL,” Compound Semiconductor, pp. 1-10, 2014. [0108] [8] D. F. Feezell, “Status and future of GaN-based vertical-cavity surface-emitting lasers,” Proc. SPIE, Vol. 9363, pp. 93631G-1-13, 2015. [0109] [9] U.S. Pat. No. 6,515,308, issued Feb. 4, 2003, to Kneissl et al., and entitled “Nitride-based VCSEL or Light Emitting Diode With P-N Tunnel Junction Current Injection.” [0110] [10] U.S. Pat. No. 7,123,638, issued Oct. 17, 2006, to Leary et al., and entitled “Tunnel-Junction Structure Incorporating N-type Layer Comprising Nitrogen and a Group VI Dopant.” [0111] [11] EP Publication No. 1,403,935, published Apr. 21, 2010, by Collins et al., and entitled “Light Emitting Devices Including Tunnel Junctions.” [0112] [12] U.S. Pat. No. 6,724,013, issued Apr. 20, 2004, to Kneissl et al., and entitled “Edge-Emitting Nitride-Based Laser Diode with P-N Tunnel Junction Current Injection.” [0113] [13] U.S. Pat. No. 6,760,357, issued Jul. 6, 2004, to Boucart et al., and entitled “Vertical Cavity Apparatus With Tunnel Junction.”
CONCLUSION
[0114] This concludes the description of the preferred embodiment of the present invention. The foregoing description of one or more embodiments of the invention has been presented for the purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed. Many modifications and variations are possible in light of the above teaching. It is intended that the scope of the invention be limited not by this detailed description, but rather by the claims appended hereto.