Nozzle assembly, device for generating an atmospheric plasma jet, use thereof, method for plasma treatment of a material, in particular of a fabric or film, plasma treated nonwoven fabric and use thereof
11357093 · 2022-06-07
Assignee
Inventors
Cpc classification
International classification
Abstract
A nozzle assembly for generating an atmospheric plasma jet includes an inlet, through which the jet can be introduced into the nozzle assembly, and a channel connected to the inlet so that the plasma jet introduced is conducted through the channel. Multiple nozzle openings are provided in the channel wall along the channel, through which a plasma jet can exit the assembly. The cross section of the channel in the region of a nozzle opening is shaped in such a way that a virtual medial plane runs between a virtual first tangent plane of the cross section through the nozzle opening and a virtual second tangent plane of the cross section opposite thereto and parallel to the first tangent plane divides the cross section into a first cross-sectional area at the nozzle opening. The cross-sectional surface of the first cross-sectional area differs from the cross-sectional surface of the second.
Claims
1. A device for generating an atmospheric plasma jet, comprising: a discharge space, wherein the device is configured to generate the atmospheric plasma jet in the discharge space, wherein a nozzle assembly is connected to the discharge space in such a way that the atmospheric plasma jet generated in the discharge space is introduced into the nozzle assembly via an inlet of the nozzle assembly, wherein the nozzle assembly comprises a channel which is connected to the inlet of the nozzle assembly such that the atmospheric plasma jet introduced into the inlet of the nozzle assembly is conducted through the channel, wherein multiple nozzle openings are provided in a channel wall along the channel, through which the atmospheric plasma jet which is conducted through the channel can exit the nozzle assembly, wherein a reference medial plane runs in a middle of a cross-section of the channel between a reference lowermost plane of the cross-section across one nozzle opening of the multiple nozzle openings and a reference uppermost plane of the cross-section on a side of the channel opposite to the one nozzle opening, wherein the reference medial plane, the reference lowermost plane, and the reference uppermost plane are parallel to each other, and wherein the cross-section of the channel in a region of the one nozzle opening is shaped in such a way that the reference medial plane divides the cross-section into a first cross-sectional area adjacent to the one nozzle opening and a second cross-sectional area on the side of the channel opposite to the one nozzle opening, and wherein a cross-sectional surface of the first cross-sectional area differs in size or shape from a cross-sectional surface of the second cross-sectional area.
2. The nozzle assembly according to claim 1, wherein the channel has a straight section, and the multiple nozzle openings are arranged in the channel wall in an extension direction of the channel.
3. The nozzle assembly according to claim 1, wherein the channel is connected on both sides to the inlet, such that the plasma jet introduced into the nozzle assembly through the inlet is conducted into the channel from both sides.
4. The nozzle assembly according to claim 1, wherein a diameter of the multiple nozzle openings in the channel walling is at most a quarter of a diameter of the channel.
5. The nozzle assembly according to claim 1, wherein the cross section of the channel widens as a distance from the inlet increases.
6. The nozzle assembly according to claim 1, wherein the nozzle assembly is formed in several parts with a nozzle element, which comprises the channel with the multiple nozzle openings, and with a distributor element, which comprises a distribution channel through which the plasma jet introduced through the inlet is conducted to the channel on one or both sides of the channel.
7. The nozzle assembly according to claim 1, wherein the cross-sectional surface of the second cross-sectional area is greater than the cross-sectional surface of the first cross-sectional area.
8. The nozzle assembly according to claim 1, wherein the nozzle assembly is formed in several parts with a first part, in a surface of which a first recess is introduced, and with a second part in a surface of which a second recess is introduced, wherein the first part and the second part adjoin each other such that the first recess and the second recess face each other and form the channel.
9. The device according to claim 1, wherein the device is configured to generate the atmospheric plasma jet by means of an arc-like discharge in a working gas, wherein the arc-like discharge can be generated by applying a high-frequency high voltage between electrodes.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) In the drawings:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
DESCRIPTION OF THE INVENTION
(17) In the following, the design and operation of a device for generating an atmospheric plasma jet will first be described.
(18) The device 2 comprises a tubular housing 4 in the form of a metal nozzle tube. The nozzle tube 4 has at one of its ends a conical taper 6, on which a replaceable nozzle head 8 is mounted, the outlet of which forms a nozzle opening 10, from which the plasma jet 12 emerges during operation.
(19) At the end opposite the nozzle opening 10, the nozzle tube 4 is connected to a working gas supply line 14. The working gas supply line 14 is connected to a pressurised working gas source (not shown) with variable flow rate. During operation, a working gas 16 is introduced from the working gas source through the working gas supply line 14 into the nozzle tube 4.
(20) In the nozzle tube 4, a swirl device 18 is further provided with a rim of bores 20, arranged obliquely in the circumferential direction, through which the working gas 16 introduced into the nozzle tube 4 is swirled during operation.
(21) The downstream part of the nozzle tube 4 is therefore perfused by the working gas 16 in the form of a vortex 22, whose core runs on the longitudinal axis of the nozzle tube 4.
(22) In the nozzle tube 4, an inner electrode 24 is additionally centrally arranged, which extends in the nozzle tube 4 coaxially in the direction of the nozzle opening 10. The inner electrode 24 is electrically connected to the swirl device 18. The swirl device 18 is electrically insulated from the nozzle tube 4 by a ceramic tube 26. Via a high-frequency line 28, a high-frequency high voltage is applied to the inner electrode 24, which is generated by a transformer 30. The nozzle tube 4 is earthed via an earth line 32. The applied voltage generates a high-frequency discharge in the form of an electric arc 34 between the inner electrode 24 and the nozzle tube 4. This area in the nozzle tube 4 thus represents a discharge space 36 of the device 2.
(23) The terms “arc”, “arc discharge “and “arc-like discharge” are used herein as phenomenological descriptions of the discharge, since the discharge occurs in the form of an electric arc. The term “electric arc” is otherwise used as a discharge form in DC voltage discharges with substantially constant voltage values. In the present case, however, it is a high-frequency discharge in the form of an electric arc, i.e. a high-frequency arc-like discharge.
(24) Due to the swirling flow of the working gas, this electric arc 34 is channelled in the vortex core in the region of the axis of the nozzle tube 4, so that it branches only in the region of the taper 6 to the wall of the nozzle tube 4.
(25) The working gas 16, which rotates with high flow velocity in the region of the vortex core and thus in the immediate vicinity of the electric arc 34, comes into intimate contact with the electric arc 34 and is thereby partially transferred to the plasma state, so that an atmospheric plasma jet 12 emerges from the device 2 through the nozzle opening 10.
(26)
(27) The device 40 comprises the nozzle assembly 42 and the device 2 from
(28) The nozzle assembly 42 furthermore comprises a distributor element 50 composed of two parts 50a-b and a nozzle element 52. A groove 54 is introduced into the nozzle element 52, which forms a channel 56 having a first end 58 and a second end 60 in the assembled state of the nozzle assembly 42, as shown in
(29) The parts 50a-b of the distributor element 50 have respective grooves 64a-b which in the assembled state form a distribution channel 66. The distribution channel has a branch 68 and connects the inlet 48 to both the first end 58 and the second end 60 of the channel 56.
(30) When a plasma jet 12 is generated with the device 2 during operation, it passes through the inlet 48 at the connecting piece 44 into the distribution channel 66 and is thus conducted to both ends 58, 60 of the channel 56 and through the channel 56, so that it emerges from the nozzle assembly 42 in the form of a plurality of partial jets 70 from the nozzle openings 62. In this way, a curtain is generated of a plurality of partial jets 70 adjacent to one another, wherein the individual partial jets 70 have a reduced intensity in relation to the plasma jet 12, so that, for example, a nonwoven fabric 72 can be transported past the nozzle openings 62 for plasma treatment, without being damaged.
(31) The fact that the plasma jet 12 is introduced via the distribution channel 66 into the channel 56 on both sides, causes the individual partial jets 70 to have a relatively similar intensity. Optionally, the intensity of the individual partial jets 70 can be further evened out by forming the channel with a cross section that widens slightly from both ends 58, 60 to the centre of the channel, thereby counteracting an excessive pressure drop in the case of longer distances to the inlet 48.
(32) The nozzle assembly 42 also has an aluminium heat sink 74 with cooling fins 76 surrounding the other components, through which the heat load introduced into the nozzle assembly 42 by the plasma jet 12 can be dissipated.
(33)
(34) The nozzle assembly 42′ differs from the nozzle assembly 42 only in that the channel 56 is connected to the inlet 48 such that the plasma jet is directed into the channel 56 from one side. For this purpose, the distributor element 50′ and the nozzle element 52′ are formed as shown in
(35) To counteract an excessive pressure drop in the channel 56 and to equalise the intensities of the partial jets 70, the cross section of the channel 56 may optionally slightly expand as the distance from the inlet 48 increases (i.e. from left to right in
(36)
(37) The nozzle assembly 42″ differs from the nozzle assembly 42′ only in that an additional gas feed 57 is provided, through which a gas 59 can be introduced into the channel 56 separately from the plasma jet. For this purpose, the groove 54″ extends as shown in
(38)
(39) For this purpose, the web-type nonwoven fabric 72 may be transported past the nozzle openings of the device 40 (or alternatively also 40′ or 40″) as shown in
(40) In order to further reduce the load on the nonwoven web 72 during the plasma treatment, the nonwoven web 72 is transported over rollers 78a-b respectively in front of and behind the treatment region 77 with the device 40, such that the rollers rotate at the same speed. In this way, tensile forces are reduced on the nonwoven web 72 in the treatment region 77. To further reduce the tensile forces, a treatment table 79 in the form of an aluminium plate is provided, over which the nonwoven web 72 is transported in the treatment region 77. In the transport direction behind the treatment region 77 suction openings 80 are provided in the treatment table 79, through which the ozone or nitrogen oxides can be sucked, which arise in the case of the preferred use of nitrogen as a working gas for the device 2 and 40 respectively.
(41) Since the device 40 allows a damage-free treatment of delicate fabrics such as the nonwoven web 72 even under atmospheric pressure, the device can be operated as shown in
(42)
(43)
(44)
(45) The sanitary product 82 has a shaping outer layer 83, a superabsorbent layer 84 (‘absorbent core’), a distribution layer (ADL/AQL) 86 made of plasma-treated nonwoven fabric, for example the nonwoven fabric 72 from
(46) When used as intended, the cotton layer is in contact with the skin surface and ensures a pleasant skin sensation. The absorbent nonwoven fabric 88 arranged underneath is plasma-treated only in the middle 92, while the edges 94 are untreated. In this way, the absorbent nonwoven fabric 88 has hydrophilic properties in the centre 92, so that liquid is conducted effectively into the underlying distribution layer 86. On the edges 94, however, the absorbent nonwoven fabric 88 has hydrophobic properties, thereby preventing liquid from leaking at the edges of the sanitary product 82. The targeted plasma treatment in the centre 92 of the absorbent nonwoven fabric 88 can in particular replace the hydrophilisation used in the prior art, which is more complex in terms of process technology and because of the application of surfactants.
(47) The distribution layer 86 arranged below the absorbent nonwoven fabric 88 distributes the liquid in the surface, so that the liquid then reaches the underlying absorbent core 84 having been distributed over a larger area. The plasma treatment of the absorbent nonwoven fabric 88 allows the liquid to be absorbed more quickly by the distribution layer 86.
(48) Through the use of the plasma-treated nonwoven fabric 72 for the absorbent nonwoven fabric 88 and/or the distribution layer 86, the production costs of the sanitary product 82 can be reduced, since it is possible to achieve absorbing or distribution layers with a short strike-through time even with more cost-effective nonwoven fabrics 72.
(49)
(50) The device 100 shown in
(51) The nozzle assembly 42 is rotatable by means of a rotary actuator 102 about an axis perpendicular to the extension direction of the channel 56. In this way, with the partial jets 70 emerging from the nozzle openings 62, a larger surface area can be treated, so that the device 100 can be used for the large-area plasma treatment 100. In particular, the device 100 can be used for the plasma treatment of a fabric, in particular a nonwoven fabric, or a plastic film.
(52)
(53) The nozzle assembly 42 is rotatable about an axis parallel to the extension direction of the channel 56 by means of a rotary actuator 112. The device 110 can likewise be used for the plasma treatment of a fabric, in particular a nonwoven fabric, or a plastic film.
(54) Furthermore, the device 110 may also be used for other purposes. In particular, a tubular component can be impinged from the inside with plasma, using the partial jets 70 projecting from the nozzle openings 62, for example, to treat a pipe inner wall with plasma.
(55)
(56) The nozzle assembly 42″ differs from the nozzle assembly 42′ in that the nozzle element 52′ has a first channel-shaped recess 120 and the distributor element 50′″ has a second channel-shaped recess 122, wherein the distributor member 50′″ and the nozzle element 52″ adjoin each other such that the first and second channel-shaped recesses 120 and 122 face each other and form the channel 56′″. By this configuration, various cross-sectional shapes of the channel 56′″ can be easily produced by shaping the recesses 120 and 122 accordingly. The nozzle openings 62 emanate from the first recess 120.
(57) For example, each of the first and second channel-shaped recesses 120, 122 may have a semicircular cross section of the same radius, so that the channel 56′″ has a circular cross section. The radius of the two semicircular cross sections of the first and second recesses 120, 122 may, for example, decrease continuously in the extension direction of the channel 56″, so that a channel 56′″ with a decreasing cross section results. Such a cross section of the channel 56′″ can be much more cost-effective and easier to produce with the two recesses 120, 122 than in a channel made of solid material.
(58)
(59)
(60)
(61) In the middle between the virtual first and second tangent plane 130 and 132, the virtual medial plane 134 is shown, which divides the cross section 124′ into a first cross-sectional area 126′ at the nozzle opening 62 and into a second cross-sectional area 128′ opposite the nozzle opening 62. Due to the different semicircular radii of the two recesses 120′ and 122′, the cross-sectional surface in the second cross-sectional area 128′ is greater than the cross-sectional surface in the first cross-sectional area 126′.
(62)
(63)
(64) The position of the virtual medial plane 134 is in principle independent of the contact surface between nozzle element 52′″ and distributor element 50′″. Thus, the medial plane 134 may coincide with the contact surface (see
(65) Experiments have shown that a more uniform distribution of the plasma power to the partial jets emerging from the individual nozzle openings 62 can be achieved by an asymmetrical cross section of the channel 56′″, as shown for example in
(66) Experiments have been performed which show the advantages of an asymmetrical channel cross section. For this purpose, in each case a device was operated which corresponded to the device 40′″ from
(67) The nozzle assemblies are respectively arranged at the top in
(68)
(69)
(70)
(71) A comparison of the photographs in
(72) A particularly uniform distribution of the plasma jet to the partial jets was achieved with the channel cross section 142 (see