METHOD AND SHAFT FURNACE FOR BURNING CARBON-CONTAINING MATERIAL IN A SHAFT FURNACE

Abstract

A shaft furnace for firing carbonate-containing material may include, in a flow direction of the material, a preheating zone, a firing zone, a cooling zone, and a material outlet for discharging the material from the shaft furnace. Burner lances project into the firing zone. At least one burner lance has a first penetration depth into the firing zone and at least one further burner lance has a second penetration depth into the firing zone that is greater than the first penetration depth. A primary air conduit may be configured to convey combustion air and may be connected to at least one burner lance. An oxygen conduit for conveying oxygen into the firing zone may be arranged such that oxygen flows from the oxygen conduit at least one burner lance having the second penetration depth.

Claims

1.-17. (canceled)

18. A shaft furnace for firing material that contains carbonate, the shaft furnace comprising: in a flow direction of the material, a preheating zone, a firing zone, a cooling zone, and a material outlet for discharging the material; burner lances that project into the firing zone, wherein a first of the burner lances has a first penetration depth into the firing zone and a second of the burner lances has a second penetration depth into the firing zone that is greater than the first penetration depth; a primary air conduit comprising: a first primary air conduit for conveying combustion air, the first primary air conduit being connected to the first burner lance, and a second primary air conduit for conveying combustion air, the second primary air conduit being connected to the second burner lance; and an oxygen conduit for conveying oxygen into the firing zone, wherein the oxygen conduit is disposed such that oxygen is configured to flow from the oxygen conduit to the second burner lance, wherein the oxygen conduit is connected exclusively to the second primary air conduit so that oxygen is configured to flow from the oxygen conduit into the second primary air conduit.

19. The shaft furnace of claim 18 wherein the oxygen conduit is connected to the second burner lance so that oxygen for combustion of fuel is configured to flow into the second burner lance.

20. The shaft furnace of claim 18 wherein the oxygen conduit is connected exclusively to burner lances that have the second penetration depth.

21. The shaft furnace of claim 18 wherein the oxygen conduit comprises means for regulating an amount of oxygen flowing through the oxygen conduit.

22. The shaft furnace of claim 18 wherein a third of the burner lances has a third penetration depth into the firing zone that is greater than the first penetration depth but less than the second penetration depth, wherein the oxygen conduit is connected to the third burner lance so that oxygen flows into the third burner lance.

23. The shaft furnace of claim 22 wherein the oxygen conduit comprises means for regulating an amount of oxygen flowing through the oxygen conduit, wherein the means for regulating is configured such that the amount of oxygen configured to flow to the second burner lance is greater than an amount of oxygen configured to flow to the third burner lance.

24. A shaft furnace for firing material containing carbonate, the shaft furnace comprising: in a flow direction of the material, a preheating zone, a firing zone, a cooling zone, and a material outlet for discharging the material; burner lances that project into the firing zone, wherein a first of the burner lances has a first penetration depth into the firing zone and a second of the burner lances has a second penetration depth into the firing zone that is greater than the first penetration depth; a first primary air conduit for conveying primary combustion air, the first primary air conduit being connected to the first burner lance; and a second primary air conduit for conveying primary combustion air, the second primary air conduit being connected to the second burner lance, wherein the second primary air conduit extends at least partly through a preheating device for heating the primary combustion air in the second primary air conduit.

25. The shaft furnace of claim 24 wherein the second primary air conduit is connected exclusively to the second burner lance so that preheated primary combustion air is configured to be fed exclusively to the second burner lance.

26. The shaft furnace of claim 24 comprising the preheating device, wherein the preheating device comprises a preheating zone within the shaft furnace, wherein the second primary air conduit runs at least partly through the preheating zone.

27. The shaft furnace of claim 26 wherein the second primary air conduit comprises immersion conduits that extend at least partly or completely through the preheating zone.

28. The shaft furnace of claim 24 wherein at least one of: the first penetration depth is equal to or less than one third of a radius of the firing zone; or the second penetration depth is about one third of the radius of the firing zone.

29. A process for firing material that contains carbonate in a shaft furnace, the process comprising: causing the material to flow through a preheating zone, a firing zone, and a cooling zone to a material outlet; introducing fuel in the firing zone or adjacent thereto via burner lances, wherein a first of the burner lances has a first penetration depth and a second of the burner lances has a second penetration depth that is greater than the first penetration depth; conveying primary combustion air to the burner lances; and conveying oxygen along with the primary combustion air to burner lances that have the second penetration depth or conveying oxygen into a primary air conduit that conveys the primary combustion air to the burner lances that have the second penetration depth.

30. The process of claim 29 comprising enriching the primary combustion air with oxygen to have an oxygen content of 40% to 90%.

31. A process for firing material that contains carbonate in a shaft furnace, the process comprising: causing the material to flow through a preheating zone, a firing zone, and a cooling zone; introducing fuel in the firing zone or adjacent thereto via burner lances, wherein a first of the burner lances has a first penetration depth and a second of the burner lances has a second penetration depth that is greater than the first penetration depth; and conveying primary combustion air that has been preheated exclusively to burner lances that have the second penetration depth.

32. The process of claim 31 comprising preheating the primary combustion air to a temperature of 250° C. to 500° C.

Description

DESCRIPTION OF THE DRAWINGS

[0033] The invention will be illustrated below with the aid of a number of working examples and with reference to the accompanying figures.

[0034] FIG. 1 shows a schematic depiction of a shaft furnace having an oxygen conduit in sectional view according to one working example.

[0035] FIG. 2 and FIG. 3 shows a schematic depiction of a shaft furnace in a cross-sectional view according to different embodiments.

[0036] FIG. 4 shows a schematic depiction of a shaft furnace having primary air preheating in a sectional view according to a working example.

[0037] FIG. 1 shows a shaft furnace 10 for firing, for example, carbon-containing material having a particle size of from about 10 to 50 mm, preferably from 40 to 80 mm, in particular from 30 to 60 mm. The shaft furnace 10 comprises a shaft space 12 which preferably extends in the vertical direction and has, for example, a constant cross section or a cross section which widens in the flow direction of the material being fired. For example, the shaft space 12 has a round, in particular circular, or angular, in particular quadrilateral, cross section. The shaft space 12 is surrounded by a shaft wall 14 which is, for example, made of steel with an adjoining refractory masonry interior wall. The shaft space 12 is open at the top and at the bottom, with the shaft furnace 10 having a material inlet 16 which is configured as upper opening of the shaft space 12 and preferably extends over the entire cross section of the shaft space 12. The material inlet 16 serves for introducing material to be fired into the shaft furnace 10. A further embodiment comprises, instead of the open material inlet 16 depicted in FIG. 1, a material lock which makes it possible to introduce the material to be fired from a material feed device into the furnace shaft, with the material lock having the task of largely preventing entry of ambient air into the top of the furnace. This embodiment is preferably used when the furnace offgas is to have a high carbon dioxide concentration and a low oxygen concentration as is necessary for downstream processes such as milling/drying of coal, beet sugar process, soda process or for the production of precipitated calcium carbonate. The flow direction of the material is denoted by an arrow in FIG. 1 and runs vertically from the top downward through the shaft furnace 10.

[0038] In the flow direction of the material, the shaft furnace 10 comprises a preheating zone 18 following the material inlet 16, a firing zone 20 and a cooling zone 22. The cooling zone 22 is followed by the outlet funnel 24 which ends in a material outlet 26 for discharging the material from the shaft furnace 10. In the outlet funnel 24, there is, for example, a discharge device 23 which serves to discharge material from the cooling zone 22 of the shaft furnace 10 into the outlet funnel 24. The discharge device 23 is, for example, a rotating plate or a pusher table. Underneath the material outlet 26, there is, for example, either a tightly closing material discharge flap or, if required, a tightly closing material lock. The material flows essentially under the action of gravity through the shaft furnace 10 and is thermally treated in countercurrent. The height of the shaft space 12 is preferably determined by the process residence times of the material being fired to be determined in conjunction with the setting of the transport speed by means of the discharge device 23. These residence times are distributed over the upper preheating zone 18 adjoining the material inlet 16, the firing zone 20 which follows in a downward direction and the cooling zone 22 which runs to the discharge device 23. The material to be fired is preferably preheated to a temperature of up to about 800° C. in the preheating zone 18, with the firing zone 20 having, for example, a temperature of from 800° C. to 1800° C. and the fired material being cooled back down to about 100° C. in the cooling zone.

[0039] The shaft furnace 10 comprises one or more air inlets 28, 30 for introducing air into the shaft furnace 10. For example, two air inlets 28, 30 are arranged in the shaft furnace 10 of FIG. 1 and introduce air into the outlet funnel 24 and also into the displacement body 23a. The air is preferably blown into the outlet funnel 24, for example into the displacement body 23a, with a gauge pressure of up to 500 mbar. The air will be referred to as secondary air in the following. The secondary air flows through the shaft furnace 10, in particular the shaft space 12, from the bottom upward in a vertical direction and in countercurrent to the material. The material inlet 16 at the same time represents, for example, an air outlet, more precisely an outlet for the total furnace offgas of the shaft furnace 10.

[0040] The shaft furnace 10 further comprises a plurality of burner lances 32, 34 which extend through the shaft wall 14 into the firing zone 20 of the shaft space 12. For example, the burner lances 32, 34 are arranged in two planes in FIG. 1, with the burner lances 32 of the upper plane having a first penetration depth into the shaft space 12 and the burner lances 34 of the lower plane having a second penetration depth into the shaft space 12. The first penetration depth of the burner lances 32 is preferably smaller than the second penetration depth of the burner lances 34 of the lower plane. It is likewise conceivable for the lower burner lances 34 to have a smaller penetration depth than the upper burner lances 32 arranged above them. The burner lances 34 having the second penetration depth are, for example, arranged entirely below the burner lances 32 having the first penetration depth. The burner lances 32, 34 each extend in the radial direction of the shaft space 12 into the latter, with the burner lances 34 penetrating more deeply extending, for example, over about two thirds of the radius of the shaft space 12. The burner lances 32 which penetrate less deeply extend, for example, over about one third of the radius of the shaft space 12. Gaseous, pulverulent or liquid fuel is introduced together with primary air into the firing zone 20 via the burner lances 32, 34. The different penetration depths of the burner lances 32, 34 lead to a different depth of the flames exiting from the burner lances 32, 34 within the firing zone 20 and thus ensure uniform heating of the material. A plurality of measurement probes for temperature measurement, which are not shown in FIG. 1, are preferably arranged over the cross section of the shaft space 12. A uniform temperature distribution over the cross section of the firing zone 20 can be checked by means of the temperature values measured in a plane of the firing zone 20. The temperature distribution can likewise be checked by means of targeted sampling of material at the discharge device 23, with samples of material from the inner region and the outer region of the shaft space 12 being checked.

[0041] The burner lances 32, 34 have, for example, a cooling jacket (not shown) for cooling a burner tube arranged within the cooling jacket. A cooling liquid preferably flows through the cooling jacket. It is likewise conceivable for the cooling jacket to be operated without a cooling liquid and be made of a heat-resistant material.

[0042] The shaft furnace 10 also comprises, for example, two primary air conduits 36, 38 for conveying air to the burner lances 32, 34. The primary air conduits 36, 38 are each connected to a fan 40, 42, preferably a compressor, so that the air is supplied through the primary air conduits 36, 38 in the direction of the burner lances. Each primary air conduit 36, 38 is connected to a respective ring conduit 44, 46 which respectively extends around the circumference of the shaft wall 14. The ring conduits 44, 46 are, for example, arranged above the burner lances 32, 34. Each ring conduit 44, 46 is connected to a plurality of burner lances 32, 34; in FIG. 1, the ring conduit 46 which is arranged above the ring conduit 44 is by way of example connected to the burner lances 34 having the greater penetration depth. For example, the shaft furnace comprises a first primary air conduit 36 which is connected to a first ring conduit 44. The lower, first ring conduit 44 is, for example, connected exclusively to the burner lances 32 having the first penetration depth, so that air flows through the first primary air conduit 36 into the first ring conduit 44 and to the burner lances 32 having the first, smaller penetration depth. The shaft furnace also comprises a second primary air conduit 38 which is connected to a second ring conduit 46. The upper, second ring conduit 46 is, for example, connected exclusively to the burner lances 34 having the second penetration depth, so that air flows through the second primary air conduit 38 into the second ring conduit 46 and to the burner lances 34 having the second, greater penetration depth. An oxygen conduit 52 having an oxygen inlet 48 is connected to the second primary air conduit 38. The oxygen conduit 52 comprises a valve 50 for regulating the amount of oxygen. The oxygen conduit 52 is connected to the second primary air conduit 38 so that oxygen flows into the second primary air conduit 38. The oxygen-enriched primary air flows through the second primary air conduit 38 into the upper, second ring conduit 46 and subsequently into the burner lances 34 having the second, greater penetration depth. The amount of oxygen flowing into the second primary air conduit 38 can be set via the valve 50. Primary air enriched with oxygen is fed exclusively to the burner lances 34 having the second penetration depth. The burner lances 32 having the first penetration depth are not connected to the oxygen inlet 48. The combustion air flowing through the second primary air conduit is preferably enriched with oxygen to such an extent that the mixture of air and oxygen has an oxygen content of from 40 to 90%.

[0043] It is likewise conceivable for the burner lances 32, 34 to be arranged in more than two planes or only in one plane, with, for example, burner lances 32 having the first penetration depth and burner lances 34 having the second penetration depth being arranged together in one plane. For example, the shaft furnace has three, four or five planes of burner lances 32, 34, with exclusively the burner lances 34 having the greatest penetration depth being connected to the oxygen conduit 52.

[0044] During operation of the shaft furnace 10, material to be fired is introduced via the material inlet 16 from above into the shaft space 12 and moves downward under the action of gravity in the vertical direction through the shaft space 12 in the direction of the discharge device 23. Secondary air or firing offgases flow in countercurrent to the material. The secondary air introduced from below through the air inlets 28, 30 into the shaft space 12 is used as combustion air in the firing zone and serves to burn a fuel, for example natural gas, heating oil or coil dust, introduced through the burner lances 32, 34 into the firing zone 20. The offgases of the combustion serve to preheat the material in the preheating zone 18 of the shaft space 12. After the preheating zone 18, the material enters the firing zone 20 and is fired, for example, calcined and/or sintered there. It is subsequently cooled by the secondary air in the cooling zone 22, with the secondary air heating up at the same time.

[0045] FIG. 2 and FIG. 3 each show a cross section through the shaft furnace 10 as depicted in FIG. 1, with different arrangements of burner lances 32, 34 being shown. FIG. 2 shows a plurality of burner lances 32 having a first penetration depth and a plurality of burner lances 34 having a second penetration depth which is greater than the first penetration depth. Furthermore, FIG. 2 also shows, by way of example, a plurality of burner lances 54 having a third penetration depth which is smaller than the second penetration depth and greater than the first penetration depth. The burner lances 32, 34, 54 are, for example, all arranged in one plane and offset relative to one another. For example, the different penetration depths of the burner lances 32, 34, 54 alternate regularly around the circumference of the firing zone 20.

[0046] For example, exclusively the burner lances 34 are connected to the oxygen conduit 52, and oxygen, especially oxygen-enriched primary air, is fed exclusively to the burner lances 34. It is also conceivable for oxygen to be fed to the burner lances 54 having the third, middle penetration depth, with the amount of oxygen fed to the burner lances 54 having the third penetration depth being able to be smaller than the amount of oxygen fed to the burner lances 34 having the second penetration depth. The greatest amount of oxygen is preferably fed to the burner lances having the greatest penetration depth. For example, the shaft furnace 10 has twelve burner lances 32 having the first penetration depth, four burner lances 34 having the second penetration depth and eight burner lances 54 having the third penetration depth in the sectional plane depicted in FIG. 1. This is merely illustrative, and any number of burner lances 32, 34, 54 having different penetration depths is conceivable. For example, the burner lances of the shaft furnace 10 have three, four or more different penetration depths, with the greatest amount of oxygen being fed to the burner lances having the greatest penetration depth. For example, the shaft furnace comprises a third primary air conduit which is connected to a further oxygen conduit. The third primary air conduit is preferably connected to a third ring conduit, with the third ring conduit being connected to the burner lances 54 having the third penetration depth, so that oxygen-enriched primary air flows through the third primary air conduit to the burner lances 54 having the third penetration depth.

[0047] FIG. 3 shows further working examples of the arrangement of the burner lances 32, 34 having the first and second penetration depths. For example, twelve burner lances 32 having the first penetration depth and four burner lances 34 having the second penetration depth are provided. The burner lances 34 having the second penetration depth are preferably supplied with oxygen-enriched primary air, with primary air without oxygen enrichment being supplied to the burner lances 32 having the first penetration depth, so that the primary air fed to the burner lances 32 having the first penetration depth has a lower proportion of oxygen than the primary air fed to the burner lances 34 having the second penetration depth.

[0048] FIG. 4 shows a shaft furnace 10 which corresponds at least largely to the shaft furnace 10 of FIG. 1, with identical elements being denoted by identical reference numerals. The shaft furnace 10 additionally comprises a gas outlet 56 for discharging the offgas from the shaft furnace 10. Such a gas outlet 56 is, for example, also present in the shaft furnace 10 of FIG. 1. In contrast to the shaft furnace of FIG. 1, the shaft furnace depicted in FIG. 4 comprises a second primary conduit 38 which partly runs through the preheating zone of the shaft space 12. The second primary air conduit 38 preferably comprises a first ring conduit 58 and a second ring conduit 60 arranged below the first ring conduit 58. The ring conduits 58, 60 are arranged around the outer circumference of the shaft space 12. The second primary air conduit comprises, for example, a plurality of immersion conduits 62 which are, for example, configured either with a U-shape or as double tube and extend from the first ring conduit 58 through the preheating zone 18 to the second ring conduit 60. The immersion conduits 62 preferably extend over part of the preheating zone 18 or the entire preheating zone 18. The second ring conduit 60 of the second primary air conduit 38 is connected to the ring conduit 46 so that preheated primary air flows to the burner lances 34 having the second penetration depth. The preheated primary air is preferably fed exclusively to the burner lances 34 having the second penetration depth.

[0049] During operation of the shaft furnace 10, part of the heat energy present in the combustion gases is used for heating the primary air, so that the preheated primary air is fed exclusively to the burner lances 34 having the second penetration depth. This heating of the primary air occurs within the shaft space 12 by the primary air being conveyed through immersion tubes 62 which dip into the firing material of the preheating zone 18 and are, for example, distributed, preferably uniformly, over the shaft space cross section in the circumferential direction of the shaft space 12. The immersion tubes 62 preferably have an identical configuration and are preferably arranged at equal distances from one another. The immersion tubes 62 preferably comprise a material which has a high thermal conductivity. The arrangement of the immersion tube 62 in the shaft space 12 in direct contact with the material being fired and the firing gases leads to particularly good heat transfer by thermal conduction, convection and thermal radiation. In addition, the heat exchange surfaces of the immersion tube 62 are automatically cleaned by the firing material flowing along them under the action of gravity.

[0050] A combination of the working example of FIGS. 1, 2, 3 and 4 is likewise conceivable. For example, the second primary air conduit 38 of FIG. 4 has an oxygen inlet for introducing oxygen into the second primary air conduit 38 so that oxygen-enriched and preheated primary combustion air is supplied to the burner lances 34 having the second penetration depth.

[0051] The cross sections of the shaft furnace 10 shown in FIGS. 2 and 3 can also be applied to the working example of the shaft furnace 10 depicted in FIG. 4, with, for example, primary air having a lower temperature compared to the primary air fed to the burner lances 34 having the second penetration depth being fed to the burner lances 54 having the third penetration depth. For example, primary air having a lower temperature compared to the primary air fed to the burner lances 34 having the second penetration depth is fed to the burner lances 54 having the third penetration depth.

LIST OF REFERENCE NUMERALS

[0052] 10 Shaft furnace [0053] 12 Shaft space [0054] 14 Shaft wall [0055] 16 Material inlet [0056] 18 Preheating zone [0057] 20 Firing zone [0058] 22 Cooling zone [0059] 23 Discharge device [0060] 23a Displacement body [0061] 24 Outlet funnel [0062] 26 Material outlet [0063] 28 Air inlet [0064] 30 Air inlet [0065] 32 Burner lance having the first penetration depth [0066] 34 Burner lance having the second penetration depth [0067] 36 First primary air conduit [0068] 38 Second primary air conduit [0069] 40 Fan [0070] 42 Fan [0071] 44 Ring conduit [0072] 46 Ring conduit [0073] 48 Oxygen inlet [0074] 50 Valve [0075] 52 Oxygen conduit [0076] 54 Burner lance having the third penetration depth [0077] 56 Gas outlet [0078] 58 Ring conduit [0079] 60 Ring conduit [0080] 62 Immersion conduits