PASSIVE REFRIGERATION SYSTEM USING CARBON DIOXIDE SNOW
20220170684 · 2022-06-02
Inventors
- Will SPAULDING (Victoria, CA)
- Adrian GUNSTONE (Victoria, CA)
- Liam WELGAN-GUNN (Victoria, CA)
- Eldad ALBER (Victoria, CA)
- Nigel DAVID (Victoria, CA)
Cpc classification
F25D3/122
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A passive refrigeration apparatus comprising: (i) a container defining a cargo space; (ii) a liquid carbon dioxide cylinder; (iii) a control valve, in fluid communication with the cylinder; (iv) a controller for activating the control valve to control the flow of liquid CO2; and (v) a heat transfer assembly within the container, in fluid communication with the control valve; wherein the heat transfer assembly has (a) an expansion section for receiving the flow of liquid CO2; and (b) an expansion chamber bounded by a heat transfer surface in thermal contact with the cargo space; wherein the expansion section allows the vaporization of the liquid CO2 into the expansion chamber to create a mixture of carbon dioxide snow and CO2, thereby cooling the cargo space via the heat transfer surface.
Claims
1. A passive refrigeration apparatus for controlled refrigeration of a product, the refrigeration apparatus comprising: an insulated container, the container defining a cargo space for receiving a load; a cylinder for supplying a flow of liquid carbon dioxide (CO.sub.2); a control valve, in fluid communication with the cylinder, via a fluid pipe; a controller, adapted to activate and deactivate the control valve, to control the flow of liquid CO.sub.2; a heat transfer assembly, disposed within the container, and in fluid communication with the control valve; and an exhaust fluid line in fluid communication with the heat transfer assembly; wherein the heat transfer assembly comprises; an expansion section, in fluid communication with the control valve, and for receiving the flow of liquid CO.sub.2; and an expansion chamber, the expansion chamber bounded by at least one heat transfer surface, the at least one heat transfer surface in thermal contact with the cargo space; wherein the expansion section is adapted to allow a vaporization of the liquid CO.sub.2 into the expansion chamber in order to create a mixture of carbon dioxide snow and CO.sub.2 gas within the expansion chamber, thereby cooling the cargo space via the at least one heat transfer surface, and wherein the CO.sub.2 gas may be exhausted through the exhaust fluid line; and wherein the heat transfer assembly additionally comprises at least one bluff body, disposed within the expansion chamber and proximate to the expansion section, wherein the at least one bluff body facilitates generation of turbulence within the expansion chamber, in order to facilitate creation and accumulation of carbon dioxide snow.
2. The apparatus of claim 1, wherein the apparatus additionally comprises a sensor for measuring a measured parameter within the cargo space or outside of the cargo space, wherein the sensor is in communication with the controller, and wherein the controller activates or deactivates the control valve in response to the measured parameter.
3. The apparatus of claim 2, wherein the sensor is a temperature sensor located within the cargo space, and wherein the measured parameter is an internal temperature of the of the cargo space, and wherein the controller activates or deactivates the control valve in order to control the internal temperature of the cargo space.
4. The apparatus of claim 2, wherein the sensor is a pressure sensor, and the measured parameter is pressure.
5. The apparatus of claim 2, wherein the sensor is a humidity sensor, and the measured parameter is humidity.
6. The apparatus of claim 2, wherein the sensor is a carbon dioxide sensor, and the measured parameter is carbon dioxide level or concentration within the cargo space.
7. The apparatus of claim 1, wherein the heat transfer assembly additionally comprises a filter for preventing carbon dioxide snow from entering the exhaust fluid line.
8. The apparatus of claim 1, wherein the heat transfer assembly additionally comprises one or more ridges disposed within the expansion chamber, and configured to facilitate accumulation of carbon dioxide snow.
9. The apparatus of claim 1, wherein the heat transfer assembly additionally comprises a mesh structure disposed within the expansion chamber, and configured to facilitate accumulation of carbon dioxide snow.
10. The apparatus of claim 1, wherein the container additionally comprises a door, and wherein the container is adapted to receive one or more pallet-sized loads.
11. The apparatus of 1, additionally comprising an exhaust manifold configured between the heat transfer assembly and the exhaust fluid line, and in fluid communication with the heat transfer assembly and the exhaust fluid line, wherein the exhaust manifold permits passage of the CO.sub.2 gas therethrough and is in thermal contact with the cargo space.
12. The apparatus of claim 11, wherein the exhaust manifold is configured in a serpentine configuration.
13. The apparatus of claim 1, wherein the heat transfer assembly is provided with a plurality of convective fins for facilitating heat transfer between the cargo space and the heat transfer assembly.
14. The apparatus of claim 1, wherein the heat transfer assembly is generally disposed in an upper portion of the cargo space.
15. The apparatus of claim 1, additionally comprising a barrier, disposed within the cargo space, for keeping the load from coming into contact with the heat transfer assembly.
16. The apparatus of claim 1, additionally comprising a barrier, disposed within the cargo space, the barrier configured to facilitate convective flow of cold air proximate the heat transfer assembly to a floor of the cargo space.
17. The apparatus of claim 1, provided with one or more additional heat transfer assemblies.
Description
BRIEF DESCRIPTION OF THE FIGURES
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DETAILED DESCRIPTION
[0036] A detailed description of one or more embodiments of the present disclosure is provided below along with accompanying figures that illustrate the principles of the disclosure. As such, this detailed description illustrates the present disclosure by way of example and not by way of limitation. The description will clearly enable one skilled in the art to make and use the disclosure, and describes several embodiments, adaptations, variations and alternatives and uses of the disclosure, including what is presently believed to be the best mode and certain embodiment for carrying out the disclosure. It is to be understood that routine variations and adaptations can be made to the disclosure as described, and such variations and adaptations squarely fall within the spirit and scope of the disclosure. For the purpose of clarity, technical material that is known in the technical fields related to the disclosure has not been described in detail so that the disclosure is not unnecessarily obscured.
[0037] Except as otherwise expressly provided, the following rules of interpretation apply to this specification (written description, claims and drawings): (a) all words used herein shall be construed to be of such gender or number (singular or plural) as the circumstances require; (b) the singular terms “a”, “an”, and “the”, as used in the specification and the appended claims include plural references unless the context clearly dictates otherwise; (c) the antecedent term “about” applied to a recited range or value denotes an approximation within the deviation in the range or value known or expected in the art from the measurements method; (d) the words “herein”, “hereby”, “hereof”, “hereto”, “herein before”, and “hereinafter”, and words of similar import, refer to this specification in its entirety and not to any certain paragraph, claim or other subdivision, unless otherwise specified; (e) descriptive headings are for convenience only and shall not control or affect the meaning or construction of any part of the specification; and (f) “or” and “any” are not exclusive and “include” and “including” are not limiting. Further, the terms “comprising,” “having,” “including,” and “containing” are to be construed as open-ended terms (i.e., meaning “including, but not limited to,”) unless otherwise noted.
[0038] Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. Where a specific range of values is provided, it is understood that each intervening value, to the tenth of the unit of the lower limit unless the context clearly dictates otherwise, between the upper and lower limit of that range and any other stated or intervening value in that stated range, is included therein. All smaller sub ranges are also included. The upper and lower limits of these smaller ranges are also included therein, subject to any specifically excluded limit in the stated range.
[0039] Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the relevant art. Although any methods and materials similar or equivalent to those described herein can also be used, the acceptable methods and materials are now described.
[0040] The term “computer” can refer to any apparatus that is capable of accepting a structured input, processing the structured input according to prescribed rules, and producing results of the processing as output. Examples of a computer include: a computer; a general purpose computer; a desktop computer, a network computer, a laptop computer; a computer on a smartphone or other portable device, a supercomputer; a mainframe; a super mini-computer; a mini-computer; a workstation; a micro-computer; a server; an interactive television; a hybrid combination of a computer and an interactive television; and application-specific hardware to emulate a computer and/or software. A computer can have a single processor or multiple processors, which can operate in parallel and/or not in parallel. A computer also refers to two or more computers connected together via a network for transmitting or receiving information between the computers. An example of such a computer includes a distributed computer system for processing information via computers linked by a network. The techniques described herein may be implemented by one or more special-purpose computers, which may be hard-wired to perform the techniques, or which may include digital electronic devices such as one or more application-specific integrated circuits (ASICs) or field programmable gate arrays (FPGAs) that are persistently programmed to perform the techniques, or which may include one or more general purpose hardware processors programmed to perform the techniques pursuant to program instructions in firmware, memory, other storage, or a combination. Such special-purpose computers may also combine custom hard-wired logic, ASICs, or FPGAs with custom programming to accomplish the techniques.
[0041] The term a “computer system” may refer to a system having a computer, where the computer comprises a computer-readable medium embodying software to operate the computer.
[0042] The term “computer-readable medium” may refer to any storage device used for storing data accessible by a computer, as well as any other means for providing access to data by a computer. Examples of a storage-device-type computer-readable medium include: a magnetic hard disk; a solid state drive; a floppy disk; an optical disk, such as a CD-ROM and a DVD; a magnetic tape; or a memory chip.
[0043] The term “software” can refer to prescribed rules to operate a computer. Examples of software include: software; code segments; instructions; computer programs; and programmed logic.
[0044] In accordance with one aspect of the present disclosure,
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[0046] The conversion from compressed liquid CO.sub.2, upstream of orifice 16, to solid CO.sub.2 (dry ice) and gaseous CO.sub.2 in expansion chamber 18, is a multistage conversion process guided and enhanced by aspects of this disclosure.
[0047] As the liquid carbon dioxide goes from a high pressure between 20 and 70 bar ahead of orifice 16 to a larger cross-sectional area with a pressure below 5 bar, it reaches high axial velocity at the nozzle and significant radial velocities as it expands in section 17 and expansion chamber 18. As the pressure drops below 5.2 bar, the carbon dioxide is transformed from a liquid to a mixture of fine solid carbon dioxide and gas at a temperature below −56.5° C. For instance, within the expansion chamber 18, is located at least one turbulence generating feature, such as the exit edges of expansion section 17 or one or more bluff body 28. These features create a multitude of small turbulent vortices. The low-pressure cores of these vortices act to provide sites where CO.sub.2 solid crystals form and start to agglomerate into larger snow particles. Larger particles continue to travel downstream and may further agglomerate into even larger particles as they collide together in the turbulent flow or on the upstream faces of bluff bodies farther downstream. Amalgamation into large multi-crystalline formations (sometimes referred to herein as “dry ice snow” or “carbon dioxide snow”) is important as the crystals originally formed are so small that they could easily pass through the downstream accumulator filters 21 and leave the heat transfer assembly without the ability to absorb the heat that is key to the fundamental functioning of the present apparatus.
[0048] For instance, the present disclosure is provided with additional features that encourage the accumulation of solid carbon dioxide snow.
[0049] The cold gas resulting from the expansion and from the sublimation of the carbon dioxide cools the walls 23 of the expansion chamber 18, before exiting into at least one exhaust pipe 20. To prevent carbon dioxide snow from flowing down the exhaust pipe 20, a filter 21 may be used between the expansion chamber 18 and the exhaust pipe or pipes 20. For instance, a filter support 22 may also be provided to help provide structural support to the filter 21, in order to maintain an “air” gap between the filter 21 and the opening of the exhaust pipes 20 for the cold gas to flow into the exhaust pipes 20.
[0050] Referring to
[0051] An important feature of the heat transfer assembly 6 is that its surface areas be sufficient to provide the necessary level of cooling to the container 1. The needed level of cooling is, at minimum, at a level sufficient to overcome to expected heat input into the container under the most challenging temperature conditions, say when the desired temperature inside is −30° C. and the external temperature is 40° C. In practice, the needed level of cooling is greater than that strictly needed to overcome the heat input because the cool down time must be sufficiently short, say of the order of 30 minutes or less. The surface area can be calculated simply by taking the needed level of cooling and a natural convective heat transfer coefficient.
[0052] In accordance with another aspect, as an alternative to ridges 19, the expansion chamber 18, as shown in
[0053] Filter 21 serves to prevent the carbon dioxide snow from flowing directly to the exhaust 20, while not restricting the gas flow. The filter 21 may be selected to retain snow crystals that are, for example, 50 microns in diameter or greater. The filter 21 can be made of a material that retains sufficient strength at low temperature, such as polyester nylon or synthetic paper filter. Alternate locations and configurations of the filter 21 may be contemplated that achieve the same intent.
[0054] In addition, the heat transfer surfaces 23 can be configured to have a plurality of convective fins 29 on one or both of the heat transfer surfaces 23 as illustrated in
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[0056] It will be apparent to one skilled in the art that different configurations of and locations for the exhaust manifold are possible which achieve the same intent.
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[0058] In any of the exhaust systems, such as those shown as examples in
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[0060] While not specifically illustrated, it is also contemplated that in other embodiments, fans may be provided within the cargo space to facilitate the convective air flow within the cargo space, i.e. the downwards flow of the cooled, denser air near the heat transfer assembly, and the upward flow of the warmer air to replace the displaced cooled, denser air. These fans may be run continuously or intermittently, as required.
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[0063] Referring to
[0064] To prevent an over-accumulation of carbon dioxide snow within the expansion chamber 18, it may be desirable to measure at least one location 52 on the surface of the heat transfer assembly 6. The control approach above described can be modified to temporarily interrupt “injections” if the heat transfer assembly wall temperature is below a set threshold that may be set automatically, for example, at 20 to 40° C. below the target temperature.
[0065] Additional temperature measurements can be made for the purpose of providing improved control, such as, for example, the temperature external to the container 51 and the load temperature 53.
[0066] Temperatures 50, 51, 52 and 53 can be stored on the controller 9 as records that can be accessed and/or monitored by the owner or leaser of the container through a variety of possible means including automatic wireless transmission of the information.
[0067] It is contemplated that the controller can be equipped with various other features including:
(i) A display to show the current temperature, the set temperature and the status of the container (on or not) and other information that might be useful for the operation of the container, such as the battery charge level, cooling status and the container CO.sub.2 level. Alternatively the controller may broadcast such information such that it can be received or accessed by an external device;
(ii) One or more buttons to set the target temperature, or an alternative means to wirelessly set the internal target temperature with an external device;
(iii) An infrared sensor to monitor the load temperature without a wire;
(iv) One or more buttons to turn the cooling on and off for the container;
(v) A door interlock such that the cooling unit does not operate while the door is opened;
(vi) A means of storing and retrieving digital information (such as via a SD card or via wireless access);
(vii) A CO.sub.2 sensor to monitor the environmental CO.sub.2 level outside the container;
(viii) A humidity sensor to monitor the humidity in the cargo space;
(ix) A pressure sensor to monitor the pressure within the heat transfer assembly;
(x) A GPS location sensor; or
(xi) An algorithm to set the target temperature at the load temperature as measured by a temperature sensor.