Method of casting articles from aluminum alloys

Abstract

The invention relates to the field of aluminum metallurgy and can be used to produce ingots from high quality aluminum alloys when manufacturing aerospace and automotive products. The use of this invention relates to the technology of secondary modification. The method of casting products from aluminum alloys includes the following stages: a) aluminum melt preparation in the alloying furnace; b) addition alloy introduction into melt; c) degassing of the aluminum melt containing the addition alloy; d) addition alloy re-introduction; e) filtration of the aluminum melt obtained at stage d) and f) feeding the filtered melt into the crystallizer. It ensures the improved effectiveness of the aluminum melt modification with addition alloys without additional constructional changes in existing lines for aluminum ingot casting. It allows reducing the alloy modification costs, decreasing the grain in resulting alloys and improving plastic and mechanical properties of the obtained cast ingots and their products.

Claims

1. The method of casting products from aluminum alloys that includes the following stages a) Aluminum melt preparation in the alloying furnace; b) Al—Ti—B addition alloy introduction into the melt; c) Degassing of the aluminum melt with the addition alloy; d) Addition alloy re-introduction; e) Filtration of the aluminum melt obtained at stage d), wherein the molten metal filtration is carried out in two stages, and f) Feeding the filtered melt into the crystallizer, where the ratio of the addition alloy supplied amount at stage b) and stage d) is from 1:1 to 9:1, and the flow rate of the molten metal from the alloying furnace to the crystallizer is 10-16 cm/s.

2. The method according to claim 1 characterized in that the re-introduction of the addition alloy at stage d) is carried out before the first filtration stage.

3. The method according to claim 1 characterized in that the re-introduction of the addition alloy at stage d) is carried out before the second filtration stage.

4. The method according to claim 1, characterized in that the re-introduction of the addition alloy at stage d) is carried out in two stages—before the first filtration stage and before the second filtration stage.

5. The method according to any of claims 1 and 2-4 differs in that the first filtration stage uses the filtration system, which allows filtering out contaminations up to 5-9 μm in size.

6. The method according to any of claims 1 and 2-4 differs in that the first stage of filtration uses the refining unit with the system of filter cartridges.

7. The method according to any of claims 1 and 2-4 differs in that the second stage of filtration uses the coarse filter.

8. The method according to claim 7 characterized in that the coarse filter consists of the filter box with several filter elements, allowing to filter out contaminations up to 70 μm in size.

9. The method according to claim 8 characterized in that the ceramic foam filter is used.

10. The method according to claim 1 differs in that the strand addition alloy is used as the addition alloy.

11. The method according to claim 1 differs in that the AlTiB alloying rod is used as the addition alloy.

12. The method according to claim 11 characterized in that the melt temperature in the places of the addition alloy feed is 690-699° C.

13. The method according to claim 1 differs in that the amount of the addition alloy fed at stage b) and stage d) is in ratio of 2:1.

Description

IMPLEMENTATION OF THE INVENTION

(1) The molten aluminum from the alloying furnace is fed into the crystallizer through a system of casting troughs. A degassing unit, a fine filter and a coarse filter, namely a ceramic foam filter are built into the system of troughs. The melt is prepared in the alloying furnace as follows: the aluminum raw material coming from the pot room is poured into the furnace, and then the melt is alloyed and refined. After the melt preparation it is fed through the system of troughs, including degassing and filtration stages, to the crystallizers, where semi-continuous casting of flat ingots was performed.

(2) At the first stage, the melt undergoes a degassing stage. Degassing is carried out by feeding a certain amount of inert gas (for example, argon) to a system of rotating impellers; upward bubble flows in the melt are created under the influence of centrifugal force. The melt is saturated with bubbles. The intensive stirring of the melt occurs in the degassing unit; at the same time, oxides, non-metallic contaminants, hydrogen and other harmful impurities are removed from the melt by means of “grasping” them with gas bubbles and migrating to the slag.

(3) Then, the melt enters the first stage of filtration, which is a refining unit with a system of filter cartridges. The aluminum melt passes through the cartridges with a porous branched morphology; as a result, all impurities up to 5-9 μm are filtered out.

(4) At the third stage, the melt is fed into the coarse filter (the second stage of filtration) consisting of a filter box with several filter elements, which additionally purify the melt from unwanted particles up to 70 μm in size. Those particles can enter the melt after the fine filter, for example, during sampling, making measurements, violation of the lining integrity or technological process failure.

(5) Temperature control of the molten metal was carried out using thermocouples. The molten metal temperature in places of the alloying rod supply was 690-700° C.

(6) Practical experience shows that during the process of multi-crystal casting the rate of feeding the molten metal from the alloying furnace to the crystallizer should be 10-16 cm/s to ensure the more intense melting of the addition alloy.

(7) The alloying rod with the known AlTiB 5/1 composition in volume of 3 kg/t was used as the addition alloy.

(8) According to the first (variant 1) variant, the addition alloy was fed in two stages—the addition alloy was fed before the degassing stage and before the first stage of filtration in the ratio of 2:1. (FIG. 1)

(9) According to the second variant (variant 2), the addition alloy was fed before degassing in a distributed manner, before the first filtration stage and before the second filtration stage in the ratio of 3:1:1 (FIG. 2)

(10) According to the third variant (variant 3), part of the addition alloy was fed before degassing, and the rest of it was fed after the first filtration stage and before the second filtration stage (FIG. 3).

(11) The grain size of finished ingots was evaluated on the template selected from the middle of the ingot using a microscope. The macrostructures of the ingot templates, which were obtained with the use of the methods described in the mentioned variants, are presented in FIG. 4. The evaluation results are shown in Table 1.

(12) TABLE-US-00001 TABLE 1 Method of feeding addition alloy Grain size of the obtained ingot, μm Prototype 160 Variant 1 112 Variant 2 122 Variant 3 140

(13) It can be seen from the table that the smallest grain (112 μm) is typical for the ingot obtained by the method according to variant 1, namely, when the addition alloy is fed in two stages—some part of the addition alloy is fed before degassing and the remaining part of the total amount of the addition alloy, introduced in the casting process, is fed before the first filtration stage.

(14) Moreover, the addition alloy was additionally fed according to variant 1, at the same time changing the ratio of the amount of the addition alloy that was fed at the first stage and at the second stage: with ratio of 1:1 (Variant 1.1) and ratio of 1:9 (Variant 1.2).

(15) The size of the finished ingot grain was evaluated on the template selected from the middle of the ingot using a microscope. The macrostructures of the ingot templates, which were obtained using the methods described in the mentioned variants, are presented in FIG. 5. The evaluation results are shown in Table 2.

(16) TABLE-US-00002 TABLE 2 Method of feeding addition alloy Grain size of the obtained ingot, μm Variant 1.1 128 Variant 1.2 150

(17) Based on the results of the study presented in Table 1 and Table 2, it can be concluded that the claimed method helps achieve the more effective dissolution of the addition alloy, since its part is fed before the degasser, which allows to intensify the addition alloy melting process, reduce the size of the agglomerates, remove oxide scabs and non-metallic inclusions in the addition alloy, which hereinafter allows the particles to pass through the filter elements of the casting line more freely.

(18) However, as a result of the studies it was unexpectedly found that the maximum effect of the addition alloy introduction is observed in cases of two-stage introduction—before the degassing stage and before the filtration stage.

(19) When introducing some part of the addition alloy before the degassing stage and the second part before filtration at ratio of 1:9, grain grinding is observed compared to the prototype, as well as significant grinding (more than 2 times) comparing to the grain obtained with the introduction of the whole amount of the addition alloy before the filtration stage. Besides, the achieved effect is observed in various variants of introducing the second part of the addition alloy both before the first filtration stage, and when its second part is fed before the second stage of filtration, or before two filtration stages in case of two-stage filtration.

(20) In addition, it was unexpectedly found that the effect of decreasing the grain is stable with the same amount of the introduced addition alloy with all the stated variants of the addition alloy introduction into the melt. Even with the introduction of the larger part of the addition alloy before the degassing stage, there is no need to compensate its loss in the degassing process by means of increasing the total amount of the introduced addition alloy to decrease the grain size in the finished product.

(21) Thus, with the same amount of the addition alloy introduced into the melt using the claimed method, the technological plasticity of ingots increases and the level of mechanical properties of deformed semi-finished products increases to much greater extent than in case of the prototype.